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At least 505 records · Page 28Linked to original sources

Processes affecting the fate of monoaromatic hydrocarbons in an aquifer contaminated by crude oil

Crude oil spilled from a subsurface pipeline in north-central Minnesota has dissolved in the groundwater, resulting in the formation of a plume of aliphatic, aromatic, and alicyclic hydrocarbons. Comparison of paired oil and groundwater samples collected along the central axis of the residual oil body shows that the trailing edge of the oil is depleted in the more soluble aromatic hydrocarbons (e.g., benzene, toluene, etc.) when compared with the leading edge. At the same time, concentrations of monoaromatic hydrocarbons in groundwater beneath the oil increase as the water moves toward the leading edge of the oil. Immediately downgradient from the leading edge of the oil body, certain aromatic hydrocarbons (e.g., benzene) are found at concentrations near those expected of a system at equilibrium, and the concentrations exhibit little variation over time (???8-20%). Other compounds (e.g., toluene) appear to be undersaturated, and their concentrations show considerably more temporal variation (???20-130%). The former are persistent within the anoxic zone downgradient from the oil, whereas concentrations of the latter decrease rapidly. Together, these observations suggest that the volatile hydrocarbon composition of the anoxic groundwater near the oil body is controlled by a balance between dissolution and removal rates with only the most persistent compounds reaching saturation. Examination of the distributions of homologous series and isomeric assemblages of alkylbenzenes reveals that microbial degradation is the dominant process controlling the fate of these compounds once groundwater moves away from the oil. For all but the most persistent compounds, the distal boundary of the plume at the water table extends no more than 10-15 m down-gradient from the oxic/anoxic transition zone. Thus, transport of the monoaromatic hydrocarbons is limited by redox conditions that are tightly coupled to biological degradation processes.

Environmental Science & Technology↗

Integrating hydrologic and geophysical data to constrain coastal surficial aquifer processes at multiple spatial and temporal scales

Since 1997, repeated, coincident geophysical surveys and extensive hydrologic studies in shallow monitoring wells have been used to study static and dynamic processes associated with surface water-groundwater interaction at a range of spatial scales at the estuarine and ocean boundaries of an undeveloped, permeable barrier island in the Georgia part of the U.S. South Atlantic Bight. Because geophysical and hydrologic data measure different parameters, at different resolution and precision, and over vastly different spatial scales, reconciling the coincident data or even combining complementary inversion, hydrogeochemcial analyses and well-based groundwater monitoring, and, in some cases, limited vegetation mapping to demonstrate the utility of an integrative, multidisciplinary approach for elucidating groundwater processes at spatial scales (tens to thousands of meters) that are often difficult to capture with traditional hydrologic approaches. The case studies highlight regional aquifer characteristics, varying degrees of lateral saltwater intrusion at estuarine boundaries, complex subsurface salinity gradients at the ocean boundary, and imaging of submarsh groundwater discharge and possible free convection in the pore waters of a clastic marsh. This study also documents the use of geophysical techniques for detecting temporal changes in groundwater salinity regimes under natural (not forced) gradients at intratidal to interannual (1998-200 Southeastern U.S.A. drought) time scales.

Book chapter↗

Macroscale water fluxes 3. Effects of land processes on variability of monthly river discharge

A salient characteristic of river discharge is its temporal variability. The time series of flow at a point on a river can be viewed as the superposition of a smooth seasonal cycle and an irregular, random variation. Viewing the random component in the spectral domain facilitates both its characterization and an interpretation of its major physical controls from a global perspective. The power spectral density functions of monthly flow anomalies of many large rivers worldwide are typified by a “red noise” process: the density is higher at low frequencies (e.g., <1 y −1 ) than at high frequencies, indicating disproportionate (relative to uncorrelated “white noise”) contribution of low frequencies to variability of monthly flow. For many high‐latitude and arid‐region rivers, however, the power is relatively evenly distributed across the frequency spectrum. The power spectrum of monthly flow can be interpreted as the product of the power spectrum of monthly basin total precipitation (which is typically white or slightly red) and several filters that have physical significance. The filters are associated with (1) the conversion of total precipitation (sum of rainfall and snowfall) to effective rainfall (liquid flux to the ground surface from above), (2) the conversion of effective rainfall to soil water excess (runoff), and (3) the conversion of soil water excess to river discharge. Inferences about the roles of each filter can be made through an analysis of observations, complemented by information from a global model of the ocean‐atmosphere‐land system. The first filter causes a snowmelt‐related amplification of high‐frequency variability in those basins that receive substantial snowfall. The second filter causes a relatively constant reduction in variability across all frequencies and can be predicted well by means of a semiempirical water balance relation. The third filter, associated with groundwater and surface water storage in the river basin, causes a strong reduction in high‐frequency variability of many basins. The strength of this reduction can be quantified by an average residence time of water in storage, which is typically on the order of 20–50 days. The residence time is demonstrably influenced by freezing conditions in the basin, fractional cover of the basin by lakes, and runoff ratio (ratio of mean runoff to mean precipitation). Large lake areas enhance storage and can greatly increase total residence times (100 to several hundred days). Freezing conditions appear to cause bypassing of subsurface storage, thus reducing residence times (0–30 days). Small runoff ratios tend to be associated with arid regions, where the water table is deep, and consequently, most of the runoff is produced by processes that bypass the saturated zone, leading to relatively small residence times for such basins (0–40 days).

Water Resources Research↗

Sources, transformations, and hydrological processes that control stream nitrate and dissolved organic matter concentrations during snowmelt in an upland forest

We explored catchment processes that control stream nutrient concentrations at an upland forest in northeastern Vermont, USA, where inputs of nitrogen via atmospheric deposition are among the highest in the nation and affect ecosystem functioning. We traced sources of water, nitrate, and dissolved organic matter (DOM) using stream water samples collected at high frequency during spring snowmelt. Hydrochemistry, isotopic tracers, and end‐member mixing analyses suggested the timing, sources, and source areas from which water and nutrients entered the stream. Although stream‐dissolved organic carbon (DOC) and dissolved organic nitrogen (DON) both originated from leaching of soluble organic matter, flushing responses between these two DOM components varied because of dynamic shifts of hydrological flow paths and sources that supply the highest concentrations of DOC and DON. High concentrations of stream water nitrate originated from atmospheric sources as well as nitrified sources from catchment soils. We detected nitrification in surficial soils during late snowmelt which affected the nitrate supply that was available to be transported to streams. However, isotopic tracers showed that the majority of nitrate in upslope surficial soil waters after the onset of snowmelt originated from atmospheric sources. A fraction of the atmospheric nitrogen was directly delivered to the stream, and this finding highlights the importance of quick flow pathways during snowmelt events. These findings indicate that interactions among sources, transformations, and hydrologic transport processes must be deciphered to understand why concentrations vary over time and over space as well as to elucidate the direct effects of human activities on nutrient dynamics in upland forest streams.

Water Resources Research↗

Evidence for mechanical and chemical alteration of iron-nickel meteorites on Mars: Process insights for Meridiani Planum

The weathering of meteorites found on Mars involves chemical and physical processes that can provide clues to climate conditions at the location of their discovery. Beginning on sol 1961, the Opportunity rover encountered three large iron meteorites within a few hundred meters of each other. In order of discovery, these rocks have been assigned the unofficial names Block Island, Shelter Island, and Mackinac Island. Each rock presents a unique but complimentary set of features that increase our understanding of weathering processes at Meridiani Planum. Significant morphologic characteristics interpretable as weathering features include (1) a large pit in Block Island, lined with delicate iron protrusions suggestive of inclusion removal by corrosive interaction; (2) differentially eroded kamacite and taenite lamellae in Block Island and Shelter Island, providing relative timing through crosscutting relationships with deposition of (3) an iron oxide-rich dark coating; (4) regmaglypted surfaces testifying to regions of minimal surface modification, with other regions in the same meteorites exhibiting (5) large-scale, cavernous weathering (in Shelter Island and Mackinac Island). We conclude that the current size of the rocks is approximate to their original postfall contours. Their morphology thus likely results from a combination of atmospheric interaction and postfall weathering effects. Among our specific findings is evidence supporting (1) at least one possible episode of aqueous acidic exposure for Block Island; (2) ripple migration over portions of the meteorites; (3) a minimum of two separate episodes of wind abrasion; alternating with (4) at least one episode of coating-forming chemical alteration, most likely at subzero temperatures.

Journal of Geophysical Research E: Planets↗

Simulating the impacts of disturbances on forest carbon cycling in North America: Processes, data, models, and challenges

Forest disturbances greatly alter the carbon cycle at various spatial and temporal scales. It is critical to understand disturbance regimes and their impacts to better quantify regional and global carbon dynamics. This review of the status and major challenges in representing the impacts of disturbances in modeling the carbon dynamics across North America revealed some major advances and challenges. First, significant advances have been made in representation, scaling, and characterization of disturbances that should be included in regional modeling efforts. Second, there is a need to develop effective and comprehensive process‐based procedures and algorithms to quantify the immediate and long‐term impacts of disturbances on ecosystem succession, soils, microclimate, and cycles of carbon, water, and nutrients. Third, our capability to simulate the occurrences and severity of disturbances is very limited. Fourth, scaling issues have rarely been addressed in continental scale model applications. It is not fully understood which finer scale processes and properties need to be scaled to coarser spatial and temporal scales. Fifth, there are inadequate databases on disturbances at the continental scale to support the quantification of their effects on the carbon balance in North America. Finally, procedures are needed to quantify the uncertainty of model inputs, model parameters, and model structures, and thus to estimate their impacts on overall model uncertainty. Working together, the scientific community interested in disturbance and its impacts can identify the most uncertain issues surrounding the role of disturbance in the North American carbon budget and develop working hypotheses to reduce the uncertainty

Journal of Geophysical Research: Biogeosciences↗

Extreme precipitation across adjacent burned and unburned watersheds reveals impacts of low severity wildfire on debris-flow processes

In steep landscapes, wildfire-induced changes to soil and vegetation can lead to extreme and hazardous geomorphic responses, including debris flows. The wildfire-induced mechanisms that lead to heightened geomorphic responses, however, depend on many site-specific factors including regional climate, vegetation, soil texture, and soil burn severity. As climate and land use change drive changes in fire regime, there is an increasing need to understand how fire alters geomorphic responses, particularly in areas where fire has been historically infrequent. Here, we examine differences in the initiation, magnitude, and particle-size distribution of debris flows that initiated within the area burned by the 2019 Woodbury Fire in central Arizona, USA, and those that initiated in a nearby unburned area. Despite similar rainfall intensities, unburned watersheds were less likely to produce debris flows. Debris flows in unburned areas initiated from both runoff and shallow landslides, while debris flows only initiated from runoff-related processes in the burned area. The grain-size distribution making up the matrix of debris-flow deposits within the burned area generally had a lower ratio of sand to silt relative to debris flows that initiated in the unburned area, though there were no systematic differences in the coarse fraction of debris-flow sediment between burned and unburned areas. Results help expand our ability to predict postwildfire debris-flow activity in a wider range of settings, specifically the Sonoran Desert ecoregion, and provide general insight into the impact of wildfire on geomorphic processes in steep terrain.

Arizona↗

Episodic nutrient addition affects water column nutrient processing rates in river-to-lake transitional zones

Storm-driven nutrient loading from tributaries can fuel eutrophication in nearshore and open water areas of lentic ecosystems. However, nutrient processing in river-to-lake transitional zones can substantially alter the amount and composition of nutrients transported to lakes from upstream surface waters. We measured the removal of nutrients and dissolved organic carbon (DOC) from the water column in the Fox rivermouth (Green Bay, Lake Michigan) to evaluate the response of rivermouth plankton to episodic nutrient enrichment. Light and dark water column incubations (8–12 hr) were conducted on four occasions from April through September to measure changes in dissolved nitrogen (N), phosphorus (P), and DOC concentrations in three locations along the Fox rivermouth. Two incubation experiments were conducted on consecutive days, (a) under ambient nutrient concentrations, and (b) under experimentally enriched N and P concentrations. Spatial and temporal variation was observed in nutrient uptake rates, but light incubations consistently had higher nutrient uptake rates than dark incubations. Nutrient enrichment increased total dissolved P and total dissolved N uptake and DOC release in light incubations, but only increased total dissolved P uptake in dark incubations. Moreover, nutrient uptake ratios (N:P) decreased from ambient to nutrient enriched conditions and indicated preferential P uptake by phytoplankton communities in light conditions. Our study substantiates that rivermouths can process nutrients bound for downstream ecosystems and demonstrates the potential of plankton communities to dynamically increase net uptake rates in response to episodic nutrient enrichment.

Wisconsin↗

A specific earthquake processing workflow for studying long-lived, explosive volcanic eruptions with application to the 2008 Okmok Volcano, Alaska, eruption

By providing unrivaled resolution in both time and space, volcano seismicity helps to chronicle and interpret eruptions. Standard earthquake detection methods are often insufficient as the eruption itself produces continuous seismic waves that obscure earthquake signals. We address this problem by developing an earthquake processing workflow specific to a high-noise volcanic environment and applying it to the explosive 2008 Okmok Volcano eruption. This process includes applying single-channel template matching combined with machine-learning and fingerprint-based techniques to expand the existing earthquake catalog of the eruption. We detected an order of magnitude more earthquakes, then located, relocated, determined locally calibrated magnitudes, and classified the events in the enhanced catalog. This new high-resolution earthquake catalog increases the number of observations by about a factor of 10 and enables the detailed spatiotemporal seismic analysis during a large eruption.

Alaska↗

Debris-flow process controls on steepland morphology in the San Gabriel Mountains, California

Steep landscapes evolve largely by debris flows, in addition to fluvial and hillslope processes. Abundant field observations document that debris flows incise valley bottoms and transport substantial sediment volumes, yet their contributions to steepland morphology remain uncertain. This has, in turn, limited the development of debris-flow incision rate formulations that produce morphology consistent with natural landscapes. In many landscapes, including the San Gabriel Mountains (SGM), California, steady-state fluvial channel longitudinal profiles are concave-up and exhibit a power-law relationship between channel slope and drainage area. At low drainage areas, however, valley slopes become nearly constant. These topographic forms result in a characteristically curved slope-area signature in log-log space. Here, we use a one-dimensional landform evolution model that incorporates debris-flow erosion to reproduce the relationship between this curved slope-area signature and erosion rate in the SGM. Topographic analysis indicates that the drainage area at which steepland valleys transition to fluvial channels correlates with measured erosion rates in the SGM, and our model results reproduce these relationships. Further, the model only produces realistic valley profiles when parameters that dictate the relationship between debris-flow erosion, valley-bottom slope, and debris-flow depth are within a narrow range. This result helps place constraints on the mathematical form of a debris-flow incision law. Finally, modeled fluvial incision outpaces debris-flow erosion at drainage areas less than those at which valleys morphologically transition from near-invariant slopes to concave profiles. This result emphasizes the critical role of debris-flow incision for setting steepland form, even as fluvial incision becomes the dominant incisional process.

California↗

Detailed observations of California foreshock sequences: Implications for the earthquake initiation process

We find that foreshocks provide clear evidence for an extended nucleation process before some earthquakes. In this study, we examine in detail the evolution of six California foreshock sequences, the 1986 Mount Lewis ( M L = 5.5), the 1986 Chalfant ( M L = 6.4), the 1986 Stone Canyon ( M L = 4.7), the 1990 Upland ( M L = 5.2), the 1992 Joshua Tree ( M W = 6.1), and the 1992 Landers ( M W = 7.3) sequence. Typically, uncertainties in hypocentral parameters are too large to establish the geometry of foreshock sequences and hence to understand their evolution. However, the similarity of location and focal mechanisms for the events in these sequences leads to similar foreshock waveforms that we cross correlate to obtain extremely accurate relative locations. We use these results to identify small-scale fault zone structures that could influence nucleation and to determine the stress evolution leading up to the mainshock. In general, these foreshock sequences are not compatible with a cascading failure nucleation model in which the foreshocks all occur on a single fault plane and trigger the mainshock by static stress transfer. Instead, the foreshocks seem to concentrate near structural discontinuities in the fault and may themselves be a product of an aseismic nucleation process. Fault zone heterogeneity may also be important in controlling the number of foreshocks, i.e., the stronger the heterogeneity, the greater the number of foreshocks. The size of the nucleation region, as measured by the extent of the foreshock sequence, appears to scale with mainshock moment in the same manner as determined independently by measurements of the seismic nucleation phase. We also find evidence for slip localization as predicted by some models of earthquake nucleation.

Journal of Geophysical Research B: Solid Earth↗

Processes affecting the distribution of selenium in shallow groundwater of agricultural areas, western San Joaquin Valley, California

A study was undertaken to evaluate the processes affecting the chemistry of shallow groundwater associated with agricultural drainage systems in the western San Joaquin Valley, California. The study was prompted by a need for an understanding of selenium mobility in areas having high selenium concentrations in shallow groundwater. Groundwater samples were collected along transects in three artificially drained fields where the age of the drainage system varied (15, 6, and 1.5 years). Selenium concentrations in the drain water also varied (430, 58, and 3700 μg/L, respectively). Isotopic enrichment and chemical composition of the groundwater samples indicate that saline- and selenium-enriched water has evolved as a result of evaporation or transpiration of groundwater. This evaporated, isotopically enriched water is being displaced by more recent, less saline irrigation water percolating through the root zone. This displacement seems to be a process whereby sodium chloride and sodium sulfate water is being replaced by more dilute calcium sulfate and calcium bicarbonate water.

California↗

Fire effects on geomorphic processes

Fire-induced geomorphic changes, such as enhanced erosion and debris-flow activity, are expected to increase with climate change owing to increases in fire activity and rainfall intensification. In this Review, we summarize how landscape attributes, rainfall and burn severity influence post-fire geomorphic responses over a range of temporal and spatial scales. Sub-hourly rainfall intensity and burn severity control the magnitude of many post-fire geomorphic process rates through their influence on ground cover and rainfall-runoff partitioning. Post-fire debris flows (PFDFs) make a substantial contribution to the post-fire sediment cascade, transporting sediment from hillslopes to channels, adjacent floodplains and alluvial fans. By the late twenty-first century, PFDF activity is estimated to increase in 68% of areas in which PFDFs have occurred in the past and decrease in only 2% of locations. Once altered by fire, geomorphic state variables — such as infiltration capacity, canopy cover, ground cover and sediment availability — can recover to their pre-fire value or be shifted to a new value. Improved understanding of the factors that influence these post-fire trajectories could support targeted management and intervention strategies. Additionally, monitoring that extends beyond the first 1–3 years after fire and deeper integration of ecohydrological processes into geomorphic models are needed to improve forecasts of post-fire geomorphic responses.

Nature Reviews Earth and Environment↗

Effects of vertebrate herbivores on soil processes, plant biomass, litter accumulation and soil elevation changes in a coastal marsh

1 Submergence of coastal wetlands in Louisiana is currently rapid and widespread. A number of factors contribute to this loss of habitat, including the activities of herbivores. The objective of this study was to examine the effects of large mammals, predominantly nutria and wild boar, on processes controlling soil elevation in coastal marshes. 2 Effects of herbivores on soil and vegetation were assessed by the use of paired fenced and unfenced plots over two successive growing seasons. Above‐ground biomass, litter production, changes in soil elevation, vertical soil accretion, shallow subsidence, below‐ground production of roots and rhizomes, the thickness of the root zone, soil bulk density, and soil organic matter were measured. 3 Above‐ground biomass, below‐ground production, soil elevation and the expansion of the root zone decreased due to herbivore activity. Litter production, the rate of soil surface accretion and shallow soil subsidence were all higher in grazed compared to ungrazed plots, while soil organic matter and bulk density did not differ significantly between treatments. 4 The results indicate that herbivores can have a negative effect on soil building processes, primarily by reducing below‐ground production and expansion of the root zone. Where natural rates of mineral sediment deposition are high, coastal marshes are expected to persist, despite herbivore activities. However, where sediment inputs are substantially less, herbivores may lead to destruction of habitat.

Louisiana↗

Removal of antibiotics from surface and distilled water in conventional water treatment processes

Conventional drinking water treatment processes were evaluated under typical water treatment plant conditions to determine their effectiveness in the removal of seven common antibiotics: carbadox, sulfachlorpyridazine, sulfadimethoxine, sulfamerazine, sulfamethazine, sulfathiazole, and trimethoprim. Experiments were conducted using synthetic solutions prepared by spiking both distilled/ deionized water and Missouri River water with the studied compounds. Sorption on Calgon WPH powdered activated carbon, reverse osmosis, and oxidation with chlorine and ozone under typical plant conditions were all shown to be effective in removing the studied antibiotics. Conversely, coagulation/flocculation/sedimentation with alum and iron salts, excess lime/soda ash softening, ultraviolet irradiation at disinfection dosages, and ion exchange were all relatively ineffective methods of antibiotic removal. This study shows that the studied antibiotics could be effectively removed using processes already in use many water treatment plants. Additional work is needed on by-product formation and the removal of other classes of antibiotics.

Journal of Environmental Engineering↗

Geologic characterization of shelf areas using usSEABED for GIS mapping, modeling processes and assessing marine sand and gravel resources

Geologic maps depicting offshore sedimentary features serve many scientific and applied purposes. Such maps have been lacking, but recent computer technology and software offer promise in the capture and display of diverse marine data. Continental margins contain landforms which provide a variety of important functions and contain important sedimentary records. Some shelf areas also contain deposits regarded as potential aggregate resources. Because proper management of coastal and offshore areas is increasingly important, knowledge of the framework geology and marine processes is critical. Especially valuable are comprehensive and integrated digital databases based on high-quality information from original sources. Products of interest are GIS maps containing thematic information, such as sediment character and texture. These products are useful to scientists modeling nearshore and shelf processes as well as planners and managers. The U.S. Geological Survey is leading a national program to gather a variety of extant marine geologic data into the usSEABED database system. This provides centralized, integrated marine geologic data collected over the past 50 years. To date, over 340,000 sediment data points from the U.S. reside in usSEABED, which combines an array of physical data and analytical and descriptive information about the sea floor and are available to the marine community through three USGS data reports for the Atlantic, Gulf of Mexico, and Pacific published in 2006, and the project web sites: (http://woodshole.er.usg s.gov/project-pages/aggregates/ and http://walrus.wr.usgs.gov/usseabed/)

Conference Paper↗

Large-scale scour of the sea floor and the effect of natural armouring processes, land reclamation Maasvlakte 2, port of Rotterdam

Morphological model computations based on uniform (non-graded) sediment revealed an unrealistically strong scour of the sea floor in the immediate vicinity to the west of Maasvlakte 2. By means of a state-of-the-art graded sediment transport model the effect of natural armouring and sorting of bed material on the scour process has been examined. Sensitivity computations confirm that the development of the scour hole is strongly reduced due to the incorporation of armouring processes, suggesting an approximately 30% decrease in terms of erosion area below the -20m depth contour.

Conference Paper↗

High-pass corner frequency selection for implementation in the USGS automated ground motion processing tool

Earthquake ground motion processing for next-generation attenuation (NGA) projects required human inspection to select high-pass corner frequencies ( f cHP ), which is time-intensive and subjective. With growth in the number of recordings per event and interest in enhancing repeatability, we sought to develop automated procedures for f cHP selection. These procedures consider signal-to-noise ratio (SNR) and non-physical features in the displacement time series that indicate high- and/or low-frequency noise effects. The procedures are implemented in a US Geological Survey software package (gmprocess). We extend previous procedures for SNR-based corner frequency selection to also check for low-frequency artifacts in the displacement record using a polynomial fit to improve f cHP selection. We evaluate the performance of the SNR and polynomial fit criteria using recordings from the 2020 M5.1 North Carolina and the 2013 M4.7 Southern Ontario earthquakes. Data processed with the SNR-only criteria can have low f cHP and displacement drift; the displacement check increases f cHP and reduces displacement drift.

Conference Paper↗