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At least 523 records · Page 29Linked to original sources

Flow and sorption controls of groundwater arsenic in individual boreholes from bedrock aquifers in central Maine, USA

To understand the hydrogeochemical processes regulating well water arsenic (As) evolution in fractured bedrock aquifers, three domestic wells with [As] up to 478 μg/L are investigated in central Maine. Geophysical logging reveals that fractures near the borehole bottom contribute 70-100% of flow. Borehole and fracture water samples from various depths show significant proportions of As (up to 69%) and Fe (93-99%) in particulates (>0.45 μm). These particulates and those settled after a 16-day batch experiment contain 560-13,000 g/kg of As and 14-35% weight/weight of Fe. As/Fe ratios (2.5-20 mmol/mol) and As partitioning ratios (adsorbed/dissolved [As], 20,000-100,000 L/kg) suggest that As is sorbed onto amorphous hydrous ferric oxides. Newly drilled cores also show enrichment of As (up to 1300 mg/kg) sorbed onto secondary iron minerals on the fracture surfaces. Pumping at high flow rates induces large decreases in particulate As and Fe, a moderate increase in dissolved [As] and As(III)/As ratio, while little change in major ion chemistry. The δD and δ 18 O are similar for the borehole and fracture waters, suggesting a same source of recharge from atmospheric precipitation. Results support a conceptual model invoking flow and sorption controls on groundwater [As] in fractured bedrock aquifers whereby oxygen infiltration promotes the oxidation of As-bearing sulfides at shallower depths in the oxic portion of the flow path releasing As and Fe; followed by Fe oxidation to form Fe oxyhydroxide particulates, which are transported in fractures and sorb As along the flow path until intercepted by boreholes. In the anoxic portions of the flow path, reductive dissolution of As-sorbed iron particulates could re-mobilize As. For exposure assessment, we recommend sampling of groundwater without filtration to obtain total As concentration in groundwater.

Maine↗

Hydrogeologic framework and conceptual groundwater-flow model of the panhandle and northwest parts of the High Plains (Ogallala) aquifer in Oklahoma, 1998–2022

This study was conducted by the U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, to update the hydrogeologic framework and conceptual flow model for the panhandle and northwest parts of the High Plains (Ogallala) aquifer in Oklahoma, which together compose the Ogallala aquifer focus area. The study included the construction of a potentiometric surface, and available geologic and hydrologic data were used to evaluate saturated thickness of the aquifer. The water budget for the updated conceptual groundwater-​flow model was based on estimated inflows and outflows for the 1998–2022 study period. Saturated thickness of the Ogallala aquifer averaged 127 and 116 feet for the panhandle and northwest parts, respectively. Groundwater withdrawals from the Ogallala aquifer for 1998–2022 averaged 422,054 and 39,645 acre-feet per year (acre-ft/yr) for the panhandle and northwest parts, respectively. Recharge, the primary inflow, was estimated at 0.63 inch per year for the 1998–2022 study period, with the panhandle part of the Ogallala aquifer receiving 175,068 acre-ft/yr and the northwest part of the Ogallala aquifer receiving 49,376 acre-ft/yr. Additional inflows included irrigation return flows, estimated at 8,111 and 642 acre-ft/yr for the panhandle and northwest parts, respectively, of the Ogallala aquifer. Net lateral groundwater flows, considered to be aquifer outflows, were estimated to account for 31,908 acre-ft/yr for the Ogallala aquifer focus area. Streambed seepage, which was an outflow of 5,535 acre-ft/yr, was only present in the northwest part of the Ogallala aquifer. Vertical leakage and saturated-zone evapotranspiration were considered negligible outflows. These findings provide a revised conceptual groundwater-flow model water budget for the Ogallala aquifer focus area in Oklahoma.

Colorado, Kansas, Oklahoma, Texas↗

Status of groundwater quality in the San Fernando--San Gabriel study unit, 2005--California GAMA Priority Basin Project

Groundwater quality in the approximately 460-square-mile San Fernando--San Gabriel (FG) study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study area is in Los Angeles County and includes Tertiary-Quaternary sedimentary basins situated within the Transverse Ranges of southern California. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA FG study was designed to provide a spatially unbiased assessment of the quality of untreated (raw) groundwater in the primary aquifer systems (hereinafter referred to as primary aquifers) throughout California. The assessment is based on water-quality and ancillary data collected in 2005 by the USGS from 35 wells and on water-quality data from the California Department of Public Health (CDPH) database. The primary aquifers were defined by the depth interval of the wells listed in the CDPH database for the FG study unit. The quality of groundwater in primary aquifers may be different from that in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. This study assesses the status of the current quality of the groundwater resource by using data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources in the primary aquifers of the FG study unit, not the treated drinking water delivered to consumers by water purveyors.

California↗

Water-level conditions in the confined aquifers of the New Jersey Coastal Plain, 2008

Groundwater-level altitudes in 10 confined aquifers of the New Jersey Coastal Plain were measured and evaluated to provide an overview of regional groundwater conditions during fall 2008. Water levels were measured in more than 900 wells in New Jersey, eastern Pennsylvania, and northern Delaware and potentiometric surface maps prepared for the confined Cohansey aquifer of Cape May County, the Rio Grande water-bearing zone, the Atlantic City 800-foot sand, the Piney Point, Vincentown, and the Wenonah-Mount Laurel aquifers, the Englishtown aquifer system, and the Upper, Middle, and Lower aquifers of the Potomac-Raritan-Magothy aquifer system. In 2008, the highest water-level altitudes were observed in the Vincentown aquifer (median, 78 ft) and the lowest in the Atlantic City 800-foot sand (median, -45 ft). Persistent, regionally extensive cones of depression were present within the potentiometric surfaces of the Englishtown aquifer system in east-central New Jersey, the Wenonah-Mount Laurel aquifer in east-central and southern New Jersey, the Upper, Middle, and Lower Potomac-Raritan-Magothy aquifers in southern New Jersey, and the Atlantic City 800-foot sand in the southeastern part of the State. Cones of depression in the potentiometric surfaces of the Upper Potomac-Raritan-Magothy and the Piney Point aquifers in east-central and southwestern New Jersey had broadened and deepened since 2003. Declining water levels in many of New Jersey’s confined Coastal Plain aquifers intensified during the late 1970s and early 1980s, prompting the designation of two water-supply Critical Areas by the New Jersey Department of Environmental Protection; Critical Areas 1 and 2 continued to be of concern. To address that concern, water-level changes were assessed in nearly 800 wells measured during the fall of 2003 and 2008, and potentiometric-surface difference maps for each aquifer were constructed and evaluated. In addition, water-level trends were calculated for 77 wells for the periods 2003–8 and 1998–2008 and for 73 wells for the period 1978–2008. From 2003 to 2008 small to moderate water-level changes were observed in many Coastal Plain aquifers in New Jersey, but in places, groundwater levels continued to decline substantially as a result of pumping. Groundwater levels in the Atlantic City 800-foot sand were lower in 2008 than in 2003; declines were greatest near pumping centers in eastern Atlantic County. Changes were less pronounced in Cape May County where water levels were, on average, 1 to 3 feet (ft) lower than those during the previous study (2003), except near Rio Grande where a localized cone of depression had formed as a result of increased withdrawals. Large and widespread declines occurred in the Piney Point aquifer in Cumberland County where water levels in and around the city of Bridgeton had fallen in excess of 100 ft since 2003, and by 30 ft to more than 60 ft in surrounding areas. Groundwater levels in the Wenonah-Mount Laurel aquifer and Englishtown aquifer system continued to recover in east-central New Jersey; however, groundwater levels in the Wenonah-Mount Laurel aquifer throughout the southern part of the State continued to decline. In the Upper Potomac-Raritan-Magothy aquifer, groundwater levels were substantially lower than in 2003 in parts of northern Ocean County but were stable in the area adjacent to Raritan Bay (Critical Area 1), and water levels continued to recover in southern New Jersey. In the Middle Potomac-Raritan-Magothy aquifer, water levels rose near Raritan Bay in Middlesex County; however, modest declines were recorded in interior areas of Monmouth and Ocean Counties. Groundwater levels in both the Middle and Lower Potomac-Raritan-Magothy aquifers were stable or rising within the regional cone of depression in Critical Area 2; beyond the critical area in southern New Jersey, however, water levels were slightly lower than in 2003. Analyses of long-term water-level changes indicate that from 1978 to 2008 downward trends occurred at 20 wells (27 percent), upward trends at 27 wells (37 percent), and trends at 26 wells (36 percent) were insubstantial. Sustained, long-term declines were observed most often at wells within the Atlantic City 800-foot sand and at wells in the Piney Point aquifer in southern New Jersey, in which rates of decline were as great as 1.4 feet/year. Upward water-level trends were observed frequently at wells screened in the Englishtown aquifer system and the Wenonah-Mount Laurel aquifer in Critical Area 1 in east-central New Jersey, and in the Potomac-Raritan-Magothy aquifer system in parts of Critical Area 1 and throughout most of Critical Area 2 in southern New Jersey. Annual rates of upward change were as great as 3.9 and 5.6 ft/yr in the Englishtown aquifer system and Wenonah-Mount Laurel aquifer, respectively. Among the units of the Potomac-Raritan-Magothy aquifer system, annual rates of recovery were greatest in the Lower aquifer. From 1998 to 2008, downward water-level trends were observed at 22 wells (29 percent), upward trends were observed at 21 wells (27 percent), and insubstantial trends at 34 wells (44 percent). Downward trends were detected most often at wells open to the Piney Point aquifer and the Atlantic City 800-foot sand. Upward water-level trends were most frequent in wells open to the Englishtown aquifer system in Critical Area 1 and in wells within the Potomac-Raritan-Magothy aquifer system in southern New Jersey.

New Jersey↗

Assessment of ground-water contamination in the alluvial aquifer near West Point, Kentucky

Well inventories, water level measurements, groundwater quality samples, surface geophysical techniques (specifically, electromagnetic techniques), and test drilling were used to investigate the extent and sources of groundwater contamination in the alluvial aquifer near West Point, Kentucky. This aquifer serves as the principal source of drinking water for over 50,000 people. Groundwater flow in the alluvial aquifer is generally unconfined and moves in a northerly direction toward the Ohio River. Two large public supply well fields and numerous domestic wells are located in this natural flow path. High concentrations of chloride in groundwater have resulted in the abandonment of several public supply wells in the West Point areas. Chloride concentrations in water samples collected for this study were as high as 11,000 mg/L. Electromagnetic techniques indicated and test drilling later confirmed that the source of chloride in well waters was probably improperly plugged or unplugged, abandoned oil and gas exploration wells. The potential for chloride contamination of wells exists in the study area and is related to proximity to improperly abandoned oil and gas exploration wells and to gradients established by drawdowns associated with pumped wells. Periodic use of surface geophysical methods, in combination with added observation wells , could be used to monitor significant changes in groundwater quality related to chloride contamination. (USGS)

Water-Resources Investigations Report↗

Evaluation of effects of groundwater withdrawals at the proposed Allen combined-cycle combustion turbine plant, Shelby County, Tennessee

The Mississippi Embayment Regional Aquifer Study groundwater-flow model was used to simulate the potential effects of future groundwater withdrawals at the proposed Allen combined-cycle combustion turbine plant in Shelby County, Tennessee. The scenario used in the simulation consisted of a 30-year average withdrawal period followed by a 30-day maximum withdrawal period. Effects of withdrawals at the Allen plant site on the Mississippi embayment aquifer system were evaluated by comparing the difference in simulated water levels in the aquifers at the end of the 30-year average withdrawal period and at the end of the scenario to a base case without the Allen combined-cycle combustion turbine plant withdrawals. Simulated potentiometric surface declines in the Memphis aquifer at the Allen plant site were about 7 feet at the end of the 30-year average withdrawal period and 11 feet at the end of the scenario. The affected area of the Memphis aquifer at the Allen plant site as delineated by the 4-foot potentiometric surface-decline contour was 2,590 acres at the end of the 30-year average withdrawal period and 11,380 acres at the end of the scenario. Simulated declines in the underlying Fort Pillow aquifer and overlying shallow aquifer were both less than 1 foot at the end of the 30-year average withdrawal period and the end of the scenario.

Arkansas, Mississippi, Tennessee↗

Characterization and occurrence of confined and unconfined aquifers in Quaternary sediments in the glaciated conterminous United States

The glacial aquifer system, which is a collection of aquifers within Quaternary sediments in the glaciated conterminous United States, is a principal aquifer that supplies groundwater that serves about 42 million people and accounts for about 5 percent of the Nation’s drinking water. This aquifer system (the area of maximum glacial advance) underlies parts of 25 States and covers 1.87×10 6 square kilometers. A hydrogeologic framework is presented that divides the glaciated United States into 17 distinct hydrogeologic terranes using a geologic approach based on previous mapping. Each hydrogeologic terrane contains Quaternary sediment that is derived from a common depositional history and can be characterized by similar texture and thickness. Characteristics of Quaternary sediments are described using attributes computed from a lithologic database of well logs compiled from 24 States (excluding Kentucky). The hydrogeologic framework presents a nationwide picture of the glacial aquifer system and provides generalizations concerning the nature of aquifers within it (for example, whether the aquifers are shallow or deep, and unconfined or confined). In this way insights can be gained from understanding the similarities and differences in distinct parts of the glacial aquifer system and how they relate to water use and quality and to aquifer vulnerability. Delineation of hydrogeologic terranes was based on an interpretation of existing geologic mapping of Quaternary sediments and the thickness of unconsolidated material. Overall thickness of Quaternary sediment was used to qualitatively rank the generalized complexity of the hydrogeologic framework in each terrane: “lower” complexity (assigned a terrane code 1), “moderate” complexity (terrane code 2), and “higher” complexity (terrane code 3). Letter designations appended to the terrane codes (for example, 1A, 1B, or 1C) differentiate terranes of similar complexity. Two unique areas, where thick, stratified, coarse-grained sediment dominates, were assigned terrane code 4. Elements of this hydrogeologic framework include a glacial environments and surficial sediments geodatabase, which includes lithologic, geomorphic, and stratigraphic characterization of Quaternary sediments based on previous mapping; a gridded database of sediment and aquifer characteristics computed from lithologic logs obtained from water-well driller records; a water-use database with information on public-water supply systems and sources of groundwater; and estimated recharge computed from a geologically based soil-water balance model. A generalized map of the bedrock geology based on previous State-level mapping is included as well. Quaternary sediment in the glaciated United States includes glacial, postglacial (Holocene) and nonglacial sediments. At land surface, 60 percent of the glacial sediment is till. Large areas of outwash and ice contact sediments are extensive throughout the Midwest but generally are confined to valleys in the Northeast and the Northwest. Lacustrine sediments were deposited in proglacial lakes adjacent to the present Great Lakes and in glacial Lake Agassiz in the eastern Dakotas and northwestern Minnesota. The median thickness of Quaternary sediment ranges from 6 to 45 meters across the 17 hydrogeologic terranes, but the maximum thickness is more than 500 meters in some areas. Quaternary sediments generally contain less than 10 percent coarse material; the median range is near zero percent under till to about 50 percent under ice contact and outwash sediments. About 80 percent of the coarse material lies within 25 to 40 meters of land surface. In most of the glaciated United States, there is a small likelihood of penetrating an aquifer-material interval containing coarse material at least 3 meters thick. A single aquifer-material interval was recorded in about 44 percent of lithologic logs, whereas about 11 percent of the logs penetrated multiple intervals. About 44 percent of water wells in the lithologic database are completed in Quaternary sediment, and many of these Quaternary water wells (42 percent) are confined by at least 7.5 meters of fine materials. About 33 percent of these Quaternary water wells are unconfined—the remainder are where only thin layers (less than 3 meters) of coarse material are present. The median depths of Quaternary water wells range from 13 to 40 meters among the 17 hydrogeologic terranes. Recharge ranges from more than 400 millimeters per year in the Northeast to 11 millimeters or less per year in the Dakotas and Montana (median value of 136 millimeters per year). Annual groundwater withdrawals compiled by county range on an areal basis from less than 1 to 370 millimeters per year, and the mean is 7.4 millimeters per year. About 36 percent of the withdrawals are for public-water supply, of which 70 percent are derived from Quaternary sediments. Groundwater withdrawals are less than 10 percent of recharge throughout most of the glaciated conterminous United States but are a larger proportion of recharge near urban areas in the Northeast and the Midwest, and in counties throughout drier parts of the Midwest. The salient characteristics of the 17 hydrogeologic terranes are presented through maps and a set of descriptive plots to facilitate visual comparisons between selected sediment and aquifer characteristics. The thickness of Quaternary sediment generally increases from the lower complexity terranes through the higher complexity terranes, consistent with their delineation. Median proportions of coarse material in Quaternary sediment and depths to aquifer-material intervals are highly variable (less than 10 to 50 percent, and 0 to 30 meters, respectively). Median thicknesses of aquifer-material intervals generally fall within a narrow range (10 to 20 meters), except in two terranes that contain thick coarse-grained sediment (30 to 35 meters). The source of water in wells varies from mostly bedrock wells in the lower complexity terranes to mostly Quaternary wells in the higher complexity terranes where the sediment is thickest. A tree diagram compiled from a hierarchical cluster analysis of a matrix composed of metrics based on sediment and aquifer characteristics, and the distribution of water wells in each terrane, indicates some groups of terranes that can be treated as comparable when analyzing groundwater flow and quality. Aquifer-material intervals indicated on maps prepared from the lithologic logs, including unconfined and confined conditions, correlate well with aquifer systems delineated on state maps for Illinois, Indiana, and North Dakota. The large scale of the study limits the resolution at which the maps can be interpreted, however, and alluvial units are not mapped correctly for some valleys in the Northeast and the Northwest. Lithologic logs used in the study are biased toward shallow depths because not all logs penetrate the entire thickness of Quaternary sediment, but this bias should not limit the utility of the sediment and aquifer descriptions because shallow depths are commonly exploited for water supply. The hydrogeologic framework will support ongoing studies of groundwater flow and quality in the U.S. Geological Survey National Water Quality Assessment program for the glaciated United States.

Scientific Investigations Report↗

Comparison of Darcian flow in corresponding flat and folded surfaces

F olds of aquifers are rarely accounted for in models of groundwater flow. To account for aquifer folds in groundwater flow models, the equation describing Darcian flow in a general surface is derived. The equation is used to calculate steady state hydraulic head distributions for corresponding folded and flat surfaces. Each flat surface has the same hydraulic conductivity distribution and boundary condition as the corresponding folded surface. The folded surfaces have folds similar to the folds of selected aquifers and have folds that have much larger changes in slope. The largest difference in hydraulic head caused by all folding is only about 0.5% of the largest difference in hydraulic head across each surface. Because of the smaller areal extent and the fact that the effect of a sequence of folds is not cumulative, the minor folds do not generate substantially larger hydraulic head differences than the major folds.

Water Resources Research↗

Improved method for simulating groundwater inundation using the MODFLOW 6 Lake Transport Package

Groundwater inundation due to sea level rise can affect island and coastal freshwater resources by exposing water tables to direct, continuous evaporation. Numerical simulations of groundwater inundation effects on coastal and island aquifers have been limited by an inability to simulate solute transport and variable density flow between the aquifer and lakes formed by groundwater inundation. Consequently, we contributed to the development of a new tool, the Lake Transport Package, for MODFLOW 6 that can calculate solute concentrations within lakes and allows for variable density flow between lakes and aquifers. Here we use groundwater inundation as an example application to showcase the functionality of the Lake Transport Package and the advantages of using this tool over past methods of representing groundwater inundation. We developed hypothetical island simulations based on hydrogeological characteristics of the Bahamas. Multiple sea level rise and lake evaporation rates were simulated to evaluate the effects of groundwater inundation on freshwater lens size for different climates. The results demonstrate the ability of the Lake Transport Package to calculate the solute concentration of the lake for transient simulations, including hypersaline concentrations. Higher sea level rise and greater lake evaporation rates lead to a greater loss of the freshwater lens and higher lake salinity. The formation of a lake and corresponding expansion due to groundwater inundation increases the loss of freshwater by 6–36%, depending on the lake evaporation rate. These simulations validate the performance and demonstrate usefulness of the Lake Transport Package as a tool in representing groundwater inundation.

Groundwater↗

Natural uranium and strontium isotope tracers of water sources and surface water-groundwater interactions in arid wetlands: Pahranagat Valley, Nevada, USA

Near-surface physical and chemical process can strongly affect dissolved-ion concentrations and stable isotope compositions of water in wetland settings, especially under arid climate conditions. In contrast, heavy radiogenic isotopes of strontium ( 87 Sr/ 86 Sr) and uranium ( 234 U/ 238 U) remain largely unaffected and can be used to help identify unique signatures from different sources and quantify end-member mixing that would otherwise be difficult to determine. The utility of combined Sr and U isotopes are demonstrated in this study of wetland habitats on the Pahranagat National Wildlife Refuge, which depend on supply from large-volume springs north of the Refuge, and from small-volume springs and seeps within the Refuge. Water budgets from these sources have not been quantified previously. Evaporation, transpiration, seasonally variable surface flow, and water management practices complicate the use of conventional methods for determining source contributions and mixing relations. In contrast, 87 Sr/ 86 Sr and 234 U/ 238 U remain unfractionated under these conditions, and compositions at a given site remain constant. Differences in Sr- and U-isotopic signatures between individual sites can be related by simple two- or three-component mixing models. Results indicate that surface flow constituting the Refuge’s irrigation source consists of a 65:25:10 mixture of water from two distinct regionally sourced carbonate aquifer springs, and groundwater from locally sourced volcanic aquifers. Within the Refuge, contributions from the irrigation source and local groundwater are readily determined and depend on proximity to those sources as well as water management practices.

Nevada↗

Preliminary investigation of groundwater flow and trichloroethene transport in the Surficial Aquifer System, Naval Industrial Reserve Ordnance Plant, Fridley, Minnesota

Industrial practices at the Naval Industrial Reserve Ordnance Plant, in Fridley, Minnesota, caused soil and groundwater contamination. Some volatile organic compounds from the plant might have discharged to the Mississippi River, forced by the natural hydraulic gradient in the surficial aquifer system. The U.S. Environmental Protection Agency included the Naval Industrial Reserve Ordnance Plant on the Superfund National Priorities List in 1989. This report describes a preliminary characterization of trichloroethene transport in the surficial and Cambrian-Ordovician aquifer systems at the Naval Industrial Reserve Ordnance Plant. The characterization first involved simulation of 2001 conditions using a model, followed by an application of this 2001 simulator to 2011 conditions. The U.S. Geological Survey, in cooperation with the U.S. Department of the Navy, used a steady-state, uniform-density groundwater flow model to simulate measured potentiometric heads in aquifer systems on August 20, 2001, and a single-phase, conservative, non-reactive, miscible transport model to simulate trichloroethene concentrations in aquifer systems measured in 2001. The U.S. Department of the Navy furnished trichloroethene source areas and trichloroethene source area concentrations to the U.S. Geological Survey for this model simulation. Furnished delineations were postulated and informed by data collected from 1995 to 2011. The groundwater flow simulation of August 20, 2001, was superior to the trichloroethene transport simulation at replicating measurements; simulated potentiometric heads matched 90 percent of measured potentiometric heads on August 20, within 2 feet at selected locations whereas simulated trichloroethene concentration contours of 3, 10, 100, 1000, and 10,000 micrograms per liter (µg/L) correctly bounded 52 percent of measured concentrations in 2001 at selected locations. The degree to which the simulated trichloroethene plume does not match trichloroethene measurements in the surficial aquifer system during the 2001 simulation may suggest that furnished trichloroethene source areas and trichloroethene source area concentrations did not accurately represent all trichloroethene sources in the hydrogeologic system. During the model simulation of 2001, trichloroethene discharged to the Mississippi River. A simulated 900-foot-long zone of benthic trichloroethene discharge flux existed in the shallow flow zone, across which simulated trichloroethene discharged from the surficial aquifer system to the Mississippi River at simulated trichloroethene concentrations that ranged from 3 µg/L to more than 100 µg/L. The Mississippi River was not sampled for volatile organic compounds in Fridley, Minn., from 1999 to 2016 (the publication of this report). Trichloroethene concentrations were measured in wells close to the Mississippi River in the surficial aquifer system on the downgradient side of the Naval Industrial Reserve Ordnance Plant groundwater flow field; for example, at well MS–43 in the shallow flow zone of the surficial aquifer system 280 feet east of the Mississippi River between December 1999 and August 2012, trichloroethene concentrations ranged from 130 to 220 µg/L. The 220-µg/L maximum concentration was reached in March 2003 and October 2006. The August 2012 concentration was 140 µg/L. The August 20, 2001, groundwater flow model simulator and the 2001 trichloroethene transport simulator were applied to a groundwater extraction and treatment system that existed in 2011. Furnished trichloroethene source areas and concentrations in the 2001 simulator were replaced with different, furnished, hypothetical source areas and concentrations. Forcing in 2001 was replaced with forcing in 2011. No trichloroethene concentrations greater than 3 µg/L were simulated as discharging to the Mississippi River during applications of the 2001 simulator to the 2011 groundwater extraction and treatment system. These applications were not intended to represent historical conditions. Differences between furnished and actual trichloroethene sources may explain differences between measurements and simulation results for the 2001 trichloroethene transport simulator. Causes of differences between furnished and actual trichloroethene sources may cause differences between hypothetical application results and the performance of the actual U.S. Department of the Navy groundwater extraction and treatment system at the Naval Industrial Reserve Ordnance Plant. Other limitations may also cause differences between application results and performance.

Minnesota↗

Depth to water, saturated thickness, and other geospatial datasets used in the design and installation of a groundwater monitoring-well network in the High Plains Aquifer, Colorado

These datasets were compiled in support of U.S. Geological Survey Data Series 456, Design and Installation of a Groundwater Monitoring-Well Network in the High Plains Aquifer, Colorado. These datasets were developed as part of a cooperative project between the U.S. Geological Survey and the Colorado Department of Agriculture. The purpose of the project was to design a 30-well network and install 20 of the 30 wells to characterize water quality in the High Plains aquifer in areas of irrigated agriculture in Colorado. The five datasets are described as follows and are further described in Data Series 456: (1) ds472_dtw: This dataset represents the depth to groundwater in the High Plains Aquifer in Colorado in 2000. This grid was used to determine areas where the depth to water was less than 200 feet below land surface. (2) Ds472_sat: This dataset represents the saturated thickness of the High Plains aquifer within Colorado in 2000. This grid was used to determine areas where the saturated thickness was greater than 50 feet. (3) Ds472_equalareas: This dataset includes 30 equal-area polygons overlying the High Plains Aquifer in Colorado having a depth to water less than 200 feet, a saturated thickness greater than 50 feet, and underlying irrigated agricultural lands. (4) Ds472_randomsites: This dataset includes 90 randomly-generated potential groundwater sampling sites. This dataset provides a first, second, and third choice placed within the 30 equal area polygons of dataset dsXX_equalareas. (5) Ds472_welldata: This dataset includes point locations and well completion data for the 20 wells installed as part of this project. The datasets that pertain to this report can be found on the U.S. Geological Survey's NSDI (National Spatial Data Infrastructure) Node, the links are provided on the sidebar.

Colorado↗

Changes in groundwater quality in a conduit-flow-dominated karst aquifer, following BMP implementation

Water quality in the Pleasant Grove Spring karst groundwater basin, Logan County, Kentucky, was monitored to determine the effectiveness of best management practices (BMPs) in protecting karst aquifers. Ninety-two percent of the 4,069-ha (10,054-acre) watershed is used for agriculture. Water-quality monitoring began in October 1992 and ended in November 1998. By the fall of 1995 approximately 72% of the watershed was enrolled in BMPs sponsored by the US Department of Agriculture Water Quality Incentive Program (WQIP). Pre-BMP nitrate-nitrogen concentration averaged 4.65 mg/1. The median total suspended solids concentration was 127 mg/1. The median triazine concentration measured by immunosorbent assay was 1.44 ??tg/l. Median bacteria counts were 418 colonies per 100 ml (col/100 ml) for fecal coliform and 540 col/100 ml for fecal streptococci. Post-BMP, the average nitrate-nitrogen concentration was 4.74 mg/1. The median total suspended solids concentration was 47.8 mg/1. The median triazine concentration for the post-BMP period was 1.48 ??g/1. The median fecal coliform count increased to 432 col/100 ml after BMP implementation, but the median fecal streptococci count decreased to 441 col/100 ml. The pre- and post-BMP water quality was statistically evaluated by comparing the annual mass flux, annual descriptive statistics, and population of analyses for the two periods. Nitrate-nitrogen concentration was unchanged. Increases in atrazine-equivalent flux and triazine geometric averages were not statistically significant. Total suspended solids concentration decreased slightly, whereas orthophosphate concentration increased slightly. Fecal streptococci counts were reduced. The BMPs were only partially successful because the types available and the rules for participation resulted in less effective BMPs being chosen. Future BMP programs in karst areas should emphasize buffer strips around sinkholes, excluding livestock from streams and karst windows, and withdrawing land from production.

Environmental Geology↗

Status of groundwater quality in the Coastal Los Angeles Basin, 2006-California GAMA Priority Basin Project

Groundwater quality in the approximately 860-square-mile (2,227-square-kilometer) Coastal Los Angeles Basin study unit (CLAB) was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study area is located in southern California in Los Angeles and Orange Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA CLAB study was designed to provide a spatially unbiased assessment of the quality of untreated (raw) groundwater in the primary aquifer system. The assessment is based on water-quality and ancillary data collected in 2006 by the USGS from 69 wells and on water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer system was defined by the depth interval of the wells listed in the CDPH database for the CLAB study unit. The quality of groundwater in the primary aquifer system may be different from that in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. This study assesses the status of the current quality of the groundwater resource by using data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources in the primary aquifer system of the CLAB study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal and (or) California regulatory or non-regulatory benchmarks for drinking-water quality. A relative-concentration greater than (>) 1.0 indicates a concentration greater than a benchmark, and a relative-concentration less than or equal to (≤) 1.0 indicates a concentration equal to or less than a benchmark. Relative-concentrations of organic and special-interest constituents [perchlorate, N -nitrosodimethylamine (NDMA), 1,2,3-trichloropropane (1,2,3-TCP), and 1,4-dioxane] were classified as "high" (relative-concentration>1.0), "moderate" (0.5 status assessment for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the area of the primary aquifer system with a relative-concentration greater than 1.0 for a particular constituent or class of constituents; percentage is based on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifer system with moderate and low relative-concentrations, respectively. Two statistical approaches-grid-based and spatially weighted-were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. Grid-based and spatially weighted estimates were comparable in the CLAB study unit (within 90-percent confidence intervals). Inorganic constituents with human-health benchmarks were detected at high relative-concentrations in 5.6 percent of the primary aquifer system and moderate in 26 percent. High aquifer-scale proportion of inorganic constituents primarily reflected high aquifer-scale proportions of arsenic (1.9 percent), nitrate (1.9 percent), and uranium (1.2 percent). Inorganic constituents with secondary maximum contaminant levels (SMCL) were detected at high relative-concentrations in 18 percent of the primary aquifer system and moderate in 47 percent. The constituents present at high relative-concentrations included total dissolved solids (1.9 percent), manganese (15 percent), and iron (9.4 percent). Relative-concentrations of organic constituents (one or more) were high in 3.7 percent, and moderate in 13 percent, of the primary aquifer system. The high aquifer-scale proportion of organic constituents primarily reflected high aquifer-scale proportions of solvents, including trichloroethene (TCE; 1.7 percent), perchloroethene (PCE; 1.1 percent), and carbon tetrachloride (1.0 percent). Of the 204 organic constituents analyzed, 44 constituents were detected. Eleven organic constituents had detection frequencies of greater than 10 percent: the trihalomethanes chloroform and bromodichloromethane, the solvents TCE, PCE, cis -1,2-dichloroethene, and 1,1-dichloroethene, the herbicides atrazine, simazine, prometon, and tebuthiuron, and the gasoline additive methyl tert -butyl ether (MTBE). Most detections were at low relative-concentrations. The special-interest constituent perchlorate was detected at high relative-concentrations in 0.5 percent of the primary aquifer system, and at moderate relative-concentrations in 35 percent. The special-interest constituent 1,4-dioxane was detected at high relative-concentrations, but an insufficient number of samples was analyzed to provide a representative estimate of aquifer-scale proportion.

California↗

Ground-water-withdrawal and water-level data used to simulate regional flow in the major coastal plain aquifers of New Jersey

The report documents groundwater withdrawal and level data for the major aquifers of the New Jersey Coastal Plain. These data have been used in the Regional Aquifer System Analysis flow model of 10 major aquifers in the New Jersey Coastal Plain. Groundwater withdrawal data from more than 1,400 wells are tabulated by year for 1956 through 1980. Total yearly withdrawals for 171 public supply and industrial purveyors for 1918 through 1955 are documented. Best estimates are given for percentages of total withdrawals by aquifer for the 1918 through 1955 data. Groundwater withdrawal data is also tabulated yearly from 1918 through 1980 by county for each aquifer. Long-term hydrographs for 89 Coastal Plain wells provide information on water level fluctuations over time. Potentiometric maps showing earliest recorded water levels in Coastal Plain aquifers delineate prepumping conditions. Groundwater withdrawals from the Coastal Plain have increased from less than 50 million gal/day in 1918 to more than 350 million gal/day in 1980. In response to these increased withdrawals, groundwater levels have been steadily declining. In some areas where wells once flowed freely, water levels are now 100 to 200 ft below land surface. (USGS)

Water-Resources Investigations Report↗

Effects of groundwater withdrawals associated with combined-cycle combustion turbine plants in west Tennessee and northern Mississippi

The Mississippi Embayment Regional Aquifer Study groundwater-flow model was used to simulate the potential effects on future groundwater withdrawals at five powerplant sites-Gleason, Weakley County, Tennessee; Tenaska, Haywood County, Tennessee; Jackson, Madison County, Tennessee; Southaven, DeSoto County, Mississippi; and Magnolia, Benton County, Mississippi. The scenario used in the simulation consisted of a 30-year average water-use period followed by a 30-day peak water-demand period. Effects of the powerplants on the aquifer system were evaluated by comparing the difference in simulated water levels in the aquifers at the end of the scenario (30 years plus 30 days) with and without the combined-cycle-plant withdrawals. Simulated potentiometric surface declines in source aquifers at potential combined-cycle-plant sites ranged from 56 feet in the upper Wilcox aquifer at the Magnolia site to 20 feet in the Memphis aquifer at the Tenaska site. The affected areas in the source aquifers at the sites delineated by the 4-foot potentiometric surface-decline contour ranged from 11,362 acres at Jackson to 535,143 acres at Southaven. The extent of areas affected by potentiometric surface declines was similar at the Gleason and Magnolia sites. The affected area at the Tenaska site was smaller than the affected areas at the other sites, most likely as a result of lower withdrawal rates and greater aquifer thickness. The extent of effect was smallest at the Jackson site, where the nearby Middle Fork Forked Deer River may act as a recharge boundary. Additionally, the Jackson site lies in the Memphis aquifer outcrop area where model-simulated recharge rates are higher than in areas where the Memphis aquifer underlies less permeable deposits. The potentiometric surface decline in aquifers overlying or underlying a source aquifer was generally 2 feet or less at all the sites except Gleason. At the Gleason site, withdrawals from the Memphis aquifer resulted in declines of as much as 9 feet in the underlying Fort Pillow aquifer. The simulated potentiometric surface change occurring in the Fort Pillow aquifer appears to be the result of leakage through the Flour Island Formation separating the Memphis and Fort Pillow aquifers where this confining unit is thin, sandy, or absent.

Arkansas;Kentucky;Mississippi;Missouri;Tennessee↗

Simulation of groundwater flow and hydrologic effects of groundwater withdrawals from the Kirkwood-Cohansey aquifer system in the Pinelands of southern New Jersey

The Kirkwood-Cohansey aquifer system is an important source of present and future water supply in southern New Jersey. Because this unconfined aquifer system also supports sensitive wetland and aquatic habitats within the New Jersey Pinelands (Pinelands), water managers and policy makers need up-to-date information, data, and projections that show the effects of potential increases in groundwater withdrawals on these habitats. Finite-difference groundwater flow models (MODFLOW) were constructed for three drainage basins (McDonalds Branch Basin, 14.3 square kilometers (km 2 ); Morses Mill Stream Basin, 21.63 km 2 ; and Albertson Brook Basin, 52.27 km 2 ) to estimate the effects of potential increases in groundwater withdrawals on water levels and the base-flow portion of streamflow, in wetland and aquatic habitats. Three models were constructed for each drainage basin: a transient model consisting of twenty-four 1-month stress periods (October 2004 through September 2006); a transient model to simulate the 5- to 10-day aquifer tests that were performed as part of the study; and a high-resolution, steady-state model used to assess long-term effects of increased groundwater withdrawals on water levels in wetlands and on base flow. All models were constructed with the same eight-layer structure. The smallest horizontal cell dimensions among the three model areas were 150 meters (m) for the 24-month transient models, 10 m for the steady-state models, and 3 m for the transient aquifer-test models. Boundary flows of particular interest to this study and represented separately are those for wetlands, streams, and evapotranspiration. The final variables calibrated from both transient models were then used in steady-state models to assess the long-term effects of increased groundwater withdrawals on water levels in wetlands and on base flow. Results of aquifer tests conducted in the three study areas illustrate the effects of withdrawals on water levels in wetlands and on base flow. Pumping stresses at aquifer-test sites resulted in measurable drawdown in each observation well installed for the tests. The magnitude of drawdown in shallow wetland observation wells at the end of pumping ranged from 5.5 to 16.7 centimeters (cm). The stresses induced by the respective tests reduced the flow of the smallest stream (McDonalds Branch) by 75 percent and slightly reduced flow in a side channel of Morses Mill Stream, but did not measurably affect the flow of Morses Mill Stream or Albertson Brook. Results of aquifer-test simulations were used to refine the estimates of hydraulic properties used in the models and to confirm the ability of the model to replicate observed hydrologic responses to pumping. Steady-state sensitivity simulation results for a variety of single well locations and depths were used to define overall “best-case” (smallest effect on wetland water levels and base flow) and “worst-case” (greatest effect on wetland water levels and base flow) groundwater withdrawal configurations. “Best-case” configurations are those for which the extent of the wetland areas within a 1-kilometer (km) radius of the withdrawal well is minimized, the well is located at least 100 m and as far from wetland boundaries as possible, and the withdrawal is from a deep well (50–90 m deep). “Worst-case” configurations are those for which the extent of wetlands within a 1-km radius of the withdrawal well is maximized, the well is located 100 m or less from a wetland boundary, and the withdrawal is from a relatively shallow well (30–67 m deep). “Best-” and “worst-case” simulations were applied by locating hypothetical wells across the study areas and assigning groundwater withdrawals so that the sum of the withdrawals for the basin is equal to 5, 10, 15, and 30 percent of overall recharge. The results were compared to the results of simulations of no groundwater withdrawals. Results for withdrawals of 5 percent of recharge show that the area of wetland water-level decline that exceeded 15 cm was as much as 1.5 percent of the total wetland area for the “best-case” simulations and as much as 9.7 percent of the total wetland area for the “worst-case” simulations. For the same withdrawals, base-flow reduction was as much as 5.1 percent for the “best-case” simulations and as much as 8.6 percent for the “worst-case” simulations. Results for withdrawals of 30 percent of recharge show that the area of wetland water-level decline that exceeded 15 cm was as much as 70 percent of the total wetland area for the “best-case” simulations and as much as 84 percent of the total wetland area for the “worst-case” simulations. For the same withdrawals, base-flow reduction was as much as 30 percent for the “best-case” simulations and as much as 51 percent for the “worst-case” simulations. Results for withdrawals of 10 and 15 percent of recharge show decreased water levels and base flow that are intermediate between those simulated for 5 and 30 percent of recharge. Several approaches for applying the results of this study to other parts of the Pinelands were explored. An analytical-modeling technique based on the Thiem equation and image-well theory was developed to estimate local drawdown distributions resulting from withdrawals in other areas within the Pinelands. Results of example applications of this technique were compared with those of the numerical simulations used in this study and were shown to be useful. Differences among the three basins in the simulated percentage of basin wetlands affected by drawdown were found to be related to the proximity of wetlands to streams, the proximity of wetlands to pumped wells, and the vertical conductance of the aquifer system. These factors formed the basis for an index of wetland vulnerability to drawdown. An empirically-derived model based on the Gompertz function and the wetland vulnerability index was developed, tested, and shown to be an effective means to evaluate potential drawdown in wetlands at a basin scale throughout the Pinelands. Base-flow reduction can be estimated from generalized results of the numerical models, estimates of evapotranspiration reduction, or available regional groundwater flow models. These approaches could be used to evaluate alternative water-supply strategies and, in conjunction with ecological-modeling results, to determine maximum basin withdrawal rates within the limits of acceptable ecological change.

New Jersey↗

Hydrogeology of Virginia

The hydrogeology of Virginia documented herein is in two parts. Part 1 consists of an overview and description of the hydrogeology within each regional aquifer system in the Commonwealth. Part 2 includes discussions of hydrogeologic research topics of current relevance including: 1. the Chesapeake Bay impact structure, 2. subsidence/compaction in the Coastal Plain, 3. groundwater age and aquifer susceptibility, 4. the occurrence of groundwater at depth in fractured-rock and karst terrains, and 5. hydrologic response of wells to earthquakes around the world.

Virginia↗