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At least 505 records · Page 28Linked to original sources
USGS1999

Lanthanide, yttrium, and zirconium anomalies in the Fire Clay coal bed, Eastern Kentucky

The Fire Clay coal bed in the Central Appalachian basin region contains a laterally-persistent tonstein that is found in the coal throughout most of its areal extent. The tonstein contains an array of minerals, including sanidine, ??-quartz, anatase and euhedral zircon, thhat constitutes strong evidence for a volcanic origin of the parting. For this study, five samples of the tonstein and four sets of coal samples underlying the tonstein were collected from five sites in eastern Kentucky. Inductively coupled plasma-mass spectroscopy (ICP-MS) analysis of the tonstein and underlying coal collected from four sites in eastern Kentucky show that although Zr concentrations are high in the tonstein (570-1820 ppm on a coal-ash basis (cab)), they are highest in the coal directly underlying the tonstein (2870-4540 ppm (cab)). A similar enrichment pattern is observed in the concentration of Y plus the sum of the rare earth elements (Y + ??REE): total Y + ??REE concentrations in the five tonstein samples range from 511 to 565 ppm (cab). However, Y + ??REE contents are highest in the coals directly underlying the tonsteins: values range from 1965 to 4198 ppm (cab). Scanning electron microscopy of samples from coal which directly underlies two of the tonstein samples show that REE-rich phosphate, tentatively identified as monazite, commonly infills cracks in clays and cells in clarain and vitrain. Zircon is rare and commonly subhedral. On the basis of coal chemistry and grain morphology, we suggest that volcanic components in the tonstein were leached by ground water. The leachate, rich in Y and REE precipitated as authigenic mineral phases in the underlying coal.The Fire Clay coal bed in the Central Appalachian basin region contains a laterally-persistent tonstein that is found in the coal throughout most of its areal extent. The tonstein contains an array of minerals, including sanidine, ??-quartz, anatase and euhedral zircon, that constitutes strong evidence for a volcanic origin of the parting. For this study, five samples of the tonstein and four sets of coal samples underlying the tonstein were collected from five sites in eastern Kentucky. Inductively coupled plasma-mass spectroscopy (ICP-MS) analysis of the tonstein and underlying coal collected from four sites in eastern Kentucky show that although Zr concentrations are high in the tonstein (570-1820 ppm on a coal-ash basis (cab)), they are highest in the coal directly underlying the tonstein (2870-4540 ppm (cab)). A similar enrichment pattern is observed in the concentration of Y plus the sum of the rare earth elements (Y+???REE): total Y+???REE concentrations in the five tonstein samples range from 511 to 565 ppm (cab). However, Y+???REE contents are highest in the coals directly underlying the tonsteins: values range from 1965 to 4198 ppm (cab). Scanning electron microscopy of samples from coal which directly underlies two of the tonstein samples show that REE-rich phosphate, tentatively identified as monazite, commonly infills cracks in clays and cells in clarain and vitrain. Zircon is rare and commonly subhedral. On the basis of coal chemistry and grain morphology, we suggest that volcanic components in the tonstein were leached by ground water. The leachate, rich in Y and REE precipitated as authigenic mineral phases in the underlying coal.

International Journal of Coal Geology↗
USGS1999

The types of data needed for assessing the environmental and human health impacts of coal

Coal is one of the most important sources of energy. Its worldwide use will continue to expand during the next several decades, particularly in rapidly developing countries such as China and India. Unfortunately, coal use may bring with it environmental and human health costs. Many of the environmental and health problems attributed to coal combustion are due to mobilization of potentially toxic elements. Some of these problems could be minimized or even avoided if comprehensive databases containing appropriate coal quality information were available to decision makers so that informed decisions could be made regarding coal use. Among the coal quality parameters that should be included in these databases are: C, H, N, O, pyritic sulfur, organic sulfur, major, minor, and trace element concentrations, modes of occurrence of environmentally sensitive elements, cleanability, mineralogy, organic chemistry, petrography, and leachability.Coal is one of the most important sources of energy. Its worldwide use will continue to expand during the next several decades, particularly in rapidly developing countries such as China and India. Unfortunately, coal use may bring with it environmental and human health costs. Many of the environmental and health problems attributed to coal combustion are due to mobilization of potentially toxic elements. Some of these problems could be minimized or even avoided if comprehensive databases containing appropriate coal quality information were available to decision makers so that informed decisions could be made regarding coal use. Among the coal quality parameters that should be included in these databases are: C, H, N, O, pyritic sulfur, organic sulfur, major, minor, and trace element concentrations, modes of occurrence of environmentally sensitive elements, cleanability, mineralogy, organic chemistry, petrography, and leachability.

International Journal of Coal Geology↗
USGS1999

A possible link between Balkan endemic nephropathy and the leaching of toxic organic compounds from Pliocene lignite by groundwater: Preliminary investigation

Balkan endemic nephropathy (BEN) is a fatal kidney disease that is known to occur only in clusters of villages in alluvial valleys of tributaries of the Danube River in Bulgaria, Romania, Yugoslavia, Bosnia, and Croatia. The confinement of this disease to a specific geographic area has led to speculation that an environmental factor may be involved in the etiology of BEN. Numerous environmental factors have been suggested as causative agents for producing BEN, including toxic metals in drinking water, metal deficiency in soils of BEN areas, and environmental mycotoxins to name a few. These hypotheses have either been disproved or have failed to conclusively demonstrate a connection to the etiology of BEN, or the clustering of BEN villages. In previous work, we observed a distinct geographic relationship between the distribution of Pliocene lignites in the Balkans and BEN villages. We hypothesized that the long-term consumption of well water containing toxic organic compounds derived from the leaching of nearby Pliocene lignites by groundwater was a primary factor in the etiology of BEN. In our current work, chemical analysis using 13C nuclear magnetic resonance (13CNMR) spectroscopy indicated a high degree of organic functionality in Pliocene lignite from the Balkans, and suggested that groundwater can readily leach organic matter from these coal beds. Semi-quantitative gas chromatography/mass spectroscopy analysis of solvent extracts of groundwater from shallow wells in BEN villages indicated the presence of potentially toxic aromatic compounds, such as napthalene, fluorene, phenanthrene, and pyrene at concentrations in the ppb range. Laboratory leaching of Balkan Pliocene lignites with distilled water yielded soluble organic matter (> 500 MW) containing large amounts of aromatic structures similar to the simple/discrete aromatic compounds detected in well water from BEN villages. These preliminary results are permissive of our hypothesis and suggest that further work on the possible relationship between the etiology of BEN and toxic aromatic substances leached from Pliocene lignites in well water is warranted.A distinct geographic relationship between the distribution of Pliocene lignites in the Balkans and villages where Balkan endemic nephropathy (BEN) occurs has been observed, indicating a possible link between BEN and the long-term consumption of well water containing toxic organic compounds derived from the leaching of nearby Pliocene lignites. Preliminary investigations by NMR spectroscopy, gas chromatography/mass spectroscopy and leaching experiments show a high degree of organic functionality in the Pliocene lignites, high-leachability by groundwater of organic matter from these beds, and the presence of toxic aromatic compounds.

International Journal of Coal Geology↗
USGS1999

Depositional history of the Fire Clay coal bed (Late Duckmantian), Eastern Kentucky, USA

More than 3800 coal thickness measurements, proximate analyses from 97 localities, and stratigraphic and sedimentological analyses from more than 300 outcrops and cores were used in conjunction with previously reported palynological and petrographic studies to map individual benches of the coal and document bench-scale variability in the Fire Clay (Hazard No. 4) coal bed across a 1860 km2 area of the Eastern Kentucky Coal Field. The bench architecture of the Fire Clay coal bed consists of uncommon leader benches, a persistent but variable lower bench, a widespread, and generally thick upper bench, and local, variable rider benches. Rheotrophic conditions are inferred for the leader benches and lower bench based on sedimentological associations, mixed palynomorph assemblages, locally common cannel coal layers, and generally high ash yields. The lower bench consistently exhibits vertical variability in petrography and palynology that reflects changing trophic conditions as topographic depressions infilled. Infilling also led to unconfined flooding and ultimately the drowning of the lower bench mire. The drowned mire was covered by an air-fall volcanic-ash deposit, which produced the characteristic flint clay parting. The extent and uniform thickness of the parting suggests that the ash layer was deposited in water on a relatively flat surface without a thick canopy or extensive standing vegetation across most of the study area. Ash deposits led to regional ponding and establishment of a second planar mire. Because the topography had become a broadly uniform, nutrient-rich surface, upper-bench peats became widespread with large areas of the mire distant to clastic sources. Vertical sections of thick (> 70 cm), low-ash yield, upper coal bench show a common palynomorph change from arborescent lycopod dominance upward to fern and densospore-producing, small lycopod dominance, inferred as a shift from planar to ombrotrophic mire phases. Domed mires appear to have been surrounded by wide areas of planar mires, where the coal was thinner (< 70 cm), higher in ash yield, and dominated by arborescent lycopods. Rectangular thickness trends suggest that syndepositional faulting influenced peat accumulation, and possibly the position of the domed mire phase. Faulting also influenced post-depositional clastic environments of deposition, resulting in sandstone channels with angular changes in orientation. Channels and lateral facies were locally draped by high-ash-yield rider coal benches, which sometimes merged with the upper coal bench. These arborescent-lycopod dominant rider coal benches were profoundly controlled by palcotopography, much like the leader coal benches. Each of the benches of coal documented here represent distinctly different mires that came together to form the Fire Clay coal bed, rather than a single mire periodically split by clastic influx. This is significant as each bench of the coal has its own characteristics, which contribute to the total coal characteristics. The large data set allows interpretation of both vertical and lateral limits to postulated domed phases in the upper coal bench, and to the delineation of subtle tectonic structures that allow for meaningful thickness projections beyond the limits of present mining.A study was conducted to analyze the depositional history of the Fire Clay coal bed in the eastern Kentucky coal field. The study involved over 3800 coal thickness measurements, proximate analyses from 97 localities, and stratigraphic and sedimentological analyses from more than 300 outcrops and cores in conjunction with previously reported palynological and petrographic studies to map individual benches of the coal and document bench-scale variability.

International Journal of Coal Geology↗
USGS1999

Predicting ground-water movement in large mine spoil areas in the Appalachian Plateau

Spoil created by surface mining can accumulate large quantities of ground-water, which can create geotechnical or regulatory problems, as well as flood active mine pits. A current study at a large (4.1 km2), thick, (up to 90 m) spoil body in eastern Kentucky reveals important factors that control the storage and movement of water. Ground-water recharge occurs along the periphery of the spoil body where surface-water drainage is blocked, as well as from infiltration along the spoil-bedrock contact, recharge from adjacent bedrock, and to a minor extent, through macropores at the spoil's surface. Based on an average saturated thickness of 6.4 m for all spoil wells, and assuming an estimated porosity of 20%, approximately 5.2 x 106 m3 of water is stored within the existing 4.1 km2 of reclaimed spoil. A conceptual model of ground-water flow, based on data from monitoring wells, dye-tracing data, discharge from springs and ponds, hydraulic gradients, chemical data, field reconnaissance, and aerial photographs indicate that three distinct but interconnected saturated zones have been established: one in the spoil's interior, and others in the valley fills that surround the main spoil body at lower elevations. Ground-water movement is sluggish in the spoil's interior, but moves quickly through the valley fills. The conceptual model shows that a prediction of ground-water occurrence, movement, and quality can be made for active or abandoned spoil areas if all or some of the following data are available: structural contour of the base of the lowest coal seam being mined, pre-mining topography, documentation of mining methods employed throughout the mine, overburden characteristics, and aerial photographs of mine progression.Spoil created by surface mining can accumulate large quantities of ground-water, which can create geotechnical or regulatory problems, as well as flood active mine pits. A current study at a large (4.1 km2), thick, (up to 90 m) spoil body in eastern Kentucky reveals important factors that control the storage and movement of water. Ground-water recharge occurs along the periphery of the spoil body where surface-water drainage is blocked, as well as from infiltration along the spoil-bedrock contact, recharge from adjacent bedrock, and to a minor extent, through macropores at the spoil's surface. Based on an average saturated thickness of 6.4 m for all spoil wells, and assuming an estimated porosity of 20%, approximately 5.2 ?? 106 m3 of water is stored within the existing 4.1 km2 of reclaimed spoil. A conceptual model of ground-water flow, based on data from monitoring wells, dye-tracing data, discharge from springs and ponds, hydraulic gradients, chemical data, field reconnaissance, and aerial photographs indicate that three distinct but interconnected saturated zones have been established: one in the spoil's interior, and others in the valley fills that surround the main spoil body at lower elevations. Ground-water movement is sluggish in the spoil's interior, but moves quickly through the valley fills. The conceptual model shows that a prediction of ground-water occurrence, movement, and quality can be made for active or abandoned spoil areas if all or some of the following data are available: structural contour of the base of the lowest coal seam being mined, pre-mining topography, documentation of mining methods employed throughout the mine, overburden characteristics, and aerial photographs of mine progression.

International Journal of Coal Geology↗
USGS1999

From in situ coal to the final coal product: A case study of the Danville Coal Member (Indiana)

A surface coal mine operation and preparation plant in southwestern Indiana was sampled to examine variations in coal quality and coal petrography parameters for the Danville Coal Member of the Dugger Formation (Pennsylvanian-Desmoinesian, Westphalian D). Representative samples from in situ coal, preparation plant feeds, and a final coal product were collected in order to compare coal quality, coal petrography, trace element concentrations, and ash chemistry of the coal to those of the product. Coal quality parameters of the in situ samples and various feeds, coarse refuse, and final product were variable. The quality of the final coal product was best predicted by the coal quality of the clean coal feed (from the middle portions of the seam). Some trace element contents, especially lead and arsenic, varied between the coal feeds and the product. Lead contents increased in the feeds and product compared to the channel sample of the raw coal, possibly due to contamination in the handling process.A surface coal mine operation and preparation plant in southwestern Indiana was sampled to examine variations in coal quality and coal petrography parameters for the Danville Coal Member of the Dugger Formation (Pennsylvanian-Desmoinesian, Westphalian D). Representative samples from in situ coal, preparation plant feeds, and a final coal product were collected in order to compare coal quality, coal petrography, trace element concentrations, and ash chemistry of the coal to those of the product. Coal quality parameters of the in situ samples and various feeds, coarse refuse, and final product were variable. The quality of the final coal product was best predicted by the coal quality of the clean coal feed (from the middle portions of the seam). Some trace element contents, especially lead and arsenic, varied between the coal feeds and the product. Lead contents increased in the feeds and product compared to the channel sample of the raw coal, possibly due to contamination in the handling process.

International Journal of Coal Geology↗
USGS2000

Metalliferous coals of the Westphalian A Joggins Formation, Cumberland basin, Nova Scotia, Canada: Petrology, geochemistry, and palynology

Five coals of Westphalian A (early Middle Pennsylvanian) age were sampled from the Joggins Formation section exposed along Chignecto Bay at Joggins, Nova Scotia. Coal beds along the bay were mined beginning in the early 17th century, yet there have been few detailed published investigation of the coal beds of this classic section. The lowermost coal, the Upper Coal 28 (Upper Fundy), is a high-vitrinite coal with a spore assemblage dominated by arboreous lycopsid spores with tree ferns subdominant. The upper portions of the coal bed have the highest ratio of well-preserved to poorly-preserved telinite of any of the coals investigated. Coal 19 ('clam coal') has 88% total vitrinite but, unlike the Fundy coal bed, the telinite has a poor preservation ratio and half the total vitrinite population comprises gelocollinite and vitrodetrinite. The latter coal bed is directly overlain by a basin-wide limestone bed. The Lower Kimberly coal shows good preservation of vitrinite with relatively abundant telinite among the total vitrinite. The Middle Kimberly coal, which underlies the tetrapod-bearing lycopsid trees found by Lyell and Dawson in 1852, exhibits an upward decrease in arboreous lycopod spores and an upward increase in the tree fern spore Punctatisporites minutus. Telinite preservation increases upwards in the Middle Kimberly but overall is well below the preservation ratio of the Upper Fundy coal bed. The coals all have high sulfur contents, yielding up to 13.7% total sulfur for the lower lithotype of the Upper Fundy coal bed. The Kimberly coals are not only high in total and pyritic sulfur, but also have high concentrations of chalcophile elements. Zinc, ranging up to 15,000 ppm (ash basis), is present as sphalerite in fusain lumens. Arsenic and lead each exceed 6000 ppm (ash basis) in separate lithotypes of the Kimberly coals. Together these data are consistent with elevated pH in planar mires. The source of the elemental enrichment in this presumed continental section is enigmatic. (C) 2000 Elsevier Science B.V. All rights reserved.Five coals of Westphalian A (early Middle Pennsylvanian) age were sampled from the Joggins Formation section exposed along Chigneto Bay at Joggins, Nova Scotia. All the coals were found to have high sulfur contents. Overall, the data obtained are consistent with elevated pH in planar mires.

International Journal of Coal Geology↗
USGS2000

In-situ analysis of solid bitumen in coal: Examples from the Bowen Basin and the Illinois Basin

Solid bitumen and associated vitrinite from selected coals from the Bowen Basin and the Illinois Basin were studied using electron microprobe and micro-FTIR techniques. The coal studied covers a range of vitrinite reflectance from 0.59% to 1.33%. Carbon content in the bitumen is generally lower than in vitrinite in coals with vitrinite reflectance below 0.67%. In coals with reflectance above 0.67%, carbon content of bitumen is higher than in vitrinite, reflecting higher aromaticity due to hydrocarbon generation. Sulfur and iron content are comparable between vitrinite and bitumen. Functional group distribution suggests the presence of two types of bitumen in the Illinois Basin coals. The more aliphatic variety occurring in veins and cleats is interpreted as pre-gas generation bitumen, and the more aromatic variety filling cells and voids in inertinite as post-gas generation bitumen. (C) 2000 Elsevier Science B.V. All rights reserved.Solid bitumen and associated vitrinite from selected coals from the Bowen Basin and the Illinois Basin were studied using electron microprobe and micro-FTIR techniques. The coal studied covers a range of vitrinite reflectance from 0.59% to 1.33%. Carbon content in the bitumen is generally lower than in vitrinite in coals with vitrinite reflectance below 0.67%. In coals with reflectance above 0.67%, carbon content of bitumen is higher than in vitrinite, reflecting higher aromaticity due to hydrocarbon generation. Sulfur and iron content are comparable between vitrinite and bitumen. Functional group distribution suggests the presence of two types of bitumen in the Illinois Basin coals. The more aliphatic variety occurring in veins and cleats is interpreted as pre-gas generation bitumen, and the more aromatic variety filling cells and voids in inertinite as post-gas generation bitumen.

International Journal of Coal Geology↗
USGS2001

Paleomagnetic data bearing on style of Miocene deformation in the Lake Mead area, Southern Nevada

Paleomagnetic and structural data from intermediate to mafic composition lava flows and related dikes in all major blocks of the late Miocene Hamblin-Cleopatra Volcano, which was structurally dismembered during the development of the Lake Mead Fault System (LMFS), provide limits on the magnitude and sense of tilting and vertical axis rotation of crust during extension of this part of the Basin and Range province. Sinistral separation along the fault system dissected the volcano into three major blocks. The eastern, Cleopatra Lobe of the volcano is structurally the most intact section of the volcano. Normal and reverse polarity data from paleomagnetic sites collected along traverses in the Cleopatra Lobe yield an in situ grand mean of Declination (D) = 339??, Inclination (I) = +54??, ??95 = 3.1??, k = 27.2, N = 81 sites. The rocks of the central core of the volcano yield an in situ grand mean of D = 3??, I = + 59??, ??95 = 6.8??, k = 42.5, N = 11 sites (six normal, five reverse polarity). Sites collected within the western Hamblin Lobe of the volcano are exclusively of reverse polarity and yield an overall in situ mean of D = 168??, I = -58??, ??95 = 6.5??. k = 28.9, N = 18 sites. Interpretation of the paleomagnetic data in the context of the structural history of the volcano and surrounding area, considers the possibility of two different types of structural corrections. A stratigraphic tilt correction involves restoring flows to the horizontal using the present strike. This correction assumes no initial, possibly radial, dip of flows of the volcano and is considered invalid. A structural tilt correction to the data assumes that dikes of the radiating swarm associated with the volcano were originally vertical and results in block mean directions of D = 9??, I = +53??, ??95 = 3.1??, k = 27.2, and D = 58??, I = + 78??, ??95 = 6.8, k = 42.5, for the Cleopatra Lobe and the central intrusive core, respectively. The data from the Cleopatra Lobe are slightly discordant, in a clockwise sense, from expected middle- to late-Miocene field directions. The data from the volcano are not consistent with a proposed structural model of uniform, moderate magnitude, statistically significant, counter-clockwise vertical axis rotation of fault-bounded blocks during overall sinsitral displacement along the LMFS. We also analyzed dikes of the northernmost part of the Miocene Wilson Ridge hypabyssal igneous complex, strata of the Triassic Chinle Formation, and basalt flows of the Miocene West End Wash/Callville Mesa volcanic centers. Dikes in the Wilson Ridge pluton and the Triassic strata yield magnetizations with directions suggestive of statistically significant, clockwise, vertical-axis rotations consistent with local, large-magnitude shear of crustal fragments near some of the faults of the LMFS. Late Cenozoic deformation of the Hamblin-Cleopatra volcano area appears to have been non-uniform in scale and magnitude and no single structural model, involving strictly strike-slip faulting, can account for the observed paleomagnetic data. ?? 2001 Elsevier Science Ltd. All rights reserved.

Journal of Structural Geology↗
USGS2002

Miocene extension and fault-related folding in the Highland Range, southern Nevada: A three-dimensional perspective

The Highland Range of southern Nevada contains a major anticline and syncline that constitute the westernmost segments of the Black Mountains accommodation zone in the highly extended Colorado River extensional corridor. The folds are defined by thick tilted sections of Miocene volcanic and sedimentary strata that accumulated immediately prior to and during regional extension. The folds are generally symmetrical, with interlimb angles that exceed 90??, subhorizontal hingelines, and steeply inclined axial surfaces. East- and west-dipping normal faults dominate the west- and east-tilted limbs of the folds, respectively. The limbs of the folds are parts of major half grabens. Tilt fanning within these half grabens and 15 new 40Ar/39Ar dates bracket major extension between about 16.5 and 11 Ma. Tilting of the opposing fold limbs occurred simultaneously and was contemporaneous with extension. The anticline and syncline are therefore interpreted as fault-related extensional folds produced by the partial, along-strike overlap of oppositely dipping normal-fault systems and attendant tilt-block domains. The anticline developed between overlapping listric normal faults that dip toward one another, including the east-dipping McCullough Range and west-dipping Keyhole Canyon faults. Each limb of the anticline is a rollover fold developed in the hanging wall of the inwardly dipping listric normal faults. The syncline formed between overlapping outwardly dipping listric faults, as adjacent fault blocks were tilted toward one another. The dominant folding style was fault-bend folding, with drag-folding and displacement-gradient folding playing subsidiary roles. The anticline and syncline significantly affected depositional patterns, with synextensional units, including two major ash-flow tuffs, thinning toward the anticlinal hinge and thickening toward the synclinal hinge. The Black Mountains accommodation zone is largely composed of intersecting northwest-trending anticlines and northeast-trending synclines, both occurring at a variety of scales depending on the amount of overlap between the opposing normal-fault systems. This three-dimensional geometry contrasts with the typical style of folding in contractional settings and may characterize extensional accommodation zones that include the partial along-strike overlap of multiple, oppositely dipping normal faults. The folds in the Highland Range serve as well-exposed analogues of similar features in hydrocarbon-rich areas of submerged continental margins. ?? 2002 Elsevier Science Ltd. All rights reserved.

Journal of Structural Geology↗
USGS2003

Predicting reservoir-scale faults with area balance: Application to growth stratigraphy

A reservoir that appears to lack faults at one scale of resolution or at one sampling density may nevertheless contain faults that are below the resolution of the observations. The area-depth relationship from a balanced cross-section is shown to contain the necessary information for predicting the sub-resolution fault heave. Existing area-depth theory is extended to include growth units, allowing structural length and thickness changes to be separated from the depositional changes. The technique is validated with a numerical model of a growth full graben and a sand-box model of a half graben; then field tested in the Gilbertown graben, a growth structure within the regional peripheral fault trend along the northern margin of the Gulf of Mexico. A cross-section developed from wells alone is used to infer the abundance of sub-resolution faults by the area-balance technique. A small but significant amount of sub-resolution extension is predicted and then confirmed with a high-resolution seismic line. ?? 2003 Elsevier Science Ltd. All rights reserved.

Journal of Structural Geology↗
USGS1997

Progressive deformation of the Chugach accretionary complex, Alaska, during a paleogene ridge-trench encounter

The Mesozoic accretionary wedge of south-central Alaska is cut by an array of faults including dextral and sinistral strike-slip faults, synthetic and antithetic thrust faults, and synthetic and antithetic normal faults. The three fault sets are characterized by quartz ± calcite ± chlorite ± prehnite slickensides, and are all relatively late, i.e. all truncate ductile fabrics of the host rocks. Cross-cutting relationships suggest that the thrust fault sets predate the late normal and strike-slip fault sets. Together, the normal and strike-slip fault system exhibits orthorhombic symmetry. Thrust faulting shortened the wedge subhorizontally perpendicular to strike, and then normal and strike-slip faulting extended the wedge oblique to orogenic strike. Strongly curved slickenlines on some faults of each set reveal that displacement directions changed over time. On dip-slip faults (thrust and normal), slickenlines tend to become steeper with younger increments of slip, whereas on strike-slip faults, slickenlines become shallower with younger strain increments. These patterns may result from progressive exhumation of the accretionary wedge while the faults were active, with the curvature of the slickenlines tracking the change from a non-Andersonian stress field at depth to a more Andersonian system (σ 1 or σ 2 nearly vertical) at shallower crustal levels. We interpret this complex fault array as a progressive deformation that is one response to Paleocene-Eocene subduction of the Kula-Farallon spreading center beneath the accretionary complex because: (1) on the Kenai Peninsula, ENE-striking dextral faults of this array exhibit mutually cross-cutting relationships with Paleocene-Eocene dikes related to ridge subduction; and (2) mineralized strike-slip and normal faults of the orthorhombic system have yielded 40 Ar/ 39 Ar ages identical to near-trench intrusives related to ridge subduction. Both features are diachronous along-strike, having formed at circa 65 Ma in the west and 50 Ma in the east. Exhumation of deeper levels of the southern Alaska accretionary wedge and formation of this late fault array is interpreted as a critical taper adjustment to subduction of progressively younger oceanic lithosphere yielding a shallower basal de´collement dip as the Kula-Farallon ridge approached the accretionary prism. The late structures also record different kinematic regimes associated with subduction of different oceanic plates, before and after ridge subduction. Prior to triple junction passage, subduction of the Farallon plate occurred at nearly right angles to the trench axis, whereas after triple junction migration, subduction of the Kula plate involved a significant component of dextral transpression and northward translation of the Chugach terrane. The changes in kinematics are apparent in the sequence of late structures from: (1) thrusting; (2) near-trench plutonism associated with normal + strike-slip faulting; (3) very late gouge-filled dextral faults.

Alaska↗
USGS1997

Initiation and growth of gypsum piercement structures in the Zechstein Basin

The importance of tectonic processes in initiating halite diapirs has become much better understood in recent years. Less well understood is the development of diapiric structures involving rocks composed predominantly of gypsum. Below about 1000 m, gypsum dehydrates to anhydrite, which often obscures primary sedimentary textures. If the strain associated with diapiric rise in the rock induces the transition to anhydrite, obliteration of primary features in the gypsum can be expected. In our study, we infer that the diapiric movement in the Werra Anhydrite member of cycle 1 of the Zechstein Formation of Europe occurred before the initial transition of gypsum to anhydrite based on the presence of pseudomorphs of bedded primary gypsum crystals, the overburden lithologies and depositional environment, and the mechanical properties of gypsum, anhydrite and carbonate rocks. Faulting and differential loading of a shallow overburden were the key components in initiating the gypsum diapirism. The transition to anhydrite occurred after burial and after cessation of diapirism. In comparison, the diapirism of calcium sulfate of the Leine Anhydrite into the Leine Halite members of cycle 3 of the Zechstein Formation probably occurred much later after burial and appears to have been triggered by halite diapirism, which in turn triggered the dehydration reaction, causing the calcium sulfate to become the incompetent phase relative to the halite.

Journal of Structural Geology↗
USGS1998

Late Cretaceous to early Tertiary transtension and strain partitioning in the Chugach Accretionary Complex, SE Alaska

Shear zones in the Late Cretaceous Sitka Graywacke of the Chugach accretionary complex in southeast Alaska record constrictional finite strains, with maximum principal s tretches plunging shallowly subparallel to strike of the shear zones. Macrostructural analysis indicates the finite strain formed during one deformation event. Microstructural analysis of the shear zones shows that this deformation is ductile, promoted mostly through deformation of low-strength lithic clasts and pressure solution. Kinematic indicators from some of the shear zones indicate dominantly dextral motion. Although multiple scenarios can explain constrictional finite strains in a shear zone, these dextral strike-slip shear zones must have experienced a component of extension across them in order to generate constrictional finite strains. Therefore, the shear zones are dextral transtensional shear zones, an uncommon tectinic regime in an accretionary complex. The transtensional shear zones reflect strike-slip motion related to partitioning of Late Cretaceous to Early Tertiary right-oblique convergence between North America and the Farallon plate. The extensional component that was superposed on the strike-slip shear zones to generate transtension resulted from contemporaneous collapse of the forearc following thickening related to underplating.Shear zones in the Late Cretaceous Sitka Graywacke of the Chugach accretionary complex in southeast Alaska record constrictional finite strains, with maximum principal stretches plunging shallowy sub-parallel to strike of the shear zones. Macrostructural analysis indicates the finite strain formed during one deformation event. Microstructural analysis of the shear zones shows that this deformation is ductile, promoted mostly through deformation of low-strength lithic clasts and pressure solution. Kinematic indicators from some of the shear zones indicate dominantly dextral motion. Although multiple scenarios can explain constrictional finite strains in a shear zone, these dextral strike-slip shear zones must have experienced a component of extension across them in order to generate constrictional finite strains. Therefore, the shear zones are dextral transtensional shear zones, an uncommon tectonic regime in an accretionary complex. The transtensional shear zones reflect strike-slip motion related to partitioning of Late Cretaceous to Early Tertiary right-oblique convergence between North America and the Farallon plate. The extensional component that was superposed on the strike-slip shear zones to generate transtension resulted from contemporaneous collapse of the forearc following thickening related to underplating.

Journal of Structural Geology↗
USGS2002

Proterozoic metamorphism and uplift history of the north-central Laramie Mountains, Wyoming, USA

The Laramie Mountains of south-eastern Wyoming contain two metamorphic domains that are separated by the 1.76 Ga. Laramie Peak shear zone (LPSZ). South of the LPSZ lies the Palmer Canyon block, where apatite U-Pb ages are c. 1745 Ma and the rocks have undergone Proterozoic kyanite-grade Barrovian metamorphism. In contrast, in the Laramie Peak block, north of the shear zone, the U-Pb apatite ages are 2.4-2.1 Ga, the granitic rocks are unmetamorphosed and supracrustal rocks record only low-T amphibolite facies metamorphism that is Archean in age. Peak mineral assemblages in the Palmer Canyon block include (a) quartz-biotite-plagioclase-garnet-staurolite-kyanite in the pelitic schists; (b) quartz-biotite-plagioclase-low-Ca amphiboles-kyanite in Mg-Al-rich schists, and locally (c) hornblende-plagioclase-garnet in amphibolites. All rock types show abundant textural evidence of decompression and retrograde re-equilibration. Notable among the texturally late minerals are cordierite and sapphirine, which occur in coronas around kyanite in Mg-Al-rich schists. Thermobarometry from texturally early and late assemblages for samples from different areas within the Palmer Canyon block define decompression from > 7 kbar to < 3 kbar. The high-pressure regional metamorphism is interpreted to be a response to thrusting associated with the Medicine Bow orogeny at c. 1.78-1.76 Ga. At this time, the north-central Laramie Range was tectonically thickened by as much as 12 km. This crustal thickening extended for more than 60 km north of the Cheyenne belt in southern Wyoming. Late in the orogenic cycle, rocks of the Palmer Canyon block were uplifted and unroofed as the result of transpression along the Laramie Peak shear zone to produce the widespread decompression textures. The Proterozoic tectonic history of the central Laramie Range is similar to exhumation that accompanied late-orogenic oblique convergence in many Phanerozoic orogenic belts.

Journal of Metamorphic Geology↗
USGS2003

Exhumation of high-pressure rocks beneath the Solund Basin, Western Gneiss Region of Norway

The Solund-Hyllestad-Lavik area affords an excellent opportunity to understand the ultrahigh-pressure Scandian orogeny because it contains a near-complete record of ophiolite emplacement, high-pressure metamorphism and large-scale extension. In this area, the Upper Allochthon was intruded by the c. 434 Ma Sogneskollen granodiorite and thrust eastward over the Middle/Lower Allochthon, probably in the Wenlockian. The Middle/Lower Allochthon was subducted to c. 50 km depth and the structurally lower Western Gneiss Complex was subducted to eclogite facies conditions at c. 80 km depth by c. 410-400 Ma. Within < 5-10 Myr, all these units were exhumed by the Nordfjord-Sogn detachment zone, producing shear strains > 100. Exhumation to upper crustal levels was complete by c. 403 Ma. The Solund fault produced the last few km of tectonic exhumation, bringing the near-ultrahigh-pressure rocks to within c. 3 km vertical distance from the low-grade Solund Conglomerate.

Journal of Metamorphic Geology↗
USGS1958

Contact metamorphism adjacent to a teschenite intrusion

Shale adjacent to the upper contact of an annular teschenite intrusion was converted to andalusite hornfels in an aureole 2–4 feet wide. At some points along the contact there is no evidence of anhydrous recrystallization. Rarely, magmatic reaction with small shale xenoliths resulted in formation of cordierite‐sillimanite (?) hornfelses, and locally a very small‐scale movement of magmatic constituents took place across the contact before consolidation of the teschenite. Very severe deuteric alteration of teschenite adjacent to the contact resulted in large losses of Si, Fe, Mg, alkalis, and probably Ca, some of which were recombined in clays and carbonates in the more porous shales and in joints, but analyses of uniformly fine‐grained shales indicate little change in bulk composition. Mineralogical evidence indicates a maximum contact temperature within the range 500°‐600° C, and a maximum intrusion temperature within the range 1000°‐1200° C.

Journal of the Geological Society of Australia↗
USGS1981

U-Th-Pb systematics of some granitoids from the northeastern Yilgarn Block, Western Australia and implications for uranium source rock potential

The Mount Boreas‐type granite and spatially associated syenitic granitoid of Western Australia yield Pb‐Pb ages of 2370 ± 100 Ma and 2760 ± 210 Ma, respectively. Th‐Pb ages, although less precise, are concordant with these ages, and therefore the apparent ages are interpreted to be the crystallisation ages for these two units. U‐Pb ages are variable and for the most part anomalously old, which suggests a Cainozoic uranium loss. However, this loss is generally small (< 3 μ g/g); therefore, neither granitoid in its fresh state provides a good source for nearby calcrete‐hosted uranium deposits. The possibility remains that the Mount Boreas‐type granite that has been completely weathered during the Tertiary could have been a source for the calcrete‐type uranium deposits in W.A. Although the Mount Boreas‐type granite is highly fractionated, it does not bear a strong geochemical imprint of a sedimentary precursor. This feature contrasts it with apparently fresh granitoids from other parts of the world that have lost large amounts of uranium (∼ 20 μ g/g ) and are associated with large roll‐type and other low temperature‐type uranium deposits.

Journal of the Geological Society of Australia↗