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A remote sensing approach for estimating the location and rate of urban irrigation in semi-arid climates

Urban irrigation is an important component of the hydrologic cycle in many areas of the arid and semiarid western United States. This paper describes a new approach that uses readily available datasets to estimate the location and rate of urban irrigation. The approach provides a repeatable methodology at 1/3 km 2 resolution across a large urbanized area (500 km 2 ). For this study, Landsat Thematic Mapper satellite imagery, air photos, climatic records, and a land-use map were used to: (1) identify the fraction of irrigated landscaping in urban areas, and (2) estimate the monthly rate of irrigation being applied to those areas. The area chosen for this study was the San Fernando Valley in Southern California. Identifying irrigated areas involved the use of 29 satellite images, air photos, and a land-use map. The fraction of a pixel that consists of irrigated landscaping (F irr ) was estimated using a linear-mixture model of two land-cover endmembers (selected pixels within a satellite image that represent a targeted land-cover). The two endmembers were impervious and fully-irrigated landscaping. In the San Fernando Valley, we used airport buildings, runways, and pavement to represent the impervious endmember; golf courses and parks were used to represent the fully irrigated endmember. The average F irr using all 29 satellite scenes was 44%. F irr calculated from hand-digitizing using air photos for 13 randomly selected single-family-residential neighborhoods showed similar results (42%). Estimating the rate of irrigation required identification of a third endmember: areas that consisted of urban vegetation but were not irrigated. This "nonirrigated" endmember was used to compute a Normalized Difference Vegetation Index (NDVI) surplus, defined as the difference between the NDVI signals of the irrigated and nonirrigated endmembers. The NDVI signals from irrigated areas remains relatively constant throughout the year, whereas the signal from nonirrigated areas rises and falls seasonally due to precipitation. The areas between airport runways were chosen to represent the nonirrigated endmember. Water-delivery records from 65 spatially-distributed single-family neighborhoods, consisting of nearly 1800 homes, were correlated with the NDVI surplus. The results show a strong exponential correlation ( r 2 = 0.94). In the absence of water-delivery records, which can be difficult to obtain, a surrogate was identified: the landscape evapotranspiration rate (ET L ). ET L was used to scale NDVI surplus (which is dimensionless) to irrigation rates using an exponential scaling function. The monthly irrigation rates calculated from satellite and climatic data compared well with irrigation rates calculated from actual water-delivery data using a paired Wilcoxan signed-rank test ( p = 0.0063). Identification of F irr at the pixel scale, along with identification of the irrigation rate for a fully-irrigated pixel, allows for mapping of urban irrigation over large areas. Maps showing the location and rate of monthly irrigation for the San Fernando study area were computed for January and August 1997.

California↗

OpenET: Filling a critical data gap in water management for the western United States

The lack of consistent, accurate information on evapotranspiration (ET) and consumptive use of water by irrigated agriculture is one of the most important data gaps for water managers in the western United States (U.S.) and other arid agricultural regions globally. The ability to easily access information on ET is central to improving water budgets across the West, advancing the use of data-driven irrigation management strategies, and expanding incentive-driven conservation programs. Recent advances in remote sensing of ET have led to the development of multiple approaches for field-scale ET mapping that have been used for local and regional water resource management applications by U.S. state and federal agencies. The OpenET project is a community-driven effort that is building upon these advances to develop an operational system for generating and distributing ET data at a field scale using an ensemble of six well-established satellite-based approaches for mapping ET. Key objectives of OpenET include: Increasing access to remotely sensed ET data through a web-based data explorer and data services; supporting the use of ET data for a range of water resource management applications; and development of use cases and training resources for agricultural producers and water resource managers. Here we describe the OpenET framework, including the models used in the ensemble, the satellite, meteorological, and ancillary data inputs to the system, and the OpenET data visualization and access tools. We also summarize an extensive intercomparison and accuracy assessment conducted using ground measurements of ET from 139 flux tower sites instrumented with open path eddy covariance systems. Results calculated for 24 cropland sites from Phase I of the intercomparison and accuracy assessment demonstrate strong agreement between the satellite-driven ET models and the flux tower ET data. For the six models that have been evaluated to date (ALEXI/DisALEXI, eeMETRIC, geeSEBAL, PT-JPL, SIMS, and SSEBop) and the ensemble mean, the weighted average mean absolute error (MAE) values across all sites range from 13.6 to 21.6 mm/month at a monthly timestep, and 0.74 to 1.07 mm/day at a daily timestep. At seasonal time scales, for all but one of the models the weighted mean total ET is within ±8% of both the ensemble mean and the weighted mean total ET calculated from the flux tower data. Overall, the ensemble mean performs as well as any individual model across nearly all accuracy statistics for croplands, though some individual models may perform better for specific sites and regions. We conclude with three brief use cases to illustrate current applications and benefits of increased access to ET data, and discuss key lessons learned from the development of OpenET.

western United States↗

Uncertainty analysis of the Operational Simplified Surface Energy Balance (SSEBop) model at multiple flux tower sites

Evapotranspiration (ET) is an important component of the water cycle – ET from the land surface returns approximately 60% of the global precipitation back to the atmosphere. ET also plays an important role in energy transport among the biosphere, atmosphere, and hydrosphere. Current regional to global and daily to annual ET estimation relies mainly on surface energy balance (SEB) ET models or statistical and empirical methods driven by remote sensing data and various climatological databases. These models have uncertainties due to inevitable input errors, poorly defined parameters, and inadequate model structures. The eddy covariance measurements on water, energy, and carbon fluxes at the AmeriFlux tower sites provide an opportunity to assess the ET modeling uncertainties. In this study, we focused on uncertainty analysis of the Operational Simplified Surface Energy Balance (SSEBop) model for ET estimation at multiple AmeriFlux tower sites with diverse land cover characteristics and climatic conditions. The 8-day composite 1-km MODerate resolution Imaging Spectroradiometer (MODIS) land surface temperature (LST) was used as input land surface temperature for the SSEBop algorithms. The other input data were taken from the AmeriFlux database. Results of statistical analysis indicated that the SSEBop model performed well in estimating ET with an R2 of 0.86 between estimated ET and eddy covariance measurements at 42 AmeriFlux tower sites during 2001–2007. It was encouraging to see that the best performance was observed for croplands, where R2 was 0.92 with a root mean square error of 13 mm/month. The uncertainties or random errors from input variables and parameters of the SSEBop model led to monthly ET estimates with relative errors less than 20% across multiple flux tower sites distributed across different biomes. This uncertainty of the SSEBop model lies within the error range of other SEB models, suggesting systematic error or bias of the SSEBop model is within the normal range. This finding implies that the simplified parameterization of the SSEBop model did not significantly affect the accuracy of the ET estimate while increasing the ease of model setup for operational applications. The sensitivity analysis indicated that the SSEBop model is most sensitive to input variables, land surface temperature (LST) and reference ET ( ET o ); and parameters, differential temperature ( dT ), and maximum ET scalar ( K max ), particularly during the non-growing season and in dry areas. In summary, the uncertainty assessment verifies that the SSEBop model is a reliable and robust method for large-area ET estimation. The SSEBop model estimates can be further improved by reducing errors in two input variables ( ET o and LST) and two key parameters ( K max and dT ).

Journal of Hydrology↗

Using thermal infrared cameras to detect avian chicks at various distances and vegetative coverages

Population monitoring of nesting waterbirds often involves frequent entries into the colony, but alternative methods such as local remotely sensed thermal imaging may help reduce disturbance while providing a cost-effective way to survey breeding populations. Such an approach can have high initial costs, however, which may have reduced the number of studies investigating functionality of paired thermal infrared camera and small unmanned aerial systems. Here, we take the first step of exploring the ability of two thermal infrared cameras to detect an avian chick under varying vegetative cover and distances, preceding field-mounting applications on a small unmanned aerial system. We created seven “bioboxes” to simulate a range of natural vegetation types and densities for a globally important colonial ground-nesting waterbird species, the common tern Sterna hirundo . We placed a juvenile chicken Gallus gallus (surrogate for the locally endangered common tern) in each box, and we tested two market-accessible infrared cameras (produced by FLIR Systems and Infrared Cameras, Inc.) at five elevations using a stationary boom (maximum height = 12 m). We applied computer-based digital thresholding to collected images, identifying pixels meeting one of seven threshold values. The chick was visible from at least one threshold value in 19 and 31 of 35 processed by the FLIR Systems and Infrared Cameras, respectively. Percentage of the chick identified across thresholds was generally highest at lower threshold values and elevations and decreased as elevation and threshold increased; however, the relative importance of each variable changed dramatically across bioboxes and camera types. Ability to detect a chick from processed images generally decreased with increasing elevation, and although we made no quantitative comparisons among boxes, detectability appeared greatest in images from both cameras when little or no vegetation was present. Interestingly, no single threshold value was best for all bioboxes. We observed notable differences between cameras including visual resolution of detected temperature differentials and image processing speed. Results of this controlled study show promise for the use of thermal infrared systems for detecting cryptic species in vegetation. Future research should work to combine thermal infrared and visual sensors with small unmanned aerial systems to test applicability in a mobile field application.

Journal of Fish and Wildlife Management↗

Multispectral red-edge indices accurately estimate nitrogen content in winter cereal cover crops

Winter cover crops reduce erosion and nutrient runoff from agricultural systems. Although cereal cover crops can decrease field nitrate leaching by 50%–95%, the magnitude of this reduction varies within and between fields, making it challenging to monitor the impact of cover crops on nitrate leaching at large spatial extents. Satellite remote sensing using red-edge bands has been shown to effectively estimate crop nitrogen (N) content (kg ha −1 ) in later growth-stage crops with a closed canopy. In this study, we evaluated 15 spectral indices derived from Sentinel-2 imagery to estimate N concentration (%) and content (kg ha −1 ) of cereal cover crops, using 1627 destructive samples collected from 2018 to 2023 in Maryland. Observed N content ranged from 0.1 to 214.7 kg ha −1 , while N concentration ranged from 0.6% to 5.5%. The 15 indices considered were poor predictors of N concentration (adj. R 2 = 0.089, root mean squared error [RMSE] = 0.802%), but were more successful at measuring N content (biomass × N concentration). Delta red-edge (ΔRE) was the best predictor of N content (adj. R 2 = 0.748, RMSE = 13.10 kg ha −1 from cross-validation with 80% train and 20% test splits iterated 100 times) using samples with imagery collected within ±4 days of destructive sampling ( n = 1110). Our findings indicate that longer red-edge wavelengths (783 and 740 nm) are more suited for estimating N content in cereal cover crops compared to shorter red-edge wavelengths, which have been shown to be more sensitive to biomass. Leave-one-year-out cross-validation demonstrated that the relationship between ΔRE and N content was robust across all four cover crop sampling years included in the study (adj. R 2 = 0.700–0.769, RMSE = 10.70–15.40 kg ha −1 ). Regression model performance improved with the addition of multiple predictors, including biomass (estimated from Normalized Difference Vegetation Index), weather variables (adj. R 2 = 0.765, RMSE = 12.37 kg ha −1 ), management variables (species, season, adj. R 2 = 0.772, and RMSE = 12.13 kg ha −1 ), and biophysical variables (height, fractional ground cover, adj. R 2 = 0.818, and RMSE = 10.29 kg ha −1 ). These findings demonstrate the feasibility of quantifying N content in cereal cover crops using a red-edge-based spectral index across large geographic extents and indicate the inclusion of additional predictors, such as weather and management data, improves model accuracy. This work has implications for quantifying reductions in N leaching associated with cover crops, aiding in policymaking and evaluation of conservation programs that impact water bodies such as Chesapeake Bay.

Maryland↗

Merapi 2010 eruption—Chronology and extrusion rates monitored with satellite radar and used in eruption forecasting

Despite dense cloud cover, satellite-borne commercial Synthetic Aperture Radar (SAR) enabled frequent monitoring of Merapi volcano's 2010 eruption. Near-real-time interpretation of images derived from the amplitude of the SAR signals and timely delivery of these interpretations to those responsible for warnings, allowed satellite remote sensing for the first time to play an equal role with in situ seismic, geodetic and gas monitoring in guiding life-saving decisions during a major volcanic crisis. Our remotely sensed data provide an observational chronology for the main phase of the 2010 eruption, which lasted 12 days (26 October–7 November, 2010). Unlike the prolonged low-rate and relatively low explosivity dome-forming and collapse eruptions of recent decades at Merapi, the eruption began with an explosive eruption that produced a new summit crater on 26 October and was accompanied by an ash column and pyroclastic flows that extended 8 km down the flanks. This initial explosive event was followed by smaller explosive eruptions on 29 October–1 November, then by a period of rapid dome growth on 1–4 November, which produced a summit lava dome with a volume of ~ 5 × 10 6 m 3 . A paroxysmal VEI 4 magmatic eruption (with ash column to 17 km altitude) destroyed this dome, greatly enlarged the new summit crater and produced extensive pyroclastic flows (to ~ 16 km radial distance in the Gendol drainage) and surges during the night of 4–5 November. The paroxysmal eruption was followed by a period of jetting of gas and tephra and by a second short period (12 h) of rapid dome growth on 6 November. The eruption ended with low-level ash and steam emissions that buried the 6 November dome with tephra and continued at low levels until seismicity decreased to background levels by about 23 November. Our near-real-time commercial SAR documented the explosive events on 26 October and 4–5 November and high rates of dome growth (> 25 m 3 s − 1 ). An event tree analysis for the previous 2006 Merapi eruption indicated that for lava dome extrusion rates > 1.2 m 3 s − 1 , the probability of a large (1872-scale) eruption was ~ 10%. Consequently, the order-of-magnitude greater rates in 2010, along with the explosive start of the eruption on 26 October, the large volume of lava accumulating at the summit by 4 November, and the rapid and large increases in seismic energy release, deformation and gas emissions were the basis for warnings of an unusually large eruption by the Indonesian Geological Agency's Center for Volcanology and Geologic Hazard Mitigation (CVGHM) and their Volcano Research and Technology Development Center (BPPTK) in Yogyakarta — warnings that saved thousands of lives.

Merapi Volcano↗

Satellite remote sensing estimation of river discharge: Application to the Yukon River Alaska

A methodology based on general hydraulic relations for rivers has been developed to estimate the discharge (flow rate) of rivers using satellite remote sensing observations. The estimates of discharge, flow depth, and flow velocity are derived from remotely observed water surface area, water surface slope, and water surface height, and demonstrated for two reaches of the Yukon River in Alaska, at Eagle (reach length 34.7 km) and near Stevens Village (reach length 38.3 km). The method is based on fundamental equations of hydraulic flow resistance in rivers, including the Manning equation and the Prandtl-von Karman universal velocity distribution equation. The method employs some new hydraulic relations to help define flow resistance and height of the zero flow boundary in the channel. Estimates are made both with and without calibration. The water surface area of the river reach is measured by using a provisional version of the U.S. Geological Survey (USGS) Landsat based product named Dynamic Surface Water Extent (DSWE). The water surface height and slope measurements require a self-consistent datum, and are derived from observations from the Jason-2 satellite altimeter mission. At both reach locations, the Jason-2 radar altimeter non-winter heights consistently tracked the stage recorded at USGS streamgages with a standard deviation of differences (error) during the non-winter periods of less than 7%. Part of the error may be due to differences in the gage and altimeter crossing locations with respect to the range of stage change and the response to changes in discharge at the upstream and downstream locations. For the non-winter periods, the radar derived slope estimates (mean = 0.0003) were constant over the mission lifetime, and in agreement with previously measured USGS water surface slopes and slopes determined from USGS topographic maps. The accuracy of the mean of the uncalibrated daily estimates of discharge varied between reaches, ranging from 13% near Stevens Village (N = 90) to −21% at Eagle (N = 246) based on the absolute error, and 5% to −6% based on the error of the log of the estimates. Calibrating to the mean of USGS daily discharge estimates from the streamflow rating for the same period of record at each streamgage resulted in mean absolute errors ranging from 1% to 2%, and log errors ranging from 1% or less. The error pattern of the estimates shows that without calibration, even though the mean is well simulated, the high and low end values over the range of estimates may have significant bias.

Alaska↗

Assessment of Mars Pathfinder landing site predictions

Remote sensing data at scales of kilometers and an Earth analog were used to accurately predict the characteristics of the Mars Pathfinder landing site at a scale of meters. The surface surrounding the Mars Pathfinder lander in Ares Vallis appears consistent with orbital interpretations, namely, that it would be a rocky plain composed of materials deposited by catastrophic floods. The surface and observed maximum clast size appears similar to predictions based on an analogous surface of the Ephrata Fan in the Channeled Scabland of Washington state. The elevation of the site measured by relatively small footprint delay-Doppler radar is within 100 m of that determined by two-way ranging and Doppler tracking of the spacecraft. The nearly equal elevations of the Mars Pathfinder and Viking Lander 1 sites allowed a prediction of the atmospheric conditions with altitude (pressure, temperature, and winds) that were well within the entry, descent, and landing design margins. High-resolution (~38 m/pixel) Viking Orbiter 1 images showed a sparsely cratered surface with small knobs with relatively low slopes, consistent with observations of these features from the lander. Measured rock abundance is within 10% of that expected from Viking orbiter thermal observations and models. The fractional area covered by large, potentially hazardous rocks observed is similar to that estimated from model rock distributions based on data from the Viking landing sites, Earth analog sites, and total rock abundance. The bulk and fine-component thermal inertias measured from orbit are similar to those calculated from the observed rock size-frequency distribution. A simple radar echo model based on the reflectivity of the soil (estimated from its bulk density), and the measured fraction of area covered by rocks was used to approximate the quasi-specular and diffuse components of the Earth-based radar echos. Color and albedo orbiter data were used to predict the relatively dust free or unweathered surface around the Pathfinder lander compared to the Viking landing sites. Comparisons with the experiences of selecting the Viking landing sites demonstrate the enormous benefit the Viking data and its analyses and models had on the successful predictions of the Pathfinder site. The Pathfinder experience demonstrates that, in certain locations, geologic processes observed in orbiter data can be used to infer surface characteristics where those processes dominate over other processes affecting the Martian surface layer. Copyright 1999 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗

A meta-analysis of global crop water productivity of three leading world crops (wheat, corn, and rice) in the irrigated areas over three decades

The overarching goal of this study was to perform a comprehensive meta-analysis of irrigated agricultural Crop Water Productivity (CWP) of the world’s three leading crops: wheat, corn, and rice based on three decades of remote sensing and non-remote sensing-based studies. Overall, CWP data from 148 crop growing study sites (60 wheat, 43 corn, and 45 rice) spread across the world were gathered from published articles spanning 31 different countries. There was overwhelming evidence of a significant increase in CWP with an increase in latitude for predominately northern hemisphere datasets. For example, corn grown in latitude 40–50° had much higher mean CWP (2.45 kg/m³) compared to mean CWP of corn grown in other latitudes such as 30–40° (1.67 kg/m³) or 20–30° (0.94 kg/m³). The same trend existed for wheat and rice as well. For soils, none of the CWP values, for any of the three crops, were statistically different. However, mean CWP in higher latitudes for the same soil was significantly higher than the mean CWP for the same soil in lower latitudes. This applied for all three crops studied. For wheat, the global CWP categories were low (≤0.75 kg/m³), medium (>0.75 to <1.10 kg/m³), and high CWP (≥1.10 kg/m³). For corn the global CWP categories were low (≤1.25 kg/m³), medium (>1.25 to ≤1.75 kg/m³), and high (>1.75 kg/m³). For rice the global CWP categories were low (≤0.70 kg/m³), medium (>0.70 to ≤1.25 kg/m³), and high (>1.25 kg/m³). USA and China are the only two countries that have consistently high CWP for wheat, corn, and rice. Australia and India have medium CWP for wheat and rice. India’s corn, however, has low CWP. Egypt, Turkey, Netherlands, Mexico, and Israel have high CWP for wheat. Romania, Argentina, and Hungary have high CWP for corn, and Philippines has high CWP for rice. All other countries have either low or medium CWP for all three crops. Based on data in this study, the highest consumers of water for crop production also have the most potential for water savings. These countries are USA, India, and China for wheat; USA, China, and Brazil for corn; India, China, and Pakistan for rice. For example, even just a 10% increase in CWP of wheat grown in India can save 6974 billion liters of water. This is equivalent to creating 6974 lakes each of 100 m³ in volume that leads to many benefits such as acting as ‘water banks’ for lean season, recreation, and numerous ecological services. This study establishes the volume of water that can be saved for each crop in each country when there is an increase in CWP by 10%, 20%, and 30%.

International Journal of Digital Earth↗

Vapor saturation and accumulation in magmas of the 1989-1990 eruption of Redoubt Volcano, Alaska

The 1989&ndash;1990 eruption of Redoubt Volcano, Alaska, provided an opportunity to compare petrologic estimates of SO 2 and Cl emissions with estimates of SO 2 emissions based on remote sensing data and estimates of Cl emissions based on plume sampling. In this study, we measure the sulfur and chlorine contents of melt inclusions and matrix glasses in the eruption products to determine petrologic estimates of SO 2 and Cl emissions. We compare the results with emission estimates based on COSPEC and TOMS data for SO 2 and data for Cl/SO 2 in plume samples. For the explosive vent clearing period (December 14&ndash;22, 1989), the petrologic estimate for SO 2 emission is 21,000 tons, or ~12% of a TOMS estimate of 175,000 tons. For the dome growth period (December 22, 1989 to mid-June 1990), the petrologic estimate for SO 2 emission is 18,000 tons, or ~3% of COSPEC-based estimates of 572,000&ndash;680,000 tons. The petrologic estimates give a total SO 2 emission of only 39,000 tons compared to an integrated TOMS/COSPEC emission estimate of ~1,000,000 tons for the whole eruption, including quiescent degassing after mid-June 1990. Petrologic estimates also appear to underestimate Cl emissions, but apparent HCl scavenging in the plume complicates Cl emission comparisons. Several potential sources of &lsquo;excess sulfur&rsquo; often invoked to explain petrologic SO 2 deficits are concluded to be unlikely for the 1989&ndash;1990 Redoubt eruption &mdash; e.g., breakdown of sulfides, breakdown of anhydrite, release of SO 2 from a hydrothermal system, degassing of commingled infusions of basalt in the magma chamber, and syn-eruptive degassing of sulfur from melt present in non-erupted magma. Leakage and/or diffusion of sulfur from melt inclusions do not provide convincing explanations for the petrologic SO 2 deficits either. The main cause of low petrologic estimates for SO 2 is that melt inclusions do not represent the total sulfur content of the Redoubt magmas, which were vapor-saturated magmas carrying most of their sulfur in an accumulated vapor phase. Almost all the sulfur of the SO 2 emissions was present prior to emission as accumulated magmatic vapor at 6&ndash;10 km depth in the magma that supplied the eruption; whole-rock normalized concentrations of gaseous excess S in these magmas remained at ~0.2 wt.% throughout the eruption, equivalent to ~0.7 vol.% at depth. Data for CO 2 emissions during the eruption indicate that CO 2 at whole-rock concentrations of ~0.6 wt.% in the erupted magma was a key factor in creating the vapor saturation and accumulation condition making a vapor phase source of excess sulfur possible at depth. When explosive volcanism involves magma with accumulated vapor, melt inclusions do not provide a sufficient basis for predicting SO 2 emissions. Thus, petrologic estimates made for SO 2 emissions during explosive eruptions of the past may be too low and may significantly underestimate impacts on climate and the chemistry of the atmosphere.

Journal of Volcanology and Geothermal Research↗

Constraints on magma processes, subsurface conditions, and total volatile flux at Bezymianny Volcano in 2007–2010 from direct and remote volcanic gas measurements

Direct and remote measurements of volcanic gas composition, SO 2 flux, and eruptive SO 2 mass from Bezymianny Volcano were acquired between July 2007 and July 2010. Chemical composition of fumarolic gases, plume SO 2 flux from ground and air-based ultraviolet remote sensing (FLYSPEC), and eruptive SO 2 mass from Ozone Monitoring Instrument (OMI) satellite observations were used along with eruption timing to elucidate magma processes and subsurface conditions, and to constrain total volatile flux. Bezymianny Volcano had five explosive magmatic eruptions between May 2007 and June 2010. The most complete volcanic gas datasets were acquired for the October 2007, December 2009, and May 2010 eruptions. Gas measurements collected prior to the October 2007 eruption have a relatively high ratio of H 2 O/CO 2 (81.2), a moderate ratio of CO 2 /S (5.47), and a low ratio of S/HCl (0.338), along with moderate SO 2 and CO 2 fluxes of 280 and 980 t/d, respectively, and high H 2 O and HCl fluxes of ~ 45,000 and ~ 440 t/d, respectively. These results suggest degassing of shallow magma (consistent with observations of lava extrusion) along with potential minor degassing of a deeper magma source. Gas measurements collected prior to the December 2009 eruption are characterized by relatively low H 2 O/CO 2 (4.13), moderate CO 2 /S (6.84), and high S/HCl (18.7) ratios, along with moderate SO 2 and CO 2 fluxes of ~ 220 and ~ 1000 t/d, respectively, and low H 2 O and HCl fluxes of ~ 1700 and ~ 7 t/d, respectively. These trends are consistent with degassing of a deeper magma source. Fumarole samples collected ~ 1.5 months following the May 2010 eruption are characterized by high H 2 O/CO 2 (63.0), low CO 2 /S (0.986), and moderate S/HCl (6.09) ratios. These data are consistent with degassing of a shallow, volatile-rich magma source, likely related to the May eruption. Passive and eruptive SO 2 measurements are used to calculate a total annual SO 2 mass of 109 kt emitted in 2007, with passive emissions comprising ~ 87–95% of the total. Total annual volatile masses for the study period are estimated to range from 1.1 × 10 6 to 18 × 10 6 t/year. Annual CO 2 masses are ~ 8 to 40 times larger than can be explained by degassing of dissolved CO 2 within eruptive magma, suggesting that the eruptive magma contained a significant quantity of exsolved volatiles sourced either from the eruptive melt or unerupted magma at depth. Variable total volatile fluxes ranging from ~ 3000 t/d in 2009 to ~ 49,000 t/d in 2007 are attributed to variations in the depth of gas exsolution and separation from the melt under open-system degassing conditions. We propose that exsolved volatiles are quickly transported to the surface from ascending magma via permeable flow through a bubble and/or fracture network within the conduit and thus retain their equilibrium composition at the time of segregation from melt. The composition of surface CO 2 and H 2 O emissions from 2007 to 2009 are compared with modeled exsolved fluid compositions for a magma body ascending from entrapment depths to estimate depth of fluid exsolution and separation from the melt. We find that at the time of sample collection magma had already begun ascent from the mid-crustal storage region and was located at maximum depths of ~ 3.7 km in August 2007, approximately 2 months prior to the next magmatic eruption, and ~ 4.6 km in July of 2009 approximately five months prior to the next magmatic eruption. These findings suggest that the exsolved gas composition at Bezymianny Volcano may be used to detect magma ascent prior to eruption.

Bezymianny Volcano↗