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At least 487 records · Page 27Linked to original sources

De facto reuse and disinfection by-products in drinking water systems in the Shenandoah River watershed

De facto reuse is increasingly being studied among the variety of stressors that are relevant to drinking water systems that obtain their source water from surface waters. De facto reuse may influence the levels and types of precursors relevant to formation of disinfection by-products (DBPs) in surface water systems. DBPs such as trihalomethanes (THMs) and haloacetic acids (HAAs) have been associated with bladder cancer and other health concerns in people who use drinking water provided by public water systems (PWSs). In this study, we used compliance monitoring data from conventional surface water PWSs in the Shenandoah River watershed to evaluate the relationship between de facto reuse in the watershed with DBP formation in those systems. The Shenandoah River watershed was selected for this study because it has a relatively small group of PWSs that draw their source water from surface waters in the watershed, the majority of whom treat their water using chlorine, and are less likely to have confounding factors (such as complex distribution systems or lengthy residence times) than other watersheds. We found that concentrations of THM4 and HAA5 increase in drinking water systems as de facto reuse increases in their source waters and that the relation is observed at both annual average and low streamflow conditions (annual average and low streamflow increases were statistically significant for THM4 with p values of 0.027 and 0,021, respectively). In addition, using a t -test, we found that a 1% level of de facto reuse was associated with significantly higher levels of THM4 and HAA5 ( p < 0.05) under annual average streamflow conditions. While the concentrations of HAA5 were also higher under annual average and low streamflow conditions, we did not find that they achieved a level of a significant difference. Results from this research will be helpful to operators of PWSs and other researchers and stakeholders with an interest in water reuse and DBPs.

Virginia↗

Fishway Entrance Palisade

This technical report summarizes the work that was conducted by the University of Massachusetts Amherst and the United States Geological Survey (USGS), along with other project partners, on the Fishway Entrance Palisade (EP), a projected funded through the Department of Energy’s (DOE) funding opportunity titled ‘Innovative Solutions for Fish Passage at Hydropower Dams’ (DE‐FOA‐0001662). The period of performance ranged from September 1, 2018 through September 30, 2021. The EP is a novel fish passage engineering technology designed to provide more favorable entry conditions for fish and to reduce costs relative to conventional fishway auxiliary water systems (AWS). The EP project has four primary components. First, the Northeast United States Auxiliary Water Systems Database was created (Northeast Fishway Auxiliary Water Systems Database Section). The database, developed with material provided by the U.S. Fish and Wildlife Service, contains information on fishway type (e.g., lift, Denil, pool and weir) and Auxiliary Water System (AWS) details (e.g., water conveyance method, diffuser type) for 60 hydroelectric sites in the region. Findings indicate that nearly 4 out of every 10 fishway in the region is a fish lift and approximately 1 out of every 4 is a Denil ladder. The remainder are a mix of vertical slot fishways, pool and weirs, and Ice Harbor fishways. Furthermore, over half of all AWS systems use floor diffusers to discharge the auxiliary (or attraction) water into the entrance of a fishway, whereas only 14% use wall diffusers. Second, limited experiments on a conventional AWS with live, actively migrating fish were conducted at the USGS Easter Ecological Science Center (EESC) S.O. Conte Research Laboratory (Conventional Auxiliary Water System Experiments Section). This study determined how water velocity through a wall diffuser, without turning vanes or timber baffles to distribute the flow, affects the behavior and passage of adult American shad, a conservative surrogate species for migratory fish on the East Coast. Two gross diffuser velocity treatments were examined, 0.5 ft/s and 1.0 ft/s. These wall diffuser velocities represented current (0.5 ft/s) and past (1.0 ft/s) design criteria guidelines set forth by the USFWS North Atlantic-Appalachian Region (Rojas 2020; USFWS 2019). Six trials with a total of 151 American Shad were conducted in June of 2019 for the two treatments. No differences in American shad passage efficiency were discovered between the two treatments, while approximately 3 in every 4 attempts were successful at passing the diffuser. While these results may appear to indicate that the generally accepted gross wall diffuser velocity criteria for American shad of 0.5 ft/s could be safely increased to 1.0 ft/s, further analysis is warranted. Furthermore, it is unknown how other migratory and resident fish species that traverse these structures would be impacted by such a change. Studying the wall diffuser hydraulics led to an important AWS observation. Without turning vanes or timber baffles in this study, doubling the diffuser area was insufficient at producing the type of flow field change one may expect by halving the gross diffuser velocity. Instead, the flow fields throughout each treatments study area were similar, which led to similar results in shad performance. This not only highlights the importance of installing flow guidance devices like turning vanes, but also to the importance of properly maintaining them, which can be costly. Third, more expansive experiments on the novel EP were conducted in the spring of 2019 and 2021 (Fishway Entrance Palisade Experiments). The goal of this study was to determine how adult American shad responded to a variety of conditions at a full-scale EP. A total of six treatments were examined by changing the average auxiliary channel velocity between 1.0 and 5.0 ft/s in intervals of 1.0 ft/s and by inserting/removing an entrance gate at the opening of the fishway. Thirty trials with a total of 1,273 shad were conducted over the two years. In all treatments, at least ~7 out of every 10 fish successfully passed the EP diffuser and swam into the entrance channel within the 3.5-hour long trial, highlighting the general effectiveness of the novel AWS technology. In both study years, lower velocities through the EP diffuser led to increased shad performance, though performance peaked for the 2 ft/s velocity treatment. This treatment condition represents an approximate six-fold increase in gross diffuser velocity relative to conventional auxiliary water systems, which in turn presents opportunities for cost savings (e.g., reduction in diffuser size). Shad performance, in general, was worse in 2019 than in 2021, potentially due to the different run timing when our trials were conducted (2019 trials occurred near the end of the migration season, unlike in 2021). Treatments in 2019 had approximately a 20% reduction in entrance efficiency by the trial end, including a 16.7% drop for the 3 ft/s velocity treatment in 2019 relative to 2021 (the only carryover treatment between years). Lastly, adding an entrance gate caused a significant delay to entry. The time to 25% entry raised ~20 minutes from the near instantaneous 25% entry that was reported for the other treatments conducted in the same year (2021). Though by the end of the 3.5-hour trial, the overall entrance efficiency nearly matched those of the other 2021 treatments. The fourth and final component of the EP project was an economic analysis that focused on the cost of attraction and environmental flows (Modeling Power Generation Losses Due to Environmental and Fish Passage Attraction Flows at a Run-Of-River Hydroelectric Operation in the Northeast). The study assessed the economic impact of meeting environmental flow requirements at a representative hydroelectric facility and fish lift in the Northeast. An initial finding of the study was that there is a paucity of published data on the costs of meeting attraction and environmental flows. This is due, in part, to the proprietary nature of this data. To explore the costs associated with these flows, three types of environmental flows were assessed: upstream fishway attraction flows, downstream fishway attraction flows, and habitat maintenance minimum flows. A physics-based model was developed and calibrated with three years of hourly generation and flow data as inputs. Gage flow inputs were adjusted and used to calculate power generated. To address hydrologic variability, the model was executed to simulate 30 years of historical flows. Results indicate that both interannual and seasonal climatic factors impact the costs of meeting environmental flow requirements. Generation potential is most strongly curtailed during dry years in terms of maximizing the capacity factor (the percent of time a plant generates at capacity). Dry years, and especially dry summers, have the most significant costs associated with mitigation flows. Of the three types of flows, habitat flows are most costly in terms of power production, followed by upstream attraction flows. Downstream attraction flows are least costly. This finding is the likely result of differences in both flow rates and duration of the seasonal requirement for each flow. Overall, environmental flows represented a 2-12% loss in annual generation, but losses during a dry summer can reach over 20%.

Final Technical Report↗

Modeling water quality in watersheds: From here to the next generation

In this synthesis, we assess present research and anticipate future development needs in modeling water quality in watersheds. We first discuss areas of potential improvement in the representation of freshwater systems pertaining to water quality, including representation of environmental interfaces, in‐stream water quality and process interactions, soil health and land management, and (peri‐)urban areas. In addition, we provide insights into the contemporary challenges in the practices of watershed water quality modeling, including quality control of monitoring data, model parameterization and calibration, uncertainty management, scale mismatches, and provisioning of modeling tools. Finally, we make three recommendations to provide a path forward for improving watershed water quality modeling science, infrastructure, and practices. These include building stronger collaborations between experimentalists and modelers, bridging gaps between modelers and stakeholders, and cultivating and applying procedural knowledge to better govern and support water quality modeling processes within organizations.

Water Resources Research↗

Sub-annual streamflow responses to rainfall and snowmelt inputs in snow-dominated watersheds of the western U.S.

Streamflow generation in mountain watersheds is strongly influenced by snow accumulation and melt, and multiple studies have found that snow loss leads to earlier snowmelt timing and declines in annual streamflow. However, hydrologic responses to snow loss are heterogeneous, and not all areas experience streamflow declines. This research examines whether streamflow generation is different for rainfall versus snowmelt inputs. We compiled a sample of 57 small U.S. Geological Survey watersheds in the western United States containing a Natural Resource Conservation Service Snow Telemetry site and having ratios of mean annual peak snow water equivalent to precipitation ratios >0.25. Daily streamflow was separated into quickflow and baseflow using a digital filter, and quickflow was then divided into quickflow response intervals using thresholds in quickflow slope. Each quickflow response interval was categorized by its fraction of input from snowmelt. Most sites exhibited two streamflow generation peaks each year, with one peak in the winter when runoff efficiency is greatest, and the second in the spring during peak snowmelt input. On average, study watersheds were dominated by snowmelt inputs (70%), and snowmelt and mixed inputs usually generated greater streamflow than rainfall because of higher inputs and longer durations. However, rainfall produced high streamflow generation in winter, when watersheds have their highest runoff efficiency (81%) across all input types. We demonstrate that while snowmelt is important for streamflow generation due to high input over long periods, increases in rain and mixed input during wet winter periods can countervail tendencies for reduced streamflow with declining snowpacks.

Water Resources Research↗

Electrical characterization of non‐Fickian transport in groundwater and hyporheic systems

Recent work indicates that processes controlling solute mass transfer between mobile and less mobile domains in porous media may be quantified by combining electrical geophysical methods and electrically conductive tracers. Whereas direct geochemical measurements of solute preferentially sample the mobile domain, electrical geophysical methods are sensitive to changes in bulk electrical conductivity (bulk EC) and therefore sample EC in both the mobile and immobile domains. Consequently, the conductivity difference between direct geochemical samples and remotely sensed electrical geophysical measurements may provide an indication of mass transfer rates and mobile and immobile porosities in situ. Here we present (1) an overview of a theoretical framework for determining parameters controlling mass transfer with electrical resistivity in situ; (2) a review of a case study estimating mass transfer processes in a pilot‐scale aquifer storage recovery test; and (3) an example application of this method for estimating mass transfer in watershed settings between streams and the hyporheic corridor. We demonstrate that numerical simulations of electrical resistivity studies of the stream/hyporheic boundary can help constrain volumes and rates of mobile‐immobile mass transfer. We conclude with directions for future research applying electrical geophysics to understand field‐scale transport in aquifer and fluvial systems subject to rate‐limited mass transfer.

Water Resources Research↗

Drought and water management in ancient Maya society

Paleoclimate research in the Maya region of Mesoamerica provides compelling evidence of drought during key periods of cultural transition in Maya society. These include the transition from the Preclassic to the Classic, and from Classic to the Postclassic. Previous research emphasized a causal relationship between drought and cultural change, or so-called “collapse” in the Maya region. Recent advances in the range and precision of climate-sensitive proxies and the development of new archives have enabled quantitative reconstructions of past hydroclimate, as well as providing evidence of high impact, short-duration events, such as tropical cyclones. Simultaneously, archaeological research has unearthed widespread evidence of technologies used by the Maya to exert control over water resources in urban, rural, and agricultural settings. Evidence suggests that many of these water features were in use for multiple generations, possibly centuries, and many were constructed during the Terminal Preclassic and Terminal Classic periods. We suggest that, given the availability of new archaeological and paleoclimate records, these data can be combined to identify the full complexity of Maya adaptation to hydroclimate variability to emphasize adaptation and resilience to both water scarcity and over-abundance (e.g., flooding). Such syntheses, which can offer lessons for present-day efforts to grapple with regional climate change, will benefit from additional studies in data-poor zones of the Maya region, as well as public archiving of paleoclimate and archaeological data.

Progress in Physical Geography: Earth and Environm↗

Normalization of stable isotope data for carbonate minerals: implementation of IUPAC guideline

Carbonate minerals provide a rich source of geochemical information because their &delta; 13 C and &delta; 18 O values provide information about surface and subsurface Earth processes. However, a significant problem is that the same &delta; 18 O value is not reported for the identical carbonate sample when analyzed in different isotope laboratories in spite of the fact that the International Union of Pure and Applied Chemistry (IUPAC) has provided reporting guidelines for two decades. This issue arises because (1) the &delta; 18 O measurements are performed on CO 2 evolved by reaction of carbonates with phosphoric acid, (2) the acid-liberated CO 2 is isotopically fractionated (enriched in 18 O) because it contains only two-thirds of the oxygen from the solid carbonate, (3) this oxygen isotopic fractionation factor is a function of mineralogy, temperature, concentration of the phosphoric acid, and &delta; 18 O value of water in the phosphoric acid, (4) researchers may use any one of an assortment of oxygen isotopic fractionation factors that have been published for various minerals at various reaction temperatures, and (5) it sometimes is not clear how one should calculate &delta; 18 O VPDB values on a scale normalized such that the &delta; 18 O value of SLAP reference water is &minus;55.5 &permil; relative to VSMOW reference water. To enable researchers worldwide to publish the same &delta; 18 O value (within experimental uncertainty) for the same carbonate sample, we have re-evaluated reported acid fractionation factors for calcite at 25, 50, and 75 &deg;C and propose a revised relation for the temperature dependence of oxygen isotopic acid fractionation factor, &alpha; CO 2 ( ACID ) -calcite &alpha;CO2(ACID)-calcite , of 1000ln &alpha; CO 2 ( ACID ) -calcite=3.48(10 3 /T)-1.47 1000ln&alpha;CO2(ACID)-calcite=3.48(103/T)-1.47 Turn MathJax on where T is temperature in kelvin. At 25 &deg;C, &alpha; CO 2 ( ACID ) -calcite=1.01025 &alpha;CO2(ACID)-calcite=1.01025 , the most commonly accepted value for this quantity. We propose a normalization protocol in which (1) the internationally distributed carbonate isotopic reference materials NBS 18 and NBS 19 are interspersed among carbonate samples analyzed by treatment with phosphoric acid, (2) the &delta; 18 O values of the calcite reference materials and the carbonate samples are calculated, respectively, by using the &alpha; CO 2 ( ACID ) -calcite &alpha;CO2(ACID)-calcite relation above and oxygen-isotope acid fractionation factors appropriate for the sample mineralogy and reaction temperature, (3) the &delta; 18 O values of solid carbonate samples are determined on the VPDB scale ( &delta; 18 O VPDB ) with IUPAC-recommended scale expansion such that the &delta; 18 O of SLAP reference water is &minus;55.5 &permil; relative to VSMOW reference water by normalizing &delta; 18 O values of carbonate samples with 2014-IUPAC-recommended &delta; 18 O values of NBS 18 and NBS 19, and (4) &delta; 18 O values on the VPDB scale are converted to &delta; 18 O values on the VSMOW-SLAP scale by using IUPAC recommendations. To ease calculations in the protocol, a software application titled &ldquo;Carbon and Oxygen Isotopic Normalization Tool for Carbonates&rdquo; is available that relies upon IUPAC-recommended &delta; 13 C and &delta; 18 O values of carbonate isotopic reference materials ( http://isotopes.usgs.gov/research/topics/carbonatesnormalizationtool.html ).

Geochimica et Cosmochimica Acta↗

Gas-driven pump for ground-water samples

Observation wells installed for artificial-recharge research and other wells used in different ground-water programs are frequently cased with small-diameter steel pipe. To obtain samples from these small-diameter wells in order to monitor water quality, and to calibrate solute-transport models, a small-diameter pump with unique operating characteristics is required that causes a minimum alternation of samples during field sampling. A small-diameter gas-driven pump was designed and built to obtain water samples from wells of two-inch diameter or larger. The pump is a double-piston type with the following characteristics: (1) The water sample is isolated from the operating gas, (2) no source of electricity is ncessary, (3) operation is continuous, (4) use of compressed gas is efficient, and (5) operation is reliable over extended periods of time. Principles of operation, actual operation techniques, gas-use analyses and operating experience are described. Complete working drawings and a component list are included. Recent modifications and pump construction for high-pressure applications also are described. (Woodard-USGS)

Water-Resources Investigations Report↗

Bibliography of U.S. Geological Survey studies of lakes and reservoirs; the first 100 years

For more than 100 years, the U.S. Geological Survey has pursued its mission of assessing and mapping the earth resources of the United States, including assessment of the Nation's water resources. Although the Survey has never been a water-management or development agency, it has assisted agencies that are responsible for such developments, and commonly provides data and information for such purposes. Because reservoirs are an intergral part of most water-development projects, the Survey has been involved in reservoir-related studies since the 1880's. The largest and longest involvement has centered on providing information on streamflows and sediment transport related to existing and proposed reservoirs. During the late 1940's, the Survey greatly expanded its activities in evaporation research. More recently, ground water, including bank storage, has gained increased attention. Most of these studies were related primarily to questions of water quantity, and the Survey continues to be involved in studies of physical hydrology. In addition, in response to the increased concern with environmental quality during the past 20 years, the number of Survey studies of the chemical and biological aspects of lakes and reservoirs have increased considerably. Prompted by the recent Centennial (1879-1979) of the U.S. Geological Survey, it is appropriate to assess the Survey's contributions to the hydrology of lakes and reservoirs. Both natural lakes and manmade reservoirs are included in this report. 1 This report includes studies in which lakes or reservoirs are the principal topics. It does not include reports of general water resources of an area in which lakes are discussed as part of that area. This report also does not include data reports in which the data are merely tabulated. The types of reports listed herein include studies of existing or proposed water bodies and associated fluxes of water to and from these water bodies. This report does not include geological or paleobiological studies of ancient lakes. This report does, however, include geological studies of proposed reservoir sites. This bibliography has three parts. The first part is an alphabetical listing that gives complete references to the given reports. Part 2 is a listing by topics, and only the authors, date of publication, and cross-reference to the State are given. Six general categories are considered: Lake hydrology; interaction of lakes and streamflow, including geological studies of reservoir sites; interaction of lakes and atmospheric water; interaction of lakes. and ground water; chemical and biological limnology; and sediment studies. The first four consist of studies of physical characteristics of lakes, and the last two of water-quality characteristics. The category of lake hydrology includes general studies of lakes that are not easily grouped into one of the more specific categories of physical characteristics. For example, it includes water-budget studies where all aspects of hydrology are discussed. It also includes studies of hydrodynamics of lakes as well as studies of lake-level fluctuations. The category of interaction of lakes and streamflow includes preimpoundment studies of streamflow discharge for reservoir design, and studies of the effects of existing reservoirs on streamflow and channel characteristics. Also included in this category are geological studies of river valleys for proposed reservoir sites. The category of interaction of lakes and atmospheric water includes primarily studies of evaporation. The interaction of lakes and ground water includes studies of bank storage. The category of chemical and biological studies was not subdivided into more specific types because of the virtually inseparable relation between chemistry and biology in most studies. This bibliography provided much of the information for two papers that discuss the history of U.S. Geological Survey studies of lakes and reservoirs. (See Winter, 1981b; and Hadley, 1981).

Circular↗

Water resources activities in Kentucky, 1993-94

The U.S. Geological Survey (USGS) is the principal Federal water-resources data collection and investigation agency. Through the Water Resources Division District Office in Kentucky, the USGS investigates the occurrence, distribution, quantity, movement, and chemical and biological quality of surface and ground water in the State. The mission of this program is to collect, interpret, and publish information on water resources. Almost all research and data collection is a cooperative effort in which planning and financial support are shared by State and local agencies and governments. Other activities are funded by other Federal agencies or by direct Congressional appropriation. This report is intended to inform the public and cooperating agencies, vitally interested in the water resources of Kentucky, as to the current status of the Distfict's data collection and investigation program. Included in the report are summaries of water-resources activities in Kentucky conducted by the USGS. Also included is a description of the USGS mission and program, District organization, funding sources and cooperating agencies, and a list of USGS publications relevant to the water resources of the State.

Open-File Report↗

Analysis of pharmaceutical and other organic wastewater compounds in filtered and unfiltered water samples by gas chromatography/mass spectrometry

Research on the effects of exposure of stream biota to complex mixtures of pharmaceuticals and other organic compounds associated with wastewater requires the development of additional analytical capabilities for these compounds in water samples. Two gas chromatography/mass spectrometry (GC/MS) analytical methods used at the U.S. Geological Survey National Water Quality Laboratory (NWQL) to analyze organic compounds associated with wastewater were adapted to include additional pharmaceutical and other organic compounds beginning in 2009. This report includes a description of method performance for 42 additional compounds for the filtered-water method (hereafter referred to as the filtered method) and 46 additional compounds for the unfiltered-water method (hereafter referred to as the unfiltered method). The method performance for the filtered method described in this report has been published for seven of these compounds; however, the addition of several other compounds to the filtered method and the addition of the compounds to the unfiltered method resulted in the need to document method performance for both of the modified methods. Most of these added compounds are pharmaceuticals or pharmaceutical degradates, although two nonpharmaceutical compounds are included in each method. The main pharmaceutical compound classes added to the two modified methods include muscle relaxants, opiates, analgesics, and sedatives. These types of compounds were added to the original filtered and unfiltered methods largely in response to the tentative identification of a wide range of pharmaceutical and other organic compounds in samples collected from wastewater-treatment plants. Filtered water samples are extracted by vacuum through disposable solid-phase cartridges that contain modified polystyrene-divinylbenzene resin. Unfiltered samples are extracted by using continuous liquid-liquid extraction with dichloromethane. The compounds of interest for filtered and unfiltered sample types were determined by use of the capillary-column gas chromatography/mass spectrometry. The performance of each method was assessed by using data on recoveries of compounds in fortified surface-water, wastewater, and reagent-water samples. These experiments (referred to as spike experiments) consist of fortifying (or spiking) samples with known amounts of target analytes. Surface-water-spike experiments were performed by using samples obtained from a stream in Colorado (unfiltered method) and a stream in New York (filtered method). Wastewater spike experiments for both the filtered and unfiltered methods were performed by using a treated wastewater obtained from a single wastewater treatment plant in New York. Surface water and wastewater spike experiments were fortified at both low and high concentrations and termed low- and high-level spikes, respectively. Reagent water spikes were assessed in three ways: (1) set spikes, (2) a low-concentration fortification experiment, and (3) a high-concentration fortification experiment. Set spike samples have been determined since 2009, and consist of analysis of fortified reagent water for target compounds included for each group of 10 to18 environmental samples analyzed at the NWQL. The low-concentration and high-concentration reagent spike experiments, by contrast, represent a one-time assessment of method performance. For each spike experiment, mean recoveries ranging from 60 to 130 percent indicate low bias, and relative standard deviations (RSDs) less than (<) 30 percent indicate low variability. Of the compounds included in the filtered method, 21 had mean recoveries ranging from 63 to 129 percent for the low-level and high-level surface-water spikes, and had low (<15 percent) RSDs for these spikes. The remaining 21 compounds generally had high bias for the low-level or the high-level spike experiments for surface water [mean recoveries <58 percent or greater than (>)132 percent]. For wastewater spikes, 24 of the compounds included in the filtered method had recoveries ranging from 61 to 130 percent for the low-level and high-level spikes. RSDs were <29 percent for both of these spike experiments for the 24 compounds. The remaining 18 compounds in the filtered method generally had high recoveries (>130 percent) or variable recoveries (RSDs >30 percent) for low-level wastewater spikes, or low recoveries (<60 percent) for high-level wastewater spikes. Of the compounds included in the filtered method, 34 had mean set-spike recoveries between 61 and 126 percent, and RSDs <30 percent. Of the compounds included in the unfiltered method, 17 had mean spike recoveries ranging from 74 to 129 percent and RSDs ranging from 5 to 25 percent for low-level and high-level surface water spikes. The remaining compounds had poor mean recoveries (<60 or >130 percent), or high RSDs (>29 percent) for these spikes. For wastewater, 14 of the compounds included in the unfiltered method had mean recoveries ranging from 62 to 127 percent and RSDs <25 percent for the low-level and high-level spikes. Most of the remaining compounds had high mean recoveries for wastewater (>130 percent), or low mean recoveries (<20 percent) or high RSDs (>33 percent) for the low-level wastewater spikes. Of the compounds found in wastewater, 24 had mean set spike recoveries ranging from 64 to 104 percent and RSDs <30 percent. Separate method detection limits (MDLs) were computed for surface water and wastewater for both the filtered and unfiltered methods. Filtered method MDLs ranged from 0.007 to 0.14 microgram per liter (μg/L) for the surface water matrix and from 0.004 to 0.62 μg/L for the wastewater matrix. Unfiltered method MDLs ranged from 0.014 to 0.33 μg/L for the surface water matrix and from 0.008 to 0.36 μg/L for the wastewater matrix.

Open-File Report↗

A geologic and anthropogenic journey from the Precambrian to the new energy economy through the San Juan volcanic field

The San Juan volcanic field comprises 25,000 km 2 of intermediate composition mid-Tertiary volcanic rocks and dacitic to rhyolitic calderas including the San Juan&ndash;Uncompahgre and La Garita caldera-forming super-volcanoes. The region is famous for the geological, ecological, hydrological, archeological, and climatological diversity. These characteristics supported ancestral Puebloan populations. The area is also important for its mineral wealth that once fueled local economic vitality. Today, mitigating and/or investigating the impacts of mining and establishing the region as a climate base station are the focuses of ongoing research. Studies include advanced water treatment, the acid neutralizing capacity (ANC) of propylitic bedrock for use in mine-lands cleanup, and the use of soil amendments including biochar from beetle-kill pines. Biochar aids soil productivity and revegetation by incorporation into soils to improve moisture retention, reduce erosion, and support the natural terrestrial carbon sequestration (NTS) potential of volcanic soils to help offset atmospheric CO 2 emissions. This field trip will examine the volcano-tectonic and cultural history of the San Juan volcanic field as well as its geologic structures, economic mineral deposits and impacts, recent mitigation measures, and associated climate research. Field trip stops will include a visit to (1) the Summitville Superfund site to explore quartz alunite-Au mineralization, and associated alteration and new water-quality mitigation strategies; (2) the historic Creede epithermal-polymetallic&ndash;vein district with remarkably preserved resurgent calderas, keystone-graben, and moat sediments; (3) the historic mining town of Silverton located in the nested San Juan&ndash;Silverton caldera complex that exhibits base-metal Au-Ag mineralization; and (4) the site of ANC and NTS studies. En route back to Denver, we will traverse Grand Mesa, a high NTS area with Neogene basalt-derived soils and will enjoy a soak in the geothermal waters of the Aspen anomaly at Glenwood Springs.

Colorado↗

On-demand global Landsat evapotranspiration product: Development, evaluation, and dissemination

Global actual evapotranspiration (ET) is one of the essential climate variables needed to understand and manage the relationships among food, energy, and water resources. The U.S. Geological Survey Earth Resources Observation and Science (EROS) Center launched a provisional ET product in 2020, offering on-demand, field-scale global coverage derived from Landsat data through the EROS Science Processing Architecture (ESPA) platform. The ESPA interface provides ET data for cloud-free Landsat overpasses starting in 1982 with Landsat 4 through the current Landsat 9. The ET data are delivered as a Provisional Level-3 Science product created using the Operational Simplified Surface Energy Balance (SSEBop) model. Landsat surface temperature and reference ET are the main model drivers along with vegetation index and net radiation for model parameterization. A large volume of Landsat-based ET orders (e.g., over 1,200,000 images from June 2020 through December 2025) around the world indicate increasing awareness and application of the ET data. The ESPA platform enables land and water resource managers and researchers to access a first-order ET product without requiring advanced knowledge of remote sensing technology or evapotranspiration modeling. We present the methodology and workflow of the on-demand Landsat ET product and its performance evaluations over diverse hydro-climatic settings. The product can help estimate field-scale consumptive water use and thus quickly and consistently assess historical water use, allocation, and budget to inform water management under changing environments. Future ET data aggregated to monthly and seasonal time scales are expected to enhance integration with decision-making tools and procedures.

Remote Sensing of Environment↗

Tektite 1, man-in-the-sea project: Marine Science Program

The Tektite experiment was designed to provide data for a number of behavioral, biomedical, and engineering studies in addition to the marine sciences program. Conditions for some of these studies were not altogether compatible with the program for the marine sciences. For example, isolation imposed by human behavioral studies precluded physical contact with the surface team, even though such contact was physically possible and desirable for the conduct of the marine sciences program. Isolation also imposed on the scientific team the duty of all in-habitat maintenance, both scheduled and unscheduled, thereby taking substantial time from scientific research. In addition, between 10 and 20 percent of the waking time was devoted to performance of psychological tests required for the biomedical studies. Most of the experiments were directed toward detecting potentially adverse changes and thus were accepted as necessary and desirable. The only health problem to affect the scientific program during the dive was a minor external ear infection contracted by all the divers. Nonetheless, the experiment demon. strated, at least to our satisfaction, the advantages of underwater habitation and saturation diving for biological and geological research. A major advantage is the opportunity for continuous monitoring of organisms or processes. In addition, underwater habitation provides for considerably more research time in the water than surface diving or intermittent bottom dwelling, and this advantage increases greatly as the depth of habitation increases. Even in the relatively shallow depths at which Tektite 1 was conducted, the undersea team could spend appreciably more time at work in the water than their colleagues on the surface. Finally, Tektite 1 demonstrated that the scientist who lives in the sea need not have the extensive qualifications of a professional diver. Of the four scientists of the in-habitat team, only Crew Chief Waller was so qualified; the other three had used scuba as a research tool, but on a relatively limited basis. Any healthy, well-conditioned marine scientist with a basic diving background is capable of extending his research into the shallow sea on a full-time basis. It is hoped that many such scientists will in the future be able to utilize the undersea laboratory.

Science↗

Primer for identifying cold-water refuges to protect and restore thermal diversity in riverine landscapes

In 2003, EPA issued Region 10 guidance for Pacific Northwest state and tribal temperature water quality standards. This document was the culmination of a multi-agency, multi-disciplinary effort to develop a temperature standard for the protection of salmon, steelhead, bull trout, and redband and Lahontan cutthroat trout (collectively termed coldwater salmonids). Since its release, the Oregon and Washington have adopted the temperature standard for their waters designated for protection of coldwater salmonids. One of the unique aspects of the temperature standard, which strived to integrate the physical nature of rivers and streams and the biological requirements of coldwater salmonids, is the requirement to protect and restore cold-water refuges. This requirement is incorporated into the temperature criterion for the protection of migration corridors in the Willamette, Columbia, and Snake rivers. The intent of this provision is the recognition that some coldwater salmonids migrate through waters during thermally stressful months of summer and most likely are able to do so by using features in the rivers that provide cold water spatially or temporally. The challenge is to ensure that these features are identified, protected, and restored in order for these waters to meet the temperature standard. This primer is intended to assist Region 10 states, tribes, and local watershed groups in meeting this goal and thereby further the protection and restoration of coldwater salmonids. It provides an up-to-date summary with easily referenced information and illustrations on the scientific advances and management applications of research on cold-water refuges and can be used as a "roadmap" for identifying cold-water refuges and learning more about processes that create thermal diversity in riverine landscapes. The specific objectives are to 1. define cold-water refuge in scientific and management contexts. 2. outline an approach for identifying cold-water refuges to address water quality standards. 3. classify and characterize the types and physical processes that create cold-water refuges. 4. review methods and tools for identifying cold-water refuges in small streams to large rivers. 5. describe ecological perspectives and on-the-ground approaches for protecting and restoring thermal diversity in rivers.

Oregon↗

Seabird, fisheries, marine mammal, and oceanographic investigations around Kasatochi, Koniuji, and Ulak Islands, August 1996 (SMMOCI 96-3)

Although islands in the Aleutians are known to support some of the highest densities of seabirds in the world, their remoteness has limited systematic research on the at-sea distribution of seabirds near these colonies. Kasatochi, Koniuji, and Ulak islands, in the central Aleutian Islands, together comprise one of nine ecological sites monitored once every 5 years on an annual rotation since 1996 by the Alaska Maritime National Wildlife Refuge (AMNWR). To supplement annual colony monitoring and examine seabird distribution away from colony sites, the AMNWR personnel in conjunction with U.S. Geological Survey (USGS) researchers, conducted a pelagic survey of the waters around these 3 islands in 1996. Previous research in this area has focused on the seabird colony sites located on Kasatochi, Koniuji, and Ulak islands. Although boat-based circumnavigations have been used to evaluate colony populations (Early et al. 1981; Bailey and Trapp 1986; Byrd and Williams 1994; Byrd 1995a, 1995b), wide ranging pelagic surveys to examine foraging patterns had not previously been conducted near the islands. The goal of this survey was to examine foraging patterns of the seabirds nesting in the study area and identify factors that may explain seabird distribution patterns.

Alaska↗

Synthesis: A framework for predicting the dark side of ecological subsidies

In this chapter, we synthesize the state of the science regarding ecological subsidies and contaminants at the land-water interface and suggest research and management approaches for linked freshwater-terrestrial ecosystems. Specifically, we focus on movements of animals with complex life histories and the detrital inputs associated with animal and plant matter delivered to freshwaters. We present a framework based on the physicochemical parameters of contaminants and how they shape the relationship between contaminant persistence within resource subsidies (“dark side” of subsidies) and movement of resource subsidies (“bright side” of subsidies) across ecosystem boundaries. This relationship between the “dark side” and “bright side” of subsidies defines an important parameter space that allows researchers and practitioners to predict the potential impacts of aquatic contaminants on resource subsidies and their interaction with other stressors on consumers. Ecological factors such as ecosystem productivity, community composition, and consumer prey preference shape the ecotoxicological outcomes of aquatic contamination on subsidies. Landscape factors such as lithology, hydrogeomorphology, hydroperiod, and land use underlie chemical, toxicological, and ecological patterns and provide the context within which effects of contaminants play out. Finally, effects of contaminants combine with effects of other global stressors on timing, quality, and quantity of subsidies that drive responses to contaminants at the land-water interface. Understanding the “dark side” of ecological subsidies requires expertise from multiple disciplines. We attempt to synthesize current knowledge from those disciplines and generate conceptual models that ecologists can use to guide future research in understanding cross-ecosystem subsidies and contaminant fate and effects.

Book chapter↗