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The influence of postfire root strength decay on shallow landslide susceptibility in western Oregon

Severe wildfires can increase the potential for postfire landslides, partly due to the loss of vegetation and root reinforcement. This study investigates the multi-year dynamics of root strength following wildfire in coniferous forests of western Oregon and evaluates implications for postfire slope stability. Root tensile strength was measured through laboratory testing of 969 roots collected from 26 test pits over four postfire timeframes: unburned conditions, 4–12 months postfire (Cedar Creek, 2022), 24–35 months postfire (Holiday Farm, 2020), and 59–67 months postfire (Eagle Creek, 2017). Variables analyzed include root diameter, tensile thread strength, stiffness, progressive tensile strength with displacement, time-dependent strength and ductility, root area ratio, and cohesion. Results indicate a 50% reduction in root strength after wildfire, with the lowest values occurring around 4 years postfire. Projections indicate it could take 10–22 years following fire for root strength to recover to 70% and 90% of the prefire original root strength, respectively. This timeline indicates a multi-year window of vulnerability for shallow landslides that reaches a maximum approximately 4 years following fire. Brittle failure behavior was observed in burned root systems compared to unburned root systems, signaling a more abrupt loss of strength at yield. Simple slope stability analyses show that reduced root strength can lead to instability on more gentle slopes and under less saturation in comparison to unburned conditions. These findings highlight the critical role of root reinforcement in postfire slope stability and the long-term implications of wildfire disturbance on landslide susceptibility.

Oregon

Techniques to estimate generalized skew coefficients of annual peak streamflow for natural basins in Texas

This report presents two techniques to estimate generalized skew coefficients used for log-Pearson Type III peak-streamflow frequency analysis of natural basins in Texas. A natural basin has less than 10 percent impervious cover, and less than 10 percent of its drainage area is controlled by reservoirs. The estimation of generalized skew coefficients is based on annual peak and historical peak streamflow for all U.S. Geological Survey streamflow-gaging stations having at least 20 years of annual peak-streamflow record from natural basins in Texas. Station skew coefficients calculated for each of 255 Texas stations were used to estimate generalized skew coefficients for Texas. One technique to estimate generalized skew coefficients involved the use of regression equations developed for each of eight regions in Texas, and the other involved development of a statewide map of generalized skew coefficients. The weighted mean of the weighted mean standard errors of the regression equations for the eight regions is 0.36 log 10 skew units, and the weighted mean standard error of the map is 0.35 log 10 skew units. The technique based on the map is preferred for estimating generalized skew coefficients because of its smooth transition from one region of the State to another.

Texas

Towards mobile wind measurements using joust configured ultrasonic anemometer for applications in gas flux quantification

Small uncrewed aerial systems (sUASs) can be used to quantify emissions of greenhouse and other gases, providing flexibility in quantifying these emissions from a multitude of sources, including oil and gas infrastructure, volcano plumes, wildfire emissions, and natural sources. However, sUAS-based emission estimates are sensitive to the accuracy of wind speed and direction measurements. In this study, we examined how filtering and correcting sUAS-based wind measurements affects data accuracy by comparing data from a miniature ultrasonic anemometer mounted on a sUAS in a joust configuration to highly accurate wind data taken from a nearby eddy covariance flux tower (aka the Tower). These corrections had a small effect on wind speed error, but reduced wind direction errors from 50° to >120° to 20–30°. A concurrent experiment examining the amount of error due to the sUAS and the Tower not being co-located showed that the impact of this separation was 0.16–0.21 ms − 1 "> ms − 1 , a small influence on wind speed errors. Lower wind speed errors were correlated with lower turbulence intensity and higher relative wind speeds. There were also some loose trends in diminished wind direction errors at higher relative wind speeds. Therefore, to improve the quality of sUAS-based wind measurements, our study suggested that flight planning consider optimizing conditions that can lower turbulence intensity and maximize relative wind speeds as well as include post-flight corrections.

Alaska

‘The fish that stop’: Drivers of historical decline for Pacific cod and implications for modern management in an era of rapidly changing climate

n the Gulf of Alaska, a series of marine heat waves depleted Pacific cod ( Gadus macrocephalus ) biomass to the lowest abundance ever recorded and led to the fishery’s closure in 2020. Although the fishery has been productive for decades, this collapse may have historical precedents. Traditional knowledge holders refer to cod as ‘the fish that stop’, and there is a suggested period of decline in the 1930s. Here we conduct a catch reconstruction of the early commercial fishery (1864–1950), confirming a rapid catch decline in the 1920s and 1930s. Next, we evaluate evidence for possible drivers. We document changes to demand and technology that contributed to declining catch. However, we also find both qualitative and quantitative evidence of depletion, suggesting catch declines were not driven entirely by social factors. Overfishing may have contributed to localized catch declines as evidenced by declining catch rates in heavily fished localities. We also find evidence for climate as a driver of regional decline, with the period of catch decline characterized by up to 2°C higher temperatures as compared to the earlier period of high fisheries production. Our analysis underscores the importance of understanding long-term drivers of fisheries productivity and the value of linking fisheries and climate histories.

Alaska

Reaction kinetics and accelerant effects of sulfides in early mature hydrocarbon generation using hydrous pyrolysis

Hydrocarbon generation in organic-rich sediments is influenced by the molecular organic composition and relative abundance of associated minerals. Certain mineral-derived elements act as catalysts and reaction intermediaries, facilitating early-stage hydrocarbon formation in potential source rocks. This study investigated the role of sulfur contributed from pyrite as an accelerant in thermal reaction, focusing on its effects on early maturation and consequent hydrocarbon generation from gilsonite (low-sulfur solid petroleum). Hydrous pyrolysis (HP) experiments were conducted on mixtures of gilsonite and pyrite in varying ratios (1:0.1, 1:0.5, 1:1, 1:2, and 1:10 w/w gilsonite:pyrite) at 320, 350, and 370 °C for 72 h. Untreated and thermally altered residues were analyzed using solid bitumen reflectance (BR o , %), total organic carbon (TOC) content, programmed temperature pyrolysis, scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), and X-ray diffraction (XRD) to evaluate the potential accelerant role of pyritic sulfur in hydrocarbon formation. The results show HP residues at 320 and 350 °C with greater pyrite concentrations had higher BR o , while reflectance values were similar in the 370 °C residues, regardless of pyrite concentration, suggesting enhanced reaction at lower thermal conditions. Increasing pyrite content systematically decreased hydrogen index (HI) values while increasing the transformation ratio (TR) and production index (PI), indicating enhanced conversion of organic matter to hydrocarbons with increasing pyrite concentrations. Gas yields increased with pyrite addition, particularly at 350 °C, confirming secondary cracking effects. However, gas production stabilized or declined at higher pyrite loadings (1:10), suggesting alternative reaction pathways such as coke formation. Our data indicate the presence of pyrite lowers the activation energy for thermal cracking, shifting peak experimental hydrocarbon generation temperatures downward by 20–30 °C, with the most pronounced accelerant effects observed at moderate pyrite concentrations (1:0.5 and 1:1). The thermodynamic framework reveals that pyrite stability is influenced by experimental conditions, with pyrrhotite formation favored in the presence of gilsonite due to reduced oxygen fugacity. Pyrite transformation to pyrrhotite, as observed through XRD, SEM-EDS, and predicted by thermodynamic data, further supports the accelerant role of S, as pyrrhotite exhibits a higher hydrogen transfer potential, promoting early oil generation. These findings highlight the importance of pyrite in modulating hydrocarbon generation pathways in organic-rich systems.

Journal of Analytical and Applied Pyrolysis

Wetland sedimentation and vegetation patterns near selected highway crossings in West Tennessee

Wetland sedimentation and vegetation patterns at 11 highway crossings in West Tennessee were studied from 1987 to 1989. The purpose of the study was to investigate potential adverse effects of highway crossings on wetlands. Sedimentation rates, determined from root-burial depths, were highly variable. Average rates offine-grained deposition ranged from 0.005 to 0.033 foot per year for stations in locally ponded areas and from -0.002 to 0.039 foot per year for stations in drained areas. Sedimentation rates upstream from highway crossings were not significantly different from downstream rates at 8 of the 11 study sites. Three study sites had significantly greater sedimentation rates downstream. Sand splays were observed downstream from bridges at most study sites. Vegetation patterns and tree growth appear most strongly related to hydropetiod, defined as the average length of time an area is covered by water each year. The influence of sedimentation on tree growth is difficult to separate from the influence of hydroperiod because areas with high sedimentation rates typically have long hydroperiods. Estimated hydroperiod increased no more than 1 percent because of backwater from the highway crossings at the 11 study sites, while the estimated average depth of flood-plain inundation increased by an average of 6 percent.

Tennessee

Groundwater-level elevations in the Denver Basin bedrock aquifers and Upper Black Squirrel Creek alluvial aquifer, El Paso County, Colorado, 2021–24

El Paso County is the second-most populous county in Colorado and is projected to grow another 15 percent by 2030. Within El Paso County is the Upper Black Squirrel Creek Designated Groundwater Basin (Black Squirrel Basin), an area where surface water is scarce and water users rely primarily on groundwater from five different aquifers (the Upper Black Squirrel Creek alluvial aquifer and four bedrock aquifers within the Denver Basin aquifer system: the lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers) to meet their needs. Currently (2024), land within the Upper Black Squirrel Creek Basin is primarily used for rural grazing and agriculture; however, municipal development is ongoing. In 2021, the U.S. Geological Survey, in cooperation with the Upper Black Squirrel Creek Ground Water Management District, began a study to establish a baseline dataset and assess the groundwater resources of the aquifers within the Black Squirrel Basin. A network of 39 wells was established in 2021; discrete groundwater-level measurements were made bimonthly. Nine of the 39 wells were equipped with pressure transducers to record hourly groundwater-level data. Seven wells had statistically significant seasonal trends, and trends at 3 wells were negative. For the discrete data, 16 wells had a significant trend for the study period, and 4 wells had negative trends. For the time-series data, 8 wells had significant trends, and 3 wells had negative trends. Potentiometric surface maps were created for this study using discrete, static groundwater levels measured in April 2023. These maps showed the estimated groundwater flow direction from the north-northwest to the south-southeast in the alluvial aquifer and from the northwest to the east-southeast for the lower Dawson and Denver aquifer wells. This study indicates the potential benefit of monitoring wells in the areas near municipal pumping. Additional monitoring could lead to a better understanding of connectivity between aquifers and be an important tool for assessing long-term sustainability of groundwater use.

Colorado

Roadway runoff induced acute mortality in juvenile coho salmon during spring storm events

Extensive mortalities of adult coho salmon ( Oncorhynchus kisutch ), often called “Urban Runoff Mortality Syndrome” (URMS), have been documented during the fall in creeks where water quality has been degraded by roadway runoff. The primary cause of mortality is 6PPD-quinone (6PPDQ; N -(1,3-dimethylbutyl)- N ′-phenyl- p -phenylenediamine quinone)–an ozone transformation product that forms on all vehicle tires. Laboratory studies have shown that juvenile coho salmon are highly sensitive to 6PPDQ exposure. Unlike adults, juveniles reside in impacted watersheds year-round, including during the spring when 6PPDQ concentrations can frequently exceed lethal thresholds during storms. To assess the potential incidence of URMS in springtime rearing habitats for juvenile coho salmon, we conducted a paired water quality and toxicology study at Miller Creek, a runoff-impacted watershed in Normandy Park, WA, USA. Using a small field facility, three naïve groups of juvenile coho salmon ( N = 720) were exposed to either creek water or groundwater ( N = 120 per treatment per storm), across three spring storms while comparing water quality and mortality end points. In creek water during exposures, peak 6PPDQ concentrations reached 73–110 ng/L, exceeding reported median lethal concentrations (LC 50 ) for coho salmon. Over each 24–73 h storm exposure period, ∼80% of Miller Creek-exposed juvenile salmon died. No mortality occurred among control fish exposed to groundwater. These results indicate previously unidentified mortality risks for juvenile life stages of coho salmon during spring storms, suggesting substantial and year-round water quality impediments to coho salmon health and recovery across roadway runoff-impacted spawning, rearing, and migratory habitats.

Washington

Evaluation of models for estimating hydraulic conductivity in glacial aquifers from NMR logging

Nuclear magnetic resonance (NMR) logging is a promising method for estimating hydraulic conductivity ( K ). During the past ∼60 years, NMR logging has been used for petroleum applications, and different models have been developed for deriving estimates of permeability. These models involve calibration parameters whose values were determined through decades of research on sandstones and carbonates. We assessed the use of five models to derive estimates of K in glacial aquifers from NMR logging data acquired in two wells at each of two field sites in central Wisconsin, USA. Measurements of K , obtained with a direct push permeameter (DPP), K DPP , were used to obtain the calibration parameters in the Schlumberger-Doll Research, Seevers, Timur-Coates, Kozeny-Godefroy, and sum-of-echoes (SOE) models so as to predict K from the NMR data; and were also used to assess the ability of the models to predict K DPP . We obtained four well-scale calibration parameter values for each model using the NMR and DPP measurements in each well; and one study-scale parameter value for each model by using all data. The SOE model achieved an agreement with K DPP that matched or exceeded that of the other models. The Timur-Coates estimates of K were found to be substantially different from K DPP . Although the well-scale parameter values for the Schlumberger-Doll, Seevers, and SOE models were found to vary by less than a factor of 2, more research is needed to confirm their general applicability so that site-specific calibration is not required to obtain accurate estimates of K from NMR logging data.

Wisconsin

Shoals and valley plugs in the Hatchie River watershed

Agricultural land use and gully erosion have historically contributed more sediment to the streams of the Hatchie River watershed than those streams can carry. In 1970, the main sedimentation problem in the watershed occurred in the tributary flood plains. This problem motivated channelization projects (U.S. Department of Agriculture, 1970). By the mid-1980's, concern had shifted to sedimentation in the Hatchie River itself where channelized tributaries were understood to contribute much of the sediment. The Soil Conservation Service [Natural Resources Conservation Service (NRCS) since 1996] estimated that 640,000 tons of bedload (sand) accumulates in the Hatchie River each year and identified roughly the eastern two-thirds of the watershed, where loess is thin or absent, as the main source of sand (U.S. Department of Agriculture, 1986a). The U.S. Geological Survey (USGS), in cooperation with the West Tennessee River Basin Authority (WTRBA), conducted a study of sediment accumulation in the Hatchie River and its tributaries. This report identifies the types of tributaries and evaluates sediment, shoal formation, and valley-plug problems. The results presented here may contribute to a better understanding of similar problems in West Tennessee and the rest of the southeastern coastal plain. This information also will help the WTRBA manage sedimentation and erosion problems in the Hatchie River watershed. The source of the Mississippi section of the Hatchie River is in the sand hills southwest of Corinth, Mississippi (fig. 1). This section of the Hatchie River flows northward in an artificial drainage canal, gathering water from tributary streams that also are channelized. The drainage canal ends 2 miles south of the Tennessee State line. The Tennessee section of the Hatchie River winds north and west in a meandering natural channel to the Mississippi River. Although most of the Hatchie River tributaries are also drainage canals, the river's main stem has kept most of its natural character. The Hatchie River flows through a wide valley bottom occupied mostly by riverine wetland. Historically, the valley bottom has supported hardwood forests. Since publication of the first Hatchie River report (U.S. Department of Agriculture, 1970), the channel of the river has become shallower, and flooding has increased (U.S. Department of Agriculture 1986b). These wetter conditions inhibit growth of hardwoods and lead to premature hardwood mortality. The NRCS has predicted that despite efforts to control erosion in the uplands, most of the valley-bottom forest will die. '...swamping may be so prevalent as to change most of the Hatchie River Basin flood plain into a marsh condition, with the only remnants of the present bottomland hardwood timber remaining. (U.S. Department of Agriculture, 1986b). Loss of channel depth has been concentrated in short reaches near tributary mouths. At the mouths of Richland, Porters, Clover, and Muddy Creeks, navigation has become difficult for recreational users (Johnny Carlin, West Tennessee River Basin Authority, oral commun., 1998). As the low-gradient alluvial system of the Hatchie River accumulates sediment, another common outcome has been the formation of valley plugs, areas where 'channels are filled with sediment, and all the additional bedload brought downstream is then spread out over the flood plain until a new channel has been formed' (Happ, 1975). Valley plugs typically form where the slope of a sand-laden tributary decreases downstream, or where the tributary joins its parent stream (Happ and others, 1940; Diehl, 1994, 1997; Smith and Diehl, 2000).

Mississippi, Tennessee

An early Holocene wet period in the southwestern United States

Multiple generations of spring-fed streams traversed ∼800 km 2 of the Las Vegas Valley in southern Nevada between ca. 10.9 ka and 8.5 ka, depositing an extensive tufa network. The scale of this network and diversity of tufa morphologies is novel in North America and offers an opportunity to obtain quantitative paleoclimate data for the region during the early Holocene. We determined isotopic compositions and estimated past temperatures using clumped isotope data from early Holocene tufa on the valley floor (698 m) as well as tufa forming today at higher elevation in the nearby Spring Mountains at Cold Creek Spring (1856 m). Modern and fossil tufa yielded comparably low δ 18 O values, implying that source waters for both were derived from high-elevation winter precipitation. Clumped isotope temperatures of modern tufa average 15.8 ± 2.5 °C, aligning with mean summer temperatures of the emergent spring water, and indicate equilibrium conditions of tufa formation. The early Holocene tufa yielded similar clumped isotope temperatures, averaging 15.2 ± 3.9 °C, meaning it precipitated at temperatures that occur at much higher elevations today. The Las Vegas tufa record, combined with nearby and temporally correlative paleospring and lacustrine records, suggest that cool/wet conditions prevailed throughout the Mojave Desert during the early Holocene. These records also demonstrate that spring ecosystems responded to millennial-scale hydroclimate variations that supersede climate change driven solely by insolation. The previously unrecognized pattern of ecosystem response to hydroclimate documented here may assist in understanding climate drivers for the early Holocene and provide critical information for the fate of groundwater-dependent ecosystems in the southwestern United States.

Nevada

Groundwater structures fish growth and production across a riverscape

Landscapes are composed of habitat patches and conditions that vary across space and time. While habitat variability and complexity can support important ecological processes and ecosystem services, the dynamic nature of habitats can also constrain organismal growth and production as optimal conditions are fleeting. In riverine ecosystems, groundwater discharge to streams stabilises water temperature and flow regimes, thus mediating how habitat complexity is expressed. Yet, how stable habitats structure growth and production within the broader landscape matrix is not well understood. In this study, we explored the effects of groundwater on spatiotemporal variation in growth and production for juvenile Yellowstone cutthroat trout ( Oncorhynchus virginalis bouvieri ) across the upper Snake River catchment, Wyoming, USA. We combined machine learning techniques and remotely sensed landscape data to estimate groundwater availability across the river network, which we linked to stream temperature regimes and conspecific density. We then used Bayesian hierarchical models to quantify the effects of temperature, density and groundwater on spatiotemporal variation in fish growth and production in 52 focal reaches. Finally, we predicted body size trajectories and trends in total production continuously over both space and time to understand the effect of groundwater at the riverscape scale. Groundwater discharged to streams where topography changes abruptly in valley-bottom areas underlain by coarse glacial deposits. Groundwater stabilised temperature regimes and was associated with high trout densities. Temperature and density, in turn, interacted to influence growth rates: growth increased strongly with temperature, but this effect was reduced when density was high. Accordingly, variation in groundwater availability among stream reaches diversified growth and production regimes. In reaches with low groundwater availability, growth and production declined over time from summer maxima. In contrast, in reaches with high groundwater availability, temporal trends in growth and production were hump-shaped—peaking in autumn—and mean production was greater. At the riverscape scale, temporal asynchrony in growth rates generated convergent spatial variation in growth capacity, but—when combined with density—led to the formation of distinct hotspots of production. Our results demonstrate how groundwater, an important driver of aquatic ecosystem heterogeneity, structures trout growth and production across space and time. Importantly, rare, but stable habitats may disproportionately affect ecological processes and serve as key sources of population diversity at larger spatial scales.

Wyoming

Metal fingerprints of Eocene rhyolite magmas coincident with Carlin-type gold deposition in Nevada USA

Eocene magmatic systems contemporaneous with world-class Carlin-type Au deposits in Nevada (USA) have been proposed by some researchers as a key ingredient for Au mineralization, though evidence conclusively demonstrating their genetic relationship remains tenuous. This study provides the first direct evidence of the pre-eruptive metal budget of volatile- and metal-charged silicic magmas coincident in time (~41 to 34 Ma) and space (within 5 km) with Carlin-type Au deposits. We characterize the pre-eruptive metal fingerprints of these diverse magmatic systems to assess their potential as sources of metals for Carlin-type Au mineralization. Metal abundances from quartz-hosted melt inclusions (Au, Te, Ag, Sb, Tl, Mo, W, Sn, As, Pb, Co, Cu, Ni, and Zn) characterized in situ by SHRIMP-RG and LA-ICP-MS represent our best (and only) estimates for the pre-eruptive metal budget in these systems. Median metal concentrations are generally within one order of magnitude of average upper crust and average continental rhyolite values. But there are two notable exceptions, with median Au contents extending >1 order of magnitude higher than average upper crust and median Cu contents ranging >1 order of magnitude lower than upper crust. Despite this, melts contain lower Au/Cu (<0.1), Au/Ag (<5), and Au/Tl (<0.3) than most ore-grade Carlin-type rock samples and quartz-hosted fluid inclusions, regardless of their age and timing relative to nearby Carlin-type Au mineralization. The metal fingerprints of these magmatic systems, de-fined both by traditional and multivariate compositional data analysis techniques, are distinct from one another. Yet none are particularly specialized, e.g., high Au/Cu, in terms of being ideal ingredients as postulated by magmatic models for Carlin-type Au mineralization. Magmatic Au contents do not appear to be correlated with rhyolite “flavors” in the way that Cu, Sn, and Nb contents are. Fluid/melt partitioning modeling and magma volume estimates support the idea that a diverse array of non-specialized silicic magmas could feasibly contribute some or potentially all of the Au, Ag, and Cu in Carlin-type systems. The compositional diversity among contemporaneous magmatic systems could possibly contribute to some of the diversity observed across Carlin-type Au districts in Nevada.

Nevada

Assessing locations susceptible to shallow landslide initiation during prolonged intense rainfall in the Lares, Utuado, and Naranjito municipalities of Puerto Rico

Hurricane Maria induced about 70 000 landslides throughout Puerto Rico, USA, including thousands each in three municipalities situated in Puerto Rico's rugged Cordillera Central range. By combining a nonlinear soil-depth model, presumed wettest-case pore pressures, and quasi-three-dimensional (3D) slope-stability analysis, we developed a landslide susceptibility map that has very good performance and continuous susceptibility zones having smooth, buffered boundaries. Our landslide susceptibility map enables assessment of potential ground-failure locations and their use as landslide sources in a companion assessment of inundation and debris-flow runout. The quasi-3D factor of safety, F 3 , showed strong inverse correlation to landslide density (high density at low F 3 ). Area under the curve (AUC) of true positive rate (TPR) versus false positive rate (FPR) indicated success of F 3 in identifying head-scarp points (AUC = 0.84) and source-area polygons (0.85 ≤ AUC ≤ 0.88). The susceptibility zones enclose specific percentages of observed landslides. Thus, zone boundaries use successive F 3 levels for increasing TPR of landslide head-scarp points, with zones bounded by F 3 at TPR = 0.75, very high; F 3 at TPR = 0.90, high; and the remainder moderate to low. The very high susceptibility zone, with 118 landslides km −2 , covered 23 % of the three municipalities. The high zone (51 landslides km −2 ) covered another 10 %.

Puerto Rice

Assessing future hydrologic extremes using an integrated hydrology and river operations model in the Russian River watershed

Study region The Russian River watershed, situated in coastal, northern California, experiences hydrologic extremes, including periodic droughts and flooding. Water managers are working to maintain sustainable water supplies and environmental flows, while mitigating flood risks. Study focus This paper introduces an integrated hydrology and river operations model for the Russian River watershed. This model is distinct from models in previous studies because it represents surface-groundwater interactions and uses climate forcings to estimate dynamic water use demands that are superimposed onto both reservoir operations and water supply constraints. The model was used to examine three historical (1990–2015) and eight future (2016–2099) water use and climate change scenarios. New hydrological insights for the region The direct connection between streams and aquifers facilitated both annual aquifer replenishment by high winter streamflows and streamflow depletion by groundwater wells (19 % of pumped groundwater in alluvial aquifers from stream leakage) during critical low flow periods. Simulated streamflow changes included 59 % longer and 54 % more severe streamflow droughts, 26 % lower seasonal low streamflows, and up to 125 % higher peak streamflows, averaged over future climate and water use scenarios, suggesting increased future flood and water availability risks. Results showed the importance of reservoir operations for mitigating the impacts of increased hydroclimatic volatility, despite a decrease in reservoir reliability at Lake Mendocino, suggesting that reservoir management may be used to decrease future risks.

California

Scenarios to assess the future water availability in the Mississippi River Valley Alluvial Aquifer for the Cache River and Grand Prairie Regions of Arkansas

The U.S. Geological Survey, as part of the Arkansas Groundwater Initiative, developed forecast scenarios using previously calibrated MODFLOW 6 groundwater models that focused on the Cache and Grand Prairie Critical Groundwater Areas to assess the impact of future climate and water management strategies on the Mississippi River Valley alluvial aquifer. A Soil Water Balance model was used to forecast recharge and irrigation water use. The forecast scenario period was from January 1, 2019, through December 31, 2055, with monthly stress periods. Twenty scenarios were simulated and included seven alternate climate forecasts, five 13 general groundwater pumping reduction scenarios (round 1), and groundwater pumping reduction scenarios by crop type and for the Bayou Meto Water Management Project and Grand Prairie Area Demonstration Project (round 2). Declines in saturated thickness within the Cache Critical Groundwater Area were larger for 18 of the 20 scenarios as compared to outside of the Critical Groundwater Area. The largest average increase in saturated thickness inside the Critical Groundwater Area was 6.4 m which occurred for the round 1, 50 percent reduction scenario. Automatic reductions in groundwater pumping by MODFLOW 6 in the Cache simulation ranged from 0.02 to 13.1 percent of total groundwater pumping. For the Grand Prairie model domain, the average change in saturated thickness of the Mississippi River Valley alluvial aquifer inside the Critical Groundwater Area for the forecast period ranged between -6.6 to 1.7 m. The average saturated thickness of the Mississippi River Valley alluvial aquifer inside the Grand Prairie Critical Groundwater Area declined for 16 of the 20 scenarios. The average reduction in requested groundwater pumping for all scenarios inside the Grand Prairie Critical Groundwater Area was 25.1 percent, and the largest reduction was 46.5 percent.

ESS Open Archive

The addition of 144Nd atomic mass to routine ICP-MS analysis as a Quick Screening Tool for Approximating Rare Earth Elements (Q-STAR) in natural waters

Rare earth elements (REEs) are a class of critical minerals, all of which can have supply chain vulnerability that impacts economic security. These elements are widely measured in environmental matrices via inductively coupled plasma mass spectrometry (ICP-MS); however, successful quantification can require time-consuming, sample-specific optimization. While a sample-by-sample approach is appropriate for targeted quantification studies, this approach is not suitable for mineral exploration efforts where rapidly screening thousands of samples for the presence of REEs is desired. Here, we demonstrated the use of a Quick Screening Tool for Approximating REEs (Q-STAR) to detect REEs in surface water and groundwater matrices, collected as part of existing environmental studies. A mass-to-charge ratio of 144 ( m / z = 144) was added to an ICP-MS method to screen for REEs in filtered water samples submitted for metals analyses to the U.S. Geological Survey (USGS) National Water Quality Laboratory. We detected the presence of REEs above a reference threshold of 1200 counts per second in 18 % of pre-selected 6626 samples. Using this screened dataset, we mapped estimated dissolved REE concentrations across the United States in relation to ecoregions and underlying geology. Data are constrained to where sample collection took place but nevertheless show estimated aqueous dissolved REE concentrations on a geographic scale that has not yet been studied. To validate Q-STAR, REEs were measured in a USGS standard reference sample, a subset of 88 archived filtered water samples, and in fresh filtered surface water samples. Our targeted analyses demonstrated a strong linear relationship between Q-STAR predicted and measured values in all archived samples for Nd (r 2 = 0.94), and light REEs (LREEs) such as lanthanum (La) (r 2 = 0.93), praseodymium (Pr) (r 2 = 0.94) and samarium (Sm) (r 2 = 0.94). Using Q-STAR screen values, nine field sites were identified and surface water samples recollected to confirm the continued presence of Nd and LREEs. Q-STAR can be used to screen an unlimited number of water samples for the presence of REEs prior to time-intensive and costly quantitative analyses and to generate large REE datasets for further investigation.

Journal of Geochemical Exploration

Simulating present and future groundwater/surface-water interactions and stream temperatures in Beaver Creek, Kenai Peninsula, Alaska

In many places, coldwater ecosystems are facing increasing pressure from anthropogenic warming. This study examined stream temperatures and the water balance in the Beaver Creek watershed on the Kenai Peninsula in south-central Alaska—an area that is experiencing rapid warming. Low-gradient streams near the Kenai coast provide important spawning and rearing habitat for salmon but may be especially vulnerable to rising temperatures, because of long residence times, inflows from abundant riparian wetlands, and reliance on groundwater discharge that may also warm, or decrease in volume with rising evapotranspiration. In recent decades, observed maximum 7-day temperatures have consistently exceeded statistical (regression-based) projections. Here we simulate total streamflows and temperatures with a physics-based model that links the Soil Water Balance, MODFLOW 6 and SNTEMP simulation codes on a 7-day timestep. The model is based on existing data and groundwater levels, instream flows, and stream temperatures collected during 2019–23. Future climate scenarios were developed for 2023–50 from downscaled climate projections. Results indicate that groundwater discharge is about 64 percent of the total streamflow during the months of May through September. Total streamflow and groundwater discharge are expected to remain similar to current conditions through 2050. Stream temperatures are expected to rise; by midcentury, near the Beaver Creek mouth the model predicts 34 to 63 additional days per year with average weekly temperatures above 13 degrees Celsius, 14 to 81 additional days with average weekly temperatures above 15 degrees Celsius, and routine exceedances of 20 degrees Celsius during the warmest periods. Projected stream temperatures vary spatially. Areas of high groundwater inflows in the lower main stem and some tributaries may be most resilient to warming air temperatures during dry conditions. During storm events, groundwater-dominated tributaries may have the coolest stream temperatures.

Alaska