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At least 523 records · Page 29Linked to original sources

Geotechnical aspects in the epicentral region of the 2011, M w 5.8 Mineral, Virginia earthquake

A reconnaissance team documented the geotechnical and geological aspects in the epicentral region of the M w (moment magnitude) 5.8 Mineral, Virginia (USA), earthquake of 23 August 2011. Tectonically and seismically induced ground deformations, evidence of liquefaction, rock slides, river bank slumps, ground subsidence, performance of earthen dams, damage to public infrastructure and lifelines, and other effects of the earthquake were documented. This moderate earthquake provided the rare opportunity to collect data to help assess current geoengineering practices in the region, as well as to assess seismic performance of the aging infrastructure in the region. Ground failures included two marginal liquefaction sites, a river bank slump, four minor rockfalls, and a ~4-m-wide, ~12-m-long, ~0.3-m-deep subsidence on a residential property. Damage to lifelines included subsidence of the approaches for a bridge and a water main break to a heavily corroded, 5-cm-diameter valve in Mineral, Virginia. Observed damage to dams, landfills, and public-use properties included a small, shallow slide in the temporary (“working”) clay cap of the county landfill, damage to two earthen dams (one in the epicentral region and one further away near Bedford, Virginia), and substantial structural damage to two public school buildings.

Virginia↗

Genetic interpretations of elemental and chemical differences in a soil chronosequence, California

Soils developed on fluvial terraces in central California have similar parent materials, climatic settings, vegetation cover and slopes but range in age from 40,000 to 3,000,000 years. The soils have chemical compositions that change systematically with increasing age. Such chemical differentiation is most likely the result of long-term weathering and mineralogical transformations that occurred since deposition of terrace fills and stabilization of the geomorphic surfaces. The changes in composition with time closely mimic other studies on mineral weathering, in which alkali and alkali-earth elements are lost more rapidly than transitional elements. The relative rates of element loss were determined by changes in element ratios over time. Net losses and gains of elements in different size fractions were monitored by their concentrations relative to Zr, the most stable constituent. Both sand and finer size fractions have lost considerable amounts of Ca, Mg, Na and K. Aluminum appears to have been lost from the sand fraction and gained in the fine fraction over a 3-million-year-time-span. Although there is no evidence for losses of Fe and Ti from sands, there is a net influx of Fe and Ti into finer fractions, probably gained from undetectable yet significant weathering of sand grains. Etching of sand grains, clay mineralogy, and microprobe analyses also indicate that the soils have undergone these chemical transformations during their formation. Mineralogical analyses also mimic other studies on mineral weathering, in which the pyroxenes weather more rapidly than hornblende, which weathers more rapidly than sphene or zircon.

California↗

High-resolution seismic-reflection image of the Chesapeake Bay impact structure, NASA Langley Research Center, Hampton, Virginia

A 1-kilometer-long (0.62-mile-long) seismic reflection and refraction profile collected at the National Aeronautics and Space Administration (NASA) Langley Research Center, Hampton, Va., provides a detailed image of part of the annular trough of the buried, 35-million-year-old Chesapeake Bay impact structure. This profile passes within 5 meters (m; 16.4 feet (ft)) of a 635.1-m-deep (2,083.8-ft-deep), continuously cored and geophysically logged test hole at the Langley Center (the USGS-NASA Langley corehole). High-resolution seismic reflection images (having a common-depth-point spacing of 2.5 m (8.2 ft)) of the upper 1,000 m (3,281 ft) along the seismic profile were generated by using refraction velocities and corehole sonic velocities to convert from time sections to depth sections. Time-distance, unmigrated depth-distance, and migrated depth-distance images show lateral variations in the geologic units observed in the USGS-NASA Langley corehole. A high-amplitude reflection at 630 to 625 m (2,067 to 2,051 ft) depth on the migrated depth image correlates with the top of weathered granite (the Langley Granite) at 626.3 m (2,054.7 ft) in the Langley core. Additional high-amplitude reflections below that depth likely represent a weathering profile developed in the upper part of the granite. Diffractions on the unmigrated images suggest that the granite contains numerous inhomogeneities that may consist of mineral veins and mineralized faults and fractures, as seen in the granite cores. Above the granite, crater unit A (minimally to moderately disturbed sands and clays of the Cretaceous Potomac Formation) is characterized by semicontinuous, horizontal and moderately inclined reflections that are broken by pervasive, subvertical, small-offset faults. Sediments of the lower beds of crater unit A below 558.1 m (1,831.0 ft) in the core have horizontal bedding and are nearly pristine. Above that depth, the upper beds of crater unit A contain thick fluidized sand intervals and fractured clay-silt beds. The contact between the granite and crater unit A is essentially horizontal on the migrated depth profile and shows minor relief produced by a few steeply dipping faults. Above crater unit A, the lower beds of crater unit B are lithologically similar to the upper beds of crater unit A and display similar impact-generated deformation. In the migrated depth image, crater unit A and the lower beds of crater unit B are combined into one unit. A thin zone (0.3 m (1.0 ft) thick) of injected glauconitic sediment at the base of the lower beds (at 442.5 m (1,451.7 ft) depth) is the only occurrence of exotic material in the lower beds of crater unit B in the core. The upper beds of crater unit B (above 427.7 m (1,403.3 ft) depth) are represented by discontinuous, locally weak, isolated, or inclined reflections on the migrated depth image. In the core, the upper beds of crater unit B are divided into megablocks and megablock zones that consist of fragmented sediments of the Potomac Formation. The megablocks are separated by matrix zones that consist of smaller blocks of sediments of the Potomac Formation suspended in a matrix of native disaggregated sediments of the Potomac Formation and injected, exotic disaggregated, glauconitic Upper Cretaceous and lower Tertiary marine sediments. Angular relationships and offsets of reflections across the high-relief contact between the upper beds of crater unit B and the underlying combined crater unit A and the lower beds of crater unit B suggest that the contact is a dip-slip fault locally. Above a contact with crater unit B at a depth of 269.4 m (884.0 ft), the Exmore beds are represented by strong, continuous and discontinuous, overstepping reflections that suggest division of the Exmore into four laterally discontinuous depositional subunits. Two of these subunits are present near the Langley corehole on the seismic images and are recognized in the core (Gohn and others, this volume, chap. C). In the Langley core, the Exmore beds consist of clasts of Cretaceous and Tertiary preimpact sediments and cataclastic, shocked, pre-Mesozoic igneous rocks suspended in a matrix of calcareous, muddy, quartz-glauconite sand and granules that contains shocked quartz. The dipping, truncated, and disrupted reflections within crater units A and B are interpreted to represent a 550-m-wide (1,805-ft-wide), stratabound collapse structure. This structure does not affect the underlying basement granite or the lower beds of crater unit A, nor does it affect the base of the Exmore beds above crater unit B. The collapse structure is not bounded laterally by major normal faults. Instead, structural displace ments appear to be distributed among abundant short, smalloffset faults and intervals of fluidized sediment. Fluidized sands above 558 m (1,831 ft) depth in crater unit A are interpreted as a low-strength zone that accommodated the widespread, latestage, gravitational collapse of the impact structure. The pro posed Langley collapse structure may be analogous to stratabound grabens in the outer zone of the Silverpit crater (North Sea). The Exmore beds are interpreted as impact-generated, ocean-resurge deposits. The upper contact of the Exmore section is a wavy, semicontinuous reflection that may represent large bedforms produced by resurge currents or returning impact-generated tsunamis, or it may represent the unmodified blocky or hummocky top of the final Exmore debris flow. Typically continuous, nearly horizontal reflections characterize the upper Eocene to Pleistocene postimpact section of dominantly marine sediments.

Virginia↗

Beyond conductive targets: Characterizing lithium-prospective lacustrine evaporite mineral systems of North America’s Basin and Range Province with regional-scale AEM

The Basin and Range province of North America hosts substantial lacustrine evaporite mineral systems prospective for lithium, a critical mineral currently listed for mineral resource assessment by the U.S. Geological Survey. Airborne electromagnetic (AEM) surveys are being conducted to support these assessments by identifying shallow clays and brines, as well as through improving the shallow subsurface geologic framework of the regional fluid flow system. In 2022-2023, three focus areas with proven lithium resources or considered highly prospective for lithium are being surveyed. Results from this effort can help to improve our understanding of the geologic conditions and geophysical signatures associated with known resource regions and benefit future lithium resource assessments by identifying regions with similar geophysical and geologic characteristics.

Arizona, California, Idaho, Nevada, Oregon, Utah↗

Impacts of mineralogical variation on CO2 behavior in small pores from producing intervals of the Marcellus Shale: Results from neutron scattering

The Near and InterMediate Range Order Diffractometer (NIMROD) was used to examine the potential impact of shale mineralogy on CO 2 behavior within micropores. Two samples with varying mineral compositions were obtained from producing intervals in the dry gas window in the Middle Devonian Marcellus Shale. One of the samples contained relatively high amounts of quartz and clay and low carbonate, the other contained relatively equal amounts of quartz, carbonate, and clay. The samples were probed with CO 2 at subcritical pressures (20–50 bar) and temperature (22 °C) and characterized over a neutron scattering vector ( Q ) range of 0.02 < Q < 50 Å –1 . This Q range provides information from the atomistic length-scale up to pore radii of 10 nm. Mineralogy variations between the samples did not affect scattering ratios over the entire Q range accessible with the NIMROD. Q values for the minimum scattering ratios of both samples at similar pressures are remarkably similar, particularly for Q < ∼0.09 Å –1 , and maximum scattering ratios are similar in both samples suggesting that mineral pores are so uncommon in the pore sizes examined that they cannot be resolved due to the overwhelming amounts of organic pores in these samples. Overall, these findings suggest that mineralogical variations have little effect on CO 2 behavior within organic matter-hosted shale micropores at high thermal maturities and they lend support to the assertion that CO 2 cannot be stored in the vast surface areas of micropores in organic material in shale formations. In addition, CO 2 enhanced oil recovery (EOR) is unlikely to displace petroleum from some of the smaller mesopores (2.5 to ∼3.5 nm) and all of the micropores because they are effectively closed to CO 2 . amples were probed with CO2 at subcritical pressures (20 50 bar) and temperature (22 oC) and characterized over a neutron scattering vector (Q) range of 0.02 < Q < 50 -1. This Q range provides information on nominal pore size radii of around 10 0.5 nm. Mineralogy variations between the samples did not affect scattering ratios over the entire Q range accessible with the NIMROD. Q values for the minimum scattering ratios of both samples at similar pressures are statistically indistinguishable and maximum scattering ratios are similar in both samples suggesting that mineral pores are either absent or are so uncommon that they cannot be resolved due to the overwhelming amounts of organic pores in these samples. Overall, these findings suggest that mineralogical variations have little effect on CO2 behavior within organic matter-hosted shale micropores at high thermal maturities and they lend support to the assertion that CO2 cannot be stored in the vast surface areas of micropores (<2.5 nm) in shale formations. In addition, CO2 enhanced oil recovery (EOR) is unlikely to displace petroleum from some of the smaller mesopores (2.5 10 nm) and all of the micropores because they are effectively closed to CO2.

Energy & Fuels↗

The gabbros and associated hornblende rocks occurring in the neighborhood of Baltimore, Maryland

Considerable attention has been devoted during late years to the metamorphism of igneous rocks, and it can now be regarded as placed beyond reasonable doubt that such rocks may be changed to more or less schistose masses, which often closely resemble crystallized sediments. This possibility has heretofore been largely ignored, owing doubtless to the extensive obliteration of those characteristics which are generally regarded as most typical of eruptive rocks. Schistose or banded structure, however, can now hardly be considered as necessarily an indication of sedimentary origin. The minerals which are most characteristic of the so-called crystalline schists have been repeatedly shown to be derived from the alteration of igneous as well as of aqueous formations. These minerals only represent the final and most stable combination of certain elements under certain conditions, and are quite independent of the earlier combinations in which these elements may have existed. A lava bed and a clay bank, if the two may be supposed to have originally had the same chemical composition, might, under the influence of the same metamorphic agencies, ultimately give rise to the same rock in spite of original differences in structure or mineralogical composition. Stratification may be obliterated by metamorphism, while foliation, or even a banded structure, may, by the same means, be secondarily induced. Neither structure nor mineral composition can be taken as an infallible guide in determining the origin or the age of rocks. The present paper is intended as a contribution to our knowledge of a particular phase of metamorphism in eruptive rocks, i. e., that one which is dependent on the secondary development of hornblende by the paramorphism or pseudomorphism of pyroxene. This is a change the frequency of which renders it of fundamental geological importance. It has already received considerable attention from many eminent geologists, but no locality heretofore studied seems to have afforded opportunities for tracing out every stage in the process of alteration superior to those offered by the area of massive rocks west and northwest of the city of Baltimore. Here, covering a district of over fifty square miles, the unchanged pyroxene rock and its resultant hornblendic equivalent occur in the most intimate relations. Exposures of both rocks in situ are numerous, and the opportunity of following out the gradual transition of one into the other is proportionately great.

Maryland↗

Mineral and energy resources of the Roswell Resource Area, East-Central New Mexico

The sedimentary formations of the Roswell Resource Area have significant mineral and energy resources. Some of the pre-Pennsylvanian sequences in the Northwestern Shelf of the Permian Basin are oil and gas reservoirs, and Pennsylvanian rocks in Tucumcari Basin are reservoirs of oil and gas as well as source rocks for oil and gas in Triassic rocks. Pre-Permian rocks also contain minor deposits of uranium and vanadium, limestone, and gases. Hydrocarbon reservoirs in Permian rocks include associated gases such as carbon dioxide, helium, and nitrogen. Permian rocks are mineralized adjacent to the Lincoln County porphyry belt, and include deposits of copper, uranium, manganese, iron, polymetallic veins, and Mississippi-Valley-type lead-zinc. Industrial minerals in Permian rocks include fluorite, barite, potash, halite, polyhalite, gypsum, anhydrite, sulfur, limestone, dolomite, brine deposits (iodine and bromine), aggregate (sand), and dimension stone. Doubly terminated quartz crystals, called 'Pecos diamonds' and collected as mineral specimens, occur in Permian rocks along the Pecos River. Mesozoic sedimentary rocks are hosts for copper, uranium, and small quantities of gold-silver-tellurium veins, as well as significant deposits of oil and gas, carbon dioxide, asphalt, coal, and dimension stone. Mesozoic rocks contain limited amounts of limestone, gypsum, petrified wood, and clay. Tertiary rocks host ore deposits commonly associated with intrusive rocks, including platinum-group elements, iron skarns, manganese, uranium and vanadium, molybdenum, polymetallic vein deposits, gold-silver-tellurium veins, and thorium-rare-earth veins. Museum-quality quartz crystals are associated with Tertiary intrusive rocks. Industrial minerals in Tertiary rocks include fluorite, vein- and bedded-barite, caliche, limestone, and aggregate. Tertiary and Quaternary sediments host important placer deposits of gold and titanium, and occurrences of silver and uranium. Important industrial commodities include caliche, limestone and dolomite, and aggregate. Quaternary basalt contains sub-ore-grade uranium, scoria, and clay deposits.

New Mexico↗

Ground water chemistry and geochemical modeling of water-rock interactions at the Osamu Utsumi mine and the Morro do Ferro analogue study sites, Poços de Caldas, Minas Gerais, Brazil

Surface and ground waters, collected over a period of three years from the Osamu Utsumi uranium mine and the Morro do Ferro thorium/rare-earth element (Th/REE) deposits, were analyzed and interpreted to identify the major hydrogeochemical processes. These results provided information on the current geochemical evolution of ground waters for two study sites within the Po&ccedil;os de Caldas Natural Analogue Project. The ground waters are a K&ndash;Fe&ndash;SO 4 &ndash;F type, a highly unusual composition related to intense weathering of a hydrothermally altered and mineralized complex of phonolites. Tritium and stable isotope data indicate that ground waters are of meteoric origin and are not affected significantly by evaporation or water&ndash;rock interactions. Recharging ground waters at both study sites demonstrate water of less than about 35 years in age, whereas deeper, more evolved ground waters are below 1 TU but still contain in most cases detectable tritium. These deeper ground waters may be interpreted as being of 35 to 60 or more years in age, resulting mainly from an admixture of younger with older ground waters and/or indicating the influence of subsurface produced tritium. Geochemical processes involving water&ndash;rock&ndash;gas interactions have been modeled using ground water compositions, mineralogic data, ion plots and computations of speciation, non-thermodynamic mass balance and thermodynamic mass transfer. The geochemical reaction models can reproduce the water chemistry and mineral occurrences and they were validated by comparing the results of thermodynamic mass transfer calculations (using the PHREEQE program, Parkhurst et al., 1980). The results from the geochemical reaction models reveal that the dominant processes are production of CO 2 in the soil zone through aerobic decay of organic matter, dissolution of fluorite, calcite, K-feldspar, albite, chlorite and manganese oxides, oxidation of pyrite and sphalerite, and precipitation of ferric oxides, silica and kaolinite. Gibbsite precipitation can be modeled for the shallow (recharge) water chemistry at Morro do Ferro, consistent with known mineralogy. Recharge waters are undersaturated with respect to barite and discharging waters and deeper ground waters are saturated to supersaturated with respect to barite demonstrating a strong solubility control. Strontium isotope data demonstrate that sources other than calcium-bearing minerals are required to account for the dissolved strontium in the ground waters. These may include K-feldspar, smectite&ndash;chlorite mixed-layer clays and goyazite [SrAl 3 (PO 4 ) 2 (OH) 5 &bull; H 2 O]. 1992.

Journal of Geochemical Exploration↗

Geology and mineral resources of the Lehighton and Palmerton quadrangles, Carbon and Northampton Counties, Pennsylvania

The Lehighton and Palmerton 73 1/2-minute quadrangles cover an area of about 112 square miles of diversified terrain in the folded Appalachian Mountain and Great Valley sections of the Valley and Ridge physiographic province in Carbon, Lehigh, and Northampton Counties, Pennsylvania. The Lehigh River and Blue Mountain are the prominent features of the topography. Rock units defined and mapped in the area are the lithified sediments that were deposited in a variety of offshore marine, marine shelf, marginal marine, and fluvial environments associated with two phases of basin filling. The rocks are separated into four lithotectonic units, each deformed semi-independently of adjacent lithotectonic units. Decollements presumably separate the lithotectonic units. Lithotectonic unit 1 consists of about 12,000 feet of slate and graywacke of the Middle and Upper Ordovician Martinsburg Formation. This unit contains mainly asymmetric, similar, and nearly isoclinal folds, with wave lengths of 1,000 to 3,000 feet and amplitudes of 400 to 2,000 feet, formed mainly by passive flow and slip. Lithotectonic unit 2 includes about 3,100 feet of sandstone, siltstone, shale, and conglomerate of the Shawangunk Formation (Ordovician(?) and Silurian), Bloomsburg Red Beds (Silurian), and the lower part of the Poxono Island Formation (Silurian). This unit contains mainly asymmetric and concentric folds, with wavelengths of about one mile and amplitudes of 1,500 to 5,000 feet, formed by flexural slip with minor passive slip and flow. Lithotectonic unit 3 contains about 750 feet of limestone, shale, siltstone, sandstone, and dolomite of the upper part of the Poxono Island Formation, Bossardville Limestone, and Decker Formation (all Silurian), the Coeymans and New Scotland Formations, Shriver Chert, and Ridgeley Formation of the Oriskany Group and the Schoharie-Esopus Formation (all Lower Devonian), and the Palmerton Formation and Buttermilk Falls Limestone (both Middle Devonian). This unit has asymmetric, concentric, similar, and flap folds, with wavelengths of 1,000 to 1,500 feet and amplitudes of about 1,550 feet, formed by flexural slip and flow and passive slip and flow. Lithotectonic unit 4 consists of more than 13,000 feet of sandstone, conglomerate, siltstone, and shale of the Middle Devonian Marcellus and Mahantango Formations, the Upper Devonian Trimmers Rock and Catskill Formations, the Devonian-Mississippian Spechty Kopf Forma tion, the Mississippian Pocono and Mauch Chunk Formations, and the Pennsylvanian Pottsville Formation. This unit contains nearly symmetric, concentric flexural-slip folds with wavelengths of more than five miles and amplitudes of about one mile. Surficial deposits occur throughout the mapped area and include: Pleistocene pre-lllinoian(?) till and outwash(?), lllinoian(?) till and outwash, Wisconsinan outwash, shale-chip rubble, boulder fields, and colluvium; and Holocene alluvium, landslide deposits, and man-made dumps. The rocks of the mapped area, except for the deeply weathered lime stones, generally have good slope stability and foundation support strength, moderate to low primary infiltration capacity and aquifer potential but moderate to high secondary values for these properties, moderate resistance to weathering, and are moderately difficult to difficult to excavate. All of these properties are strongly influenced by the abundant bedding, cleavage, and joint partings of the rocks. Similar evaluations for the surficial deposits indicate less desirable values except for the ease of excavation of most of the unconsolidated materials. Currently active and potential mineral resources are numerous in the Lehighton and Palmerton quadrangles and include slate, sand, paint ore, building stone, crushed rock, lightweight aggregate, clinker residue, clay, hydraulic cement, and roofing granules.

Pennsylvania↗

Mineral resource potential map of the Savannah Roadless Area, Liberty County, Florida

The Savannah Roadless Area is underlain by sedimentary rocks having low potential for oil and gas and minerals. The low potential for oil or gas notwithstanding, the possibilities for discovery cannot be ruled out because the area and nearby lands have not been thoroughly explored. No minerals have been mined within the Savannah Roadless Area, and the only production nearby has been the digging of clayey sand used in stabilizing U.S. Forest Service roads. Fuller's earth, quartz sand and gravel, clayey sand, and common clay presently are produced elsewhere in the region, and limestone and peat have been produced in the past. No clay suitable for structural clay products or fuller's earth is present in the roadless area; however, a bed of quartz sand and gravel of excellent quality was penetrated at a depth interval of 37-50 ft by one drill hole. Although this bed is coarser grained-and therefore is more suitable for many uses-than the sand deposits worked elsewhere in the Big Bend region, its mineral resource potential is reduced by the thickness of overburden above it and by its distance from markets in population centers. The Apalachicola National Forest has been explored for phosphate and reconnoitered for heavy minerals, but no valuable deposits of either have been found.

Florida↗

Euramerican tonsteins: Overview, magmatic origin, and depositional-tectonic implications

Carboniferous tonsteins (kaolinized volcanic-ash beds) of wide geographic distribution are known in both Europe and North America. Relict volcanic minerals common in these Euramerican tonsteins are volcanic quartz (including beta-quartz paramorphs), zircon and ilmenite; less common are magnetite, fayalite, rutile, monazite, xenotime, apatite and sanidine. Data for two relatively thick (3-13 cm) and widespread (>400 km) European tonsteins (Erda and Sub-Worsley Four-foot) indicate an increase in detrital quartz near the top of the beds which indicates mixing with normal clastic sediments, including the introduction of heavy detrital minerals (e.g., tourmaline and garnet). These thick tonsteins show multiple horizontal bedding, normal graded bedding, disturbed bedding, and centimeter-scale scour surfaces. The Fire Clay tonstein in North America represents from one to five separate volcanic air-fall ash deposits as determined by normal graded bedding and mineralogical analysis. These features indicate several episodes of volcanic-ash deposition and very localized subsequent erosion and bioturbation. Electron microprobe data from glass inclusions in volcanic quartz in Euramerican tonsteins indicate a rhyolitic origin for these tonsteins and reveal chemical "fingerprints" valuable for intra- and inter-basinal correlations. However, the tectonic framework for European and North American tonsteins was quite different. In Europe, volcanic-ash beds were associated with Variscan collisional tectonics, whereas in North America, volcanic ash was associated with Ouachita tectonic activity, explosive volcanism from the Yucatan block, collision between the South American and North American plates, and the formation of Pangea.

Palaeogeography, Palaeoclimatology, Palaeoecology↗

Lithology, reservoir properties, and burial history of portion of Gammon Shale (Cretaceous), southwestern North Dakota

In the northern Great Plains, large quantities of biogenic methane are contained at shallow depths in Cretaceous marine mudstones. The Gammon Shale and equivalents of the Milk River Formation in Canada, which comprise most sediments deposited offshore during the Eagle-Telegraph Creek regression, are typical of such gas-bearing rocks. At Little Missouri field, southwestern North Dakota, Gammon reservoirs consist of discontinuous lenses and laminae of siltstone, less than 10 mm thick, enclosed by silty clay shale. Large amounts of allogenic clay, including highly expansible mixed-layer illite-smectite cause great water sensitivity and high measured and calculated water-saturation values. Reconstructed burial depths, clay mineralogy, and organic matter maturation studies show that the Gammon has not undergone thermal conditions sufficient for oil or thermal gas generation. Scarce authigenic minerals such as pyrite, siderite, and calcite probably formed as a result of bacterial metabolism early in the burial history. The scarcity of authigenic silicates suggests that diagenesis has been inhibited during much of the burial history by the presence of free methane. Shale layers are practically impermeable whereas siltstone microlenses are porous (30 to 40%) and have permeabilities on the order of 3 to 30 md. Reservoir continuity between siltstone layers is poor and, overall, reservoir permeability is probably less than 0.4 md. Connecting passageways between siltstone lenses are 0.1 µm or less in diameter. Organic matter in the low-permeability reservoirs served as the source of biogenic methane, and capillary forces acted as the trapping mechanism for gas accumulation. At Little Missouri field, reservoirs and non-reservoirs cannot be distinguished on the basis of lithology, and much of the Gammon interval is potentially economic. Future research should be directed toward determining the physical basis of log response in the low-permeability reservoirs and toward the development or application of water-free recovery technology.

North Dakota↗

Mineral and energy resources of the BLM Roswell Resource Area, east-central New Mexico

The sedimentary formations of the Roswell Resource Area have significant mineral and energy resources. Some of the pre-Pennsylvanian sequences in the Northwestern Shelf of the Permian Basin are oil and gas reservoirs, and Pennsylvanian rocks in Tucumcari basin are reservoirs of oil and gas as well as source rocks for oil and gas in Triassic rocks. Pre-Permian rocks also contain minor deposits of uranium and vanadium, limestone, and associated gases. Hydrocarbon reservoirs in Permian rocks include associated gases such as carbon dioxide, helium, and nitrogen. Permian rocks are mineralized adjacent to the Lincoln County porphyry belt, and include deposits of copper, uranium, manganese, iron, polymetallic veins, and Mississippi-valley-type (MVT) lead-zinc. Industrial minerals in Permian rocks include fluorite, barite, potash, halite, polyhalite, gypsum, anhydrite, sulfur, limestone, dolomite, brine deposits (iodine and bromine), aggregate (sand), and dimension stone. Doubly terminated quartz crystals, called "Pecos diamonds" and collected as mineral specimens, occur in Permian rocks along the Pecos River. Mesozoic sedimentary rocks are hosts for copper, uranium, and small quantities of gold-silver-tellurium veins, as well as significant deposits of oil and gas, COa, asphalt, coal, and dimension stone. Mesozoic rocks contain limited amounts of limestone, gypsum, petrified wood, dinosaur remains, and clays. Tertiary rocks host ore deposits commonly associated with intrusive rocks, including platinum group elements, iron skarns, manganese, uranium and vanadium, molybdenum, polymetallic vein deposits, gold-silver- tellurium veins, and thorium-rare earth veins. Museum-quality quartz crystals in Lincoln County were formed in association with intrusive rocks in the Lincoln County porphyry belt. Industrial minerals in Tertiary rocks include fluorite, vein- and bedded-barite, caliche, limestone, and aggregate. Tertiary and Quaternary sediments host important placer deposits of gold and titanium, and minor silver, uranium occurrences, as well as important industrial commodities, including caliche, limestone and dolomite, and aggregate (sand). Quaternary basalt contains sub-ore-grade uranium, scoria, and clay deposits.

New Mexico↗

Spectral characteristics of iron-bearing phyllosilicates: Comparison to Orgueil (CI1), Murchison and Murray (CM2)

Phyllosilicate alteration minerals are commonly found in low petrologic types of carbonaceous chondrites. Previous spectral studies have examined Mg-bearing phyllosilicates with limited success in matching the spectral properties of CM and CI chondrites. Transmission electron microscope and other analytical techniques suggest that Fe-bearing clays are more abundant in CI and CM chondrites than magnesian varieties. Here, we present the results of an examination of the reflectance spectra of Fe-phyllosilicates, including serpentines and berthierines, of which the latter were formerly known as septechlorites. We have measured the diffuse reflectance spectra of powdered samples from 0.3 to 25 ??m. We find that these minerals provide a better spectral match to many of the features seen in CI and CM chondrites, and simple linear combinations of the spectra of both Fe- and Mg-phyllosilicates closely approximate the spectra of CM and CI chondrites.

Meteoritics and Planetary Science↗

Tonsteins and clay-rich layers in coal-bearing intervals of the Eocene Manning formation, east-central Texas

Six samples from clay-rich intervals in the coal-bearing upper part of the Eocene Manning Formation were analyzed by scanning-electron microscopy and energy-dispersive X-ray fluorescence to determine the origin of minerals in the samples. Two samples were from surface-mine exposures of the 3500 coal bed near Bryan, Texas, and the remaining samples were from an exposure of a correlative interval at the Lake Somerville spillway about 60 km (37 mi) southwest of Bryan. Preliminary data suggest that both a 2-cm-thick (0.75-in) claystone from the upper part of the 3500 bed and the upper part of an 11-cm-thick (4.25-in) mudstone from the floor of the lower coal bed at the spillway were derived from volcanic ash falls. Both clay layers identified as possible tonsteins are composed of kaolinite and accessory quartz, euhedral to subhedral zircon, feldspars, and Ca-Al phosphates (crandallite?). Both alkali and plagioclase feldspars are observed in the two samples, but K-feldspar predominates in the upper clay layer of the 3500 bed, and plagioclase, with accessory Ti-bearing biotite, predominates in the sample from the floor of the spillway. These compositional differences suggest two separate volcanic ash falls. The other sampled clay layers contain rounded to subrounded zircons and feldspars in a mixed-layer clay groundmass, which suggests detrital rather than ash-fall origins.

Texas↗

The copper and uranium deposits of the Coyote district, Mora County, New Mexico

The copper and uranium-vanadium deposits of the Coyote district, Mora County, N. Mec, are confined to the lower 2,000 feet of the Sangre de Gristo formation of Pennsylvanian and Permian age. A narrow belt of deposits in steeply dipping or overturned rocks extends for 7 miles along Coyote Creek south of Guadalupita. Earlier studies showed that the copper deposits contained uranium, but both the reserves and the uranium content of the copper-bearing shale are too low to permit the recovery of uranium. However, small, commercial grade uranium deposits have been discovered in sandstone. Small lenses of copper-bearing carbonaceous shale, siltstone, limestone or sandstone, interbedded with predominantly red rocks, are present at intervals at 12 or more stratigraphic levels. The better deposits, in carbonaceous shale, average about 2 percent copper. The copper content of the other rocks is usually lower, but small concentrations may contain 6 percent copper. The principal copper minerals are chalcocite and malachite. Chalcocite replaces wood and forms nodules that contain small, variable amounts of pyrite, bornite, covellite, and rarely, uraninite. The uranium deposits occur as small closely spaced pockets that are commonly localized by sedimentary structures within one or more fluviatile arkosic sandstone beds near the middle of the formation, particularly" where carbonized wood, clay galls, and rock fragments are abundant. The uraniferous sandstone is commonly stained pink by hematite that probably was introduced with the uranium. The color increases in intensity with the radioactivity. The outcrops of the uranium deposits are typically inconspicuous, but close inspection shows they contain malachite, chalcopyrite, black vanadium minerals of micaceous habit, metatyuyamunite and microscopic grains of an unidentified black uraniferous substance. The proportion of copper, uranium, and vanadium is variable and any metal may be dominant. The metals probably were derived from pre-Cambrian granitic rocks. Copper and minor amounts of uranium were deposited in local stagnant basins by reaction with hydrogen sulfide. and decaying organic material. The uraniferous shales and the copper deposits are believed to be syngenetic, or nearly so, but the uranium deposits in sandstone are epigenetic and probably were deposited from ground waters with a possible hydrothermal admixture. The uranium and vanadium may have been reconcentrated from earlier, low-grade, syngenetic deposits.

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