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USGS2007

From Projectile Points to Microprocessors - The Influence of Some Industrial Minerals

In the language of economic geology, Earth materials are classified as metallic ores, fuel minerals, gemstones, and industrial minerals. Most people know that metallic ores yield shiny, conductive, ductile elements such as copper, iron, or gold. Most understand that energy-producing coals constitute a fuel mineral. Likewise, dazzling rubies and rare sapphires are universally recognized as gemstones. The fourth group, industrial minerals, is largely unknown to the general public, even though industrial minerals are as essential to daily life as metals and fuel minerals. This report examines the occurrence and practical uses of nine important industrial minerals - constituting just a few of the more than 50 industrial minerals that shape human culture.

Circular↗

USGS2012

Lithium use in batteries

Lithium has a number of uses but one of the most valuable is as a component of high energy-density rechargeable lithium-ion batteries. Because of concerns over carbon dioxide footprint and increasing hydrocarbon fuel cost (reduced supply), lithium may become even more important in large batteries for powering all-electric and hybrid vehicles. It would take 1.4 to 3.0 kilograms of lithium equivalent (7.5 to 16.0 kilograms of lithium carbonate) to support a 40-mile trip in an electric vehicle before requiring recharge. This could create a large demand for lithium. Estimates of future lithium demand vary, based on numerous variables. Some of those variables include the potential for recycling, widespread public acceptance of electric vehicles, or the possibility of incentives for converting to lithium-ion-powered engines. Increased electric usage could cause electricity prices to increase. Because of reduced demand, hydrocarbon fuel prices would likely decrease, making hydrocarbon fuel more desirable. In 2009, 13 percent of worldwide lithium reserves, expressed in terms of contained lithium, were reported to be within hard rock mineral deposits, and 87 percent, within brine deposits. Most of the lithium recovered from brine came from Chile, with smaller amounts from China, Argentina, and the United States. Chile also has lithium mineral reserves, as does Australia. Another source of lithium is from recycled batteries. When lithium-ion batteries begin to power vehicles, it is expected that battery recycling rates will increase because vehicle battery recycling systems can be used to produce new lithium-ion batteries.

Circular↗

USGS2010

Geologic cross section, gas desorption, and other data from four wells drilled for Alaska rural energy project, Wainwright, Alaska, coalbed methane project, 2007-2009

Energy costs in rural Alaskan communities are substantial. Diesel fuel, which must be delivered by barge or plane, is used for local power generation in most off-grid communities. In addition to high costs incurred for the purchase and transport of the fuel, the transport, transfer, and storage of fuel products pose significant difficulties in logistically challenging and environmentally sensitive areas. The Alaska Rural Energy Project (AREP) is a collaborative effort between the United States Geological Survey (USGS) and the Bureau of Land Management Alaska State Office along with State, local, and private partners. The project is designed to identify and evaluate shallow (<3,000 ft) subsurface resources such as coalbed methane (CBM) and geothermal in the vicinity of rural Alaskan communities where these resources have the potential to serve as local-use power alternatives. The AREP, in cooperation with the North Slope Borough, the Arctic Slope Regional Corporation, and the Olgoonik Corporation, drilled and tested a 1,613 ft continuous core hole in Wainwright, Alaska, during the summer of 2007 to determine whether CBM represents a viable source of energy for the community. Although numerous gas-bearing coal beds were encountered, most are contained within the zone of permafrost that underlies the area to a depth of approximately 1,000 ft. Because the effective permeability of permafrost is near zero, the chances of producing gas from these beds are highly unlikely. A 7.5-ft-thick gas-bearing coal bed, informally named the Wainwright coal bed, was encountered in the sub-permafrost at a depth of 1,242 ft. Additional drilling and testing conducted during the summers of 2008 and 2009 indicated that the coal bed extended throughout the area outlined by the drill holes, which presently is limited to the access provided by the existing road system. These tests also confirmed the gas content of the coal reservoir within this area. If producible, the Wainwright coal bed contains sufficient gas to serve as a long-term source of energy for the community.

Open-File Report↗

USGS1985

Records of wells, test borings, and some measured geologic sections near the Western New York Nuclear Service Center, Cattaraugus County, New York

The Western New York Nuclear Service Center (WNYNSC) is a 3 ,336-acre tract of land in northern Cattaraugus County, NY, about 30 mi south of Buffalo. In 1963, 247 acres within the WNYNSC was developed for a nuclear-fuel reprocessing plant and ancillary facilities, including (1) a receiving and storage facility to store fuel prior to reprocessing, (2) underground storage tanks for liquid high-level radioactive wastes from fuel reprocessing, (3) a low-level wastewater treatment plant, and (4) two burial grounds for shallow burial of solid radioactive waste. A series of geologic and hydrologic investigations was done as part of the initial development and construction of the facilities by numerous agencies during 1960-62; these produced a large quantity of well data, some of which are difficult to locate or obtain. This report is a compilation of well and boring data collected during this period. The data include records of 236 wells, geologic logs of 145 wells and 167 test borings, and descriptions of 20 measured geologic sections. Two oversized maps show locations of the reported data. (USGS)

Open-File Report↗

USGS1990

Preliminary investigation of soil and ground-water contamination at a U.S. Army Petroleum Training Facility, Fort Lee, Virginia, September-October 1989

Fuel-oil constituents in the soil and groundwater at the Fort Lee Petroleum Training Facility near Petersburg, Virginia, were studied by the U.S. Geological Survey (USGS) in cooperation with the Department of Defense, U.S. Army. The study included installation of 25 groundwater monitoring wells and description of groundwater flow patterns of the shallow-aquifer system underlying the facility. Soil and groundwater samples were collected to determine the concentrations of fuel-oil constituents and to determine the potential for off-site migration of the constituents. Total petroleum hydrocarbon concentrations up to 18,400 mg/km were reported in soil samples. Concentrations of benzene in water from wells at the facility were up to 130 micrograms per liter (ug/L), and concentrations of ethylbenzene and xylene were up to 54 and 120 ug/L, respectively. Potential exists for off-site migration of the contaminants and migration of contaminants downward to deeper aquifers. Further investigations of these potential contamination-migration pathways are warranted. Risk identification at the Petroleum Training Facility cannot be properly addressed because the distribution of the fuel-oil constituents has not been fully characterized. Preliminary identification of risk, however is presented by an examination of toxicity data for the chemical constituents reported in the groundwater at the facility. Concentrations of constituents were compared to the maximum contaminant levels (MCLs) for drinking water established by the U.S. Environmental Protection Agency (USEPA). Concentrations of benzene in water from wells at the facility exceed the USEPA 's 5 ug/L MCL by as much as 26 times. Sufficient data are not available to fully design the remedial-action plan for the facility; however, general responses to contamination of the type associated with the facility include no-action, monitoring, institutional controls, removal, and treatment.

Virginia↗

USGS1993

A preliminary review of coal exploration activities conducted by the government of Armenia and the coal resource potential of Armenia

A coal resource assessment team from the U.S. Geological Survey (USGS), in cooperation with the Armenian Department of Underground Resources (DUR) and elements of the Ministry of Energy and Fuel, has completed an initial visit to Armenia under the auspices of the U.S. Agency for International Development JUSAID). The visit included discussions of the coal resources, identification of problems associated with on-going exploration and development activities, and field visits to selected solid fuel areas. The USGS team will return in November with a draft of the final report for discussion of conclusions and recommendations with Armenian counterparts, representatives of USAID, and the American Embassy. The final report, which will contain tabulated coal-sample analytical results and detailed recommendations, will be submitted to the USAID by the end of December 1993. Preliminary conclusions are that: 1) Armenia has usable deposits of coal that could form a viable, though relatively small, component of Armenia's energy budget; 2) on-going exploration and development activities must be augmented and expedited to increase understanding of the coal resource potential and subsequent utilization; 3) deficiencies in supplies (primarily fuel) and equipment (replacement of aging parts and units) have greatly reduced the gathering of necessary resource data; and 4) training of Armenian counterparts in conducting and managing coal exploration activities is desirable.

Open-File Report↗

USGS1995

Status of ground-water resources at U.S. Navy Support Facility, Diego Garcia; summary of hydrologic and climatic data through September 1993

This report contains hydrologic and climatic data that describe the status of ground-water resources at U.S. Navy Support Facility, Diego Garcia. Data are presented through September 1993, one month into the annual wet season. At the end of September 1993, the chloride concentration of the composite water supply was 66 milligrams per liter, well below the 250 milligrams per liter secondary drinking water standard established by the U.S. Environmental Protection Agency. Most of the production wells appeared to be operating at levels consistent with past operations. Several wells at Air Operations remain out of service while they are being used to hydraulically divert the nearby fuel spill. Rainfall thus far in 1993 is 8 percent below the mean annual rainfall of 106 inches. This follows a year when rainfall was 12 percent below the mean annual rainfall. Withdrawal has averaged 856,000 gallons per day during 1993, a decrease from the 1992 average of 936,000 gallons per day. The chloride concentration of pumped water rose during the current quarter (July through September 1993) in most areas, coincident with the annual dry season (March through August). This continues a general trend of increasing chloride concentration that has persisted for more than a year, beginning in the 1992 dry season. Chloride concentration rose progressively during the current quarter in monitoring wells at Cantonment and Air Operations. Chloride concentrations in the deeper monitoring wells have generally been increasing since 1992. A fuel spill at Air Operations caused the shutdown of ten wells in May 1991. Four of the wells have resumed pumping to the water supply, but water from the remaining six wells is being used to hydraulically contain and divert fuel migration.

Open-File Report↗

USGS2014

Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

Fossil fuels from the Appalachian basin region have been major contributors to the Nation’s energy supplies over much of the last three centuries. Appalachian coal and petroleum resources are still available in sufficient quantities to contribute significantly to fulfilling the Nation’s energy needs. Although both conventional oil and gas continue to be produced in the Appalachian basin, most new wells in the region are drilled in shale reservoirs to produce natural gas. U.S. Geological Survey (USGS) Professional Paper 1708 is a modern, indepth collection of reports, cross sections, and maps that describe the geology of the Appalachian basin and its fossil fuel resources. This publication supplements and updates older USGS regional studies of Appalachian basin coal and petroleum resources. Some chapters are new, and several have been published in outside journals or as other USGS publications. Although this volume is not a comprehensive regional treatment of all notable geologic and fossil fuel localities in the Appalachian basin, the selected study areas and topics presented in the chapters pertain to large segments of the basin and a wide range of stratigraphic intervals. This volume discusses the locations of coal and petroleum accumulations, the stratigraphic and structural framework, and the geochemical characteristics of the coal beds and petroleum in the basin, as well as the results of recent USGS assessments of coal, oil, and gas resources in the basin. Many of the maps and accompanying data supporting the reports in this volume are available from chapter I.1 as downloadable geographic information system (GIS) data files about the characteristics of selected coal beds and oil and gas fields, locations of oil and gas wells, coal production, coal chemistry, total petroleum system (TPS) boundaries, and bedrock geology. Log ASCII Standard (LAS) files for geophysical (gamma ray) wireline well logs are included in other chapters. Professional Paper 1708 is intended primarily for geoscientists in academia, industry, and government who are interested in Appalachian basin geology and its coal and petroleum resources. Other users, however, may find the topics, papers, and digital images valuable for land-use and policy planning. Among the anticipated benefits of the report are improvements in (1) resource assessment estimates and methodology, (2) exploration strategies, (3) basin models, and (4) energy use policies.

Appalachian basin↗

USGS2014

Digital data in support of studies and assessments of coal and petroleum resources in the Appalachian basin

The Appalachian basin is a mature basin containing abundant oil, gas, and coal resources. Its fossil-fuel-bearing strata range in age from Cambrian to Permian and extend over the States of New York, Pennsylvania, Maryland, Ohio, West Virginia, Virginia, Kentucky, Tennessee, Georgia, and Alabama. The basin has provided abundant fossil fuels to support the Nation’s economic growth for at least 150 years and U.S. Geological Survey (USGS) assessments suggest that substantial untapped resources remain. A merger of new and old geologic data and ideas is required to locate and extract those remaining resources. This chapter brings together abundant existing datasets in a common and integrated spatial format to advance our understanding of the distribution, geologic framework, burial history, and geochemical character of the basin’s oil, gas, and coal resources. These datasets support the information and findings in chapters B through G of this volume, which include (1) geologic cross sections, seismic profiles, and burial history models that document the depositional and structural framework of the basin; (2) assessments of Carboniferous coal-bed gas and Devonian shale gas; (3) studies about the distribution of oil, gas, and coal fields and the geochemistry of natural gas and oil; and (4) a history of fossil-fuel production in the basin. The data that supported these studies were refined and made more accessible using geographic information system (GIS) tools. The following types of data are included: (1) the bedrock geology of States included within the boundary of the Appalachian basin, (2) the locations of oil and gas wells and fields, (3) data produced for the National Oil and Gas Assessment, and (4) the stratigraphy, geochemistry, and production of coal. Data layers are available in shapefile and Zipped Keyhole Markup Language (KMZ) formats, which can be viewed using ArcGIS, Google Earth, or any software package that supports these data formats. Metadata for these datasets are available in HTML and XML formats. Metadata files contain information about the sources of data used to create the dataset, the creation process steps, the data quality, the geographic coordinate system and horizontal datum used for the dataset, the values of attributes used in the dataset table, information about the publication and the publishing organization, and other information that may be useful to the reader. All links in the metadata were valid at the time of compilation. Some of these links may no longer be valid. No attempt has been made to determine the new online location (if one exists) for the data.

Appalachian basin↗

USGS2011

Contributing recharge areas, groundwater travel time, and groundwater quality of the Missouri River alluvial aquifer near the Independence, Missouri, well field, 1997-2008

The City of Independence, Missouri, operates a well field in the Missouri River alluvial aquifer. Contributing recharge areas (CRA) were last determined for the well field in 1996. Since that time, eight supply wells have been installed in the area north of the Missouri River and well pumpage has changed for the older supply wells. The change in pumping has altered groundwater flow and substantially changed the character of the CRA and groundwater travel times to the supply wells. The U.S Geological Survey, in a cooperative study with the City of Independence, Missouri, simulated steady-state groundwater flow for 2007 well pumpage, average annual river stage, and average annual recharge. Particle-tracking analysis was used to determine the CRA for supply wells and monitoring wells, and the travel time from recharge areas to supply wells, recharge areas to monitoring wells, and monitoring wells to supply wells. The simulated CRA for the well field is elongated in the upstream direction and extends to both sides of the Missouri River. Groundwater flow paths and recharge areas estimated for monitoring wells indicate the origin of water to each monitoring well, the travel time of that water from the recharge area, the flow path from the vicinity of each monitoring well to a supply well, and the travel time from the monitoring well to the supply well. Monitoring wells 14a and 14b have the shortest groundwater travel time from their contributing recharge area of 0.30 years and monitoring well 29a has the longest maximum groundwater travel time from its contributing recharge area of 1,701 years. Monitoring well 22a has the shortest groundwater travel time of 0.5 day to supply well 44 and monitoring well 3b has the longest maximum travel time of 31.91 years to supply well 10. Water-quality samples from the Independence groundwater monitoring well network were collected from 1997 to 2008 by USGS personnel during ongoing annual sampling within the 10-year contributing recharge area (CRA) of the Independence well field. Statistical summaries and the spatial and temporal variability of water quality in the Missouri River alluvial aquifer near the Independence well field were characterized from analyses of 598 water samples. Water-quality constituent groups include dissolved oxygen and physical properties, nutrients, major ions and trace elements, wastewater indicator compounds, fuel compounds, and total benzene, toluene, ethylbenzene, and xylene (BTEX), alachlor, and atrazine. The Missouri Secondary Maximum Contaminant Level (SMCL) for iron was exceeded in almost all monitoring wells. The Missouri Maximum Contaminant Level (MCL) for arsenic was exceeded 32 times in samples from monitoring wells. The MCL for barium was exceeded five times in samples from one monitoring well. The SMCL for manganese was exceeded 160 times in samples from all monitoring wells and the combined well-field sample. The most frequently detected wastewater indicator compounds were N,N-diethyl-meta-toluamide (DEET), phenol, caffeine, and metolachlor. The most frequently detected fuel compounds were toluene and benzene. Alachlor was detected in 22 samples and atrazine was detected in 37 samples and the combined well-field sample. The MCL for atrazine was exceeded in one sample from one monitoring well. Samples from monitoring wells with median concentrations of total inorganic nitrogen larger than 1 milligram per liter (mg/L) are located near agricultural land and may indicate that agricultural land practices are the source of nitrogen to groundwater. Largest median values of specific conductance; total inorganic nitrogen; dissolved calcium, magnesium, sodium, iron, arsenic, manganese, bicarbonate, and sulfate and detections of wastewater indicator compounds generally were in water samples from monitoring wells with CRAs that intersect the south bank of the Missouri River. Zones of higher specific conductance were located just upstream from the Independence well field at south-bank outfalls from wastewater treatment plants, the Blue River, and the south bank of the Missouri River near the closed oil refinery. The long-term presence of these south-bank outfalls and the large specific conductance indicate that the surface water at the south bank of the Missouri River near the Independence well field may have consistently higher dissolved solids and nutrients that can be induced into the aquifer by pumping. Large median concentrations of sodium and chloride from samples from monitoring wells may be the result of road salt use on State Highway 291 or from Mill Creek, which drains the uplands south of the Independence well field. Large median concentrations of arsenic in samples from some monitoring well nests are most likely associated with dissolution of iron and sulfide minerals and fluctuation between oxidizing and reducing conditions. Largest median concentrations for arsenic are in the shallow depth interval where fluctuations between oxidizing and reducing conditions occur. Median concentrations of iron are large in all monitoring wells and are most likely caused by the interaction between fluctuating oxidizing and reducing conditions and siderite and ferric hydroxide. Spatial and temporal trends are not evident from the fuel compounds or total BTEX sample results. Alachlor and atrazine were detected in most monitoring wells and atrazine was detected more often than alachlor. The source of alachlor and atrazine in groundwater near the Independence well field is most likely from nearby agricultural land management practices and (or) the Missouri River. Many of the samples from monitoring wells with alachlor or atrazine detections greater than 10 percent have contributing recharge areas that intersect either agricultural land or the Missouri River bed.

Missouri↗

USGS2003

Chemical quality of water, sediment, and fish in Mountain Creek Lake, Dallas, Texas, 1994-97

The occurrence, trends, and sources of numerous inorganic and organic contaminants were evaluated in Mountain Creek Lake, a reservoir in Dallas, Texas. The study, done in cooperation with the Southern Division Naval Facilities Engineering Command, was prompted by the Navy’s concern for potential off-site migration of contaminants from two facilities on the shore of Mountain Creek Lake, the Naval Air Station Dallas and the Naval Weapons Industrial Reserve Plant. Sampling of stormwater (including suspended sediment), lake water, bottom sediment (including streambed sediment), and fish was primarily in Mountain Creek Lake but also was in stormwater outfalls from the Navy facilities, nearby urban streams, and small streams draining the Air Station. Volatile organic compounds, predominantly solvents from the Reserve Plant and fuel-related compounds from the Air Station, were detected in stormwater from both Navy facilities. Fuel-related compounds also were detected in Mountain Creek Lake at two locations, one near the Air Station inlet where stormwater from a part of the Air Station enters the lake and one at the center of the lake. Concentrations of volatile organic compounds at the two lake sites were small, all less than 5 micrograms per liter. Elevated concentrations of cadmium, chromium, copper, lead, mercury, nickel, silver, and zinc, from 2 to 4 times concentrations at background sites and urban reference sites, were detected in surficial bottom sediments in Cottonwood Bay, near stormwater outfalls from the Reserve Plant. Elevated concentrations of polycyclic aromatic hydrocarbons and polychlorinated biphenyls, compared to background and urban reference sites, were detected in surficial sediments in Cottonwood Bay. Elevated concentrations of polycyclic aromatic hydrocarbons, indicative of urban sources, also were detected in Cottonwood Creek, which drains an urbanized area apart from the Navy facilities. Elevated concentrations of polychlorinated biphenyls were detected in two inlets near the Air Station shoreline. Polycyclic aromatic hydrocarbon and heavy metal concentrations near the Air Station shoreline were not elevated compared to urban reference sites. Much larger concentrations of selected heavy metals, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls were detected in deeper, older sediments than in surficial sediments in Cottonwood Bay. The decreases in concentrations coincide with changes in wastewater discharge practices at the Reserve Plant. Elevated concentrations of polycyclic aromatic hydrocarbons and polychlorinated biphenyls also were detected in older sediments in the Air Station inlet. On the basis of dated sediment cores and contaminant discharge histories, contaminant accumulation rates in Cottonwood Bay were much greater historically than recently. Most heavy metals, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls that accumulated in the central and eastern parts of Cottonwood Bay appear to have come from the west lagoon on the Reserve Plant. Treated sewage and industrial-process wastewater were discharged to the west lagoon from about 1941 to 1974. Estimated annual contaminant accumulation rates in Cottonwood Bay decreased by from 1 to 2 orders of magnitude after 1974, when most point-source discharges to the west lagoon ceased. Polychlorinated biphenyls were detected in 61 of 62 individual fish-tissue samples. The largest average concentrations were in eviscerated channel catfish and the smallest were in largemouth bass fillets. Polychlorinated biphenyl and selenium concentrations from analyses of this study were large enough to prompt the Texas State Department of Health to issue a fish-possession ban for Mountain Creek Lake in 1996. Suspended sediments in stormwater at the lagoon outfalls and at sites on Cottonwood Creek were sampled and analyzed for major and trace elements, polycyclic aromatic hydrocarbons, organochlorine pesticides, and polychlorinated biphenyls. The suspended sediments from the outfalls contained about the same mixture of heavy metals and organic compounds, in elevated concentrations compared to reference sites, as bottom sediments from the lagoons and surficial bottom sediments in Cottonwood Bay. Diagnostic ratios of polycyclic aromatic hydrocarbons indicate that uncombusted fuel sources contribute to older sediments and that pyrogenic sources of polycyclic aromatic hydrocarbons dominate recently deposited sediments in Cottonwood Bay and along the Air Station shoreline.

Texas↗

USGS1991

Delineation of ground-water contamination using soil-gas analyses near Jackson, Tennessee

An investigation of the ground-water resources near Jackson, West Tennessee, was conducted during 1988-89. The study included determination of the occurrence of contaminants in the shallow aquifer using soil-gas analyses in the unsaturated zone. Between 1980 and 1988, an underground fuel-storage tank leaked about 3,000 gallons of unleaded fuel to the water table about 4 feet below land surface. A survey of soil gas using a gas chromatograph equipped with a photoionization detector showed concentrations of volatile organic compounds greater than IO, 000 parts per million near the leak These compounds were detected in an area about 240 feet long and 110 feet wide extending west from the point source. The chromatograms provided two distinct 'fingerprints' of volatile organic compounds. The first revealed the presence of benzene, toluene, andxylenes, which are constituents of unleaded fuel, in addition to other volatile compounds, in soil gas in the area near the leak The second did not reveal any detectable benzene, toluene, or xylenes in the soil-gas samples, but showed the presence of other unidentified volatile organic compounds in soil gas north of the storage tank. The distribution of total concentrations of volatile organic compounds in the unsaturated zone indicated that a second plume about 200 feet long and 90 feet wide was present about 100 feet north of the storage tank The second plume could have been the result of previous activities at this site during the 1950's or earlier. Activities at the site are believed to have included storage of solvents used at the nearby railyard and flushing of tanks containing tar onto a gravel-covered parking area. The delineation of these plumes has shown that soil-gas analyses can be a useful technique for identifying areas of contamination with volatile organic compounds in shallow water-table aquifers and may have broad applications in similar situations where the water table is relatively close to the surface.

Tennessee↗

USGS2015

North America's net terrestrial CO 2 exchange with the atmosphere 1990–2009

Scientific understanding of the global carbon cycle is required for developing national and international policy to mitigate fossil fuel CO 2 emissions by managing terrestrial carbon uptake. Toward that understanding and as a contribution to the REgional Carbon Cycle Assessment and Processes (RECCAP) project, this paper provides a synthesis of net land–atmosphere CO 2 exchange for North America (Canada, United States, and Mexico) over the period 1990–2009. Only CO 2 is considered, not methane or other greenhouse gases. This synthesis is based on results from three different methods: atmospheric inversion, inventory-based methods and terrestrial biosphere modeling. All methods indicate that the North American land surface was a sink for atmospheric CO 2 , with a net transfer from atmosphere to land. Estimates ranged from −890 to −280 Tg C yr −1 , where the mean of atmospheric inversion estimates forms the lower bound of that range (a larger land sink) and the inventory-based estimate using the production approach the upper (a smaller land sink). This relatively large range is due in part to differences in how the approaches represent trade, fire and other disturbances and which ecosystems they include. Integrating across estimates, "best" estimates (i.e., measures of central tendency) are −472 ± 281 Tg C yr −1 based on the mean and standard deviation of the distribution and −360 Tg C yr −1 (with an interquartile range of −496 to −337) based on the median. Considering both the fossil fuel emissions source and the land sink, our analysis shows that North America was, however, a net contributor to the growth of CO 2 in the atmosphere in the late 20th and early 21st century. With North America's mean annual fossil fuel CO 2 emissions for the period 1990–2009 equal to 1720 Tg C yr −1 and assuming the estimate of −472 Tg C yr −1 as an approximation of the true terrestrial CO 2 sink, the continent's source : sink ratio for this time period was 1720:472, or nearly 4:1.

Biogeosciences↗

USGS2013

LANDFIRE 2010 - updated data to support wildfire and ecological management

Wildfire is a global phenomenon that affects human populations and ecosystems. Wildfire effects occur at local to global scales impacting many people in different ways (Figure 1). Ecological concerns due to land use, fragmentation, and climate change impact natural resource use, allocation, and conservation. Access to consistent and current environmental data is a constant challenge, yet necessary for understanding the complexities of wildfire and ecological management. Data products and tools from the LANDFIRE Program help decision-makers to clarify problems and identify possible solutions when managing fires and natural resources. LANDFIRE supports the reduction of risk from wildfire to human lives and property, monitoring of fire danger, prediction of fire behavior on active incidents, and assessment of fire severity and impacts on natural systems [1] [2] [3]. LANDFIRE products are unique in that they are nationally consistent and provide the only complete geospatial dataset describing vegetation and wildland fuel information for the entire U.S. As such, LANDFIRE data are useful for many ecological applications [3]. For example, LANDFIRE data were recently integrated into a decision-support system for resource management and conservation decision-making along the Appalachian Trail. LANDFIRE is a joint effort between the U.S. Department of the Interior Office of Wildland Fire, U.S. Department of Agriculture Forest Service Fire & Aviation Management, and The Nature Conservancy. To date, seven versions of LANDFIRE data have been released, with each successive version improving the quality of the data, adding additional features, and/or updating the time period represented by the data. The latest version, LANDFIRE 2010 (LF 2010), released mid-2013, represents circa 2010 landscape conditions and succeeds LANDFIRE 2008 (LF 2008), which represented circa 2008 landscape conditions. LF 2010 used many of the same processes developed for the LF 2008 effort [3]. Ongoing refinement of the LANDFIRE vegetation and fuel data is necessary to improve the quality and usability of the data and to capture landscape disturbance. LANDFIRE relies on Landsat multi-spectral imagery to produce and update vegetation and fuel data. The deep Landsat archive provides data needed for vegetation classification, change analysis, and historical disturbance characterization, for which LANDFIRE has used more than 24,000 image scenes since the program’s inception. In addition, LF 2010 used airborne and spaceborne lidar, and spaceborne synthetic aperture radar (SAR) to map vegetation structure in areas where ground-based field information was lacking, including Alaska and U.S.-affiliated islands in the Caribbean and the Pacific. The mapping of insular areas is new for the 2010 data release; previous versions of LANDFIRE were limited to the conterminous U.S., Alaska, and Hawaii.

Earthzine↗

USGS2006

Executive summary

Geospatial data describing wildland fuel and current as well as historical vegetation conditions are essential for planning, implementing, and monitoring projects supported by the National Fire Plan and the Healthy Forests Restoration Act. Scientifically credible, consistent, and standardized spatial data allow fire and land managers to accurately identify the amount and locations of lands or communities with hazardous fuel build-up or extreme departure from historical conditions. These data also facilitate the prioritization of ecosystem restoration and hazardous fuel reduction treatments to protect ecosystems, property, and people. Moreover, these data may be used during specific wildland fire incidents to maximize firefighter safety, pre-position resources, and evaluate fire behavior under a variety of weather conditions.

General Technical Report↗

USGS1999

Temporal trends of bulk precipitation and stream water chemistry (1977-1997) in a small forested area, Krusne hory, northern Bohemia, Czech Republic

The Krusne hory (Erzgebirge or Ore Mountains) has been heavily affected by high atmospheric pollutant deposition caused by fossil fuel combustion in an adjacent Tertiary coal basin. Long-term routine sampling of bulk precipitation (1977-1996) and stream water (1977-1998) in a forested area on the south-eastern slope of the mountains were used to evaluate trends and patterns in solute concentration and flux with respect to controlling processes. From 1977 to 1996, the annual volume-weighted Ca 2+ and SO4 2- concentrations decreased in bulk precipitation. However, after 1989, when a pronounced and continuous decrease occurred in coal production, annual volume-weighted concentrations decreased for most solutes, except H+. The concentration decreases were marked, with 1996 levels at or below 50% of those in 1989. The lack of a trend in H + is attributed to similar decreases in both acid anions and neutralizing base cations. Stream water concentrations of most solutes, i.e. H + , Ca 2+ , Mg 2+ , SO4 2- and NO 3- , were highest at the onset of sampling in 1977, decreased markedly from 1977 to 1983 and decreased more gradually from 1983 to 1998. The spruce forest die-back and removal reduced dry deposition of these solutes by reducing the filtering action, which was provided by the forest canopy. A notable decrease in stream water Ca 2+ concentrations occurred after 1995 and may be due to the depletion of Ca 2+ , which was provided by catchment liming in 1986, 1988 and 1989. Solute flux trends in bulk atmospheric deposition and stream water generally were not significant and the lack of trend is attributed to the large interannual variability in precipitation quantity and runoff, respectively. All solutes except Na + varied seasonally. The average seasonal concentrations varied between the solutes, but for most solutes were highest in winter and spring and lowest in summer, correlating with the seasonal trend and runoff. For Ca 2+ , Mg 2+ and SO 4 2- , the concentration minimum occurs in September and the maximum occurs in February or March, correlating with the seasonal baseflow. These solutes are primarily controlled by the contribution of soil water and groundwater to stream flow. During snowmelt, the meltwater generally causes concentrations to decrease as soil water and groundwater are diluted. For NO3, average minimum concentrations occur in August at the end of the growing season concurrent with the lowest stream flow, and the maximum occurs in February and March with high stream flow during snowmelt. Seasonal stream water NO3- concentration variations are large compared with the long-term decrease.The Krusne hory (Erzgebirge or Ore Mountains) has been heavily affected by high atmospheric pollutant deposition caused by fossil fuel combustion in an adjacent Tertiary coal basin. Long-term routine sampling of bulk precipitation (1977-1996) and stream water (1977-1998) in a forested area on the south-eastern slope of the mountains were used to evaluate trends and patterns in solute concentration and flux with respect to controlling processes. From 1977 to 1996, the annual volume-weighted Ca2+ and SO42- concentrations decreased in bulk precipitation. However, after 1989, when a pronounced and continuous decrease occurred in coal production, annual volume-weighted concentrations decreased for most solutes, except H+. The concentration decreases were marked, with 1996 levels at or below 50% of those in 1989. The lack of a trend in H+ is attributed to similar decreases in both acid anions and neutralizing base cations. Stream water concentrations of most solutes, i.e. H + , Ca 2+ , Mg 2+ , SO 4 2- and NO 3- , were highest at the onset of sampling in 1977, decreased markedly from 1977 to 1983 and decreased more gradually from 1983 to 1998. The spruce forest die-back and removal reduced dry deposition of these solutes by reducing the filtering action, which was provided by the forest canopy. A notable decrease in stream water Ca2+ concentrations occurred after 1995 an

Hydrological Processes↗

USGS1984

Evaluation of potential embryotoxicity and teratogenicity of 42 herbicides, insecticides, and petroleum contaminants to mallard eggs

Results are reported for the embryotoxicity of 42 environmental contaminants applied externally to mallard ( Anas platyrhynchos ) eggs including crude and refined petroleum, and commercial formulations of herbicides and insecticides. Many of the petroleum pollutants were embryotoxic and moderately teratogenic and had LD 50 s of 0.3 to 5 μl per egg (∼6–90 μg/g egg). The most toxic was a commercial oil used for control of road dust followed by South Louisiana crude oil, Kuwait crude, no. 2 fuel oil, bunker C fuel oil, and industrial and automotive waste oil. Prudhoe Bay crude, unused crankcase oil, aviation kerosene, and aliphatic hydrocarbon mixtures were less toxic ( LD 50 s of 18 to over 75 μl) and less teratogenic. The LC 50 s of herbicides and insecticides in aqueous emulsion were measured by egg immersion; the most toxic were paraquat and trifluralin ( LC 50 s of about 1.5 Ibs/A; 1.7 kg/ha). Propanil, bromoxynil with MCPA, methyl diclofop, prometon, endrin, sulprofos, and parathion were toxic ( LC 50 s of 7 to 40 Ibs/A; 7.8–44.8 kg/ha), whereas 2,4-D, glyphosate, atrazine, carbaryl, dalapon, dicamba, methomyl, and phosmet were only slightly toxic or not toxic ( LC 50 s of 178 to over 500 Ibs/A; 199–560 kg/ha). Pesticides in nontoxic oil vehicle applied by microliter pipet were up to 18 times more toxic than when applied in water vehicle, which was probably due to better penetration of the pesticide past the eggshell and its membranes. Teratogenic effects and impaired embryonic growth are reported and results discussed in terms of potential hazard at field levels of application. A discussion is provided on the effects of pollutants on the eggs of other species of birds under laboratory and field conditions.

Archives of Environmental Contamination and Toxico↗

USGS1981

Uptake and depuration of petroleum hydrocarbons by crayfish

No differences were noted in the amount of naphthalene uptake (approximately 125 μ g) by individual crayfish exposed for 1, 2, or 4 hr at 25°C in open, non-aerated glass jars containing 14 C-naphthalene-5% of a water-soluble fraction (WSF) of No. 2 fuel oil. The cephalothorax, containing the hepatopancreas (a food absorption organ), showed greater uptake of naphthalene than the tail flesh or tail skeleton of individual crayfish exposed to the oil for 3 hr at 25°C. Crayfish exposed to the oil for 1, 2, or 4 hr and then placed in open, non-aerated containers of oil-free water lost most of the carbon-14 activity during the first 24 hr, with smaller losses occurring at 24 hr intervals up to and including 96 hr. Carbon-14 naphthalene in a 5% WSF of No. 2 fuel oil held in 12 open, non-aerated, oil-free, glass jars for 1, 2, 3, 4, and 5 hr at 25°C showed little volatilization (P > 0.4).

Archives of Environmental Contamination and Toxico↗