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[No abstract available]
The authors regret that two sets of data (Atacama (Rao et al., 2010) and Mars Meteorite Range (Kounaves et al., 2014)) in Fig. 2 of our article were plotted in the wrong units. The correction does not change the relationship between ClO 3 − "> ClO3− and ClO 4 − "> ClO4− ; it only shifts the magnitude of the concentrations. The conclusions of the article are not affected. The corrected Fig. 2 appears below.
In a recent contribution [1] , Johnson et al. reported the equilibrium isotope fractionation factor between dissolved Fe(II) and Fe(III) in aqueous solutions at pH=2.5 and 5.5. They suggest that because the iron isotope fractionation observed in their experiments spans virtually the entire range observed in sedimentary rocks, Fe(II)–Fe(III) aqueous speciation may play a major role in determining iron isotope variations in nature where Fe(II) and Fe(III) can become physically separated. They discounted earlier conclusions by us and others [2] ; [3] that significant equilibrium fractionation between specific coexisting Fe(II)- or Fe(III)-aqueous complexes (e.g., between aqueous Fe(II)(OH) x(aq) and Fe(II) (aq) ion) is capable of producing iron isotope contrasts that can be preserved in nature. This is an important contribution not only because the authors recognize the importance of abiotic equilibrium iron isotope fractionation in nature in contrast to previous assertions [4] , but also because it will help to focus discussion on the development and evaluation of experimental approaches that can reveal abiotic fractionation mechanisms. However, in this Comment we propose that the experiments presented in this paper cannot be interpreted as straightforwardly as Johnson et al. contend. In particular, we show that in one of their critical experiments attainment of either isotope mass balance or equilibrium was not demonstrated, and thus the results of that experiment cannot be used to calculate an Fe(II)–Fe(III) equilibrium fractionation factor.
No abstract available.
The Queen Charlotte-Fairweather Fault (QC-FF) system off the coast of British Columbia and southeast Alaska is a highly active dextral strike-slip plate boundary that accommodates ∼50 mm/yr of relative motion between the Pacific and North America plates. Nine M W ≥ 6.7 earthquakes have occurred along the QC-FF system since 1910, including a M S (G-R) 8.1 event in 1949. Two recent earthquakes, the October 28, 2012 Haida Gwaii ( M W 7.8) and January 5, 2013 Craig, Alaska ( M W 7.5) events, produced postseismic transient deformation that was recorded in the motions of 25 nearby continuous Global Positioning System (cGPS) stations. Here, we use 5+ yr of cGPS measurements to characterize the underlying mechanisms of postseismic deformation and to constrain the viscosity structure of the upper mantle surrounding the QC-FF. We construct forward models of viscoelastic deformation driven by coseismic stress changes from these two earthquakes and explore a large set of laterally heterogeneous viscosity structures that incorporate a relatively weak back-arc domain; we then evaluate each model based on its fit to the postseismic signals in our cGPS data. In determining best-fit model structures, we additionally incorporate the effects of afterslip following the 2012 event. Our results indicate the occurrence of a combination of temporally decaying afterslip and vigorous viscoelastic relaxation of the mantle asthenosphere. In addition, our best-fit viscosity structure (transient viscosity of 1.4–2.0 × 10 18 Pa s; steady-state viscosity of 10 19 Pa s) is consistent with the range of upper mantle viscosities determined in previous studies of glacial isostatic rebound and postseismic deformation.
Secular, annual, and semiannual changes were obtained from the midnight values of field on specially determined days of quiet magnetospheric conditions. From a selection of North American observatories the latitude variation of these changes was evaluated from 20° to 65°. Results for the active and quiet sun years (1958 and 1965) were compared, and changes at Tucson were traced from 1958 through 1974. The year-to-year variance in the determination of a secular change seemed to be decreased by the present analysis method in comparison to a method which uses the annual mean of hourly values. The annual horizontal field variations were largely northward in early summer and southward in early winter; quiet year amplitudes of 2 to 3 γ about doubled in the solar active year. The amplitudes of the semiannual field vectors were about one half that of the annual vectors; the directions were apparently inconsistent from year to year.
A spherical harmonic expansion to degree and order 29 is derived using a selected magnetically quiet sample of Magsat data. Global maps representing the contribution due to terms of the expansion above n = 13 at 400 km altitude are compared with previously published residual anomaly maps and shown to be similar, even in polar regions. An expansion with such a high degree and order displays all but the sharpest features seen by the satellite and gives a more consistent picture of the high-order field structure at a constant altitude than do component maps derived independently.
No abstract available.
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Malaria is a major global public health problem, particularly in Sub-Saharan Africa. The spatial heterogeneity of malaria can be affected by factors such as hydrological processes, physiography, and land cover patterns. Tropical wetlands, for example, are important hydrological features that can serve as mosquito breeding habitats. Mapping and monitoring of wetlands using satellite remote sensing can thus help to target interventions aimed at reducing malaria transmission. The objective of this study was to map wetlands and other major land cover types in the Amhara region of Ethiopia and to analyze district-level associations of malaria and wetlands across the region. We evaluated three random forests classification models using remotely sensed topographic and spectral data based on Shuttle Radar Topographic Mission (SRTM) and Landsat TM/ETM+ imagery, respectively. The model that integrated data from both sensors yielded more accurate land cover classification than single-sensor models. The resulting map of wetlands and other major land cover classes had an overall accuracy of 93.5%. Topographic indices and subpixel level fractional cover indices contributed most strongly to the land cover classification. Further, we found strong spatial associations of percent area of wetlands with malaria cases at the district level across the dry, wet, and fall seasons. Overall, our study provided the most extensive map of wetlands for the Amhara region and documented spatiotemporal associations of wetlands and malaria risk at a broad regional level. These findings can assist public health personnel in developing strategies to effectively control and eliminate malaria in the region.
Reducing uncertainty in data inputs at relevant spatial scales can improve tidal marsh forecasting models, and their usefulness in coastal climate change adaptation decisions. The Marsh Equilibrium Model (MEM), a one-dimensional mechanistic elevation model, incorporates feedbacks of organic and inorganic inputs to project elevations under sea-level rise scenarios. We tested the feasibility of deriving two key MEM inputs—average annual suspended sediment concentration (SSC) and aboveground peak biomass—from remote sensing data in order to apply MEM across a broader geographic region. We analyzed the precision and representativeness (spatial distribution) of these remote sensing inputs to improve understanding of our study region, a brackish tidal marsh in San Francisco Bay, and to test the applicable spatial extent for coastal modeling. We compared biomass and SSC models derived from Landsat 8, DigitalGlobe WorldView-2, and hyperspectral airborne imagery. Landsat 8-derived inputs were evaluated in a MEM sensitivity analysis. Biomass models were comparable although peak biomass from Landsat 8 best matched field-measured values. The Portable Remote Imaging Spectrometer SSC model was most accurate, although a Landsat 8 time series provided annual average SSC estimates. Landsat 8-measured peak biomass values were randomly distributed, and annual average SSC (30 mg/L) was well represented in the main channels (IQR: 29–32 mg/L), illustrating the suitability of these inputs across the model domain. Trend response surface analysis identified significant diversion between field and remote sensing-based model runs at 60 yr due to model sensitivity at the marsh edge (80–140 cm NAVD88), although at 100 yr, elevation forecasts differed less than 10 cm across 97% of the marsh surface (150–200 cm NAVD88). Results demonstrate the utility of Landsat 8 for landscape-scale tidal marsh elevation projections due to its comparable performance with the other sensors, temporal frequency, and cost. Integration of remote sensing data with MEM should advance regional projections of marsh vegetation change by better parameterizing MEM inputs spatially. Improving information for coastal modeling will support planning for ecosystem services, including habitat, carbon storage, and flood protection.
No abstract available.
In this unique volume, renowned experts discuss the applications of fractals in petroleum research-offering an excellent introduction to the subject. Contributions cover a broad spectrum of applications from petroleum exploration to production. Papers also illustrate how fractal geometry can quantify the spatial heterogeneity of different aspects of geology and how this information can be used to improve exploration and production results.
Kahoolawe Island, Hawaii (18×11 km), is a basaltic shield volcano with caldera-filling lavas, seven identified postshield vents, and at least two occurrences of apparent rejuvenated-stage eruptive. We examined 42 samples that represent all stages of Kahoolawe volcano stratigraphy for their petrography, whole-rock major-and trace-element contents, mineral compositions, and K−Ar ages. The two oldest shield samples have an average age of 1.34±0.08 Ma, and four postshield samples (3 are alkalic) average 1.15±0.03 Ma; ages of 1.08 and 0.99 Ma for two additional tholeiitic samples probably are minimum ages. Whole-rock major- and trace-element and mineral compositions of Kahoolawe shield and caldera-fill laves are generally similar to the lavas forming Kilauea and Mauna Loa tholeiitic shields, but in detail, Kahoolawe shield lavas have distinctive compositions. An unusual aspect of many postshield Ka-hoolawe lavas is anomalously high REE and Y abundances (up to 200 ppm La and 175 ppm Y) and negative Ce anomalies. These enrichments reflect surficial processes, where weathering and soil development promoted REE-Y transport at the weathering front. Major element abundances (MgO, 10–6 wt.%) for shield and caldera-fill basalts are consistent with fractionation of ol+px+pl in frequently replenished magma reservoirs. In general, tholeiitic basalts erupted from late vents are higher in SiO 2 than the shield lavas, and temporal differences in parental magma compositions are the likely explanation. Alkalic basalts that erupted from vents are comparable in composition to those at other Hawaiian volcanoes. Trace-element abundance ratios indicate that alkalic basalts represent either relatively lower degrees of melting of the shield source or a distinct source. Apparent rejuvenated-stage basalts (i.e., emplaced after substantial Kahoolawe erosion) are tholeiitic, unlike the rejuvenated-stages at other Hawaiian volcanoes (alkalic). Kahoolawe, like several other Hawaiian volcanoes, has intercalated tholeiitic and alkalic basalts in the postshield stage, but it is the only volcano that appears to have produced tholeiitic rejuvenated-stage lavas.
In a study of the effect of montmorillonite on the dissolution of BaSO4 (barite), SrSO4 (celestite), and 226Ra from U mill tailings, it was found that: (1) More of these substances dissolve in an aqueous system that contains montmorillonite than dissolve in a similar system without clay, due to the ion exchange properties of the clay; (2) Na-montmorillonite is more effective in aiding dissolution than is Ca-montmorillonite; (3) the amount of Ra that moves from mill tailings to an exchanger increases as solution sulfate activity decreases. Leaching experiments suggest that 226Ra from H2SO4-circuit U mill tailings from Edgemont, South Dakota, is not present as pure Ra sulfate or as an impurity in anhydrite or gypsum; it is less soluble, and probably occurs as a trace constituent in barite.
Five models for near-surface crustal stresses induced by gravity and horizontal deformation and the influence of rock property contrasts, rock strength, and stress relaxation on these stresses are presented. Three of the models-the lateral constraint model, the model for crustal stresses caused by horizontal deformation, and the model for the effects of anisotropy-are linearly elastic. The other two models assume that crustal rocks are brittle or viscoelastic in order to account for the effects of rock strength and time on near-surface stresses. It is shown that the lateral constraint model is simply a special case of the combined gravity-and deformation-induced stress field when horizontal strains vanish and that the inclusion of the effect of rock anisotropy in the solution for crustal stresses caused by gravity and horizontal deformation broadens the range for predicted stresses. It is also shown that when stress levels in the crust reach the limits of brittle rock strength, these stresses become independent of strain rates and that stress relaxation in ductile crustal rocks subject to constant horizontal strain rates causes horizontal stresses to become independent of time in the long term. ?? 1992 Birkha??user Verlag.
[No abstract available]