USGS Science⌕ Search

SEARCH · USGS Science

Results for “Chemical Geology”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 469 records · Page 26Linked to original sources

Biosolids, crop, and groundwater data for a biosolids-application area near Deer Trail, Colorado, 2007 and 2008

During 2007 and 2008, the U.S. Geological Survey monitored the chemical composition of biosolids, crops, and groundwater related to biosolids applications near Deer Trail, Colorado, in cooperation with the Metro Wastewater Reclamation District. This monitoring effort was a continuation of the monitoring program begun in 1999 in cooperation with the Metro Wastewater Reclamation District and the North Kiowa Bijou Groundwater Management District. The monitoring program addressed concerns from the public about potential chemical effects from applications of biosolids to farmland in the area near Deer Trail, Colo. This report presents chemical data from 2007 and 2008 for biosolids, crops, and alluvial and bedrock groundwater. The chemical data include the constituents of highest concern to the public (arsenic, cadmium, copper, lead, mercury, molybdenum, nickel, selenium, zinc, and plutonium) in addition to many other constituents. The groundwater section also includes data for precipitation, air temperature, and depth to groundwater at various groundwater-monitoring sites.

Colorado↗

Biosolids, crop, and groundwater data for a biosolids-application area near Deer Trail, Colorado, 2009 and 2010

During 2009 and 2010, the U.S. Geological Survey monitored the chemical composition of biosolids, crops, and groundwater related to biosolids applications near Deer Trail, Colorado, in cooperation with the Metro Wastewater Reclamation District. This monitoring effort was a continuation of the monitoring program begun in 1999 in cooperation with the Metro Wastewater Reclamation District and the North Kiowa Bijou Groundwater Management District. The monitoring program addressed concerns from the public about potential chemical effects from applications of biosolids to farmland in the area near Deer Trail, Colo. This report presents chemical data from 2009 and 2010 for biosolids, crops, and alluvial and bedrock groundwater. The chemical data include the constituents of highest concern to the public (arsenic, cadmium, copper, lead, mercury, molybdenum, nickel, selenium, zinc, and plutonium) in addition to many other constituents. The groundwater section also includes data for precipitation, air temperature, and depth to groundwater at various groundwater-monitoring sites.

Colorado↗

Potential factors controlling benthic algae in the upper White River Basin, Colorado, 2018–21

Nuisance levels of benthic algae are becoming increasingly common in surface waters of the western United States and can compromise aesthetic quality, limit recreational activities, block water infrastructure, and negatively affect aquatic life. In cooperation with the White River and Douglas Creek Conservation Districts, the Colorado River Basin Salinity Control Forum, and the Colorado River Water Conservation District, the U.S. Geological Survey studied physical, chemical, and biological factors potentially controlling the occurrence of benthic algae in the upper White River Basin, Colorado, from 2018 through 2021. Multiple approaches were used to assess nutrients and physical conditions in the upper White River Basin. A linear mixed-effects model was used to evaluate the relative effect of different factors on algal biomass across water-quality sites. The frequency and severity of algal blooms in the upper White River Basin may be affected by long-term changes in nutrient availability and streamflow, specifically changes in the timing and magnitude of high and low streamflow. The effects of large peak streamflow, including movement of the streambed, may be the dominant control on the occurrence of algal blooms through years. Large, late, and long-lasting peak streamflow may limit algal blooms during the same year and into subsequent years. Without streambed disturbance, other factors such as nutrients and water temperature may have a larger effect on algal biomass.

Colorado↗

Water-quality data of lakes and wetlands in the Yukon Flats, Alaska, 2007–2009

Over a three-year period (2007–2009), in-situ measurements were taken and water-quality samples were collected from 111 lakes and wetlands located in the Yukon Flats, Alaska, during a U.S. Fish and Wildlife Service wetlands inventory. The U.S. Geological Survey performed the chemical analyses on the retrieved water-quality samples. Results from the analyses of water samples for dissolved carbon gases and carbon isotopes, hydrogen and oxygen stable isotopes, dissolved organic carbon, and major cations and anions, along with supporting site data, are presented in this report.

Alaska↗

Ground-water quality in selected areas serviced by septic tanks, Dade County, Florida

During 1971-74, the U.S. Geological Survey investigated the chemical, physical, bacteriological, and virological characteristics of the ground water in five selected areas serviced by septic tanks in Dade County, Florida. Periodic water samples were collected from multiple-depth groups of monitor wells ranging in depth from 10 to 60 ft at each of the five areas. Analyses of ground water from base-line water-quality wells in inland areas remote from urban development indicated that the ground water is naturally high in organic nitrogen, ammonia, organic carbon and chemical oxygen demand. Some enrichment of ground water with sodium provided a possible key to differentiating septic-tank effluent from other urban ground-water contaminant sources. High ammonia nitrogen, phosphorus, and the repetitive detection of fecal coliform bacteria were characteristic of two 10-foot monitor wells that consistently indicated the presence of septic-tank effluent in ground water. Dispersion, dilution, and various chemical processes have presumably prevented accumulation of septic-tank effluent at depths greater than 20 ft, as indicated by the 65 types of water analyses used in the investigation. Fecal coliform bacteria were present on one or two occasions in many monitor wells but the highest concentration, 1,600 colonies/100 ml, was related to storm-water infiltration rather than septic-tank discharge. Areal variations in the composition and the hydraulic conductivity of the sand and limestone aquifer had the most noticeable influence on the overall ground-water quality. The ground water in the more permeable limestone in south Dade County near Homestead contained low concentrations of septic-tank related constituents, but higher concentrations of dissolved sulfate and nitrate. The ground water in north Dade County, where the aquifer is less permeable, contained the highest dissolved iron, manganese, COD, and organic carbon.

Florida↗

Geology, hydrology, and groundwater contamination in the vicinity of Central Chemical facility, Hagerstown, Maryland

The soil and groundwater at the Central Chemical facility, Hagerstown, Maryland, are contaminated due to the blending and production of pesticides and fertilizers during much of the 20th century. Remedial investigations focus on two operable units (OU) consisting of the surface soils and waste disposal lagoon (OU-1) and the groundwater (OU-2). The contaminants of concern (COC) for groundwater include 41 compounds categorized within the subgroups of volatile organic compounds (VOCs), semi-volatile organic compounds (SVOCs), pesticides, and metals. The purpose of this report is to provide a conceptual site model of the hydrogeology and groundwater contaminant transport at and near the Central Chemical facility. The conceptual model was developed through review, synthesis, and interpretation of the results of hydrogeologic, soil, and other environmental investigations conducted at and in the vicinity of the facility in recent decades and is intended to support plans for environmental remediation of the groundwater in OU-2. The extent and nature of the groundwater contaminant plume associated with the bedrock was characterized for OU-2 of the site. Lithologic and structural comparisons between shallow soil, weathered rock, and epikarst and deeper competent but bedded, dipping, fractured, and karstic limestones illustrate two connected flow systems—a surficial flow system consisting of the unconsolidated overburden and epikarst and a structurally dominant bedrock flow system below the epikarst. Uncertainties exist regarding the nature and transport of contaminants within the epikarst system particularly within voids and perched epikarst water tables. Karst dissolution features are observed within the site including sinkholes and dissolution voids within wells at the site. Of interest, one well in the northern part of the study area (MW-J-71) appears to have a dissolution void connected to an offsite well (OW-2-115) farther to the north. This connection is supported by groundwater level data and elevated concentrations of total suspended solids (TSS) and chlorobenzene in both wells. The high level of TSS supports the possibility of offsite transport of particle-bound contaminants within the conduit system. Episodically elevated concentrations of COC from different groups also were observed within select wells in the epikarst near the waste disposal lagoon (particularly MW-A-51). The variability observed between different COC within the same well may be the result of additional contaminated source materials unrelated to the disposal lagoon. Storage and episodic transport of contaminated material within the epikarst system has the potential to hinder remediation efforts if not considered in the remedial action.

Maryland↗

Availability and quality of ground water in the Winston area, Douglas County, Oregon

A map of the Winston area, Douglas County, Oreg., shows areal geology and locations and chemical diagrams of wells with water analyses. Another map of the area has diagrams showing the depth to water, pumping level, total depth, and yields of selected wells. Reported yields of wells range from less than 1 to as much as 70 gallons per minute; the average is less than 10. A table listing chemical analyses of water shows that, although most ground water is of adequate quality for domestic use, some wells yield water with dissolved constituents in excess of recommended limits. (Woodard-USGS)

Oregon↗

Chemical analyses of coal from the Emery and Ferron Sandstone members of the Mancos Shale, Henry Mountains Field, Wayne and Garfield counties, Utah

As part of a continuing program by the U.S. Geological Survey to collect and chemically analyze representative samples of U.S. coals, 18 samples were collected from the Upper Cretaceous Emery and Ferron Sandstone Members of the Mancos Shale in the Henry Mountains coal field, Wayne and Garfield Counties, Utah (fig. 1). The 18 samples are briefly described in table 1. Thirteen of these samples were collected from seven holes that were drilled in connection with the Henry Mountains EMRIA (Energy Mineral Rehabilitation Inventory and Analyses) study (U.S. Department of the Interior, 1978). The locations of the seven core holes and the four other sampling sites are shown on figure 2. The Henry Mountains coal field is adjacent to the Henry Mountains of southeastern Utah. The basin is a long, narrow syncline about 110 km long and 24 km wide bounded on the west by the Waterpocket Fold and on the east by the Henry Mountains. The most comprehensive geologic report available on the area is by Hunt and others (1953). Their work included a considerable amount of information on the coal resources. Other work in the area concerning coal or stratigraphy of coal bearing units includes: Doelling (1972), Peterson and Ryder (1975), Doelling (1975), Law (1977; 1978; 1979 a,b), and U.S. Department of the Interior (1978). In the Henry Mountains field, there are three coal bearing units in rocks of Late Cretaceous age. In ascending order they are the Dakota Sandstone, the Ferron Sandstone Member of the Mancos Shale, and the Emery Sandstone Member of the Mancos Shale. The coal beds of the Henry Mountains coal field originated as layers of peat that were deposited, for the most part, in coastal swamp environments. Individual coal beds are discontinuous and exhibit large variations in thickness and quality. The thickest and most continuous coal beds occur in the Emery Sandstone Member along or near the axis of the Henry Mountains syncline (Law, 1978).

Utah↗

Chemical analyses of coal and coal-associated rock samples from the Coalmont Formation, McCallum and Coalmont areas, North Park, Jackson County, Colorado

As part of a continuing program by the U.S. Geological Survey to collect and chemically analyze representative samples of U.S. coals, 44 coal and coal-associated rock samples were collected from the Paleocene and Eocene, Coalmont Formation in the McCallum and Coalmont areas, North Park, Jackson County, Colorado. Twenty-eight samples (24 coal and 4 coal-associated rock) are from the McCallum area and 16 samples (12 coal and 4 coal-associated rock) are from the Coalmont area. Locations of ten core holes and three mines where the samples were collected, and an outline of North Park are shown on figure 1. The 44 samples are briefly described in table 1.

Colorado↗

Geology and ground-water resources of North Dakota, with a discussion of the chemical character of the water

Water is the most valuable of the mineral resources. The study of ground waters is therefore clearly within the field of economic geology and constitutes an important part of the work of the geological surveys, both State and national, as defined by law. In the spring of 1911 the investigation of the ground waters of North Dakota was begun by the North Dakota Geological Survey, and the work was assigned to the author of this paper. During each of the three summers 1911, 1912, and 1913 several weeks were devoted by the author to the field work of a general survey. A report on the ground waters of the State was then prepared by him and was transmitted by the director of the North Dakota Geological Survey to the State printing commission for publication. However, owing to lack of available funds the report was not published. A portion of the summer of 1914 was given to a study of artesian conditions in the Souris River Basin. Since that time considerable work has been done in connection with detailed surveys made for a number of cities and villages in an effort to obtain the best available supply of water for public use. During the summer of 1920 arrangements were made by the United States Geological Survey with the North Dakota Geological Survey whereby the author completed the work as fully as possible by correspondence and brought the report up to date. In the spring of 1921 samples of water from 196 sources were collected by the author and J. H. Buchanan and were sent to the United States Geological Survey for analysis. Most of these samples were analyzed by H. B. Riffenburg, who has used the analyses for a description of the chemical character of ground waters in the State. In addition to the analyses of samples collected in connection with the preparation of this report, over 700 partial analyses from different sources were examined. These analyses are not given in this paper, because the location of many of the wells was not stated definitely, and most of the analyses were incomplete. They were useful, however, in confirming the conclusions based on the analyses that are printed, particularly for counties where only a few samples were collected for this report.

North Dakota↗

Chemical analyses of coal and coal-associated rock samples from the Rosebud and McKay coal beds, Tongue River Member of the Fort Union Formation, Colstrip coal deposit, Rosebud County, Montana

As part of a continuing program by the U.S. Geological Survey to collect and chemically analyze representative samples of U.S. coals, 61 coal and coal-associated rock samples were collected from the Rosebud and McKay beds in the Paleocene Tongue River Member of the Fort Union Formation in Rosebud County, Montana. This area is located in the Montana part of the Powder River region, specifically within the Coistrip coal deposit as defined by Matson and Blumer, 1974. Forty of the samples (36 coal and 4 coal-associated rock) are from the Rosebud bed and 21 samples (all coal) are from the McKay bed. The McKay bed is between 5.5 and 18.6 m. below the Rosebud bed. The samples were collected from the Big Sky Mine and from 13 core holes in sec. 1, 2, and 27, T. 1 N., R. 41 E.; sec. 23 and 35, T. 2 N., R. 41 E.; and in sec. 1, 3, 5, 9, 15, and 16, T. 1 N., R. 40 E. The location of the sample collection area is shown in figure 1. Brief descriptions of all 61 samples are listed in table 1 and locations of sampling sites are shown in figure 2. Estimated strippable coal resources for the Rosebud bed in this area exceed 1,305 metric tons (1,439 million short tons) (Matson and Blumer, 1974). There are currently no estimates of coal resources for the McKay bed from this area. Analyses of samples D172034 through D172051 have previously been published in Swanson and others (1976) and are included here in order to provide a more complete data listing. For additional information on sulfur and trace element contents in the Rosebud and McKay coal beds, see Chadwick, Woodriff and others (1975) and Chadwick, Rice and others (1975).

Montana↗

Chemical analyses of coal from the Tongue River Member of the Fort Union Formation, Moorhead and southeastern part of the northward extension of the Sheridan coal fields, Powder River and Big Horn counties, Montana

As part of a continuing program by the U.S. Geological Survey to collect and chemically analyze representative samples of U.S. coals, 83 samples were collected from 23 core holes in the Paleocene Tongue River Member of the Fort Union Formation in Big Horn and Powder River counties, Montana. These holes are located in the Montana part of the Powder River coal region, specifically in the western part of the Moorhead coal field and on the eastern margin of the Northward Extension of the Sheridan coal field (fig. 1)

Montana↗

Industrial limestones and dolomites in Virginia: northern and central parts of the Shenandoah Valley

The area described in this report includes the northern and central parts of Shenandoah Valley in Virginia extending from the West Virginia line southwestward to the vicinity of Greenville, Augusta County. It contains extensive deposits of high-calcium limestone averaging more than 97 per cent calcium carbonate. The Mosheim limestone, composed largely of high-calcium limestone, is the important "quarry rock" of the area. Other formations containing high-calcium limestone include locally a part of the Lenoir, the upper part of the Chambersburg in the western belts of Shenandoah County, and relatively thin units in the Beekmantown along the eastern side of the Massanutten Mountain syncline north of Rockingham County. Some of the thickest deposits of high-calcium limestone near railroads are in Frederick, Shenandoah, Rockingham, and Augusta counties. Extensive exposures of the Tomstown (Shady) dolomite, containing more than 42 per cent magnesium carbonate, occur in the eastern part df Clarke County. Locally near the North Mountain fault in parts of Shenandoah and Rockingham counties, 80 feet or more of brecciated dolomite in the Elbrook formation contains about 43.5 per cent magnesium carbonate and generally less than 2 per cent silica. Most of the sampled dolomite units in the Elbrook, Conococheague, and Beekmantown formations contain less than 40 per cent magnesium carbonate. Special study was made of the carbonate rocks suitable for chemical use and favorably located near railroads. Limestones, containing less than 95 per cent calcium carbonate, were studied locally in some detail. Descriptions of the belts of industrial limestone and dolomite are supplemented by geologic maps and sections, and chemical analyses.

Virginia↗

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of nonpurgeable suspended organic carbon by wet-chemical oxidation and infrared spectrometry

Precision and accuracy results are described for the determination of nonpurgeable suspended organic carbon (SOC) by silver-filter filtration, wet-chemical oxidation, and infrared determination of hte resulting carbon dioxide (CO2) used at the U.S. Geological Survey's nationalWater Quality Laboratory. An aliquot of raw water isfiltered through a 0.45-micrometer silver filter. The trapped organic material is oxidized using phosphoric acid and potassium persulfate in a scaled glass ampule,and the rseulting CO2 is measured by an infrared CO2 detector. The amount of CO3 is proportional to the concentration of chemically oxidizable nonpurgeable organic carbon in the sample. The SOC method detection limit for routine analysis is 0.2 milligram per liter. The average percent recovery is 97.1 percent and the average standard deviation is 11 percent.

Open-File Report↗

Chemical hydrogeology in natural and contaminated environments

Chemical hydrogeology, including organic and inorganic aspects, has contributed to an increased understanding of groundwater flow systems, geologic processes, and stressed environments. Most of the basic principles of inorganic-chemical hydrogeology were first established by investigations of organic-free, regional-scale systems for which simplifying assumptions could be made. The problems of groundwater contamination are causing a shift of emphasis to microscale systems that are dominated by organic-chemical reactions and that are providing an impetus for the study of naturally occurring and manmade organic material. Along with the decrease in scale, physical and chemical heterogeneity become major controls. Current investigations and those selected from the literature demonstrate that heterogeneity increases in importance as the study site decreases from regional-scale to macroscale to microscale. Increased understanding of regional-scale flow systems is demonstrated by selection of investigations of carbonate and volcanic aquifers to show how applications of present-day concepts and techniques can identify controlling chemical reactions and determine their rates; identify groundwater flow paths and determine flow velocity; and determine aquifer characteristics. The role of chemical hydrogeology in understanding geologic processes of macroscale systems is exemplified by selection of investigations in coastal aquifers. Phenomena associated with the mixing zone generated by encroaching sea water include an increase in heterogeneity of permeability, diagenesis of minerals, and formation of geomorphic features, such as caves, lagoons, and bays. Ore deposits of manganese and uranium, along with a simulation model of ore-forming fluids, demonstrate the influence of heterogeneity and of organic compounds on geochemical reactions associated with genesis of mineral deposits. In microscale environments, importance of heterogeneity and consequences of organic reactions in determining the distribution and concentrations cf. constituents are provided by several studies, including infiltration of sewage effluent and migration of creosote in coastal plain aquifers. These studies show that heterogeneity and the dominance of organically controlled reactions greatly increase the complexity of investigations.Current investigations and those selected from the literature demonstrate that heterogeneity increases in importance as the study site decreases from regional-scale to macroscale to microscale. Increased understanding of regional-scale flow systems is demonstrated by selection of investigations of carbonate and volcanic aquifers to show how application of present-day concepts and techniques can identify controlling chemical reactions and determine their rates; identify groundwater flow paths and determine flow velocity; and determine aquifer characteristics. The role of chemical hydrogeology in understanding geologic processes of macroscale systems is exemplified by selection of investigations in coastal aquifers. Ore deposits of manganese and uranium, along with a simulation model of ore-forming fluids, demonstrate the influence of heterogeneity and of organic compounds on geochemical reactions associated with genesis of mineral deposits. In microscale environments, importance of heterogeneity is illustrated by studies of infiltration of sewage effluent and migration of creosote in coastal plain aquifers.

Journal of Hydrology↗

Investigation of coal deposits in the Fairview and Coal City basins, Coosa Field, St. Clair County, Ala.: reserves, petrography, and chemical properties of coals: washability characteristics of coal from Fairview bed: geology of area

Report issued by the Bureau of Mines discussing the coal deposits in Saint Clair County, Alabama. Investigations of the estimated reserves and analyses of the coal fields in this area are presented. This report includes tables, maps, illustrations, and photographs.

Alabama↗

Chemical quality of surface waters, and sedimentation in the Grand River drainage basin, North and South Dakota

An investigation of the chemical quality of surface waters and of the sedimentation in the Grand River drainage basin by the U.S. Geological Survey began in 1946. The chemical quality of the water was studied to obtain information on the nature and amounts of dissolved solids in the streams and on the suitability of the water for domestic, industrial, and irrigation uses. Sedimentation was studied to determine the quantity of sediment that is transported by the streams, the particle sizes of the sediment, and the probable specific weight of the sediment when deposited in a reservoir. The basin is underlain by consolidated sedimentary rocks of Cretaceous and Tertiary age; along the Grand River and its tributaries thefe rocks are mantled by alluvium of Quaternary age. The Hell Creek and Fort Union Formations underlie about 4,700 of the 5,680 square miles of drainage area. The climate of the basin is semiarid and is characterized by tot summers and cold winters. Mean annual runoff is about 53 acre-feet per square mile of drainage area and is equal to about 7 percent of the mean annual precipitation. The highest streamflows on the Grand River and major- tributaries are caused by melting of snow in March and April. Streamflow is extremely variable from year to year. Most of the surface waters in the basin are of the sodium sulfate or sodium bicarbonate type. High percent sodium is typical of almost all the surface water's. The streamflow-quality patterns of the Grand River and its two forks are very similar; dissolved-solids concentration, which usually c'oes not exceed 3,000 ppm, is maximum during low-flow periods. The water in Shadehill Reservoir became stratified during the flood inflow of 1952; about 75 percent of the flood water, which was of good qutlity, passed through the reservoir. The quality of the water became almost uniform throughout the reservoir the latter part of July 1952. After the specific conductance became relatively stable in 1956, it fluctuated from abrut 1,300 to 1,600 micromhos per centimeter and was between 1,400 and 1,500 rnicromhos per centimeter most of the time. During the representative period July 1937 to June 1950 the quantity of dissolved solids passing the station near Wakpala was estimated to have been about 140,000 tons per year. Yields computed for different parts of the basin ranged from about 22 to 32 tons per square mile. Except for sulfate, concentrations of chemical constituents usually do not exceed the maximum concentrations recommended for domestic supplies. The rather high dissolved solids and hardness of most of the surface waters prevent the use of these waters for most industrial purposes unless the quality is improved by treatment. Classified for irrigation use according to its specific conductance and sodiumadsorption-ratio, the water stored in Shadehill Reservoir has a high salinity hazard and a medium sodium hazard. The water can be used safely forsustained irrigation on soils of the proposed irrigation unit if adequate teaching is practiced and if gypsum or some other calcium compound is added to the water or land during the high sodium cycle.

North Dakota, South Dakota↗