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478 records · Page 27Linked to original sources
USGS2004

Chemical Data for Detailed Studies of Irrigation Drainage in the Salton Sea Area, California, 1995?2001

The primary purpose of this report is to present all chemical data from the Salton Sea area collected by the U.S. Geological Survey between 1995 and 2001. The data were collected primarily for the Department of the Interior's National Irrigation Water Quality Program (NIWQP). The report also contains a brief summary and citation to investigations done for the NIWQP between 1992 and 1995. The NIWQP began studies in the Salton Sea area in 1986 to evaluate effects on the environment from potential toxins, especially selenium, in irrigation-induced drainage. This data report is a companion to several reports published from the earlier studies and to interpretive publications that make use of historical and recent data from this area. Data reported herein are from five collection studies. Water, bottom material, and suspended sediment collected in 1995-96 from the New River, the lower Colorado River, and the All-American Canal were analyzed for elements, semi-volatile (extractable) organic compounds, and organochlorine compounds. Sufficient suspended sediment for chemical analyses was obtained by tangential-flow filtration. A grab sample of surficial bottom sediment collected from near the deepest part of the Salton Sea in 1996 was analyzed for 44 elements and organic and inorganic carbon. High selenium concentration confirmed the effective transfer (sequestration) of selenium into the bottom sediment. Similar grab samples were collected 2 years later (1998) from 11 locations in the Salton Sea and analyzed for elements, as before, and also for nutrients, organochlorine compounds, and polycyclic aromatic hydrocarbons. Nutrients were measured in bottom water, and water-column profiles were obtained for pH, conductance, temperature, and dissolved oxygen. Element and nutrient concentrations were obtained in 1999 from cores at 2 of the above 11 sites, in the north subbasin of the Salton Sea. The most-recent study reported herein was done in 2001 and contains element data on suspended material isolated by continuous-flow centrifugation on samples collected in transects extending out from the Whitewater, the Alamo, and the New Rivers into the Salton Sea. Chemical data on suspended sediment and bottom material from tributory rivers and the Salton Sea itself show that many insoluble constituents, including selenium and DDE, are concentrated in the fine-grained, organic- and carbonate-rich bottom sediment from deep areas near the center of the Salton Sea. Data also show that selenium and arsenic are markedly enriched in seston (plankton, partially-degraded algal detritus, and mineral matter that compose suspended particulates in the lake) collected just below the water surface in the Salton Sea. This result indicates that bio-concentration in primary producers in the water column provides an important pathway whereby high selenium residues accumulate in fish and fish-eating birds at the Salton Sea.

Scientific Investigations Report↗
USGS2024

Distribution, abundance, breeding activities, and habitat use of the Least Bell's Vireo at Marine Corps Base Camp Pendleton, California—2023 annual report

Executive Summary The purpose of this report is to provide the Marine Corps with an annual summary of abundance, breeding activity, demography, and habitat use of endangered Least Bell’s Vireos ( Vireo bellii pusillus ) at Marine Corps Base Camp Pendleton, California (MCBCP or Base). Surveys for the Least Bell's Vireo were completed at MCBCP between April 11 and July 20, 2023. Core survey areas and a subset of non-core areas in drainages containing riparian habitat suitable for vireos were surveyed two to four times. We detected 561 territorial male vireos and 28 transient vireos in core survey areas. An additional 103 territorial male vireos and 15 transients were detected in non-core survey areas. Transient vireos were detected on 10 of the 15 drainages/sites surveyed (core and non-core areas). In core survey areas, 90 percent of vireo territories were on the four most populated drainages, with the Santa Margarita River containing 72 percent of all territories in core areas surveyed on Base. In core areas, 79 percent of male vireos were confirmed as paired; 69 percent of male vireos in non-core areas were confirmed as paired. The number of documented Least Bell’s Vireo territories in core survey areas on MCBCP decreased 2 percent from 2022. In two core survey area drainages, the number of territories increased by at least three, and in two core survey area drainages, the number of vireo territories decreased by at least four between 2022 and 2023. The number of vireo territories at the lower San Luis Rey River increased 2 percent from 2022, in contrast to the decrease at MCBCP; however, this change was negligible overall. Although the 10-percent decrease at Marine Corps Air Station, Camp Pendleton from 2022 to 2023 was superficially less trivial, this 10-percent decrease represented the loss of a single territory. The proportion of surveys during which Brown-headed Cowbirds ( Molothrus ater ) were detected decreased to 0.20 from a peak of 0.45 in 2022. Cowbirds were detected from April through July in 2023. Most core-area vireos (62 percent, including transients) used mixed willow ( Salix spp.) riparian habitat. An additional 7 percent of birds occupied willow habitat co-dominated by Western sycamores ( Platanus racemosa ) or Fremont cottonwoods ( Populus fremontii ). Riparian scrub dominated by mule fat ( Baccharis salicifolia ), sandbar willow ( S. exigua ), or blue elderberry ( Sambucus mexicana ) was used by 29 percent of vireos. Habitat dominated by coast live oak ( Quercus agrifolia ) and sycamore or non-native habitat was used by 1 percent of vireos; fewer than 1 percent of vireo territories were in upland scrub and habitat dominated by white alder ( Alnus rhombifolia ). In 2019, MCBCP began operating an artificial seep along the Santa Margarita River; then in 2021, two additional artificial seeps became operational. The artificial seeps pumped water to the surface starting in March and ending in August each year during daylight hours and were designed to increase the amount of surface water present to enhance Southwestern Willow Flycatcher ( Empidonax traillii extimus ) breeding habitat. Although this enhancement was designed to benefit flycatchers, few flycatchers have inhabited MCBCP, including the seep areas, within the past several years; therefore, vireos were selected as a surrogate species to determine effects of the habitat enhancement. This report presents the fourth year of analyses of vireo and vegetation response to the artificial seeps. In 2020, we established four study sites along the Santa Margarita River, two surrounding and extending downstream of seep pumps at the Old Treatment Ponds and along Pump Road, and two Reference sites in similar habitat but further downstream of the Seep sites. In 2023, seep pumps at one Seep site did not function, and we recategorized that study site as Intermediate. Soil moisture was higher at sites that had surface water augmentation (Seep and Intermediate sites) than at the Reference site, and soil moisture also decreased with increasing distance from the seep pumps. We sampled vegetation at these sites to determine the effects of surface water enhancement by seep pumps. Soil moisture was positively related to total foliage cover, woody cover, and native herbaceous cover below 1 meter (m), and also positively related to native herbaceous cover between 1 and 2 m. The Seep site had greater total vegetation cover in the understory (71–79 percent) than the Intermediate (52–66 percent) and Reference (61–69 percent) sites. Total herbaceous cover below 3 m was higher at the Seep site than at the Intermediate site; total herbaceous cover between 1 and 3 m was higher at the Seep site than at the Reference sites. Native herbaceous cover below 3 m was greater at the Seep site than at the Reference sites; native herbaceous cover between 2 and 3 m was also greater at the Seep site than at the Intermediate site. Non-native cover below 3 m was greater at Seep and Reference sites than at the Intermediate site. We found no difference in woody cover among site types at any height. Vireo territory density among the Seep, Intermediate, and Reference sites was similar before the seep pumps were installed. However, vireo territory density at Seep and Intermediate sites combined was significantly higher than at Reference sites after the seep pumps were installed. The U.S. Geological Survey has been color banding Least Bell’s Vireos on Marine Corps Base Camp Pendleton since 1995. By the end of 2022, over 1,000 Least Bell’s Vireos had been color banded on Base. In 2023, we continued to color band and resight color banded Least Bell’s Vireos to evaluate adult survival, site fidelity, between-year movement, and the effect of surface water enhancement on vireo return rate, site fidelity, and between-year movement. We banded 180 Least Bell's Vireos for the first time during the 2023 season, including 1 adult vireo and 179 nestlings. Adult vireos were banded with unique color combinations, whereas nestlings were banded with a single gold numbered federal band on the right leg. We resighted 57 Least Bell's Vireos on Base in 2023 that had been banded before the 2023 breeding season, 20 of which we were unable to identify. Of the 37 that we could identify, 34 were banded on Base, 2 were originally banded on the San Luis Rey River, and 1 was banded at Marine Corps Air Station, Camp Pendleton. Adult birds of known age ranged from 1 to 8 years old. Base-wide survival of vireos was affected by sex, age, and year. Males had significantly higher annual survival than females. Adults had higher annual survival than first-year vireos. Survival for adults and first-year birds was lowest from 2020 to 2021 and highest from 2007 to 2008 and from 2012 to 2013. The return rate of adult vireos to Seep, Intermediate, or Reference sites was not affected by the original banding site (Seep versus Intermediate versus Reference). Most returning adult vireos, predominantly males, showed strong between-year site fidelity. Of the adults present in 2022, 88 percent (96 percent of males; 25 percent of females) returned in 2023 to within 100 m of their previous territory. The discrepancy between male and female return rates follows the pattern observed in previous years. The average between-year movement for returning adult vireos was 0.4±1.9 kilometers (km). The average movement of first-year vireos detected in 2023 that fledged from a known nest on MCBCP in 2022 was 0.9±0.5 km. We monitored Least Bell's Vireo pairs to evaluate the effects of surface water enhancement on nest success and breeding productivity. We monitored vireo nesting activity at 13 territories in the Seep site, 12 territories at the Intermediate site, and 25 territories in the Reference sites between April 8 and July 26. All territories except one at a Seep site and one at a Reference site were occupied by pairs, and all were fully monitored, meaning that all nesting attempts were monitored at these territories. During the monitoring period, 99 nests (26 in the Seep site, 28 at the Intermediate site, and 45 in Reference sites) were monitored. Breeding productivity was similar among Seep, Intermediate, and Reference sites (2.9, 3.6, and 3.0 young fledged per pair, respectively), and a similar percentage of pairs at Seep, Intermediate, and Reference sites fledged at least 1 young (83, 83, and 96 percent, respectively). Other measures of breeding productivity were also similar among Seep, Intermediate, and Reference site pairs. According to the best model, daily nest survival in 2023 was not related to site. Fledging success appeared lower at Intermediate and Seep sites than at the Reference sites in 2023 (48, 46, and 67 percent, respectively), although the difference was not statistically significant. Predation was believed to be the primary source of nest failure at all sites. Predation accounted for 85, 77, and 71 percent of nest failures at Seep, Intermediate, and Reference sites, respectively. Failure of the remaining nests was attributed to infertile eggs, collapse of the vegetation supporting the nest, and other unknown causes. We found no relationships between vireo productivity and understory (below 3 m) vegetation cover. Vireos placed their nests in 15 plant species in 2023. We found few differences in nest placement between successful and unsuccessful vireo nests. At Reference sites, successful vireo nests were placed slightly but significantly higher in the vegetation than unsuccessful nests, and at Intermediate sites, successful nests were placed significantly closer to the edge of the nest plant than unsuccessful nests. We did not find differences in nest placement among Seep, Intermediate, and Reference sites. We found that as bio-year precipitation increased, the number of fledglings produced per vireo pair also increased. We did not find a link between bio-year precipitation and adult survival.

California↗
USGS2012

Waterbird nest monitoring program in San Francisco Bay (2005-10)

Historically, Forster’s Terns ( Sterna forsteri ), American Avocets ( Recurvirostra americana ), and Black-necked Stilts ( Himantopus mexicanus ) were uncommon residents of San Francisco Bay, California (Grinnell and others, 1918; Grinnell and Wythe, 1927; Sibley, 1952). Presently, however, avocets and stilts are the two most abundant breeding shorebirds in San Francisco Bay (Stenzel and others, 2002; Rintoul and others, 2003). More than 4,000 avocets and 1,000 stilts, roughly 20 percent of their San Francisco Bay wintering populations, breed within the estuary, making San Francisco Bay the largest breeding area for these species on the Pacific Coast (Stenzel and others, 2002; Rintoul and others, 2003). Forster’s Terns were first observed breeding in the San Francisco Bay in 1948 (110 nests); they had increased to over 4000 individuals by the 1980s (Sibley, 1952; Gill, 1977; Harvey and others, 1992; Carter and others, 1990) and were estimated at 2000–3000 for 1998–2002; (Strong and others, 2004). It is hypothesized that the relatively large size of the current waterbird breeding populations is a result of the creation of artificial salt evaporation ponds from the 1930s through the 1950s (Gill, 1977; Goals Project, 1999). Until recently, these salt ponds and associated islands used by waterbirds for nesting have been managed relatively similarly and have supported large breeding waterbird populations. Recently, the South Bay Salt Pond Restoration Project has implemented plans to convert 50–90 percent of the 15,000 acres of salt ponds in the South San Francisco Bay back to tidal marsh habitat. Therefore, there is concern that the Restoration Project, while benefiting other native species, could negatively influence local breeding populations of waterbirds that are reliant on salt pond habitats for both breeding and foraging. A primary goal of the South Bay Salt Pond Restoration Project is to maintain current breeding waterbird populations (South Bay Salt Pond Long-Term Restoration Project, 2004); thus, specific efforts are planned to ensure that the Restoration Project enhances the habitats of the remaining salt ponds for breeding waterbirds. Here, we provide a summary of nesting ecology data for Forster’s Terns, American Avocets, and Black-necked Stilts, collected from 2005 to 2010 in the areas of the South Bay Salt Pond Restoration Project, including lands managed by the Don Edwards San Francisco Bay National Wildlife Refuge and Eden Landing Ecological Reserve. These results provide baseline conditions for breeding waterbirds prior to implementation of most restoration actions and can be used to both guide future restoration actions as well as to determine the effect of the South Bay Salt Pond Restoration Project on breeding waterbirds. It is imperative to continue to collect nesting waterbird data annually to assess the response of birds to the South Bay Salt Pond Restoration Project.

California↗
USGS2023

Least Bell's Vireos and Southwestern Willow Flycatchers at the San Luis Rey Flood Risk Management Project Area in San Diego County, California—Breeding activities and habitat use—2022 annual report

Executive Summary We completed four protocol surveys for Least Bell’s Vireos ( Vireo bellii pusillus ; vireo) during the breeding season, supplemented by weekly territory monitoring visits. We identified a total of 133 territorial male vireos; 114 were confirmed as paired, and 3 were confirmed as single males. For the remaining 16 territories, we were unable to confirm breeding status. Two transient vireos were detected in 2022. The vireo population in the Project Area increased by 9 percent from 2021 to 2022. The vireo population at Marine Corps Base Camp Pendleton also increased (4 percent), whereas the population at Marine Corps Air Station remained relatively stable (decreased from 10 pairs to 9) and the Otay River population decreased by 10 percent (2 territories). We used an index of treatment (Treatment Index) to evaluate the effect of on-going vegetation clearing on the Project Area vireo population. The Treatment Index measures the cumulative effect of vegetation treatment within a territory (since 2005) by using the percentage area treated weighted by the number of years since treatment. We determined that the Treatment Index for unoccupied habitat was more than four times that of occupied habitat, indicating that vireos selected habitat that was less treated in which to settle. We monitored vireo nests at three general site types: (1) within the flood channel where exotic and native vegetation removal has occurred regularly (Channel), (2) three sites near the flood channel where limited exotic and native vegetation removal has occurred (Off-channel), and (3) three sites that have been actively restored by planting native vegetation (Restoration). Nesting activity was monitored in 80 territories, 3 of which were occupied by single males and 1 by a male whose breeding status could not be confirmed. Overall, 38 percent of completed nests were successful and nest success did not differ among the three sites. In 2022, there were no differences with regard to clutch size, hatching, or fledging success among Channel, Off-channel and Restoration sites. Overall breeding success and productivity were slightly higher in 2022 than in 2021, with 72 percent of pairs fledgling at least one young and pairs fledging an average of 2.2±1.7 young. To investigate if the cumulative years of treatment had an effect on vireo reproductive effort, we looked at the effects of the Treatment Index on reproductive parameters. Results from generalized linear models indicated that treatment did not have an effect on vireo nesting effort or the number of vireo fledglings per pair produced in 2022. Similarly, we did not detect an effect of Treatment Index on daily survival rate (DSR) of nests. Analysis of vegetation data collected at vireo nests from 2006 to 2022 did not reveal an effect of vegetation cover at the nest on DSR. We did find, however, that Channel nests were placed higher in the host plant than Off-channel nests. In the Channel and Off-channel sites, successful nests were placed closer to the edge of the host plants than unsuccessful nests. Additionally, successful Off-channel nests were placed lower in the vegetation, in shorter host plants, and closer to the edge of the vegetation clump than unsuccessful nests. Red/arroyo willow ( Salix laevigata or Salix lasiolepis ) were the species most commonly selected for nesting by vireos in all three site types. Black willow ( Salix gooddingii ) and mule fat ( Baccharis salicifolia ) also were commonly used. Vireos used a wider variety of species for nesting in Channel and Off-channel sites (eight and six species, respectively) compared to Restoration sites (two species), although there was limited nesting in Restoration sites in 2022. There were 43 vireos banded before the 2022 breeding season that were resighted and identified at the Project Area in 2022, all of which were originally banded in the Project Area. Adult birds of known age ranged from 1 to 7 years old. A total of 146 vireos were newly banded in 2022. There were 8 adult vireos banded with a unique color combination, and 138 nestlings were banded with a single dark blue numbered federal band on the left leg. Between 2006 and 2022, survivorship of males (66±11 percent) was consistently higher than that of females (59±12 percent). First-year birds from 2006 to 2022 had an average annual survivorship of 15±6 percent. First-year dispersal in 2022 averaged 6.7±7.4 kilometers (km), with the longest dispersal (15.3 km) by a male that was recaptured at Fallbrook Creek, Fallbrook Naval Weapons Station (FNWS). From 2007 to 2011, most returning first-year vireos returned to the Project Area, whereas from 2014 to 2016, the majority of returning birds dispersed to areas outside of the Project Area. From 2018 to 2021, the trend shifted, and more first-year vireos returned to the Project area. In 2022, only one first-year vireo returned to the project area and two dispersed to sites outside the Project Area (upstream to the middle San Luis Rey River and to Fallbrook Creek, FNWS). However, the total number of identified first-year vireos was low and the trend in 2022 will likely shift as additional returning first-year vireos are identified in subsequent years. Most of the returning adult male vireos showed strong between-year site fidelity to their previous territories. Seventy-three percent of males (27/37) occupied a territory in 2022 that they had defended in 2021 (within 100 meters [m]). There were no females (0/4) detected in 2022 that returned to a territory they occupied in 2021; however, 50 percent of females (2/4) detected in 2022 returned to areas adjacent to their previous territories (within 300 m). The average between-year movement for returning adult vireos was 0.3±0.7 km. The amount of treatment at adults’ 2021 territories did not affect the distance adults moved to their 2022 territories. We completed four protocol surveys for the endangered Southwestern Willow Flycatcher ( Empidonax traillii extimus ; flycatcher) at the Project Area between May 16 and July 25, 2022. Four transient Willow Flycatchers were detected in the Project Area in 2022. Two transients were detected in Reach 1, one in Reach 3a, and one in Pilgrim Pond. There were not any resident flycatchers documented in the Project Area in 2022. A total of 46 vegetation transects (528 points) were sampled at the Project Area in 2022. Seventy-one percent (378/528) of points were located in the Channel, and 22 percent (115/528) were in Upper Pond. The remaining 7 percent (35/528) of points were at the Whelan Restoration site. Foliage cover below 2 m was higher at the Channel points compared to Upper Pond and Whelan Restoration, which can be attributed to the dense herbaceous vegetation that grows after mowing. Above 2 m, foliage cover was similar at the Channel and Whelan Restoration sites and was higher than at Upper Pond. Average canopy height was higher in the Channel (5.6±3.4 m) compared to Upper Pond (4.7±2.9 m) and Whelan Restoration (4.6±1.9 m). From 2006 to 2022, total foliage cover declined above 2 m in the Channel, in contrast to Upper Pond and Whelan Restoration, where little directional change in vegetation cover has occurred and where vegetation cover has largely recovered to 2006 levels. Within the Channel, the steepest declines occurred between 2009 and 2013 and between 2014 and 2016. Since 2016, we observed an increase in foliage cover, largely herbaceous, between 0 and 2 m within the Channel. The percent cover remained below levels detected before 2009 for other height classes. We sampled vegetation at 44 vireo nests and 44 random plots (“territory” plots) within territories in the Channel and Upper Pond after the 2022 breeding season. Vireos in the Channel established territories in areas with significantly more cover from 3 to 6 m but less cover below 2 m relative to the available habitat. Within territories, Channel vireos selected nest sites with significantly more foliage cover from 2 to 3 m. Vireos at Upper Pond established territories in areas with significantly more foliage cover from 5 to 6 m and below 1 m relative to available habitat. However, within territories, Upper Pond vireos selected nest sites with significantly less foliage cover from 5 to 6 m and below 1 m. Data either are not available or have limited availability owing to restrictions of the funding entity (U.S. Army Corps of Engineers). Please contact Christopher Chabot, Planning Division, Los Angeles District, U.S. Army Corps of Engineers, for more information.

Califoria↗
USGS2015

Long‐term time‐dependent probabilities for the third Uniform California Earthquake Rupture Forecast (UCERF3)

The 2014 Working Group on California Earthquake Probabilities (WGCEP 2014) presents time-dependent earthquake probabilities for the third Uniform California Earthquake Rupture Forecast (UCERF3). Building on the UCERF3 time-independent model, published previously, renewal models are utilized to represent elastic-rebound-implied probabilities. A new methodology has been developed that solves applicability issues in the previous approach for un-segmented models. The new methodology also supports magnitude-dependent aperiodicity and accounts for the historic open interval on faults that lack a date-of-last-event constraint. Epistemic uncertainties are represented with a logic tree, producing 5,760 different forecasts. Results for a variety of evaluation metrics are presented, including logic-tree sensitivity analyses and comparisons to the previous model (UCERF2). For 30-year M≥6.7 probabilities, the most significant changes from UCERF2 are a threefold increase on the Calaveras fault and a threefold decrease on the San Jacinto fault. Such changes are due mostly to differences in the time-independent models (e.g., fault slip rates), with relaxation of segmentation and inclusion of multi-fault ruptures being particularly influential. In fact, some UCERF2 faults were simply too long to produce M 6.7 sized events given the segmentation assumptions in that study. Probability model differences are also influential, with the implied gains (relative to a Poisson model) being generally higher in UCERF3. Accounting for the historic open interval is one reason. Another is an effective 27% increase in the total elastic-rebound-model weight. The exact factors influencing differences between UCERF2 and UCERF3, as well as the relative importance of logic-tree branches, vary throughout the region, and depend on the evaluation metric of interest. For example, M≥6.7 probabilities may not be a good proxy for other hazard or loss measures. This sensitivity, coupled with the approximate nature of the model and known limitations, means the applicability of UCERF3 should be evaluated on a case-by-case basis.

Bulletin of the Seismological Society of America↗
USGS2001

Geochemical and mineralogical controls on trace element release from the Penn Mine base-metal slag dump, California

Base-metal slag deposits at the Penn Mine in Calaveras County, California, are a source of environmental contamination through leaching of potentially toxic elements. Historical Cu smelting at Penn Mine (1865-1919) generated approximately 200,000 m3 of slag. The slag deposits, which are flooded annually by a reservoir used for drinking water and irrigation, also may be in contact with acidic ground waters (pH < 4) from the adjacent mine area. Slags vary from grey to black, are glassy to crystalline, and range in size from coarse sand to large (0.6 ?? 0.7 ?? 1.5 m), tub-shaped casts. Metals are hosted by a variety of minerals and two glass phases. On the basis of mineralogy, slags are characterized by 4 main types: fayalite-rich, glassy, willemite-rich, and sulfide-rich. The ranges in metal and metalloid concentrations of 17 slag samples are: As, 0.0004-0.92; Ba, 0.13-2.9; Cd, 0.0014-1.4; Cu, 0.18-6.4; Pb, 0.02-11; and Zn, 3.2-28 wt.%. Leachates from Toxicity Characteristic Leaching Procedure tests (acetic acid buffered at pH 4.93) on two wiltemite-rich slags contained Cd and Pb concentrations (up to 2.5 and 30 mg/l, respectively) in excess of US Environmental Protection Agency (USEPA) regulatory limits. Analyses of filtered (0.45 ??m) water, collected within the flooded slag dump during reservoir drawdown, reveal concentrations of Cd (1.7 ??g/l), Cu (35 ??g/l), and Zn (250 ??g/l) that exceed USEPA chronic toxicity guidelines for the protection of aquatic life. Data from field and laboratory studies were used to develop geochemical models with the program EQ3/6 that simulate irreversible mass-transfer between slag deposits and reservoir waters. These models include kinetic rate laws for abiotic sulfide oxidation and surface-controlled dissolution of silicates, oxides, and glass. Calculations demonstrate that the main processes controlling dissolved metal concentrations are (1) dissolution of fayalite, willemite, and glass; (2) sulfide oxidation; and (3) secondary phase precipitation. Close agreement between model results and measured concentrations of Al, Ba, Cu, Fe, SiO2, and SO4 in the slag dump pore waters suggests that the dissolved concentrations of these elements are controlled by solubility equilibrium with secondary phases. Differences between predicted and measured Cd and Pb concentrations imply that field weathering rates of glass and sulfides are approximately two orders of magnitude lower than laboratory rates. Overprediction of Pb release may also reflect other attenuation processes in the natural system, such as sorption or coprecipitation. ?? 2001 Elsevier Science Ltd. All rights reserved.

Applied Geochemistry↗
USGS2017

Changes in the abundance and distribution of waterfowl wintering in the Central Valley of California, 1973–2000

The Central Valley of California is one of the most important areas for wintering waterfowl in the world and the focus of extensive conservation efforts to mitigate for historical losses and counter continuing stressors to habitats. To guide conservation, we analyzed trends in the abundance and distribution (spatiotemporal abundance patterns) of waterfowl and their habitats in the Central Valley and its major subregions (Sacramento Valley, Suisun Marsh, Delta, San Joaquin Valley), from 1973 through 2000. We used existing databases, satellite imagery, and aerial photography to measure habitat area, and aerial surveys and radio telemetry to track the abundance and distribution of wintering waterfowl. Wetlands increased throughout the Central Valley, but agricultural fields flooded after harvest increased greatly to the north in the Sacramento Valley and decreased to the south in the San Joaquin Valley, resulting in an overall increase in the relative availability of winter habitat in the former region. Reflecting the continental decline of the most abundant wintering species (Northern Pintail, Anas acuta ), the overall abundance of wintering waterfowl in the Central Valley declined during our study. By contrast, numbers of the American Wigeon ( A. americana ), Mallard ( A. platyrhynchos ), and Northern Shoveler ( A. clypeata ) were stable, and numbers of the Green-winged Teal ( A. crecca ), Gadwall ( A. strepera ), diving ducks, and geese increased from 1973–1982 to 1998–2000. The areas of greatest abundance of wintering waterfowl within the Central Valley shifted northward as many species responded to changes in the distribution of habitats. Wintering waterfowl migrated earlier in fall and winter from the San Joaquin Valley, Suisun Marsh, and Delta to the Sacramento Valley, and fewer waterfowl emigrated from the Sacramento Valley to other parts of the Central Valley. Because changes in waterfowl distribution were primarily a response to the increase of a beneficial agricultural practice (i.e., the flooding of rice after harvest) in the Sacramento Valley, changing agro-economics, reduction of water supplies, or other factors that reduce this practice could change the abundance and distribution of wintering waterfowl in the Central Valley rapidly. Thus to maintain abundant suitable habitat and restore the historical distribution of wintering waterfowl, our results suggest a continuing need for the conservation of wetlands and other waterfowl habitats with secure water supplies throughout the Central Valley. Despite our findings, achieving goals for winter waterfowl populations in the Central Valley likely will depend on a combination of factors including some acting in breeding ranges farther north or elsewhere outside of the valley.

California↗
USGS2021

Least Bell's Vireos and Southwestern Willow Flycatchers at the San Luis Rey flood risk management project area in San Diego County, California—Breeding activities and habitat use—2020 annual report

Executive Summary Surveys and monitoring for the endangered Least Bell’s Vireo ( Vireo bellii pusillus ; vireo) were done at the San Luis Rey Flood Risk Management Project Area (Project Area) in the city of Oceanside, San Diego County, California, between March 31 and July 20, 2020. We completed four protocol surveys during the breeding season, supplemented by weekly territory monitoring visits. We identified a total of 161 territorial male vireos; 145 were confirmed as paired and 4 were confirmed as single males. For the remaining 12 territories, we were unable to confirm pair status. Three transient vireos were detected in 2020. The vireo population in the Project Area increased by 26 percent from 2019 to 2020. Vireo populations increased across San Diego County, with a 39-percent increase documented at Marine Corps Base Camp Pendleton (MCBCP); a 58-percent increase at Marine Corps Air Station; a 78-percent increase on the Otay River; and a 7-percent increase in the population on the middle San Luis Rey River. We used an index of treatment (Treatment Index) to evaluate the impact of on-going vegetation clearing on the Project Area vireo population. The Treatment Index measures the cumulative effect of vegetation treatment within a territory (since 2005) by using the percent area treated weighted by the number of years since treatment. We found that the Treatment Index for unoccupied habitat was more than five times that of occupied habitat, indicating that vireos selected less disturbed habitat in which to settle. We monitored vireo nests at three general site types: (1) within the flood channel where exotic and native vegetation removal has occurred regularly (Channel), (2) three sites next to the flood channel where limited exotic and native vegetation removal has occurred (Off-channel), and (3) three sites that have been actively restored by planting native vegetation (Restoration). Nesting activity was monitored in 100 territories, 4 of which were occupied by single males. Hatching success was higher in the Channel relative to the Off-channel. We found no other differences between Channel, Off-channel, and Restoration nests in terms of clutch size or fledging success. There also was no difference in measures of productivity per pair between Channel, Off-channel, Restoration, and Mixed territories (territories that were classified as one site type but nesting occurred in another site type, or where multiple site types were used for nesting). Overall, breeding success and productivity were lower in 2020 than in 2019, with 69 percent of pairs fledgling at least one young and pairs fledging an average of 2.1±1.7 young. To investigate whether the cumulative years of treatment had an impact on vireo reproductive effort, we looked at the effects of the Treatment Index on reproductive parameters. Results from generalized linear models indicated that treatment did not have an effect on vireo nesting effort or the number of vireo fledglings per pair produced in 2020. Similarly, our analysis of nest survival for 2020 revealed no effect of Treatment Index on daily survival rate. Analysis of vegetation data collected at vireo nests from 2006 to 2020 revealed that vegetation at 1–2 meters (m) from the ground was the most important predictor of daily survival rate. There were differences in nest-placement characteristics among site types and successful/unsuccessful nests. Channel nests were placed higher in the vegetation than Off-channel or Restoration nests. Host plant height, distance to edge of host plant, and distance to edge of vegetation clump were greater at Channel sites compared with Off-channel sites, but were not different from Restoration sites. Within sites, we found only one difference between successful and unsuccessful nests. At Off-channel sites, successful nests were placed higher in the vegetation than unsuccessful nests. Red/arroyo willow ( Salix laevigata or Salix lasiolepis ) and mule fat ( Baccharis salicifolia ) were the species most commonly selected for nesting by vireos in all 3 site types. Vireos used a wider variety of species for nesting in Channel and Off-channel sites (7 and 10 species, respectively) compared to Restoration sites (3 species). Ninety-three vireos banded before the 2020 breeding season were resighted and identified at the Project Area in 2020, all of which were originally banded at the Project Area. Adult birds of known age ranged from 1 to 9 years old. A total of 171 vireos were newly banded in 2020. Twenty-eight adult vireos were banded with a unique color combination, and 143 nestlings were banded with a single dark blue numbered federal band on the left leg. Between 2006 and 2020, survivorship of males (67±10 percent) was consistently higher than females (59±11 percent). First-year birds from 2006 to 2020 had an average over-winter survivorship of 17±5 percent. First-year dispersal in 2020 averaged 2.9±2.9 kilometers (km), with the longest dispersal (13.5 km) by a female that was recaptured at Las Flores Creek, MCBCP. From 2007 to 2012, most returning first-year vireos returned to the Project Area, whereas from 2013 to 2017, the majority of returning birds dispersed to areas outside of the Project Area. In 2018, the trend shifted, and most first-year vireos returned to the Project area. This trend continued in 2020 with most first-year vireos returning to the Project Area; 77 percent of all re-encountered first-year birds returned to the Project Area and 23 percent dispersed to areas outside of the Project Area (upstream to the middle San Luis Rey River and to drainages on MCBCP). Most of the returning adult male vireos showed strong between-year site fidelity to their previous territories. Eighty percent of males (45/56) occupied a territory in 2020 that they had defended in 2019 (within 100 m). Thirty-three percent of females (2/6) detected in 2020 returned to a territory that they occupied in 2019. The average between-year movement for returning adult vireos was 0.1±0.5 km. We completed four protocol surveys for the endangered Southwestern Willow Fycatcher ( Empidonax traillii extimus ; flycatcher) at the Project Area between May 20 and July 20, 2020. No Willow Flycatchers were detected in the Project Area in 2020. A total of 46 vegetation transects (526 points) were sampled at the San Luis Rey Flood Risk Management Project Area in 2020. Seventy-one percent (376/526) of points were in the Channel and 22 percent (115/526) were at Upper Pond. The remaining 7 percent (35/526) were at the Whelan Restoration site. Foliage cover below 1 m was higher at the Channel points compared to Upper Pond and Whelan Restoration. Higher foliage cover in the Channel was attributed to the higher herbaceous component. However, foliage cover from 1 to 3 m was higher at the Whelan Restoration site compared to both Upper Pond and the Channel. Average canopy height was similar at all three site types and was 4.4 m or less. From 2006 to 2020, total foliage cover declined above 1 m in the Channel, from 4 to 5 m at Upper Pond, and above 8 m at Whelan Restoration. Within the Channel, the steepest declines occurred between 2009 and 2013 and between 2014 and 2016. Since 2016, we observed an increase in percent foliage between 0 and 2 m within the Channel, but for other height classes, percent cover remained below levels detected before 2009. Changes in cover at Upper Pond and Whelan Restoration appeared to be driven by the loss of tall tree cover. The vegetation mowing and treatment activities, in combination with lack of precipitation (especially between 2012 and 2016), may have contributed to the decline in foliage cover observed from 2006 to 2020. We sampled vegetation at 49 vireo nests and 49 random plots (“territory” plots) within territories in the Channel and Upper Pond following the 2020 breeding season. Vireos in the Channel selected territories with significantly more foliage cover above 2 m but less cover below 1 m relative to the available habitat. In contrast, Channel vireos selected nest sites within their territories with lower foliage cover above 3 m and were non-selective with regard to cover below 2 m. Vireos at Upper Pond generally were less selective with regard to territory and nest sites but tended to select territories with more foliage cover from 1 to 2 m and above 8 m, and they selected nest sites within their territories with greater foliage cover from 0 to 1 m.

California↗
USGS2010

Legacy of the California Gold Rush: Environmental geochemistry of arsenic in the southern Mother Lode Gold District

Gold mining activity in the Sierra Nevada foothills, both recently and during the California Gold Rush, has exposed arsenic-rich pyritic rocks to weathering and erosion. This study describes arsenic concentration and speciation in three hydrogeologic settings in the southern Mother Lode Gold District: mineralized outcrops and mine waste rock (overburden); mill tailings submerged in a water reservoir; and lake waters in this monomictic reservoir and in a monomictic lake developing within a recent open-pit mine. These environments are characterized by distinct modes of rock-water interaction that influence the local transport and fate of arsenic. Arsenic in outcrops and waste rock occurs in arsenian pyrite containing an average of 2 wt% arsenic. Arsenic is concentrated up to 1300 ppm in fine-grained, friable, iron-rich weathering products of the arsenian pyrite (goethite, jarosite, copiapite), which develop as efflorescences and crusts on weathering outcrops. Arsenic is sorbed as a bidentate complex on goethite, and substitutes for sulfate in jarosite. Submerged mill tailings obtained by gravity core at Don Pedro Reservoir contain arsenic up to 300 ppm in coarse sand layers. Overlying surface muds have less arsenic in the solid fraction but higher concentrations in porewaters (up to 500 μg/L) than the sands. Fine quartz tailings also contain up to 3.5 ppm mercury related to the ore processing. The pH values in sediment porewaters range from 3.7 in buried gypsum-bearing sands and tailings to 7 in the overlying lake sediments. Reservoir waters immediately above the cores contain up to 3.5 μg/L arsenic; lake waters away from the submerged tailings typically contain less than 1 μg/L arsenic. Dewatering during excavation of the Harvard open-pit mine produced a hydrologic cone of depression that has been recovering toward the pre-mining groundwater configuration since mining ended in 1994. Aqueous arsenic concentrations in the 80 m deep pit lake are up to 1000 μg/L. Redistribution of the arsenic occurs during summer stratification, with highest concentrations at middle depths. The total mass of arsenic in the pit lake increases coinciding with early winter rains that erode, partially dissolve, and transport arsenic-bearing salts into the pit lake. Arsenic concentration, speciation, and distribution in the Sierra Nevada foothills depend on many factors, including the lithologic sources of arsenic, climatic influences on weathering of host minerals, and geochemical characteristics of waters with which source and secondary minerals react. Oxidation of arsenian pyrite to goethite, jarosite, and copiapite causes temporary attenuation of arsenic during summer, when these secondary minerals accumulate; subsequent rapid dissemination of arsenic into the aqueous environment is caused by annual winter storms. As the population of the Mother Lode area grows, it is increasingly important to consider these effects during planning and development of land and groundwater resources.

California↗
USGS1996

Detailed study of water quality, bottom sediment, and biota associated with irrigation drainage in the Klamath Basin, California and Oregon, 1990-92

The effect of irrigation drainage on the water quality and wildlife of the Klamath Basin in California and Oregon was evaluated during 1990-92 as part of the National Irrigation Water Quality Program of the U.S. Department of the Interior. The study focused on land serviced by the Bureau of Reclamation Klamath Project, which supplies irrigation water to agricultural land in the Klamath Basin and the Lost River Basin. The Tule Lake and Lower Klamath National Wildlife Refuges, managed by the U.S. Fish and Wildlife Service, are in the study area. These refuges provide critical resting and breeding habitat for waterfowl on the Pacific flyway and are dependent on irrigation drainwater from upstream agriculture for most of their water supply. Water-quality characteristics throughout the study area were typical of highly eutrophic systems during the summer months of 1991 and 1992. Dissolved-oxygen concentrations and pH tended to fluctuate each day in response to diurnal patterns of photosynthesis, and frequently exceeded criteria for protection of aquatic organisms. Nitrogen and phosphorus concentrations were generally at or above threshold levels characteristic of eutrophic lakes and streams. At most sites the bulk of dissolved nitrogen was organically bound. Elevated ammonia concentrations were common in the study area, especially downstream of drain inputs. High pH of water increased the toxicity of ammonia, and concentrations exceeded criteria at sites upstream and downstream of irrigated land. Concentrations of ammonia in samples from small drains on the Tule Lake refuge leaseland were higher than those measured in the larger, integrating drains at primary monitoring sites. The mean ammonia concentration in leaseland drains [1.21 milligrams per liter (mg/L)] was significantly higher than the mean concentration in canals delivering water to the leaseland fields (0.065 mg/L) and higher than concentrations reported to be lethal to Daphnia magna (median lethal concentration of 0.66 mg/L). Dissolved-oxygen concentrations also were lower, and Daphnia survivability measured during in situ bioassays was correspondingly lower in the leaseland drains than in water delivery canals. In static laboratory bioassays, water samples collected at the primary monitoring sites caused toxicity in up to 78 percent of Lemna minor tests, in up to 49 percent of Xenopus laevis tests, in 17 percent and 8 percent of Hyalella azteca and Pimephales promelas tests, respectively, and 0 percent in Daphnia magna tests. In situ exposure at the sites caused mortality in more than 83 percent of Pimephales tests and in more than 41 percent of Daphnia and Hyalella tests. Much of the observed toxicity appears to have been caused by low dissolved oxygen, high pH, and ammonia. Although water in the study area was toxic to a variety of organisms, no statistically significant differences in the degree of toxicity between sites were observed above or below irrigated agricultural land in any of the bioassays. Pesticides were frequently detected in water samples collected at the monitoring sites during the 1991 and 1992 irrigation seasons. Among the most frequently detected compounds were the herbicides simazine, metribuzin, EPTC, and metolachlor and the insecticide terbufos. All the insecticides detected were at concentrations substantially below acute toxicity values reported for aquatic organisms. The herbicide acrolein has been used extensively in the basin to manage aquatic plant growth in irrigation canals and drains. The concentration of acrolein was monitored in a canal near Tule Lake after an application in order to evaluate the potential for the pesticide to be transported to refuge waters. Although acrolein concentrations were toxic to fish in the channels adjacent to Tule Lake, very little of the canal water entered the refuge during the monitoring period. Organochlorine pesticide concentrations in 25 surficial sediment samples collected in 1990 were below baseline levels commonly found in soils and sediment. Seventeen sediment samples were analyzed for chlorophenoxy acid herbicides and two samples were analyzed for organophosphorus and carbamate insecticides in 1992. No pesticides were detected in any of these samples. Residues of the trace elements selenium, mercury, and arsenic in algae, invertebrates, fish, and avian eggs revealed no bioaccumulation problems. Concentrations of organochlorine compounds, especially of p,p' DDE, were associated with a mean 11-percent eggshell thinning in white-faced ibis. However, ibis populations appear to be increasing, and some eggs of ibis were relatively low in DDE concentration. DDE concentrations in eggs of western grebes were not as high as in the eggs of ibis. Concentrations and types of organochlorine compounds detected in grebe and ibis eggs were highly variable, indicating that the birds were exposed to these compounds outside the basin. Fish and invertebrates inhabiting drainwater were representative of pollution-tolerant species assemblages. The aquatic communities retained little of their historic ecological structure. Extensive hydrologic modifications and hypereutrophic conditions in Klamath Basin waterways have degraded the quality of aquatic habitat and altered aquatic communities.

California, Oregon↗