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Design, revisions, and considerations for continued use of a ground-water-flow model of the coastal plain aquifer system in Virginia

A digital numerical model of the ground-water-flow system in the Virginia Coastal Plain was constructed as part of the Regional Aquifer System Analysis program of the U.S. Geological Survey and subsequently revised based on reinterpretations of the hydrogeologic framework. The revised model has been incorporated by the Virginia Department of Environmental Quality as a means to evaluate the effects of existing and proposed ground-water withdrawals. The revised model, which is documented here, includes many design features of the original model. Principal modifications are (1) reassignment of some model layers to represent different aquifers, (2) replacement of applied recharge and the uppermost surface-water layer by constant-head cells to represent the unconfined aquifer, and (3) revision of the lateral extents and transmissivity and vertical leakance values assigned to model layers. Ground-water levels simulated by the revised model under steady-state conditions, using withdrawal rates representing the period 1978-80, generally are similar to the water levels simulated by the original model under transient conditions using the same withdrawal rates. Differences probably result largely from changes in transmissivity and vertical leakance values. T he revised model enables the continued evaluation of development of the large and complex aquifer system. Improved information on parts of some aquifers has been incorporated. Only large, regional-scale trends in ground-water water levels, flow directions, and flow rates are simulated, however, and not local trends and (or) short-term changes in water level and flow. Changing hydraulic stresses, knowledge of hydrogeologic conditions, and resource-management needs require periodic revision of the model to maintain its usefulness for the management of ground-water resources in the Virginia Coastal Plain.

Virginia

Geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within Hays County, Texas

During 2023–24, the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, revised a previous publication of the geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers that was completed during 2018 within Hays County, Texas. The purpose of this report is to present the updated geologic framework and hydrostratigraphy of the rocks containing the Edwards and Trinity aquifers in Hays County from field observations of the surficial expressions of the rocks. The report includes a detailed 1:24,000-scale hydrostratigraphic map with names and descriptions of the geologic framework and hydrostratigraphic units (HSUs) in the study area. The study includes updates to the interpretation of the Kainer Formation of the Edwards Group with the addition of a burrowed unit between the basal nodular and dolomitic members. Hydrostratigraphy was also updated with the addition of the Seco Pass HSU for the burrowed member of the Kainer Formation. The study also includes updates to the interpretation of the hydrostratigraphy of the Trinity aquifer with the addition of the cavernous HSU at the top of the upper zone of the Trinity aquifer and the Herff Falls HSU between the Bulverde and Rust HSUs of the middle zone of the Trinity aquifer. This updated report provides additional information about a complex aquifer system. The complexity in the aquifer system results from a combination of the original depositional history, bioturbation, development of primary and secondary porosity, postdepositional diagenesis, fracturing, and faulting.

Texas

Estimation of the accessible and useful resource base for electric-grade enhanced geothermal systems (EGS) resources of the Great Basin, USA

Scientists with the U.S. Geological Survey (USGS) recently completed a provisional assessment of the electric-grade geothermal resources associated with the low-permeability geologic formations of the Great Basin, USA, where resources are assumed to be accessible using enhanced geothermal systems (EGS) technologies (i.e., the engineering of sufficient permeability to facilitate efficient heat extraction). This assessment required estimation of the accessible resource base (electric-grade heat [>90ºC] at depths where drilling and stimulation are deemed achievable using current technology) and useful resource (heat that can be extracted from the accessible region). Electric-grade heat can be estimated from existing temperature models. The accessible resource base can be estimated as the electric-grade heat that exists at depths shallower than 6 km based on the limitations of current drilling and stimulation technologies, along with evidence for sustained natural fracture conductivity at depth. The useful part of the accessible heat can be estimated as the product of three efficiencies and factors: the heat extraction efficiency, the viable geology factor, and the reservoir spacing efficiency. The accessible and useful parts of the resource can be estimated in units of heat, or in units of electric power using an electrical conversion efficiency, which is a function of resource temperature. We also estimate the ranges for each of the efficiencies and describe the motivations behind the choice of best estimates used for the recent assessment. An analytic solution is provided for the useful resource above any depth (in units of electric power), where efficiency estimation assumes nearly steady heat extraction rates that cool reservoirs to 90ºC over 30 years of power generation.

Great Basin

Effect of deicing chemicals on the hydrologic environment in Massachusetts; evaluation of surface-water data collection

The objective of this study is to develop predictive relationships that can be used to describe the impact of highway deicing salts on the hydrologic environment. A method, presented in an earlier report, for estimating yearly mean chloride concentrations from estimated or actual runoff and salt-application data was applied to the period 1971 through1974 and the results compared with yearly mean chloride concentrations computed from records of specific conductance. Estimates were found to be from minus 63 percent to plus 56 percent in error when the error was expressed as the difference between estimated and computed values as a percentage of the computed values. Chloride concentrations used in this study are computed from specific conductance/chloride concentration relationships and records of specific conductance. Preliminary results from graphic analyses and least-squares regression analysis show that relationships between measured values of specific conductance and chloride concentration have correlation coefficients ranging from 0.30 to 0.97. Analysis of streamflow for all major dissolved constituents is recommended with the purpose of attempting to describe the variations in the specific conductance/chloride concentration relationships.

Massachusetts

Hydrogeologic mapping and three-dimensional geologic modeling of glacial deposits in a multicounty area of southeastern Michigan, northeastern Indiana, and northwestern Ohio

The glacial deposits underlying southeastern Michigan, northeastern Indiana, and northwestern Ohio are a substantial source of water to communities, agriculture, and industry in the region. Previous efforts to characterize aquifer materials in the area cited a need for additional information about the underlying hydrogeologic characteristics and related groundwater availability as well as improved mapping of the extent and properties of the glacial deposits. Recent U.S. Geological Survey multi-State compilations of water-well drilling records have greatly increased access to high-resolution geologic data, particularly in glacial depositional environments. This study by the U.S. Geological Survey, in cooperation with the Ohio Environmental Protection Agency, uses processed data from the State-managed collections of well records to characterize the glacial deposits in the study area using two methods. The first method creates two-dimensional maps of basic hydrogeologic information commonly required for assessments of groundwater availability, including (1) total thickness of glacial deposits, (2) total thickness of coarse-grained deposits, (3) specific-capacity-based transmissivity and hydraulic conductivity, and (4) texture-based estimated equivalent horizontal and vertical hydraulic conductivity and transmissivity. The second method builds a hydrogeologic framework of the complex glacial aquifer through construction of a volumetric geologic model by using three-dimensional kriging. Results of the volumetric model indicate that aquifer materials are primarily concentrated in the western parts of the study area near the Indiana-Ohio border. Coarse-grained sediments are also present as surficial deposits in the north of the study area where intermixing glacial advances created complex distributions of unconsolidated deposits. Two-dimensional maps of hydrogeologic properties support the volumetric model, showing thicknesses of coarse-grained deposits that reach up to 250 feet in the western sections of the study area and progressively thin to near absence in the east. Visualization of the aquifer materials with a volumetric model generally shows a highly discontinuous distribution of coarse- and fine-grained materials, with no clearly defined boundaries to delineate the extent of the aquifer. Comparisons of cross sections derived from the volumetric model with existing published maps support previous near-surface hydrogeologic interpretations while filling gaps where data are sparse, particularly in deeper parts of the aquifer. Both the two-dimensional maps and the volumetric model provide data that can directly inform assessments of groundwater availability, in addition to having future applications to studies of groundwater flow and transport.

Indiana, Michigan, Ohio

Seismic response of rock towers at the Trona Pinnacles (U.S.A.) to the 2019 Ridgecrest earthquake sequence: Theory, observations, and models

We analyze the seismic response of a class of fragile geologic features (FGFs), referred to as rock towers (RTs) at the Trona Pinnacles, a group of RTs in southern California that suffered strong shaking during the 2019 Ridgecrest earthquake sequence. FGFs, including RTs, may provide maximum constraints on past earthquake shaking intensity, and thereby support probabilistic seismic hazard assessments (PSHAs). In a rare case study, we explore the hypothesis that RT structural integrity is time dependent, as damage accumulates progressively. We develop finite‐element method (FEM) models of the RTs using photogrammetric shape models. We validate the models by comparing numerical simulations of their response to broadband ground shaking with low‐intensity seismic recordings obtained at the Pinnacles. Results of our simulations are in good agreement with the seismic recordings of actual earthquake aftershocks. We next use the results of the FEM models to analyze the response and evolution of RTs. Our analyses elucidate the influence of geometry over their seismic response, providing a rationale that may explain the rarity of slender RTs at Trona: high‐aspect‐ratio structures that respond in bending develop detrimental tensile stresses that crack the rock, whereas low‐aspect‐ratio ones’ response also includes shearing, which does not compromise material integrity as much as tension. Field measurements with a rebound hammer support this finding, suggesting that the material around the base of slender rocks has been weakened relative to other parts of the RT. We also study how to define simplified mechanical models (“archetypes”) to predict the natural frequencies of RTs. Results from our work illuminate the fundamental mechanisms of seismic response and progressive failure of RTs, and open new avenues of research to potentially incorporate these geologic features as long‐return period constraints on PSHA, in ways analogous to those of the widely used precariously balanced rocks.

California

A history of cryohydrogeology modeling and recent advancements through the integration of solute transport

Groundwater flow systems and permafrost are interrelated because permafrost thaw enhances permeability, while groundwater flow can advect heat and accelerate permafrost thaw (McKenzie et al. 2021). Given amplified climate change in cold regions, there is renewed interest in ‘cryohydrogeology’, the study of groundwater in cold regions. Many data-driven studies have shown that permafrost thaw is leading to activated aquifers and increased baseflow across the pan-Arctic region (e.g. Walvoord and Striegl 2007, Evans et al. 2020). Empirical evidence of a subsurface ‘replumbing’ (Walvoord and Kurylyk 2016) in permafrost regions raises questions about the fate of sequestered contaminants in the North (Langer et al. 2023). We will discuss the history of and emerging opportunities in cryohydrogeological modeling, with a focus on recent contaminant transport modeling.

Conference Paper

The potential impact of three-dimensional distributed slip models derived from real-time GNSS data on the performance of the ShakeAlert earthquake early warning system for slab interface earthquakes

The ShakeAlert® earthquake early warning (EEW) system is designed to warn users of imminent strong ground motion with sufficient time to take protective actions. ShakeAlert currently uses three algorithms to characterize the earthquake source. One estimates the location and magnitude using the first few seconds of the P wave and, while fast, tends to underestimate magnitude for M w 7.0+ earthquakes. A second estimates the location, orientation, length, and corresponding magnitude of a line source using observed peak ground acceleration and contributes primarily to M w 5.5+ earthquakes. The third infers earthquake magnitude from peak ground displacement measured using Global Navigation Satellite System (GNSS) data and offers nonsaturating magnitudes for M w 7.0+ earthquakes. Other EEW algorithms exist that infer temporally evolving spatially variable slip on a 3D fault surface from real‐time GNSS data, information that might enable more accurate and timely alerts in the event of large‐magnitude subduction interface earthquakes. Here, we evaluate the potential contribution of one such algorithm, BEFORES ( Minson et al. , 2014 ), to improve ShakeAlert performance through a simulated real‐time implementation of Bayesian evidence‐based fault orientation and real‐time earthquake slip (BEFORES) and other ShakeAlert algorithms using data for eight M w 7.6+ earthquakes. The test results demonstrate that BEFORES can produce well‐constrained and accurate magnitude estimates as soon as or sooner than other EEW algorithms, in turn enabling it to increase the amount of warning time users receive in many cases. However, with a modified Mercalli intensity (MMI) threshold of 3.5, which is commonly used for issuing alerts, BEFORES would tend to alert large geographic regions that did not feel strong shaking (MMI 6+). This effect can be mitigated using a higher alert threshold of MMI 4.5 without negative impact on the amount of warning time obtainable with BEFORES.

Bulletin of the Seismological Society of America

Monazite and xenotime U-Pb geochronology and thermometry of the Blue Ridge and Inner Piedmont of North Carolina: Implications for the thermal-metamorphic evolution of the southern Appalachian metamorphic “core”

The southern Appalachian orogen preserves a complex distribution of metamorphism and deformation varying in timing, magnitude, and spatial extent. These complexities give rise to disparate interpretations for southern Appalachian tectonic evolution, which complicates the testing and interpretation of tectonic models in this system. New monazite (Mnz) and xenotime (Xtm) laser ablation split stream (LASS) analyses alongside Mnz-Xtm thermometry in the orogenic core in the eastern Blue Ridge (EBR), western Inner Piedmont (WIP), and Cat Square terranes (CST) of North Carolina yield new constraints that define distinct pro- and retrograde metamorphic events. The EBR preserves two prograde thermal events: the Taconic (∼470-440 Ma, >660°C) and Neoacadian (∼380-340 Ma, 600–700°C), separated by a period of cooling (exhumation?) and followed by garnet breakdown from 339 to 329 Ma. Evidence of pervasive Neoacadian ductile deformation in the EBR is largely limited to the Brevard fault zone (BFZ), indicating that a major rheological gradient existed across the BFZ during the Neoacadian and early Alleghanian. Southeast of the BFZ, in the WIP and CST, monazite data define a protracted Neoacadian evolution from early mineral growth at ∼405 Ma at ∼450–600°C to >700°C at ∼360 Ma, followed by early Alleghanian retrograde metamorphism and deformation (<345 Ma, 350–500°C). These constraints, together with previously reported thermobarometric data, define a P-T-t evolution for the WIP and CST consistent with Neoacadian crustal flow, while the coeval presence of a thermal-rheological boundary along the BFZ further supports a model of Neoacadian crustal “escape” flow within the orogen.

North Carolina

Origin of the Pd/Pt ratio of the J-M Reef, Stillwater Complex, Montana, USA

The J-M reef of the Stillwater Complex is characterized by a high Pd/Pt ratio (mean ~3.8 with a standard error of 0.03) with a homogeneous geospatial distribution at the deposit scale. In this contribution, we demonstrate that the Pd/Pt ratio of the reef is the product of equilibration of an immiscible sulfide liquid with a silicate melt rich in Pd relative to Pt. Despite the high tenors of the J-M reef sulfides (avg 2,700 ppm Pt and 770 ppm Pt), numerical modeling shows that the parental melts did not have extraordinary Pd and Pt concentrations. Instead, the initial composition of a plausible parental silicate melt can have Pd and Pt contents well within the expected range of a normal, mantle-derived partial melt (i.e., ~10–20 ppb for both Pd and Pt with Pd/Pt of ~1). The relative differences in the partitioning behavior of Pt and Pd between sulfide liquid and silicate melt are unlikely to produce a consistent Pd/Pt ratio across a wide range of silicate melt to sulfide liquid mass ratios (i.e., R factors). Instead, the pre-emplacement fractionation of Pt alloy from S-undersaturated silicate magma accounts for the homogeneous and high Pd/Pt ratio of the J-M reef. We show that batch equilibration of sulfide liquid with silicate melt can produce the high Pd/Pt ratios of the reef if the partition coefficients between sulfide liquid and silicate melt for Pd and Pt are extremely high (>10 6 ). In an alternative model, Pd enrichment could be achieved by sulfide upgrading in resident footwall mush even if the partition coefficients between sulfide liquid and silicate melt are relatively small (between 10 4 and 10 6 ) because the instantaneous mass ratio of silicate melt to sulfide liquid is small (R ≈ 100–700), so the partitioning behavior of Pt and Pd has little impact on the composition of sulfide liquid.

Montana

Analysis of minimum 7-day discharges and estimation of minimum 7-day, 2-year discharges for streamflow-gaging stations in the Brazos River basin, Texas

The minimum 7-day, 2-year discharge (7Q2) was estimated for each of 97 streamflow-gaging stations in the Brazos River Basin, Texas, with at least 10 years of unregulated or 10 years of regulated discharge data using the Pearson Type III distribution fitted by L-moment statistics of the annual minimum 7-day discharges. Forty-six stations have at least 10 years of unregulated discharge data only, 26 stations have at least 10 years of regulated discharge data only, and 25 stations have at least 10 years of unregulated and 10 years of regulated discharge data. Statistical tests were applied to the annual minimum 7-day discharges to determine if the unregulated and regulated data have trends; and to determine if the data before regulation are significantly different from the data after regulation. Results of the Mann-Kendall test indicate a significant trend at the 95-percent confidence level for 8 of the 46 unregulated-only stations, for 6 of the 26 regulated-only stations, and for 5 stations before regulation and for 10 stations after regulation of the 25 stations with both unregulated and regulated data. Results of the Wilcoxon rank-sum test indicate a significant difference between the unregulated and regulated annual minimum 7-day discharges at the 95-percent confidence level for 16 of the 25 stations with both types of data. The 7Q2 is zero for 31 of the 46 unregulated-only stations and for 9 of the 26 regulated-only stations. The 7Q2 also is zero for 9 stations before regulation and for 3 stations after regulation of the 25 stations with both unregulated and regulated data. The 7Q2 ranges from 33 to 631 cubic feet per second for the eight regulated-only stations on the mainstem Brazos River. For the seven stations on the mainstem Brazos River with at least 10 years of unregulated and 10 years of regulated discharge data, the 7Q2 ranges from 0 to 568 cubic feet per second before regulation and from 0.30 to 670 cubic feet per second after regulation. The 7Q2 increased during regulation for 19 of the 25 stations with both unregulated and regulated data. The effect of regulation for most stations generally was an increase in the magnitude of the 7Q2.

Texas

Are the horizontal-to-vertical spectral ratios of earthquakes and microtremors the same?

We consider the similarities and differences between earthquake and microtremor horizontal‐to‐vertical spectral ratios (eHVSR and mHVSR, respectively) using a dataset of 161 sites in southern California. Quantitative comparisons are made in terms of the eHVSR and mHVSR lognormal median curves, as well as the frequencies and amplitudes associated with the fundamental‐ and higher‐mode resonances where present. The results show only 58% of the eHVSR–mHVSR pairs agree in terms of their median curve and only 25% of the eHVSR–mHVSR pairs agree in terms of shared resonances, which increases to 68% if flat HVSRs are considered equivalent. Furthermore, while the shared resonances match very well in terms of frequency (root mean square error, RMSE, <0.11 Hz), the amplitudes of those resonances do not agree (RMSE >1.6). These findings demonstrate that while eHVSR and mHVSR agree at some sites, they are not equivalent at all sites. To investigate if the agreement between eHVSR and mHVSR could be related to features of the microtremor data, earthquake recordings, and/or the site conditions, three machine learning (ML) models at varying levels of interpretability are presented. The ML models—which include multivariate logistic regression, gradient‐boosted trees, and support vector machines—show only partial success at using site‐specific data to predict whether eHVSR and mHVSR will likely agree in terms of their median curve (accuracy of 78%) and number of resonances (accuracy of 84%). Therefore, we conclude that while eHVSR and mHVSR can be quite similar in terms of resonant frequencies at some sites, they are not identical at all sites. Furthermore, preliminary evidence shows that the agreement of eHVSR and mHVSR can be predicted a priori given features of the microtremor measurements, earthquake recordings, and site conditions, although a larger dataset will be necessary for developing a robust predictive model.

California

Characterization of the hydrogeologic framework, groundwater-flow system, geochemistry, and aquifer hydraulic properties of the shallow groundwater system in the Wilcox and Lorraine process areas of the Wilcox Oil Company Superfund site near Bristow, Oklahoma, 2022

The Wilcox Oil Company Superfund site (hereinafter referred to as “the site”) was formerly an oil refinery northeast of Bristow in Creek County, Oklahoma. Historical refinery operations contaminated the soil, surface water, streambed sediments, alluvium, and groundwater with refined and stored products at the site. The Wilcox and Lorraine process areas are where the highest concentrations of volatile organic compounds, semivolatile organic compounds, polycyclic aromatic hydrocarbons, and trace elements (including metals) (collectively hereinafter referred to as “contaminants”) were measured in a local shallow perched groundwater system within the alluvium (hereinafter referred to as the “alluvial aquifer”) at the site during previous site assessments. In order to understand the potential migration of contaminants through the soil and groundwater in these areas, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, investigated aquifer characteristics of the alluvial aquifer in the Wilcox and Lorraine process areas of the site to (1) document hydraulic conductivity and other aquifer characteristics of the alluvial aquifer that govern contaminant fate and transport, (2) describe the geospatial extent and concentration of the contaminants in the alluvial aquifer in the Wilcox and Lorraine process areas, and (3) describe the geochemical controls pertaining to oxidation and reduction governing the fate and transport and the degradation potential of contaminants in the groundwater. Various data were compiled and collected to evaluate the aquifer characteristics at the site including the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer. A total of 20 new (2022) groundwater monitoring wells were installed at the site to collect data used to supplement groundwater-level altitude and groundwater-quality data collected from older, existing groundwater monitoring wells and piezometers. Data compiled and collected for the study were used to evaluate the characteristics of the alluvial aquifer at the site. These aquifer characteristics are defined by the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer.

Oklahoma

Geology and geochemistry of Ni-Co laterite occurrences of northern California and southern Oregon

Ni-Co laterite occurrences in the Klamath Mountains of southern Oregon and northern California contain Ni, Co, and Sc values comparable to global deposits. However, they are thin and limited in extent, often occurring as landslides and slumps. Olivine in the parent material contains Ni and Co and enstatite contains Sc. Through pervasive weathering, these elements where concentrated in Fe- and Mn-oxides. Unlike the mined Nickel Mountian deposit near Riddle, Oregon, these occurrences have no hydrous-Mg silicate minerals. Although the region experienced pervasive weathering in the Eocene, preservation of the laterite profiles was limited in the Klamath Mountains due to accelerated uplift and erosion compared to the Coast Range Provence.

Conference Paper

Approximate inland extent of saltwater intrusion at the base of the Biscayne aquifer, Miami-Dade County, Florida, 2022

Miami-Dade County is part of a densely populated urban corridor in southeastern Florida. The Biscayne aquifer serves as Miami-Dade County’s primary drinking water source and is characterized by highly permeable karstic limestone and carbonate sand. The aquifer’s coastal location and permeable nature make it susceptible to saltwater intrusion. Monitoring the current inland extent and the rate of movement of the saltwater front in the aquifer can inform management strategies for conserving the long-term sustainability of the county’s water supply. In the 1950s, the U.S. Geological Survey published a map of the inland extent of saltwater intrusion in the Biscayne aquifer and has continued to update this map to monitor changes over time, with the most recent update published in 2018. An updated map has been created showing the approximate inland extent of saltwater intrusion in the Biscayne aquifer in eastern Miami-Dade County in 2022, with the 2018 extent shown for comparison. The inland extent of saltwater intrusion was mapped through the interpretation of borehole electromagnetic induction logs and measurements of chloride and specific conductance in groundwater samples. The location of the saltwater interface at the base of the Biscayne aquifer was represented by the 1,000-milligram-per-liter isochlor. This report describes changes in the location of the saltwater interface from 2018 to 2022. By 2022, the saltwater interface had moved farther inland in both the northern and southern parts of the county, advancing by as much as 0.3 kilometer in the north and up to 0.8 kilometer in the Model Land Area to the south. However, it remained relatively unchanged from its 2018 position in the east-central part of the county.

Florida

The mineral chemistry networks of tin and tungsten reflect metallogenic eras of the Mesozoic

Continental remobilization is a crucial driver of metallogenesis and the formation of ore deposits. Some of the world’s largest mineral deposits of the economically valuable elements tin (Sn), tungsten (W), gold (Au), copper (Cu), lead (Pb), and zinc (Zn) formed during the Mesozoic Era. Additionally, the chemistry and distribution of the elements Sn and W have been investigated in previous studies to understand planetary formation and differentiation processes. These two elements are largely co-located during certain South China Mesozoic metallogenic events but are not co-located during other time periods in the same regions. Here, we investigated the mineral chemistry network similarities and dissimilarities of Sn and W to understand their mineral formation and distribution during the Mesozoic Era and throughout Earth history. Mineral chemistry network community detection analysis and electronegativity associations among mineral constituent elements of Sn minerals and W minerals indicate that the elements have similar chemistry among their oxide minerals. However, Sn forms a much wider range of minerals that also contain S compared to W, which occurs in a limited number of S-containing minerals. The divergent constituent element interactions among S-containing Sn minerals and W minerals reflect the redox sensitivity and importance of oxygen (O) fugacity in Sn mineral formation. Conversely, extensive W mineral deposits are known to form at both high and low O fugacities. The similarities and differences between the mineral chemistry networks of Sn and W reflect the mineral distribution of the two elements in the Sn-W mineralization event from 160 to 139 Ma vs. the Sn–uranium (U) mineralization event from 125 to 98 million years ago (Ma). The mineral chemistry and distribution of Mesozoic Sn and W deposits illustrate the contrasting importance of redox and O fugacity on the mineral formation of different elements, and the dynamic crustal evolution that took place during this period of Earth history.

Geosciences

An inventory of three-dimensional geologic models—U.S. Geological Survey, 2004–22

A database of spatial footprints and characteristics of three-dimensional geological models that were constructed by the U.S. Geological Survey between 2004 and 2022 was compiled as part of ongoing development of subsurface geologic information by the USGS National Cooperative Geologic Mapping Program. This initial inventory resulted in the compilation of 38 three-dimensional geological models that vary widely in their spatial extent, the type and purpose of the model, the number of subsurface units characterized by the model, and the software platforms used to create the model. This Data Report provides the scientific rationale and explanation of the contents of a companion USGS digital data release of spatial data and attributes associated with each three-dimensional model.

Data Report

Origin of the high Pd/Pt ratio of the J-M Reef, Stillwater Complex Montana USA

The J-M Reef of the Stillwater Complex exhibits a high and consistent Pd/Pt ratio (~3.8). This ratio results from the equilibration of an immiscible sulfide liquid with a relatively high Pd/Pt silicate melt rather than an unusually Pd- and Pt-enriched parental melt. Numerical modeling suggests that the original silicate melt contained typical mantle-derived concentrations of Pd and Pt (~10–20 ppb Pd/Pt ~1). The partitioning of Pt and Pd between sulfide liquid and silicate melt alone cannot explain the consistently high Pd/Pt ratio across variable melt-to-sulfide mass ratios (R factors). Instead Pt-depletion caused by the early fractionation of Pt-alloy from S-undersaturated silicate magma likely established the high Pd/Pt signature. High Pd/Pt ratios can form through batch equilibration of sulfide liquid with silicate melt if partition coefficients are extremely high (>10⁶). Alternatively Pd enrichment may result from sulfide upgrading within the resident footwall mush under smaller partition coefficients (10⁴–10⁶) in this model the instantaneous R factors remain low (R ≈ 100–700). This limits the impact of Pt and Pd partitioning on sulfide composition and helps explain the Pd-enriched character of the J-M Reef.

Montana