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Salinas Valley integrated hydrologic and reservoir operations models, Monterey and San Luis Obispo Counties, California
The area surrounding the Salinas Valley groundwater basin in Monterey and San Luis Obispo Counties of California is a highly productive agricultural area, contributes significantly to the local economy, and provides a substantial portion of vegetables and other agricultural commodities to the Nation. This region of California provides about half of the Nation’s lettuce, celery, broccoli, and spinach each year. Thus, this agricultural area provides significant volumes of agricultural products not just for California but the entire United States. Changes in population and increased agricultural development, which includes a shift toward more water-intensive crops, and climate variability, have put increasing demand on both surface water and groundwater resources in the valley. This has resulted in water management challenges in the Salinas Valley that are predominantly related to distribution of water supply throughout the basin. Where and when the water is present in the surface and subsurface does not coincide with where and when the water is needed. To deal with the distribution issue, historically water has been used conjunctively in the valley. Conjunctive use is a water management strategy that coordinates surface water and groundwater use to maximize water availability. Groundwater is used throughout the Salinas Valley to meet water demands when surface water supplies are insufficient. Availability of surface water is constrained by climate. Precipitation and streamflow vary seasonally and year to year. Although there are two reservoirs in the Salinas Valley to capture and store water during wet periods, the only conveyance of reservoir water to coastal agricultural areas is the Salinas River. Increasing demand on groundwater and surface water resources throughout the Salinas Valley has resulted in undesirable effects of unsustainable water use, such as surface water depletion, groundwater level declines, storage depletion in the principal aquifers, and seawater intrusion. To address these escalating issues, local communities, water management agencies, and groundwater sustainability agencies are evaluating how to sustainably manage both their surface water and groundwater resources. To meet water demands and reduce undesirable effects of unsustainable water use, continued conjunctive management of surface water and groundwater would ideally incorporate strategies to deal with increases in demand and a variable climate. To evaluate the challenging water management issues in the Salinas Valley, the U.S. Geological Survey, Monterey County Water Resource Agency, and the Salinas Valley Basin Groundwater Sustainability Agency developed a comprehensive suite of models that represent the Salinas Valley Hydrogeologic system called the Salinas Valley System Model. The Salinas Valley Geologic Framework was developed to characterize the subsurface using various topographic and geologic data sources, including information on hydrogeologic units, their surfaces and extents, geologic structures, lithology, and elevations from borehole data and cross sections, as well as details on faults and existing models. The Salinas Valley Watershed Model simulates the entire Salinas River watershed. Monthly surface water inflows into the integrated hydrologic model domain were simulated using the Salinas Valley Watershed Model. The historical model uses historical climate data, water and land use data, and reservoir releases to simulate agricultural operations, including landscape water demands, diversions, and reclaimed wastewater. The operational model adds an embedded reservoir operations framework to the simulation of the historical model that allows specified operational rules to simulate reservoir releases and changes in reservoir storage. The operational model assumes current reservoir operations and constant land use, which differs from historical conditions. Thus, the operational model is a hypothetical baseline model that can be used by local water managers to evaluate and quantify potential benefits of water supply projects. Together, the geologic framework, watershed, historical, and operational models form a tool that can be used to simulate irrigated agriculture and associated reservoir operations of the integrated hydrologic system of the Salinas Valley.
Methods for quantifying interactions between groundwater and surface water
Driven by the need for integrated management of groundwater (GW) and surface water (SW), quantification of GW–SW interactions and associated contaminant transport has become increasingly important. This is due to their substantial impact on water quantity and quality. In this review, we provide an overview of the methods developed over the past several decades to investigate GW–SW interactions. These methods include geophysical, hydrometric, and tracer techniques, as well as various modeling approaches. Different methods reveal valuable information on GW–SW interactions at different scales with their respective advantages and limitations. Interpreting data from these techniques can be challenging due to factors like scale effects, heterogeneous hydrogeological conditions, sediment variability, and complex spatiotemporal connections between GW and SW. To facilitate the selection of appropriate methods for specific sites, we discuss the strengths, weaknesses, and challenges of each technique, and we offer perspectives on knowledge gaps in the current science.
Continuous hydrologic simulation of runoff for the Middle Fork and South Fork of the Beargrass Creek basin in Jefferson County, Kentucky
The Hydrological Simulation Pro-gram-FORTRAN (HSPF) was applied to an urban drainage basin in Jefferson County, Ky to integrate the large amounts of information being collected on water quantity and quality into an analytical framework that could be used as a management and planning tool. Hydrologic response units were developed using geographic data and a K-means analysis to characterize important hydrologic and physical factors in the basin. The Hydrological Simulation Program FORTRAN Expert System (HSPEXP) was used to calibrate the model parameters for the Middle Fork Beargrass Creek Basin for 3 years (June 1, 1991, to May 31, 1994) of 5-minute streamflow and precipitation time series, and 3 years of hourly pan-evaporation time series. The calibrated model parameters were applied to the South Fork Beargrass Creek Basin for confirmation. The model confirmation results indicated that the model simulated the system within acceptable tolerances. The coefficient of determination and coefficient of model-fit efficiency between simulated and observed daily flows were 0.91 and 0.82, respectively, for model calibration and 0.88 and 0.77, respectively, for model confirmation. The model is most sensitive to estimates of the area of effective impervious land in the basin; the spatial distribution of rain-fall; and the lower-zone evapotranspiration, lower-zone nominal storage, and infiltration-capacity parameters during recession and low-flow periods. The error contribution from these sources varies with season and antecedent conditions.
Using a time-of-travel sampling approach to quantify per- and polyfluoroalkyl substances (PFAS) stream loading and source inputs in a mixed-source, urban catchment
Understanding per- and polyfluoroalkyl substances (PFAS) mass distribution in surface and groundwater systems can support source prioritization, load reduction, and water management. Thirteen sites within an urban catchment were sampled utilizing a time-of-travel sampling approach to minimize the influence of subdaily fluctuations in mass from PFAS point sources and to quantify PFAS and ancillary chemical loads from various PFAS sources. A larger increase in perfluoroalkyl sulfonate (PFSA) loads (8 to 11 μg/s, up to 618%) than in perfluoroalkyl carboxylate (PFCA) loads (no change to 3.4 μg/s, up to 122%) was observed at sites below tributaries influenced by military bases with known groundwater discharge. Point discharges from two sewage treatment plants (STPs) resulted in increases in PFCA and PFSA loads that were similar (6 and 10 μg/s respectively) below the first STP and greater for PFCA compared to PFSA loads (23 and 13 μg/s respectively) below the second STP. Overall, percent increases in total PFAS load ranged from 20 to 277% for military base inputs and 44 to 77% for STP inputs. A focus catchment that represents only 14% (76.9 km 2 ) of the drainage area at the most downstream site (544 km 2 ) accounted for about 70% of PFSA and 40% of PFCA loads observed at the most downstream site. Results show that by using a time-of-travel sampling approach in mixed, urban settings with several PFAS sources, it is possible to quantify stream loads from individual PFAS sources, thereby improving source attribution and providing actionable data for water-resource managers.
Salinas Valley integrated hydrologic and reservoir operations models, Monterey and San Luis Obispo Counties, California
The area surrounding the Salinas Valley groundwater basin in Monterey and San Luis Obispo Counties of California is a highly productive agricultural area, contributes substantially to the local economy, and provides a substantial portion of vegetables and other agricultural commodities to the Nation. This region of California provides about half of the Nation’s lettuce, celery, broccoli, and spinach each year. Thus, this agricultural area provides substantial volumes of agricultural products not just for California but for the United States. Changes in population and increased agricultural development, which includes a shift toward more water-intensive crops, and climate variability, have put increasing demand on both surface-water and groundwater resources in the valley. This situation has resulted in water management challenges in the Salinas Valley that generally relate to the distribution of the water supply throughout the basin. Where and when the water is present in the surface and subsurface does not coincide with where and when the water is needed. Historically, to deal with the distribution issue, water has been used conjunctively in the valley. Conjunctive use is a water management strategy that coordinates surface-water and groundwater use to maximize water availability. Groundwater is used throughout the Salinas Valley to meet water demands when surface-water supplies are insufficient. The availability of surface water is constrained by climate. Precipitation and streamflow vary seasonally and year to year. Although there are two reservoirs in the Salinas Valley to capture and store water during wet periods, the only conveyance of reservoir water to coastal agricultural areas is the Salinas River. Increasing demand for groundwater and surface-water resources throughout the Salinas Valley has resulted in undesirable effects from unsustainable water use, such as surface-water depletion, groundwater-level declines, storage depletion in the principal aquifers, and seawater intrusion. To address these escalating issues, local communities, water management agencies, and groundwater sustainability agencies are evaluating how to sustainably manage both their surface-water and groundwater resources. To meet water demands and reduce the undesirable effects of unsustainable water use, continued conjunctive management of surface water and groundwater would ideally incorporate strategies to deal with increases in demand and climate variability. To evaluate the challenging water management issues in the Salinas Valley, the U.S. Geological Survey, Monterey County Water Resources Agency, and the Salinas Valley Basin Groundwater Sustainability Agency developed a comprehensive suite of models that represent the Salinas Valley hydrogeologic system called the Salinas Valley System Model. The geologic framework is known as the Salinas Valley Geologic Framework and was developed to characterize the subsurface using various topographic and geologic data sources, including information on hydrogeologic units, their surfaces and extents, geologic structures, lithology, and elevations from borehole data and cross sections, as well as details on faults and existing models. The surface-water model is called the Salinas Valley Watershed Model and simulates the Salinas River watershed. Monthly surface-water inflows into the integrated hydrologic model domain were simulated using the Salinas Valley Watershed Model. The historical model uses historical climate data, water and land use data, and reservoir releases to simulate agricultural operations, including landscape water demands, diversions, and reclaimed wastewater. The operational model adds an embedded reservoir operations framework to the simulation of the historical model that allows specified operational rules to simulate reservoir releases and changes in reservoir storage. The operational model assumes current reservoir operations and constant land use, which differs from historical conditions. Thus, the operational model is a hypothetical baseline model that can be used by local water managers to evaluate and quantify potential benefits of water supply projects. Together, the geologic framework, watershed, historical, and operational models form a tool that can be used to simulate irrigated agriculture and associated reservoir operations of the integrated hydrologic system of the Salinas Valley.
Spatial distribution of API gravity and gas/oil ratios for petroleum accumulations in Upper Cretaceous strata of the San Miguel, Olmos, and Escondido Formations of the south Texas Maverick Basin—Implications for petroleum migration and charge history
The Maverick Basin of south Texas is currently undergoing active exploration and production of gas and oil from tight sandstone reservoirs. The most productive tight sandstones in the basin are in the Upper Cretaceous San Miguel, Olmos, and Escondido Formations. These units are second only to the Eagle Ford Shale in terms of cumulative production volumes. The structural history of the Maverick Basin, from rifting to subsidence to exhumation, has had a profound effect on the characteristics of these reservoirs and the petroleum resources contained therein. This U.S. Geological Survey review of the production history of these strata reflects a recent shift from conventional production to horizontal drilling (unconventional) that exploits low permeability reservoirs in previously overlooked areas of existing oil and gas fields in southern Texas, typically outside of established field boundaries. To investigate the physical properties of the Maverick Basin hydrocarbon accumulations, this case study compiled American Petroleum Institute (API) gravity measurements and calculated cumulative gas/oil ratios (GOR) for thousands of producing wells from the San Miguel, Olmos, and Escondido Formations. Maps were generated from the compiled well production data to show the spatial heterogeneity of API gravity and GOR values for the three formations within the Maverick Basin and immediately outside the basin to the northeast. Within the Maverick Basin, the spatial patterns of API gravity values indicate lighter oils downdip towards the southern basin edge. GOR values indicative of wet and dry gases within the basin are seen interspersed, with values that correspond to black and heavy oils. Differences in the spatial patterns of the petroleum properties within the Maverick Basin are interpreted as effects of Eocene basin inversion caused by Laramide orogenic deformation, and the resulting reservoir exhumation of basin strata. East of the Maverick Basin, spatial distributions of API gravity and GOR values show progressively heavier oils updip to the northwest, grading to dry gases downdip to the southeast, which correlates to the oil and gas windows of the underlying Eagle Ford Shale. Correlation of API gravity and GOR values from the San Miguel, Olmos, and Escondido Formations with thermal maturity data from the Eagle Ford Shale suggests that the Eagle Ford Shale is the petroleum source, and that petroleum migration was approximately vertical for areas to the east of the Maverick Basin. The discontinuity of API gravity and GOR properties within the Maverick Basin implies a complex petroleum charge history, possibly involving the remigration of petroleum and the addition of petroleum from other source intervals in Mexico, to the southwest. Depressurization of exhumed, overpressured reservoirs of the San Miguel, Olmos, and Escondido Formations can explain the intermittent occurrence of gas production throughout the southern Maverick Basin by exsolution of gas from formation brines and the resulting dry gas flushing of hydrocarbon-charged reservoirs. The introduction of dry gas through flushing can, in turn, explain why the patterns of API gravity and GOR values are so dissimilar in the Maverick Basin. This process has implications for possible future production of unconventional resources from undiscovered tight-gas reservoirs in strata of the San Miguel, Olmos, and Escondido Formations, and a different approach to petroleum exploration may be needed in the Maverick Basin relative to exploration techniques applied in other basins within the northern Gulf of Mexico.
Aeromagnetic and magnetotelluric imaging of west-central Idaho and the Stibnite-Yellow Pine mining district: A regional to district perspective
Aeromagnetic and magnetotelluric (MT) data are used to better understand the geology and mineral resources near the Stibnite-Yellow Pine mining district in central Idaho. The reduced-to-pole (RTP) transformation of regional-scale aeromagnetic data shows that allochthonous island-arc rocks west of the Salmon River suture are significantly more magnetic than the Laurentian continental rocks east of the suture and that the granitoids of the Idaho batholith have moderate to low magnetization in both early, metaluminous, and late, peraluminous phases. Application of tilt derivative to aeromagnetic data highlights major crustal-scale structures. The 5-km upward continued magnetic data indicate island-arc rocks have deep magnetic sources. The 110-km-long MT profile images resistivity structure to depths around 30 km. At shallow depths, resistivity corresponds to mapped geologic units, with moderate resistivities underlying volcanic and roof-pendant metasedimentary rocks and moderate to high resistivities occurring beneath the Idaho batholith. Crustal-scale moderate resistivities beneath the suture image the results of tectonomagmatic processes that accompanied suturing and translating allochthonous terranes. Low resistivity values beneath and fringing the batholith are derived from metasedimentary rocks that may have served as a melt source and reductant during melt generation and provided metals during later ore formation. In the Stibnite-Yellow Pine mining district, a high-resolution aeromagnetic compilation is shown to correlate with mapped lithologies and mineral deposit-related structures. The RTP transform distinguishes magnetic and nonmagnetic granitoid phases of the Idaho batholith. The tilt derivative highlights metasedimentary rocks, some of which are favorable ore hosts. The Meadow Creek fault hosts the Stibnite and Hangar Flats deposits and is imaged as a magnetic low due to hydrothermal alteration. Reconstructions of magnetic anomaly offsets and orebodies indicate around 3 km of post-95 Ma dextral separation, with some or all of the offset inferred to postdate the main Au mineralization episode (61–66 Ma).
Unraveling protracted modification of Archean and Paleoproterozoic crust in central Laurentia, Penokean orogen, with garnet and accessory mineral geochronology and microstructural analysis
Proterozoic metamorphism and deformation of the southern margin of the Superior craton in the Lake Superior region is attributed to the Penokean orogeny (1890−1830 Ma). This model includes a period of crustal inversion in which Archean basement blocks were exhumed through overlying Paleoproterozoic strata, producing the corridor of gneiss domes that parallels the trend of the Penokean orogen across the northern Midcontinent, USA. However, recent geologic mapping and 40 Ar/ 39 Ar geochronology challenge this interpretation, suggesting instead that the gneiss dome structures reflect younger episodes of tectonic activity along the southern margin of Laurentia. In absence of integrated pressure-temperature-time-deformation constraints for these rocks, interpretations are largely limited to their final cooling history, making it difficult to both identify the tectonic forces that shaped the architecture of the Penokean orogenic belt and assess the extent to which later Proterozoic tectonism modified the southern Superior craton. We address this problem with an approach joining thermodynamic modeling, garnet and accessory mineral geochronology, and microstructural analysis for several metamorphic rocks across the gneiss dome corridor. The U-Pb ages of titanite reveal that the Proterozoic geometries of exhumed basement gneiss domes are governed by preexisting Archean structures. Garnet Lu-Hf geochronology constrains the timing of prograde-to-peak metamorphism in the Penokean orogenic belt. Granulite facies metamorphism is related to the final stages of the Penokean orogeny at 1837 Ma and localized in a belt of high-grade rocks near a major Penokean suture. Garnet Lu-Hf ages of samples adjacent to gneiss domes reflect regional metamorphism following the accretionary phase of the Penokean orogeny, between 1825 Ma and 1782 Ma, which we suggest reflects continued crustal thickening related to convergence farther south during this time interval. Combination of garnet microstructures and Sm-Nd ages reflects later exhumation of gneiss domes and buried metasedimentary rocks by ca. 1750 Ma, consistent with previously published 40 Ar/ 39 Ar cooling ages across the region. Reset Lu-Hf and Sm-Nd garnet ages and U-Pb ages of syn-kinematic titanite reflect reactivation of primary Penokean structures during this period of basement uplift. These data document significant modification of the Penokean orogen and the Archean crust of the southern Superior province between 1800 Ma and 1700 Ma. Tectonic activity during this interval coincides with collisional events recognized in western Laurentia, suggesting that the period immediately following the Penokean orogeny may be a broadly important time for crustal growth and modification in proto-North America.
A generalized deep learning model to detect and classify volcano seismicity
Volcano seismicity is often detected and classified based on its spectral properties. However, the wide variety of volcano seismic signals and increasing amounts of data make accurate, consistent, and efficient detection and classification challenging. Machine learning (ML) has proven very effective at detecting and classifying tectonic seismicity, particularly using Convolutional Neural Networks (CNNs) and leveraging labeled datasets from regional seismic networks. Progress has been made applying ML to volcano seismicity, but efforts have typically been focused on a single volcano and are often hampered by the limited availability of training data. We build on the method of Tan et al. [2024] ( 10.1029/2024JB029194 ) to generalize a spectrogram-based CNN termed the VOlcano Infrasound and Seismic Spectrogram Neural Network ( VOISS-Net ) to detect and classify volcano seismicity at any volcano. We use a diverse training dataset of over 270,000 spectrograms from multiple volcanoes: Pavlof, Semisopochnoi, Tanaga, Takawangha, and Redoubt volcanoes\replaced (Alaska, USA); Mt. Etna (Italy); and Kīlauea, Hawai`i (USA). These volcanoes present a wide range of volcano seismic signals, source-receiver distances, and eruption styles. Our generalized VOISS-Net model achieves an accuracy of 87 % on the test set. We apply this model to continuous data from several volcanoes and eruptions included within and outside our training set, and find that multiple types of tremor, explosions, earthquakes, long-period events, and noise are successfully detected and classified. The model occasionally confuses transient signals such as earthquakes and explosions and misclassifies seismicity not included in the training dataset (e.g. teleseismic earthquakes). We envision the generalized VOISS-Net model to be applicable in both research and operational volcano monitoring settings.
Effects of groundwater withdrawals for water bottling and municipal use, Wards Brook Valley, Maine and New Hampshire
Hydrologic models for the Wards Brook valley near Fryeburg, Maine were developed for historical (2016 – 2021) and hypothetical future conditions (2046 – 2065 and 2080 – 2099) to understand the effects of groundwater withdrawals for bottled water and municipal use on hydrologic conditions (stream base flows and groundwater levels). Analyses showed that the simulated base flows in Wards Brook were reduced because of pumping for both municipal water supplies and for water bottling, and about half of the total pumping impact on the base flows in Wards Brook was from the bottled water extraction. Simulated flows were greater than the minimum recommended streamflow of 2,180 cubic meters per day (400 gallons per minute) throughout the historical period. Simulated groundwater levels at two of three nearby ponds (Round Pond and Davis Pond) were minimally affected by pumping conditions, and effects were primarily from the municipal well closest to the ponds. Several estimates of future projected recharge were used to understand the potential effects of groundwater withdrawals on hydrologic conditions under multiple hypothetical climate conditions. Annual projected recharge rates in the mid- and late-21st century from two climate scenarios (stabilized greenhouse-gas emissions and high greenhouse-gas emissions) were similar to rates for 2016 – 2021. However, monthly recharge patterns for the future periods shifted toward more recharge in the winter months (December, January, and February) and less recharge in April, May, and October relative to 2016 – 2021. The lowest mean monthly base flows from the future emission scenarios all remain larger than the minimum recommended streamflow and indicate no long-term declines in flow relative to historical conditions. However, simulated base flows during hypothetical 3-year drought scenarios declined below minimum recommended streamflow during the summer months in the stabilized- and high-emission scenarios in the mid-21st century. Although water is generally plentiful in the Wards Brook valley, reduced pumping may be needed to maintain streamflows in Wards Brook under future climate conditions similar to modeled drought scenarios.
Estimated average annualized losses from potential building damage and fatalities due to earthquake-generated tsunamis in the United States
Earthquake-generated tsunamis represent substantial economic threats to states and territories in the United States (U.S.), but we are unaware of any effort to quantify potential impacts at the national level. This gap is partially due to the lack of nationally consistent data on tsunamigenic sources and associated return periods. This study addresses this issue and provides estimates of average annualized losses (AAL) for potential residential fatalities and capital stock losses associated with building damage (i.e., structural, non-structural, contents, and inventory damage) in the U.S. by curating tsunami-hazard information based on deterministic scenarios and probabilistic approaches, calculating potential losses, and estimating return periods where necessary. This assessment was done for the U.S. West Coast, Alaska, Hawaii, U.S. Pacific Territories, and U.S. Atlantic Territories. We estimate that earthquake-generated tsunamis that could affect these states and territories collectively represent $1 billion in potential AAL with 79 % of losses due to residential fatalities and 21 % of losses due to capital stock losses from building damage. We identify AAL variations based on county and county equivalents, states and territories, geographic regions, return periods, and departure-delay assumptions for evacuating residents. Results include high AAL values for potential fatalities in Puerto Rico and the U.S. Pacific Northwest region, high AAL values for potential building-related damage in Hawaii and California, and high building- and population-loss ratios for county equivalents in Alaska and U.S. territories.
Determination of per- and polyfluoroalkyl substances in water by direct injection of matrix-modified centrifuge supernatant and liquid chromatography/tandem mass spectrometry with isotope dilution
A direct-injection liquid chromatography/tandem mass spectrometry method was developed to determine 34 per- and polyfluoroalkyl substances (PFAS), including selected branched isomers, in centrifuge supernatant of matrix-modified (amended with approximately 50 percent methanol) water samples. The method has been validated in reagent water, surface water, groundwater, and wastewater effluent. Other water types (for example, drinking water, untreated wastewater, and landfill leachate) have been analyzed by the method but not systematically validated. Recovery of isotope-dilution standards, added to each sample, may be used to assess method performance in nonvalidated matrices on a sample-by-sample basis. Using this method, PFAS concentrations were determined in the range of 2–2,000 nanograms per liter in water samples. This range can be extended by diluting concentrated samples. At circumneutral pH, most compounds are present in the environment in their ionized form, and data are reported as such (for example, perfluorooctanoic acid is referred to as “perfluorooctanoate” [PFOA], perfluorooctane sulfonic acid is referred to as “perfluorooctane sulfonate” [PFOS]). Sample preparation procedures were designed without the use of filtration and with minimum sample handling steps to mitigate procedural losses of target compounds due to sorption to surfaces. Further, isotope-dilution quantification allowed for the correction of bias that may result from procedural losses, matrix-induced signal suppression or enhancement, and other factors. Validation experiments to characterize bias and variability, method detection level, and holding time were done in four distinct water matrices—reagent water, surface water, treated wastewater effluent, and groundwater—at multiple concentration levels. Mean PFAS recoveries met data quality objectives of bias and variability studies in all four validation matrices except for two compounds with low and variable recovery in the reagent water matrix only. Isotope-dilution standards, treated as surrogate compounds, were analyzed in more than 1,500 customer-submitted environmental samples with aggregate recovery of 102.5±6.5 percent (mean±standard deviation). Maximum holding times for all target compounds in the four validation matrices were 28 days for refrigerated samples and 90 days for frozen samples.
Comparing magmatism and hydrothermal alteration using magnetic modelling and stable isotopes at the Clementine porphyry copper prospect, Montana, USA
Recent mapping of the underexplored Clementine prospect in southwestern Montana has revealed evidence of hydrothermal alteration and mineralized breccia vein gossan interpreted to represent the upper expression of a Cretaceous, sediment-hosted copper porphyry system. The prospect is at the nexus of several Cretaceous granites, including the pre-mineralization Butte Granite and Big Hole Canyon plutons and local pre- to post-mineralization granite intrusions. Here, 3D magnetic inversions and stable isotope data are used to evaluate the spatial and genetic relationship of mineralization and Cretaceous magmatism. Magnetic inversions reveal a zone of high magnetic susceptibility beneath the prospect that is related to an exposure of unaltered, likely post-mineralization granite. The granite appears to connect to the Big Hole Canyon pluton at depth, suggesting it is a late-stage differentiate of the cooling, pre-mineralization pluton that may have been one of several potential heat sources for the mineral system at Clementine. This is supported by carbon isotope values of graphite that indicate organic material in shale of the Cretaceous Kootenai Formation was subject to metamorphism. Preliminary light hydrogen isotope values of actinolite hydrothermal orbs suggest formation following magmatic outgassing during thermal advection from an underlying intrusion.
Nutrients and pesticides in ground water of the Ozark Plateaus in Arkansas, Kansas, Missouri, and Oklahoma
A total of 229 ground-water samples were collected from 215 sites as part of the Ozark Plateaus study unit of the National Water-Quality Assessment Program. These samples were collected from 1993 through 1995 using a network of springs and wells with three scale-dependent components. The first component, the study-unit survey, consisted of 99 randomly selected springs and domestic wells in the Springfield Plateau and Ozark aquifers. The second component, two land-use studies, consisted of 42 springs and domestic wells in a poultry-dominated agricultural area and 40 springs and domestic wells in a cattle-dominated agricultural area overlying the Springfield Plateau aquifer. The third component, the small-watershed study, consisted of 4 springs, 18 domestic wells, and 11 monitoring wells in a small basin within the poultry land-use study area. Samples were analyzed for major ions, nutrients, dissolved organic carbon, methylene blue active substances, tritium, and 88 pesticides and metabolites.The water-quality data from these samples were analyzed with descriptive and statistical methods. Nitrite plus nitrate, which was detected more often and in greater concentrations than any of the other nutrients, ranged from less than 0.05 to 25 milligrams per liter as nitrogen. Nitrite plus nitrate concentrations positively correlated to percent agricultural land use around each site. Median nitrite plus nitrate concentrations generally were greater in samples from springs than in samples from wells. Concentrations of nitrite, ammonia, and ammonia plus organic nitrogen were also affected by land use and also by concentrations of dissolved oxygen in the ground water. Concentrations of phosphorus and orthophosphate probably were affected by land use and also by phosphorus solubility. Pesticides were detected in 80 of 229 samples from 73 of 215 sites. A total of 20 pesticides were detected with a maximum of 5 pesticides detected in any 1 sample. The most commonly detected pesticides were tebuthiuron, atrazine, prometon, desethylatrazine, and simazine. Maximum concentrations ranged from 0.003 to 1.0 microgram per liter. The occurrence and distribution of pesticides were related to land use. Percent agricultural land use was greater for samples with pesticides detected than for samples with no pesticides detected. Pesticides were detected more often in samples from springs than in samples from wells. The occurrence of pesticides also was related to seasonality and chemical characteristics, such as solubility and persistence, of the compounds.
Forecasting storm-induced coastal flooding for 21st century sea-level rise scenarios in the Hawaiian, Mariana, and American Samoan Islands
Oceanographic, coastal engineering, ecologic, and geospatial data and tools were combined to evaluate the increased risks of storm-induced coastal flooding in the populated Hawaiian, Mariana, and American Samoan Islands as a result of climate change and sea-level rise. We followed a hybrid (dynamical and statistical) downscaling approach to map flooding due to waves and storm surge at 10-square meter resolution along all 1,870 kilometers of these islands’ coastlines for annual (1-year), 20-year, and 100-year return-interval storm events and +0.00 meter (m), +0.25 m, +0.50 m, +1.00 m, +1.50 m, +2.00 m, and +3.00 m sea-level rise scenarios. We quantified the coastal flood depths and extents using the latest climate forcing from Intergovernmental Panel for Climate Change’s Sixth Assessment Report Coupled Model Intercomparison Project. The data generated using these methods provide stakeholders and decision makers with a spatially explicit, rigorous valuation of how, where, and when climate change and sea-level rise increase coastal storm-induced flooding to help identify areas where management and (or) restoration could potentially help reduce the risk to, and increase the resiliency of, the coastal communities in the populated Hawaiian, Mariana, and American Samoan Islands.
Noble and base metal distribution and processes affecting ore tenors in the disrupted lower stratigraphy of the Stillwater Complex, USA
Exploration continues for contact-style Ni-Cu sulfide and chromitite-associated PGE mineralization in ultramafic rocks of the Stillwater Complex. At the Iron and Chrome Mountain areas, massive sulfides occur along the complex’s footwall contact and anomalous concentrations of PGE+Au are associated with the three lowermost chromitite seams. Southeast of Chrome Mountain, magmatic layering is highly disrupted by the presence of faults, magmatic breccias, serpentinized discordant dunites, pyroxenite pegmatoids, and disaggregated chromitite seams. The bulk rock chemistry, sulfide chemistry, and noble metal mineralogy of samples from this area were examined to determine the deportment of PGE and processes that led to enrichments in PGE, Au, Cu, Co and Ni. Results show that a sulfide liquid was the principal collector of PGE. If sulfide liquid was initially deposited with chromite, it was disaggregated or redistributed by subsequent melt or fluid infiltration, which may have resulted in the offset of peak PGE(+Cu, Ni) from peak Cr 2 O 3 concentrations, and upgraded PGE tenors. Upon cooling, PGE exsolved from sulfides to form discrete bismuth tellurides, arsenides, arsenic sulfides, antimonides, and alloys, commonly along the margins of sulfide globules. Calculated metal tenors are highest in the disseminated sulfides southwest of Chrome Mountain, whereas massive and net-textured sulfides near the Iron Mountain-Camp zone represent monosulfide solid solution cumulates. At progressively shallower levels, higher metal tenors combined with lower S/Se ratios are consistent with increasing R-factors from 100 to 100,000. Serpentinization and talc-tremolite alteration resulted in S loss through partial replacement of sulfides by secondary silicate+carbonate+magnetite+sulfide assemblages, further upgrading Ni-Cu-PGE tenors. The present work shows that processes responsible for the disruption of magmatic layering and post-magmatic fluid alteration along the intrusion’s lower contact led to noble and base metal enrichments.