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A time-space model of graphite mineral systems

Increasing demand for graphite in energy storage systems warrants review of graphite ore genesis in a mineral systems framework. Orogenic graphite encompasses the metamorphic and orogenic mineral systems that produce flake graphite and hydrothermal vein (lump and chip) graphite deposits, respectively. A common feature of orogenic graphite deposits is an association with upper amphibolite- to granulite-facies metasedimentary rocks in continent-continent or continent-island arc collisional orogens. Orogenic flake graphite deposits form primarily through graphitization of organic carbon during regional metamorphism, but strain localization and partial melting of pelitic protoliths are likely important processes for graphite grade and quality enrichment. Orogenic vein graphite deposits precipitate from hydrothermal fluids, possibly derived from metamorphism or anatexis at depth. Decarbonation reactions in mixed calcareous-carbonaceous metasedimentary sequences are the most likely carbon sources for the veins. In contrast, intrusion-related graphite includes magmatic-hydrothermal and metamorphic mineral systems that form primarily in continental arc settings via the interaction of magmas with carbonaceous sedimentary packages. Magmatic-hydrothermal flake graphite deposits are hosted in plutonic and volcanic rocks, and result from the exsolution of CO 2 -CH 4 -rich fluids from melts contaminated by such packages. Contact metamorphism of carbonaceous sedimentary rocks by plutons produces some microcrystalline (amorphous) graphite deposits, including many in China. Compilation of geologic data from known graphite deposits globally suggests that pulses of carbon deposition in the Paleoproterozoic, Mesoproterozoic, and Neoproterozoic provided source carbon material. Subsequent supercontinent orogenesis at ca. 2,100 to 1,700 Ma (Columbia), ca. 1,300 to 1,000 Ma (Rodinia), and ca. 650 to 500 Ma (Gondwana) resulted in the genesis of orogenic flake and vein graphite deposits, where favorable geologic components overlapped with organic ± carbonate carbon-rich strata. Cryogenian deposition of graphite protoliths and Cryogenian – Cambrian metamorphic mineralization account for nearly 75% of all known resources globally and coincide with profound carbon isotope excursions and climate variability, implying a link with the global carbon budget. Comparatively few graphite deposits are associated with Pangea-forming orogens, attributed to less exhumation and/or denudation. High-temperature metasedimentary belts containing organic carbon-rich protoliths are most favorable for hosting orogenic flake graphite deposits, whereas sequences that also contain carbonate protoliths are favorable for orogenic graphite veins. Continent-scale orogenic belts may host both deposit types along with vanadium deposits. Use of a time-space mineral systems framework for graphite deposits can improve exploration models needed to ensure future supply of this critical mineral and provide insights into Earth’s long-term carbon cycle.

Mineralium Deposita

Pediment formation and subsequent erosion in Gale crater: Clues to the climate history of Mars

Evidence of paleo-rivers, fans, deltas, lakes, and channel networks across Mars has prompted much debate about what climate conditions would permit the formation of these surface water derived features. Pediments, gently sloping erosional surfaces of low relief developed in bedrock, have also been identified on Mars. On Earth, these erosional landforms, often thought to be created by overland flow and shallow channelized runoff, are typically capped by fluvial sediments, and thus in exceptionally arid regions, pediments are interpreted to record past wet periods. Here we document the Greenheugh pediment in Gale crater, exploiting the observational capability of the Curiosity rover. The absence of a fluvial cap suggests that the pediment was likely cut by wind erosion, not fluvial processes. The pediment was then buried by an aeolian deposit (Stimson sandstone) that mantled the lower footslopes of Aeolis Mons (informally known as Mt. Sharp). This burial terminated active wind erosion, preserving the pediment surface (as an angular unconformity). Groundwater was present prior-to, during, and shortly after Stimson deposition, perhaps contributing to lithification and certainly to early diagenesis. Post lithification, wind erosion first cut canyons in the northern most footslopes (north of Vera Rubin ridge). Unlithified gravels were deposited in these canyons, likely due to runoff from Mt. Sharp. Boulder-rich fluvial and debris flow deposits built a > 70 m thick sequence (Gediz Vallis ridge) on the southern Greenheugh pediment. Continued wind erosion left elevated patches of gravel on the northern footslopes, and exposure age dating shows that erosion essentially ceased before 1 Ga (but possibly much earlier). Erosion to the south led to emergence of Vera Rubin ridge, retreat of the Greenheugh pediment, and the formation of Glen Torridon valley. Hence, this footslope environment of Mt. Sharp records climate-driven periods of wind erosion, aeolian deposition (and groundwater activity), surface runoff and sediment deposition, followed by further significant wind erosion that declined to present very slow rates. This likely occurred during the late Hesperian and possibly into the Amazonian.

Icarus

Distributed volcanic fields—Patterns, products, processes, and plumbing

Distributed volcanic fields—also referred to as “monogenetic fields” or simply “volcanic fields”—are found on every continent, on the seafloors, and in every tectonic setting on Earth. Yet, our understanding of what constitutes a distributed volcanic field, and our knowledge of the common products, spatiotemporal patterns in activity, and plumbing systems of these fields, are commonly poor and (or) debated. Here we provide an overview of the current understanding of distributed volcanic fields (DVFs) through review and compilation of published data, with an emphasis on understanding the characteristics of fields that are essential to prepare for future hazardous volcanic activity. Distributed fields can erupt restricted to variable magma compositions. Activity in these fields produces nearly all types of volcanoes, including scoria and spatter cones, maars, low shields, lava fields, stratovolcanoes, and calderas, but monogenetic volcanoes are the defining characteristic of DVFs. The number of vents and lifespans of DVFs vary greatly; vent numbers range from 2 to greater than 1,000, and fields can remain active for 150,000 to 10 million years. Some characteristics of DVFs appear field dependent. Although the volumes of single monogenetic eruptions within DVFs globally are variable (from less than 0.1 to a few cubic kilometers), each field may have a characteristic range in eruption volumes. Eruptions within distributed volcanic fields can have a random distribution and timing, but spatial and (or) temporal vent clustering and alignment are common, and eruptions may be time or volume predictable. Average eruption recurrence intervals in DVFs span over an order of magnitude, from less than 3 to greater than 100 thousand years. Exposures of the shallow portions of older systems reveal that many magma batches end their ascent before reaching the surface, with some dikes stopping within only meters of the surface. Petrologic insights into the deeper plumbing systems of DVF volcanoes indicate variable depths of magma crystallization and (or) stalling, and that magma transport and storage systems may be unique to a particular DVF and its underlying crustal structure. Both seismic and petrologic data for mafic DVF eruptions corroborate intrusions of magma into storage systems in the months to years before eruption, as well as variable ascent rates through the crust (days to weeks). Few distributed fields are closely monitored, as they erupt infrequently, but these observations imply that the amount of time available to install monitoring instrumentation after the first felt seismicity may be short, as precursory activity is frequently on the order of days to months for modern DVF eruptions. Satellite-based geodesy may provide useful warning in such cases. This chapter concludes with outstanding questions and areas for future research that will aid in our understanding and preparedness for future DVF eruptions.

Professional Paper

Geologic map of the northwest flank of Mauna Loa volcano, Island of Hawai‘i, Hawaii

Mauna Loa, the largest active volcano on Earth, has erupted 34 times since written descriptions became available in A.D. 1832. The most recent eruption of Mauna Loa occurred on November 27, 2022, after a 38 year hiatus; it lasted for 12 days. Some eruptions began with only brief seismic unrest, whereas others followed several months to a year of increased seismicity. Once underway, Mauna Loa’s eruptions can produce lava flows that may reach the sea in less than 24 hours, severing roads and utilities. For example, lava flows that erupted from the Southwest Rift Zone in 1950 advanced at an average rate of 9.3 kilometers per hour (5.8 miles per hour); all three lobes reached the ocean within ~24 hours. Near the eruptive vents, the flows likely traveled even faster. In terms of eruption frequency, pre-eruption warning, and rapid flow emplacement, Mauna Loa has great volcanic-hazard potential for the Island of Hawai‘i. Volcanic hazards on Mauna Loa can be anticipated, and risk substantially mitigated, by documenting its past activity to refine our knowledge of the hazards, and by alerting the public and local government officials of our findings and their implications for hazards assessments and risk. The map of the north and west flanks of Mauna Loa shows the distribution and relation of volcanic and surficial sedimentary deposits. It incorporates previously reported work published as generalized small-scale maps and a more detailed map. Within the mapped area, lava has flowed from three different source regions: the Northeast Rift Zone (22 percent), the summit (64 percent), and radial vents (14 percent). All three have different points of origin which, in turn, affect the flow characteristics and periodicity of activity. The map area includes the uppermost part of the NERZ and extends from the highest elevation––13,040 feet at the south end of the Kokoolau quadrangle, just below the summit caldera––to the sea northwest and west of the summit. Lava that erupts from the north and west flanks typically flows to the west, northwest, or north, depending on the vent location. Both morphologic lava flow types—‘a‘ā and pāhoehoe—are present. Pāhoehoe units tend to spread out or widen in low-slope regions, such as in the saddle regions between Mauna Loa and Mauna Kea or between Mauna Loa and Hualālai. In comparison, ʻaʻā flows generally produce narrower flow lobes that have higher relief. This map is the fifth in a series of five maps that will cover Mauna Loa volcano. NOTE: Map sheet 1 contains lines and type with overprint. This feature may be turned on or off in the Adobe Acrobat page display preferences.

Hawaii

Lunar analog study using portable gamma-ray neutron detector: Radiochemical mapping of silicic-to-basaltic volcanic terrains in the San Francisco Volcanic Field, Arizona

Studying lunar silicic volcanism provides key insights into the Moon’s crustal evolution, magmatic processes, and volcanic history. The Lunar-VISE (Lunar Vulkan Imaging and Spectroscopy Explorer) mission will investigate the Gruithuisen domes, a unique lunar region hypothesized to have formed through silicic volcanism. Using instruments on a Firefly Aerospace lander and a Honeybee Robotics rover, Lunar-VISE will analyze mineralogy, geochemistry, and surface properties to determine the origin and evolution of the domes, with a gamma-ray and neutron spectrometer (LV-GRNS) among its payload instruments. In preparation for this mission, we conducted preliminary fieldwork using a handheld gamma-ray neutron detector with NaI(Tl) and Cs LiYCl :Ce (CLYC) scintillators. This study focuses on various rhyolitic and basaltic volcanic centers in the San Francisco Volcanic Field (SFVF) near Flagstaff, Arizona—specifically Sugarloaf Peak, Bonito Lava Flow, and Robinson Mountain, a region containing several well-characterized lunar analog sites. The SFVF was selected for this study due to its broad compositional diversity spanning basaltic to rhyolitic compositions, its well-preserved volcanic morphologies, and its extensive use in previous NASA field campaigns and astronaut training exercises, making it an ideal terrestrial laboratory for testing planetary exploration techniques. We measured natural radioactivity, specifically from potassium (K), thorium (Th), and uranium (U) and other elements in their decay chains, which serve as diagnostic tracers of magmatic differentiation and crustal evolution processes, to assess geochemical variability across compositionally diverse terrains. The detector’s sensitivity was assessed across varying concentration levels. Regionally averaged concentrations of radioisotopes were determined by gamma-ray spectroscopy at selected sites. Our measurements reveal significant compositional variations between sites, with Sugarloaf Peak (rhyolitic, silicic dome) exhibiting the highest average radioisotope concentrations (K: 3.29 ± 0.24 wt%, U: 14.35 ± 1.81 ppm, Th: 27.14 ± 2.43 ppm), while Bonito Lava Flow (K: 1.13 ± 0.08 wt%, U: 3.86 ± 0.52 ppm, Th: 7.52 ± 1.02 ppm), and Robinson Mountain (K: 1.46 ± 0.16 wt%, U: 5.59 ± 1.06 ppm, Th: 11.75 ± 1.98 ppm) show lower concentrations aligned with basaltic compositions. Gamma-ray fluxes were elevated by a factor of approximately three to four at Sugarloaf Peak relative to nearby basaltic terrains, consistent with expected geochemical differentiation patterns. Furthermore, at meter scales, proximity to geological features significantly affects measurements. Th concentrations adjacent to a cliff face at Sugarloaf’s base were 28% higher than values measured 3-5 meters away from the same feature, demonstrating localized compositional heterogeneity. Analysis of station-by-station measurements reveals that K, U, and Th concentrations show an elevation trend at Robinson Mountain and generally higher concentrations near Sugarloaf Peak’s summit, suggesting progressive magmatic differentiation and/or the presence of more evolved lithologies at higher elevations. By mapping these elements on Earth using GRNS, we aim to optimize measurement techniques for Lunar-VISE and similar rover-borne missions by demonstrating the applicability of portable GRNS instruments for planetary surface exploration in an analog environment.

Arizona

Prediction of the probability of elevated nitrate concentrations at groundwater depths used for drinking-water supply in the Puget Sound basin, Washington, 2004–19

The Puget Sound basin encompasses the 13,700-square-mile area that drains to the Puget Sound and the adjacent marine waters of Washington State. Well more than 4 million people live within the basin, with numbers continuing to increase, who rely on the basin’s natural resources including groundwater. The Puget Sound Partnership was created by a Washington State statute to implement a science-based recovery of the Puget Sound to help address impacts to these resources. As part of the recovery, the partnership developed the Puget Sound Vital Signs as measures of ecosystem health that guide the assessment of progress toward Puget Sound recovery goals. The Puget Sound Partnership Leadership Council adopted a Drinking Water Vital Sign associated with human health and quality of life, recognizing certain indicators as integral to the sustainability of Puget Sound recovery efforts. One such Vital Sign indicator was the vulnerability of groundwater throughout the aquifers of the Puget Sound basin to elevated nitrate concentrations as defined by the probability of exceeding 2 milligrams/liter (mg/L) at a specific location and well depth. The U.S. Geological Survey (USGS) led the effort to characterize groundwater vulnerability. For this study, groundwater vulnerability refers to a probability with which a contaminant applied at or near the land surface can migrate to the aquifer of interest for a given set of land-use practices. Nitrate concentration data were selected for evaluation because elevated nitrate concentrations are typically caused by anthropogenic activities and have been associated with deleterious impacts on human health. To identify groundwater vulnerability to elevated nitrate concentrations, logistic regression was used to relate anthropogenic (human associated) and natural variables to the occurrence of elevated nitrate concentrations in untreated groundwater from large public water supply system wells found within the Washington State Department of Health Sentry database. Variables that were analyzed included well depth, soil hydraulic conductivity, precipitation, population density, fertilizer application amounts, and land-use types. Statistically significant models that predicted the probabilities of groundwater nitrate concentrations greater than 2 mg/L based on the predictor variables were created for the time periods 2000–04, 2005–09, 2010–14, and 2015–19. For all time periods, well depth and a measure of the abundance of urban and agricultural land over or near the well consistently helped explain the vulnerability of the well to elevated nitrate concentrations defined as a probability of exceeding 2 mg/L of nitrate. Precipitation and (or) soil hydraulic conductivity were also important predictor variables in the models. The models for each time period were used to create maps of groundwater vulnerability at 150- and 300-foot depths throughout the Puget Sound basin. As expected, the most vulnerable locations were associated with shallower well depths and increased agriculture and urban land cover. Across all four time periods, groundwater vulnerability throughout the Puget Sound was low, with probabilities of exceeding 2 mg/L concentrations of nitrate at depths at 150 and 300 feet typically less than 50 percent. Results also found a slight decrease in probabilities of elevated nitrate concentrations throughout the basin over time. More specifically, additional statistical tests found that groundwater with probabilities of less than about 60 percent declined from 2000 to 2019 and represented more than 75 percent of the modeled Puget Sound basin aquifer. Wells with greater than 60 percent probability increased over the same time period but represented only about 25 percent of the aquifer. The maps and statistical analysis presented in the study provide valuable and informative evaluation of the vulnerability of groundwater in the Puget Sound basin to elevated nitrate concentrations. The probability maps do not represent measured nitrate concentrations in groundwater, but rather they present the probability that nitrate concentrations exceed 2 mg/L. The models and predictions from this study are a viable indicator for the Puget Sound Partnership’s Healthy Human Population—Drinking Water Vital Sign. The logistic regression modeling approach presented here benefits water managers by allowing them to assess temporal trends in a range of probabilities, explore vulnerability changes as new regional land cover and anthropogenic data are generated, and distinguish vulnerabilities at different depths within the aquifer.

Washington

High-resolution transboundary vegetation community maps of the Sonoran and Mojave Desert ecoregion to support critical landscape conservation planning and habitat management needs

We produced a 30-m resolution binational land cover map of Bird Conservation Region 33 (BCR 33) for the U.S. North American Bird Conservation Initiative. The region covers large portions of the Sonoran and Mojave Deserts. The map can support the U.S. Fish and Wildlife Service (FWS) Migratory Bird Program’s recovery planning efforts and constitutes the first known binational land cover dataset spanning sections of the United States–Mexico border and using a consistent classification system for both countries. The mapped region includes 152 distinct land cover classes, covering a total area of 38,421,453 ha (148,345 mi 2 ), of which 13,148,345 ha (52,706 mi 2 ) are located in Mexico and 24,770,640 ha (95,639 mi 2 ) in the United States. We primarily used Landsat 8 (OLI) imagery, supplemented by limited ground surveys from two field campaigns, drone-based aerial data, and existing vegetation classification frameworks from both countries. The classification applied a data-fusion approach integrating 30-m Landsat 8 imagery, decadal phenology metrics from vegetation indices, and a random forest model trained mainly with datasets from a comprehensive national mapping project from the U.S. Geological Survey (USGS) GAP Analysis Project (GAP) and federal wildland fire agencies’ Landscape Fire and Resource Management Planning Tools (LANDFIRE) (GAP/LANDFIRE) [United States side] and the National Institute of Statistics and Geography (INEGI) [Mexico side] as well as land cover maps and opportunistic open-access and field observations. Mapping of the full BCR 33 region was carried out in two phases: 1) Phase I, the prototype map, covered a smaller portion of the transboundary area and identified 31 land cover classes, and 2) Phase II, the full BCR 33 map (refer to Figure 1), which resulted in 152 land cover classes. Using a Random Forest classifier, we achieved an overall prediction accuracy of 92% for the Phase I map and 87% for the Phase II full region map. This slight decrease can be attributed to working on a larger, more complex area with a greater number of land cover classes. No formal validation was conducted, aside from using a subset of the collected field observations and training data to assess model performance during and after training. The training sites were further verified using Google Earth (Google, 2026) imagery. Two undergraduate students who worked for over a year visually inspected imagery and open access public images to confirm each training site during model training using in-house developed, online, visual tools. A portion of this field training data was reserved for model validation, and the corresponding results are to be presented in later sections. The project developed an end-to-end, medium- and fine-resolution remote sensing–based data fusion mapping approach. This effort produced a map (Nagler et al., 2025) and the online tools to support a dynamic, live, online map for visualizing the transboundary vegetation communities in BCR 33. The toolset is currently hosted by the University of Arizona (UofA) Vegetation Index and Phenology (VIP) Lab to support FWS partners (https://vip.arizona.edu/viplab_data_explorer?LCM_BCR33). The online map is designed to allow rapid updates using new training, validation, or correction data, making it dynamic and maintainable. The approach we took established a framework for rapid updating and correction of land cover maps, as the model can be quickly retrained with new field observations, updated training data, or other sources. This enables dynamic mapping and change detection of the region’s vegetation. This framework is an advance in data fusion and crowdsourced mapping of complex, vulnerable regions, providing support to regional stakeholders and the wider user community. This transboundary map can inform the protection, conservation, and restoration of vegetation, habitat, and ecosystems, particularly for threatened and endangered species across the two nations using consistent and harmonized binational mapping systems. Beyond supporting land management decisions and stakeholders in the transboundary desert ecoregions, this BCR 33 mapping effort establishes a foundation for future rapid, low-cost, cross-border land cover mapping that can benefit and advance ecosystem management.

Arizona, Baja California, California, Nevada, Sina

Streams, springs, and volcanic lakes for volcano monitoring

Introduction Volcanic unrest can trigger appreciable change to surface waters such as streams, springs, and volcanic lakes. Magma degassing produces gases and soluble salts that are absorbed into groundwater that feeds streams and lakes. As magma ascends, the amount of heat and degassing will increase, and so will any related geochemical and thermal signal. Subsurface magma movement can cause pressurization that alters hydrostatic head and may induce groundwater discharge. Fluid-pressure changes have been linked to distal volcano-tectonic earthquakes (White and McCausland, 2016; Coulon and others, 2017) and phreatic eruptions (for example, Yamaoka and others, 2016). Clearly, changes in groundwater and surface waters are both indicators of unrest and clues to how and where magma is rising toward the surface. Where possible, it is prudent to incorporate real-time hydrologic data into multiparameter monitoring of restless volcanoes. Hydrologic dynamics can also be tracked by changes in groundwater levels that are commonly measured in shallow boreholes (see of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–K, 5 p., https://doi.org/10.3133/sir20245062k. ">chapter K , this volume, on boreholes; Hurwitz and Lowenstern, 2024). Although inferred to be common, relatively few volcano-hydrology anomalies are well documented, and many are essentially anecdotal (Newhall and others, 2001), reflecting the fact that high-resolution time series remain rare. Extreme examples include the 2008 eruption of Nevado del Huila, Colombia, where relatively minor phreatomagmatic eruptions were accompanied by expulsion of as much as 300 million cubic meters of groundwater from fissures high on the volcano (Worni and others, 2011), generating large lahars. Substantial decreases in flow rate from springs about 8 kilometers from the summit of Mayon Volcano, Philippines, have been noted before most eruptions in the 20th century (Newhall and others, 2001). Stream monitoring at Redoubt Volcano in 2009 allowed Werner and others (2012) to recognize that groundwater was unable to absorb (or scrub) the high flux of volcanic gas and that a high CO 2 /SO 2 precursor signal had been evident for 5 months prior to the eruption. A key to better interpreting hydrologic anomalies—or even identifying them—is therefore obtaining adequate baseline data. Most hydrologic monitoring at U.S. volcanoes has been accomplished by intermittent sampling surveys with annual or less frequent sampling (for example, https://hotspringchem.wr.usgs.gov/index.php ). More frequent sampling, however, generally is needed to establish reliable baselines. A recent hydrologic and hydrothermal monitoring experiment at 25 sites and 10 of the 12 level 4 (very high threat) volcanoes in the U.S. portion of the Cascade Range demonstrated that there is sufficient temporal variability in hydrothermal fluxes, even during quiescent periods, that one-time measurements will commonly have limited interpretive value (Crankshaw and others, 2018). Thus, surveys are best augmented with data from streamgages (for example, Evans and others, 2004; Bergfeld and others, 2008). Streamflow (water discharge) data allow measured temperature and specific conductance to be converted to heat and solute mass fluxes, which could be insightful parameters for detecting anomalous activity (McCleskey and others, 2012). At the Yellowstone Caldera, long-term monitoring of river solutes has allowed calculation of the chloride flux, a proxy for heat discharge (Hurwitz and others, 2007; McCleskey and others, 2016) from the subsurface magma. This is readily accomplished because data from streamgages are continuously recorded and archived by the U.S. Geological Survey (USGS) National Water Information System (NWIS) (USGS, 2024). Similar studies on stratovolcanoes or shield volcanoes would be scientifically useful, and yet are logistically challenging, requiring streamgages on numerous radial drainages complemented by either frequent manual sampling or numerous deployments of equipment to measure water temperature and specific conductance as a proxy for water chemistry. Another challenge is that some volcanic areas, especially shield volcanoes, are characterized by near-surface porous rocks and soils, such that surface streams are rare and replaced by distant, dilute large-volume springs with only a trace of any original volcanically sourced water (Manga, 2001; Hurwitz and others, 2021). Volcanic lakes are worthy of special attention for monitoring efforts, as their temperature and composition can provide evidence of increased flux of volatile-rich fluids from below. Quantifying changes in volatile and heat release from magma can be simpler in lakes than for volcanoes with radial drainages and no major lakes. Moreover, volcanic lakes pose a range of hazards themselves, including phreatomagmatic eruptions, debris flows, flank collapse, tsunamis, and toxic gas release (Mastin and Witter, 2000; Delmelle and others, 2015; Manville, 2015; Rouwet and others, 2015)—hazards that have historically been responsible for substantial loss of life at many volcanoes worldwide (Manville, 2015). Catastrophic CO 2 release at Lake Nyos, Cameroon, in 1986 suffocated about 1,750 people and about 3,500 livestock and was probably triggered by a large landslide into the gas-saturated lake (Kling and others, 1987; Evans and others, 1993). Gas-charged springs in Soda Bay within Clear Lake (California) have caused almost a dozen deaths to bathers in the past hundred years (ABC News, 2000). A 2005 example of lake overturn and abundant gas release was documented at Mount Chiginagak in Alaska (Schaefer and others, 2008) but did not result in any human casualties. Although thermally stratified lakes, which promote trapping of exsolved magmatic gas, tend to develop in tropical regions, the phenomenon can also arise where salinity creates meromixis (a condition in which a lake does not mix completely), as occurs in Mono Lake, California (Jellison and Melack, 1993; Jellison and others, 1998). If magma erupts or flows into a lake, the interaction between hot magma and cold water can be explosive (Mastin and others, 2004; Zimanowski and others, 2015) and substantially expand the area affected by the eruption. Another hazard is the breaching of crater rims by landslides triggered by volcanic and (or) seismic activity. Under some circumstances, substantial volumes of water can be displaced, leading to large floods and lahars. Late Holocene lake flooding from Aniakchak Crater in the Alaska Peninsula (Waythomas, 2022) and from Paulina Lake in Newberry Crater, Oregon (Chitwood and Jensen, 2000), caused by the failure of outlet sills, testify to the substantial hazards at lake-filled calderas. Several volcanic systems in the United States host lakes known to receive heat and gas from underlying magma. These lakes vary widely in area, depth, and chemical composition. Lakes are present at level 4 volcanoes, including Crater Lake and Newberry Volcano in Oregon; Yellowstone Caldera in Wyoming; Long Valley Caldera, Clear Lake volcanic field, Medicine Lake, and Salton Buttes in California; and Aniakchak Crater, Mount Katmai, Fisher Caldera, Mount Okmok, and Kaguyak Crater, among others, in Alaska. A water lake was present in Halemaʻumaʻu, the crater of Kīlauea, Hawai‘i (fig. F1), from October 2019 to December 2020. Level 3 volcanoes with lakes include Mono Lake volcanic field (Calif.), Mount Bachelor (Ore.), Ukinrek Maars and Mount Chiginagak (Alaska), and Soda Lake (Nevada). In addition, there are lakes at many levels 1 and 2 volcanoes. In the United States, there are no strongly acidic lakes that receive abundant input of magmatic gas, such as those found at Mount Ruapehu (New Zealand), Ijen and Kelud (Indonesia), and Poás (Costa Rica). Nevertheless, many contain fluids that provide clues to magmatic processes below. Since publication of a previous report on recommended instrumentation for volcano monitoring (Moran and others, 2008), continuous hydrologic monitoring has become increasingly feasible. However, changes in water pressure, temperature, and chemistry remain, in general, poorly studied phenomena at volcanoes (Sparks, 2003; National Academies of Sciences, Engineering, and Medicine, 2017). Recent efforts by the USGS have included the temporary study of Cascade Range volcanoes, which included frequent (15 minute to hourly) temporal sampling of temperature, depth, and conductivity (Crankshaw and others, 2018; Ingebritsen and Evans, 2019). At Yellowstone Caldera, many streamgages have now added thermistors and specific conductance sensors, allowing estimation of time-dependent chloride flux as a proxy for variations in subsurface heat flux (McCleskey and others, 2012, 2016). Efforts to better understand lakes have also accelerated, with bathymetric mapping and sampling carried out at several locations in the United States. Especially thorough work was done at Yellowstone Lake thanks to the Hydrothermal Dynamics of Yellowstone Lake (HD-YLAKE, https://hdylake.org ) project, funded primarily by the National Science Foundation. In addition to geophysical surveys and recovery of cores and other samples, HD-YLAKE investigations included remotely operated vehicle (ROV) investigations of hydrothermal vents on the lake floor (fig. F2). Data collected by the ROV provided a better understanding of the thermal and chemical influx from lake-bottom hydrothermal systems (Sohn and others, 2017). In this chapter, we focus on detecting changes in the chemistry, temperature, discharge, or water levels of streams, springs, and lakes that can be caused by seismicity, volumetric strains, or increases in gas flux associated with ascending magma. There is unavoidable overlap with other chapters of this report. Samples of water and gas can also be obtained in boreholes ( of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–K, 5 p., https://doi.org/10.3133/sir20245062k. ">chapter K , this volume; Hurwitz and Lowenstern, 2024), both shallow and deep. Gas monitoring ( of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–E, 11 p., https://doi.org/10.3133/sir20245062e.">chapter E , this volume; Lewicki and others, 2024) relies in part on samples from springs and wells, particularly where measurable gas plumes are absent. Water acts as a trigger and lubricant for landslides and sediment-rich floods, and so hydrology has obvious relevance for lahar monitoring, as discussed in of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–H, 6 p., https://doi.org/10.3133/sir20245062h. ">chapter H (this volume; Thelen and others, 2024). Shared situational awareness among scientists engaged in geophysical, gas, and hydrologic monitoring will improve overall understanding of the volcanic hazard.

Scientific Investigations Report

Monitoring marine eruptions

Introduction Submarine volcanoes produce much of the same seismicity and eruptive activity as subaerial volcanoes and can pose hazards to society. Although they can be monitored with similar techniques and methods as described in other chapters of this volume, their submerged location brings unique challenges. This chapter addresses these challenges and provides recommendations for monitoring volcanoes fully or partly in marine environments to meet the capabilities described in other chapters of this volume. The United States and its territories host dozens of submarine volcanoes with most (around 60) in the Commonwealth of the Northern Mariana Islands. Approximately 20 of the Northern Mariana Islands submarine volcanoes are known to be hydrothermally active, and 10 have confirmed eruptions since the 1950s (for example, Baker and others, 2008; Tepp and others, 2019a). Nine of those volcanoes were considered by the National Volcanic Threat Assessment (Ewert and others, 2018) to have a combination of eruptive type and summit depth that poses a higher risk of hazardous eruptions, although only one was listed as a moderate (level 3) threat. Other notable submarine volcanoes of interest to the United States that have historically erupted are Axial Seamount off the Washington State coast, Kamaʻehuakanaloa in Hawaiʻi, and Vailuluʻu seamount in American Samoa. All of these, however, have a low risk of hazards because of their depth (greater than 600 meters below sea level) and eruptive type and so are not included in the National Volcanic Threat Assessment. In addition to submarine volcanoes, the submerged flanks of island volcanoes can also be a source of hazardous submarine eruptions—for example, the 1877 eruption of Mauna Loa, Hawai‘i, in Kealakekua Bay (Wanless and others, 2006). The most notable submarine eruption in recent times was the 2022 eruption of Hunga Tonga–Hunga Haʻapai in Tonga, which was one of the largest eruptions on Earth in the past 100 years. It created a massive volcanic plume, unprecedented shock waves, and far-reaching tsunami (Lynett and others, 2022). Other recent submarine eruptions in the Pacific Ocean Basin have produced subaerial plumes that reached aircraft heights (Carey and others, 2014) and large pumice rafts that can affect marine traffic and harbors (for example, Jutzeler and others, 2014; Kornei, 2019). These examples illustrate the potential hazards of major submarine eruptions. Yet, submarine volcanoes are largely unmonitored, and many eruptions occur that are unnoticed or only identified hours or days afterward. Within U.S. territory, submarine volcanoes in the Northern Mariana Islands have been known to produce eruptive activity that can affect society. Reports from fishermen and other marine vessels in the Northern Mariana Islands have noted underwater explosions, sea-surface discoloration, and bubbling water, all of which are known to be signs of submarine volcanic activity. South Sarigan seamount, located about 160 kilometers (km) north of Saipan, erupted in 2010 from greater than 150 meters below the sea surface, resulting in a gas and ash plume that reached more than 11.9 km into the atmosphere (for example, Searcy, 2013; Embley and others, 2014), high enough to affect international air traffic. Precursory and co-eruptive seismicity was detected on the regional Northern Mariana Islands seismic network (Searcy, 2013) and on global monitoring instruments (Green and others, 2013). Monitoring of submarine volcanoes is best accomplished with marine-based instrumentation, which is also useful for monitoring small island volcanoes that may not have the land area necessary for comprehensive subaerial monitoring. The primary marine-based instrumentation used for submarine volcanoes includes ocean-bottom pressure sensors to assess sea-floor deformation, ocean-bottom seismometers (OBSs) to detect seismicity, and both moored and ocean-bottom hydrophones to detect submarine explosions. Other sensors offer important monitoring data, such as turbidity, temperature, and chemistry of hydrothermal emissions. Marine-based instruments are typically deployed in campaign-style networks with no real-time telemetry owing to cost considerations and technical limitations. However, when necessary, marine instruments can be operated in real time using cables to transmit data to land-based facilities; other technologies for this purpose are in use or in development, such as acoustic transmission from the instrument to a moored buoy (Matsumoto and others, 2016) and a winch-based system with a satellite antenna that is part of the instrument mooring (Matsumoto and others, 2019). Emerging technologies for marine-based monitoring may be considered as part of a future monitoring plan. These technologies include ocean gliders and floats with on-board hydrophones that have been used to record earthquakes and submarine eruptions (for example, Matsumoto and others, 2013; Sukhovich and others, 2015) and fiber-optic cables that have been used as strainmeters to detect earthquakes (for example, Marra and others, 2018; Lindsey and others, 2019). Land-based instruments and satellites can also provide some capability for monitoring submarine volcanoes, but they provide more limited observations than marine-based instrumentation.

Scientific Investigations Report

ShakeAlert®—Communication, education, outreach and technical engagement strategic vision

Executive Summary In 2006, the U.S. Geological Survey (USGS) began directly supporting ShakeAlert ® research and in 2012 the ShakeAlert demonstration system began testing ( Given and others, 2018 ). The ShakeAlert earthquake early warning (EEW) system is a partnership between the U.S. Geological Survey (USGS) and the three West Coast States (Washington, Oregon, and California) served by the ShakeAlert System, which is part of the larger Advanced National Seismic System (ANSS). With more than 143 million people exposed to potentially damaging shaking in the United States ( Jaiswal and others, 2015 ), earthquakes are a national hazard. Most of our Nation’s earthquake risk is concentrated in the highly populated areas on the active plate tectonic boundaries on the West Coast of the conterminous United States. ShakeAlert is the first public alert system in the United States to provide rapid mass notification of earthquake detection, potentially offering seconds of warning before strong shaking arrives. A few seconds may not seem like much time, but the information in ShakeAlert Messages can be used to trigger automated actions that can prevent injury or death, reduce immediate damage, and speed recovery from earthquakes. The information product issued by the ShakeAlert system is called a ShakeAlert Message and is one of the information products and tools of the ANSS. The ShakeAlert System includes the USGS component, plus the pathways by which ShakeAlert-powered products and (or) services are delivered to end users. Alerts can be delivered to cell phones or be used to trigger automated systems to protect equipment, facilities, and infrastructure, such as slowing or stopping a train. ShakeAlert-powered automated actions can include fire house doors that can be opened to prevent jamming, heavy equipment (for example, trains, elevators, and cranes) that can be automatically stopped or parked in safe positions, and pipeline valves that can be closed to prevent surges and spills. A few seconds of warning also may be sufficient for people to take protective actions, such as drop, cover, and hold on or modified protective actions for a broad range of populations. Advance training may increase the benefit of a speedy response to an alert. Outreach and education about EEW may raise awareness of the overall earthquake threat and how people can best react when they receive an alert or feel shaking. ShakeAlert communication, education, outreach, and technical engagement (CEO&TE) efforts are highly collaborative and essential for the success of the ShakeAlert System. This strategic vision informs how the vast ShakeAlert CEO&TE Community operates and works together. The CEO&TE Community delineates a strategic framework that is intended to set the path for a long-term, sustainable approach to CEO&TE through three focus areas and five priorities. Focus Areas Technical engagement.— The objective of this focus area is to expand and broaden ShakeAlert technical engagement and implementation. External engagement.— This focus area targets engagement in long-term communication, education, and outreach planning, implementation, and evaluation. Internal engagement.— The purpose of this focus area is to build and sustain a robust infrastructure to optimize collaboration, information sharing, and project planning among the community of stakeholders charged with implementing ShakeAlert CEO&TE. Priorities The enumeration of the five priorities listed below does not suggest priority ranking. Public safety, preparedness, and resilience; Technical implementation and engagement; Consistent messaging and communication; Integration with other Federal and State earthquake hazards products; and Educational resources development and dissemination. This strategic vision is a tangible outcome of collaboration among many stakeholders beginning in July 2016. Since then, the work of the ShakeAlert CEO&TE Community has grown into an international effort. The USGS has developed, tested, and implemented a broad spectrum of communication, education, and outreach tools and resources—all of which recognize that seconds matter when it comes to safety and mitigating harm from earthquake hazards. The CEO&TE social science research effort has provided invaluable insights into the ShakeAlert System’s human interface. USGS-licensed technical partners develop, test, and implement real-world applications using ShakeAlert Messages. The success of ShakeAlert CEO&TE efforts is predicated on robust collaboration across numerous agencies, organizations, and groups. As such, this strategic vision outlines a “partnership model” that delineates roles and responsibilities to ensure alignment with focus areas and priorities. The partnership model includes the CEO&TE lead agency (USGS); its principal partners (State agencies and university partners); its implementation partners (for example, technical partners who build systems to deliver ShakeAlert-powered products and (or) services [focus area one]), earthquake education partners who work to increase public preparedness for seismic events (focus area two); and other organizations that work together to enhance the adoption and effectiveness of the ShakeAlert System. These partners collaborate and convene through a variety of working groups and forums, which are also described in this strategic vision and align with focus area three (internal engagement). The CEO&TE Community collaboratively developed its operating principles and a consensus-based, decision-making strategic framework to guide its collective work. Performance metrics are used to continually measure success. Ultimately, the USGS and ShakeAlert CEO&TE Community are advancing the ShakeAlert System that as of the publication of this strategic vision to “provide earthquake early warning for all” serves more than 50 million people.

Circular

Capitalization of positional (Lower/Middle/Upper) and temporal (Early/Middle/Late) adjectives in the names of formal chronostratigraphic and geochronologic units of the Phanerozoic

Many authors are understandably confused about the capitalization of the words “lower,” “middle,” “upper,” “early,” and “late.” Where these words are used simply as descriptive adjectives, they should be in lowercase; where they form the first word of a formal chronostratigraphic or geochronologic unit name, they should be in uppercase.

Professional Paper

The effects of the Chesapeake Bay impact crater on the geological framework and correlation of hydrogeologic units of the lower York-James Peninsula, Virginia

This report documents the highly variable structure, stratigraphy, and buried topography of the outer rim of the Chesapeake Bay impact crater created by its impact and burial. Lithologies of cores are correlated with borehole geophysical logs to characterize the physical properties of the stratigraphic units and their geophysical signatures. The correlation between cores, well cuttings, and borehole geophysical logs is augmented with seismic-reflection data, and these data are compiled into a lithostratigraphic cross section that illustrates the geological framework of the lower York-James Peninsula and immediate surrounding areas.

Virginia

Methodology for construction of a three-layer geologic model of the conterminous United States using land surface, top of bedrock, and top of basement

This report describes the methodology used for the construction of a digital three-layer geologic model of the conterminous United States by mapping the altitude of three surfaces: land surface, the top of bedrock, and the top of basement. These surfaces are mapped through the compilation and synthesis of published stratigraphic horizons from numerous topical studies. The mapped surfaces create a three-layer geologic model with three geomaterial-based subdivisions: unconsolidated to weakly consolidated sediment; layered consolidated rock strata that constitute bedrock; and crystalline rocks that are described as “basement,” consisting of either igneous, metamorphic, or highly deformed rocks. The data compilation and synthesis are highly dependent on the definition of the informal terms “bedrock” and “basement,” which may describe different ages or types of rock in different parts of the conterminous United States. This report presents the conceptualization of the three mapped layers, describes the datasets used, and summarizes the decisions made while compiling the three-layer model from the various sources. This digital dataset was created as part of efforts by the U.S. Geological Survey to develop subsurface geologic data in geospatial form as part of a broad directive to develop two-dimensional and three-dimensional geologic information at detailed, national, and continental scales. This digital dataset partly fulfills the goal of the U.S. Geological Survey’s National Cooperative Geologic Mapping Program to construct a national-scale three-dimensional geologic model.

conterminous United States

Satellite imagery of the north-central Gulf of Mexico, June 1993-May 1997

This CD contains imagery collected by the Advanced Very High Resolution Radiometer (AVHRR) on the NOAA polar-orbiting weather satellites. The AVHRR provides almost daily coverage of a site at a resolution of approximately 1 km. The data types included are sea surface temperature (SST), water reflectance (REF), and a false-color infrared overview (FCI).

Alabama, Florida, Louisiana, Mississippi

Production of mineral commodities and geospatial map of the mineral industries and related infrastructure of China

As part of the U.S. Geological Survey’s (USGS) mission to distribute global mineral information and analyze supply chains, this study provides a comprehensive review of the global significance of China’s mineral production and capacity in 2023. Of 77 mineral commodities in the USGS dataset, China produced 74 and was the world’s first-ranked producer for 39 of the 74. Compared to the high share of global mineral production, including up to 98 percent of global gallium production, the country’s share of global mineral reserves was relatively small, ranging from 20 percent (zinc ore) to 52 percent (tungsten ore). China’s imports of metal ores, slag, and ash accounted for 64 percent of global imports of such commodities by value. The country’s exports of base metals and articles of base metal accounted for 17 percent of the global exports. To help nongeographic information system users assess the spatial distribution of mineral mines, processing facilities, and ports for trades in China, this study created a geospatial (also called “georeferenced”) portable document format (GeoPDF) map. In addition, the GeoPDF contains mineral resource tracts (such as antimony, copper, potash, coal, and oil and gas), exploration sites, and energy infrastructure based on the preexisting USGS data.

Open-File Report