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At least 469 records · Page 26Linked to original sources

USGS1949

Distribution of uranium in the Florida phosphate field

Land-pebble phosphate, hard-rock phosphate, and river-pebble phosphate are the three types of phosphatic rock found in Florida. This report is concerned primarily with the land-pebble deposits, the only type which contains a significant amount of uranium. The most productive part of the land-pebble district is in Polk and Hillsborough Counties, in the west-central part of the Florida peninsula. Phosphate occurs in both the Hawthorn formation of lower middle Miocene age and the Bone Valley formation of Pliocene age. The phosphate in the Bone Valley is generally of higher grade, probably as the result of mechanical reworking and further precipitation during submergence in Pliocene time. In a few places, leached parts of the Hawthorn formation are also of minable grade. , Pleistocene terrace deposits and beach sands unconformably overlie the Bone Valley. In Polk and Hillsborough Counties, the high-grade part of the land-pebble phosphate district, uranium occurs principally in the Bone Valley formation and is concentrated in the upper part of the formation, which has been leached by ground water. The maximum tenor found to date is 0.1 percent uranium. The basal member of the Bone Valley has a maximum grade of .02 percent uranium, and averages about .01 percent uranium. Fresh, unweathered Hawthorn formation has little or no uranium, but leached Hawthorn, rich in P 2 O 5 , contains a maximum of 0.01 percent uranium. The Pleistocene sands have no uranium except where they contain reworked phosphatic material from the Bone Valley formation. South of the high- grade district, in Manatee and Hardee Counties, the Bone Valley, Hawthorn, and Pleistocene formations contain only very minor amounts of uranium. The uranium in the land-pebble deposits was probably syngenetic in origin. Subsequent leaching of soluble material has resulted in residual enrichment of uranium. The uranium seems to be associated with the phosphate mineral.

Florida↗

USGS2007

Methane gas hydrate effect on sediment acoustic and strength properties

To improve our understanding of the interaction of methane gas hydrate with host sediment, we studied: (1) the effects of gas hydrate and ice on acoustic velocity in different sediment types, (2) effect of different hydrate formation mechanisms on measured acoustic properties (3) dependence of shear strength on pore space contents, and (4) pore pressure effects during undrained shear. A wide range in acoustic p-wave velocities (V p ) were measured in coarse-grained sediment for different pore space occupants. V p ranged from less than 1 km/s for gas-charged sediment to 1.77–1.94 km/s for water-saturated sediment, 2.91–4.00 km/s for sediment with varying degrees of hydrate saturation, and 3.88–4.33 km/s for frozen sediment. V p measured in fine-grained sediment containing gas hydrate was substantially lower (1.97 km/s). Acoustic models based on measured V p indicate that hydrate which formed in high gas flux environments can cement coarse-grained sediment, whereas hydrate formed from methane dissolved in the pore fluid may not. The presence of gas hydrate and other solid pore-filling material, such as ice, increased the sediment shear strength. The magnitude of that increase is related to the amount of hydrate in the pore space and cementation characteristics between the hydrate and sediment grains. We have found, that for consolidation stresses associated with the upper several hundred meters of sub-bottom depth, pore pressures decreased during shear in coarse-grained sediment containing gas hydrate, whereas pore pressure in fine-grained sediment typically increased during shear. The presence of free gas in pore spaces damped pore pressure response during shear and reduced the strengthening effect of gas hydrate in sands.

Journal of Petroleum Science and Engineering↗

USGS2009

Anatomy of the dead sea transform from lithospheric to microscopic scale

Fault zones are the locations where motion of tectonic plates, often associated with earthquakes, is accommodated. Despite a rapid increase in the understanding of faults in the last decades, our knowledge of their geometry, petrophysical properties, and controlling processes remains incomplete. The central questions addressed here in our study of the Dead Sea Transform (DST) in the Middle East are as follows: (1) What are the structure and kinematics of a large fault zone? (2) What controls its structure and kinematics? (3) How does the DST compare to other plate boundary fault zones? The DST has accommodated a total of 105 km of leftlateral transform motion between the African and Arabian plates since early Miocene (???20 Ma). The DST segment between the Dead Sea and the Red Sea, called the Arava/ Araba Fault (AF), is studied here using a multidisciplinary and multiscale approach from the ??m to the plate tectonic scale. We observe that under the DST a narrow, subvertical zone cuts through crust and lithosphere. First, from west to east the crustal thickness increases smoothly from 26 to 39 km, and a subhorizontal lower crustal reflector is detected east of the AF. Second, several faults exist in the upper crust in a 40 km wide zone centered on the AF, but none have kilometer-size zones of decreased seismic velocities or zones of high electrical conductivities in the upper crust expected for large damage zones. Third, the AF is the main branch of the DST system, even though it has accommodated only a part (up to 60 km) of the overall 105 km of sinistral plate motion. Fourth, the AF acts as a barrier to fluids to a depth of 4 km, and the lithology changes abruptly across it. Fifth, in the top few hundred meters of the AF a locally transpressional regime is observed in a 100-300 m wide zone of deformed and displaced material, bordered by subparallel faults forming a positive flower structure. Other segments of the AF have a transtensional character with small pull-aparts along them. The damage zones of the individual faults are only 5-20 m wide at this depth range. Sixth, two areas on the AF show mesoscale to microscale faulting and veining in limestone sequences with faulting depths between 2 and 5 km. Seventh, fluids in the AF are carried downward into the fault zone. Only a minor fraction of fluids is derived from ascending hydrothermal fluids. However, we found that on the kilometer scale the AF does not act as an important fluid conduit. Most of these findings are corroborated using thermomechanical modeling where shear deformation in the upper crust is localized in one or two major faults; at larger depth, shear deformation occurs in a 20-40 km wide zone with a mechanically weak decoupling zone extending subvertically through the entire lithosphere. Copyright 2009 by the American Geophysical Union.

Reviews of Geophysics↗

USGS2010

Isotopic composition and origin of indigenous natural perchlorate and co-occurring nitrate in the southwestern United States

Perchlorate (ClO 4 − ) has been detected widely in groundwater and soils of the southwestern United States. Much of this ClO 4 − appears to be natural, and it may have accumulated largely through wet and dry atmospheric deposition. This study evaluates the isotopic composition of natural ClO 4 − indigenous to the southwestern U.S. Stable isotope ratios were measured in ClO 4 − (δ 18 O, Δ 17 O, δ 37 Cl) and associated NO 3 − (δ 18 O, Δ 17 O, δ 15 N) in groundwater from the southern High Plains (SHP) of Texas and New Mexico and the Middle Rio Grande Basin (MRGB) in New Mexico, from unsaturated subsoil in the SHP, and from NO 3 − -rich surface caliche deposits near Death Valley, California. The data indicate natural ClO 4 − in the southwestern U.S. has a wide range of isotopic compositions that are distinct from those reported previously for natural ClO 4 − from the Atacama Desert of Chile as well as all known synthetic ClO 4 − . ClO 4 − in Death Valley caliche has a range of high Δ 17 O values (+8.6 to +18.4 ‰), overlapping and extending the Atacama range, indicating at least partial atmospheric formation via reaction with ozone (O 3 ). However, the Death Valley δ 37 Cl values (−3.1 to −0.8 ‰) and δ 18 O values (+2.9 to +26.1‰) are higher than those of Atacama ClO 4 − . In contrast, ClO 4 − from western Texas and New Mexico has much lower Δ 17 O (+0.3 to +1.3‰), with relatively high δ 37 Cl (+3.4 to +5.1 ‰) and δ 18 O (+0.5 to +4.8 ‰), indicating either that this material was not primarily generated with O 3 as a reactant or that the ClO 4 − was affected by postdepositional O isotope exchange. High Δ 17 O values in ClO 4 − (Atacama and Death Valley) are associated with high Δ 17 O values in NO 3 − , indicating that both compounds preserve characteristics of O 3 -related atmospheric production in hyper-arid settings, whereas both compounds have low Δ 17 O values in less arid settings. Although Δ 17 O variations in terrestrial NO 3 − can be attributed to mixing of atmospheric (high Δ 17 O) and biogenic (low Δ 17 O) NO 3 − , variations in Δ 17 O of terrestrial ClO 4 − are not readily explained in the same way. This study provides important new constraints for identifying natural sources of ClO 4 − in different environments by multicomponent isotopic characteristics, while presenting the possibilities of divergent ClO 4 − formation mechanisms and(or) ClO 4 − isotopic exchange in biologically active environments.

Environmental Science & Technology↗

USGS2012

Uncertainty

Management decisions will often be directly informed by model predictions. However, we now know there can be no expectation of a single ‘true’ model; thus, model results are uncertain. Understandable reporting of underlying uncertainty provides necessary context to decision-makers, as model results are used for management decisions. This, in turn, forms a mechanism by which groundwater models inform a risk-management framework because uncertainty around a prediction provides the basis for estimating the probability or likelihood of some event occurring. Given that the consequences of management decisions vary, it follows that the extent of and resources devoted to an uncertainty analysis may depend on the consequences. For events with low impact, a qualitative, limited uncertainty analysis may be sufficient for informing a decision. For events with a high impact, on the other hand, the risks might be better assessed and associated decisions made using a more robust and comprehensive uncertainty analysis. The purpose of this chapter is to provide guidance on uncertainty analysis through discussion of concepts and approaches, which can vary from heuristic (i.e. the modeller’s assessment of prediction uncertainty based on trial and error and experience) to a comprehensive, sophisticated, statistics-based uncertainty analysis. Most of the material presented here is taken from Doherty et al. (2010) if not otherwise cited. Although the treatment here is necessarily brief, the reader can find citations for the source material and additional references within this chapter.

Book chapter↗

USGS1965

Osmotic equilibrium and overthrust faulting

The two principal suggested modes of facilitating overthrust faulting are (1) lubrication at the sole by evaporite beds or micaceous shales and (2) flotation due to anomalously high (> hydrostatic) pore-water pressures. Past rapid sedimentation and tectonic compression have been suggested as important causes of anomalously high water pressure (Hubbert and Rubey, 1959). We suggest osmosis as another important possibility. Field data on shale beds and experimental studies on compacted clays show that such material can act as semipermeable membranes that greatly retard passage of dissolved electrolytes relative to H 2 O. Equilibrium osmotic pressure, π, across an ideal membrane is given by (a, activity; V H2O 0 1 , molar volume of distilled water). At 80°C, π is 470 bars between saturated halite solution and distilled water; it is 360 bars between saturated and 10 per cent solutions. At 25°C the values are 20 per cent lower. Other dissolved components, if present in similar proportions, will enhance the effect. Anomalous water pressures of at least 400 bars above hydrostatic have been measured in oil wells; many of these wells penetrate evaporites and/or shales which separate formation waters of differing salt concentrations. These pressures are explicable by assuming osmotic equilibrium across a membrane which separates saturated halite solution from solutions up to 10 weight per cent NaCl. Thus, osmotic equilibrium may be an important mechanism for floating thrust sheets. Lubrication of thrust sheets by shales or evaporites and flotation by anomalously high pressures may be simply different manifestations of the same geologic milieu. © 1965, The Geological Society of America, Inc.

Geological Society of America Bulletin↗

USGS2014

Formation of fine sediment deposit from a flash flood river in the Mediterranean Sea

We identify the mechanisms controlling fine deposits on the inner-shelf in front of the Besòs River, in the northwestern Mediterranean Sea. This river is characterized by a flash flood regime discharging large amounts of water (more than 20 times the mean water discharge) and sediment in very short periods lasting from hours to few days. Numerical model output was compared with bottom sediment observations and used to characterize the multiple spatial and temporal scales involved in offshore sediment deposit formation. A high-resolution (50 m grid size) coupled hydrodynamic-wave-sediment transport model was applied to the initial stages of the sediment dispersal after a storm-related flood event. After the flood, sediment accumulation was predominantly confined to an area near the coastline as a result of preferential deposition during the final stage of the storm. Subsequent reworking occurred due to wave-induced bottom shear stress that resuspended fine materials, with seaward flow exporting them toward the midshelf. Wave characteristics, sediment availability, and shelf circulation determined the transport after the reworking and the final sediment deposition location. One year simulations of the regional area revealed a prevalent southwestward average flow with increased intensity downstream. The circulation pattern was consistent with the observed fine deposit depocenter being shifted southward from the river mouth. At the southern edge, bathymetry controlled the fine deposition by inducing near-bottom flow convergence enhancing bottom shear stress. According to the short-term and long-term analyses, a seasonal pattern in the fine deposit formation is expected.

Journal of Geophysical Research: Oceans↗

USGS2004

Impact of clay minerals on sulfate-reducing activity in aquifers

Previous studies have shown that sulfate-reduction activity occurs in a heterogeneous manner throughout the terrestrial subsurface. Low-activity regions are often observed in the presence of clay minerals. Here we report that clays inhibit sulfate reduction activity in sediments and in a pure culture of Desulfovibrio vulgaris . Clay minerals including bentonite and kaolinite inhibited sulfate reduction by 70–90% in sediments. Intact clays and clay colloids or soluble components, capable of passing through a 0.2-µm filter, were also inhibitory to sulfate-reducing bacteria. Other adsorbent materials, including anion or cation exchangers and a zeolite, did not inhibit sulfate reduction in sediments, suggesting that the effect of clays was not due to their cation-exchange capacity. We observed a strong correlation between the Al 2 O 3 content of clays and their relative ability to inhibit sulfate reduction in sediments ( r 2 = 0.82). This suggested that inhibition might be a direct effect of Al 3+ (aq) on the bacteria. We then tested pure aluminum oxide (Al 2 O 3 ) and showed it to act in a similar manner to clay. As dissolved aluminum is known to be toxic to a variety of organisms at low concentrations, our results suggest that the effects of clay on sulfate-reducing bacteria may be directly due to aluminum. Thus, our experiments provide an explanation for the lack of sulfate-reduction activity in clay-rich regions and presents a mechanism for the effect.

Microbial Ecology↗

USGS1998

Geologic controls on the formation of lakes in north-central Florida

Fluid exchange between surficial waters and groundwater, as well as the processes that control this exchange, are of critical concern to water management districts and planners. Digital high-resolution seismic systems were used to collect geophysical data from 30 lakes of north-central Florida. Although using seismic profile data in the past has been less than successful, the use of digital technology has increased the potential for success. Seismic profiles collected from the lakes of north-central Florida have shown the potential application of these techniques in understanding the formation of individual lakes. In each case study, lake structure and geomorphology were controlled by solution and/or mechanical processes. Processes that control lake development are twofold: 1) karstification or dissolution of the underlying limestone, and 2) me collapse, subsidence, or slumping of overburden to form sinkholes. Initial lake formation is directly related to the karst topography of the underlying host limestone. Lake size and shape are a factor of the thickness of overburden and size of the collapse or subsidence and/or clustering of depressions allowing for lake development. Lake development is through progressive sequence stages to maturity that can be delineated into geomorphic types. Case studies have shown that lakes can be divided by geomorphic types into progressive developmental phases: (1) active subsidence or collapse phase (young) - the open to partially filled collapse structures typically associated with sink holes; (2) transitional phase (middle age) - the sinkhole is plugged as the voids within the collapse are filled with sediment, periodic reactivation may occur; (3) baselevel phase (mature) - active sinkholes are progressively plugged by the continual erosion of material into the basin, and eventually sediment fills the basins; and (4) polje (drowned prairie) - broad flat-bottom basins located within the epiphreatic zone that are inundated at high stages of the water table and have one or all phases of sinkhole development and many types of karst and karren features. Most lakes in this study have a small diameter (<1 km) making stratigraphic correlations from lake to lake difficult. Seismic profiles of subsurface features were used to define the lake geologic history and to locate possible breaches in the confining layer that maintains these lakes. Nine types of acoustical signatures were identified from the profiles to describe the structural history of each lake. Using these criteria, Florida lakes can be classified by size, fill, subsurface features, and geomorphology. Classification of the lakes has led to a better understanding of the relation between the geology and hydrology of Florida.

Florida↗

USGS2024

Analyzing spatial distributions and alignments of pitted cone features in Utopia Planitia on Mars

Martian geomorphology and surface features provide links to understanding past geologic processes such as fluid movement, local and regional tectonics, and feature formation mechanisms. Pitted cones are common features in the northern plains basins of Mars. They have been proposed to have formed from upwelling volatile-rich fluids, such as magma or water-sediment slurries. In this study, we map the spatial distributions of pitted cone features across the Utopia Planitia (UP) basin. Using the Average Nearest Neighbor technique, we find that pitted cone features appear to be clustered across the basin, occurring in a narrow band around the circumferential rim of UP. Additionally, we find that pitted cone features also appear to be aligned in chains that are sub-parallel with the basin margin. Parallel bands of cones generally follow elevation contours of the UP basin, which suggests elevation or a correlated factor plays a major role in pitted cone and cone chain formation. We propose that pitted cones and cone chains may be related to vertical fractures formed around the UP basin rim from subsidence of infilling basin material.

Icarus↗

USGS2015

Paleodischarge of the Mojave River, southwestern U.S.A, investigated with single-pebble measurements of 10Be

The paleohydrology of ephemeral stream systems is an important constraint on paleoclimatic conditions in arid environments, but remains difficult to constrain quantitatively. For example, sedimentary records of the size and extent of pluvial lakes in the Mojave Desert have been used as a proxy for Quaternary climate variability. Although the delivery mechanisms of this additional water are still being debated, it is generally agreed that the discharge of the Mojave River, which supplied water for several Pleistocene pluvial lakes along its course, must have been significantly greater during lake high stands. We used the 10Be concentrations of 10 individual quartzite pebbles sourced from the San Bernardino Mountains and collected from a ~25 ka strath terrace of the Mojave River near Barstow, Calif., to test whether pebble ages record the timing of large paleodischarge of the Mojave River. Our exposure ages indicate that periods of discharge large enough to transport pebble-sized sediment occurred at least four times over the past ~240 ky; individual pebble ages cluster into four groups with exposure ages of 24.82 ± 2.52 ka (n=3), 55.79 ± 2.59 ka (n=2), 99.14 ± 6.04 ka (n=4) and 239.9 ± 52.16 ka (n=1). These inferred large discharge events occurred during both glacial and interglacial conditions. We demonstrate that bedload materials provide information about the frequency and duration of transport events in river systems. This approach could be further improved with the addition of additional measurements of one or more cosmogenic nuclides coupled with models of river discharge and pebble transport.

Geosphere↗

USGS1970

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from activities of man. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural fresh water. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position: of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken all together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in composition of moving water and the effects of particulate suspended material. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, most probable forms of elements and ions in solution, solubility controls, expected concentration ranges and other chemical factors. Concentrations of elements that are commonly present in amounts less than a few tens of micrograms per liter cannot always be easily explained, but present information suggests many are controlled by solubility of hydroxide or carbonate or by sorption on solid particles. Chemical analyses may be grouped and statistically evaluated by averages, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among waters, probable sources of solutes, areal water-quality regimen, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrologic parameters, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 75 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also utilized in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Activities of man may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of sea water in ground-water aquifiers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural water composition is required for rational management of water quality.

Water Supply Paper↗

USGS1959

Study and interpretation of the chemical characteristics of natural water

Water Supply Paper↗

USGS1995

Thermodynamics of gas and steam-blast eruptions

Eruptions of gas or steam and non-juvenile debris are common in volcanic and hydrothermal areas. From reports of non-juvenile eruptions or eruptive sequences world-wide, at least three types (or end-members) can be identified: (1) those involving rock and liquid water initially at boiling-point temperatures (‘boiling-point eruptions’); (2) those powered by gas (primarily water vapor) at initial temperatures approaching magmatic (‘gas eruptions’); and (3) those caused by rapid mixing of hot rock and ground- or surface water (‘mixing eruptions’). For these eruption types, the mechanical energy released, final temperatures, liquid water contents and maximum theoretical velocities are compared by assuming that the erupting mixtures of rock and fluid thermally equilibrate, then decompress isentropically from initial, near-surface pressure (≤10 MPa) to atmospheric pressure. Maximum mechanical energy release is by far greatest for gas eruptions (≤∼1.3 MJ/kg of fluid-rock mixture)-about one-half that of an equivalent mass of gunpowder and one-fourth that of TNT. It is somewhat less for mixing eruptions (≤∼0.4 MJ/kg), and least for boiling-point eruptions (≤∼0.25 MJ/kg). The final water contents of crupted boiling-point mixtures are usually high, producing wet, sloppy deposits. Final erupted mixtures from gas eruptions are nearly always dry, whereas those from mixing eruptions vary from wet to dry. If all the enthalpy released in the eruptions were converted to kinetic energy, the final velocity ( v max ) of these mixtures could range up to 670 m/s for boiling-point eruptions and 1820 m/s for gas eruptions (highest for high initial pressure and mass fractions of rock ( m r ) near zero). For mixing eruptions, v max ranges up to 1150 m/s. All observed eruption velocities are less than 400 m/s, largely because (1) most solid material is expelled when m r is high, hence v max is low; (2) observations are made of large blocks the velocities of which may be less than the average for the mixture; (3) heat from solid particles is not efficiently transferred to the fluid during the eruptions; and (4) maximum velocities are reduced by choked flow or friction in the conduit.

Bulletin of Volcanology↗

USGS2009

Anatomy of the western Java plate interface from depth-migrated seismic images

Newly pre-stack depth-migrated seismic images resolve the structural details of the western Java forearc and plate interface. The structural segmentation of the forearc into discrete mechanical domains correlates with distinct deformation styles. Approximately 2/3 of the trench sediment fill is detached and incorporated into frontal prism imbricates, while the floor sequence is underthrust beneath the d??collement. Western Java, however, differs markedly from margins such as Nankai or Barbados, where a uniform, continuous d??collement reflector has been imaged. In our study area, the plate interface reveals a spatially irregular, nonlinear pattern characterized by the morphological relief of subducted seamounts and thicker than average patches of underthrust sediment. The underthrust sediment is associated with a low velocity zone as determined from wide-angle data. Active underplating is not resolved, but likely contributes to the uplift of the large bivergent wedge that constitutes the forearc high. Our profile is located 100 km west of the 2006 Java tsunami earthquake. The heterogeneous d??collement zone regulates the friction behavior of the shallow subduction environment where the earthquake occurred. The alternating pattern of enhanced frictional contact zones associated with oceanic basement relief and weak material patches of underthrust sediment influences seismic coupling and possibly contributed to the heterogeneous slip distribution. Our seismic images resolve a steeply dipping splay fault, which originates at the d??collement and terminates at the sea floor and which potentially contributes to tsunami generation during co-seismic activity. ?? 2009 Elsevier B.V.

Earth and Planetary Science Letters↗

USGS1989

Recharge of the early atmosphere of Mars by impact-induced release of CO2

Channels on the Martian surface suggest that Mars had an early, relatively thick atmosphere. If the atmosphere was thick enough for water to be stable at the surface, CO 2 in the atmosphere would have been fixed as carbonates on a relatively short time scale, previously estimated to be 1 bar every 10 7 years. This loss must have been offset by some replenishment mechanism to account for the numerous valley networks in the oldest surviving terrains. Impacts could have released CO 2 into the atmosphere by burial, by shock-induced release during impact events, and by addition of carbon to Mars from the impacting bolides. Depending on the relationship between the transient cavity diameter and the diameter of the resulting crater, burial rates as a result of impact gardening at the end of heavy bombardment are estimated to range from 20 to 45 m/10 6 years, on the assumption that cratering rates in Mars were similar to those of the Nectarian Period on the Moon. At these rates 0.1-0.2 bar of CO 2 could have been released every 107 years as a result of burial to depths where dissociation temperatures of carbonates were reached. Modeling of large impacts suggests that an additional 0.01 to 0.02 bar of CO 2 could have been released every 10 7 years during the actual impacts. In the unlikely event that all the impacting material was composed of carbonaceous chondrites, a further 0.3 bar of CO 2 could have been added to the atmosphere every 10 7 years by oxidation of meteoritic carbon. Even when supplemented by the volcanically induced release of CO 2 , these release rates are barely sufficient to sustain an early atmosphere if water were continuously present at the surface. The results suggest that water may have been only intermittently present on the surface early in the planet's history.

Icarus↗

USGS2021

Mars: Abundant recurring slope lineae (RSL) following the planet-encircling dust event (PEDE) of 2018

Recurring slope lineae (RSL) are dark linear markings on Mars that regrow annually and likely originate from the flow of either liquid water or granular material. Following the great dust storm (or planet-encircling dust event, PEDE) of Mars year (MY) 34, Mars Reconnaissance Orbiter/High Resolution Imaging Science Experiment has seen many more candidate RSL than in typical Mars years. They have been imaged at more than 285 unique locations from August 2018 (when the atmosphere was clearing as the PEDE decayed) to August 2019, about half (157) of which are locations where RSL have not been documented previously. In MY34, 150 active RSL sites were identified in the southern middle latitudes (SML, -60° to -30°), whereas an average of 36 active sites were observed in each previous year (MY28–33). Post-PEDE RSL are also present during southern summer over a wider range of latitude, slope aspect, and L s (areocentric longitude of the sun) than in prior years. These RSL sites usually show evidence for recent dust deposition: obscuration of relatively dark areas, an overall brighter and redder surface than in prior years, and dust devil tracks, which indicate dust lifting by several mechanisms. We speculate that dust-lifting processes may initiate and sustain RSL activity. The RSL may form from flows of dust (perhaps clumped) and/or sand that is destabilized by dust movement or directly mobilized by dust devils. If this is the case, then the otherwise puzzling recurrence and year-to-year variability of RSL activity can be at least partly explained. The dust replenishment varies from year to year, which could explain interannual variations in RSL activity.

Journal of Geophysical Research: Planets↗

USGS1996

Implications of fault constitutive properties for earthquake prediction

The rate- and state-dependent constitutive formulation for fault slip characterizes an exceptional variety of materials over a wide range of sliding conditions. This formulation provides a unified representation of diverse sliding phenomena including slip weakening over a characteristic sliding distance D(c), apparent fracture energy at a rupture front, time- dependent healing after rapid slip, and various other transient and slip rate effects. Laboratory observations and theoretical models both indicate that earthquake nucleation is accompanied by long intervals of accelerating slip. Strains from the nucleation process on buried faults generally could not be detected if laboratory values of D, apply to faults in nature. However, scaling of D(c) is presently an open question and the possibility exists that measurable premonitory creep may precede some earthquakes. Earthquake activity is modeled as a sequence of earthquake nucleation events. In this model, earthquake clustering arises from sensitivity of nucleation times to the stress changes induced by prior earthquakes. The model gives the characteristic Omori aftershock decay law and assigns physical interpretation to aftershock parameters. The seismicity formulation predicts large changes of earthquake probabilities result from stress changes. Two mechanisms for foreshocks are proposed that describe observed frequency of occurrence of foreshock-mainshock pairs by time and magnitude. With the first mechanism, foreshocks represent a manifestation of earthquake clustering in which the stress change at the time of the foreshock increases the probability of earthquakes at all magnitudes including the eventual mainshock. With the second model, accelerating fault slip on the mainshock nucleation zone triggers foreshocks.

Conference Paper↗