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USGS2013

Arsenic in New Jersey Coastal Plain streams, sediments, and shallow groundwater: effects from different geologic sources and anthropogenic inputs on biogeochemical and physical mobilization processes

Arsenic (As) concentrations in New Jersey Coastal Plain streams generally exceed the State Surface Water Quality Standard (0.017 micrograms per liter (µg/L)), but concentrations seldom exceed 1 µg/L in filtered stream-water samples, regardless of geologic contributions or anthropogenic inputs. Nevertheless, As concentrations in unfiltered stream water indicate substantial variation because of particle inputs from soils and sediments with differing As contents, and because of discharges from groundwater of widely varying chemistry. In the Inner Coastal Plain, streams draining to lower reaches of the Delaware River traverse As-rich glauconitic sediments of marine origin in which As contents typically are about 20 milligrams per kilogram (mg/kg) or greater. In some of these sedimentary units, As concentrations exceed the New Jersey drinking-water maximum contaminant level (5 µg/L) in shallow groundwater that discharges to streams. Microbes, fueled by organic carbon beneath the streambed, reduce iron (Fe) and As, releasing As and Fe into solution in the shallow groundwater from geologic materials that likely include (in addition to glauconite) other phyllosilicates, apatite, and siderite. When the groundwater discharges to the stream, the dissolved Fe and As are oxidized, the Fe precipitates as a hydroxide, and the As sorbs or co-precipitates with the Fe. Because of the oxidation/precipitation process, dissolved As concentrations measured in filtered stream waters of the Inner Coastal Plain are about 1 µg/L, but the total As concentrations (and loads) are greater, substantially amplified by As-bearing suspended sediment in stormflows. In the Outer Coastal Plain, streams draining to the Atlantic Ocean traverse quartz-rich sediments of mainly deltaic origin where the As content generally is low (<8 mg/kg). In unfiltered and filtered water samples, As concentrations typically are less than 1 µg/L in the acidic stream water and groundwater of the Outer Coastal Plain, but are greater in waters from urban areas. Despite the generally small geologic contributions to Outer Coastal Plain groundwater, where wastewater inputs were indicated, concentrations of As in unfiltered shallow groundwater discharging to small urban streams exceeded the maximum contaminant level. With a history of agriculture in the New Jersey Coastal Plain, anthropogenic inputs of As, such as residues from former pesticide applications in soils, can amplify any geogenic As in runoff. Such inputs contribute to an increased total As load to a stream at high stages of flow. As a result of yet another anthropogenic influence, microbes that reduce and mobilize As beneath the streambeds are stimulated by inputs of dissolved organic carbon (DOC). Although DOC is naturally occurring, anthropogenic contributions from wastewater inputs may deliver increased levels of DOC to subsurface soils and ultimately groundwater. Arsenic concentrations may increase with the increases in pH of groundwater and stream water in developed areas receiving wastewater inputs, as As mobilization caused by pH-controlled sorption and desorption reactions are likely to occur in waters of neutral or alkaline pH (for example, Nimick and others, 1998; Barringer and others, 2007b). Because of the difference in As content of the geologic materials in the two sub-provinces of the Coastal Plain, the amount of As that is mobile in groundwater and stream water is, potentially, substantially greater in the Inner Coastal Plain than in the Outer Coastal Plain. In turn, streams within the Inner and Outer Coastal Plain can receive substantially more As in groundwater discharge from developed areas than from environments where DOC appears to be of natural origin.

New Jersey↗

USGS2014

Simulation of groundwater flow in the "1,500-foot" sand and "2,000-foot" sand, with scenarios to mitigate saltwater migration in the "2,000-foot" sand of the Baton Rouge area, Louisiana

Groundwater withdrawals have caused saltwater to encroach into freshwater-bearing aquifers beneath Baton Rouge, Louisiana. Groundwater investigations in the 1960s identified a freshwater-saltwater interface located at the Baton Rouge Fault, across which abrupt changes in water levels occur. Aquifers south of the fault generally contain saltwater, and aquifers north of the fault contain freshwater, though limited saltwater encroachment has been detected within 7 of the 10 aquifers north of the fault. The 10 aquifers beneath the Baton Rouge area, which includes East and West Baton Rouge Parishes, Pointe Coupee Parish, and East and West Feliciana Parishes, provided about 167 million gallons per day (Mgal/d) for public supply and industrial use in 2010. Groundwater withdrawals from the “2,000-foot” sand in East Baton Rouge Parish have caused water-level drawdown as great as 356 feet (ft) and induced saltwater movement northward across the fault. Saltwater encroachment threatens industrial wells that are located about 3 miles north of the fault. Constant and variable-density groundwater models were developed with the MODFLOW and SEAWAT groundwater modeling codes to evaluate strategies to control saltwater migration, including changes in the distribution of groundwater withdrawals and installation of “scavenger” wells to intercept saltwater before it reaches existing production wells. Six hypothetical scenarios simulated the effects of different groundwater withdrawal options on groundwater levels within the “1,500-foot” sand and the “2,000-foot” sand and the transport of saltwater within the “2,000-foot” sand during 2008–47. Scenario 1 is considered a base case for comparison to the other five scenarios and simulates continuation of 2007 reported groundwater withdrawals. Scenario 2 simulates discontinuation of withdrawals from seven selected industrial wells located in the northwest corner of East Baton Rouge Parish and predicts that water levels within the “1,500-foot” sand will be about 10 to 12 ft higher with this withdrawal reduction than under scenario 1. Scenario 3 simulates the effects of a scavenger well on water levels and chloride concentrations within the “2,000-foot” sand. The scavenger well, which withdraws water from the base of the “2,000-foot” sand at a rate of 2.0 Mgal/d, is simulated at two possible locations. In comparison to the concentrations simulated in scenario 1, operation of the scavenger well at the locations specified in scenario 3 reduces the chloride concentrations at all existing chloride-observation well locations. Scenario 4 simulates a 3.6 Mgal/d reduction in total groundwater withdrawals from selected wells screened in the “2,000-foot” sand that are located in the Baton Rouge industrial district. Under scenario 4, chloride concentrations decrease in the leading portion of the plume south of the industrial district but increase in areas farther east. Scenario 5 simulates the effects of total cessation of withdrawals from the “2,000-foot” sand in the industrial district, which causes a change in the groundwater-flow direction toward municipal supply wells and increased chloride concentrations in the area where municipal supply wells are located. Scenario 6 simulates the combined effect of withdrawal reductions from the “2,000-foot” sand and operation of a scavenger well and was most effective at decreasing the size of the plume area and median and mean chloride concentrations within the “2000-foot” sand in the Baton Rouge area.

Louisiana↗

USGS2014

Hydrogeologic framework, groundwater movement, and water budget of the Kitsap Peninsula, west-central Washington

This report presents information used to characterize the groundwater-flow system on the Kitsap Peninsula, and includes descriptions of the geology and hydrogeologic framework, groundwater recharge and discharge, groundwater levels and flow directions, seasonal groundwater-level fluctuations, interactions between aquifers and the surface‑water system, and a water budget. The Kitsap Peninsula is in the Puget Sound lowland of west-central Washington, is bounded by Puget Sound on the east and by Hood Canal on the west, and covers an area of about 575 square miles. The peninsula encompasses all of Kitsap County, the part of Mason County north of Hood Canal, and part of Pierce County west of Puget Sound. The peninsula is surrounded by saltwater and the hydrologic setting is similar to that of an island. The study area is underlain by a thick sequence of unconsolidated glacial and interglacial deposits that overlie sedimentary and volcanic bedrock units that crop out in the central part of the study area. Geologic units were grouped into 12 hydrogeologic units consisting of aquifers, confining units, and an underlying bedrock unit. A surficial hydrogeologic unit map was developed and used with well information from 2,116 drillers’ logs to construct 6 hydrogeologic sections and unit extent and thickness maps. Unconsolidated aquifers typically consist of moderately to well-sorted alluvial and glacial outwash deposits of sand, gravel, and cobbles, with minor lenses of silt and clay. These units often are discontinuous or isolated bodies and are of highly variable thickness. Unconfined conditions occur in areas where aquifer units are at land surface; however, much of the study area is mantled by glacial till, and confined aquifer conditions are common. Groundwater in the unconsolidated aquifers generally flows radially off the peninsula in the direction of Puget Sound and Hood Canal. These generalized flow patterns likely are complicated by the presence of low-permeability confining units that separate discontinuous bodies of aquifer material and act as local groundwater-flow barriers. Groundwater-level fluctuations observed during the monitoring period (2011–12) in wells completed in unconsolidated hydrogeologic units indicated seasonal variations ranging from 1 to about 20 feet. The largest fluctuation of 33 feet occurred in a well that was completed in the bedrock unit. Streamgage discharge measurements made during 2012 indicate that groundwater discharge to creeks in the area ranged from about 0.41 to 33.3 cubic feet per second. During 2012, which was an above-average year of precipitation, the groundwater system received an average of about 664,610 acre-feet of recharge from precipitation and 22,122 acre-feet of recharge from return flows. Most of this annual recharge (66 percent) discharged to streams, and only about 4 percent was withdrawn from wells. The remaining groundwater recharge (30 percent) left the groundwater system as discharge to Hood Canal and Puget Sound.

Washington↗

USGS2015

Water quality of groundwater and stream base flow in the Marcellus Shale Gas Field of the Monongahela River Basin, West Virginia, 2011-12

The Marcellus Shale gas field underlies portions of New York, Pennsylvania, Ohio, Virginia, Maryland, Tennessee, and West Virginia. Development of hydraulic fracturing and horizontal drilling technology led to extensive development of gas from the Marcellus Shale beginning about 2007. The need to identify and monitor changes in water-quality conditions related to development of the Marcellus Shale gas field prompted the U.S. Geological Survey, in cooperation with the West Virginia Department of Environmental Protection, Division of Water and Waste Management, to document water quality for comparison with water quality in samples collected at a future date. The identification of change in water-quality conditions over time is more difficult if baseline water-quality conditions have not been documented. U.S. Geological Survey personnel sampled groundwater and surface water in West Virginia’s Monongahela River Basin during 2011–12. A groundwater survey, in which 39 wells and 2 springs were sampled, was conducted during June through September 2011. A base-flow survey was conducted during July through October 2012; 50 stream sites were sampled under base-flow conditions in this survey. Because additives to hydraulic fracturing fluids are variable and decrease in flowback water over a relatively short time, water-quality analyses for this study focused on documenting the water-quality characteristics typical of water from shallow aquifers; water derived from contact with the Marcellus Shale (flowback from hydraulic fracturing or formation water); and water with constituents from conventional oil and gas development, sewage effluent, and coal-mine drainage. All samples were analyzed for field properties (water temperature, pH, specific conductance, dissolved oxygen, and turbidity), major ions, trace elements, naturally occurring radioactive materials, and stable isotopes. In addition to documenting baseline water-quality conditions for an area of shale-gas development, these data were examined for patterns in water quality. Groundwater and base-flow survey data were compared to historical data from the Monongahela River Basin in West Virginia. Additionally, groundwater- and base-flow survey samples were grouped by Marcellus Shale gas production in the subbasin in which that sampling site was located. The comparisons of data collected as part of this study with historical data identified few differences. No significant difference was found in a comparison of groundwater survey data and historical data. Base-flow survey samples differed significantly from historical data for pH, chloride, and strontium, all of which had higher concentrations in the base-flow survey samples. Differences in pH are likely related to changes in mining regulation beginning in 1977. Concentrations of chloride and strontium elevated above background concentrations may be related to saline groundwater; saline water is within 300 feet of the land surface in parts of the study area. In the comparison of base-flow survey samples grouped by shale-gas-production setting, significant differences were found for fluoride and barium. Concentrations of fluoride and barium were higher in stream subbasins with active Marcellus Shale production than in subbasins not near active Marcellus Shale production. Elevated fluoride and barium are associated with deep brines. Generally, naturally occurring radioactive materials were not found in elevated concentrations in either groundwater or base-flow samples. Only 3 samples, 2 from the groundwater survey and one from the base-flow survey, exceeded the U.S. Environmental Protection Agency maximum contaminant level for radium isotopes of 5.0 picocurie per liter for either a single isotope or a combined value of radium-226 and radium-228. Stable isotope composition indicates broad similarity among surface water, shallow groundwater, and precipitation in the region. Neither shallow groundwater nor surface water showed a marked similarity with the deep brines associated with shale gas. In most of the groundwater survey samples, 38 of 41 samples, dissolved gas profiles were similar to those previously found in samples from shallow, domestic wells in the region. This study provides a baseline of water-quality conditions in the Monongahela River Basin in West Virginia during the early phases of development of the Marcellus Shale gas field. Although not all inclusive, the results of this study provide a set of reliable water-quality data against which future data sets can be compared and the effects of shale-gas development may be determined.

West Virginia↗

USGS2015

Simulation of groundwater flow and streamflow depletion in the Branch Brook, Merriland River, and parts of the Mousam River watersheds in southern Maine

Watersheds of three streams, the Mousam River, Branch Brook, and Merriland River in southeastern Maine were investigated from 2010 through 2013 under a cooperative project between the U.S. Geological Survey and the Maine Geological Survey. The Branch Brook watershed previously had been deemed “at risk” by the Maine Geological Survey because of the proportionally large water withdrawals compared to estimates of the in-stream flow requirements for habitat protection. The primary groundwater withdrawals in the study area include a water-supply well in the headwaters of the system and three water-supply wells in the coastal plain near the downstream end of the system. A steady-state groundwater flow model was used to understand the movement of water within the system, to evaluate the water budget and the effect of groundwater withdrawals on streamflows, and to understand streamflow depletion in relation to the State of Maine’s requirements to maintain in-stream flows for habitat protection. Delineation of the simulated groundwater divides compared to the surface-water divides suggests that the groundwater divides in the headwater areas do not exactly correspond to the surface-water divides. Under both pumping and non-pumping conditions, groundwater flows from the headwaters of the Branch Brook watershed into the Mousam River watershed. Pumping in the Mousam River watershed captures a small amount of groundwater from the Branch Brook basin. The cumulative effect of groundwater withdrawals on base flows in two rivers in the study area (Branch Brook and the Merriland River) was evaluated using the groundwater flow model. Streamflow depletion in the headwaters of Branch Brook was 0.12 cubic feet per second (ft 3 /s) for the steady-state simulation, or about 10 percent of the average base flow at that location. Downstream on Branch Brook, the total streamflow depletion from all the wells was 0.59 ft 3 /s, or 3 percent of the average base flow at that location. In the Merriland River downstream from the Merriland River well, the total amount of streamflow depletion was 0.6 ft 3 /s, or about 7 percent of the average base flow. The groundwater model was used to evaluate several different scenarios that could affect streamflow and groundwater discharging to the rivers and streams in the study area. The scenarios were (1) no pumping from the water-supply wells; (2) current pumping from the water-supply wells, but simulated drought conditions (25 percent reduction in recharge); (3) current recharge, but with increased pumping from the large water-supply wells; and (4) drought conditions and increased pumping combined. Simulations of increased pumping in the water-supply wells resulted in streamflow depletion in the headwaters of Branch Brook increasing to 16 percent of the headwater base flow. Simulated increases in the pumping in the coastal plain wells increased the amount of streamflow depletion to 6 percent of the flow in Branch Brook and to 8 percent of the flow in the Merriland River. The additional stress of a drought imposed on the model (25 percent less recharge) had a substantial impact on streamflows, as expected. If the simulated drought occurred simultaneously with an increase in pumping, the base flows would be reduced 48 percent in the headwaters of Branch Brook, compared to the no-pumping scenario. Downstream in Branch Brook, the total reduction in flow would be 29 percent of the simulated base flows in the no-pumping scenario, and in the Merriland River, the reduction would be 33 percent of the base flows in the no-pumping scenario. The study evaluated two different methods of calculating in-stream flow requirements for Branch Brook and the Merriland River—a set of statewide equations used to calculate monthly median flows and the MOVE.1 record-extension technique used on site-specific streamflow measurements. The August median in-stream flow requirement in the Merriland River was calculated as 7.18 ft 3 /s using the statewide equations but was 3.07 ft 3 /s using the MOVE.1 analysis. In Branch Brook, the August median in-stream flow requirements were calculated as 20.3 ft 3 /s using the statewide equations and 11.8 ft 3 /s using the MOVE.1 analysis. In each case, using site-specific data yields an estimate of in-stream flow that is much lower than an estimate the statewide equations provide.

Maine↗

USGS2015

Hydrogeology, hydrologic effects of development, and simulation of groundwater flow in the Borrego Valley, San Diego County, California

Executive Summary The Borrego Valley is a small valley (110 square miles) in the northeastern part of San Diego County, California. Although the valley is about 60 miles northeast of city of San Diego, it is separated from the Pacific Ocean coast by the mountains to the west and is mostly within the boundaries of Anza-Borrego Desert State Park. From the time the basin was first settled, groundwater has been the only source of water to the valley. Groundwater is used for agricultural, recreational, and municipal purposes. Over time, groundwater withdrawal through pumping has exceeded the amount of water that has been replenished, causing groundwater-level declines of more than 100 feet in some parts of the basin. Continued pumping has resulted in an increase in pumping lifts, reduced well efficiency, dry wells, changes in water quality, and loss of natural groundwater discharge. As a result, the U.S. Geological Survey began a cooperative study of the Borrego Valley with the Borrego Water District (BWD) in 2009. The purpose of the study was to develop a greater understanding of the hydrogeology of the Borrego Valley Groundwater Basin (BVGB) and to provide tools to help evaluate the potential hydrologic effects of future development. The objectives of the study were to (1) improve the understanding of groundwater conditions and land subsidence, (2) incorporate this improved understanding into a model that would assist in the management of the groundwater resources in the Borrego Valley, and (3) use this model to test several management scenarios. This model provides the capability for the BWD and regional stakeholders to quantify the relative benefits of various options for increasing groundwater storage. The study focuses on the period 1945–2010, with scenarios 50 years into the future. This report documents and presents (1) an analysis of the conceptual model, (2) a description of the hydrologic features, (3) a compilation and analysis of water-quality data, (4) the measurement and analysis of land subsidence by using geophysical and remote sensing techniques, (5) the development and calibration of a two-dimensional borehole-groundwater-flow model to estimate aquifer hydraulic conductivities, (6) the development and calibration of a three-dimensional (3-D) integrated hydrologic flow model, (7) a water-availability analysis with respect to current climate variability and land use, and (8) potential future management scenarios. The integrated hydrologic model, referred to here as the “Borrego Valley Hydrologic Model” (BVHM), is a tool that can provide results with the accuracy needed for making water-management decisions, although potential future refinements and enhancements could further improve the level of spatial and temporal resolution and model accuracy. Because the model incorporates time-varying inflows and outflows, this tool can be used to evaluate the effects of temporal changes in recharge and pumping and to compare the relative effects of different water-management scenarios on the aquifer system. Overall, the development of the hydrogeologic and hydrologic models, data networks, and hydrologic analysis provides a basis for assessing surface and groundwater availability and potential water-resource management guidelines.

California↗

USGS2015

Groundwater and surface-water interaction and effects of pumping in a complex glacial-sediment aquifer, phase 2, east-central Massachusetts

The U.S. Geological Survey, in cooperation with the Town of Framingham, Massachusetts, has investigated the potential of proposed groundwater withdrawals at the Birch Road well site to affect nearby surface water bodies and wetlands, including Lake Cochituate, the Sudbury River, and the Great Meadows National Wildlife Refuge in east-central Massachusetts. In 2012, the U.S. Geological Survey developed a Phase 1 numerical groundwater model of a complex glacial-sediment aquifer to synthesize hydrogeologic information and simulate potential future pumping scenarios. The model was developed with MODFLOW-NWT, an updated version of a standard USGS numerical groundwater flow modeling program that improves solution of unconfined groundwater flow problems. The groundwater model and investigations of the aquifer improved understanding of groundwater–surface-water interaction and the effects of groundwater withdrawals on surface-water bodies and wetlands in the study area. The initial work also revealed a need for additional information and model refinements to better understand this complex aquifer system. In this second phase of the study, the original groundwater flow model was revised to improve representation of groundwater and surface-water hydrology, stabilize the model, and reduce model error. The model was simplified by reducing the number of layers from 5 to 3 and adding the MODFLOW lake package (LAK) to simulate Lake Cochituate and Pod Meadow Pond and better represent interaction between the lakes and the aquifer. Model revisions improved stability and shortened run times, allowing use of automated parameter estimation software (PEST) to further refine the model hydraulic parameters and reduce simulation errors. Model simulations indicate that under average base-flow conditions, the Birch Road wells have a small effect on flow in the Sudbury River during most months, even at the maximum pumping rate of 4.9 ft 3 /s (3.17 Mgal/d). Maximum percent streamflow depletion in the Sudbury River caused by simulated pumping takes place during simulated drought conditions, when streamflow decreased by as much as 21 percent under maximum continuous pumping. Simulations also indicate that groundwater withdrawals at the Birch Road site could be managed so that adverse streamflow impacts are substantially ameliorated. Under the most ecologically conservative simulated drought conditions, simulated streamflow depletion was reduced from 21 percent to 3 percent by pumping at the maximum rate for 6 months rather than for 12 months. Simulations that return 10 percent of the Birch Road well withdrawals to Pod Meadow Pond indicate a modest reduction in the Sudbury River streamflow depletion and provide a larger percentage increase to streamflow just downstream of the pond. The groundwater model also indicates that well locations can have a large effect on the sustainable pumping rate and so should be chosen carefully. The model provides a tool for evaluating alternative pumping rates and schedules not included in this analysis.

Massachusetts↗

USGS2017

Estimation of the groundwater resources of the bedrock aquifers at the Kettle Moraine Springs State Fish Hatchery, Sheboygan County, Wisconsin

Groundwater resources information was needed to understand regional aquifer systems and water available to wells and springs for rearing important Lake Michigan fish species at the Kettle Moraine Springs State Fish Hatchery in Sheboygan County, Wisconsin. As a basis for estimating the groundwater resources available, an existing groundwater-flow model was refined, and new groundwater-flow models were developed for the Kettle Moraine Springs State Fish Hatchery area using the U.S. Geological Survey (USGS) finite-difference code MODFLOW. This report describes the origin and construction of these groundwater-flow models and their use in testing conceptual models and simulating the hydrogeologic system. The study area is in the Eastern Ridges and Lowlands geographical province of Wisconsin, and the hatchery property is situated on the southeastern edge of the Kettle Moraine, a north-south trending topographic high of glacial origin. The bedrock units underlying the study area consist of Cambrian, Ordovician, and Silurian units of carbonate and siliciclastic lithology. In the Sheboygan County area, the sedimentary bedrock sequence reaches a thickness of as much as about 1,600 feet (ft). Two aquifer systems are present at the Kettle Moraine Springs State Fish Hatchery. A shallow system is made up of Silurian bedrock, consisting chiefly of dolomite, overlain by unconsolidated Quaternary-age glacial deposits. The glacial deposits of this aquifer system are the typical source of water to local springs, including the springs that have historically supplied the hatchery. The shallow aquifer system, therefore, consists of the unconsolidated glacial aquifer and the underlying bedrock Silurian aquifer. Most residential wells in the area draw from the Silurian aquifer. A deeper confined aquifer system is made up of Cambrian- and Ordovician-age bedrock units including sandstone formations. Because of its depth, very few wells are completed in the Cambrian-Ordovician aquifer system (COAS) near the Kettle Moraine Springs State Fish Hatchery. Three groundwater-flow models were used to estimate the water resources available to the hatchery from bedrock aquifers under selected scenarios of well placement and seasonal water requirements and subject to constraints on the effects of pumping on neighboring wells, local springs, and creeks. Model input data (recharge, water withdrawal, and boundary conditions) for these models were compiled from a number of data and information sources. The first model, named the “KMS model,” (KMS stands for Kettle Moraine Springs) is an inset model derived from a published USGS regional Lake Michigan Basin model and was constructed to simulate groundwater pumping from the semiconfined Silurian aquifer. The second model, named the “Pumping Test model,” was constructed to evaluate an aquifer pumping test conducted in the COAS as part of this project. The Pumping Test model was also used to simulate the local effects of 20 years of groundwater pumping from this deep bedrock aquifer for future hatchery operations. The third model, named the “LMB modified model,” is a version of the published Lake Michigan Basin (LMB) model that was modified with aquifer parameters refined in an area around the hatchery (approximately a 5-mile radius circle, corresponding to the area stressed by the aquifer pumping test). This LMB modified model was applied to evaluate regional effects of pumping from the confined COAS. The available Silurian aquifer groundwater resource was estimated using the KMS model with three scenarios—named “AllConstraints,” “Constraints2,” and “Constraints3”—that specified local water-level and flow constraints such as drawdown at nearby household wells, water levels inside pumping well boreholes, and flow in local streams and springs. Each scenario utilized the MODFLOW Groundwater Management Process (GWM) to select three locations from six candidate locations that provided the greatest combined flow while satisfying the constraints. The three constraint scenarios provided estimates of 430 gallons per minute (gal/min), 480 gal/min, and 520 gal/min pumping from three wells—AllConstraints, Constraints2, and Constraints3, respectively. The same three wells were selected for the scenarios that estimated 480 gal/min and 520 gal/min; the scenario that estimated 430 gal/min shared two of these same wells, but the third selected well was different. The available COAS groundwater resource was estimated by two scenarios with each conducted over a period of 20 years with the Pumping Test model and the LMB modified model . The Pumping Test model was used to simulate local effects of pumping, and the LMB modified model was used to simulate regional effects of pumping. The scenarios simulate a range of total and seasonal pumping rates potentially linked to site activities. Scenario 1 simulates two wells completed in the Cambrian-Ordovician aquifer system, each pumping for 8 months at 300 gal/min, followed by pumping for 4 months at 600 gal/min. The average yearly pumping rate of Scenario 1 is 800 gal/min. Scenario 2 simulates three wells completed in the Cambrian-Ordovician aquifer system pumping for 8 months at 200 gal/min, followed by pumping for 4 months at 500 gal/min. The average yearly pumping rate of Scenario 2 is 900 gal/min. The Pumping Test model simulations confirmed that drawdown in the boreholes of the pumping wells at the selected 2-well or 3-well rates will meet the desired condition that the pumping water level remains at least 100 ft above the highest Cambrian-Ordovician unit open to the well. The LMB modified model was used to evaluate the regional drawdown of the pumping from the confined COAS under the same 2-well and 3-well scenarios. At the nearest known existing COAS well, Campbellsport production well #4, the simulated drawdown for Scenario 1 after 20 years of cyclical pumping with two pumping wells averaging a total of 800 gal/min is 16.9 ft, whereas the simulated drawdown for Scenario 2 after 20 years of pumping with three pumping wells averaging a total of 900 gal/min is 19.0 ft. The total deep aquifer thickness at the Campbellsport location is on the order of 620 ft, meaning that the simulated drawdown for either scenario is about 3 percent of the confined aquifer thickness. The models developed as part of this project are archived in the project data release. The archive includes the model input and output files as well as MODFLOW source code and executables. ( Haserodt and others, 2017 ).

Wisconsin↗

USGS2018

The Ozark Plateaus Regional Aquifer Study—Documentation of a groundwater-flow model constructed to assess water availability in the Ozark Plateaus

Recent short-term drought conditions have emphasized the need to better understand the delicate balance between abundance, sustainability, and scarcity of groundwater in the Ozark Plateaus aquifer system. In 2014, the U.S. Geological Survey began construction of a groundwater-flow model as a tool for the assessment of groundwater availability in the Ozark Plateaus aquifer system. The model was developed to benefit concurrent and future investigations involving groundwater-pumping scenarios, optimization, particle transport, and groundwater-monitoring network analysis. The groundwater model simulates 116 years (1900–2015) of hydrologic conditions and the response of the groundwater system to changes in stress including changes in recharge and groundwater pumping for water supply. Semiseasonal stress periods were simulated from the later part of 1991 to 2015 and represent higher demand and lower recharge in the spring and summer months and lower demand and higher recharge in the fall and winter months. Groundwater pumping increases throughout the simulation period with a maximum rate of about 600 million gallons per day (Mgal/d). The process of matching historical hydrologic data for the Ozark Plateaus aquifer system model was accomplished by a combination of manual changes to parameter values and automated calibration methods. Observation data used in the development and evaluation of the model included 19,045 hydraulic-head observations from 6,683 wells within the model area. Observation data also included stream leakage estimates summed to calculate a net gain or net loss value for approximately 81 named streams. The majority (mean of over 95 percent) of the recharge component is discharged through streams simulated in the model. The total simulated discharge to streams fluctuates seasonally between 7,500 and 17,500 Mgal/d with a mean outflow of 11,500 Mgal/d. Much of the remaining balance between modeled recharge inflows and stream outflows is made up by water moving into or out of storage in the aquifer system resulting in changes in modeled groundwater levels. The goal of the model was to develop a model capable of suitable accuracy at regional scales. The intent was not to reproduce individual local-scale details, which are typically not possible given the uniform cell size of 1 square mile. Although the model may not represent each local-scale detail, the model can be applied for a better understanding of the regional flow system and to evaluate responses to changes in climate and groundwater pumping.

Ozark Plateaus aquifer system↗

USGS2020

Hydrogeology and interactions of groundwater and surface water near Mill Creek and the Herring River, Wellfleet, Massachusetts, 2017–18

Groundwater levels and stream stage were monitored by the U.S. Geological Survey, in cooperation with the Friends of Herring River, at 19 sites in the Mill Creek Basin, a tributary of the Herring River in Wellfleet, Massachusetts, on outer Cape Cod, to provide baseline data prior to a proposed restoration of tidal flow to the Herring River estuary at the Cape Cod National Seashore. Tidal flow in the Herring River has been restricted by a tide-control structure since 1909. Baseline data are necessary to understand current conditions and provide information on water levels for comparison to future water levels under the proposed Herring River restoration, which includes restoration of salt marshes by enhancing tidal flow to the Herring River and construction of a tide-control structure on Mill Creek to prevent the flooding of upstream private properties, including a golf course. Analysis of data collected during monitoring-well installation at eight locations on or near the golf course and Mill Creek, along with analysis of existing information, determined that parts of the study area are underlain by salt marsh deposits up to 18 feet (ft) thick. These marsh deposits are directly underlain by estuarine sediments, and adjacent upland areas are underlain by medium to very coarse sand. The freshwater lens on the golf course is 70 ft thick or more. Groundwater levels at individual wells in the study area fluctuated by 1.3 to 2.6 ft during the study period (June 1, 2017, to June 14, 2018). Total precipitation during this period was 60.8 inches, about 10 inches greater than the long-term (2000–17) annual average (50.3 inches). Groundwater levels on Cape Cod generally were normal to above normal during the study owing to the higher than normal precipitation. Tidal amplitudes of groundwater levels caused by daily fluctuations at nearby tidal waterbodies (M2 tidal harmonic) were as large as 0.12 ft at a well 105 ft from the tidally restricted Herring River and as large as 0.06 ft at a well 575 ft from Wellfleet Harbor. Tidal fluctuations in groundwater levels were generally limited to areas about 1,500 ft from the nearest tidal waterbody. Under the initial proposed restoration, where mean tides would be maintained similar to current conditions, tidal fluctuations would be restored to parts of Mill Creek, and subsequent tidal fluctuations in groundwater levels could increase at some of the areas closest to the proposed tide-control structure, but the fluctuations would be less than about 0.06 ft in magnitude. Regression models were used to describe the variability of daily mean tidally filtered groundwater levels and daily maximum stream stage in Mill Creek. Significant independent variables for the groundwater-level model included daily tidally filtered Wellfleet Harbor stage with a lag time of zero to 2 days, 7-day precipitation, the growing degree days (50 degrees Fahrenheit), and the quartile of groundwater levels relative to a long period of record at a nearby observation well. Significant independent variables to predict the Mill Creek stage included daily mean groundwater levels in nearby wells, 7-day precipitation, growing degree days (50 degrees Fahrenheit), and a binary indicator of either a flooded or nonflooded condition on the golf course near Mill Creek. Flooding in Mill Creek occurred primarily when groundwater levels at nearby wells reached certain thresholds, when the precipitation in the preceding 7 days was at least 0.92–1.04 inches, and during the nongrowing season.

Massachusetts↗

USGS2021

Assessment of groundwater trends near Crex Meadows, Wisconsin

Crex Meadows Wildlife Area (Crex) is a 30,000-acre property in Burnett County, Wisconsin. Crex is managed by the Wisconsin Department of Natural Resources (WDNR) with the goal of providing public recreation opportunities while also protecting the quality of native ecological communities and species on the property. The WDNR’s management strategy includes controlling water levels at flowages in Crex using a system of dikes, water control structures, ditches, and a diversion pump. For the past several decades there has been concern among nearby landowners that the water manage-ment strategy at Crex may be contributing to groundwater flooding in adjacent, privately held properties. This issue has been particularly contentious during periods when regional groundwater elevations are already high. This study was conducted in response to those concerns. For the study, a network of 12 monitoring wells was installed in and to the west of Crex. Groundwater elevations were recorded in the wells before, during, and after water-level changes in the western Crex flowages to assess if groundwater elevations to the west of Crex are detectably affected by the flowage water levels. This study successfully collected groundwater elevations in 11 study wells during a 3-month period in 2019 when water elevations in the Dike 6 flowage and Erickson flowage were lowered and then raised. The data logger at a 12th location failed and no data were recorded. The groundwater elevation trends in these study wells were compared with groundwater elevation trends at a regional U.S. Geological Survey well to provide information for determining if changing the flowage elevations had a noticeable response in the study wells west of Crex Meadows. This analysis was done by (1) evaluating study well groundwater elevation trends compared to the regional well, (2) using a scatter plot of study well and regional well data during raising and lowering periods, (3) assessing horizontal hydraulic gradient data during the study period, and (4) assessing the cumulative departure from the mean groundwater elevation for each well. Overall, regional groundwater elevations had a down-ward trend before and during the flowage lowering period and then had an upward trend during the flowage raising period. This pattern was observed in the regional well and in all the study wells adjacent to and several miles from the flowages. The similarity in patterns indicates that precipitation and regional groundwater flow conditions were the dominant drivers of the system during the study period. The scatter plot and cumulative departure from the mean analysis showed that in addition to regional trends, wells 1, 6, and 7 were likely affected by the changes in the flowage water levels. Overall, at least on the timescale of this study, water management at Crex likely did not have detectable effects on wells outside the Crex property. Wells installed on the Crex property including the wells in the lakebeds of the flowages (wells 1 and 7) and possibly well 6 east of the flowages showed what seems to be minor affects due to water management at Crex.

Wisconsin↗

USGS2021

Evaluating the effects of replacing septic systems with municipal sewers on groundwater quality in a densely developed coastal neighborhood, Falmouth, Massachusetts, 2016–19

Land disposal of sewage wastewater through septic systems and cesspools is a major cause of elevated concentrations of nitrogen in the shallow coastal aquifers of southern New England. The discharge of nitrogen from these sources at the coast is affecting the environmental health of coastal saltwater bodies. In response, local, State, and Federal agencies are considering expensive actions to mitigate these effects, including installing municipal sewer systems. To increase the understanding of the effects of municipal sewering on groundwater quality discharging to coastal surface waters, a network of multilevel monitoring wells was established in a densely developed coastal neighborhood on the Maravista peninsula, Falmouth, Massachusetts, which was undergoing conversion from onsite septic disposal to municipal sewering. The geohydrology of the study area on the peninsula is generally characterized as consisting of fine to coarse, well-sorted sands containing 2.9 to 9.3 meters of fresh groundwater and a flow system characterized by a groundwater divide slightly west of the center of the peninsula. The magnitude of hydraulic gradients at the water table is gently sloping, ranging from 0.000032 to 0.00059, and affected by daily and bimonthly tidal fluctuations from adjacent coastal ponds. On the western side of the divide, upgradient from Little Pond, average linear groundwater velocities and traveltimes along shallow flow paths, estimated from observed hydraulic gradients and estimated aquifer hydraulic conductivity and effective porosity, range from 0.076 to 0.094 meters per day and 7.8 to 9.7 years, respectively. The groundwater monitoring network consists of 14 profile sites on the peninsula that each include a multilevel sampler for water-quality data collection and a shallow monitoring well for groundwater-level measurements. The study area encompasses about 230 residences that transitioned from onsite septic disposal to municipal sewering between spring 2017 and summer 2019. An additional multilevel sampler that was in a residential coastal setting but not undergoing sewering also was sampled periodically as a reference site. Elevated nitrogen, as compared to typical uncontaminated, fresh groundwater in the Cape Cod aquifer, predominately as nitrate, was measured in 15 water-quality profiles at nitrate concentrations as great as 26.2 milligrams per liter as nitrogen ( n =749; mean and median values were 5.1 and 4.1 milligrams per liter as nitrogen, respectively). At all 14 profile sites and the reference profile site on a nearby peninsula, wastewater effects were denoted by increased nitrate, boron, and specific conductance, and by decreased pH and dissolved oxygen. The highest concentrations of nitrate typically occurred in the deepest one-half of the freshwater zone and in intervals of suboxic and oxic groundwater. Thickness-weighted mean and maximum nitrate concentrations, and total nitrate mass from four sampling rounds, provided a metric to evaluate expected changes at the 14 profile sites on the peninsula. Nitrate concentrations varied moderately by site between sampling rounds through both the presewering (June 2016 and April 2017) and transitional periods (April 2018 and June 2019). Nitrate concentrations greater than the U.S. Environmental Protection Agency maximum contaminant level for nitrate in drinking water (10 milligrams per liter as nitrogen), were detected at 9 of the 14 profile sites and at the reference site. The average of the mean thickness-weighted nitrate concentrations for the four full sampling rounds was greater than 5.0 milligrams per liter as nitrogen at 8 sites (7 profile sites and the reference site) and greater than 8 milligrams per liter as nitrogen at 3 profile sites. The total nitrate mass per square meter of land area at each profile site ranged from 1,830 to 36,800 milligrams per square meter. Nitrate mass flux, across a 500-meter-long section upgradient from Little Pond and covering about 15 percent of the total pond shoreline length, ranged from 124.3 to 192.6 kilograms per year for the four full sampling rounds under three groundwater-flow conditions. The expected improvements in groundwater quality in the freshwater zone should be characterized by decreases in concentrations of dissolved total and inorganic nitrogen and common ions such as boron, chloride, and fluoride. A statistical analysis using the Regional Kendall test for sampling points grouped in specific depth ranges confirmed that water-quality changes were statistically significant in at least one depth group during the 3-year sampling period (nitrate: −0.76 milligram per liter per year; specific conductance: −12.1 microsiemens per centimeter at 25 degrees Celsius per year; dissolved oxygen: 0.82 milligram per liter per year); however, the rate at which the water-quality improvements will result in decreases in nitrate mass loads to the coastal ponds primarily depends on groundwater traveltimes and the rate of flushing of wastewater constituents from the aquifer.

Massachusetts↗

USGS2022

Status and understanding of groundwater quality in the Sacramento Metropolitan Domestic-Supply Aquifer study unit, 2017—California GAMA Priority Basin Project

Groundwater quality in the Sacramento Metropolitan Domestic-Supply Aquifer study unit (SacMetro-DSA) was studied from August to November 2017 as part of the second phase of the Priority Basin Project of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in parts of Amador, Placer, Sacramento, and Sutter Counties, and the extent of the study unit was defined by the location of three California Department of Water Resources groundwater subbasins: the North American, the South American, and the Cosumnes. The SacMetro-DSA focused on groundwater resources used for domestic drinking-water supply, which generally correspond to shallower parts of aquifer systems than those of groundwater resources used for public drinking water supply in the same area. The assessments characterized the quality of untreated groundwater, not the quality of drinking water. This study included two components: (1) a status assessment, which characterized the status of the quality of the groundwater resources used for domestic supply and (2) an understanding assessment, which evaluated the natural and human factors potentially affecting water quality in those resources. The first component of this study—the status assessment—was based on water-quality data collected from 49 sites sampled by the U.S. Geological Survey for the GAMA Priority Basin Project in 2017. The samples were analyzed for volatile organic compounds, pesticides, and naturally present inorganic constituents, such as major ions and trace elements. To provide context, concentrations of constituents measured in groundwater were compared to U.S. Environmental Protection Agency and California State Water Resources Control Board Division of Drinking Water regulatory and non-regulatory benchmarks for drinking-water quality. The status assessment used a grid-based method to estimate the proportion of the groundwater resources that had concentrations of water-quality constituents approaching or above benchmark concentrations. This method provides statistically unbiased results at the study-area scale and permits comparisons to other GAMA Priority Basin Project study areas. The second component of this study—the understanding assessment—identified the natural and human factors that potentially affect groundwater quality by evaluating land-use characteristics, groundwater age, and geochemical and hydrologic conditions of the domestic-supply aquifer and related these data to constituents identified in the status assessment for further evaluation. In the SacMetro-DSA study unit, arsenic was the only inorganic constituent detected above health-based benchmarks and was detected in 10 percent of the domestic-supply aquifer system. Inorganic constituents were detected above the non-health-based California State Water Resources Control Board—Division of Drinking Water secondary maximum contaminant levels (SMCL-CA) in 16 percent of the system. The inorganic constituents detected above the SMCL-CA were chloride, iron, manganese, and total dissolved solids (TDS). Organic constituents (volatile organic compounds and pesticides) with health-based benchmarks were not detected above health-based benchmarks; however, chloroform was detected at concentrations higher than 10 percent of the health-based benchmark (80 micrograms per liter) in 2 percent of the domestic-supply aquifer system. Of the 310 organic constituents analyzed, 16 constituents were detected; however, only bentazon and chloroform had detection frequencies greater than 10 percent. Inorganic constituents with health-based benchmarks that were evaluated in the understanding assessment included arsenic and hexavalent chromium. Arsenic and hexavalent chromium are natural constituents of aquifer sediments in the study unit and did not appear to be influenced by anthropogenic processes; rather, the presence of arsenic and hexavalent chromium appeared to be related to geochemical conditions controlled by oxidation–reduction reactions in the aquifer system. Naturally occurring inorganic constituents with SMCL-CAs evaluated in the understanding assessment were the trace elements iron and manganese, the major ion chloride, and TDS. Like arsenic and hexavalent chromium, the presence of iron and manganese was most strongly related to geochemical conditions in the aquifer system, specifically reducing conditions, which were most common near the western edge of the study unit close to the Sacramento River. Concentrations of chloride and TDS are indicators of salinity and were correlated with variables related to well location and included redox, agricultural land use, and elevation. Chloride and TDS were positively correlated to reducing conditions, and agricultural land use was negatively correlated to elevation and well depth. Observed correlations among variables were likely driven by the characteristics of the western part of the study unit, such as its higher proportion of agricultural land use and its relatively low elevation. A large portion of the western edge of the study unit is located in the center of the Sacramento Valley, defined by the location of the Sacramento River. The special-interest constituent perchlorate, also included in the understanding assessment, has natural and anthropogenic sources. Perchlorate was detected frequently and at moderate relative concentrations. In some areas of the study unit, concentrations of perchlorate were higher than what might be expected in nature; therefore, anthropogenic introduction of perchlorate or anthropogenically induced migration of native perchlorate could be occurring.

California↗

USGS2023

An integrated hydrologic model to support the Central Platte Natural Resources District Groundwater Management Plan, central Nebraska

The groundwater and surface-water supply of the Central Platte Natural Resources District supports a large agricultural economy from the High Plains aquifer and Platte River, respectively. This study provided the Central Platte Natural Resources District with an advanced numerical modeling tool to assist with the update of their Groundwater Management Plan. An integrated hydrologic model, called the Central Platte Integrated Hydrologic Model, was constructed using the MODFLOW-One-Water Hydrologic Model code with the Newton solver. This code integrates climate, landscape, surface water, and groundwater-flow processes in a fully coupled approach. Model framework included 163 rows; 327 columns; 2,640 feet cell sides; and 3 vertical layers. A predevelopment model simulated steady-state hydrologic conditions prior to April 30, 1895, and a development period model discretized into 610 stress periods simulated transient hydrologic conditions from May 1, 1895, to December 31, 2016, using 170 biannual stress periods from 1895 to 1980, and monthly stress periods from May 1, 1980, to December 31, 2016. Calibration of the Central Platte Integrated Hydrologic Model involved two phases: a manual adjustment of parameters, followed by the automated calibration completed using BeoPEST that was facilitated by the employment of the singular value decomposition-assist features of PEST that specified 50 super parameters assembled from the 435 adjustable parameters and Tikhonov regularization. The average absolute groundwater-level residuals for model layers one, two, and three were 6.1, 12.4, and 7.4 feet, respectively. Calibrated horizontal hydraulic conductivity was about 70, 32, and 35 feet per day for layers 1, 2, and 3, respectively. The largest development period inflow to groundwater was recharge from deep percolation past the root zone, averaging 1,122,257 acre-feet per year (2.7 inches per year), and the largest outflow was to irrigation wells, averaging 693,171 acre-feet per year (10.2 inches per year for the Central Platte Natural Resources District). Other substantial groundwater outflows included evapotranspiration and base flow. For the total development period, there was a net change in storage of −122,393 acre-feet per year (−0.3 inch per year). The calibrated Central Platte Integrated Hydrologic Model was used to simulate eight different potential future climate and irrigation pumping conditions from January 1, 2017, to December 31, 2049. Simulated future groundwater levels within the Central Platte Natural Resources District varied significantly between scenarios and locally, from 13.8 feet below to 7.6 feet above baseline 1982 groundwater levels. Most areas exhibited groundwater-level declines for the drought scenarios and rises for the alternate irrigation scenarios. Changes in scenario groundwater levels correlated with the relations between farm net recharge and irrigation pumping. Linear “first order second moment” techniques indicated that the uncertainty in projected groundwater altitudes was reduced by 15.33 feet through model calibration.

Nebraska↗

USGS2024

Characterization of groundwater resources near the southeastern part of Puget Sound, Washington

More than 1 million people live within the active model area (AMA) in the southeastern part of the lowlands surrounding Puget Sound, or Puget Lowland, Washington, and groundwater is the source for approximately one-half of their public, domestic, and irrigation water demands. The 887-square-mile AMA, located in King and Pierce Counties, represents the area of analysis for the conceptual hydrogeologic framework and numerical groundwater-flow models within the study area and includes the Puyallup River and Chambers-Clover Creek watersheds. To assess the potential hydrologic and anthropogenic impacts to groundwater and the connected surface-water resources, conceptual and numerical groundwater-flow models of groundwater flow were developed by the U.S. Geological Survey Washington Water Science Center in close cooperation with 18 water-resource agencies and stakeholders. This multichapter volume documents the development of the conceptual and numerical groundwater-flow models of groundwater flow. Chapters A, B, and C provide an overall introduction to the multichapter volume (Chapter A), the conceptual hydrogeologic framework (Chapter B), and the groundwater budget (Chapter C). Chapters D and E describe numerical groundwater-flow model construction and calibration (Chapter D) and the numerical groundwater-flow model results (Chapter E). Collectively, these reports present a characterization and simulation tool for groundwater resources near the southeastern part of Puget Sound, Washington.

Scientific Investigations Report↗

USGS2024

Groundwater and surface-water interactions in the Lower Duwamish Waterway, Seattle, Washington

The U.S. Geological Survey (USGS), in cooperation with the Washington State Department of Ecology (Ecology), conducted a study to describe the current understanding of the regional groundwater system of the lower Duwamish River valley and groundwater and surface-water interactions in the lower Duwamish Waterway. The lower Duwamish Waterway is the final 5-mile (mi) reach of the Duwamish River before it empties into Elliott Bay in Puget Sound near Seattle, Washington. A nearshore site (hereinafter referred to as “Nearshore Site” to distinguish the particular site from general discussions of nearshore areas) along the western shoreline of the Duwamish River, about 1.5 mi upstream from the river mouth, was selected for focused groundwater data collection by USGS. Data loggers were deployed in seven groundwater wells and one stilling well in the Duwamish River to measure specific conductance, temperature, and depth at 15-minute intervals for a period of about 2 years. At the Nearshore Site during 2020–22, water levels in the shallow wells were 3–8 feet (ft) higher than water levels in the deep wells, providing evidence for a low-permeability layer between the shallow and deep aquifers in this area. The shallow wells had a pronounced seasonal variability, with high water levels in winter and low water levels in summer. Data from the deep wells showed far less seasonal variability, with slight increases in winter and a near-constant water level from spring to autumn. The deep wells had a strong hydraulic connection to the Duwamish River, as evidenced by the synchronous water-level variability during the tidal cycle, whereas the shallow wells had minimal to no tidal response. The potentiometric maps developed for the Nearshore Site and surrounding areas indicate large differences in groundwater-flow directions for the shallow and deep aquifers at low and high tides. For the shallow aquifer, flow is toward the lower Duwamish Waterway near the Nearshore Site, regardless of the tidal condition. For the deep aquifer, a potentiometric trough forms parallel to the shoreline during high tide, indicating that groundwater flow converges from the uplands to the west and the Duwamish River to the east. The geometry of the potentiometric surfaces between the nearshore-most well and the shoreline is complex and is further confounded by intermittent shoreline armoring and other buried infrastructure, which could serve as either a barrier or a conduit to flow. Groundwater and surface-water interactions in the lower Duwamish Waterway are inherently complex as a result of three overarching factors. First, water levels in the lower reaches of the Duwamish River vary daily by 11–16 ft because of tides from Puget Sound, which create large swings in the hydraulic gradient in the nearshore groundwater system. Second, the density and chemical composition of water in the Duwamish River change daily with the tides and seasonally, which constrains how river water entering the nearshore sediments interacts with discharging groundwater. Third, the nearshore subsurface and shoreline conditions are heterogenous because of extensive shoreline armoring over the past century, which governs the flow of groundwater and infiltrating river water. These unique features of groundwater and surface-water interactions in the lower Duwamish Waterway thus govern the transport of terrestrial contaminants to the lower Duwamish Waterway. Furthermore, the heterogenous aquifer properties in the lower Duwamish Waterway contribute to spatially and temporally dynamic contaminant-transport processes.

Washington↗

USGS2025

Multidecadal change in pesticide concentrations relative to human health benchmarks in the Nation’s groundwater

Groundwater-quality trend assessments identify aquifers that are responding to changes in pesticide use and the compounds that may pose a threat to water availability. The U.S. Geological Survey has been monitoring pesticide concentrations in groundwater for 25 principal aquifers across the conterminous United States since 1993. The groundwater well locations represent a range of soils, climate, and landforms. The wells are used to monitor groundwater underlying selected agricultural and urban settings and groundwater used for domestic supply. This study examined changes in relative concentrations, defined here as the percentage of wells with pesticide concentrations exceeding a human health benchmark (HHB). HHBs used in this report are legally enforceable drinking-water standards and nonenforceable drinking water levels. Relative pesticide concentration increases may lead to decreased water availability, as restrictions may be put in place for groundwater used as a drinking-water source. This study focused on concentration changes in 22 pesticides that were included in laboratory analysis from 1993 to 2023. The analysis and interpretation of these pesticide concentrations in groundwater have been separated into approximate decadal intervals (decade 1 (1993–2001), decade 2 (2002–12), and decade 3 (2013–22). For one pesticide, 1,2-dibromo-3-chloropropane (DBCP), concentration data were also collected in decade 4 (2023–onward). Atrazine, deethylatrazine, alachlor, prometon, and simazine were 5 pesticides detected at moderate concentrations (greater than 10 percent of the HHB but less than or equal to the HHB). The percentage of wells that had groundwater pesticide concentrations in the moderate concentration category decreased from 7 percent in decade 1 to 2 percent in decade 3. The agricultural networks had the highest percentages of wells with moderate concentrations, and these percentages decreased from 13 percent in decade 1 to 4 percent in decade 3. Moderate concentrations in the urban networks decreased between decades 1 and 2 from 4 percent to 0 percent. No moderate concentrations occurred in the urban networks in decade 3. The percentage of wells with moderate concentrations in the domestic supply networks (1 percent) was the lowest of all the network types and did not change across the three decades. Moderate atrazine or deethylatrazine concentrations occurred across all three decades in aggregated ecoregions representing similar soils, climate, and landforms in the Semiarid West, Midcontinent, and Northeastern United States. Moderate concentrations of prometon, alachlor, and simazine also occurred in the Midcontinent, Arid West, Northeast, South Atlantic Gulf, and Semiarid West regions, but the moderate concentrations did not persist across all three decades. DBCP was the only pesticide that exceeded its respective HHB, and the exceedances occurred across all four decades. In this report, the DBCP analysis was limited to one well network in the Central Valley, California. Agricultural use of DBCP was suspended in 1977. Forty-five years after being banned, DBCP concentrations were greater than the maximum contaminant level of 2 micrograms per liter (μg/L), but the number of exceedances decreased from 50 percent to 15 percent of the samples between 1993 and 2023. This assessment of decadal groundwater pesticide concentrations provides a characterization of changes in water availability because of pesticide contamination in areas where groundwater is used as a drinking-water source. The results highlight the importance of continued long-term monitoring and assessment of groundwater pesticides to identify locations and specific compounds that may pose a potential risk to human health.

continental United States↗

USGS2019

Guidelines and standard procedures for high-frequency groundwater-quality monitoring stations—Design, operation, and record computation

High-frequency water-quality monitoring stations measure and transmit data, often in near real-time, from a wide range of aquatic environments to assess the quality of the Nation’s water resources. Common instrumentation for high-frequency water-quality data collection uses a multi-parameter sonde, which typically has sensors that measure and record water temperature, specific conductance, pH, and dissolved oxygen. Nitrate, turbidity, and fluorescent dissolved organic matter can also be monitored at high frequency. High-frequency groundwater-quality monitoring stations provide high-resolution time-series data to improve understanding of the timing of water-quality changes in the subsurface, especially for aquifer systems with short groundwater-residence times. High-frequency time-series data are used to monitor surface-water to groundwater interaction, quantify contaminant transport rates, and study water-quality variability in relation to variability of precipitation and groundwater pumping rates. High-frequency monitoring for contaminants or their surrogates have the added benefit of providing an early warning to protect valuable or sensitive aquifer resources. High-frequency time-series data also reveal short-term trends in groundwater quality, which may not be identifiable from monthly or annual sampling programs which facilitate the interpretation of decadal conditions. Systematic application of water-quality sonde operational procedures and a standard record-computation process are part of the required quality assurance for producing and documenting complete and accurate high-frequency groundwater-quality monitoring records. To collect quality high-frequency groundwater times-series data, water-quality sondes and sensors require careful field operation, cleaning, and calibration, as well as specific procedures for data computation, evaluation, review, and publication of final records. This report provides guidelines for the use of water-quality sondes and sensors for high-frequency groundwater-quality monitoring and updates the guidance pertaining to standardized records computation procedures for a wide range of groundwater environments. This report builds on previous continuous surface-water-quality monitoring guidance documentation for water temperature, specific conductance, pH, dissolved oxygen, and nitrate. The specific groundwater-quality monitoring guidelines presented in this report address station selection, design, installation, and operations; sonde and sensor inspections and cleaning and calibration methods; troubleshooting procedures; data evaluations, data corrections, and record computations; and record review, approval, and auditing procedures for the groundwater environment.

Techniques and Methods↗