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Interlaboratory comparability, bias, and precision for four laboratories measuring constituents in precipitation, November 1982-August 1983

Four laboratories were evaluated in their analysis of identical natural and simulated precipitation water samples. Interlaboratory comparability was evaluated using analysis of variance coupled with Duncan 's multiple range test, and linear-regression models describing the relations between individual laboratory analytical results for natural precipitation samples. Results of the statistical analyses indicate that certain pairs of laboratories produce different results when analyzing identical samples. Analyte bias for each laboratory was examined using analysis of variance coupled with Duncan 's multiple range test on data produced by the laboratories from the analysis of identical simulated precipitation samples. Bias for a given analyte produced by a single laboratory has been indicated when the laboratory mean for that analyte is shown to be significantly different from the mean for the most-probable analyte concentrations in the simulated precipitation samples. Ion-chromatographic methods for the determination of chloride, nitrate, and sulfate have been compared with the colorimetric methods that were also in use during the study period. Comparisons were made using analysis of variance coupled with Duncan 's multiple range test for means produced by the two methods. Analyte precision for each laboratory has been estimated by calculating a pooled variance for each analyte. Analyte estimated precisions have been compared using F-tests and differences in analyte precisions for laboratory pairs have been reported. (USGS)

Water-Resources Investigations Report↗

Geohydrology of parts of Muhlenberg, Ohio, Butler, McLean, Todd, and Logan counties, Kentucky

Water-level, water-use, water-quality, and aquifer-yield data were collected during a well inventory in 1991 in part of western Kentucky. The data were overlaid on digital maps, using a Geographic Information System, to interpret the geohydrologic conditions within the study area. The discontinuous lithology of rocks in the area results in aquifers of limited areal extent in which local ground-water flow systems are developed; however, the regional ground-water flow generally is toward the broad alluvial areas along the Green and Rough Rivers. Fewer wells were in use in 1991 than in the 1960's when a similar well inventory was conducted; this decrease is probably due to expansion of service areas of several public water-supply systems. The quality of ground water is generally suitable for domestic use, except for a few wells that produce water with low pH and high concentrations of metals. The specific capacity of wells was found to range from 0.08 to 0.3 gallons per minute, per foot of draw- down. This range is somewhat less than values previously reported.

Water-Resources Investigations Report↗

Estimated freshwater withdrawals in Texas, 1990

This report presents 1990 freshwater withdrawal estimates for Texas by source and category. Withdrawal source is either ground water or surface water. Withdrawal categories include: self-supplied irrigation, thermoelectric-power generation, water supply, industrial and mining, and other (domestic, commercial, livestock). Withdrawal data are aggregated by county, major aquifer, and principal river basin. Only the four major categories of irrigation, thermoelectric-power generation, water supply, and industrial and mining are illustrated in this report, although all data are tabulated.

Texas↗

Field techniques for fluorescence measurements targeting dissolved organic matter, hydrocarbons, and wastewater in environmental waters: Principles and guidelines for instrument selection, operation and maintenance, quality assurance, and data reporting

The use of field deployable fluorescence sensors by the U.S. Geological Survey has become increasingly common for a wide variety of surface water and groundwater investigations. This report addresses field deployable fluorometers that measure the fluorescence response of various substances in water exposed to incident light generated by the sensor. An introduction to the basic principles of field measurements of fluorescence is provided, as well as technical background information on sensors that target dissolved organic matter, wastewater, and hydrocarbons, including sensor selection, operating principles, key features, and design elements. General deployment, operation and maintenance protocols, quality-assurance techniques, and suggestions for data reporting are presented to facilitate and standardize the collection and accurate communication of data collected by the U.S. Geological Survey across studies, sites, and sensor types. Sensor performance issues and common interferences are also described. An appendix is included to describe sensor calibration criteria and procedures, reporting units, and specific approaches to correct for interferences for fluorescence of dissolved organic matter sensors.

Techniques and Methods↗

Guidelines for Evaluating Ground-Water Flow Models

Ground-water flow modeling is an important tool frequently used in studies of ground-water systems. Reviewers and users of these studies have a need to evaluate the accuracy or reasonableness of the ground-water flow model. This report provides some guidelines and discussion on how to evaluate complex ground-water flow models used in the investigation of ground-water systems. A consistent thread throughout these guidelines is that the objectives of the study must be specified to allow the adequacy of the model to be evaluated.

Scientific Investigations Report↗

Precipitation-runoff processes in the Feather River basin, northeastern California, and streamflow predictability, water years 1971-97

Precipitation-runoff processes in the Feather River Basin of northern California determine short- and long-term streamflow variations that are of considerable local, State, and Federal concern. The river is an important source of water and power for the region. The basin forms the headwaters of the California State Water Project. Lake Oroville, at the outlet of the basin, plays an important role in flood management, water quality, and the health of fisheries as far downstream as the Sacramento-San Joaquin Delta. Existing models of the river simulate streamflow in hourly, daily, weekly, and seasonal time steps, but cannot adequately describe responses to climate and land-use variations in the basin. New spatially detailed precipitation-runoff models of the basin have been developed to simulate responses to climate and land-use variations at a higher spatial resolution than was available previously. This report characterizes daily rainfall, snowpack evolution, runoff, water and energy balances, and streamflow variations from, and within, the basin above Lake Oroville. The new model's ability to predict streamflow is assessed. The Feather River Basin sits astride geologic, topographic, and climatic divides that establish a hydrologic character that is relatively unusual among the basins of the Sierra Nevada. It straddles a north-south geologic transition in the Sierra Nevada between the granitic bedrock that underlies and forms most of the central and southern Sierra Nevada and volcanic bedrock that underlies the northernmost parts of the range (and basin). Because volcanic bedrock generally is more permeable than granitic, the northern, volcanic parts of the basin contribute larger fractions of ground-water flow to streams than do the southern, granitic parts of the basin. The Sierra Nevada topographic divide forms a high altitude ridgeline running northwest to southeast through the middle of the basin. The topography east of this ridgeline is more like the rain-shadowed basins of the northeastern Sierra Nevada than the uplands of most western Sierra Nevada river basins. The climate is mediterranean, with most of the annual precipitation occurring in winter. Because the basin includes large areas that are near the average snowline, rainfall and rain-snow mixtures are common during winter storms. Consequently, the overall timing and rates of runoff from the basin are highly sensitive to winter temperature fluctuations. The models were developed to simulate runoff-generating processes in eight drainages of the Feather River Basin. Together, these models simulate streamflow from 98 percent of the basin above Lake Oroville. The models simulate daily water and heat balances, snowpack evolution and snowmelt, evaporation and transpiration, subsurface water storage and outflows, and streamflow to key streamflow gage sites. The drainages are modeled as 324 hydrologic-response units, each of which is assumed homogeneous in physical characteristics and response to precipitation and runoff. The models were calibrated with emphasis on reproducing monthly streamflow rates, and model simulations were compared to the total natural inflows into Lake Oroville as reconstructed by the California Department of Water Resources for April-July snowmelt seasons from 1971 to 1997. The models are most sensitive to input values and patterns of precipitation and soil characteristics. The input precipitation values were allowed to vary on a daily basis to reflect available observations by making daily transformations to an existing map of long-term mean monthly precipitation rates that account for altitude and rain-shadow effects. The models effectively simulate streamflow into Lake Oroville during water years (October through September) 1971-97, which is demonstrated in hydrographs and statistical results presented in this report.

Northeastern California↗

Water Resources of the Basin and Range Carbonate-Rock Aquifer System, White Pine County, Nevada, and Adjacent Areas in Nevada and Utah

INTRODUCTION This report summarizes results of a water-resources study for White Pine County, Nevada, and adjacent areas in east-central Nevada and western Utah. The Basin and Range carbonate-rock aquifer system (BARCAS) study was initiated in December 2004 through Federal legislation (Section 301(e) of the Lincoln County Conservation, Recreation, and Development Act of 2004; PL108-424) directing the Secretary of the Interior to complete a water-resources study through the U.S. Geological Survey, Desert Research Institute, and State of Utah. The study was designed as a regional water-resource assessment, with particular emphasis on summarizing the hydrogeologic framework and hydrologic processes that influence ground-water resources. The study area includes 13 hydrographic areas that cover most of White Pine County; in this report however, results for the northern and central parts of Little Smoky Valley were combined and presented as one hydrographic area. Hydrographic areas are the basic geographic units used by the State of Nevada and Utah and local agencies for water-resource planning and management, and are commonly defined on the basis of surface-water drainage areas. Hydrographic areas were further divided into subbasins that are separated by areas where bedrock is at or near the land surface. Subbasins are the subdivisions used in this study for estimating recharge, discharge, and water budget. Hydrographic areas are the subdivision used for reporting summed and tabulated subbasin estimates.

Scientific Investigations Report↗

Identification and evaluation of scientific uncertainties related to fish and aquatic resources in the Colorado River, Grand Canyon - summary and interpretation of an expert-elicitation questionnaire

Identifying areas of scientific uncertainty is a critical step in the adaptive management process (Walters, 1986; Runge, Converse, and Lyons, 2011). To identify key areas of scientific uncertainty regarding biologic resources of importance to the Glen Canyon Dam Adaptive Management Program, the Grand Canyon Monitoring and Research Center (GCMRC) convened Knowledge Assessment Workshops in May and July 2005. One of the products of these workshops was a set of strategic science questions that highlighted key areas of scientific uncertainty. These questions were intended to frame and guide the research and monitoring activities conducted by the GCMRC in subsequent years. Questions were developed collaboratively by scientists and managers. The questions were not all of equal importance or merit—some questions were large scale and others were small scale. Nevertheless, these questions were adopted and have guided the research and monitoring efforts conducted by the GCMRC since 2005. A new round of Knowledge Assessment Workshops was convened by the GCMRC in June and October 2011 and January 2012 to determine whether the research and monitoring activities conducted since 2005 had successfully answered some of the strategic science questions. Oral presentations by scientists highlighting research findings were a centerpiece of all three of the 2011–12 workshops. Each presenter was also asked to provide an answer to the strategic science questions that were specific to the presenter’s research area. One limitation of this approach is that these answers represented the views of the handful of scientists who developed the presentations, and, as such, they did not incorporate other perspectives. Thus, the answers provided by presenters at the Knowledge Assessment Workshops may not have accurately captured the sentiments of the broader group of scientists involved in research and monitoring of the Colorado River in Glen and Grand Canyons. Yet a fundamental ingredient of resilient decisionmaking and problem-solving is incorporation of a wide range of perspectives (Carpenter and others, 2009). To ensure that a wide range of scientists had an opportunity to weigh in on the strategic science questions, the GCMRC elicited additional perspectives through written questionnaires. Independently soliciting responses from scientists through questionnaires had the added advantage of allowing all scientists to freely and openly share their views on complex and controversial topics—something which may not have occurred in the group setting of the June 2011 Knowledge Assessment Workshop because of dominance by one or more scientists. The purpose of this report is to document and interpret the questionnaire responses.

Arizona↗

Flood profiles of the Pithlachascotee River, west-central Florida

Data defining the magnitude and frequency of flooding are provided for a nontidal 16-mile reach of the Pithlachascotee River in Florida. These data include areal flood-frequency relations and flood heights for the 2-, 2.33-, 5-, 10-, 25-, 50- , 100-, 200-, and 500-year recurrence intervals. Flood profiles are provided for the 2.33-, 5-, 10-, 100-, and 500-year recurrence intervals. Study results indicate that flood discharges in the study area are highly variable and are one-third to one-half of regional estimates. Differences between study area and regional estimates are due to large quantities of flood-water drainage to the regional aquifer system in the upper basin, a large karst area of about 138 square miles. Graded roads and bridges located at three sites along the upper study reach will be inundated by various frequency floods. Flood inundation maps can be prepared from flood data presented in this report.

Florida↗

Hydro-Climatic Data Network (HCDN) Streamflow Data Set, 1874-1988

The potential consequences of climate change to continental water resources are of great concern in the management of those resources. Critically important to society is what effect fluctuations in the prevailing climate may have on hydrologic conditions, such as the occurrence and magnitude of floods or droughts and the seasonal distribution of water supplies within a region. Records of streamflow that are unaffected by artificial diversions, storage, or other works of man in or on the natural stream channels or in the watershed can provide an account of hydrologic responses to fluctuations in climate. By examining such records given known past meteorologic conditions, we can better understand hydrologic responses to those conditions and anticipate the effects of postulated changes in current climate regimes. Furthermore, patterns in streamflow records can indicate when a change in the prevailing climate regime may have occurred in the past, even in the absence of concurrent meteorologic records. A streamflow data set, which is specifically suitable for the study of surface-water conditions throughout the United States under fluctuations in the prevailing climatic conditions, has been developed. This data set, called the Hydro-Climatic Data Network, or HCDN, consists of streamflow records for 1,659 sites throughout United States and its Territories. Records cumulatively span the period 1874 through 1988, inclusive, and represent a total of 73,231 water years of information. Development of the HCDN Data Set: Records for the HCDN were obtained through a comprehensive search of the extensive surface- water data holdings of the U.S. Geological Survey (USGS), which are contained in the USGS National Water Storage and Retrieval System (WATSTORE). All streamflow discharge records in WATSTORE through September 30, 1988, were examined for inclusion in the HCDN in accordance with strictly defined criteria of measurement accuracy and natural conditions. No reconstructed records of 'natural flow' were permitted, nor was any record extended or had missing values 'filled in' using computational algorithms. If the streamflow at a station was judged to be free of controls for only a part of the entire period of record that is available for the station, then only that part was included in the HCDN, but only if it was of sufficient length (generally 20 years) to warrant inclusion. In addition to the daily mean discharge values, complete station identification information and basin characteristics were retrieved from WATSTORE for inclusion in the HCDN. Statistical characteristics, including the monthly mean discharge, as well as the annual mean, minimum and maximum discharge values, were derived for the records in the HCDN data set. For a full description of the development and content of the Hydro-Climatic Data Network, please take a look at the HCDN Report.

Water-Resources Investigations Report↗

Estimated withdrawals and use of freshwater in New Hampshire, 1990

Estimated freshwater withdrawals during 1990 in New Hampshire totaled about 422 million gallons per day from ground-water and surface-water sources. The largest withdrawals were for thermoelectric-power generation (60 percent), public supply (23 percent), and industrial use (9 percent). Most withdrawals, 358 million gallons per day, were made from surface- water sources, as compared to 63.7 million gallons per day from ground-water sources. The largest with- drawals were in the Merrimack river basin (322 million gallons per day). An additional 46,000 million gallons per day was used instream for hydroelectric-power generation, primarily in the Upper Androscoggin and Upper Connecticut River subbasins. Other information describing water-use patterns is shown in tables, bar graphs, pie charts, maps, and accompanying text. The data are aggregated by river basin (hydrologic cataloging unit), and all values are reported in million gallons per day.

Water-Resources Investigations Report↗

Estimated withdrawals and use of freshwater in Vermont, 1990

Estimated freshwater withdrawals during 1990 in Vermont totaled about 632 million gallons per day. The largest withdrawals were for thermoelectric- power generation (82 percent), industrial use (7 percent), and public supply (6 percent). Most withdrawals, 587 million gallons per day, were made from surface-water sources as compared to 44.9 million gallons per day from ground-water sources. The largest withdrawals were in the Upper Connecticut-Mascomo River Basin (525 million gallons per day). About 17,700 million gallons per day were used instream for hydroelectric-poser generation, the largest of which were in the Upper Connecticut-Mascoma and Otter River Basins. Other information describing water-use patters is shown in tables, bar graphs, pie charts, maps, and accompanying text. The data are aggregated by river basin (hydrologic cataloging unit), and all amounts are reports in million gallons per day.

Vermont↗

Quality of surface water and ground water in the proposed artificial-recharge project area, Rillito Creek basin, Tucson, Arizona, 1994

Controlled artificial recharge of surface runoff is being considered as a water-management technique to address the problem of ground-water overdraft. The planned use of recharge facilities in urban areas has caused concern about the quality of urban runoff to be recharged and the potential for ground-water contamination. The proposed recharge facility in Rillito Creek will utilize runoff entering a 1-mile reach of the Rillito Creek between Craycroft Road and Swan Road for infiltration and recharge purposes within the channel and excavated overbank areas. Physical and chemical data were collected from two surface-water and two ground-water sites in the study area in 1994. Analyses of surface-water samples were done to determine the occurrence and concentration of potential contaminants and to determine changes in quality since samples were collected during 1987-93. Analyses of ground-water samples were done to determine the variability of ground-water quality at the monitoring wells throughout the year and to determine changes in quality since samples were collected in 1989 and 1993. Surface-water samples were collected from Tanque Verde Creek at Sabino Canyon Road (streamflow-gaging station Tanque Verde Creek at Tucson, 09484500) and from Alamo Wash at Fort Lowell Road in September and May 1994, respectively. Ground-water samples were collected from monitoring wells (D- 13-14)26cbb2 and (D-13-14)26dcb2 in January, May, July, and October 1994. In surface water, calcium was the dominant cation, and bicarbonate was the dominant anion. In ground water, calcium and sodium were the dominant cations and bicarbonate was the dominant anion. Surface water in the area is soft, and ground water is moderately hard to hard. In surface water and ground water, nitrogen was found predominantly as nitrate. Concentrations of manganese in ground-water samples ranged from 60 to 230 micrograms per liter and exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level for drinking water of 50 micrograms per liter. None of the constituents in surface-water and ground-water samples exceeded the U.S. Environmental Protection Agency primary maximum contaminant levels for drinking water or State of Arizona aquifer water-quality standards. Concentrations of major ions, nutrients, and trace elements in water from the monitoring wells did not vary significantly throughout the year and were not significantly different from concentrations in samples collected in March 1989 and January and September 1993. Priority pollutants were not found in surface-water samples or ground-water samples, and organochlorine pesticides were not found in ground-water samples. Dieldrin and biphenyl polychlor were the only pesticides found in surface water and were at the minimum reporting levels in one sample from Alamo Wash.

Water-Resources Investigations Report↗

Effects of highway deicing chemicals on shallow unconsolidated aquifers in Ohio, interim report, 1988-93

Effects of the application of highway deicing chemicals during winter months on ground- water quality are being studied by the U.S. Geological Survey in cooperation with the Ohio Department of Transportation and the Federal Highway Administration. Eight sites throughout the State were selected along major undivided highways where drainage is by open ditches and ground-water flow is approximately perpendicular to the highway. At these sites, records of deicer application rates are being kept and apparent movement of deicing chemicals through shallow, unconsolidated aquifers is being monitored by means of periodic measurements of specific con ductance and concentrations of dissolved sodium, calcium, and chloride. The counties and corre sponding sections of state routes being monitored are the following: State Route (SR) 3 in Ashland County, SR 84 in Ashtabula County, SR 29 in Champaign County, SR 4 in Clark County, SR 2 in Lucas County, SR 104 in Pickaway County, SR 14 in Portage County, and SR 97 in Richland County. The study began in January 1988 with background data collection, extensive literature review, and site selection. This process, including drilling of wells at the eight selected sites, lasted 3 years. Routine ground-water sampling at 4- to 6-week intervals began in January 1991. A relatively new type of multilevel, passive flow ground-water sampling device was constructed and used. Other conditions monitored on a regular basis included ground-water level (monitored con tinuously), specific conductance, air and soil temperature, precipitation, chloride concentration in soil samples, ground conductivity, and deicing chemical application times and rates. For the interim reporting period, water samples were collected from January 1991 through September 1993. Evidence from water analysis, specific conductance measurements, and surface geophysical measurements indicates that four of the eight sites (Ashtabula County, Lucas County, Portage County, and Richland County sites) are potentially affected by direct application of deic ing chemicals. Climatic data from the period January 1991 through September 1993 show that cold weather, and therefore deicing chemical application rates, varied widely across the State. As a consequence, only minor traces of dissolved chloride above background concentrations (mean, 12-25 mg/L) were determined in ground-water samples from the Pickaway County, Clark County, and Champaign County sites. At the Ashland and Richland County sites, dissolved chlo ride concentrations increased above background concentrations (from the upgradient well, pre sumably unaffected by road salt) only intermittently (mean background concentrations of 3-25 mg/L, rising to a mean of 49-77 mg/L). For the interim reporting period, the mean dissolved chloride concentration for all downgradient wells was about 2 times the background concentra tion (25mg/L) at the Ashland County site (50 mg/L) and 14 times the background concentration (3 mg/L) at the Richland County site (40 mg/L). At the Lucas County, Portage County, and Ash tabula County sites, deicing-chemical application was consistent throughout the winter, and downgradient dissolved chloride concentrations rarely returned to background concentrations (mean 6-32 mg/L) throughout the period. For the interim reporting period, the mean dissolved chloride concentration for all downgradient wells was about 3 times the background concentra tion at the Lucas County site (92 mg/L), 72 times the background concentration at the Portage County site (432 mg/L, 2 downgradient wells), and 21 times the background concentration at the Ashtabula County site (279 mg/L). Other factors that may affect the movement of deicing chemicals through the aquifer were examined, such as precipitation amounts; the types of subsurface materials; ground-water velocity and gradient; hydraulic conductivity; soil type; land use; and ODOT deicing priority. A final report is planned for 2001 afte

Ohio↗

Water-quality trends in the Santa Ana River at MWD Crossing and below Prado Dam, Riverside County, California

The Santa Ana River, located in an extensively urbanized basin, drains about 2,670 square miles near Los Angeles, California. Almost all flow in the river, about 200,000 acre-feet annually, is diverted to ponds where it infiltrates and recharges underlying aquifers. About 2 million people are dependent on these aquifers for water supply. In recent years, base flow in the river has increased as a result of increased discharge of treated municipal wastewater, and high flows have increased as a result of increase precipitation and urbanization. Trends in water quality were calculated for two sites?at the Metropolitan Water District (MWD) Crossing (an upstream site) and below Prado Dam (a downstream site)?using the computer program ESTREND. Water-quality data for these sites were collected by the U.S. Geological Survey from 1969 to 1995. At MWD Crossing, flow-adjusted downward trends of -1.1 microsiemens per centimeter (iS/cm) per year and -1.6 milligrams per liter (mg/L) per year were calculated for specific conductance and dissolved solids, respectively. In contrast, a flow-adjusted upward trends of 2.2 iS/cm per year for dissolved solids was calculated for the Santa Ana River below Prado Dam. Specific conductance and dissolved solids in the Santa Ana River below Prado Dam had downward unadjusted trends (not adjusted for streamflow) of -8.3 iS/cm per year and -6.0 mg/L per year, respectively. For the Santa Ana River below Prado Dam, downward unadjusted trends were calculated for ammonia (-0.04 mg/L per year) and total organic carbon (0.19 mg/L per year); flow-adjusted upward trends were calculated for nitrite plus nitrate (0.15 mg/L per year), total dissolved nitrogen (0.39 mg/L per year), and orthophosphate (0.03 mg/L per year). Statistically significant unadjusted and flow-adjusted trends were not obtained for organic nitrogen, phosphorus, and dissolved organic carbon. Data for selected trace elements and organic compounds collected between 1970-94 also are summarized in this report.

Water-Resources Investigations Report↗