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At least 487 records · Page 27Linked to original sources
USGS1989

Humic substances in the Suwannee River, Georgia; interactions, properties, and proposed structures

Humic substances as a collective term and humic and fulvic acids as specific terms are not household words. For about a century, these terms belonged to the domain of the soil scientist. Even^though their chemical structures remained elusive, they were recognized as important entities in soil. During the past decade or so, there has been a renewed interest in humic substances in soil and water. Such interest has been the result of improved analytical instrumentation, and by a need to understand the structure and function of natural organic substances in water. A responsibility of the U.S. Geological Survey is to assess the Nation's water resources; this includes water quality, which is the study of material in water. Such material may be suspended, colloidal, or in true solution. Because humic substances are a major carbon source in water, they have received attention by Geological Survey scientists. This attention has been a major focus by members of the Geological Survey's organic-chemistry group. For more than a decade, this group has collected samples, made analyses, and worked toward determining the structures and function of humic substances in water. Their work has brought worldwide recognition to the field, and in 1981, through Geological Survey support, they helped organize the International Humic Substances Society, which held its first meeting in Estes Park, Colorado, in August 1983. At the second meeting of the Society in Birmingham, England, in August 1984, it became apparent that Geological Survey scientists were rapidly advancing the study of the chemistry of humic substances. It seemed appropriate, therefore, to publish this Open-File report on humic and fulvic acids from the Suwannee River in Georgia. The results represent our most definitive findings to date (1986). Though this work is not conclusive, it is state-of-the-science. Hopefully, our reporting on this work will aid in moving the science of humic substances forward as others read of our progress, findings, and theories. If so, this Open-File report will have served its purpose.

Georgia↗
USGS2002

A two-dimensional hydrodynamic model of the St. Clair-Detroit River waterway in the Great Lakes basin

The St. Clair-Detroit River waterway connects Lake Huron with Lake Erie in the Great Lakes basin to form part of the international boundary between the United States and Canada. A two-dimensional hydrodynamic model is developed to compute flow velocities and water levels as part of a source water assessment of public water intakes. The model, which uses the generalized finite-element code RMA2, discretizes the waterway into a mesh formed by 13,783 quadratic elements defined by 42,936 nodes. Seven steady-state scenarios are used to calibrate the model by adjusting parameters associated with channel roughness in 25 material zones. An inverse modeling code is used to systematically adjust model parameters and to determine their associated uncertainty by use of nonlinear regression. Calibration results show close agreement between simulated and expected flows in major channels and water levels at gaging stations. Sensitivity analyses describe the amount of information available to estimate individual model parameters, and quantify the utility of flow measurements at selected cross sections and water-level measurements at gaging stations. Further data collection, model calibration analysis, and grid refinements are planned to assess and enhance two-dimensional flow simulation capabilities describing the horizontal flow distributions in St. Clair and Detroit Rivers and circulation patterns in Lake St. Clair.

St. Clair-Detroit River waterway↗
USGS1989

Tectonostratigraphic terranes and their Paleozoic boundaries in the central and southern Appalachians

Parts of the central and southern Appalachian orogen appear to have evolved away from Proterozoic North America (Laurentia) and to have been accreted to it during the Paleozoic orogenies that collectively formed the orogen. Identifying each tectonostratigraphic terrane is a necessary step in understanding the evolution of the orogen. The terranes in the central and southern Appalachians are delineated, interpreted, and classified with varying degrees of confidence as: (1) Laurentian native terranes , (2) internal continental terranes of the Appalachian orogen, (3) disrupted terranes , (4) possible oceanic crustal remnants, (5) volcanic-arc terranes , (6) a continental terrane of Gondwanaland affinity, and (7) metamorphic complexes of undetermined affinity. The Laurentian native terranes consist of external massifs of Laurentian basement (Grenvillian and older), their rift- and shelf-facies cover rocks, and slope-rise prism deposits. External massifs are present in the Blue Ridge tectonic province, Reading Prong, and Honey Brook Upland. Rocks of the Talladega block are stratigraphically tied to Laurentia and, with the possible exception of the Hillabee greenstone, are also considered native. Offshore, deep-water, post-rift deposits of the Hamburg and Westminster terranes have no direct stratigraphic ties to Laurentia and are considered discrete native (not suspect) terranes . The internal continental terranes of the Appalachian orogen are isolated massifs of Middle Proterozoic (Grenvillian) continental basement and their cover sequences that occur within the metamorphic core of the orogen. These terranes , the Baltimore, Sauratown, and Pine Mountain terranes , could be either structurally isolated outliers of Laurentia or microcontinental fragments of Laurentian crust displaced by rifting or transcurrent faulting and later reassembled. Disrupted terranes in the central and southern Appalachians contain mélange complexes as well as more coherent terrane fragments (volcanic, ophiolitic, or continental) intermingled with the mélange complexes. Those identified include the Jefferson, Potomac, Smith River, Inner Piedmont, Falls Lake, Juliette, and Sussex terranes . The Bel Air-Rising Sun terrane (Baltimore Complex) in Maryland and Pennsylvania is the only terrane named separately as a possible oceanic crustal remnant. Similar mafic and ultramafic complexes are present in all of the disrupted terranes , but are too small to consider as separate terranes . Volcanic-arc terranes include the Chopawamsic, Carolina, Spring Hope, Roanoke Rapids, and Charleston terranes . The only terrane recognized as a continental terrane of Gondwanaland affinity is the Suwannee terrane , which contains rocks believed to correlate with those now exposed in west Africa. Metamorphic complexes of undetermined affinity are terranes that could not be clearly classified on the basis of available data. These include the Milton, Gaffney, Uchee, Crabtree, Goochland, Wilmington, and Hatteras terranes . The Penobscottian, Taconian, Acadian, and Alleghanian Paleozoic compressional events collectively assembled the various terranes into what is now the Appalachian orogen. Only the central and southern parts of the U.S. Appalachians are considered here. The Penobscottian orogeny, about 550 to 490 Ma, amalgamated the Potomac, the Chopawamsic, probably the Bel Air-Rising Sun, and possibly other exotic terranes at some unknown distance from Laurentia. This was followed by the Taconian orogeny, about 470 to 440 Ma, which accreted the previously amalgamated terranes and probably other terranes such as the Carolina terrane to Laurentia. The younger age limit for the Taconian event is partly constrained by Middle and Late Ordovician faunal assemblages in successor basin deposits of the Arvonia Slate and Quantico Formation. The significance of the Acadian orogeny, dated about 400 to 380 Ma in New England, is unclear in the central and southern Appalachians . In the Talladega block of Alabama and Georgia, an Early to Middle Devonian dynamothermal event is firmly bracketed between Early Devonian fossils and K-Ar ages that indicate a thermal peak no later than Middle Devonian time. A regional tectonothermal event and faulting of approximately this age are also suggested by isotopic studies in terranes to the east. The late Paleozoic (Alleghanian) continental collision between Laurentia and Gondwanaland, which formed the supercontinent Pangea, marks the final stage of accretionary history in the Appalachian -Caledonide orogen. Effects evident in the central and southern Appalachian region include: (1) the accretion of the Suwannee terrane and perhaps the Charleston terrane to what is now North America, (2) slicing and shifting of terranes along dextral strike-slip faults, particularly in the eastern Piedmont, (3) westward transport of native and previously accreted terranes in the western Piedmont and Blue Ridge as part of a composite crystalline thrust sheet, (4) deposition of clastic wedges in the Appalachian foreland, and (5) imbricate thrusting and folding of the resultant strata in the Valley and Ridge Province.

Appalachians↗
USGS2006

Transport pathways in the lower reaches of Hood Canal

In 2003, studies revealed that the waters in the lower reaches of Hood Canal in Washington State had very low dissolved-oxygen concentrations, low enough to cause some fish kills between June and October of that year. In order to determine the transport patterns and the persistence of the low oxygen level in this portion of the canal, the U. S. Geological Survey deployed two instrumented platforms on the seabed near the head of the canal that measured currents over the whole water column, water level, near-bed temperature, salinity and oxygen for 2 months in the fall of 2004. Tidal currents, the dominant current component in the canal, flowed primarily along the canal axis and had speeds of 15-20 cm/s. There was also a persistent internal seiche that caused currents to flow along the canal axis with speeds of a few cm/s. The seiche, which had a period of a few days, caused currents in the surface layer to flow in an opposite direction to currents in water depths deeper than 15 m. A pool of warmer, saltier and more oxygenated water moved past the measurement sites toward the head of the canal with a speed of 1 cm/s. CTD measurements taken near the 2 measurement sites during the deployment indicated that this more oxygenated layer of water extended from the bed to the thermocline. Oxygen data from the tripods showed that this water remained in the region until at least the end of October 2004, when the tripods were recovered.

Washington↗
USGS2022

Response of Green Lake, Wisconsin, to changes in phosphorus loading, with special emphasis on near-surface total phosphorus concentrations and metalimnetic dissolved oxygen minima

Green Lake is the deepest natural inland lake in Wisconsin, with a maximum depth of about 72 meters. In the early 1900s, the lake was believed to have very good water quality (low nutrient concentrations and good water clarity) with low dissolved oxygen (DO) concentrations occurring in only the deepest part of the lake. Because of increased phosphorus (P) inputs from anthropogenic activities in its watershed, total phosphorus (TP) concentrations in the lake have increased; these changes have led to increased algal production and low DO concentrations not only in the deepest areas but also in the middle of the water column (metalimnion). The U.S. Geological Survey has routinely monitored the lake since 2004 and its tributaries since 1988. Results from this monitoring led the Wisconsin Department of Natural Resources (WDNR) to list the lake as impaired because of low DO concentrations in the metalimnion, and they identified elevated TP concentrations as the cause of impairment. As part of this study by the U.S. Geological Survey, in cooperation with the Green Lake Sanitary District, the lake and its tributaries were comprehensively sampled in 2017–18 to augment ongoing monitoring that would further describe the low DO concentrations in the lake (especially in the metalimnion). Empirical and process-driven water-quality models were then used to determine the causes of the low DO concentrations and the magnitudes of P-load reductions needed to improve the water quality of the lake enough to meet multiple water-quality goals, including the WDNR’s criteria for TP and DO. Data from previous studies showed that DO concentrations in the metalimnion decreased slightly as summer progressed in the early 1900s but, since the late 1970s, have typically dropped below 5 milligrams per liter (mg/L), which is the WDNR criterion for impairment. During 2014–18 (the baseline period for this study), the near-surface geometric mean TP concentration during June–September in the east side of the lake was 0.020 mg/L and in the west side was 0.016 mg/L (both were above the 0.015-mg/L WDNR criterion for the lake), and the metalimnetic DO minimum concentrations (MOMs) measured in August ranged from 1.0 to 4.7 mg/L. The degradation in water quality was assumed to have been caused by excessive P inputs to the lake; therefore, the TP inputs to the lake were estimated. The mean annual external P load during 2014–18 was estimated to be 8,980 kilograms per year (kg/yr), of which monitored and unmonitored tributary inputs contributed 84 percent, atmospheric inputs contributed 8 percent, waterfowl contributed 7 percent, and septic systems contributed 1 percent. During fall turnover, internal sediment recycling contributed an additional 7,040 kilograms that increased TP concentrations in shallow areas of the lake by about 0.020 mg/L. The elevated TP concentrations then persisted until the following spring. On an annual basis, however, there was a net deposition of P to the bottom sediments. Empirical models were used to describe how the near-surface water quality of Green Lake would be expected to respond to changes in external P loading. Predictions from the models showed a relatively linear response between P loading and TP and chlorophyll- a (Chl- a ) concentrations in the lake, with the changes in TP and Chl- a concentrations being less on a percentage basis (50–60 percent for TP and 30–70 percent for Chl- a ) than the changes in P loading. Mean summer water clarity, quantified by Secchi disk depths, had a greater response to decreases in P loading than to increases in P loading. Based on these relations, external P loading to the lake would need to be decreased from 8,980 kg/yr to about 5,460 kg/yr for the geometric mean June–September TP concentration in the east side of the lake, with higher TP concentrations than in the west side, to reach the WDNR criterion of 0.015 mg/L. This reduction of 3,520 kg/yr is equivalent to a 46-percent reduction in the potentially controllable external P sources (all external sources except for precipitation, atmospheric deposition, and waterfowl) from those measured during water years 2014–18. The total external P loading would need to decrease to 7,680 kg/yr (a 17-percent reduction in potentially controllable external P sources) for near-surface June–September TP concentrations in the west side of the lake to reach 0.015 mg/L. Total external P loading would need to decrease to 3,870–5,320 kg/yr for the lake to be classified as oligotrophic, with a near-surface June–September TP concentration of 0.012 mg/L. Results from the hydrodynamic water-quality model GLM–AED (General Lake Model coupled to the Aquatic Ecodynamics modeling library) indicated that MOMs are driven by external P loading and internal sediment recycling that lead to high TP concentrations during spring and early summer, which in turn lead to high phytoplankton production, high metabolism and respiration, and ultimately DO consumption in the upper, warmer areas of the metalimnion. GLM–AED results indicated that settling of organic material during summer might be slowed by the colder, denser, and more viscous water in the metalimnion and thus increase DO consumption. Based on empirical evidence from a comparison of MOMs with various meteorological, hydrologic, water quality, and in-lake physical factors, MOMs were lower during summers, when metalimnetic water temperatures were warmer, near-surface Chl- a and TP concentrations were higher, and Secchi depths were lower. GLM–AED results indicated that the external P load would need to be reduced to about 4,060 kg/yr, a 57-percent reduction from that measured in 2014–18, to eliminate the occurrence of MOMs less than 5 mg/L during more than 75 percent of the years (the target provided by the WDNR). Large reductions in external P loading are expected to have an immediate effect on the near-surface TP concentrations and metalimnetic DO concentrations in Green Lake; however, it may take several years for the full effects of the external-load reduction to be observed because internal sediment recycling is an important source of P for the following spring.

Wisconsin↗
USGS2012

Presence of selected chemicals of emerging concern in water and bottom sediment from the St. Louis River, St. Louis Bay, and Superior Bay, Minnesota and Wisconsin, 2010

The St. Louis Bay of Lake Superior receives substantial urban runoff, wastewater treatment plant effluent, and industrial effluent. In 1987, the International Joint Commission designated the St. Louis Bay portion of the lower St. Louis River as one of the Great Lakes Areas of Concern. Concerns exist about the potential effects of chemicals of emerging concern on aquatic biota because many of these chemicals, including endocrine active chemicals, have been shown to affect the endocrine systems of fish. To determine the occurrence of chemicals of emerging concern in the St. Louis River, the St. Louis Bay, and Superior Bay, the U.S. Geological Survey in cooperation with the Minnesota Pollution Control Agency and the Wisconsin Department of Natural Resources collected water and bottom-sediment samples from 40 sites from August through October 2010. The objectives of this study were to (1) identify the extent to which chemicals of emerging concern, including pharmaceuticals, hormones, and other organic chemicals, occur in the St. Louis River, St. Louis Bay, and Superior Bay, and (2) identify the extent to which the chemicals may have accumulated in bottom sediment of the study area. Samples were analyzed for selected wastewater indicators, hormones, sterols, bisphenol A , and human-health pharmaceuticals. During this study, 33 of 89 chemicals of emerging concern were detected among all water samples collected and 56 of 104 chemicals of emerging concern were detected in bottom-sediment samples. The chemical N,N -diethyl- meta -toluamide (DEET) was the most commonly detected chemical in water samples and 2,6-dimethylnaphthalene was the most commonly detected chemical in bottom-sediment samples. In general, chemicals of emerging concern were detected at a higher frequency in bottom-sediment samples than in water samples. Estrone (a steroid hormone) and hexahydrohexamethyl cyclopentabensopyran (a synthetic fragrance) were the most commonly detected endocrine active chemicals in water samples; beta -sitosterol (a plant sterol), estrone, and 4- tert -octylphenol (an alkylphenol) were the most commonly detected endocrine active chemicals in bottom-sediment samples. The greater detection frequency of chemicals in bottom-sediment samples compared to the detection frequency in water samples indicates that bottom sediment is an important sink for chemicals of emerging concern. At least one polycyclic aromatic hydrocarbon was detected in every sample; and in most samples, all nine polycyclic aromatic hydrocarbons included in analyses were detected. Bottom sediment collected from Superior Bay had the most polycyclic aromatic hydrocarbon detections of the sediment sampling locations.

Minnesota;Wisconsin↗
USGS2012

Methylation of Hg downstream from the Bonanza Hg mine, Oregon

Speciation of Hg and conversion to methyl-Hg were evaluated in stream sediment, stream water, and aquatic snails collected downstream from the Bonanza Hg mine, Oregon. Total production from the Bonanza mine was >1360t of Hg, during mining from the late 1800s to 1960, ranking it as an intermediate sized Hg mine on an international scale. The primary objective of this study was to evaluate the distribution, transport, and methylation of Hg downstream from a Hg mine in a coastal temperate climatic zone. Data shown here for methyl-Hg, a neurotoxin hazardous to humans, are the first reported for sediment and water from this area. Stream sediment collected from Foster Creek flowing downstream from the Bonanza mine contained elevated Hg concentrations that ranged from 590 to 71,000ng/g, all of which (except the most distal sample) exceeded the probable effect concentration (PEC) of 1060ng/g, the Hg concentration above which harmful effects are likely to be observed in sediment-dwelling organisms. Concentrations of methyl-Hg in stream sediment collected from Foster Creek varied from 11 to 62ng/g and were highly elevated compared to regional baseline concentrations (0.11-0.82ng/g) established in this study. Methyl-Hg concentrations in stream sediment collected in this study showed a significant correlation with total organic C (TOC, R 2 =0.62), generally indicating increased methyl-Hg formation with increasing TOC in sediment. Isotopic-tracer methods indicated that several samples of Foster Creek sediment exhibited high rates of Hg-methylation. Concentrations of Hg in water collected downstream from the mine varied from 17 to 270ng/L and were also elevated compared to baselines, but all were below the 770ng/L Hg standard recommended by the USEPA to protect against chronic effects to aquatic wildlife. Concentrations of methyl-Hg in the water collected from Foster Creek ranged from 0.17 to 1.8ng/L, which were elevated compared to regional baseline sites upstream and downstream from the mine that varied from <0.02 to 0.22ng/L. Aquatic snails collected downstream from the mine were elevated in Hg indicating significant bioavailability and uptake of Hg by these snails. Results for sediment and water indicated significant methyl-Hg formation in the ecosystem downstream from the Bonanza mine, which is enhanced by the temperate climate, high precipitation in the area, and high organic matter.

Oregon↗
USGS2005

Managing vegetation in surface-flow wastewater-treatment wetlands for optimal treatment performance

Constructed wetlands that mimic natural marshes have been used as low-cost alternatives to conventional secondary or tertiary wastewater treatment in the U.S. for at least 30 years. However, the general level of understanding of internal treatment processes and their relation to vegetation and habitat quality has not grown in proportion to the popularity of these systems. We have studied internal processes in surface-flow constructed wastewater-treatment wetlands throughout the southwestern U.S. since 1990. At any given time, the water quality, hydraulics, water temperature, soil chemistry, available oxygen, microbial communities, macroinvertebrates, and vegetation each greatly affect the treatment capabilities of the wetland. Inside the wetland, each of these components plays a functional role and the treatment outcome depends upon how the various components interact. Vegetation plays a uniquely important role in water treatment due to the large number of functions it supports, particularly with regard to nitrogen transformations. However, it has been our experience that vegetation management is critical for achieving and sustaining optimal treatment function. Effective water treatment function and good wildlife quality within a surface-flow constructed wetland depend upon the health and sustainability of the vegetation. We suggest that an effective tool to manage and sustain healthy vegetation is the use of hummocks, which are shallow emergent plant beds within the wetland, positioned perpendicular to the water flow path and surrounded by water sufficiently deep to limit further emergent vegetation expansion. In this paper, we describe the use of a hummock configuration, in conjunction with seasonal water level fluctuations, to manage the vegetation and maintain the treatment function of wastewater-treatment wetlands on a sustainable basis.

Ecological Engineering↗
USGS2014

Appendix E—List of current publications concerning ground water

Alexander, W. H., Jr., Broadhurst, W. L., and White, W. N., Progress report on ground water In the High Plains in Texas, Tex. State Bd. Water Engrs., 12 pp., 7 tigs. (mimeogranhedl May 1944. Ashley, George H.,and Graham, Jack B., Groundwater investigations in Pennsylvania Pa. Dep. Internal Affairs, Monthly Bull., v. 13, pp. 10–13 and 28, 1945.

Eos, Transactions, American Geophysical Union↗
USGS2017

Atmospheric rivers emerge as a global science and applications focus

Recent advances in atmospheric sciences and hydrology have identified the key role of atmo-spheric rivers (ARs) in determining the distribution of strong precipitation events in the midlatitudes. The growth of the subject is evident in the increase in scientific publications that discuss ARs (Fig. 1a). Combined with related phenomena, that is, warm conveyor belts (WCBs) and tropical moisture exports (TMEs), the frequency, position, and strength of ARs determine the occurrence of floods, droughts, and water resources in many parts of the world. A conference at the Scripps Institution of Oceanography in La Jolla, California, recently gathered over 100 experts in atmospheric, hydrologic, oceanic, and polar science; ecology; water management; and civil engineering to assess the state of AR science and to explore the need for new information. This first International Atmospheric Rivers Conference (IARC) allowed for much needed introductions and interactions across fields and regions, for example, participants came from five continents, and studies covered ARs in six continents and Greenland (Fig. 1b). IARC also fostered discussions of the status and future of AR science, and attendees strongly supported the idea of holding another IARC at the Scripps Institution of Oceanography in the summer of 2018.

Bulletin of the American Meteorological Society↗
USGS2021

Spatial and temporal distribution of radio-tagged Lost River (Deltistes luxatus) and shortnose (Chasmistes brevirostris) suckers in Clear Lake Reservoir and associated spawning tributaries, Northern California, 2015–17

Executive Summary Data from a multi-year radio telemetry study were used to assess seasonal distribution patterns for two long-lived, federally endangered catostomids across substantially different water conditions in Clear Lake Reservoir, northern California. Lost River ( Deltistes luxatus ) and shortnose ( Chasmistes brevirostris ) suckers, two species endemic to the Klamath Basin, were implanted with radio transmitters in each of 3 years in an effort to expand our understanding of seasonal sucker movements within the reservoir and their migrations in spawning tributaries. Clear Lake Reservoir and its tributaries are part of a critical management unit within the Lost River Basin Recovery Unit for populations of Lost River and shortnose suckers. We documented residency and migratory behaviors and how behaviors were affected by lake surface elevations and water management practices. Adult suckers were captured during autumn trammel net sampling in the west lobe of the reservoir and implanted with internal radio transmitters. A total of 163 suckers were radio-tagged (75 in 2014, 64 in 2015, and 24 in 2016); 27 more shortnose suckers were tagged than Lost River suckers to reflect the larger population of shortnose suckers in the reservoir. Sex ratios were approximately equal for each species. Aerial telemetry surveys were used to monitor radio-tagged fish from January 20 to December 2 each year and to document the upstream extent of spawning migrations in the tributaries. Surveys were scheduled more frequently during the spawning season (February–June) when suckers are known to move out of the reservoir and into spawning tributaries.

California↗
USGS2021

Appendix E. Water quality and hydrology of Green Lake, Wisconsin, and the response in its near-surface water-quality and metalimnetic dissolved oxygen minima to changes in phosphorus loading

Green Lake is the deepest natural inland lake in Wisconsin, USA, with a maximum depth of about 72 meters (m). In the early 1900’s, the lake was believed to have very good water quality (low nutrient concentrations and good water clarity), with low dissolved oxygen (DO) concentrations only in the deepest part of the lake. Because of increased phosphorus (P) inputs from anthropogenic activities in its watershed, total phosphorus (TP) concentrations in the lake increased, which led to increased algal production and low DO concentrations not only occurring in its deepest areas but also in the middle of the water column (metalimnion). Routine monitoring of the lake and its tributaries has been conducted by the U.S. Geological Survey since 2004 and 1988, respectively. Results from this monitoring led to the Wisconsin Department of Natural Resources (WDNR) listing the lake as impaired because of low DO concentrations in the metalimnion, with elevated TP concentrations identified as the cause of impairment. As part of this study, comprehensive sampling of the lake and its tributaries was conducted in 2017–2018 to augment ongoing monitoring and further describe the low DO concentrations in the lake (especially in the metalimnion). Empirical and process-driven water quality models were then used to determine the causes of the low DO concentrations and the magnitude of P load reductions needed to improve the water quality of the lake to meet multiple water-quality goals, including the WDNR criteria for TP and DO. Data from previous studies showed that DO concentrations in the metalimnion decreased slightly as summer progressed in the early 1900’s, but since the late 1970s have typically dropped below 5 milligrams per liter (mg/L), which is the WDNR criterion for impairment. During 2014–2018 (baseline period for this study), the near-surface geometric-mean TP concentration during June–September in the east side of the lake was 0.020 mg/L and in the west side was 0.016 mg/L (both were below the 0.015 mg/L WDNR criterion for the lake), and the minimum metalimnetic DO concentrations measured in August ranged from 1.0 to 4.7 mg/L. It was believed that the degradation in water quality was caused by excessive P inputs to the lake; therefore, the total P inputs to the lake were estimated. The mean annual external P load during 2014–2018 was estimated to be 8,980 kilograms per year (kg/yr), of which monitored and unmonitored tributary inputs contributed 84 percent, atmospheric inputs contributed 8 percent, waterfowl contributed 7 percent, and septic systems contributed 1 percent. At fall turnover, internal sediment recycling contributed an additional 7,040 kg that increased TP concentrations in shallow areas of the lake by about 0.020 mg/L. The elevated TP concentrations then persisted until the following spring. On an annual basis, however, there is a net deposition of P to the bottom sediments. Empirical models were used to describe how the near-surface water quality of Green Lake would be expected to respond to changes in external P loading. Predictions from the models showed a relatively linear response between P loading and TP and chlorophyll-a (Chl-a) concentrations in the lake, with the changes in TP and Chl-a concentrations being less on a percentage basis (50–60 percent for TP and 30–70 percent for Chl-a) than the changes in P loading. Mean summer water clarity, indicated by Secchi disk depths, had a larger response to decreases in P loading than to increases in loading. Based on these relations, external P loading to the lake would need to be decreased from 8,980 kg/yr to about 5,460 kg/yr for the geometric mean June–September TP concentration on the east side of the lake, with higher TP concentrations than the west side, to reach the WDNR criterion of 0.015 mg/L. This reduction of 3,520 kg/yr equates to a 46-percent reduction in the potentially controllable external P sources (all external sources except precipitation, atmospheric deposition, and waterfowl) from that measured during water years (WYs) 2014–2018. The total external P loading would need to be decreased to 7,680 kg/yr (17-percent reduction in potentially controllable external P sources) for near-surface June–September TP concentrations in the west side of the lake to reach 0.015 mg/L. Total external P loading would need to be decreased to 3,870–5,320 kg/yr for the lake to be classified as oligotrophic, with a near-surface June-September TP concentration of 0.012 mg/L. Results from the hydrodynamic water-quality model GLM-AED (General Lake Model coupled to the Aquatic Ecodynamics modeling library) indicated that metalimnetic DO minima are driven by external P loading and internal sediment recycling that lead to high TP concentrations during spring and early summer, which in turn lead to high phytoplankton production, high metabolism and respiration, and ultimately DO consumption in the upper, warmer areas of the metalimnion. GLM-AED results indicated that settling of organic material during summer may be slowed by the colder, denser, and more viscous water in the metalimnion and increase DO consumption. Based on empirical evidence comparing minimum metalimnetic DO concentrations with various meteorological, hydrologic, water quality, and in-lake physical factors, lower metalimnetic DO concentrations occurred when there was warmer metalimnetic water temperatures, higher near-surface Chl-a and TP concentrations, and lower Secchi depths during summer. GLM-AED results indicated that the external P load would need to be reduced to about 4,010 kg/yr, a 57-percent reduction from that measured in 2014–2018, to eliminate the occurrence of metalimnetic DO minima of less than 5 mg/L in over 75 percent of the years (the target provided by the WDNR). Large reductions in external P loading are expected to have an immediate effect on the near-surface TP concentrations and metalimnetic DO concentrations in Green Lake. However, it may take several years for the full effects of the external load reduction to be observed because internal sediment recycling is an important source of P for the following spring.

Wisconsin↗
USGS2018

Minimum energy requirements for desalination of brackish groundwater in the United States with comparison to international datasets

This paper uses chemical and physical data from a large 2017 U.S. Geological Survey groundwater dataset with wells in the U.S. and three smaller international groundwater datasets with wells primarily in Australia and Spain to carry out a comprehensive investigation of brackish groundwater composition in relation to minimum desalination energy costs. First, we compute the site-specific least work required for groundwater desalination. Least work of separation represents a baseline for specific energy consumption of desalination systems. We develop simplified equations based on the U.S. data for least work as a function of water recovery ratio and a proxy variable for composition, either total dissolved solids, specific conductance, molality or ionic strength. We show that the U.S. correlations for total dissolved solids and molality may be applied to the international datasets. We find that total molality can be used to calculate the least work of dilute solutions with very high accuracy. Then, we examine the effects of groundwater solute composition on minimum energy requirements , showing that separation requirements increase from calcium to sodium for cations and from sulfate to bicarbonate to chloride for anions , for any given TDS concentration. We study the geographic distribution of least work, total dissolved solids, and major ions concentration across the U.S. We determine areas with both low least work and high water stress in order to highlight regions holding potential for desalination to decrease the disparity between high water demand and low water supply. Finally, we discuss the implications of the USGS results on water resource planning, by comparing least work to the specific energy consumption of brackish water reverse osmosis plants and showing the scaling propensity of major electrolytes and silica in the U.S. groundwater samples.

Water Research↗
USGS1997

Water-quality trends in the Rio Grande/Rio Bravo Basin using sediment cores from reservoirs

Water-quality trends reflect the relation between water quality and human activities, chronicling changes in concentrations of environmental contaminants, introduction of new contaminants, and successful efforts in environmental pollution remediation. Historical data available for analyzing trends often have severe limitations, from questionable accuracy to unknown sampling and analytic methodologies. Where data are unavailable or have such limitations, water-quality trends sometimes can be reconstructed using sediment cores from lakes and reservoirs. The purpose of this fact sheet is to summarize the findings of a study to assess historical changes in surface-water quality in the Rio Grande Basin (known as the R&iacute;o Bravo Basin in Mexico) by analyzing changes in sediment chemistry in cores from three reservoirs: Elephant Butte Reservoir, Amistad International Reservoir, and Falcon International Reservoir (fig. 1). Sediments that erode from the land surface are transported by tributaries into the Rio Grande/R&iacute;o Bravo. Metals and some persistent pesticides and industrial organic compounds sorb to these sediments, which eventually accumulate at the bottom of the reservoirs or are transported to the Gulf of Mexico. Although use of reservoir cores has limitations&mdash;for example, the cores do not record trends in non-persistent compounds&mdash;in many cases the data provide a partial historical record of water quality. In 1991, the U.S. Geological Survey (USGS) began full implementation of the National Water-Quality Assessment (NAWQA) Program (Leahy and others, 1990). Also in 1991, the State of Texas established the Clean Rivers Program (CRP) administered by the Texas Natural Resource Conservation Commission (TNRCC). The coring study reported here was a collaborative effort between the NAWQA Program and the CRP Rio Grande Border Environmental Assessment Team, with additional funding support from the El Paso County Water Improvement District No. 1.

Colorado, New Mexico, Texas↗
USGS2019

Integrating stream gage data and Landsat imagery to complete time-series of surface water extents in Central Valley, California

Accurate monitoring of surface water location and extent is critical for the management of diverse water resource phenomena. The multi-decadal archive of Landsat satellite imagery is punctuated by missing data due to cloud cover during acquisition times, hindering the assembly of a continuous time series of inundation dynamics. This study investigated whether streamflow volume measurements could be integrated with satellite data to fill gaps in monthly surface water chronologies for the Central Valley region of California, USA, from 1984 to 2015. We aggregated measurements of maximum monthly water extent within each of the study area’s 50 8-digit hydrologic unit code [HUC] watersheds from two Landsat-derived datasets: the European Commission’s Joint Research Centre (JRC) Monthly Water History and the U.S. Geological Survey Dynamic Surface Water Extent (DSWE). We calculated Spearman rank correlation coefficients between water extent values in each HUC and streamflow discharge data. Linear regression fits of the water extent/streamflow data pairs with the highest correlations served as the basis for interpolation of missing imagery surface water values on a HUC-wise basis. Results show strong (ρ > 0.7) maximum correlations in 11 (22.4%) and 25 (51.0%) HUCs for the DSWE and JRC time series, respectively, when comparisons were restricted to imagery and gages co-located in each HUC. Strong maximum correlations occurred in 39 (79.6%; DSWE) and 42 (85.7%; JRC) HUCs when imagery was paired with discharge data from any study area gage, providing a solid basis for reconstruction of water extent values. We generated continuous time series of 30+ years in 35 HUCs, demonstrating that this technique can provide quantitative estimates of historical surface water extents and elucidate flooding or drought events over the period of data collection. Results of a non-parametric trend analysis of the long-term time series on an annual, seasonal, and monthly basis varied among HUCs, though most trends indicate an increase in surface water over the past 30 years.

California↗
USGS2007

Remote sensing of tidal chlorophyll-a variations in estuaries

Simultaneous acquisition of surface chlorophyll-a concentrations for 39 samples from boats and Daedalus 1260 Multispectral Scanner data from a U-2 aircraft was conducted in the northern reaches of San Francisco Bay on 28 August 1980. These data were used to develop regression models for predicting surface chlorophyll-a concentrations over the study area for ebb-tide (8.40 a.m. P.D.T. (Pacific Daylight Time)) and flood-tide (3.10 p.m. P.D.T.) conditions. After selection of a single &lsquo;best fitting&rsquo; model for both morning and afternoon data sets, the chlorophyll-a concentration was predicted for ebb and flood tide for the entire study area at approximately 40m &times; 40m resolution. The predicted spatial display of chlorophyll-a revealed a localized area of high phytoplankton biomass that has been inferred from field surveys and appears to be a common summer phenomenon. Knowledge of the distribution of phytoplankton and the location of this zone of high biomass is valuable in establishing management policies for this ecologically important estuary. Furthermore, the techniques used here may provide an alternative cost-effective method for assessing water-quality conditions and they may prove useful for studying spatial variations (patchiness) and seasonal variations in phytoplankton biomass in other estuaries and coastal waters.

California↗
USGS2006

A laboratory and field evaluation of a portable immunoassay test for triazine herbicides in environmental water samples

The usefulness and sensitivity, of a portable immunoassay test for the semiquantitative field screening of water samples was evaluated by means of laboratory and field studies. Laboratory results indicated that the tests were useful for the determination of atrazine concentrations of 0.1 to 1.5 &mu;g/L. At a concentration of 1 &mu;g/L, the relative standard deviation in the difference between the regression line and the actual result was about 40 percent. The immunoassay was less sensitive and produced similar errors for other triazine herbicides. After standardization, the test results were relatively insensitive to ionic content and variations in pH (range, 4 to 10), mildly sensitive to temperature changes, and quite sensitive to the timing of the final incubation step, variances in timing can be a significant source of error. Almost all of the immunoassays predicted a higher atrazine concentration in water samples when compared to results of gas chromatography. If these tests are used as a semiquantitative screening tool, this tendency for overprediction does not diminish the tests' usefulness. Generally, the tests seem to be a valuable method for screening water samples for triazine herbicides.

International Journal of Environmental Analytical ↗