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Hydrogeologic investigation and simulation of ground-water flow in the Upper Floridan Aquifer of north-central Florida and southwestern Georgia and delineation of contributing areas for selected city of Tallahassee, Florida, water-supply wells

A 4-year investigation of the Upper Floridan aquifer and ground-water flow system in Leon County, Florida, and surrounding counties of north-central Florida and southwestern Georgia began in 1990. The purpose of the investigation was to describe the ground-water flow system and to delineate the contributing areas to selected City of Tallahassee, Florida, water-supply wells. The investigation was prompted by the detection of low levels of tetrachloroethylene in ground-water samples collected from several of the city's water-supply wells. Hydrologic data and previous studies indicate that; ground-water flow within the Upper Floridan aquifer can be considered steady-state; the Upper Floridan aquifer is a single water-bearing unit; recharge is from precipitation; and that discharge occurs as spring flow, leakage to rivers, leakage to the Gulf of Mexico, and pumpage. Measured transmissivities of the aquifer ranged from 1,300 ft 2 /d (feet squared per day) to 1,300,000 ft2/d. Steady-state ground-water flow in the Upper Floridan aquifer was simulated using a three-dimensional ground- water flow model. Transmissivities ranging from less than 5,000 ft2/d to greater than 11,000,000 ft 2 /d were required to calibrate to observed conditions. Recharge rates used in the model ranged from 18.0 inches per year in areas where the aquifer was unconfined to less than 2 inches per year in broad areas where the aquifer was confined. Contributing areas to five Tallahassee water-supply wells were simulated by particle- tracking techniques. Particles were seeded in model cells containing pumping wells then tracked backwards in time toward recharge areas. The contributing area for each well was simulated twice, once assuming a porosity of 25 percent and once assuming a porosity of 5 percent. A porosity of 25 percent is considered a reasonable average value for the Upper Floridan aquifer; the 5 percent porosity simulated the movement of ground-water through only solution-enhanced bedding plains and fractures. The contributing areas were generally elliptical in shape, reflecting the influence of the sloping potentiometric surface. The contributing areas delineated for a 5 percent porosity were always much larger than those determined using a 25 percent porosity. The lowest average ground-water velocity computed within a contributing area, using a 25 percent porosity, was 1.0 ft/d (foot per day) and the highest velocity was 1.6 ft/d. The lowest average ground-water velocity, determined using a 5 percent porosity, was 2.4 ft/d and the highest was 7.4 ft/d. The contributing areas for each of the five wells was also determined analytically and compared to the model-derived areas. The upgradient width of the simulated contributing areas were larger than the upgradient width of the analytically determined contributing areas for four of the five wells. The model could more accurately delineate contributing areas because of the ability to simulate wells as partially penetrating and by incorporating complex, three-dimensional aquifer characteristics, which the analytical method could not.

Florida, Georgia

Enhanced hydrologic monitoring and characterization of groundwater drainage features

Groundwater drains to the land surface, generating the baseflow of streams, lakes, and wetlands. The hydrologic resilience of baseflow during prolonged dry periods and after disturbance can be assessed with evolving remote sensing analysis paired with localized monitoring of groundwater drainage features and creative model calibration strategies.

Nature Water

Physicochemical properties and bioreactivity of sub-10 µm geogenic particles: Comparison of volcanic ash and desert dust

Exposure to ambient particulate matter (PM) with an aerodynamic diameter of <10 μm (PM 10 ) is a well-established health hazard. There is increasing evidence that geogenic (Earth-derived) particles can induce adverse biological effects upon inhalation, though there is high variability in particle bioreactivity that is associated with particle source and physicochemical properties. In this study, we investigated physicochemical properties and biological reactivity of volcanic ash from the April 2021 eruption of La Soufrière volcano, St. Vincent, and two desert dust samples: a standardized test dust from Arizona and an aeolian Gobi Desert dust sampled in China. We determined particle size, morphology, mineralogy, surface texture and chemistry in sub-10 μm material to investigate associations between particle physicochemical properties and observed bioreactivity. We assessed cellular responses (cytotoxic and pro-inflammatory effects) to acute particle exposures (24 hr) in monocultures at the air-liquid interface using two types of cells of the human airways: BEAS-2B bronchial epithelial cells and A549 alveolar type II epithelial cells. In acellular assays, we also assessed particle oxidative potential and the presence of microorganisms. The results showed that volcanic ash and desert dust exhibit intrinsically different particle morphology, surface textures and chemistry, and variable mineralogical content. We found that Gobi Desert dust is more bioreactive than freshly erupted volcanic ash and Arizona test dust, which is possibly linked to the presence of microorganisms (bacteria) and/or nanoscale elongated silicate minerals (potentially clay such as illite or vermiculite) on particle surfaces.

GeoHealth

Methodology for construction of a three-layer geologic model of the conterminous United States using land surface, top of bedrock, and top of basement

This report describes the methodology used for the construction of a digital three-layer geologic model of the conterminous United States by mapping the altitude of three surfaces: land surface, the top of bedrock, and the top of basement. These surfaces are mapped through the compilation and synthesis of published stratigraphic horizons from numerous topical studies. The mapped surfaces create a three-layer geologic model with three geomaterial-based subdivisions: unconsolidated to weakly consolidated sediment; layered consolidated rock strata that constitute bedrock; and crystalline rocks that are described as “basement,” consisting of either igneous, metamorphic, or highly deformed rocks. The data compilation and synthesis are highly dependent on the definition of the informal terms “bedrock” and “basement,” which may describe different ages or types of rock in different parts of the conterminous United States. This report presents the conceptualization of the three mapped layers, describes the datasets used, and summarizes the decisions made while compiling the three-layer model from the various sources. This digital dataset was created as part of efforts by the U.S. Geological Survey to develop subsurface geologic data in geospatial form as part of a broad directive to develop two-dimensional and three-dimensional geologic information at detailed, national, and continental scales. This digital dataset partly fulfills the goal of the U.S. Geological Survey’s National Cooperative Geologic Mapping Program to construct a national-scale three-dimensional geologic model.

conterminous United States

Relationship of basin structure and bedrock lithology to faulting in the 2019 Ridgecrest earthquake region, California, from gravity and aeromagnetic data

We investigate patterns of cumulative offsets on the faults that ruptured in 2019 and along the Garlock Fault in the Ridgecrest region, California using recently published gravity and aeromagnetic data. We also examine the relationship of basin structure and bedrock structure to the 2019 M7.1 Ridgecrest earthquake ruptures (Fig. 1A), which were primarily along a dextral northwest-striking fault system, and along a sinistral northeast-striking fault, which ruptured hours earlier with a M6.4 event.

California

Guidelines for collection and field analysis of ground-water samples for selected unstable constituents

The unstable nature of many chemical and physical constituents in ground water requires special collection procedures and field analysis immediately after collection. This report describes the techniques and equipment commonly used in the collection and field analysis of samples for pH, temperature, carbonate, bicarbonate, specific conductance, Eh, and dissolved oxygen.

Open-File Report

Are the horizontal-to-vertical spectral ratios of earthquakes and microtremors the same?

We consider the similarities and differences between earthquake and microtremor horizontal‐to‐vertical spectral ratios (eHVSR and mHVSR, respectively) using a dataset of 161 sites in southern California. Quantitative comparisons are made in terms of the eHVSR and mHVSR lognormal median curves, as well as the frequencies and amplitudes associated with the fundamental‐ and higher‐mode resonances where present. The results show only 58% of the eHVSR–mHVSR pairs agree in terms of their median curve and only 25% of the eHVSR–mHVSR pairs agree in terms of shared resonances, which increases to 68% if flat HVSRs are considered equivalent. Furthermore, while the shared resonances match very well in terms of frequency (root mean square error, RMSE, <0.11 Hz), the amplitudes of those resonances do not agree (RMSE >1.6). These findings demonstrate that while eHVSR and mHVSR agree at some sites, they are not equivalent at all sites. To investigate if the agreement between eHVSR and mHVSR could be related to features of the microtremor data, earthquake recordings, and/or the site conditions, three machine learning (ML) models at varying levels of interpretability are presented. The ML models—which include multivariate logistic regression, gradient‐boosted trees, and support vector machines—show only partial success at using site‐specific data to predict whether eHVSR and mHVSR will likely agree in terms of their median curve (accuracy of 78%) and number of resonances (accuracy of 84%). Therefore, we conclude that while eHVSR and mHVSR can be quite similar in terms of resonant frequencies at some sites, they are not identical at all sites. Furthermore, preliminary evidence shows that the agreement of eHVSR and mHVSR can be predicted a priori given features of the microtremor measurements, earthquake recordings, and site conditions, although a larger dataset will be necessary for developing a robust predictive model.

California

Cambrian and Ordovician stratigraphy, conodont biostratigraphy, and microfacies analysis to support 1:24,000-scale geologic mapping of the southern Lake Champlain valley, New York and Vermont

Introduction Geologic mapping in the southern Lake Champlain valley of New York and Vermont (fig. 1) has required evaluation of stratigraphic nomenclature used since the early 1900s. The paleogeography of the Cambrian and Ordovician adjacent to the Adirondack Highlands, the high-relief mountains of Proterozoic igneous and metamorphic rocks of northern New York, has impacted the lithostratigraphic succession, facies changes, and several hiatuses that occur within the package of clastic and carbonate rocks that demonstrates overall deepening consistent from the southern to northern Appalachians. The stratigraphic nomenclature used for the geologic mapping of the Cambrian and Ordovician strata of the study area is derived from evaluation of names put forth by previous workers from areas of northern New York and western Vermont. Descriptions of type localities or type sections and other criteria set forth by the North American Stratigraphic Code (North American Commission on Stratigraphic Nomenclature [NACSN], 2021) were consulted. The North American Stratigraphic Code states that lithostratigraphic units, such as the fundamental unit, the formation, be defined by lithic character and be mappable (NACSN, 2021, Article 24). However, some early workers (Walcott, 1912; Kay, 1937; Fisher and Hanson, 1951; Oxley and Kay, 1959) have defined stratigraphic units based on fossil content, which may or may not be facies dependent, and hence may not be mappable as lithostratigraphic units. Although preservation of older names takes priority in stratigraphic nomenclature (NACSN, 2021, Article 7), some do not have adequately defined stratotypes or are located a distance away with different lithologies than that in the study area. Biostratigraphy can be a helpful tool for understanding correlations and facies changes. Herein, conodont biostratigraphy is utilized to date and correlate separate lithologic units. Further, microfacies analyses of units through inspection of petrographic thin sections provide paleogeographic information that helps in understanding the genesis of geologic units.

New York, Vermont

Using peak geometry and shifts in the x-ray spectrum of carbon from electron probe microanalysis to determine thermal maturity of organic matter

During the burial of mudstones, the associated organic matter undergoes gradual thermal maturation, a key process that can influence the reactivity of organic matter during catagenesis, the formation of hydrocarbon deposits and the chemical weathering of mudstones. Conventional methods for assessing the thermal maturity of organic matter often fail to reflect the geochemical heterogeneity between individual organic phases in mudstone samples. Here, we report an alternative, non-destructive, surficial and micro-scale (analytical spot size of ~ 300 nm with about 4 μm diffusion depth for micrometre-size organic grains) method to evaluate the thermal maturity of organic matter in mudstones using the carbon K α X-ray spectrum measured by field emission-electron probe microanalyser (FE-EPMA). Using this method, we observed correlations between parameter values derived from FE-EPMA spectra, including the peak position, the peak area and the intra-sample heterogeneity of these measurements, and independently measured vitrinite/solid bitumen reflectance for a suite of mudstones, representing different age, geological context and burial depth. With the increased values in peak area and position, we identified an increase in the carbon mass fraction of organic matter and the mean nominal oxidation state of carbon approaching zero. These trends, which are consistent with aromatisation and graphitisation, provide the rationale for using FE-EPMA to estimate the thermal maturity of organic matter. To explore some of these trends in more detail, we employed time-of-flight secondary ionisation mass spectrometry, X-ray photoelectron spectroscopy and optical reflectance measurements on a subset of samples.

Geostandards and Geoanalytical Research

A history of cryohydrogeology modeling and recent advancements through the integration of solute transport

Groundwater flow systems and permafrost are interrelated because permafrost thaw enhances permeability, while groundwater flow can advect heat and accelerate permafrost thaw (McKenzie et al. 2021). Given amplified climate change in cold regions, there is renewed interest in ‘cryohydrogeology’, the study of groundwater in cold regions. Many data-driven studies have shown that permafrost thaw is leading to activated aquifers and increased baseflow across the pan-Arctic region (e.g. Walvoord and Striegl 2007, Evans et al. 2020). Empirical evidence of a subsurface ‘replumbing’ (Walvoord and Kurylyk 2016) in permafrost regions raises questions about the fate of sequestered contaminants in the North (Langer et al. 2023). We will discuss the history of and emerging opportunities in cryohydrogeological modeling, with a focus on recent contaminant transport modeling.

Conference Paper

Investigating the influence of climate and volcanic surface aging on fluvial erosion: A case study of Réunion Island, Indian Ocean

Precipitation is one of the dominant drivers of landscape erosion and evolution; however, the effects of typical rainfall compared with less frequent, high-magnitude precipitation events on erosion remain unclear. Volcanic islands are ideal locations to study such phenomena due to their simple geometries, nontectonic construction, and strong spatiotemporal rainfall gradients. However, spatial variation in surface age, created during their construction, often complicates their degradation histories by introducing temporal changes in erosion rates as drainage networks develop. Réunion Island (western Indian Ocean) presents a clear example of this, with an east–west gradient in both surface age and mean annual precipitation, as well as infrequent cyclones that alter the background rainfall pattern. In this study, we analyze the effects of surface age, average rainfall, and rainfall variability on basin development and fluvial erosion across the island. We calculate basin-averaged values of basin morphology, age, precipitation, river discharge, eroded volumes, and erosion rates, and use these to analyze the dominant drivers of landscape evolution through a series of correlation analyses. Our results indicate a temporal dependence on the influence of precipitation, with young surfaces being dominantly eroded by high-rainfall events and older surfaces eroded by mean annual rainfall patterns. Furthermore, we show that drainage development of shield volcanoes follows similar trends to other volcano types, and suggest that surface permeability and groundwater structure are important controls on runoff-driven erosion on shield volcanoes. These results add new components to the question of how precipitation impacts erosion.

Réunion Island

Groundwater and surface-water interactions in the Waihe‘e-Kahalu‘u watershed, O‘ahu, Hawai‘i—Analysis of historical data and numerical groundwater-model simulations

The Waihe‘e-Kahaluʻu watershed and surrounding areas lie in a dike-impounded groundwater setting of the Ko‘olau Range, O‘ahu, Hawai‘i, where groundwater withdrawal from wells and tunnels have resulted in reductions in streamflow. Resource managers and surface-water users seek information that can be used to balance the needs of competing uses of groundwater and streamflow in the watershed. This study assesses the effects of four groundwater developments in the Waihe‘e-Kahalu‘u watershed—Kahaluu Tunnel, Waihee Tunnel, Kahaluu Well, and Waihee Incline Wells—on Kahalu‘u and Waihe‘e Streams. Analyses of historical streamflow, withdrawal, and rainfall data indicate that base flow (the component of streamflow that is supplied from groundwater discharge) in Kahalu‘u and Waihe‘e Streams decreased in response to withdrawals from wells and tunnels within and outside the watershed. Groundwater-model simulations indicate that shutdown of selected tunnels and wells in the Waihe‘e-Kahaluʻu watershed will result in increases of groundwater discharge, but not all of the increase will occur in streams within the watershed; increases will also occur in streams outside the basin, the ocean, and tunnels other than those that were shut down. The analysis of historical data and model simulations is consistent in showing that the effects of withdrawal changes on streams are not constrained by the topographic boundaries of watersheds. Stream base flows in the Waihe‘e-Kahalu‘u watershed are subject to a complex interaction of multiple withdrawals from wells and tunnels installed at various times within and outside the watershed. The correspondence between withdrawals and base-flow changes is consistent with the conceptual model and understanding of the connection between groundwater and streamflow in the dike-impounded groundwater setting of the Waihe‘e-Kahalu‘u watershed and the Ko‘olau Range.

Hawaii

Hydrogeologic mapping and three-dimensional geologic modeling of glacial deposits in a multicounty area of southeastern Michigan, northeastern Indiana, and northwestern Ohio

The glacial deposits underlying southeastern Michigan, northeastern Indiana, and northwestern Ohio are a substantial source of water to communities, agriculture, and industry in the region. Previous efforts to characterize aquifer materials in the area cited a need for additional information about the underlying hydrogeologic characteristics and related groundwater availability as well as improved mapping of the extent and properties of the glacial deposits. Recent U.S. Geological Survey multi-State compilations of water-well drilling records have greatly increased access to high-resolution geologic data, particularly in glacial depositional environments. This study by the U.S. Geological Survey, in cooperation with the Ohio Environmental Protection Agency, uses processed data from the State-managed collections of well records to characterize the glacial deposits in the study area using two methods. The first method creates two-dimensional maps of basic hydrogeologic information commonly required for assessments of groundwater availability, including (1) total thickness of glacial deposits, (2) total thickness of coarse-grained deposits, (3) specific-capacity-based transmissivity and hydraulic conductivity, and (4) texture-based estimated equivalent horizontal and vertical hydraulic conductivity and transmissivity. The second method builds a hydrogeologic framework of the complex glacial aquifer through construction of a volumetric geologic model by using three-dimensional kriging. Results of the volumetric model indicate that aquifer materials are primarily concentrated in the western parts of the study area near the Indiana-Ohio border. Coarse-grained sediments are also present as surficial deposits in the north of the study area where intermixing glacial advances created complex distributions of unconsolidated deposits. Two-dimensional maps of hydrogeologic properties support the volumetric model, showing thicknesses of coarse-grained deposits that reach up to 250 feet in the western sections of the study area and progressively thin to near absence in the east. Visualization of the aquifer materials with a volumetric model generally shows a highly discontinuous distribution of coarse- and fine-grained materials, with no clearly defined boundaries to delineate the extent of the aquifer. Comparisons of cross sections derived from the volumetric model with existing published maps support previous near-surface hydrogeologic interpretations while filling gaps where data are sparse, particularly in deeper parts of the aquifer. Both the two-dimensional maps and the volumetric model provide data that can directly inform assessments of groundwater availability, in addition to having future applications to studies of groundwater flow and transport.

Indiana, Michigan, Ohio

Review and synthesis of the applications of machine learning to coalbed methane recovery

Over the last 30 years, a substantial literature has evolved on the use of machine learning (ML) to assess, predict, and improve the efficiency of coalbed methane (CBM) recovery. In the United States, the production of CBM declined as shale gas production matured, but CBM continues to be an important energy resource in other parts of the world. ML applications that have the potential to improve CBM reservoir management and production forecasts, and to increase exploration and operational efficiency, are still of significant interest. The integration of geostatistical techniques into the CBM ML applications has been largely absent but represents an opportunity for improvement. The literature demonstrates the widespread interest in, and applicability of, ML algorithms applied to CBM problems, and that they continue to result in improvements in predictive performance. However, (1) much of the research is more academic than operational, (2) many results are based on simulations, or small or proprietary datasets, (3) ML performance information can be inconsistent and sometimes entirely omitted, (4) most methodologies are unique to the specific CBM situation and likely not generalizable, (5) no standard data repositories are available to directly compare the performance of competing algorithms, and (6) the spatial component is often omitted. Finally, relatively new ML protocols involving causality analysis and reinforced learning, as well as hybrid workflows combining both supervised and unsupervised learning, are anticipated to dominate the future investigations. Integration of geostatistical and geospatial analysis with ML should enhance performance.

Book chapter

Design, revisions, and considerations for continued use of a ground-water-flow model of the coastal plain aquifer system in Virginia

A digital numerical model of the ground-water-flow system in the Virginia Coastal Plain was constructed as part of the Regional Aquifer System Analysis program of the U.S. Geological Survey and subsequently revised based on reinterpretations of the hydrogeologic framework. The revised model has been incorporated by the Virginia Department of Environmental Quality as a means to evaluate the effects of existing and proposed ground-water withdrawals. The revised model, which is documented here, includes many design features of the original model. Principal modifications are (1) reassignment of some model layers to represent different aquifers, (2) replacement of applied recharge and the uppermost surface-water layer by constant-head cells to represent the unconfined aquifer, and (3) revision of the lateral extents and transmissivity and vertical leakance values assigned to model layers. Ground-water levels simulated by the revised model under steady-state conditions, using withdrawal rates representing the period 1978-80, generally are similar to the water levels simulated by the original model under transient conditions using the same withdrawal rates. Differences probably result largely from changes in transmissivity and vertical leakance values. T he revised model enables the continued evaluation of development of the large and complex aquifer system. Improved information on parts of some aquifers has been incorporated. Only large, regional-scale trends in ground-water water levels, flow directions, and flow rates are simulated, however, and not local trends and (or) short-term changes in water level and flow. Changing hydraulic stresses, knowledge of hydrogeologic conditions, and resource-management needs require periodic revision of the model to maintain its usefulness for the management of ground-water resources in the Virginia Coastal Plain.

Virginia

Low flows and flow duration of Tennessee streams through 1981

Estimates of low-flow characteristics and flow duration for the period of record at continuous-record streamflow gages are essential in hydrologic studies and water-resources management. This report provides estimates of low flow for 1, 3, 7, 14, 30, 60, and 90 consecutive days for recurrence intervals of 2, 5, 10, and 20 years for continuous-record streamflow gages. These estimates were used in correlation methods to estimate low flow at partial-record streamflow sites for 1, 3, and 7 consecutive days for a recurrence interval of 10 years; and 3 consecutive days for a recurrence interval of 20 years.

Tennessee