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At least 523 records · Page 29Linked to original sources

Editor’s message: Groundwater modeling fantasies - Part 2, down to earth

Simplicity is the final achievement. After one has played a vast quantity of notes and more notes, it is simplicity that emerges as the crowning reward of art. (Frédéric Chopin, a musician and composer, quoted in If Not God, Then What? by Fost 2007 ) Despite the dubious developments discussed in part 1 of this Editor’s Message (Voss 2011 ), groundwater modeling really does represent the state of the art in hydrogeology, and groundwater modeling is in fact one of our most powerful tools for enhancing hydrogeologic understanding and for informing management of subsurface resources, at least when in the hands of competent hydrologists.

Hydrogeology Journal↗

Non-spore forming eubacteria isolated at an altitude of 20,000 m in Earth's atmosphere: extended incubation periods needed for culture-based assays

On 13 August 2004, an atmospheric sample was collected at an altitude of 20,000 m along a west to east transect over the continental United States by NASA’s Stratospheric and Cosmic Dust Program. This sample was then shipped to the US Geological Survey’s Global Desert Dust program for microbiological analyses. This sample, which was plated on a low nutrient agar to determine if cultivable microorganisms were present, produced 590 small yellow to off-white colonies after approximately 7 weeks of incubation at room-temperature. Of 50 colonies selected for identification using 16S rRNA sequencing, 41 belonged to the family Micrococcaceae , seven to the family Microbacteriaceae , one to the genus Staphylococcus , and one to the genus Brevibacterium . All of the isolates identified were non-spore-forming pigmented bacteria, and their presence in this sample illustrate that it is not unusual to recover viable microbes at extreme altitudes. Additionally, the extended period required to initiate growth demonstrates the need for lengthy incubation periods when analyzing high-altitude samples for cultivable microorganisms.

Aerobiologia↗

Biocrusts: The living skin of the Earth

Biological soil crusts (biocrusts) form a “living skin” at the soil surface in many low productivity ecosystems around the world including water- and cold-limited environments, and early successional seres (Belnap et al. 2003). They may be composed of any configuration of soil surface-dwelling cyanobacteria, eukaryotic algae, lichens, mosses or liverworts, and support assemblages of decomposers and a faunal food web (Belnap et al. 2003). These soil surface communities have global relevance, as it has been recently estimated that they cover about 12% of the terrestrial surface currently (Rodriguez-Caballero et al. 2018). Biocrust communities are perhaps an ideal subject for the journal Plant and Soil, because they are simultaneously plant-like, due to their dominance by autotrophs, yet biocrusts are also clearly a physical feature of the soil given that component organisms are enmeshed in, adherent to, or otherwise in direct contact with the soil surface. The activity of the organisms is what engineers the well-aggregated thin layer at the soil surface that we recognize as a biocrust (Belnap et al. 2003). The contributions of biocrusts to ecosystem function has fueled much research interest, initially in the observation of biocrusts’ soil aggregating and erosion-resisting nature, and later as a multifunctional, globally-relevant ecosystem element instrumental in: 1. building or otherwise altering soil nutrient stocks through N-fixation (Elbert et al. 2012), dust trapping (Reynolds et al. 2001) and nutrient cycling (Strauss et al. 2012), 2. influencing hydrological properties of soil such as the water balance (Chamizo et al. 2016), and 3. The thermal energy balance of the ecosystem (Coradeau et al. 2016, Rutherford et al. 2017).

Plant and Soil↗

An experimental study of the partitioning of a rare earth element (Gd) in the system diopside—Aqueous vapour

The partitioning of Gd in the experimental system diopside-aqueous vapor as a function of temperature, pressure, composition of the phases, time, grain size, solid-liquid ratio and Gd concentration has been investigated. A radioactive tracer measurement was used to determine Gd concentration in the separated phases. Diposides were reacted with aqueous vapor containing tracer Gd and reversibility was tested by reacting Gd-doped diopsides with pure aqueous vapor. Equilibration of Gd between the bulk of the diopside and the liquid was found to be limited by the slow rate of Gd diffusion in diopside, maximum value of D = 2 × 10 −15 cm 2 sec −1 at 800°C and 1 kb. Depending on whether the diopside was previously synthesized or synthesized from an oxide mix during the experiment, Gd concentrations were zoned in the crystal such that higher concentrations existed at the edges or center, respectively. Equilibrium is difficult to achieve in these experiments, but at the optimum experimental conditions for equilibration, the Gd diopside-aqueous vapor distribution coefficient is 20 ± 6 (800°C, 1 kb) in approximate agreement with previous results of 55 ± 23. Changing the composition of the aqueous vapor indicated that possible mechanisms for Gd substitution included coupling of Gd 3+ with H + or Na + replacing 2Ca 2+ , or substitution of 2Gd 3+ for 3Ca 2+ with formation of a cation vacancy.

Geochimica et Cosmochimica Acta↗

Reference samples for the earth sciences

A revised list of reference samples of interest to geoscientists has been extended to include samples for the agronomist, the archaeologist and the environmentalist. In addition to the source from which standard samples may be obtained, references or pertinent notes for some samples are included. The number of rock reference samples is now almost adequate, and the variety of ore samples will soon be sufficient. There are very few samples for microprobe work. Oil shales will become more important because of the outlook for world petroleum resources. The dryland equivalent of a submarine basalt might be useful in studies of sea-floor spreading and of the geochemistry of basalts. The Na- and K-feldspars of BCS (British Chemical Standards—Bureau of Analysed Samples), NBS (National Bureau of Standards), and ANRT (Association Kationale de la Recherche Technique) could serve as trace-element standards if such data were available. Similarly, the present NBS flint and plastic clays, as well as their predecessors, might be useful for archaeological pottery studies. The International Decade for Ocean Exploration may stimulate the preparation of ocean-water standards for trace elements or pollutants and a standard for manganese nodules.

Geochimica et Cosmochimica Acta↗

Erosion by catastrophic floods on Mars and Earth

The large Martian channels, especially Kasei, Ares, Tiu, Simud, and Mangala Valles, show morphologic features strikingly similar to those of the Channeled Scabland of eastern Washington, produced by the catastrophic breakout floods of Pleistocene Lake Missoula. Features in the overall pattern include the great size, regional anastomosis, and low sinuosity of the channels. Erosional features are streamlined hills, longitudinal grooves, inner channel cataracts, scour upstream of flow obstacles, and perhaps marginal cataracts and butte and basin topography. Depositional features are bar complexes in expanding reaches and perhaps pendant bars and alcove bars. Scabland erosion takes place in exceedingly deep, swift floodwater acting on closely jointed bedrock as a hydrodynamic consequence of secondary flow phenomena, including various forms of macroturbulent votices and flow separations. If the analogy to the Channeled Scabland is correct, floods involving water discharges of millions of cubic meters per second and peak flow velocities of tens of meters per second, but perhaps lasting no more than a few days, have occurred on Mars.

Icarus↗

Ring distributions in alkali- and alkaline-earth aluminosilicate framework glasses- A raman spectroscopic study

Raman spectra of crystalline polymorphs of a number of tectosilicate minerals having various sizes of smallest rings of TO 4 tetrahedra (T = Si, Al) have been investigated to identify the bands that are sensitive indicators of the smallest rings in the network. The information obtained from the Raman spectra of tectosilicate minerals (e.g., SiO 2 polymorphs, NaAlSi 3 O 8 (Ab), NaAlSiO 4 (Ne), KAlSi 3 O 8 (Or), and KAlSi 2 O 6 (Lc)) is used to interpret the Raman spectra of the isochemical glasses. It is shown that the frequency of the dominant ν s (TOT) band in the spectra of both crystals and glasses is related to the dominant size of TO 4 rings in the structure. In agreement with previous X-ray RDF work, it is found that in the glasses of Ab and Jd (NaAlSi 2 O 6 ) compositions, six-membered rings of TO 4 tetrahedra predominate. The Raman spectrum of Or glass, however, indicates that clusters of intermixed four- and six-membered rings of TO 4 tetrahedra, similar to those existing in crystalline leucite, are also present in the glass. Raman evidence indicates that four-membered rings of TO 4 tetrahedra predominate in the glass of An composition. Similarly, the higher frequency of the ν s (TOT) band in the spectrum of Ne glass as compared with the frequency the ν s (TOT) band in the spectra of crystalline cargenieite and nephelite indicates either an admixture of the four- and six-membered rings or the puckering of six-membered rings in the glass structure.

Journal of Non-Crystalline Solids↗

Ice ages and the thermal equilibrium of the earth, II

The energy required to sustain midlatitude continental glaciations comes from solar radiation absorbed by the oceans. It is made available through changes in relative amounts of energy lost from the sea surface as net outgoing infrared radiation, sensible heat loss, and latent heat loss. Ice sheets form in response to the initial occurrence of a large perennial snowfield in the subarctic. When such a snowfield forms, it undergoes a drastic reduction in absorbed solar energy because of its high albedo. When the absorbed solar energy cannot supply local infrared radiation losses, the snowfield cools, thus increasing the energy gradient between itself and external, warmer areas that can act as energy sources. Cooling of the snowfield progresses until the energy gradients between the snowfield and external heat sources are sufficient to bring in enough (latent plus sensible) energy to balance the energy budget over the snowfield. Much of the energy is imported as latent heat. The snow that falls and nourishes the ice sheet is a by-product of the process used to satisfy the energy balance requirements of the snowfield. The oceans are the primary energy source for the ice sheet because only the ocean can supply large amounts of latent heat. At first, some of the energy extracted by the ice sheet from the ocean is stored heat, so the ocean cools. As it cools, less energy is lost as net outgoing infrared radiation, and the energy thus saved is then available to augment evaporation. The ratio between sensible and latent heat lost by the ocean is the Bowen ratio; it depends in part on the sea surface temperature. As the sea surface temperature falls during a glaciation, the Bowen ratio increases, until most of the available energy leaves the oceans as sensible, rather than latent heat. The ice sheet starves, and an interglacial period begins. The oscillations between stadial and interstadial intervals within a glaciation are caused by the effects of varying amounts of glacial meltwater entering the oceans as a surface layer that acts to reduce the amount of energy available for glacial nourishment. This causes the ice sheet to melt back, which continues the supply of meltwater until the ice sheet diminishes to a size consistent with the reduced rate of nourishment. The meltwater supply then decreases, the rate of nourishment increases, and a new stadial begins.

Quaternary Research↗

A simple model of a phreatic surface through an earth dam

A simple numerical model for estimating a phreatic surface in an earthen dam is presented. The numerical approach is based upon the Complex Variable Boundary Element Method (CVBEM). By expanding the CVBEM approximation geometric functions into a first order Taylor series, the unknown phreatic surface location geometrics can be approximated without iteration by solving a single matrix system. The developed technique provides for the numerical solution of the inverse problem of locating the phreatic surface coordinates. A comparison of results produced from this simple approach to results produced from a finite element analog and an iterative CVBEM analog for an example problem is presented.

Advances in Water Resources↗

40Ar/39Ar systematics and argon diffusion in amber: Implications for ancient earth atmospheres

Argon isotope data indicate retained argon in bulk amber (matrix gas) is radiogenic [ 40 Ar/ 39 Ar ≃32o] than the much more abundant surface absorbed argon [ 40 Ar/ 39 Ar ≃295.5]. Neutron-induced 39 Ar is retained in amber during heating experiments to 150° -250°C, with no evidence of recoiled 39 Ar found after irradiation. A maximum permissible volume diffusion coefficient of argon in amber (at ambient temperature) D≤1.5 x 10 −17 cm 2 S −1 is calculated from 39 Ar retention. 40 Ar/ 39 Ar age calculations indicate Dominican Republic amber is ≃ 45 Ma and North Dakota amber is ≃ 89 Ma, both at least reasonable ages for the amber based upon stratigraphic and paleontological constraints and upon the small amount of radiogenic 40 Ar. To date, over 300 gas analyses of ambers and resins of Cretaceous to Recent age that are geographically distributed among fifteen noted world locations identify mixtures of gases in different sites within amber (Berner and Landis, 1988). The presence of multiple mixing trends between compositionally distinct end-members gases within the same sample and evidence for retained radiogenic argon within the amber argue persuasivley against rapid exchange by diffusion of amber-contained gases with moder air. Only gas in primary bubbles entrapped between successive flows of tree resin has been interpreted as original “ancient air”, which is an O 2 -rich end-member gas with air-like N 2 /Ar ratios. Gas analyses of these primary bubbles indicate atmospheric O 2 levels in the Late Cretaceous of ≃ 35%, and that atmospheric O 2 dropped by early Tertiary time to near a present atmospheric level of 21% O 2 . A very low argon diffusion coefficient in amber persuasively argues for a gas in primary bubbles trapped in amber being ancient air (possibly modified only by O 2 reaction with amber).

North Dakota↗

Wildfire and landscape change

Wildfire is a worldwide phenomenon that is expected to increase in extent and severity in the future, due to fuel accumulations, shifting land management practices, and climate change. It immediately affects the landscape by removing vegetation, depositing ash, influencing water-repellent soil formation, and physically weathering boulders and bedrock. These changes typically lead to increased erosion through sheetwash, rilling, dry ravel, and increased mass movement in the form of floods, debris flow, rockfall, and landslides. These process changes bring about landform changes as hillslopes are lowered and stream channels aggrade or incise at increased rates. Furthermore, development of alluvial fans, debris fans, and talus cones are enhanced. The window of disturbance to the landscape caused by wildfire is typically on the order of 3–4 years, with some effects persisting up to 30 years.

Book chapter↗

On the formation and structure of rare-earth element complexes in aqueous solutions under hydrothermal conditions with new data on gadolinium aqua and chloro complexes

Synchrotron X-ray spectroscopy experiments were made on the Gd(III) aqua and chloro complexes in low pH aqueous solutions at temperatures ranging from 25 to 500????C and at pressures up to 480??MPa using a hydrothermal diamond anvil cell. Analysis of fluorescence Gd L3-edge X-ray absorption fine structure (XAFS) spectra measured from a 0.006m Gd/0.16m HNO3 aqueous solution at temperatures up to 500????C and at pressures up to 260??MPa shows that the Gd-O distance of the Gd3+ aqua ion decreases steadily at a rate of ??? 0.007??A??/100????C whereas the number of coordinated H2O molecules decreases from 9.0 ?? 0.5 to 7.0 ?? 0.4. The loss of water molecules in the Gd3+ aqua ion inner hydration shell over this temperature range (a 22% reduction) is smaller than exhibited by the Yb3+ aqua ion (42% reduction) indicating that the former is significantly more stable than the later. We conjecture that the anomalous enrichment of Gd reported from measurement of REE concentrations in ocean waters may be attributed to the enhanced stability of the Gd3+ aqua ion relative to other REEs. Gd L3-edge XAFS measurements of 0.006m and 0.1m GdCl3 aqueous solutions at temperatures up to 500????C and pressures up to 480??MPa reveal that the onset of significant Gd3+-Cl- association occurs around 300????C. Partially-hydrated stepwise inner-sphere complexes most likely of the type Gd(H2O)??-nCln+3-n occur in the chloride solutions at higher temperatures, where ?? ??? 8 at 300????C decreasing slightly to an intermediate value between 7 and 8 upon approaching 500????C. This is the first direct evidence for the occurrence of partially-hydrated REE Gd (this study) and Yb [Mayanovic, R.A., Jayanetti, S., Anderson, A.J., Bassett, W.A., Chou, I-M., 2002a. The structure of Yb3+ aquo ion and chloro complexes in aqueous solutions at up to 500 ??C and 270 MPa. J. Phys. Chem. A 106, 6591-6599.] chloro complexes in hydrothermal solutions. The number of chlorides (n) of the partially-hydrated Gd(III) chloro complexes increases steadily with temperature from 0.4 ?? 0.2 to 1.7 ?? 0.3 in the 0.006m chloride solution and from 0.9 ?? 0.7 to 1.8 ?? 0.7 in the 0.1m GdCl3 aqueous solution in the 300-500????C range. Conversely, the number of H2O ligands of Gd(H2O)??-nCln+3-n complexes decreases steadily from 8.9 ?? 0.4 to 5.8 ?? 0.7 in the 0.006m GdCl3 aqueous solution and from 9.0 ?? 0.5 to 5.3 ?? 1.0 in the 0.1m GdCl3 aqueous solution at temperatures from 25 to 500????C. Analysis of our results shows that the chloride ions partially displace the inner-shell water molecules during Gd(III) complex formation under hydrothermal conditions. The Gd-OH2 bond of the partially-hydrated Gd(III) chloro complexes exhibits slightly smaller rates of length contraction (??? 0.005??A??/100????C) for both solutions. The structural aspects of chloride speciation of Gd(III) as measured from this study and of Yb(III) as measured from our previous experiments are consistent with the solubility of these and other REE in deep-sea hydrothermal fluids. ?? 2006 Elsevier B.V. All rights reserved.

Chemical Geology↗

When the earth doesn’t stop shaking: How experiences over time influenced information needs, communication, and interpretation of aftershock information during the Canterbury Earthquake Sequence, New Zealand

The Canterbury Earthquake Sequence (CES) began with the Darfield earthquake on 4 September 2010. Continual large and small aftershocks since that time have meant communities have cycled through repeated periods of impact, response and recovery. Scientific communication about aftershocks during such a prolonged sequence has faced distinct challenges. We conducted research to better understand aftershock information needs for agencies and the public, and how people interpreted and responded to such information. We found that a wide range of information was needed from basic facts about aftershocks through to more technical information, and in different formats (e.g. maps, tables, graphs, text, analogies). Information needs also evolved throughout the sequence, and differed depending on people’s roles and experiences, and the phase of impact, response and recovery communities were in. Interpretation of aftershock information was influenced by a variety of factors including how understandable and relevant the information was, whether people had prior knowledge or experience of aftershocks, whether the information was personalised or contextualised, emotions and feelings, credibility and trust, and external influences. Given that such a diversity of evolving information is required, it is imperative that geoscientists strategize how to provide such information before a significant earthquake occurs.

Natural Hazards↗

Elastic stress transmission and transformation (ESTT) by confined liquid: A new mechanics for fracture in elastic lithosphere of the earth

We report on a new mechanical principle, which suggests that a confined liquid in the elastic lithosphere has the potential to transmit a maximum applied compressive stress. This stress can be transmitted to the internal contacts between rock and liquid and would then be transformed into a normal compressive stress with tangential tensile stress components. During this process, both effective compressive normal stress and tensile tangential stresses arise along the liquid–rock contact. The minimum effective tensile tangential stress causes the surrounding rock to rupture. Liquid-driven fracture initiates at the point along the rock–liquid boundary where the maximum compressive stress is applied and propagates along a plane that is perpendicular to the minimum effective tensile tangential stress and also is perpendicular to the minimum principal stress. Liquid-driven fractures and dikes propagate along the axes of cylindrical zones that are perpendicular to the minimum compressive principal stress in rocks in non-tectonic regions. The minimum depth for liquid-driven fracture, which is induced by a spherical confined liquid and an isolated magma chamber in the elastic lithosphere, ranges from 2 to 6 km, whereas dikes with hemi-cylinder-shaped ends propagate upwards closer to the surface under gravity. Transmission of pumping pressure, i.e. the pressure differences on the underside of a dike that is connected with a chamber, from the source magma chamber to intermediate and shallow chambers increases liquid pressure and also the effective tensile tangential stress and therefore leads to new fractures and dike formation and to upwards transport of magmas that have stagnated in the intermediate chamber. Tectonic stress alters local stress fields in the surrounding country rocks and therefore synchronously varies the local effective tensile tangential stress and the nature and geometry of the liquid-driven fractures.

Tectonophysics↗

Comparison of flood lavas on Earth and Mars

Flood lavas, by definition, cover vast areas in great sheets of lava, without the construction of major edifices (e.g., Geikie, 1880; Washington, 1922; Tyrrell, 1937; Self et al ., 1997). The flat terrain that flood lavas produce has led to the term “plateau volcanism” to be used as a synonym for flood volcanism. In addition, the classic erosion pattern of flood lavas leaves a series of topographic steps. Thus many flood basalt provinces are known as “traps” from the Scandinavian word for steps. Plateau volcanism transitions to “plains” volcanism when low shields become common (Greeley and King, 1977). It is not surprising that these large-volume eruptions are usually composed of the most common of volcanic rocks: basalt. Thus, the term “flood basalt” is often used interchangeably with “flood volcanism.” However, there can be interesting and significant compositional variability within flood “basalt” provinces. The most general term to describe all large-volume volcanism is “Large Igneous Province” (LIP) (e.g., Coffin and Eldholm, 1994). LIPs represent a major geologic event with significant repercussions on the interior of a planetary body. The extraction of such large volumes of magma can alter the thermal state of the mantle, indicate major changes in the convection patterns within the mantle, and lead to geochemical evolution of the mantle on a regional scale (e.g., Coffin and Eldholm, 1994 and references therein). Flood lavas also alter the face of a planet for geologically significant time.

Book chapter↗