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At least 469 records · Page 26Linked to original sources

Geochemical modeling of changes in shallow groundwater chemistry observed during the MSU-ZERT CO2 injection experiment

A field experiment involving the release of carbon dioxide (CO 2 ) into a shallow aquifer was conducted near Bozeman, Montana, during the summer of 2008, to investigate the potential groundwater quality impacts in the case of leakage of CO 2 from deep geological storage. As an essential part of the Montana State University Zero Emission Research and Technology (MSU-ZERT) field program, food-grade CO 2 was injected over a 30 day period into a horizontal perforated pipe a few feet below the water table of a shallow aquifer. The impact of elevated CO 2 concentrations on groundwater quality was investigated by analyzing water samples taken before, during, and following CO 2 injection, from observation wells located in the vicinity of the injection pipe, and from two distant monitoring wells. Field measurements and laboratory analyses showed rapid and systematic changes in pH, alkalinity, and conductance, as well as increases in the aqueous concentrations of naturally occurring major and trace element species. The geochemical data were evaluated using principal component analysis (PCA) to (1) understand potential correlations between aqueous species, and (2) to identify minerals controlling the chemical composition of the groundwater prior to CO 2 injection. These evaluations were used to assess possible geochemical processes responsible for the observed increases in the concentrations of dissolved constituents, and to simulate these processes using a multicomponent reaction path model. Reasonable agreement between observed and modeled data suggests that (1) calcite dissolution was the primary pH buffer, yielding increased Ca +2 concentrations in the groundwater, (2) increases in the concentrations of most major and trace metal cations except Fe could be a result of Ca +2 -driven exchange reactions, (3) the release of anions from adsorption sites due to competitive adsorption of carbonate could explain the observed trends of most anions, and (4) the dissolution of reactive Fe minerals (presumed ferrihydrite and fougerite, from thermodynamic analyses) could explain increases in total Fe concentration. Highlights ► Because the possibility of CO 2 leakage cannot be completely ruled out, the potential impact of CO 2 intrusion on the quality of fresh water aquifers overlying CO 2 storage sites needs to be investigated. ► Geochemical data from a field experiment involving the release of carbon dioxide (CO 2 ) into a shallow aquifer were evaluated. ► Geochemical model used to assess possible geochemical processes responsible for the observed increases in the concentrations of dissolved constituents. ► Reasonable agreement between observed and modeled data suggests that increases in the concentrations of most major and trace metal cations except Fe could be a result of Ca +2 -driven exchange reactions and the release of anions from adsorption sites due to competitive adsorption of carbonate could explain the observed trends of most anions.

Montana↗

Larval Lake Whitefish (Coregonus clupeaformis) zooplankton consumption remains constant despite variation in prey densities in western Lake Erie

Larval fish growth and survival could be limited or reduced due to patchiness of zooplankton densities, even in productive aquatic systems. Recent declines in Lake Whitefish ( Coregonus clupeaformis ) populations prompted research to identify underlying mechanisms controlling survival at early life stages. In Lake Erie, the bottleneck window controlling year-class strength of Lake Whitefish likely occurs during the first growing season, suggesting that availability of important prey could influence year-class strength. Therefore, spatial and temporal larval Lake Whitefish distribution, diet, and prey utilization were evaluated in western Lake Erie. The pelagic Lake Whitefish larval period in the western basin extends from April 1 to May 15 with most larvae concentrated nearshore at the surface both day and night. Cyclopoid copepods were the most important prey item; however, calanoid copepods and Cladocera were consistently consumed, indicating that copepods and Cladocera were important larval Lake Whitefish prey items. Copepod and Cladocera biomass were the highest nearshore, overlapping with the highest larval Lake Whitefish densities. However, the amount of food consumed by larvae was consistent in all areas, suggesting that offshore areas in western Lake Erie with relatively low zooplankton biomass harbor enough food to satiate larval Lake Whitefish. Therefore, it is unlikely that prey availability limits survival through means of starvation during the larval phase.

western Lake Erie↗

Common hydraulic fracturing fluid additives alter the structure and function of anaerobic microbial communities

The development of unconventional oil and gas (UOG) resources results in the production of large volumes of wastewater containing a complex mixture of hydraulic fracturing chemical additives and components from the formation. The release of these wastewaters into the environment poses potential risks that are poorly understood. Microbial communities in stream sediments form the base of the food chain and may serve as sentinels for changes in stream health. Iron-reducing organisms have been shown to play a role in the biodegradation of a wide range of organic compounds, and so to evaluate their response to UOG wastewater, we enriched anaerobic microbial communities from sediments collected upstream (background) and downstream (impacted) of an UOG wastewater injection disposal facility in the presence of hydraulic fracturing fluid (HFF) additives: guar gum, ethylene glycol, and two biocides, 2,2-dibromo-3-nitrilopropionamide (DBNPA) and bronopol (C 3 H 6 BrNO 4 ). Iron reduction was significantly inhibited early in the incubations with the addition of biocides, whereas amendment with guar gum and ethylene glycol stimulated iron reduction relative to levels in the unamended controls. Changes in the microbial community structure were observed across all treatments, indicating the potential for even small amounts of UOG wastewater components to influence natural microbial processes. The microbial community structure differed between enrichments with background and impacted sediments, suggesting that impacted sediments may have been preconditioned by exposure to wastewater. These experiments demonstrated the potential for biocides to significantly decrease iron reduction rates immediately following a spill and demonstrated how microbial communities previously exposed to UOG wastewater may be more resilient to additional spills.

Applied and Environmental Microbiology↗

Geologic map of the upper Parashant Canyon and vicinity Mohave County, northwestern Arizona

The geologic map of the upper Parashant Canyon area covers part of the Colorado Plateau and several large tributary canyons that make up the western part of Arizona's Grand Canyon. The map is part of a cooperative U.S. Geological Survey and National Park Service project to provide geologic information for areas within the newly established Grand Canyon/Parashant Canyon National Monument. Most of the Grand Canyon and parts of the adjacent plateaus have been geologically mapped; this map fills in one of the remaining areas where uniform quality geologic mapping was needed. The geologic information presented may be useful in future related studies as to land use management, range management, and flood control programs for federal and state agencies, and private concerns. The map area is in a remote region of the Arizona Strip, northwestern Arizona about 88 km south of the nearest settlement of St. George, Utah. Elevations range from about 1,097 m (3,600 ft) in Parashant Canyon (south edge of map area) to 2,145 m (7,037 ft) near the east-central edge of the map area. Primary vehicle access is by dirt road locally known as the Mount Trumbull road; unimproved dirt roads and jeep trails traverse various parts of the map area. Travel on the Mount Trumbull road is possible with 2-wheel-drive vehicles except during wet conditions. Extra fuel, two spare tires and extra food and water are highly recommended when traveling in this remote area. The map area includes about 26 sections of land belonging to the State of Arizona, about 40 sections of private land, and a small strip of the Lake Mead National Recreation Area (southeast edge of the map area). The private land is mainly clustered around the abandoned settlement of Mt. Trumbull, locally known as Bundyville, and a few sections are scattered in the upper Whitmore Canyon area just south of Bundyville. Lower elevations within the canyons support a sparse growth of sagebrush, cactus, grass, creosote bush, and a variety of desert shrubs. Sagebrush, grass, cactus, cliffrose bush, pinyon pine trees, juniper trees, and some ponderosa pines thrive at higher elevations. Surface runoff in the north half of the map area drains northward towards the Virgin River in Utah via Hurricane Wash. In the south half of the area, it drains towards the Colorado River in Grand Canyon via Parashant and Whitmore Canyons. Upper Parashant and Whitmore Canyons are part of the physiography of the western Grand Canyon, but are not included within Grand Canyon National Park. The entire map area is now within the newly established Grand Canyon/Parashant Canyon National Monument (as of January, 2000), and is jointly managed by the Lake Mead National Recreational Area, Boulder City, Nevada, and the Bureau of Land Management, Arizona Strip District, St. George, Utah. Surface runoff in the north half of the map area drains northward towards the Virgin River in Utah via Hurricane Wash. In the south half of the area, it drains towards the Colorado River in Grand Canyon via Parashant and Whitmore Canyons. Upper Parashant and Whitmore Canyons are part of the physiography of the western Grand Canyon, but are not included within Grand Canyon National Park. The entire map area is now within the newly established Grand Canyon/Parashant Canyon National Monument (January, 2000), and is jointly managed by the Lake Mead National Recreational Area, Boulder City, Nevada, and the Bureau of Land Management, Arizona Strip District, St. George, Utah.

Arizona↗

Cruise Report; RV Moana Wave cruise M1-01-GM; the bathymetry and acoustic backscatter of the mid shelf to upper slope off Panama City, Florida, northeastern Gulf of Mexico; September 3, through October 12, 2001, Panama City, FL to Panama City, FL

A zone of deep-water reefs is thought to extend from the mid and outer shelf south of Mississippi and Alabama to at least the northwestern Florida shelf off Panama City, Florida (Figure 1, 67kb). The reefs off Mississippi and Alabama are found in water depths of 60 to 120 m (Ludwick and Walton, 1957; Gardner et al., in press) and were the focus of a multibeam echosounder (MBES) mapping survey by the U.S. Geological Survey (USGS) in 2000 (Gardner et al., 2000; in press). If this deep-water-reef trend does exist along the northwestern Florida shelf, then it is critical to determine the accurate geomorphology and type of the reefs that occur because of their importance as benthic habitats for fisheries. Precisely georeferenced high-resolution mapping of bathymetry is a fundamental first step in the study of areas suspected to be critical habitats. Morphology is thought to be critical to defining the distribution of dominant demersal plankton/planktivores communities. Fish faunas of shallow hermatypic reefs have been well studied, but those of deep ahermatypic reefs have been relatively ignored. The ecology of deep-water ahermatypic reefs is fundamentally different from hermatypic reefs because autochthonous intracellular symbiotic zooxanthellae (the carbon source for hermatypic corals) do not form the base of the trophic web in ahermatypic reefs. Instead, exogenous plankton, transported to the reef by currents, serves as the primary carbon source. Thus, one of the principle uses of the morphology data will be to identify whether any reefs found are hermatypic or ahermatypic in origin. Community structure and trophodynamics of demersal fishes of the outer continental of the northeastern Gulf of Mexico presently are the focus of a major USGS reseach project. A goal of the project is to answer questions concerning the relative roles played by morphology and surficial geology in controling biological differentiation. Deep-water reefs are important because they are fish havens, key spawning sites, and are critical early larval and juvenile habitats for economically important sport/food fishes. It is known that deep-water reefs function as a key source for re-population (via seasonal and ontogenetic migration) of heavily impacted inshore reefs. The deep-water reefs south of Mississippi and Alabama support a lush fauna of ahermatypic hard corals, soft corals, black corals, sessile crinoids and sponges, that together form a living habitat for a well-developed fish fauna. The fish fauna comprises typical Caribbean reef fishes and Carolinian shelf fishes, plus epipelagic fishes, and a few deep-sea fishes. The base of the megafaunal invertebrate food web is plankton, borne by essentially continuous semi-laminar currents generated by eddies, spawned off the Loop Current, that periodically travel across the shelf edge. A few, sidescan-sonar surveys have been made of areas locally identified as Destin Pinnacles, Steamboat Lumps Marine Reserve (Koenig et al., 2000; Scanlon, et al., 2000; 2001), Twin Ridges (Briere, et al., 2000; Scanlon, et al., 2000), and Madison-Swanson Marine Reserve (Koenig et al., 2000; Scanlon, et al., 2000; 2001). However, no quantitative and little qualitative information about the geomorphology and surficial geology can be gained from these data. Existing bathymetry along the northwestern Florida shelf suggests the existence of areas of possible isolated deep-water reefs. NOAA bathymetric maps NOS NH16-9 and NG16-12 show geomorphic expressions that hint of the presence of reefs in isolated areas rather than in a continuous zone. There has been no systematic, high-resolution bathymetry collected in this area, prior to this cruise. After the successful mapping of the deep-water reefs on the Mississippi and Alabama shelf (Gardner et al., 2000; in press), a partnership composed of the USGS, Minerals Management Service, and NOAA was formed to continue the deep-reef mapping to the northwest Florida mid shelf and upper slope. This cruise is the first fruit of that partnership.

Florida↗

Effects of a drawdown on plant communities in a freshwater impoundment at Lacassine National Wildlife Refuge, Louisiana

Disturbance is an important natural process in the creation and maintenance of wetlands. Water depth manipulation and prescribed fire are two types of disturbance commonly used by humans to influence vegetation succession and composition in wetlands with the intention of improving wildlife habitat value. A 6,475-hectare (ha) impoundment was constructed in 1943 on Lacassine National Wildlife Refuge in southwest Louisiana to create freshwater wetlands as wintering waterfowl habitat. Ten years after construction of the impoundment, called Lacassine pool, was completed, refuge staff began expressing concerns about increasing emergent vegetation cover, organic matter accumulation, and decreasing area of open water within the pool. Because the presence of permanent standing water impedes actions that can address these concerns, a small impoundment within the pool where it was possible to manipulate water depth was created. The 283-ha subimpoundment called Unit D was constructed in 1989. Water was pumped from Unit D in 1990, and the unit was permanently reflooded about 3 years later. Four prescribed fires were applied during the drawdown. A study was initiated in 1990 to investigate the effect of the experimental drawdown on vegetation and soils in Unit D. Four plant community types were described, and cores were collected to measure the depth of the soil organic layer. A second study of Unit D was conducted in 1997, 4 years after the unit was reflooded, by using the same plots and similar sampling methods. This report presents an analysis and synthesis of the data from the two studies and provides an evaluation of the impact of the management techniques applied. We found that plant community characteristics often differed among the four communities and varied with time. Species richness increased in two of the communities, and total aboveground biomass increased in all four during the drawdown. These changes, however, did not persist when Unit D was reflooded; by 1997, species richness and aboveground biomass were equivalent to values before the drawdown. The change in waterfowl food value of the plant communities during the drawdown varied; it did not change in two communities, increased in one, and decreased in one. A consistent pattern noted was that waterfowl food value was higher in communities that contained open water than in those dominated by emergent plants, both soon after the drawdown was initiated in Unit D and 4 years after reflooding. A reduction in depth of the soil organic layer became apparent 20 months after drawdown was initiated, and this reduction persisted in 1997, 4 years after reflooding. A separate 2003 study on soil characteristics in Lacassine pool found that the depth to the clay layer was lower in Unit D than in the rest of the pool. We were not able to establish a cause-and-effect relation between any changes noted and the fact water levels in the unit were drawn down because the initial study in 1990 did not include control plots. Changes in vegetation and soil organic layer depth identified in Unit D may have occurred in the surrounding Lacassine pool habitat as well. Similarly, we were unable to form any conclusions about the effect of the prescribed fire treatments because there was no information on which plots were burned. Because of the known relation between anaerobic soil conditions and reduced decomposition of organic matter, however, it is likely that the drawdown in Unit D resulted in an increased decomposition rate and a reduction in the depth of the soil organic layer.

Louisiana↗

Toxicity of five forest insecticides to cutthroat trout and two species of aquatic invertebrates

The Northern Rocky Mountain region has had scattered infestation of the western spruce budworm Christoneura occidentalis since the early 1900's (U.S. DEPARTMENT OF AGRICULTURE (USDA) 1976b). On the basis of aerial surveys in 1975, TUNNOCK et al. (1976), estimated that budworm defoliation occurred on 2,278,804 acres of six National Forests in Montana. Since the use of DDT was banned in 1972, there has been a need to develop alternative insecticides with the efficacy of DDT but without its environmental risk. These insecticides must be effective in controlling the budworm, but should not persist in the environment or be toxic to other organisms. The organophosphate and carbamate insecticides are relatively nonpersistent and generally present only a moderate hazard to fish when applied according to label recommendations. The USDA Forest Service has been investigating the effectiveness of these two classes of insecticides against the budworm, and the Columbia National Fisheries Research Laboratory of the U.S. Fish and Wildlife Service has been cooperating with the Forest Service conducted pilot control projects in eastern Montana in 1975 and 1976 to determine the efficacy and environmental impact of acephate, carbaryl, and trichlorfon in controlling the western budworm (USDA 1976 b). In 1975, a similar type project was carried out in Maine with aminocarb, fenitrothion, and trichlorfon (USDA 1976 a). Acephate, fenitrothion, and trichlorfon (organophosphate insecticides) and aminocarb and carbaryl (carbamate insecticides) were selected for toxicity tests against cutthroat trout ( Salmo clarki ), a stonefly ( Pteronarcella badia ), and a freshwater amphipod ( Gammarus pseudolimnaeus ) edemic in streams of the northern Rocky Mountains. Populations of cutthroat trout inhabit lakes and streams in the Rocky Mountains which include some of the most pristine habitat and fisheries in North America. Pteronarcella and Gammarus provide forage for cutthroat trout and feed on decaying vegetation in riffle areas in streams and rivers. Stonefly naiads and amphipods were selected as test organisms because of their importance as trout food and their wide distribution in mountain stream communities. We determined the effect of various water types representing different biogeographical areas in the Intermountain West on the toxicity of these five forest insecticides.

Bulletin of Environmental Contamination and Toxico↗

Quantitative subsurface characterization illuminates the origin of the Quaternary Mississippi River Valley alluvial aquifer

The Mississippi River Valley alluvial aquifer (MRVA) is vital to U.S. food security and global agricultural supply. However, quantitative understanding of its Quaternary origin, architecture, and hydrologic function remains incomplete. Here we develop a three-dimensional hydrostratigraphic model to characterize the deposition of clay and silt, fine-medium sands, and graveliferous sands using lithologic data from 75,000 boreholes compiled across the Lower Mississippi Valley and a geostatistical method—interval kriging. We find that cyclic glacial entrenchments, evidenced by remnants of pre-Wisconsinan postglacial sediments, alongside geodynamic activities shaped the MRVA basal configuration. Stratal weakening from faulting and salt diapirism enhanced glacial incision and thereby produced abrupt aquifer thickening. We demarcate the top of graveliferous sands as the regional marker of the Pleistocene-Holocene transition. The MRVA hydrostratigraphy reveals hydrologic function and geologic controls on groundwater storage and quality, advancing the assessment of aquifer sustainability under a changing climate, with implications for alluvial aquifers globally.

Arkansas, Illinois, Kentucky, Louisiana, Mississip↗

Multiple sublethal chemicals negatively affect tadpoles of the green frog, Rana clamitans

Many habitats may be exposed to multiple chemical contaminants, particularly in agricultural areas where fertilizer and pesticide use are common; however, the singular and interactive effects of contaminants are not well understood. The objective of our study was to examine how realistic, sublethal environmental levels of ammonium nitrate fertilizer (0, 10, 20 mg/L and ammonium chloride control) and the common insecticide carbaryl (0 or 2.5 mg/L) individually and interactively affect the development, size, and survival of green frog ( Rana clamitans ) tadpoles. We reared tadpoles for 95 d in outdoor 1,000-L polyethylene ponds. We found that the combination of carbaryl and nitrate had a negative effect on development and mass of tadpoles compared to the positive effect that either contaminant had alone. Presence of carbaryl was generally associated with short-term increases in algal resources, including ponds exposed to both carbaryl and nitrate. However, with exposure to nitrate and carbaryl, tadpole mass and development were not positively affected as with one chemical stressor alone. The combination of these sublethal contaminants may reduce the ability of amphibians to benefit from food-rich environments or have metabolic costs. Our study demonstrates the importance of considering multiple stressors when evaluating population-level responses.

Environmental Toxicology↗

Development of industrial minerals in Colorado

Technology and engineering have helped make mining safer and cleaner for both humans and the environment. Inevitably, mineral development entails costs as well as benefits. Developing a mine is an environmental, engineering, and planning challenge that must conform to many Federal, State, and local regulations. Community collaboration, creative design, and best management practices of sustainability and biodiversity can be positive indicators for the mining industry. A better understanding of aesthetics, culture, economics, geology, climate, vegetation and wildlife, topography, historical significance, and regional land planning is important in resolving land-use issues and managing mineral resources wisely. Ultimately, the consuming public makes choices about product use (including water, food, highways, housing, and thousands of other items) that influence operations of the mineral industry. Land planners, resource managers, earth scientists, designers, and public groups have a responsibility to consider sound scientific information, society's needs, and community appeals in making smart decisions concerning resource use and how complex landscapes should change. An effort to provide comprehensive geosciences data for land management agencies in central Colorado was undertaken in 2003 by scientists of the U.S. Geological Survey and the Colorado Geological Survey. This effort, the Central Colorado Assessment Project, addressed a variety of land-use issues: an understanding of the availability of industrial and metallic rocks and minerals, the geochemical and environmental effects of historic mining activity on surface water and groundwater, and the geologic controls on the availability and quality of groundwater. The USDA Forest Service and other land management agencies have the opportunity to contribute to the sustainable management of natural aggregate and other mineral resources through the identification and selective development of mineral resources and the reclamation of mines on lands that they administer. The information in this Circular will help them carry out that task.

Colorado↗

Increasing phosphorus loss despite widespread concentration decline in US rivers

The loss of phosphorous (P) from the land to aquatic systems has polluted waters and threatened food production worldwide. Systematic trend analysis of P, a nonrenewable resource, has been challenging, primarily due to sparse and inconsistent historical data. Here, we leveraged intensive hydrometeorological data and the recent renaissance of deep learning approaches to fill data gaps and reconstruct temporal trends. We trained a multitask long short-term memory model for total P (TP) using data from 430 rivers across the contiguous United States (CONUS). Trend analysis of reconstructed daily records (1980–2019) shows widespread decline in concentrations, with declining, increasing, and insignificantly changing trends in 60%, 28%, and 12% of the rivers, respectively. Concentrations in urban rivers have declined the most despite rising urban population in the past decades; concentrations in agricultural rivers however have mostly increased, suggesting not-as-effective controls of nonpoint sources in agriculture lands compared to point sources in cities. TP loss, calculated as fluxes by multiplying concentration and discharge, however exhibited an overall increasing rate of 6.5% per decade at the CONUS scale over the past 40 y, largely due to increasing river discharge. Results highlight the challenge of reducing TP loss that is complicated by changing river discharge in a warming climate.

conterminous United States↗

Laboratory evaluation of phototaxis in cultured Cisco larvae

Objective Field observations in a Lake Ontario embayment suggested that there is a phototaxic response of larval coregonines that changes with development. Methods We used a controlled laboratory experiment with hatchery-reared larvae exposed to three different light regimes (24-h light, 24-h dark, or 12-h light followed by 12-h dark) to test for phototaxis in Cisco Coregonus artedi . Results Larval depth distributions were not uniform, and contrasts between vertical distributions within early and late portions of the time series when larvae were exposed to light showed evidence of phototaxis and transition to a preference for the bottom around 68 d posthatch. Larval behavior in dark treatments contrasted with those exposed to light and also suggested that other influences on depth distribution could be operating. Conclusions As observed in other species, larval Cisco phototaxis response would likely result in diel vertical migrations and may be an adaptation to changes in food distributions balanced with predation risk as the larvae grow and become stronger swimmers. This has implications for the success of Cisco restoration in the Great Lakes, particularly as climate change affects environmental conditions and phenology.

Transactions of the American Fisheries Society↗

Acid precipitation and food quality: Inhibition of growth and survival in black ducks and mallards by dietary aluminum, calcium and phosphorus

In areas impacted by acid precipitation, water chemistry of acidic ponds and streams often changes, resulting in increased mobilization of aluminum and decreased concentration of calcium carbonate. Aluminum binds with phosphorus and inhibits its uptake by organisms. Thus, invertebrate food organisms used by waterfowl may have inadequate Ca and P or elevated Al for normal growth and development. Acid rain and its effects may be one of the factors negatively impacting American black ducks ( Anas rubripes ) in eastern North America. One-day old mallards ( A. platyrhynchos ) and black ducks were placed on one of three Ca:P regimens: low:low (LL), normal:normal (NN), and low:high (LH) with each regimen divided further into three or four Al levels for 10 weeks. Forty-five % of the black ducks died on nine different diets whereas only 28% of the mallards died on three different diets. Mortality was significantly related to diet in both species. Growth rates for body weight, culmens, wings, and tarsi of both species on control diets exceeded those on many treatment diets but the differences were less apparent for mallards than for black ducks. Differences among treatments were due to both Ca:P and A1 levels.

Archives of Environmental Contamination and Toxico↗

Geologic Map of Part of the Uinkaret Volcanic Field, Mohave County, Northwestern Arizona

The geologic map of part of the Uinkaret Volcanic Field is one product of a cooperative project between the U.S. Geological Survey, the National Park Service, and the Bureau of Land Management to provide geologic information about this part of the Grand Canyon-Parashant Canyon National Monument of Arizona. The Uinkaret Volcanic Field is a unique part of western Grand Canyon where volcanic rocks have preserved the geomorphic development of the landscape. Most of the Grand Canyon, and parts of adjacent plateaus have already been mapped. This map completes one of the remaining areas where uniform quality geologic mapping was needed. A few dozen volcanoes and lava flows within the Grand Canyon are not included in the map area, but their geologic significance to Grand Canyon development is documented by Hamblin (1994) and mapped by Billingsley and Huntoon (1983) and Wenrich and others (1997). The geologic information in this report may be useful to resource managers of the Bureau of Land Management for range management, biological, archaeological, and flood control programs. The map area lies within the Shivwits, Uinkaret, and Kanab Plateaus, which are subplateaus of the Colorado Plateaus physiographic province (Billingsley and others, 1997), and is part of the Arizona Strip north of the Colorado River. The nearest settlement is Colorado City, Arizona, about 58 km (36 mi) north of the map area (fig. 1). Elevations range from about 2,447 m (8,029 ft) at Mount Trumbull, in the northwest quarter of the map area, to about 732 m (2,400 ft) in Cove Canyon, in the southeast quarter of the map area. Vehicle access is via the Toroweap and Mount Trumbull dirt roads (fig. 1). Unimproved dirt roads traverse other parts of the area except in designated wilderness. Extra fuel, two spare tires, and extra food and water are highly recommended for travelers in this remote area. The U.S. Bureau of Land Management, Arizona Strip Field Office, St. George, Utah manages most of the area. In addition, there are 12 sections belonging to the State of Arizona, about 12 sections are private land, and several sections are within the Grand Canyon National Park and Lake Mead National Recreational Area (U.S. Department of the Interior, 1993). The private land is in Potato Valley and Lake Valley, southwest and west of Mount Trumbull, and in Whitmore Canyon and Toroweap (Tuweap) Valley. Portions of the Sawmill Mountains, Mount Logan, and Mount Trumbull areas were originally established as part of the Dixie National Forest in 1904. In 1924, Dixie National Forest land became part of the Kaibab National Forest. Then on February 13, 1974, management of this part of the Kaibab National Forest was transferred to the Bureau of Land Management, Arizona Strip Field Office (personal commun. Becky Hammond, Bureau of Land Management, 1997). Mount Logan and part of the Sawmill Mountains are now designated as the Mount Logan Wilderness Area, and Mount Trumbull is designated as the Mount Trumbull Wilderness Area. Most of the map area is now part of the new Grand Canyon-Parashant Canyon National Monument established January 11, 2000. Lower elevations within Hells Hollow, Whitmore Canyon, Toroweap Valley, and Cove Canyon support a sparse growth of sagebrush, cactus, grass, and a variety of desert shrubs. Sagebrush, grass, cactus, cliffrose bush, pinion pine, and juniper trees thrive at elevations above 1,830 m (6,000 ft). Ponderosa pine and oak forests thrive at higher elevations in the Mount Trumbull and Mount Logan areas. Surface runoff within the map area drains south towards the Colorado River through Hells Hole, Hollow, Whitmore Canyon, Toroweap Valley, and Cove Canyon. Upper Toroweap Valley, upper Hells Hollow, and Whitmore Canyon are part of the physiographic area of Grand Canyon, but are not within Grand Canyon National Park (Billingsley and others, 1997). As of January 11, 2000, these areas are now part of the new Grand Canyon-Parashant

Miscellaneous Field Studies Map↗

The effects of sediment and mercury mobilization in the South Yuba River and Humbug Creek confluence area, Nevada County, California: Concentrations, speciation, and environmental fate – Part 1: Field characterization

Millions of pounds of mercury (Hg) were deposited in the river and stream channels of the Sierra Nevada from placer and hard-rock mining operations in the late 1800s and early 1900s. The resulting contaminated sediments are relatively harmless when buried and isolated from the overlying aquatic environment. The entrained Hg in the sediment constitutes a potential risk to human and ecosystem health should it be reintroduced to the actively cycling portion of the aquatic system, where it can become methylated and subsequently bioaccumulated in the food web. Each year, sediment is mobilized within these fluvial systems during high stormflows, transporting hundreds of tons of Hg-laden sediment downstream. The State of California and resource-management agencies, including the Bureau of Land Management (BLM) and the U.S. Forest Service, are concerned about additional disturbances, such as from suction gold dredging activities, which have the potential to mobilize Hg associated with buried sediment layers elevated in Hg that are otherwise likely to remain buried under normal storm conditions. The BLM initiated a study looking at the feasibility of removing Hg-contaminated sediment at the confluence of the South Yuba River and Humbug Creek in the northern Sierra Nevada of California by using standard suction-dredge technology. Additionally, the California State Water Resources Control Board (SWRCB) supported a comprehensive characterization of the intended dredge site. Together, the BLM and SWRCB supported a comprehensive characterization of Hg contamination at the site and the potential effects of sediment disturbance at locations with historical hydraulic mining debris on downstream environments. The comprehensive study consisted of two primary components: field studies and laboratory experiments. The field component, described in this report, had several study elements: 1) a preliminary, smallscale, in-stream dredge test; 2) comprehensive characterization of grain size distribution, Hg speciation, and mineralogy of bed and suspended sediment; 3) a determination of the past and current sources of sediment in the study area; 4) an assessment of Hg bioaccumulation in the local invertebrate population; and 5) a comparison of potential Hg transport caused by natural storm disturbances with potential Hg mobilization caused by suction dredging as a method of Hg removal at the study site. The laboratory component of the study assessed the potential influence of the disturbance of Hg-contaminated sediment through experiments designed to simulate in-stream transport, deposition, and potential methylation of Hg, described in a companion report (see Marvin-DiPasquale and others, 2011). Results of the field studies indicate that the fine-grained fraction (silt-clay, less than 0.063 millimeters) contains the greatest concentration of Hg in contaminated sediment. Because the fine-grained fraction is the most susceptible to longrange fluvial transport, disturbance of Hg-contaminated sediment is likely to increase the concentration and load of Hg in downstream waters. The preliminary, small-scale dredge test showed an increase in the concentration of fine particles and Hg in the water column caused by the dredge activity, despite relatively low concentrations of fine particles and Hg (about 300 nanograms per gram) at the dredge site. Characterization of sediment from two test pits and other sites in the vicinity of the confluence of the South Yuba River and Humbug Creek revealed a highly variable distribution of fine- and coarse-grained sediment. The highest levels of Hg contamination (up to 11,100 ng/g) were associated with the fine-grained fraction of sediment from the bedrock contact zone of Pit 2, a horizon which also yielded grains of gold and gold-Hg amalgam. A closed-circuit tank experiment with a venturi dredge at the base of Pit 1, in a gravel bar within the South Yuba River, resulted in fine-grained suspended sediment remaining in suspension more than 40 hours following the disturbance simulation. Although the volumetric concentration of Hg declined over time as particles settled out, the concentration of Hg on the suspended particles increased over time as the suspended material became finer grained, because Hg is preferentially adsorbed on to clay-sized particles. Mineralogical and chemical analyses indicated that the buried fine-grained material with the greatest Hg contamination was derived from hydraulic mining debris, which consist primarily of Eocene gravels mined in the Malakoff Diggins, North Bloomfield, and Lake City areas within the South Yuba River watershed. Coarse material and more recently deposited sediment were derived primarily from upstream sources on the South Yuba River. The biota assessment indicated that invertebrate taxa collected from all sites on the South Yuba River in 2007, including lower Humbug Creek, had elevated concentrations of total mercury (THg) and methylmercury (MeHg) compared to a reference site on the Bear River, upstream of mining effects. Differences with the reference site were less pronounced in 2008 when a significant reduction in MeHg concentrations was observed in biota across all taxa from concentrations in 2007. It is possible that the inter-annual variation was related to the fact that suction dredging was active in the South Yuba River in 2007 but not in 2008 when a local moratorium was imposed by the BLM. There were significant variations among taxa for both THg and MeHg concentrations, with the water striders (Gerridae) having the highest concentrations of both THg and MeHg; variation among sites was not as strong as between years or among taxa. These results suggest that additional monitoring would be helpful to investigate the possible linkage between variations in MeHg bioaccumulation and levels of suction dredge activity in areas of historical gold mining. Results from the field studies indicate that disturbance of the finegrained Hg-contaminated sediment would likely lead to enhanced mobilization of Hg to downstream environments; therefore, the use of suction dredging to remove Hg at the South Yuba River and Humbug Creek confluence area would likely result in enhanced Hg transport downstream relative to natural conditions.

California↗

Toxicity to woodlice of zinc and lead oxides added to soil litter

Previous studies have shown that high concentrations of metals in soil are associated with reductions in decomposer populations. We have here determined the relation between the concentrations of lead and zinc added as oxides to soil litter and the survival and reproduction of a decomposer population under controlled conditions. Laboratory populations of woodlice (Porcellio scaber Latr) were fed soil litter treated with lead or zinc at concentrations that ranged from 100 to 12,800 ppm. The survival of the adults, the maximum number of young alive, and the average number of young alive, were recorded over 64 weeks. Lead at 12,800 ppm and zinc at 1,600 ppm or more had statistically significant (p < 0.05) negative effects on the populations. These results agree with field observations suggesting that lead and zinc have reduced populations of decomposers in contaminated forest soil litter, and concentrations are similar to those reported to be associated with reductions in natural populations of decomposers. Poisoning of decomposers may disrupt nutrient cycling, reduce the numbers of invertebrates available to other wildlife for food, and contribute to the contamination of food chains.

Ambio↗

Dicofol (Kelthane®)-induced eggshell thinning in captive american kestrels

Reproductive parameters of American kestrels ( Falco sparverius ) were measured through two breeding seasons. Exposure to Kelthane® (containing no DDT-related compounds) at dietary concentrations of 0 (control), 1,3, 10 and 30 μg/g (wet weight) began in late November before, and continued through, the second season. Kelthane thinned eggshells and lowered the thickness index at dietary concentrations ≥3 μg/g and it reduced shell weight at ≥10μg/g when comparisons were to concurrent controls. Kelthane reduced the thickness index at ≥3 μg/g and it reduced shell thickness and weight at ≥10 μg/g when comparisons were to the same birds during the previous season. All changes were dose-related. It was not previously known that as little as 3 μg/g dicofol could cause these effects. Kestrels resembled previously studied eastern screech-owls ( Otus asio ) in that 10 μg/g reduced hatchability of eggs. Both these raptors showed eggshell changes without serious effects on production of young. Available data show dicofol only equal to or less effective than DDE as a shell-thinning agent. Also, DDE may have more impact than dicofol on such critical aspects of reproduction as egg hatchability and survivability of hatchlings. Field studies of dicofol residues in food chains and of residue concentrations in eggs vs. nesting success from areas of heavy dicofol use are needed to judge this chemical's ecological impact.

Environmental Toxicology and Chemistry↗

Abiotic & biotic responses of the Colorado River to controlled floods at Glen Canyon Dam, Arizona, USA

Closure of Glen Canyon Dam reduced sand supply to the Colorado River in Grand Canyon National Park by about 94% while its operation has also eroded the park's sandbar habitats. Three controlled floods released from the dam since 1995 suggest that sandbars might be rebuilt and maintained, but only if repeated floods are timed to follow tributary sand deliveries below the dam. Monitoring data show that sandbars are dynamic and that their erosion after bar building is positively related with mean daily discharge and negatively related with tributary sand production after controlled floods. The March 2008 flood affected non-native rainbow trout abundance in the Lees Ferry tailwater, which supports a blue ribbon fishery. Downstream trout dispersal from the tailwater results in negative competitive interactions and predation on endangered humpback chub. Early survival rates of age-0 trout increased more than fourfold following the 2008 flood, and twofold in 2009, relative to prior years (2006-2007). Hatch-date analysis indicated that early survival rates were much higher for cohorts that emerged about 2 months after the 2008 flood relative to cohorts that emerged earlier that year. The 2009 survival data suggest that tailwater habitat improvements persisted for at least a year, but apparently decreased in 2010. Increased early survival rates for trout coincided with the increased availability of higher quality drifting food items after the 2008 flood owing to an increase in midges and black flies, preferred food items of rainbow trout. Repeated floods from the dam might sustainably rebuild and maintain sandbars if released when new tributary sand is available below the tailwater. Spring flooding might also sustain increased trout abundance and benefit the tailwater fishery, but also be a potential risk to humpback chub in Grand Canyon.

Arizona;Nevada;Utah↗