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Water-quality assessment of south-central Texas — Descriptions and comparisons of nutrients, pesticides, and volatile organic compounds at three intensive fixed sites, 1996-98

Water-quality samples were collected during April 1996-April 1998 at three intensive fixed sites in the San Antonio region of the South-Central Texas study unit as part of the U.S. Geological Survey National Water-Quality Assessment Program. The sampling strategy for the intensive fixed-site assessment is centered on obtaining information about the occurrence and seasonal patterns of selected constituents including nutrients, pesticides, and volatile organic compounds. The three sites selected to determine the effects of agriculture and urbanization on surface-water quality in the study unit are Medina River at LaCoste (agriculture indicator site), Salado Creek (lower station) at San Antonio (urban indicator site), and San Antonio River near Elmendorf (integrator site). Concentrations of two nutrients, dissolved nitrite plus nitrate nitrogen and total phosphorus, were largest at the integrator site, which is downstream of municipal wastewater treatment plants. Nitrite plus nitrate nitrogen concentrations at this site often exceeded the U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) for drinking water. All total phosphorus concentrations at the site exceeded the EPA recommended maximum concentration for streams not discharging directly into reservoirs. Nitrite plus nitrate nitrogen concentrations at the integrator site tended to be smaller, and total phosphorus concentrations at the urban site tended to be larger in samples collected during stormflow than during base flow. The most detections and largest concentrations of three pesticides (atrazine, diazinon, and prometon) were in samples collected at the urban site. Some pesticide concentrations at the agriculture site showed a seasonal pattern of increasing concentrations during spring, the peak application season. Four pesticides (atrazine, deethylatrazine, diazinon, and prometon) were detected in at least 38 percent of samples collected at all three sites. The concentrations of all detected pesticides that have an MCL were less than the MCL at the three sites. More volatile organic compounds (VOC) were detected at the urban indicator site than at the agriculture indicator site, mostly likely because more sources are located in urbanized areas. The most VOCs detected and the largest concentrations of two VOCs (chloroform and tetrahydrofuran) were in samples from the integrator site. More VOCs were detected in samples collected at the integrator site during stormflow than during base flow. The concentrations of all detected VOCs that have an MCL were less than the MCL at the three sites.

Texas

Water resources related to breccia pipe uranium mining in the Grand Canyon region

Introduction In the arid Grand Canyon region, water resources are limited to primarily the Colorado River and associated tributaries and to groundwater in the form of seeps and springs. Groundwater resources in the region supply water for human use and support diverse and rich ecosystems in the locations immediately surrounding the seeps and springs. Throughout the region, uranium resources occur and may interact with water resources in both mined and unmined uranium deposits. There is a need to better understand groundwater in the region and the effects from uranium mining in order to better manage the limited water resources in the area. This Fact Sheet summarizes results from U.S. Geological Survey studies that were conducted on this topic from 2012 to 2023.

Arizona

USGS Geochron Database

Introduction Geochronology helps us understand Earth’s history by determining when important events, like volcanic eruptions, the rise of mountains, the formation of mineral resources, and changes in the landscape, happened. Geochronological data directly support geologic mapping and can inform decisions about geologic hazard mitigation, natural resource management, and infrastructure resilience. The U.S. Geological Survey (USGS) Geochron database provides access to more than 300,000 published, publicly available age measurements from more than 40,000 geological samples. This database is the result of a collaborative effort with State geological surveys and geoscientists from across the globe. The USGS Geochron database is the most comprehensive collection of geochronological data available for the United States. Users can view data through an interactive map explorer, download datasets, and integrate data into geospatial software or other analysis tools.

Fact Sheet

Estimating the probability of elevated nitrate (NO2+NO3-N) concentrations in ground water in the Columbia Basin Ground Water Management Area, Washington

Logistic regression was used to relate anthropogenic (man-made) and natural factors to the occurrence of elevated concentrations of nitrite plus nitrate as nitrogen in ground water in the Columbia Basin Ground Water Management Area, eastern Washington. Variables that were analyzed included well depth, depth of well casing, ground-water recharge rates, presence of canals, fertilizer application amounts, soils, surficial geology, and land-use types. The variables that best explain the occurrence of nitrate concentrations above 3 milligrams per liter in wells were the amount of fertilizer applied annually within a 2-kilometer radius of a well and the depth of the well casing; the variables that best explain the occurrence of nitrate above 10 milligrams per liter included the amount of fertilizer applied annually within a 3-kilometer radius of a well, the depth of the well casing, and the mean soil hydrologic group, which is a measure of soil infiltration rate. Based on the relations between these variables and elevated nitrate concentrations, models were developed using logistic regression that predict the probability that ground water will exceed a nitrate concentration of either 3 milligrams per liter or 10 milligrams per liter. Maps were produced that illustrate the predicted probability that ground-water nitrate concentrations will exceed 3 milligrams per liter or 10 milligrams per liter for wells cased to 78 feet below land surface (median casing depth) and the predicted depth to which wells would need to be cased in order to have an 80-percent probability of drawing water with a nitrate concentration below either 3 milligrams per liter or 10 milligrams per liter. Maps showing the predicted probability for the occurrence of elevated nitrate concentrations indicate that the irrigated agricultural regions are most at risk. The predicted depths to which wells need to be cased in order to have an 80-percent chance of obtaining low nitrate ground water exceed 600 feet in the irrigated agricultural regions, whereas wells in dryland agricultural areas generally need a casing in excess of 400 feet. The predicted depth to which wells need to be cased to have at least an 80-percent chance to draw water with a nitrate concentration less than 10 milligrams per liter generally did not exceed 800 feet, with a 200-foot casing depth typical of the majority of the area.

Washington

Lithium resource in the Smackover Formation brines of Southern Arkansas

Lithium-rich brine deposits occur throughout the United States, including in the Smackover Formation. The concentration of lithium in Smackover Formation brines was predicted across southern Arkansas by using a machine-learning model that incorporated lithium concentration data and geologic information. Between 5.1 and 19.0 million metric tons of lithium are calculated to be present in the brines of the Smackover Formation in southern Arkansas. The range in possible total lithium reflects the uncertainty in machine-learning predictions of lithium concentrations and the range of Smackover Formation porosity. This estimate quantifies the in-place lithium resource and does not consider the technological and economic feasibility of extracting the lithium from the brines.

Arkansas

Nutrients and pesticides in ground water of the Ozark Plateaus in Arkansas, Kansas, Missouri, and Oklahoma

A total of 229 ground-water samples were collected from 215 sites as part of the Ozark Plateaus study unit of the National Water-Quality Assessment Program. These samples were collected from 1993 through 1995 using a network of springs and wells with three scale-dependent components. The first component, the study-unit survey, consisted of 99 randomly selected springs and domestic wells in the Springfield Plateau and Ozark aquifers. The second component, two land-use studies, consisted of 42 springs and domestic wells in a poultry-dominated agricultural area and 40 springs and domestic wells in a cattle-dominated agricultural area overlying the Springfield Plateau aquifer. The third component, the small-watershed study, consisted of 4 springs, 18 domestic wells, and 11 monitoring wells in a small basin within the poultry land-use study area. Samples were analyzed for major ions, nutrients, dissolved organic carbon, methylene blue active substances, tritium, and 88 pesticides and metabolites.The water-quality data from these samples were analyzed with descriptive and statistical methods. Nitrite plus nitrate, which was detected more often and in greater concentrations than any of the other nutrients, ranged from less than 0.05 to 25 milligrams per liter as nitrogen. Nitrite plus nitrate concentrations positively correlated to percent agricultural land use around each site. Median nitrite plus nitrate concentrations generally were greater in samples from springs than in samples from wells. Concentrations of nitrite, ammonia, and ammonia plus organic nitrogen were also affected by land use and also by concentrations of dissolved oxygen in the ground water. Concentrations of phosphorus and orthophosphate probably were affected by land use and also by phosphorus solubility. Pesticides were detected in 80 of 229 samples from 73 of 215 sites. A total of 20 pesticides were detected with a maximum of 5 pesticides detected in any 1 sample. The most commonly detected pesticides were tebuthiuron, atrazine, prometon, desethylatrazine, and simazine. Maximum concentrations ranged from 0.003 to 1.0 microgram per liter. The occurrence and distribution of pesticides were related to land use. Percent agricultural land use was greater for samples with pesticides detected than for samples with no pesticides detected. Pesticides were detected more often in samples from springs than in samples from wells. The occurrence of pesticides also was related to seasonality and chemical characteristics, such as solubility and persistence, of the compounds.

Arkansas, Kansas, Missouri, Oklahoma

Hydrologic investigation of water level fluctuations at Moreau Lake, Moreau Lake State Park, town of Moreau, New York

The causes of water level fluctuations at Moreau Lake, within Moreau Lake State Park in the town of Moreau, New York, were investigated from 2016 to 2021 after lake water levels dropped between 2015 and 2016, raising concerns about the loss of a shallow swimming area at the park beach. Annual variation in precipitation records from the area did not account for the lake water level decline. Two possible causes for the low lake water levels were investigated: the increase in groundwater withdrawals from new residential development since about 2000 and seasonal changes (nongrowing and growing seasons) in precipitation. Investigation of the potential effects of nearby groundwater withdrawals required the compilation and collection of well-log data, seismic surveys, and measurements of lake and groundwater levels, field chemical parameters, and water isotopes to define the hydrogeologic system and to estimate water use. The net result of this work was the determination that Moreau Lake is a “flow though” lake with no surface water outlet; groundwater enters the lake on the upgradient side and exits through the downgradient side, however, groundwater does not flow southward from the lake toward nearby groundwater withdrawals from the semiconfined aquifer, and thus groundwater withdrawals were unlikely to have an effect on lake water levels. Investigation of the historic precipitation records during nongrowing (November through April) and growing (May through October) indicated that (1) nongrowing season precipitation from 2011–12 to 2015–16 was more deficient than any similar period during the past 78 years and (2) since about 2000, nongrowing seasons have been drier overall and growing seasons have been considerably wetter. Initiation of lake water level monitoring in 2016 provided an opportunity to compare seasonal precipitation with seasonal lake water level changes. Nongrowing season lake water levels are very sensitive to precipitation, such that high precipitation (40 percent above the seasonal median) resulted in a 5-foot rise in lake water level. In contrast, the growing season lake water levels are sensitive to dry conditions; for example, deficient rainfall (about 6 percent below the seasonal median) resulted in a decline of lake water levels of about 3.5 feet. However, lake water levels are insensitive to high growing season rainfall inputs (about 10 to 47 percent above the seasonal median); lake water levels consistently declined about by 0.8 feet above this range of seasonal excessive precipitation.

New York

Hydrogeologic framework of the Mountain Home area, southern Idaho

In the arid western Snake River Plain around the City of Mountain Home, Idaho, declining groundwater levels concern agricultural, municipal, and other water users who rely on groundwater for sustenance because surface-water resources are limited. The U.S. Geological Survey developed this hydrogeologic framework to provide an updated characterization of groundwater resources in the western Snake River Plain around the City of Mountain Home. The hydrogeologic framework comprises: (1) a conceptual description of hydrogeologic units, (2) a three-dimensional hydrogeologic model and borehole database, (3) a map of groundwater levels and change, and (4) a discussion of groundwater occurrence and movement within the study area. Hydrogeologic units were defined based on existing literature and the borehole database compiled for this study; the five hydrogeologic units are granite, rhyolite, basalt, fine-grained sediments, and coarse-grained sediments. Each unit can bear water, but the main regional aquifer in the study area occurs in the basalt and fine-grained sediment units with depth to water ranging from 150 to 765 feet. A perched groundwater zone near the City of Mountain Home is primarily hosted in basalt and used domestically with most depths to water ranging from 30 to 100 feet. Interflow zones, scoria, and vertical fractures create heterogeneity within the basalt hydrogeologic unit that exerts strong control on groundwater movement, creating horizontal perching conditions and zones of enhanced vertical conductivity that facilitate downward groundwater percolation. In the fine- and coarse-grained sediments and rhyolite units, inferred faults both impede and enhance groundwater movement. The borehole database was constructed by digitizing 540 well-driller reports and was used to build a three-dimensional hydrogeologic framework model which reasonably represents the spatial distribution of hydrogeologic units in the study area. Generally, fine-grained sediments underlie much of the study area, with basalt concentrated in the central and western study area and rhyolite and granite in the uplands to the north. Groundwater levels were measured in 180 wells in March and November 2023; these data were used to develop water-table contour maps and describe groundwater-level change over an irrigation season. Groundwater generally flows south-southwest to the Snake River and groundwater levels declined across most of the study area (from 0.03 to 22.01 feet) between spring and autumn 2023, which is consistent with long-term declines in the Cinder Cone Butte Critical Groundwater Area and Mountain Home Groundwater Management Area. Groundwater levels rose (0.6 to 15.44 feet) over the irrigation season in most wells in the perched groundwater zone near the City of Mountain Home and near the Snake River, indicating the importance of surface-water recharge to groundwater in areas where surface water irrigation occurs. In aggregate, this hydrogeologic framework provides an updated characterization of and new insights into groundwater resources in the study area to help inform water resources management.

Idaho

Inset groundwater-flow models for the Cache and Grand Prairie Critical Groundwater Areas, northeastern Arkansas

The water resources in the Mississippi alluvial plain, located in parts of Missouri, Kentucky, Tennessee, Mississippi, Louisiana, and Arkansas, supports a multibillion-dollar agricultural industry that relies heavily on pumping of groundwater for irrigation of crops and aquaculture. The primary source of groundwater for agricultural-related pumping is the Mississippi River Valley alluvial aquifer, which has declined in storage for decades; secondary groundwater sources include the middle Claiborne aquifer and Wilcox aquifer system. Two areas in northeastern Arkansas that lie within the Mississippi alluvial plain, part of the Cache and Grand Prairie regions, have been designated as Critical Groundwater Areas owing to decades of groundwater declines that resulted from past and current water use. The multidisciplinary Mississippi Alluvial Plain project, led by the U.S. Geological Survey, and funded by their Water Availability and Use Science Program, included objectives to develop numerical groundwater models in focus regions, including the part of the Cache and Grand Prairie regions of northeastern Arkansas. Two inset models were developed using the child model capabilities of MODFLOW 6, the U.S. Geological Survey’s Modular Hydrologic Model simulation software. Both models, called the Cache model and Grand Prairie model, simulated the groundwater system and surface-water/groundwater interactions for the Mississippi River Valley alluvial aquifer and underlying Tertiary-age aquifers and confining units to the Midway confining unit. Each model was spatially discretized into 500-meter x 500-meter orthogonal cells on a grid with 5-meter constant-thickness vertical layers that represented the Mississippi River Valley alluvial aquifer and increasing thickness layers for the aquifers and confining units below the alluvial aquifer. The Cache and Grand Prairie models were calibrated with the PEST++ iterative ensemble smoother Version 5 and employed high dimensional parameterization schemes of 13,740 and 30,436 parameters, respectively. The Cache mean absolute residual for groundwater-level observations within each model domain for the priority well was 1.58 meters. Grand Prairie mean absolute residuals for the alluvial aquifer and middle Claiborne aquifer groundwater-level observations were 2.71 and 10.78 meters, respectively. The groundwater budgets for the Cache and Grand Prairie models were characterized by substantial outflows to irrigation wells, which constituted about 52 and 54 percent of all outflows, with the primary source of water to those wells being releases from unconfined aquifer storage.

Arkansas

Introduction to recommended capabilities and instrumentation for volcano monitoring in the United States

Introduction The National Volcano Early Warning System (NVEWS) was authorized and partially funded by the U.S. Government in 2019. In response, the U.S. Geological Survey (USGS) Volcano Hazards Program asked its scientists to reflect on and summarize their views of best practices for volcano monitoring. The goal was to review and update the recommendations of a previous report (Moran and others, 2008) and to provide a more detailed analysis of capabilities and instrumentation for monitoring networks for U.S. volcanoes. This Scientific Investigations Report and its chapters reflect those USGS scientists’ views and summaries and will serve as a guide for future network upgrades funded through NVEWS. Given the well-documented hazards posed by volcanoes to population centers and aviation (for example, Blong, 1984; Scott, 1989; Neal and others, 1997, 2019; Guffanti and others, 2010; Shroder and Papale, 2014; Prata and Rose, 2015; Palmer, 2020), volcano monitoring is critical for ensuring public safety and for mitigating the impacts of volcanic activity. Accurate and timely forecasts are facilitated by well-designed monitoring networks that are in place long enough to allow for background behavior to be recognized and understood. Because precursory signals may be limited and unrest may progress rapidly to an eruption, our goal is to deploy monitoring systems that enable detection of the reactivation of dormant volcanoes as early as possible, allowing for public safety and risk mitigation. NVEWS planning is also informed by the results of Ewert and others (2005, 2018), whereby 161 U.S. volcanoes are currently categorized and ranked commensurate with their relative threat. In each chapter, author(s) considered the need for some redundancy of instrumentation and telemetry, given the likelihood of occasional equipment failure, particularly in extreme and remote environments. Establishing digital telemetry networks requires advanced planning, sighting, radio-shot testing, and, inevitably, troubleshooting in the field. This is harder to achieve rapidly during a crisis; thus, an important goal for monitoring U.S. volcanoes is to establish digital telemetry backbones with redundancy and extra capacity to absorb additional instruments should a volcano begin to exhibit signs of unrest (fig. A1). The National Telecommunications and Information Administration (NTIA) imposed new regulations in the United States, eliminating the use of older analog radios for many purposes, which had been one previous means for redundant data delivery. However, the resulting conversion from analog to digital systems usefully enables stations to accommodate new and multivariate real-time data streams (for example, Global Navigation Satellite System [GNSS] receivers, infrasound arrays, gas spectrometers, visible and infrared cameras, and broadband seismometers). We note that other USGS and broader national and international hazard programs can leverage NVEWS instrumentation plans. Examples of this include the following: Improved seismic coverage of volcanoes will increase the capability of the USGS Earthquake Hazards Program to detect and locate earthquakes, estimate ground shaking, and provide timely early warnings through the ShakeAlert Earthquake Early Warning System (Given and others, 2018). The National Oceanic and Atmospheric Administration’s Tsunami Program will benefit from additional seismic stations, particularly within the sparsely instrumented Aleutian Islands, Northern Mariana Islands, and American Samoa. Infrasound stations can detect signals from landslides, debris flows and lahars, floods, and weather events, providing benefits to the National Weather Service and the USGS Landslide Hazards Program.

Scientific Investigations Report

Hydrogeologic mapping and three-dimensional geologic modeling of glacial deposits in a multicounty area of southeastern Michigan, northeastern Indiana, and northwestern Ohio

The glacial deposits underlying southeastern Michigan, northeastern Indiana, and northwestern Ohio are a substantial source of water to communities, agriculture, and industry in the region. Previous efforts to characterize aquifer materials in the area cited a need for additional information about the underlying hydrogeologic characteristics and related groundwater availability as well as improved mapping of the extent and properties of the glacial deposits. Recent U.S. Geological Survey multi-State compilations of water-well drilling records have greatly increased access to high-resolution geologic data, particularly in glacial depositional environments. This study by the U.S. Geological Survey, in cooperation with the Ohio Environmental Protection Agency, uses processed data from the State-managed collections of well records to characterize the glacial deposits in the study area using two methods. The first method creates two-dimensional maps of basic hydrogeologic information commonly required for assessments of groundwater availability, including (1) total thickness of glacial deposits, (2) total thickness of coarse-grained deposits, (3) specific-capacity-based transmissivity and hydraulic conductivity, and (4) texture-based estimated equivalent horizontal and vertical hydraulic conductivity and transmissivity. The second method builds a hydrogeologic framework of the complex glacial aquifer through construction of a volumetric geologic model by using three-dimensional kriging. Results of the volumetric model indicate that aquifer materials are primarily concentrated in the western parts of the study area near the Indiana-Ohio border. Coarse-grained sediments are also present as surficial deposits in the north of the study area where intermixing glacial advances created complex distributions of unconsolidated deposits. Two-dimensional maps of hydrogeologic properties support the volumetric model, showing thicknesses of coarse-grained deposits that reach up to 250 feet in the western sections of the study area and progressively thin to near absence in the east. Visualization of the aquifer materials with a volumetric model generally shows a highly discontinuous distribution of coarse- and fine-grained materials, with no clearly defined boundaries to delineate the extent of the aquifer. Comparisons of cross sections derived from the volumetric model with existing published maps support previous near-surface hydrogeologic interpretations while filling gaps where data are sparse, particularly in deeper parts of the aquifer. Both the two-dimensional maps and the volumetric model provide data that can directly inform assessments of groundwater availability, in addition to having future applications to studies of groundwater flow and transport.

Indiana, Michigan, Ohio

The 3D Elevation Program—Supporting Ohio's economy

Introduction High-quality elevation data are proving to be a resource of great economic value in dealing with many important issues in Ohio. Current and accurate high-resolution elevation data support flood risk management, water quantity and quality assessment, precision farming, conservation planning, impervious-surface modeling, forest and other natural resources management, abandoned mine and geologic hazard assessment, karst mapping, and siting of wellhead pads for horizontal drilling. These data also support coastal zone management, traffic safety and preliminary engineering site-selection studies for transportation infrastructure, solar potential and other renewable energy planning, aviation safety, and identification of features of interest or concern such as archaeological sites and orphan oil and gas wells. Critical applications that meet the State’s management needs depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features.

Ohio

Comparison of two approaches for determining ground-water discharge and pumpage in the lower Arkansas River Basin, Colorado, 1997-98

In March 1994, the Colorado Division of Water Resources (CDWR) adopted “Rules Governing the Measurement of Tributary Ground Water Diversions Located in the Arkansas River Basin” (Office of the State Engineer, 1994); these initial rules were amended in February 1996 (Office of the State Engineer, 1996). The amended rules require users of wells that divert tributary ground water to annually report the water pumped monthly by each well. The rules allow a well owner to report the pumpage measured by a totalizing flowmeter (TFM) or pumpage determined from electrical power data and a power conversion coefficient (PCC) (Hurr and Litke, 1989). Opinions by representatives of the State of Kansas, presented before the Special Master hearing a court case [State of Kansas v. State of Colorado, No. 105 Original (1996)] concerning post-Compact well pumping, stated that the PCC approach does not provide the same level of accuracy and reliability as a TFM when used to determine pumpage. In 1997, the U.S. Geological Survey (USGS), in cooperation with the CDWR, began a 2-year study to compare ground-water pumpage estimates made using the TFM and the PCC approaches. The study area was along the Arkansas River between Pueblo, Colorado, and the Colorado-Kansas State line (fig. 1). The two approaches for estimating ground-water discharge and pumpage were compared for more than 100 wells completed in the alluvial aquifer of the Arkansas River Basin. The TFM approach uses an inline flowmeter to directly measure instantaneous discharge and the total volume of water pumped at a well. The PCC approach uses electrical power consumption records and a power conversion coefficient to estimate the pumpage at ground-water wells. This executive summary describes the results of the comparison of the two approaches. Specifically, (1) the differences in instantaneous discharge measured with three portable flowmeters and measured with an inline TFM are evaluated, and the statistical differences in paired instantaneous discharge between the two approaches are determined; (2) short- and long-term variations in the PCC’s are presented; (3) differences in pumpage between the two approaches are evaluated, and the statistical differences in pumpage between the two approaches are determined; (4) potential sources of discrepancy between pumpage estimates are discussed; and (5) differences in total network pumpage using the two approaches are presented. During the irrigation seasons of 1997 and 1998, instantaneous discharge and electrical power demand were measured at randomly selected wells to determine PCC’s. At more than 100 wells, the PCC’s determined during the 1998 season were applied to total electrical power consumption data that was recorded between the initial and final readings at each network well site in 1998 to estimate total ground-water pumpage. At each site, an inline TFM was installed in a full-flowing, acceptable test section of pipe on the discharge side of the pump where the measurement of discharge was made. Measurements of instantaneous ground-water discharge also were made using three different types of portable flowmeters. The average velocity multiplied by the cross-sectional area of the discharge pipe was used to compute the discharge in gallons per minute. Whenever possible, discharge measurements were made at each network site using all three types of portable flowmeters.

Colorado

Field observations and logs from the Rose Hip trench exposure across a north-facing scarp within the Seattle Fault Zone, southern Bainbridge Island, Washington

The Seattle Fault Zone is an approximately 70-km-long, east-west-trending zone of south-dipping blind reverse faults within the Puget lowland region in Washington. Because of the proximity, the Seattle Fault Zone poses a significant earthquake hazard to the Puget sound and Seattle metropolitan regions. We present preliminary mapping and trench-site information from a paleoseismic investigation across a newly identified active fault scarp located within the hanging wall of the Seattle Fault Zone on southern Bainbridge Island, Washington. The trench exposed monoclinally folded Miocene bedrock, fractured and faulted glacial-related deposits, and laminated lacustrine deposits capped by slope-derived colluvium. The observations from this investigation record late Pleistocene to Holocene north-vergent folding and faulting along this new fault scarp.

Washington

Evaluation of best management practices at an edge-of-field site in the Eagle Creek watershed, Ohio, 2012–20

In 2010, the U.S. Geological Survey worked in partnership with the Great Lakes Restoration Initiative and the Natural Resources Conservation Service to identify farm fields in priority watersheds—watersheds critically important to Great Lake health. Intensive best management practices were implemented in five States to test the efficacy of best management practices, also referred to as agricultural conservation practices, to reduce sediment and nutrient runoff on agricultural fields. These fields were chosen as representatives of the priority watersheds because their farming practices and geographical conditions were common among farms in those watersheds. A farm site located near Findlay, Ohio, in the Eagle Creek watershed used two conservation practices, cover crop (Natural Resources Conservation Service practice standard 340) and variable rate technology (VRT; Natural Resources Conservation Service practice standard 590), which represent common practices in the Maumee priority watershed. This study monitored surface runoff and subsurface tile runoff at the Eagle Creek watershed site. The effects of cover crop and VRT nutrient application on sediment and nutrient runoff were assessed from October 2012 to September 2020. Cover crops were applied in fall of 2016, 2017, and 2018, coinciding with VRT applications. The following parameters were analyzed as part of the study: runoff discharge; peak discharge; and concentrations and loads of total phosphorus, particulate phosphorus, dissolved reactive phosphorus, and suspended sediment. High peak runoff events disproportionally affected nutrient concentrations and loads in runoff. A threshold of the 85th percentile of the peak discharge was chosen to assess the effect of cover crop and VRT nutrient application on nutrient mitigation at each gage. Runoff events below the 85th percentile were considered small, and runoff events over the 85th percentile were considered large. Concentrations from collected water-quality samples were used for the analysis; estimated concentrations were excluded from the statistical evaluation. All surface runoff parameters during small runoff events, except surface runoff volume, were significantly lower in the period with cover crops and VRT implementation. Contrarily, subsurface runoff parameters during small events were not statistically different between the periods with and without cover crops and VRT implementation. Surface and subsurface parameters during large events were also not statistically different between the periods with and without cover crops and VRT implementation. These results indicate cover crops and VRT may improve water quality during small runoff events, but additional best management practices that mitigate large runoff events may lead to greater water-quality improvement given the contribution of large events to overall losses.

Ohio

Hydrologic and water-quality conditions in the Horse Creek basin, west-central Florida, October 1992-February 1995

A baseline study of the 241-square-mile Horse Creek basin was undertaken from October 1992 to February 1995 to assess the hydrologic and water-quality conditions of one of the last remaining undeveloped basins in west-central Florida. During the period of the study, much of the basin remained in a natural state, except for limited areas of cattle and citrus production and phosphate mining. Rainfall in 1993 and 1994 in the Horse Creek basin was 8 and 31 percent, respectively, above the 30-year long-term average. The lowest and highest maximum instantaneous peak discharge of the six daily discharge stations occurred at the Buzzard Roost Branch and the Horse Creek near Arcadia stations with 185 to 4,180 cubic feet per second, respectively. The Horse Creek near Arcadia station had the lowest number of no-flow days with zero days and the Brushy Creek station had the highest number with 113 days. During the study, the West Fork Horse Creek subbasin had the highest daily mean discharge per square mile with 30.6 cubic feet per second per square mile, and the largest runoff coefficient of 43.7 percent. The Buzzard Roost Branch subbasin had the lowest daily mean discharge per square mile with 5.05 cubic feet per second per square mile, and Brushy Creek and Brandy Branch shared the lowest runoff coefficient of 0.6 percent. Brandy Branch had the highest monthly mean runoff in both 1993 and 1994 with 11.48 and 19.28 inches, respectively. During the high-baseflow seepage run, seepage gains were 8.87 cubic feet per second along the 43-mile Horse Creek channel. However, during the low-baseflow seepage run, seepage losses were 0.88 cubic foot per second. Three methods were used to estimate average annual ground-water recharge in the Horse Creek basin: (1) well hydrograph, (2) chloride mass balance, and (3) streamflow hydrograph. Estimated average annual recharge using these three methods ranged from 3.6 to 8.7 inches. The high percentage of carbonate plus bicarbonate analyzed at the Carlton surficial aquifer well could indicate an upward ground-water flow from the underlying intermediate aquifer system. Based on constituent concentrations in water samples from the six daily discharge stations, concentrations generally are lower in the upper three subbasins, West Fork Horse Creek, Upper Horse Creek, and Brushy Creek than in the lower three subbasins. Typically, concentrations were highest for major ions at Buzzard Roost Branch and nutrients at Brushy Creek.

Florida

The Long Island Sound and Watershed Metadata map application

The Long Island Sound and its watershed encompass an area of about 17,000 square miles and include the Connecticut, Housatonic, and Thames Rivers, which all drain to the sound. Dozens of organizations from government agencies, nonprofits, and Tribal Nations have developed projects and monitoring programs to analyze and protect the water resources of the watershed and sound. The abundance of data and lack of an existing searchable index require a centralized metadata repository to allow users to find water resources data more efficiently. The U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the Long Island Sound Study, has created an interactive map application to visualize and search for metadata information across organizations working to monitor and protect the Long Island Sound.

Connecticut, Massachusetts, New Hampshire, New Yor

Groundwater-level elevations in the bedrock aquifers of the Denver Basin aquifer system, Elbert County, Colorado, 2015–23

Water users in Elbert County, Colorado, rely on groundwater from bedrock aquifers in the Denver Basin aquifer system (upper Dawson, lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers) for approximately half of their water uses. Withdrawals from the bedrocks aquifers have increased to meet the water use needs of expanding regional population growth and development. The U.S. Geological Survey, in cooperation with the Elbert County Board of County Commissioners, began a study in 2015 to monitor groundwater levels within Elbert County. The primary purpose of this report is to present a summary of groundwater levels measured during the study period (2015–23) and present results from statistical analyses of changes in groundwater-level elevations through time. Discrete groundwater levels were measured at 36 wells within Elbert County. Seven of those wells contained equipment to make and record continuous groundwater-level measurements at hourly intervals. All aquifers, except the lower Dawson aquifer, had only declining groundwater-level elevations in discrete measurements for wells with statistically significant trends. Of the eight statistically significant trends in the lower Dawson aquifer, two wells indicated increasing groundwater-level elevation from discrete measurements. The groundwater-level elevation trend medians in the upper Dawson, lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers were −0.23, −0.66, −0.64, −0.39, and −0.63 feet per year, respectively, for discrete groundwater-level elevation measurements. Trends in continuous groundwater-level elevations were in agreement with statistically significant trends in discrete groundwater-level elevations for all wells. The groundwater-level elevation trend medians in this study, compared to the overall trends in a 2015−2018 study, both indicated declining groundwater-level elevations except in the upper Dawson aquifer, where the trend direction was opposite, a positive trend from 2015 to 2018 and a negative trend (declining groundwater elevations) from 2015 to 2023. The change in trends within the upper Dawson aquifer may be affected by differences in the study period and the trend analysis applied. Trends during the 2015–23 study period were compared to departures from the median 2015 groundwater-level elevation for each site in each aquifer. In general, the departures from the 2015 median supported trends observed at each site and correlated spatially with greater departures near the western border of Elbert County. Additionally, 30-year precipitation data showing wet and dry periods were overlaid with the departure from the 2015 median to assess groundwater-level patterns in wells in the five aquifers. Departures from the 2015 median groundwater-level elevations appeared greatest during the dry period between 2020 and 2023. Potentiometric-surface maps of the upper and lower Dawson aquifers created from static April 2023 groundwater elevations indicated groundwater-flow direction is generally from the south to the north. Results of this study could be used to guide additional groundwater monitoring in Elbert County and could aid in long-term planning of water resources.

Colorado