USGS Science⌕ Search

SEARCH · USGS Science

Results for “Frontiers in Ecology and Environment”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

1,673 records · Page 29Linked to original sources
USGS2026

A targeted approach for mapping groundwater discharge to surface water and fish thermal refuge in four Lake Ontario tributaries

The duration, magnitude, and frequency of heatwaves are predicted to increase in the coming decades, a combination that can reduce the survival of many fish species. Across the world, there is broad interest in identifying thermal refuge for heat-intolerant fish species and exploring opportunities to enhance or protect these areas. Because deeper groundwater maintains a relatively constant temperature, groundwater-influenced areas along streams can provide cool-water refuge for fish during periods of extreme heat. A targeted approach was developed for identifying existing cold-water zones and areas of substantial groundwater discharge in four high priority Lake Ontario tributaries. Our approach included: (1) predicting where groundwater discharge is most likely with a simple geospatial model and (2) using model predictions to select field sites for intensive high-resolution study, including ground-based mapping of groundwater features (springs, seeps, tributaries) as well as drone-based optical and thermal infrared surveys. Results from field sites were used to both verify model performance and map different types and aerial extents of thermal anomalies. Geospatial modelling successfully predicted regions of widespread groundwater upwelling, later verified and mapped by field and drone surveys. Comparison of model and field survey results further highlighted specific geospatial layers, such as soil/bedrock types and topographic wetness index, as being particularly useful for predicting groundwater influence on streams in the study area. In addition, a comparison of geospatial model results with a model of fish abundances along the studied streams showed significant positive correlations for many heat-intolerant fish species over a wide geographic area. The approach developed in this study can be applied to other watersheds to highlight areas of probable groundwater discharge and could be used by fishery and water resource managers to support cold-water fish habitat management decision-making and resource conservation.

New York↗
USGS2026

Polystyrene microplastics alter the accumulation and elimination dynamics of silver nanoparticles in Daphnia magna

Rationale Microplastics (MPs) can interact with engineered nanomaterials and alter their environmental fate and bioavailability. However, their influence on the bioaccumulation dynamics of silver nanoparticles (AgNPs) in aquatic filter feeders under environmentally relevant conditions remains poorly understood. We hypothesized that polystyrene microplastics (PS-MPs) alter the uptake, elimination and overall bioaccumulation dynamics of AgNPs in Daphnia magna . Methodology Adult D. magna were exposed to isotopically labeled citrate-coated 109 AgNPs in the presence and absence of PS-MPs. Waterborne uptake, dietary uptake, assimilation efficiency, food ingestion and elimination were quantified experimentally and incorporated into a biodynamic model to predict steady-state silver (Ag) concentrations under environmentally relevant exposure scenarios. Results PS-MPs increased waterborne Ag accumulation by approximately eightfold compared with AgNPs exposure alone. However, Ag elimination was substantially faster, with 98% of accumulated Ag eliminated after five days of depuration compared with 66% without PS-MPs. PS-MPs also reduced food ingestion rates (IRs), while assimilation efficiency remained largely unchanged. Biodynamic modeling predicted that steady-state Ag accumulation was approximately fivefold greater in the presence of PS-MPs, with waterborne exposure becoming the dominant accumulation pathway. Discussion These findings suggest that PS-MPs alter bioaccumulation dynamics of AgNPs in filter-feeding organisms by enhancing organism-associated Ag during waterborne exposure while accelerating Ag elimination, likely through particle-associated transport and gut egestion. Collectively, these results underscore the complexity of Ag bioaccumulation processes when MPs and AgNPs interact and highlight the importance of studies conducted under environmentally relevant conditions.

Environmental Chemistry↗
USGS2025

Multidecadal change in pesticide concentrations relative to human health benchmarks in the Nation’s groundwater

Groundwater-quality trend assessments identify aquifers that are responding to changes in pesticide use and the compounds that may pose a threat to water availability. The U.S. Geological Survey has been monitoring pesticide concentrations in groundwater for 25 principal aquifers across the conterminous United States since 1993. The groundwater well locations represent a range of soils, climate, and landforms. The wells are used to monitor groundwater underlying selected agricultural and urban settings and groundwater used for domestic supply. This study examined changes in relative concentrations, defined here as the percentage of wells with pesticide concentrations exceeding a human health benchmark (HHB). HHBs used in this report are legally enforceable drinking-water standards and nonenforceable drinking water levels. Relative pesticide concentration increases may lead to decreased water availability, as restrictions may be put in place for groundwater used as a drinking-water source. This study focused on concentration changes in 22 pesticides that were included in laboratory analysis from 1993 to 2023. The analysis and interpretation of these pesticide concentrations in groundwater have been separated into approximate decadal intervals (decade 1 (1993–2001), decade 2 (2002–12), and decade 3 (2013–22). For one pesticide, 1,2-dibromo-3-chloropropane (DBCP), concentration data were also collected in decade 4 (2023–onward). Atrazine, deethylatrazine, alachlor, prometon, and simazine were 5 pesticides detected at moderate concentrations (greater than 10 percent of the HHB but less than or equal to the HHB). The percentage of wells that had groundwater pesticide concentrations in the moderate concentration category decreased from 7 percent in decade 1 to 2 percent in decade 3. The agricultural networks had the highest percentages of wells with moderate concentrations, and these percentages decreased from 13 percent in decade 1 to 4 percent in decade 3. Moderate concentrations in the urban networks decreased between decades 1 and 2 from 4 percent to 0 percent. No moderate concentrations occurred in the urban networks in decade 3. The percentage of wells with moderate concentrations in the domestic supply networks (1 percent) was the lowest of all the network types and did not change across the three decades. Moderate atrazine or deethylatrazine concentrations occurred across all three decades in aggregated ecoregions representing similar soils, climate, and landforms in the Semiarid West, Midcontinent, and Northeastern United States. Moderate concentrations of prometon, alachlor, and simazine also occurred in the Midcontinent, Arid West, Northeast, South Atlantic Gulf, and Semiarid West regions, but the moderate concentrations did not persist across all three decades. DBCP was the only pesticide that exceeded its respective HHB, and the exceedances occurred across all four decades. In this report, the DBCP analysis was limited to one well network in the Central Valley, California. Agricultural use of DBCP was suspended in 1977. Forty-five years after being banned, DBCP concentrations were greater than the maximum contaminant level of 2 micrograms per liter (μg/L), but the number of exceedances decreased from 50 percent to 15 percent of the samples between 1993 and 2023. This assessment of decadal groundwater pesticide concentrations provides a characterization of changes in water availability because of pesticide contamination in areas where groundwater is used as a drinking-water source. The results highlight the importance of continued long-term monitoring and assessment of groundwater pesticides to identify locations and specific compounds that may pose a potential risk to human health.

continental United States↗
USGS2024

Beyond the wedge: Impact of tidal streams on salinization of groundwater in a coastal aquifer stressed by pumping and sea-level rise

Saltwater intrusion (SWI) is a well-studied phenomenon that threatens the freshwater supplies of coastal communities around the world. The development and advancement of numerical models has led to improved assessment of the risk of salinization. However, these studies often fail to include the impact of surface waters as potential sources of aquifer salinity and how they may impact SWI. Based on field-collected data, we developed a regional, variable-density groundwater model using SEAWAT for east Dover, Delaware. In this location, major users of groundwater from the surficial aquifer are the City of Dover and irrigation for agriculture. Our model includes salinized marshland and tidal streams, along with irrigation and municipal pumping wells. Model scenarios were run for 100 years and included changes in pumping rates and sea-level rise (SLR). We examined how these drivers of SWI affect the extent and location of salinization in the surficial aquifer by evaluating differences in chloride concentration near surface waters and the subsurface freshwater-saltwater interface. We found the presence of the marsh inverts the typical freshwater-saltwater wedge interface and that the edge of the interface did not migrate farther inland. Additionally, we found that tidal streams are the dominant pathways of SWI at our site with salinization from streams being exacerbated by SLR. Our results also show that spatial distribution of pumping affects both the magnitude and extent of salinization, with an increase in concentrated pumping leading to more intensive salinization than a more widely distributed increase of the same total pumping volume.

Delaware↗
USGS2024

Assessing locations susceptible to shallow landslide initiation during prolonged intense rainfall in the Lares, Utuado, and Naranjito municipalities of Puerto Rico

Hurricane Maria induced about 70 000 landslides throughout Puerto Rico, USA, including thousands each in three municipalities situated in Puerto Rico's rugged Cordillera Central range. By combining a nonlinear soil-depth model, presumed wettest-case pore pressures, and quasi-three-dimensional (3D) slope-stability analysis, we developed a landslide susceptibility map that has very good performance and continuous susceptibility zones having smooth, buffered boundaries. Our landslide susceptibility map enables assessment of potential ground-failure locations and their use as landslide sources in a companion assessment of inundation and debris-flow runout. The quasi-3D factor of safety, F 3 , showed strong inverse correlation to landslide density (high density at low F 3 ). Area under the curve (AUC) of true positive rate (TPR) versus false positive rate (FPR) indicated success of F 3 in identifying head-scarp points (AUC = 0.84) and source-area polygons (0.85 ≤ AUC ≤ 0.88). The susceptibility zones enclose specific percentages of observed landslides. Thus, zone boundaries use successive F 3 levels for increasing TPR of landslide head-scarp points, with zones bounded by F 3 at TPR = 0.75, very high; F 3 at TPR = 0.90, high; and the remainder moderate to low. The very high susceptibility zone, with 118 landslides km −2 , covered 23 % of the three municipalities. The high zone (51 landslides km −2 ) covered another 10 %.

Puerto Rice↗
USGS2025

Megafaunal community structure on ferromanganese and phosphorite hardgrounds in the Southern California Borderland

The Southern California Borderland (SCB) is a topographically complex region on the active continental margin that hosts varied hardground habitats, including ferromanganese (FeMn) crusts and phosphorites, marine minerals being considered for resource extraction. The SCB is influenced by seasonal upwelling and terrestrial inputs, and has a well-defined oxygen-minimum zone (OMZ). We analyzed megafaunal community composition, density, and diversity across 41 ROV video transects at 10 SCB hard substrate sites spanning depth (378–2765 m), temperature (1.79–7.96 °C), and oxygen (3.91–105.67 μM) gradients, with varying rock types (FeMn crusts, phosphorites, other rocks). We counted 32,426 individuals representing 146 unique taxa over a total area of 21,935 m 2 . Echinodermata contributed 48 % of the total abundance; Cnidaria 24 %; Porifera 13 %; Annelida 6 %; Arthropoda 6 %; Chordata 2 %; Mollusca, Foraminifera, and Hemichordata <1 %. Megafauna communities showed clear heterogeneity, with density, diversity, and community composition varying among transects within sites and across sites. Rock type recorded no influence on megafaunal density, but habitats that included FeMn crusts had higher diversity and distinct taxonomic composition. Location, depth, and oxygen were the most important variables explaining variance among megafaunal communities, with distinct communities formed at deeper depths and within the OMZ. This study provides baseline information about the megafauna inhabiting SCB hardgrounds, particularly those associated with minerals considered for their resource potential. It extends existing documentation of such communities to greater depths, reveals increased representation of sponges and corals below 1000 m, and highlights the variability within and among deep-sea megafaunal communities, offering context for informed policy decisions.

Southern California borderland↗
USGS2024

Earthquake relocations delineate discrete a fault network and deformation corridor throughout Southeast Alaska and Southwest Yukon

Deformation in southeastern Alaska and southwest Yukon is governed by the subduction and translation of the Pacific-Yakutat plates relative to the North American plate in the St. Elias region. Despite notable historical seismicity and major regional faults, studies of the region between the Fairweather and Denali faults are complicated by glacial coverage and the remote setting. In the last decade, significant improvements have been made to the density of regional broadband seismometer networks. We relocate more than 5,000 earthquakes between 2010 and 2021 in the region of southeastern Alaska and southwestern Yukon utilizing these improved seismic networks. With reductions in catalog uncertainty, particularly in depth, we quantify the thickness of the seismogenic layer in the crust throughout the region and locate seismicity on a shallow network of upper-crustal faults. Relocated earthquakes, combined with an updated focal-mechanism catalog, permit estimating and classifying motion of active faults. This includes mapping the Totschunda-Fairweather “Connector” fault, which plays an important role in explaining regional deformation, and identifying new faults like the Kathleen Lake fault. We draw similarities between our seismic observations and simplified conceptual models of regional tectonics, which describe a dominant transpressional regime and localized slip partitioning. Our results support a hypothesis where current deformation is taking place on a well-defined and evolved network of shallow faults in the corridor between the Totschunda-Fairweather “Connector” and Denali faults.

Alaska, Yukon↗
USGS2024

Wave propagation in layered soil deposits

Recent advances in the general theory of viscoelastic waves and rays in layered media provide a rigorous mathematical framework for site-specific, soil-response models used for earthquake resistant design. The advances provide general closed-form anelastic solutions for the classic problems of the response of a stack of soil layers to S and P waves, ray theory for reflected and refracted waves, Rayleigh- and Love-Type surface waves, and head waves. These general solutions valid for anelastic media regardless of the amount of material damping yield new insights regarding the characteristics of seismic waves and their ray paths that are not provided by conventional models. They provide corresponding numerical ground-response models and ray-tracing computation algorithms that account for changes in velocity and attenuation of anelastic waves associated with changes in inhomogeneity of the waves induced by anelastic soil and soil-rock boundaries. These anelastic effects manifest themselves as variations in amplitude response, amplitude attenuation, raypath location, and travel time as observed at the Earth’s surface. Implications of these anelastic effects for soil-response models used for earthquake resistant design are provided herein.

Conference Paper↗
USGS2025

Ages and trace element fertility of porphyry-related mineralization in the Philipsburg polymetallic district, Montana, with a comparison to Butte

The Philipsburg mining district is a Mo-Cu porphyry system with associated Cordilleran polymetallic veins. Geochronology was employed to date the porphyry (~66 Ma, U/Pb in zircon) and molybdenite mineralization from the veins (~76 Ma, Re-Os). Age results suggest that the two-mineralization events model proposed by Lund et al. (2018) for the Butte district can be applied to the Philipsburg deposit. Furthermore, common fertility indicators from zircon trace elements were analyzed with variable success to characterize the existing Mo-Cu mineralization of the Philipsburg porphyry. This raises concerns about the benefits of this method and/or the importance of sampling, which could impact exploration for similar porphyry deposits.

Montana↗
USGS2026

Geologic map of pre-Middle Jurassic basement rocks beneath the Atlantic and Gulf Coastal Plains in Florida

Much of the southeastern United States, including all of Florida, is covered by flat-lying sedimentary strata of the Atlantic and Gulf Coastal Plains which have accumulated since Middle Jurassic time. The pre-Middle Jurassic rocks that underlie these coastal plains in Florida, here collectively referred to as “basement,” are known only from a relatively small number of boreholes. This scientific investigations map presents an interpretation of the basement geology in a 1:1,000,000-scale subsurface geologic map with supporting text, data, and figures. The subsurface mapping methodology integrates petrographic, geochronological, thermochronological, geochemical, and mineralogical analyses of drill cores and cuttings in the context of regional geophysical data. The pre-Middle Jurassic rocks of Florida consist of the Gondwanan (West African) Suwannee terrane which was accreted to Laurentia during the Alleghanian orogeny and subsequently intruded by Permian granites, superposed by early Mesozoic rift basins, and partially overlain by bimodal Jurassic volcanic rocks. The younger basement components, specifically the Southwest Florida volcanic province, North Florida tholeiites, early Mesozoic rift basins, and Alleghanian granitoids, have correlative and contemporaneous units throughout the Appalachian orogen. In contrast, Florida’s older basement rocks, including Paleozoic siliciclastic strata of the Suwannee basin, North Florida volcanic series, Osceola and Gaskin intrusive complexes, and the St. Lucie Metamorphic Complex, have neither surface exposures nor unequivocal correlates. Major structures include early Mesozoic normal faults and northwest-striking transfer zones such as the Jay fault. Many of these faults define the boundaries of subbasins within the South Georgia rift system. Top-of-basement structure contours show gentle arches and embayments that are also recognized in overlying coastal plain strata.

Florida↗
USGS2025

Smectite-rich horizons in Inceptisols trigger shallow landslides in tropical granitic terranes

Puerto Rico was affected by >70,000 landslides in the wake of 2017 Hurricane Maria, and landslide prevalence was especially high in the Utuado region in the Cordillera Central. Landslide density was highest where soil parent material is granodiorite; landslide slip surfaces tended to be shallow (<60 cm), and often were mobilized rapidly and with long runout distances. This study combines field observations with soil mineralogy (bulk and clay fractions), soil geochemistry (bulk fraction), and soil strength as determined by field cone penetrometer testing (CPT) to test the hypothesis that clay-rich subsoil horizons function as slip planes when water-logged. Soil pits were excavated to depths of ∼200 cm in Ultisols on an undulating plateau and to ∼100 cm in Inceptisols on steep slopes (36-43 o ) that flank the plateau and cone penetrometer tests (CPT) were done within 2 m of the soil pit. Six pits were located adjacent to scarps from previous landslides, enabling analysis of soil profiles downward through extrapolated slip surfaces. Results from X-ray diffraction (XRD), X-ray fluorescence (XRF) and thermogravimetric analysis (TGA) indicate that soils are heterogeneous, often with subsoil horizons enriched in clay minerals and immobile elements (Al, Fe, Ti). Inceptisols on steep slopes often contain smectite-rich horizons at 30–60 cm depth that appear to function as slip surfaces; in other Inceptisols, such horizons are not present and landslide susceptibility is potentially lower. In Ultisols, soil mineralogy is dominated by kaolinite with minor halloysite, and increased kaolinite content at soil depths ≥80 cm at some sites suggests potential slip surfaces enhancing probability of landslides. The origin of clay-rich horizons appears to be (1) fractures in granodiorite that facilitate water flow and leaching, accelerating mineral dissolution during early weathering stages, and (2) smectite-rich buried soils under permeable colluvium likely deposited by a prior mass wasting event. Where clay-rich layers occur beneath more-permeable horizons, rapid infiltration then absorption of water in clay-rich subsoil horizons causes decreased shear strength and increased landslide susceptibility.

Puerto Rico↗
USGS2025

Preserving and increasing water resources—Natural infrastructure in dryland streams in Baja California Sur, Mexico

The Los Planes watershed of Baja California Sur, Mexico, and its underlying aquifer are experiencing groundwater decline owing to low average annual rainfall (28.1 centimeters per year) and rising water demand from population growth and agricultural activities. This decline in water availability can lead to desertification—a process that changes arable land to desert by degrading soil and vegetation—and can pose serious challenges to livelihoods that depend on the land. To address these issues, a ranch in the Los Planes watershed has installed many natural infrastructures in dryland streams (NIDS) in channels for soil and water conservation. In 2022, the U.S. Geological Survey (USGS) began working with regional researchers and land managers to investigate the effects of NIDS on natural biological, geochemical, and physical processes and determine the efficacy of NIDS for water augmentation in the Los Planes watershed. The USGS also worked with local academic institutions and nonprofit organizations to create public educational opportunities focused on the area’s hydrogeology. These and other collaborative efforts with the U.S. Water Partnership and Innovaciones Alumbra aim at enhancing water resources in the Baja California Sur region and promoting water security and safeguarding community well-being. Resume La cuenca de Los Planes, ubicada en Baja California Sur, México, y su acuífero subyacente, están sufriendo una disminución de las aguas subterráneas debido a la baja precipitación media anual (28.1 centímetros por año) y la alta demanda de agua por parte de una población creciente y la actividad agrícola. Esta disminución de la disponibilidad de agua puede conducir a la desertificación—un proceso que por medio de la degradación del suelo y la vegetación convierte a la tierra cultivable en desierto—representando un serio desafío para los medios de vida de las personas. Para abordar estos problemas, un rancho en la cuenca de Los Planes ha instalado numerosas obras de Infraestructura Natural en Arroyos de Tierras Áridas (INATS) para conservación del suelo y del agua. En 2022, el Servicio Geológico de los Estados Unidos (USGS, por sus siglas en inglés) comenzó a trabajar con investigadores regionales y gestores de tierras para estudiar los efectos de INATS en los procesos biológicos, geoquímicos y físicos, y determinar su eficacia en el aumento de los recursos hídricos en la cuenca de Los Planes. El USGS se ha asociado con instituciones académicas y organizaciones locales sin fines de lucro para crear oportunidades educativas públicas centradas en la hidrogeología de la zona. Estos y otros esfuerzos colaborativos con la Asociación del Agua de Estados Unidos (U.S. Water Partnership) e Innovaciones Alumbra, tienen como objetivo mejorar el uso de los recursos hídricos en la región de Baja California Sur, promover la seguridad hídrica y proteger el bienestar de la comunidad.

Baja California Sur↗
USGS2025

Properties of solid bitumen formed during hydrous, anhydrous, and brine pyrolysis of oil shale: Implications for solid bitumen reflectance in source-rock reservoirs

Solid bitumen reflectance (BR o in %) is widely used as a thermal maturity proxy in source-rock reservoirs, yet solid bitumen texture and physical attributes may be affected by varying environmental constraints during its formation, e.g., water saturation, mineral catalysis, or salinity. Herein we investigated the development of solid bitumen properties during artificial maturation using three diverse (lacustrine to marine) oil shale samples containing abundant amorphous H-rich sedimentary organic matter (bituminite). The oil shales were treated via pyrolysis (320 °C, 72 h) using hydrous, anhydrous, and brine conditions, causing the development of a newly formed solid bitumen in the experiment residues from the thermal conversion of bituminite. The properties of the newly formed solid bitumen then were evaluated via geochemical screening tests, optical and electron microscopy, and infrared spectroscopy. Experimental residues also were treated via solvent extraction, allowing characterization of the effects of extraction on solid bitumen. Results showed that bituminite with higher resin and asphaltene components evolved to a solid bitumen with higher reflectance (as a percentage of the original value) when exposed to the same heat treatment, relative to bituminite with higher saturate and aromatic components. Aromatization of solid bitumen also was generally more pronounced in the presence of deionized water relative to anhydrous conditions, supporting prior observations. These results suggest the compositions of primary sedimentary organic matter, and the local concentration of water, affect the development of solid bitumen during thermal advance, potentially explaining the origin of multiple solid bitumen populations with varying reflectance in source-rock reservoir samples or in a single microscope field. Experiments using brine were inconclusive regarding enhanced/decreased aromatization, which could be attributed to the salinities of the brines used in the tests. Extraction of residues caused a consistent increase in BR o values, suggesting that migrating or expelled oils could cause an increase in BR o via natural solvation and absent an increase in temperature. This work provides insights into the development and evolution of BR o in source-rock reservoirs as a function of the composition of the original bituminite and changing environmental conditions, with potentially broad application for petroleum prospecting and resource estimation.

Colorado↗
USGS2026

Water use permits as of July 2024 and reported water use near the North Unit of Theodore Roosevelt National Park, North Dakota, 1980–2023

Starting in the early 2000s, increasing oil and gas development in western North Dakota created a need for additional water resources from surface-water and groundwater sources near the North Unit of Theodore Roosevelt National Park. To summarize the use of water in that area, the U.S. Geological Survey, in cooperation with the National Park Service, developed a map of surface-water and groundwater resources, aquifers, and water-use diversions, and plotted water-use trends from 1980 to 2023. Reported water used from permits in the map area has more than doubled since 2020, increasing from about 750 acre-feet in 2020 to about 2,300 acre-feet in 2022 and 2,000 acre-feet in 2023. Surface water provided the primary source of reported water used for the study period with an average of about 410 acre-feet per year from 1980 through 2017 and about 1,330 acre-feet per year from 2018 through 2023. After 2011, groundwater sourced from the Little Missouri River, Tobacco Garden Creek, Fox Hills, Fort Union, and Dakota aquifers became a larger portion of total annual reported water use from permits in the map area. From 1980 through 2015, water use for irrigation averaged 86 percent of the total annual reported surface-water and groundwater use in the map area. Starting in 2011, however, industrial uses became a proportionally larger total use of water, and in 2015, became the highest reported volume of water use in the map area. From 2011 to 2023, industrial use designated for water depots increased from 50 acre-feet to about 1,370 acre-feet, accounting for about 70 percent of total reported water use in the map area in 2023.

North Dakota↗
USGS2025

Quality of groundwater used for domestic supply in the Gilroy-Hollister basin and surrounding areas, California, 2022

More than 2 million Californians rely on groundwater from domestic wells for drinking-water supply. This report summarizes a 2022 California Groundwater Ambient Monitoring and Assessment Priority Basin Project (GAMA-PBP) water-quality survey of 33 domestic and small-system drinking-water supply wells in the Gilroy-Hollister Valley groundwater basin and the surrounding areas, where more than 20,000 residents are estimated to utilize privately owned domestic wells. The study area includes the Llagas subbasin in the north, the North San Benito subbasin in the south, and the surrounding uplands. The study was focused on groundwater resources used for domestic drinking-water supply, which are mostly drawn from shallower parts of aquifer systems rather than those of groundwater resources used for public drinking-water supply in the same area. This assessment characterized the quality of ambient groundwater in the aquifer before filtration or treatment, rather than the quality of drinking water delivered to the tap. To provide context, the measured concentrations of constituents in groundwater were compared to Federal and California State regulatory and non-regulatory benchmarks for drinking-water quality. A grid-based method was used to estimate the areal proportions of groundwater resources used for domestic drinking wells that have water-quality constituents present at high concentrations (above the benchmark), moderate concentrations (between one-half of the benchmark and the benchmark for inorganic constituents, or between one-tenth of the benchmark and the benchmark for organic constituents), and low concentrations (less than one-half or one-tenth the benchmark for inorganic and organic constituents, respectively). This method provides statistically representative results at the study-area scale and permits comparisons to other GAMA-PBP study areas. In the study area, inorganic constituents in groundwater were greater than regulatory benchmarks (U.S. Environmental Protection Agency [EPA] or State of California maximum contaminant levels [MCLs]) for public drinking-water quality in 24 percent of domestic groundwater resources. The inorganic constituents present at concentrations greater than MCLs for drinking water were nitrate (as nitrogen), barium, chromium, and selenium. Total dissolved solids (TDS) or manganese were present at concentrations greater than the secondary maximum contaminant levels (SMCLs) that the State of California uses as aesthetic-based benchmarks in 48 percent of domestic groundwater resources. No volatile organic compounds or pesticide constituents were present at concentrations greater than regulatory benchmarks. Total coliform bacteria and enterococci were detected in 4 percent of domestic groundwater resources. Per- and polyfluoroalkyl substances (PFAS) were detected in 19 percent of domestic groundwater resources, and 10 percent had concentrations greater than recently enacted (April 2024) EPA MCLs. Physical and chemical factors from natural and anthropogenic sources that could affect the groundwater quality were evaluated using results from statistical testing of associations between constituent concentrations and potential explanatory variables. In this study, relevant physical factors include well construction characteristics, groundwater age, site proximity to groundwater recharge or discharge zones, and potential sources of contamination. Relevant chemical factors include the initial chemistry of the recharge water, the mineralogy of the aquifer sediments, and the subsequent shifts in chemistry as biologic and geologic reactions alter groundwater in the subsurface. Nitrate concentrations were correlated to agricultural land use, distance from the boundary of the Gilroy-Hollister Valley groundwater basin, and the proportion of modern (post-1950s) water captured by the well. Denitrification under anoxic redox conditions can mitigate some nitrate derived from fertilizer application. Total dissolved solids primarily were derived from water-rock interactions with soils and aquifer materials in the study area, but there were high concentrations where agricultural practices contributed additional TDS. Mineralogy of aquifer sediments and rocks also affect barium, selenium, boron, and chromium concentrations in the Gilroy-Hollister Valley groundwater basin. PFAS were positively correlated with urban land use and the proportion of modern water captured by the well.

California↗
USGS2025

Synergy between geology and geophysics in graphite mineral resource assessment

Graphite is designated as a critical mineral by the U.S. Government due to its essential role in modern technology and its vulnerability to supply chain disruption. To evaluate domestic graphite resources, the U.S. Geological Survey (USGS) conducted two airborne electromagnetic (AEM) surveys as part of the Earth Mapping Resources Initiative (Earth MRI) over prospective areas in the southern Appalachians of Alabama and the Seward Peninsula of Alaska. These surveys aimed to refine areas of interest by revealing subsurface electrical resistivity patterns indicative of graphite-bearing rocks. The results of the AEM surveys were integrated with existing geological knowledge and supplemented by field observations to assess the likelihood of undiscovered resources in these regions. This multidisciplinary approach combined geophysical techniques with traditional geological methods, enhancing the understanding of graphite potential in areas that may have been previously overlooked. The findings from this initiative are expected to contribute significantly to the ongoing efforts to secure a reliable domestic supply of graphite, thereby reducing import reliance and supporting national interests in mineral resource management.

Conference Paper↗
USGS2025

Evaluation of solid bitumen created from marine oil shale bituminite under hydrous and anhydrous pyrolysis conditions

To test the influence of environmental conditions on aromaticity of solid bitumen generated during petroleum generation, four organic-rich (26–36 wt% total organic carbon) oil shale samples collected from the Neoproterozoic–Lower Cambrian restricted marine Salt Range Formation in the upper Indus Basin, Pakistan, were pyrolyzed under hydrous and anhydrous conditions. Experiments used closed system batch reactors at subcritical water temperatures between 300 and 370°C for 72 h. Thermal conversion of bituminite in the Salt Range oil shales created a newly formed solid bitumen, similar to previous observations from experiments on the Eocene lacustrine Green River Formation Mahogany zone oil shale. Newly formed solid bitumen in the Salt Range Formation oil shales generally has higher reflectance (R o ) in hydrous residues compared to anhydrous experiments subjected to the same time-temperature conditions, also similar to prior observations. This finding supports the hypothesis that radical disproportionation is favored in the presence of hydrogen contributed by water, promoting aromatization in the solid bitumen residue with concomitant increased expulsion of saturated hydrocarbons. Indigenous solid bitumen (and vitrinite in a comparison sample) also shows higher reflectance values in hydrous versus anhydrous residues, indicating that additional aromatization in the presence of exogenous hydrogen occurs both in newly formed organic matter and in organic matter that is present throughout the experiment. Despite similarities in their bulk rock geochemical screening parameters, R o evolution shows different trajectories amongst the four Salt Range oil shales, suggesting as-yet undetermined differences in kinetic properties which are probably related to differences in a priori chemical composition. These results have implications for the use of solid bitumen reflectance (BR o ) as a thermal proxy, suggesting BR o values and appearance could vary as a function of the concentration of water. Variation in water concentration may be present at the reservoir or formation scale, but may also be present at a much finer scale in tight oil shales where permeability is several orders of magnitude lower than conventional reservoirs. Therefore, local variations in the presence of water potentially could explain substantial variation in BR o values and appearance in closely spaced source rock samples and even within an individual microscope field.

Journal of Analytical and Applied Pyrolysis↗
USGS2025

Reaction kinetics and accelerant effects of sulfides in early mature hydrocarbon generation using hydrous pyrolysis

Hydrocarbon generation in organic-rich sediments is influenced by the molecular organic composition and relative abundance of associated minerals. Certain mineral-derived elements act as catalysts and reaction intermediaries, facilitating early-stage hydrocarbon formation in potential source rocks. This study investigated the role of sulfur contributed from pyrite as an accelerant in thermal reaction, focusing on its effects on early maturation and consequent hydrocarbon generation from gilsonite (low-sulfur solid petroleum). Hydrous pyrolysis (HP) experiments were conducted on mixtures of gilsonite and pyrite in varying ratios (1:0.1, 1:0.5, 1:1, 1:2, and 1:10 w/w gilsonite:pyrite) at 320, 350, and 370 °C for 72 h. Untreated and thermally altered residues were analyzed using solid bitumen reflectance (BR o , %), total organic carbon (TOC) content, programmed temperature pyrolysis, scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), and X-ray diffraction (XRD) to evaluate the potential accelerant role of pyritic sulfur in hydrocarbon formation. The results show HP residues at 320 and 350 °C with greater pyrite concentrations had higher BR o , while reflectance values were similar in the 370 °C residues, regardless of pyrite concentration, suggesting enhanced reaction at lower thermal conditions. Increasing pyrite content systematically decreased hydrogen index (HI) values while increasing the transformation ratio (TR) and production index (PI), indicating enhanced conversion of organic matter to hydrocarbons with increasing pyrite concentrations. Gas yields increased with pyrite addition, particularly at 350 °C, confirming secondary cracking effects. However, gas production stabilized or declined at higher pyrite loadings (1:10), suggesting alternative reaction pathways such as coke formation. Our data indicate the presence of pyrite lowers the activation energy for thermal cracking, shifting peak experimental hydrocarbon generation temperatures downward by 20–30 °C, with the most pronounced accelerant effects observed at moderate pyrite concentrations (1:0.5 and 1:1). The thermodynamic framework reveals that pyrite stability is influenced by experimental conditions, with pyrrhotite formation favored in the presence of gilsonite due to reduced oxygen fugacity. Pyrite transformation to pyrrhotite, as observed through XRD, SEM-EDS, and predicted by thermodynamic data, further supports the accelerant role of S, as pyrrhotite exhibits a higher hydrogen transfer potential, promoting early oil generation. These findings highlight the importance of pyrite in modulating hydrocarbon generation pathways in organic-rich systems.

Journal of Analytical and Applied Pyrolysis↗