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USGS2005

Petrology, mineralogy and geochemistry of mined coals, western Venezuela

Upper Paleocene to middle Miocene coal samples collected from active mines in the western Venezuelan States of Táchira, Mérida and Zulia have been characterized through an integrated geochemical, mineralogical and petrographic investigation. Proximate, ultimate, calorific and forms of sulfur values, major and trace element, vitrinite reflectance, maceral concentrations and mineral matter content have been determined for 16 channel samples from 14 mines. Ash yield generally is low, ranging from < 1 to 17 wt.% (mean = 5 wt.%) on a dry basis (db). Total sulfur content is low to moderate, ranging from 1 to 6 wt.%, db (average = 1.7 wt.%). Calorific value ranges from 25.21 to 37.21 MJ/kg (10,840–16,000 Btu/lb) on a moist, mineral-matter-free basis (average = 33.25 MJ/kg, 14,300 Btu/lb), placing most of the coal samples in the apparent rank classification of high-volatile bituminous. Most of the coal samples exhibit favorable characteristics on the various indices developed to predict combustion and coking behavior and concentrations of possible environmentally sensitive elements (As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, Th and U) generally are similar to the concentrations of these elements in most coals of the world, with one or two exceptions. Concentrations of the liptinite maceral group range from < 1% to 70 vol.%. Five samples contain > 20 vol.% liptinite, dominated by the macerals bituminite and sporinite. Collotelinite dominates the vitrinite group; telinite was observed in quantities of ≤ 1 vol.% despite efforts to better quantify this maceral by etching the sample pellets in potassium permanganate and also by exposure in an oxygen plasma chamber. Inertinite group macerals typically represent < 10 vol.% of the coal samples and the highest concentrations of inertinite macerals are found in distantly spaced (> 400 km) upper Paleocene coal samples from opposite sides of Lago de Maracaibo, possibly indicating tectonic controls on subsidence related to construction of the Andean orogen. Values of maximum reflectance of vitrinite in oil ( R o max ) range between 0.42% and 0.85% and generally are consistent with the high-volatile bituminous rank classification obtained through ASTM methods. X-ray diffraction analyses of low-temperature ash residues indicate that kaolinite, quartz, illite and pyrite dominate the inorganic fraction of most samples; plagioclase, potassium feldspar, calcite, siderite, ankerite, marcasite, rutile, anatase and apatite are present in minor or trace concentrations. Semiquantitative values of volume percent pyrite content show a strong correlation with pyritic sulfur and some sulfide-hosted trace element concentrations (As and Hg). This work provides a modern quality dataset for the western Venezuela coal deposits currently being exploited and will serve as the foundation for an ongoing coal quality research program in Venezuela.

International Journal of Coal Geology↗

USGS2007

Organic petrology of Paleocene Marcelina Formation coals, Paso Diablo mine, western Venezuela: Tectonic controls on coal type

About 7??Mt of high volatile bituminous coal are produced annually from the four coal zones of the Upper Paleocene Marcelina Formation at the Paso Diablo open-pit mine of western Venezuela. As part of an ongoing coal quality study, we have characterized twenty-two coal channel samples from the mine using organic petrology techniques. Samples also were analyzed for proximate-ultimate parameters, forms of sulfur, free swelling index, ash fusion temperatures, and calorific value. Six of the samples represent incremental benches across the 12-13??m thick No. 4 bed, the stratigraphically lowest mined coal, which is also mined at the 10??km distant Mina Norte open-pit. Organic content of the No. 4 bed indicates an upward increase of woody vegetation and/or greater preservation of organic material throughout the life of the original mire(s). An upward increase in telovitrinite and corresponding decrease in detrovitrinite and inertinite illustrate this trend. In contrast, stratigraphically higher coal groups generally exhibit a 'dulling upward' trend. The generally high inertinite content, and low ash yield and sulfur content, suggest that the Paso Diablo coals were deposited in rain-fed raised mires, protected from clastic input and subjected to frequent oxidation and/or moisture stress. However, the two thinnest coal beds (both 0.7??m thick) are each characterized by lower inertinite and higher telovitrinite content relative to the rest of Paso Diablo coal beds, indicative of less well-established raised mire environments prior to drowning. Foreland basin Paleocene coals of western Venezuela, including the Paso Diablo deposit and time-correlative coal deposits of the Ta??chira and Me??rida Andes, are characterized by high inertinite and consistently lower ash and sulfur relative to Eocene and younger coals of the area. We interpret these age-delimited coal quality characteristics to be due to water availability as a function of the tectonic control of subsidence rate. It is postulated that slower subsidence rates dominated during the Paleocene while greater foreland basin subsidence rates during the Eocene-Miocene resulted from the loading of nappe thrust sheets as part of the main construction phases of the Andean orogen. South-southeastward advance and emplacement of the Lara nappes during the oblique transpressive collision of the Caribbean and South American tectonic plates in the Paleocene was further removed from the sites of peat deposition, resulting in slower subsidence rates. Slower subsidence in the Paleocene may have favored the growth of raised mires, generating higher inertinite concentrations through more frequent moisture stress. Consistently low ash yield and sulfur content would be due to the protection from clastic input in raised mires, in addition to the leaching of mineral matter by rainfall and the development of acidic conditions preventing fixation of sulfur. In contrast, peat mires of Eocene-Miocene age encountered rapid subsidence due to the proximity of nappe emplacement, resulting in lower inertinite content, higher and more variable sulfur content, and higher ash yield.

International Journal of Coal Geology↗

USGS1981

Proceedings of the Symposium on Mineral Deposits of the Pacific Northwest: Geological Society of America, Cordilleran Section meeting at Corvallis, Oregon, March 20-21, 1980

Stratiform and volcanogenic zinc-lead-barium deposits occur within the pelagic Kagvik sequence in the Red Dog Creek and Drenchwater Creek areas in the DeLong Mountains and Howard Pass quadrangles. The sulfide deposits occur together with barite, tuff, sandstone, shale, chert, and keratophyre flows and sills. The three main occurrences of the stratiform zinc-lead-barium deposits in the Red Dog Creek area are: (1) thinly-bedded stratiform sulfide minerals in organic-rich Mississippian shale and chert; (2) massive sulfide vein and breccia fillings in Mississippian shale; and (3) massive stratiform barite lenses and nodules in chert and shale of the Siksikpuk Formation. The Drenchwater Creek area has only the first type. Sulfide-bearing zones of up to several thousand meters long occur in both areas with up to 19.5 percent Zn, 9.5 percent Pb, and locally more than 150 ppm Ag. Radiolaria from sulfide-bearing chert indicate in the Red Dog Creek area a Mississippian age of sulfide deposition. K/Ar ages of 319 + 10 m.y. and 330 + 17 m.y. obtained from biotite in keratophyre associated with sulfide-bearing tuff and chert in the Drenchwater Creek area indicate a Mississippian age of sulfide deposition. Sulfur isotope analyses of sulfur-bearing minerals from the Red Dog Creek area indicate that a combination of sea water sulfate and deep-seated sulfur was probably the source of the barite sulfate whereas sulfur in the sulfide minerals may have had a deep-seated source. Sulfur isotope values for sphalerite and galena are similar in vein and stratiform occurrences. Using sulfur isotope geothermetry, spalerite-galena pairs yield paleotemperatures of between 115° and 305° C. Lead isotope analyses of galena from both the Red Dog Creek and Drenchwater Creek areas yield Triassic model ages of approximately 200 m.y. Lead isotope data from both areas approximate typical orogene, i.e., Andean-type arc, or mature island-arc values and exclude ocean floor rifting for the generation of lead. The isotopic, petrologic, and field data indicate the stratiform zinc-lead-barium deposits in the Red Dog Creek and Drenchwater Creek areas formed during a short-lived period of Mississippian submarine volcanism in either an incipient Andean-type arc, or mature island arc environment.

Alaska, British Columbia, California↗

USGS1984

The Loma Seca tuff and the Calabozos caldera: a major ash-flow and caldera complex in the southern Andes of central Chile

A 26 × 14-km composite ring-structure caldera of late Pleistocene age has been discovered and mapped near the Andean crest in central Chile (35°30′S). Rhyodacitic to dacitic zoned ash-flow sheets, each representing 150 to 300 km 3 of magma, were emplaced 0.8, 0.3, and 0.15 m.y. ago; the youngest of the associated collapses was closely followed by resurgent doming of the caldera floor and development of a longitudinal graben. Postcaldera eruptions of dacite and andesite have persisted into Holocene time, and active hot springs are abundant along caldera-marginal and resurgent fault systems, suggesting a significant geothermal-energy resource. The Pleistocene eruption rate of this district and the abundance of older Quaternary to Miocene ash-flow remnants in the 33°S to 36°S segment of the glaciated southern Andes indicate that ash-flow magmatism has been no less important here than in the arid central Andes (16°S–28°S), where ash-flow sheets are far better preserved.

Geological Society of America Bulletin↗

USGS1978

Igneous and metamorphic petrology of the southwestern Dana Mountains, Lassiter Coast, Antarctic Peninsula

The southwestern Dana Mountains of the southern Antarctic Peninsula are underlain by the western part of a composite concentrically zoned Upper Cretaceous batholith consisting largely of granodiorite. The granodiorite (felsic phase) was intrusive into older heterogeneous gabbro-diorite (mafic phase) which makes up the margin of the batholith. Flat-lying pegmatite bodies and abundant inclusions, roof pendants, and septa of metasedimentary rocks and gabbrodiorite suggest that the granodiorite lies near the roof of the batholith. Petrography, chemistry, field relations, and radiometric age dates indicate that the batholith is part of the Andean intrusive suite, a suite of calc-alkaline plutonic rocks that crops out extensively throughout the Antarctic Peninsula and Chilean and Patagonian Andes. Textural features, mineralogy, and chemical data indicate that both phases of the batholith in the southwestern Dana Mountains have been contaminated by assimilation of the Latady Formation, an Upper Jurassic sequence of shale, siltstone, and sandstone that underlies large parts of the southern Antarctic Peninsula. Composition of the granodiorite also has been modified by assimilation of lesser amounts of the gabbro-diorite phase. Such contaminated plutonic rocks occur in several places in the northern Antarctic Peninsula; the batholith in the southwestern Dana Mountains represents the southernmost exposures of contaminated igneous rocks known from the Antarctic Peninsula. Hornblende andesite dikes cut both the mafic and felsic phases of the batholith. Chemical data imply that the dikes represent small amounts of mafic material remobilized by intrusion of the granodiorite. During the austral summers of 1969

Antarctic Peninsula, Dana Mountains, Lassiter Coas↗

USGS1973

Trans-Andean geophysical profile, southern Colombia

Negative Bouguer anomalies (−80 mgals) near the Pacific coast of southern Colombia define the position of the Tertiary Bolívar trough. Values increase eastward to a huge positive anomaly (+75 mgals) over Mesozoic “eugeosynclinal” rocks of the western Andes. This anomaly is part of the West Colombian gravity high, which extends from Panamá into western Ecuador and is caused by shallow mafic crust. Bouguer anomalies are strongly negative (−220 mgals) over pre-Mesozoic(?) metamorphic rocks, Mesozoic(?) granitic bodies, and Tertiary to Holocene volcanic rocks of the central Andes between Pasto and Ipiales. The steep gravity gradient between the West Colombian gravity high and the negative anomaly of the central Andes represents the transition between mafic crust to the west and continental crust to the east. This zone parallels the Romeral-Cauca megashear system. East of the Andes, Bouguer anomalies range from −50 to −120 mgals over a Mesozoic-Tertiary basin of the Putumayo district, indicating that the crust there is thinner or denser than it is beneath the central Andes. Models derived from gravity data suggest that the crust is about 45 km thick under the south-central Colombian Andes. If this is correct, the crust must thicken southward along the strike of the Andes, as thicknesses of 70 km have been reported in the Andes of southern Perú, Bolivia, and northern Chile by Lomnitz (1962) and James (1971a). Such differing crustal thicknesses may reflect different intensities of tectonic activity, greater crustal thickness indicating more intense or rapid growth of the volcano-plutonic arc or foreshortening of an existing crustal section.

Geological Society of America Bulletin↗

USGS1993

Factors influencing the composition of detrital heavy mineral suites in Holocene sands of the Apure River drainage basin, Venezuela

Heavy mineral assemblages in rivers in the Apure River drainage basin of Venezuela and Colombia closely reflect the nature of the source regions, which lie in the Andean orogenic terranes to the west and northwest. The Caribbean Mountains, largely composed of greenschist-facies pelites, phyllites, carbonates, and metavolcanics, supply assemblages dominated by epidote and calcic amphibole. Minor amounts of the high-pressure index minerals glaucophane and lawsonite indicate the presence of blueschistfacies rocks, reflecting the origin of the Caribbean Mountains by subduction-related tectonism. The northern Mérida Andes, which comprise basement gneisses and granites overlain by unmetamorphosed to low-grade metamorphosed clastics, supply two types of assemblage reflecting these two lithological types: garnet-sillimanite-staurolite-amphibole suites from the basement rocks, and epidote-amphibole suites from the overlying cover sequence. The southern Mérida Andes supply stable heavy mineral suites reflecting recycling from the extensive unmetamorphosed sandstones that occur at outcrop. By considering suites from different physiographical provinces, the effects of short-term alluvial storage in the Llanos on heavy mineral assemblages have been evaluated. Weathering during alluvial storage appears to be effective in modifying the apatite-tourmaline ratio, which shows a steady, marked decline with distance from the mountain front, resulting from the removal of apatite during weathering. Clinopyroxene and garnet may also show evidence of loss through weathering, although the trends are poorly constrained statistically. Epidote and amphibole proportions remain essentially constant, possibly through a balance between loss through weathering and continual resupply from the breakdown of rock fragments. In general, the heavy mineral assemblages are less affected than the bulk mineralogy by alluvial storage on the Llanos.

Special Paper of the Geological Society of America↗

USGS2006

Upper Cretaceous to Holocene magmatism and evidence for transient Miocene shallowing of the Andean subduction zone under the northern Neuquén Basin

Evidence for a Miocene period of transient shallow subduction under the Neuquén Basin in the Andean backarc, and an intermittent Upper Cretaceous to Holocene frontal arc with a relatively stable magma source and arc-to-trench geometry comes from new 40 Ar/ 39 Ar, major- and trace-element, and Sr, Pb, and Nd isotopic data on magmatic rocks from a transect at &sim;36°–38°S. Older frontal arc magmas include early Paleogene volcanic rocks erupted after a strong Upper Cretaceous contractional deformation and mid-Eocene lavas erupted from arc centers displaced slightly to the east. Following a gap of some 15 m.y., ca. 26–20 Ma mafic to acidic arc-like magmas erupted in the extensional Cura Mallín intra-arc basin, and alkali olivine basalts with intraplate signatures erupted across the backarc. A major change followed as ca. 20–15 Ma basaltic andesite–dacitic magmas with weak arc signatures and 11.7 Ma Cerro Negro andesites with stronger arc signatures erupted in the near to middle backarc. They were followed by ca. 7.2–4.8 Ma high-K basaltic to dacitic hornblende-bearing magmas with arc-like high field strength element depletion that erupted in the Sierra de Chachahuén, some 500 km east of the trench. The chemistry of these Miocene rocks along with the regional deformational pattern support a transient period of shallow subduction that began at ca. 20 Ma and climaxed near 5 Ma. The subsequent widespread eruption of Pliocene to Pleistocene alkaline magmas with an intraplate chemistry in the Payenia large igneous province signaled a thickening mantle wedge above a steepening subduction zone. A pattern of decreasingly arc-like Pliocene to Holocene backarc lavas in the Tromen region culminated with the eruption of a 0.175 ± 0.025 Ma mafic andesite. The northwest-trending Cortaderas lineament, which generally marks the southern limit of Neogene backarc magmatism, is considered to mark the southern boundary of the transient shallow subduction zone.

Neuquen Basiin↗

USGS1991

Controls on the composition of fluvial sands from a tropical weathering environment: Sands of the Orinoco River drainage basin, Venezuela and Colombia

Fluvial sands in the Orinoco River drainage basin fall into three main compositional groupings: (1) sands of subarkose and arkose composition, from high-relief parts of the Guayana Shield, where crystalline rocks are exposed; (2) sands of litharenite and sub-litharenite composition from the active orogenic belt at the western and northwestern margins of the drainage basin, and in those parts of the Llanos (Andean foreland basin) proximal to the mountain belt; and (3) sands of quartz-arenite composition, widespread throughout the remainder of the basin. Multicycle sands of quartz-arenite composition are produced from platform cover on parts of the elevated shield and from uplifted foreland-basin fill in the eastern Llanos. First-cycle sands of quartz-arenite composition are produced from granitic rocks on low-relief regions of the Guayana Shield and from reworked Holocene alluvium in parts of the western Llanos distal to the orogenic terranes. Erosion in the Orinoco River drainage basin may be described in terms of transport-limited and weathering-limited denudation regimes. In active orogenic terranes and in parts of the elevated shield, transport processes can remove weathered material as rapidly as it is produced by chemical weathering. Thin soils and short soil-mineral residence time result in sands that are incompletely chemically weathered and accurately reflect source-rock composition. In the orogenic terranes, subtle variations in source-rock lithology are preserved in sand composition. In contrast, in low-relief parts of the Guayana Shield and on flat erosion surfaces of the upland shield, weathering exceeds the rate at which transport processes can remove weathered material. Thick soils accumulate, soil-mineral residence time is long, and detritus is highly altered chemically. On much of the lowland Guayana Shield, upper soil layers consist of nearly pure quartz sand that erodes to produce first-cycle fluvial sand of quartz-arenite composition. Chemically weathered orogenically derived sand enters the Orinoco River on the left bank, while feldspathic shield-derived sand enters on the right bank. This geometry is responsible for the nearly total lack of longitudinal variation in sand composition along the 1,400-km length of the Orinoco River mainstem. Except in the upper 100 km of the Orinoco River mainstem, cross-channel heterogeneity in sand composition is also modest. Nevertheless, a weighted linear least-squares modeling approach suggests that sand moves down the Orinoco River mainstem in distinct pulses, perhaps corresponding to times of accelerated erosion in headwater regions. Because rivers that head in the orogenic terranes and traverse the Llanos contribute more than 99% of the sand in the lower Orinoco River mainstem, the composition of this sand is dominated by chemically weathered sands from the Llanos. The Orinoco River—the third largest river in the world—delivers first-cycle sands of quartz-arenite composition to its delta.

Geological Society of America Bulletin↗

USGS1990

The Ag-Mn-Pb-Zn vein, replacement, and skarn deposits of Uchucchacua, Peru; studies of structure, mineralogy, metal zoning, Sr isotopes, and fluid inclusions

Uchucchacua is an Ag-Mn-Pb-Zn vein, replacement, and skarn mineral district in the central Andes of Peru. Host rocks are massive Jumasha Formation shelf limestones of Turonian age that have been folded into an asymmetric northeast-verging anticline of Andean trend. Strata near the fold crest are cut by minor dacitic intrusions and have been displaced by a conjugate set of steep wrench faults that strike northwest-southeast and northeast-southwest. Most ore occurrences are restricted to host rocks that lie below marly limestone at the top of the middle Jumasha Formation. Vein ores located along the fracture system have formed by fissure infill and by replacement of limestone wall rocks. Larger sheetlike replacement orebodies are parallel and adjacent to a large fault. Replacement is in zones of brecciation adjacent to fault bends which were dilatent during sinistral slip of the master fracture. Such fracture belts may have been subject to paleokarst solution processes before mineralization.Four paragenetic stages have been identified. Fe, Mn, and Si were introduced at the exoskarn stage (I) as the anhydrous silicates ferroan tephroite, johannsenite, rhodonite, and bustamite. During the early main stage (II) ferroan tephroite was replaced by friedelite and magnetite under oxidizing conditions at a relatively low pH. Pb, Zn, Fe, Cu, and B were introduced; principal sulfides are pyrrhotite, Fe-rich sphalerite, Mn-rich wurtzite, alabandite, galena, chalcopyrite, and tetrahedrite. Pyrrhotite was replaced by other sulfides during later stage II. Main gangue minerals were calcite, kutnohorite, rhodochrosite, and quartz. Ag, As, and Sb were introduced during the late stage (III) in the form of sulfosalts, principally pyrargyrite. Redistribution of metals introduced at stage II resulted in the growth of Fe-poor sphalerite and alabandite accompanied by calcite gangue. Decreasing Fe contents of alabandite and sphalerite during late stage II and stage III, together with the appearance of pyrite, indicate an increase in sulfur fugacity and/or decrease in temperature over this period. The supergene stage (IV) affects the upper 30 to 150 m of most veins and involves the growth of Mn hydroxides, goethite, orpiment, marcasite, cerussite, and siderite.Distribution patterns of metal ratios and high metal values define ore bands, with a succession of antiforms and synforms. Ore-band locations are determined by vein width, itself a function of wall-rock reactivity, and fracture permeability. Metal ratio distributions in the Luz vein show symmetric dispersion of metals at right angles to the ore-band axis. Ag shows the least dispersion with progressively greater dispersion of Pb and Zn.Geologic considerations indicate mineralization at a minimum depth of 1,600 m. Most primary fluid inclusions in calcite of probable stage II origin were trapped over a temperature range of about 200 degrees to 337 degrees C (hydrostatic pressure) or about 225 degrees to 362 degrees C (lithostatic). Fluid inclusions from late stage II quartz were trapped at about 165 degrees to 205 degrees C (hydrostatic) or 190 degrees to 230 degrees C (lithostatic). Salinity ranged from 0.5 to 29.7 equiv wt percent NaCl-CaCl 2 with little relation to temperature. Calcite 87 Sr/ 86 Sr values of 0.70743 to 0.71122 extend well outside the range of values both determined for magmatic rocks of the region and estimated for the host limestones but are probably compatible with older sedimentary rocks of the mine district. Salinity levels and NaCl/CaCl 2 ratios are similar to basinal brines associated with Mississippi Valley-type deposits. It is concluded that basinal brine, expelled from the deforming Mesozoic sequence, was a significant component of the ore fluid. This fluid was probably heated by dacitic magmas or cooling dacitic intrusions; a polygenetic high-salinity magmatic-basinal fluid then rose along existing strike-slip fractures toward the mineralization site where it mixed with heated low-salinity ground water.

Uchucchacua↗