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At least 505 records · Page 28Linked to original sources

Pesticides in US Rivers: Regional differences in use, occurrence, and environmental toxicity, 2013 to 2017

Pesticides pose a threat to the environment, but because of the substantial number of compounds, a comprehensive assessment of pesticides and an evaluation of the risk that they pose to human and aquatic life is challenging. In this study, improved analytical methods were used to quantify 221 pesticide concentrations in surface waters over the time period from 2013 to 2017. Samples were collected from 74 river sites in the conterminous US (CONUS). Potential toxicity was assessed by comparing surface water pesticide concentrations to standard concentrations that are considered to have adverse effects on human health or aquatic organisms. The majority of pesticide use is related to agriculture, and agricultural production varies across the CONUS. Therefore, our results were summarized by region (Northeast, South, Midwest, West and Pacific), with the expectation that crop production differences would drive variability in pesticide use, detection frequency, and benchmark exceedance patterns. Although agricultural pesticide use was at least 2.5 times higher in the Midwest (49 kg km −2 ) than in any of the other four regions (Northeast, South, West, and Pacific, 3 to 21 kg km −2 ) and the average number of pesticides detected in the Midwest was at least 1.5 higher ( n = 25) than the other four regions ( n = 8 to n = 16), the potential toxicity results were more evenly distributed. At least 50% of the sites within each of the 5 regions had at least 1 chronic benchmark exceedance. Imidacloprid posed the greatest potential threat to aquatic life with a total of 245 benchmark exceedances at 60 of the 74 sites. These results show that pesticides persist in the environment beyond the site of application and expected period of use. Continued monitoring and research are needed to improve our understanding of pesticide effects on aquatic and human life.

Science of the Total Environment↗

Landscape transcriptomics as a tool for addressing global change effects across diverse species

Landscape transcriptomics is an emerging field studying how genome-wide expression patterns reflect dynamic landscape-scale environmental drivers, including habitat, weather, climate, and contaminants, and the subsequent effects on organismal function. This field is benefitting from advancing and increasingly accessible molecular technologies, which in turn are allowing the necessary characterization of transcriptomes from wild individuals distributed across natural landscapes. This research is especially important given the rapid pace of anthropogenic environmental change and potential impacts that span levels of biological organization. We discuss three major themes in landscape transcriptomic research: connecting transcriptome variation across landscapes to environmental variation, generating and testing hypotheses about the mechanisms and evolution of transcriptomic responses to the environment, and applying this knowledge to species conservation and management. We discuss challenges associated with this approach and suggest potential solutions. We conclude that landscape transcriptomics has great promise for addressing fundamental questions in organismal biology, ecology, and evolution, while providing tools needed for conservation and management of species.

Molecular Ecology Resources↗

Estimating groundwater pumping for irrigation: A method comparison

Effective groundwater management is critical to future environmental, ecological, and social sustainability and requires accurate estimates of groundwater withdrawals. Unfortunately, these estimates are not readily available in most areas due to physical, regulatory, and social challenges. Here, we compare four different approaches for estimating groundwater withdrawals for agricultural irrigation. We apply these methods in a groundwater-irrigated region in the state of Kansas, USA, where high-quality groundwater withdrawal data are available for evaluation. The four methods represent a broad spectrum of approaches: (1) the hydrologically-based Water Table Fluctuation method (WTFM); (2) the demand-based SALUS crop model; (3) estimates based on satellite-derived evapotranspiration (ET) data from OpenET; and (4) a landscape hydrology model which integrates hydrologic- and demand-based approaches. The applicability of each approach varies based on data availability, spatial and temporal resolution, and accuracy of predictions. In general, our results indicate that all approaches reasonably estimate groundwater withdrawals in our region, however, the type and amount of data required for accurate estimates and the computational requirements vary among approaches. For example, WTFM requires accurate groundwater levels, specific yield, and recharge data, whereas the SALUS crop model requires adequate information about crop type, land use, and weather. This variability highlights the difficulty in identifying what data, and how much, are necessary for a reasonable groundwater withdrawal estimate, and suggests that data availability should drive the choice of approach. Overall, our findings will help practitioners evaluate the strengths and weaknesses of different approaches and select the appropriate approach for their application.

Kansas↗

Development of an assessment tool for agricultural best management practice implementation in the Great Lakes Restoration Initiative priority watersheds—Upper East River, tributary to Green Bay, Wisconsin

Introduction The Great Lakes face a number of serious challenges that cause damage to water quality, habitat, ecology, and coastal health. Excess nutrients from point and nonpoint sources have a history of causing harmful algal blooms (HABs); since the late 1990s, a resurgence of HABs have forced beach closures and resulted in water quality impairments across the Great Lakes. Studies increasingly point to phosphorus (P) runoff from agricultural lands as the cause of these HABs. In 2010, the Great Lakes Restoration Initiative (GLRI) was launched to revitalize the Great Lakes. The GLRI aims to address the challenges facing the Great Lakes and provide a framework for restoration and protection. As part of this effort, the Priority Watersheds Work Group (PWWG), cochaired by the U.S. Environmental Protection Agency (EPA) and the U.S. Department of Agriculture-Natural Resources Conservation Service (USDA–NRCS), is targeting Priority Watersheds (PWs) to reduce the amount of P reaching the Great Lakes. Within the PWs, USDA–NRCS identifies small-scale subbasins with high concentrations of agriculture for coordinated nutrient reduction efforts and enhanced monitoring and modeling. The USDA–NRCS supplies financial and/or technical assistance to producers to install or implement best management practices (BMPs) to lessen the negative effects of agriculture to water quality; additional funding is provided by the GLRI through USDA–NRCS to saturate the small-scale subbasins with BMPs. The watershed modeling component, introduced in this fact sheet, assesses the effectiveness of USDA–NRCS funded BMPs, and nutrient reductions because of GLRI or other funding programs are differentiated. Modeling scenarios consider BMPs that have already been applied and those planned to be implemented across the small-scale subbasins.

Wisconsin↗

Development of an assessment tool for agricultural best management practice implementation in the Great Lakes restoration initiative priority watersheds—Eagle Creek, tributary to Maumee River, Ohio

Introduction The Great Lakes face a number of serious challenges that cause damage to water quality, habitat, ecology, and coastal health. Excess nutrients from point and nonpoint sources have a history of causing harmful algal blooms (HABs); since the late 1990s, a resurgence of HABs have forced beach closures and resulted in water quality impairments across the Great Lakes. Studies increasingly point to phosphorus (P) runoff from agricultural lands as the cause of these HABs. In 2010, the Great Lakes Restoration Initiative (GLRI) was launched to revitalize the Great Lakes. The GLRI aims to address the challenges facing the Great Lakes and provide a framework for restoration and protection. As part of this effort, the Priority Watersheds Work Group (PWWG), cochaired by the U.S. Environmental Protection Agency (EPA) and the U.S. Department of Agriculture-Natural Resources Conservation Service (USDA–NRCS), is targeting Priority Watersheds (PWs) to reduce the amount of P reaching the Great Lakes. Within the PWs, USDA–NRCS identifies small-scale subbasins with high concentrations of agriculture for coordinated nutrient reduction efforts and enhanced monitoring and modeling. The USDA–NRCS supplies financial and/or technical assistance to producers to install or implement best management practices (BMPs) to lessen the negative effects of agriculture to water quality; additional funding is provided by the GLRI through USDA–NRCS to saturate the small-scale subbasins with BMPs. The watershed modeling component, introduced in this fact sheet, assesses the effectiveness of USDA–NRCS funded BMPs, and nutrient reductions because of GLRI or other funding programs are differentiated. Modeling scenarios consider BMPs that have already been applied and those planned to be implemented across the small-scale subbasins.

Ohio↗

Development of an assessment tool for agricultural best management practice Implementation in the Great Lakes Restoration Initiative priority watersheds—Alger Creek, tributary to Saginaw River, Michigan

The Great Lakes face a number of serious challenges that cause damage to water quality, habitat, ecology, and coastal health. Excess nutrients from point and nonpoint sources have a history of causing harmful algal blooms (HABs); since the late 1990s, a resurgence of HABs have forced beach closures and resulted in water quality impairments across the Great Lakes. Studies increasingly point to phosphorus (P) runoff from agricultural lands as the cause of these HABs. In 2010, the Great Lakes Restoration Initiative (GLRI) was launched to revitalize the Great Lakes. The GLRI aims to address the challenges facing the Great Lakes and provide a framework for restoration and protection. As part of this effort, the Priority Watersheds Work Group (PWWG), cochaired by the U.S. Environmental Protection Agency (EPA) and the U.S. Department of Agriculture-Natural Resources Conservation Service (USDA–NRCS), is targeting Priority Watersheds (PWs) to reduce the amount of P reaching the Great Lakes. Within the PWs, USDA–NRCS identifies small-scale subbasins with high concentrations of agriculture for coordinated nutrient reduction efforts and enhanced monitoring and modeling. The USDA–NRCS supplies financial and/or technical assistance to producers to install or implement best management practices (BMPs) to lessen the negative effects of agriculture to water quality; additional funding is provided by the GLRI through USDA–NRCS to saturate the small-scale subbasins with BMPs. The watershed modeling component, introduced in this fact sheet, assesses the effectiveness of USDA–NRCS funded BMPs, and nutrient reductions because of GLRI or other funding programs are differentiated. Modeling scenarios consider BMPs that have already been applied and those planned to be implemented across the small-scale subbasins.

Michigan↗

Drought, deluge and declines: the impact of precipitation extremes on amphibians in a changing climate

The Class Amphibia is one of the most severely impacted taxa in an on-going global biodiversity crisis. Because amphibian reproduction is tightly associated with the presence of water, climatic changes that affect water availability pose a particularly menacing threat to both aquatic and terrestrial-breeding amphibians. We explore the impacts that one facet of climate change—that of extreme variation in precipitation—may have on amphibians. This variation is manifested principally as increases in the incidence and severity of both drought and major storm events. We stress the need to consider not only total precipitation amounts but also the pattern and timing of rainfall events. Such rainfall “pulses” are likely to become increasingly more influential on amphibians, especially in relation to seasonal reproduction. Changes in reproductive phenology can strongly influence the outcome of competitive and predatory interactions, thus potentially altering community dynamics in assemblages of co-existing species. We present a conceptual model to illustrate possible landscape and metapopulation consequences of alternative climate change scenarios for pond-breeding amphibians, using the Mole Salamander, Ambystoma talpoideum , as an example. Although amphibians have evolved a variety of life history strategies that enable them to cope with environmental uncertainty, it is unclear whether adaptations can keep pace with the escalating rate of climate change. Climate change, especially in combination with other stressors, is a daunting challenge for the persistence of amphibians and, thus, the conservation of global biodiversity.

Biology↗

Interactions between chemical and climate stressors: A role for mechanistic toxicology in assessing climate change risks

Incorporation of global climate change (GCC) effects into assessments of chemical risk and injury requires integrated examinations of chemical and nonchemical stressors. Environmental variables altered by GCC (temperature, precipitation, salinity, pH) can influence the toxicokinetics of chemical absorption, distribution, metabolism, and excretion as well as toxicodynamic interactions between chemicals and target molecules. In addition, GCC challenges processes critical for coping with the external environment (water balance, thermoregulation, nutrition, and the immune, endocrine, and neurological systems), leaving organisms sensitive to even slight perturbations by chemicals when pushed to the limits of their physiological tolerance range. In simplest terms, GCC can make organisms more sensitive to chemical stressors, while alternatively, exposure to chemicals can make organisms more sensitive to GCC stressors. One challenge is to identify potential interactions between nonchemical and chemical stressors affecting key physiological processes in an organism. We employed adverse outcome pathways, constructs depicting linkages between mechanism-based molecular initiating events and impacts on individuals or populations, to assess how chemical- and climate-specific variables interact to lead to adverse outcomes. Case examples are presented for prospective scenarios, hypothesizing potential chemical–GCC interactions, and retrospective scenarios, proposing mechanisms for demonstrated chemical–climate interactions in natural populations. Understanding GCC interactions along adverse outcome pathways facilitates extrapolation between species or other levels of organization, development of hypotheses and focal areas for further research, and improved inputs for risk and resource injury assessments.

Environmental Toxicology and Chemistry↗

Exploring the potential value of satellite remote sensing to monitor chlorophyll-a for U.S. lakes and reservoirs

Assessment of chlorophyll-a, an algal pigment, typically measured by field and laboratory in situ analyses, is used to estimate algal abundance and trophic status in lakes and reservoirs. In situ-based monitoring programs can be expensive, may not be spatially, and temporally comprehensive and results may not be available in the timeframe needed to make some management decisions, but can be more accurate, precise, and specific than remotely sensed measures. Satellite remotely sensed chlorophyll-a offers the potential for more geographically and temporally dense data collection to support estimates when used to augment or substitute for in situ measures. In this study, we compare available chlorophyll-a data from in situ and satellite imagery measures at the national scale and perform a cost analysis of these different monitoring approaches. The annual potential avoided costs associated with increasing the availability of remotely sensed chlorophyll-a values were estimated to range between $5.7 and $316 million depending upon the satellite program used and the timeframe considered. We also compared sociodemographic characteristics of the regions (both public and private lands) covered by both remote sensing and in situ data to check for any systematic differences across areas that have monitoring data. This analysis underscores the importance of continued support for both field-based in situ monitoring and satellite sensor programs that provide complementary information to water quality managers, given increased challenges associated with eutrophication, nuisance, and harmful algal bloom events.

Environmental Monitoring and Assessment↗

Competitive interactions among H, CU, and Zn ion moderate aqueous uptake of Cu and Zn by an aquatic insect

The absorption of aqueous copper (Cu) and zinc (Zn) by aquatic insects, a group widely used to assess water quality, is unresolved. This study examined interactions among Cu, Zn, and protons that potentially moderate Cu and Zn uptake by the acid-tolerant stonefly Zapada sp. Saturation uptake kinetics was imposed to identify competitive mechanisms. Decreasing pH reduced the maximum transport capacity, Jmax, in both metals, had little effect on the Cu dissociation constant, KD, and increased the Zn KD. Partial noncompetitive (Cu) and partial mixed competitive (Zn) inhibitor models most closely tracked the observed Cu and Zn influx across pH treatments. The estimated values for acid dissociation constants for the binary (proton-receptor) and ternary (proton-metal-receptor) complexes indicated the strong inhibitory effect of protons on Cu and Zn. In neutral pH water, Cu inhibited Zn uptake, but Zn had little effect on Cu uptake. The mechanism of Cu-Zn interaction was not identified. Results from separate Zn experiments suggested that the insect’s developmental stage may affect the apparent Jmax. The study underscores some of the challenges of modeling metal bioaccumulation and informs future research directions.

Environmental Pollution↗

Potential Environmental and Environmental-Health Implications of the SAFRR Tsunami Scenario in California: Chapter F in The SAFRR (Science Application for Risk Reduction) Tsunami Scenario

The California Tsunami Scenario models the impacts of a hypothetical, yet plausible, tsunami caused by an earthquake offshore from the Alaska Peninsula. In this chapter, we interpret plausible tsunami-related contamination, environmental impacts, potential for human exposures to contaminants and hazardous materials, and implications for remediation and recovery. Inundation-related damages to major ports, boat yards, and many marinas could release complex debris, crude oil, various fuel types and other petroleum products, some liquid bulk cargo and dry bulk cargo, and diverse other pollutants into nearby coastal marine environments and onshore in the inundation zone. Tsunami-induced erosion of contaminated harbor bottom sediments could re-expose previously sequestered metal and organic pollutants (for example, organotin or DDT). Inundation-related damage to many older buildings could produce debris containing lead paint, asbestos, pesticides, and other legacy contaminants. Intermingled household debris and externally derived debris and sediments would be left in flooded buildings. Post tsunami, mold would likely develop in inundated houses, buildings, and debris piles. Tsunamigenic fires in spilled oil, debris, cargo, vehicles, vegetation, and residential, commercial, or industrial buildings and their contents would produce potentially toxic gases and smoke, airborne ash, and residual ash/debris containing caustic alkali solids, metal toxicants, asbestos, and various organic toxicants. Inundation of and damage to wastewater treatment plants in many coastal cities could release raw sewage containing fecal solids, pathogens, and waste chemicals, as well as chemicals used to treat wastewaters. Tsunami-related physical damages, debris, and contamination could have short- and longer-term impacts on the environment and the health of coastal marine and terrestrial ecosystems. Marine habitats in intertidal zones, marshes, sloughs, and lagoons could be damaged by erosion or sedimentation, and could receive an influx of debris, metal and organic contaminants, and sewage-related pathogens. Debris and re-exposed contaminated sediments would be a source of sea- or rain-water-leachable metal and organic contaminants that could pose chronic toxicity threats to ecosystems. If human populations are successfully evacuated prior to the tsunami arrival, there would be no or limited numbers of drownings, other casualties, or related injuries, wounds, and infections. Immediately after the tsunami, human populations away from the inundation zone could be transiently exposed to airborne gases, smoke, and ash from tsunamigenic fires. Cleanup and disposal, particularly of hazardous materials, would pose substantial logistical challenges and economic costs. Given the high value of the coastal residential and commercial properties in the inundation zone, it can be postulated that there would be substantial insurance claims for environmental restoration, mold mitigation, disposal of debris that contains hazardous materials, and costs of litigation related to environmental liability. Post-tsunami cleanup, if done with appropriate mitigation (for example, dust control), personal protection, and disposal measures, would help reduce the potential for cleanup-worker and resident exposures to toxicants and pathogens in harbor waters, debris, soils, ponded waters, and buildings. A number of other steps can be taken by governments, businesses, and residents to help reduce the environmental impacts of tsunamis and to recover more quickly from these environmental impacts. For example, development of State and local policies that foster rapid assessment of potential contamination, as well as rapid decision making for disposal options should hazardous debris or sediment be identified, would help enhance recovery by speeding cleanup.

California↗

Toxicity of carbon dioxide to freshwater fishes: Implications for aquatic invasive species management

Carbon dioxide (CO 2 ) has been approved by the US Environmental Protection Agency as a new aquatic pesticide to control invasive Asian carps and other aquatic nuisance species in the United States. However, limited CO 2 toxicity data could make it challenging for resource managers to characterize the potential risk to nontarget species during CO 2 applications. The present study quantified the toxicity of CO 2 to 2 native riverine fishes, bluegill ( Lepomis macrochirus ) and fathead minnow ( Pimephales promelas ), using 12‐h continuous flow‐through CO 2 exposure at 5, 15, and 25 °C water temperatures. Resulting survival indicated that bluegill (median lethal concentration [LC50] range 91–140 mg/L CO 2 ) were more sensitive to CO 2 than fathead minnow (LC50 range 235–306 mg/L CO 2 ) across all water temperatures. Bluegill were also more sensitive to CO 2 at 5 °C (LC50 91 mg/L CO 2 , 95% CI 85–96 mg/L CO 2 ) than at 25 °C (LC50 140 mg/L CO 2 , 95% CI 135–146 mg/L CO 2 ). Fathead minnow showed an opposite response and were less sensitive at 5 °C (LC50 306 mg/L CO 2 , 95% CI 286–327 mg/L CO 2 ) relative to 25 °C (LC50 235 mg/L CO 2 , 95% CI 224–246 mg/L CO 2 ). Our results show that CO 2 toxicity can differ by species and water temperature. Data from the present study may inform decisions related to the use of CO 2 as a control tool. Environ Toxicol Chem 2020;39:2247–2255. Published 2020. This article is a U.S. government work and is in the public domain in the USA.

Environmental Toxicology and Chemistry (ET&C)↗

Leveraging artificial intelligence and machine learning to advance Chesapeake Bay research and management: A review of status, challenges, and opportunities

The Chesapeake Bay and its watershed (hereafter “Chesapeake Bay region”) have been the focus of extensive restoration efforts for several decades. These restoration efforts are guided by the Chesapeake Bay Watershed Agreement (Chesapeake Executive Council 2014) which outlines 10 goals and 31 measurable outcomes. The Chesapeake Bay is globally recognized as a model for coastal restoration due to long-term investments in monitoring, modeling, implementation and research by the Chesapeake Bay Program (CBP) partnership. These monitoring network spans tidal and non-tidal regions and provides data across multiple scales. Artificial intelligence (AI), particularly machine-learning (ML) and deep learning (DL), has emerged as a powerful tool for analyzing large, complex datasets. These techniques have gained widespread adoption across various disciplines, including ecology, hydrology, and environmental science. In the Bay context, AI/ML is increasingly being used to explore drivers of environmental change, analyze system dynamics, and predict conditions in areas with limited monitoring. The CBP partnership, particularly its Scientific and Technical Advisory Committee (STAC), has increasingly recognized the growing role of AI/ML in watershed and estuarine management. Recent Chesapeake Community Research Symposium sessions and initiatives such as the Chesapeake Global Collaboratory highlight increasing regional momentum to apply big data and AI/ML for environmental solutions. Together, these developments underscore the timely need to explore how AI/ML can help advance Chesapeake Bay restoration and management. This STAC workshop, titled “Leveraging Artificial Intelligence and Machine learning to Advance Chesapeake Bay Research and Management: A review of status, challenges, and opportunities,” was held from February 24-25, 2025, in Edgewater, Maryland to bring together over 50 federal, state, and academic scientists and partners to synthesize the current state of AI/ML applications and identify research gaps in Chesapeake Bay research and management. The workshop focused on three main objectives: 1. Summarize recent AI/ML applications and lessons learned in both tidal and nontidal areas of the Chesapeake Bay region. 2. Identify challenges and gaps in applying AI/ML approaches to Chesapeake Bay data. Such challenges and gaps may include data limitations, harmonization issues, ineffective communication of AI/ML insights, and a lack of coordination among research and management institutions. 3. Develop recommendations and identify opportunities for leveraging AI/ML to address issues across the Chesapeake Bay region. Key areas of focus may include generating new information to support watershed management, delivering AI/MLgenerated insights to managers in a clear and actionable way, and fostering greater collaboration among stakeholders within the CBP Partnership. Workshop participants engaged in science presentations and breakout sessions to develop recommendations for advancing the integration of AI/ML techniques into research and management across the Chesapeake Bay region. By synthesizing current applications, identifying challenges, and exploring new opportunities, the workshop has provided valuable insights and recommendations for better leveraging AI/ML approaches to support the success of Bay restoration efforts. Together, these recommendations provide a roadmap for enhancing data-driven, science-based decision making aligned with the goals and outcomes of the Chesapeake Bay Watershed Agreement.

Delaware, Maryland, Virginia↗

A Comparison of Natural and Urban Characteristics and the Development of Urban Intensity Indices Across Six Geographic Settings

As part of the U.S. Geological Survey National Water-Quality Assessment Program, the effects of urbanization on stream ecosystems have been intensively investigated in six metropolitan areas in the United States. Approximately 30 watersheds in each area, ranging in size from 4 to 560 square kilometers (median is 50 square kilometers), and spanning a development gradient from very low to very high urbanization, were examined near Atlanta, Georgia; Raleigh, North Carolina; Denver, Colorado; Dallas-Fort Worth, Texas; Portland, Oregon; and Milwaukee-Green Bay, Wisconsin. These six studies are a continuation of three previous studies in Boston, Massachusetts; Birmingham, Alabama; and Salt Lake City, Utah. In each study, geographic information system data for approximately 300 variables were assembled to (a) characterize the environmental settings of the areas and (b) establish a consistent multimetric urban intensity index based on locally important land-cover, infrastructure, and socioeconomic variables. This paper describes the key features of urbanization and the urban intensity index for the study watersheds within each area, how they differ across study areas, and the relation between the environmental setting and the characteristics of urbanization. A number of features of urbanization were identified that correlated very strongly to population density in every study area. Of these, road density had the least variability across diverse geographic settings and most closely matched the multimetric nature of the urban intensity index. A common urban intensity index was derived that ranks watersheds across all six study areas. Differences in local natural settings and urban geography were challenging in (a) identifying consistent urban gradients in individual study areas and (b) creating a common urban intensity index that matched the site scores of the local urban intensity index in all areas. It is intended that the descriptions of the similarities and differences in urbanization and environmental settings across these study areas will provide a foundation for understanding and interpreting the effects of urbanization on stream ecosystems in the studies being conducted as part of the National Water-Quality Assessment Program.

Scientific Investigations Report↗

The Global Observation System for Mercury dataset for mercury stable isotope signatures in environmental media

The natural variability in the abundance ratios of stable isotopes of mercury (Hg), which collectively forms its isotopic composition, provides information on Hg sources and biogeochemical pathways. Modern mass spectrometry has allowed for measurement of Hg isotope ratios across atmospheric, aquatic, and terrestrial compartments, often at trace levels. Since realizing the utility of Hg isotope ratios, hundreds of studies have generated a wealth of data that is increasingly challenging to summarize and interpret for individual scientists. Arising as a complimentary initiative under the Global Observation System for Mercury (GOS 4 M) that supports the Minamata Convention on Mercury, we describe the establishment of the iGOS 4 M Hg isotope dataset. In its present form, iGOS 4 M has > 11,000 data entries from 190 studies, which together with metadata on sample type, geographical location, Hg concentration, and other environmental and ecological parameters, provide a long-needed catalogue of knowledge gathered by and for the Hg isotope community. We introduce the structure of iGOS 4 M and a standardization rubric to promote global consistency in measurement and data reporting.

Scientific Data↗

From subsidies to stressors: Shifting ecological baselines alter biological responses to nutrients in highly modified agricultural streams

Subsidy–stress gradients offer a useful framework for understanding ecological responses to perturbation and may help inform ecological metrics in highly modified systems. Historic, region-wide shifts from bottomland hardwood forest to row crop agriculture can cause positively skewed impact gradients in alluvial plain ecoregions, resulting in tolerant organisms that typically exhibit a subsidy response (increased abundance in response to environmental stressors) shifting to a stress response (declining abundance at higher concentrations). As a result, observed biological tolerance in modified ecosystems may differ from less modified regions, creating significant challenges for detecting biological responses to restoration efforts. Using the agriculturally dominated Mississippi Alluvial Plain (MAP) ecoregion in Mississippi, USA, as a case study, we tested the hypothesis that macroinvertebrate taxa that typically display a subsidy response to nutrient enrichment in less modified ecoregions (i.e., nutrient-tolerance) shift to a stress response to increasing nutrients in highly modified watersheds with elevated baseline nutrient conditions (i.e., nutrient intolerance). The abundance and diversity of MAP-specific intolerant taxa identified with threshold indicator taxa analysis were either unresponsive or exhibited a subsidy response to increasing nutrients in less modified ecoregions in Mississippi with less land alteration and lower nutrient concentrations, but declined at higher concentrations, providing evidence for a stress response to elevated nutrients in the MAP. Additionally, MAP-specific tolerant and intolerant taxa richness responded to increased nutrients predictably and consistently across space and time within the MAP. However, in MAP streams, elevated specific conductance was predicted to dampen the response of tolerant and intolerant taxa richness to increasing nutrient concentrations, highlighting the importance of considering multistressor interactions when interpreting biological data. Lastly, we demonstrate the efficacy of this approach with sediment bacterial communities characterized with amplicon sequencing, which lack sufficient life history characteristics necessary for the development of multimetric indices. Both macroinvertebrate and bacterial communities responded similarly to increasing nutrient concentrations, suggesting DNA-based approaches may provide an efficient biological assessment tool for monitoring water quality improvements in highly modified watersheds.

Mississippi↗

The added value of time-variable microgravimetry to the understanding of how volcanoes work

During the past few decades, time-variable volcano gravimetry has shown great potential for imaging subsurface processes at active volcanoes (including some processes that might otherwise remain “hidden”), especially when combined with other methods (e.g., ground deformation, seismicity, and gas emissions). By supplying information on changes in the distribution of bulk mass over time, gravimetry can provide information regarding processes such as magma accumulation in void space, gas segregation at shallow depths, and mechanisms driving volcanic uplift and subsidence. Despite its potential, time-variable volcano gravimetry is an underexploited method, not widely adopted by volcano researchers or observatories. The cost of instrumentation and the difficulty in using it under harsh environmental conditions is a significant impediment to the exploitation of gravimetry at many volcanoes. In addition, retrieving useful information from gravity changes in noisy volcanic environments is a major challenge. While these difficulties are not trivial, neither are they insurmountable; indeed, creative efforts in a variety of volcanic settings highlight the value of time-variable gravimetry for understanding hazards as well as revealing fundamental insights into how volcanoes work. Building on previous work, we provide a comprehensive review of time-variable volcano gravimetry, including discussions of instrumentation, modeling and analysis techniques, and case studies that emphasize what can be learned from campaign, continuous, and hybrid gravity observations. We are hopeful that this exploration of time-variable volcano gravimetry will excite more scientists about the potential of the method, spurring further application, development, and innovation.

Earth-Science Reviews↗

Recent seasonal variations in arid landscape cover and aeolian sand mobility, Navajo Nation, southwestern U.S.

The socioeconomic impacts of climate change pose problems not only in devel- oping countries but also to residents of arid lands in the United States among marginalized societies with limited economic means. In the Navajo Nation, warming temperatures and recent drought have increased aeolian sediment mobility such that large, migrating sand dunes affect grazing lands, housing, and road access. Dust derived from this region also affects albedo and longevity of the Rocky Mountains snowpack, located downwind. We present initial results from a study that monitors sand transport and vegetation within a 0.2 km2 site in the Navajo lands, measuring the effects of drought on landscape stability since 2009. Sand mobility decreased substantially as 1 year with near-normal monsoon rainfall (2010) somewhat abated a decade-long drought, temporarily doubling vegetation cover. Vegetation that grew during 2010, with adequate rain, died off rapidly during dry conditions in 2011. Short-term increases in rainfall that promote annual, but not perennial, plant growth will not improve landscape stability in the long term. Climate projections suggest that a warmer, drier climate and potentially enhanced sediment supply from ephem- eral washes will further increase aeolian sand transport and dune activity, worsening the present challenges to people living in this region. Connections among climate, vegetation, and aeolian sediment erodibility in this region are highly relevant to other areas of the world with similar environmental problems.

Arizona↗