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At least 469 records · Page 26Linked to original sources
USGS1974

Hydrologic analysis of the Mojave River, California, using a mathematical model

The channel of the Mojave Rive'r in California is normally dry and is highly permeable over much of its length, and large quantities of water from natural floodflows in the channel infiltrate through the channel bed to the underlying ground-water body. From 1930 to 1972 only 18 floods at The Forks produced flow at Barstow, 55 miles (88 kilometres) downstream from The Forks. Peak discharges at Barstow from these floods ranged from 180 cubic feet per second (5 cubic metres per second) in 1967 to 64,300 cubic feet per second (1,820 cubic metres per second) in 1938. Total stream infiltration, primarily as ground-water recharge, ranged from 3,600 acre-feet (4.40 cubic hectometres) in 1935 to 50,400 acre-feet (62.1 cubic hectometres) in 1969 between The Forks and Victorville and from about 7,000 acre-feet (8.61 cubic hectometres) in 1935 to 128,000 acre-feet (158 cubic hectometres) in 1969 between Victorville and Barstow. The Mojave Water Agency is considering the use of the channel of the river to convey water imported from northern California through Silverwood Reservoir (5 miles or 8 kilometres upstream from The Forks) downstream to the Barstow area. The imported water would be used to replenish aquifers underlying the Barstow area. A mathematical model was developed that simulates the advance of discharge down the initially dry channel of the Mojave River, and the model was used to evaluate the potential of the channel to move imported water downstream to Barstow. Results of simulation by modeling indicate that the channel of the Mojave River can be used to efficiently convey imported water to Barstow only when the absorption capacity of the channel has been reduced by an antecedent flood. The volume of imported water that can reach Barstow depends on the volume and duration of the antecedent flood, on the volume of imported water released trom Silverwood Reservoir, and on the rate at which imported water is released. A release of 20,000 acre-feet (24.6 cubic hectometres) of imported water may produce at Barstow a maximum volume of imported water of 2,500, 8,000, 11,000, or 15,000 acre-feet (3.08, 9.86, 13.6, or 18.4 cubic hectometres) for a release rate of 500, 750, 1,000, or 2,000 cubic feet per second (14.2, 21.2, 28.3, or 56.8 cubic metres per second). For planning purposes in evaluating some of the hydraulic effects of recharge on the aquifer, a simulation of the aquifer near the Barstow area using an electrical analog model showed that a combination of no pumping and a yearly recharge of 5,000 acre-feet (6.17 cubic hectometres) for 10 years could raise ground-water levels at least 10 feet (3 metres) over an area of about 10 square miles (25 square kilometres). To obtain the water-level changes due to the combined effects of pumping and recharge, the above water-level changes should be superimposed on the separate effects of pumping.

California↗
USGS2019

Mountain-block recharge: A review of current understanding

Mountain-block recharge (MBR) is the subsurface inflow of groundwater to lowland aquifers from adjacent mountains. MBR can be a major component of recharge but remains difficult to characterize and quantify due to limited hydrogeologic, climatic, and other data in the mountain block and at the mountain front. The number of MBR-related studies has increased dramatically in the 15 years since the last review of the topic was conducted by Wilson and Guan (2004), generating important advancements. We review this recent body of literature, summarize current understanding of factors controlling MBR, and provide recommendations for future research priorities. Prior to 2004, most MBR studies were performed in the southwestern United States. Since then, numerous studies have detected and quantified MBR in basins around the world, typically estimating MBR to be 5–50% of basin-fill aquifer recharge. Theoretical studies using generic numerical modeling domains have revealed fundamental hydrogeologic and topographic controls on the amount of MBR and where it originates within the mountain block. Several mountain-focused hydrogeologic studies have confirmed the widespread existence of mountain bedrock aquifers hosting considerable groundwater flow and, in some cases, identified the occurrence of interbasin flow leaving headwater catchments in the subsurface—both of which are required for MBR to occur. Future MBR research should focus on the collection of high-priority data (e.g., subsurface data near the mountain front and within the mountain block) and the development of sophisticated coupled models calibrated to multiple data types to best constrain MBR and predict how it may change in response to climate warming.

Water Resources Research↗
USGS2002

The effects of atmospheric nitrogen deposition in the Rocky Mountains of Colorado and southern Wyoming— A synthesis and critical assessment of published results

The Rocky Mountain region of Colorado and southern Wyoming receives as much as 7 kilograms per hectare per year ((kg/ha)/yr) of atmospheric nitrogen (N) deposition, an amount that may have caused changes in aquatic and terrestrial life in otherwise pristine ecosystems. The Rocky Mountain National Park, in its role of protecting air-quality related values under provisions of the Clean Air Act Amendments of 1977, has provided support for this synthesis and critical assessment of published literature on the effects of atmospheric N deposition. Results from published studies indicate a long-term increase in the rate of atmospheric N deposition during the 20th century, but no region-wide increase during the past 2 decades, although the rate of atmospheric N deposition has increased at three sites east of the Continental Divide in the Front Range region since the mid-1980s. Much of the increase in atmospheric N deposition at all three sites has resulted from an increase in the ammonium concentrations of wet deposition; this suggests an increase in contributions from agricultural areas or from vehicle traffic east of the Rocky Mountains. Lakes at two study sites in the Front Range (Loch Vale and Green Lakes Valley) had NO 3 - concentrations of 30 to 40 micromoles per liter (µmol/L) during early spring snowmelt and remained at 5 to 10 µmol/L during summer. Retention of N in atmospheric wet deposition in some sub-catchments of these lakes was less than 50 percent, which reflects an advanced stage of N saturation. Nitrate concentrations in surface waters west of the Continental Divide were lower—often less than 10 µmol/L during snowmelt and less than 2 µmol/L during summer -- than surface waters east of the Divide, except in areas such as the Mt. Zirkel Wilderness that receive elevated amounts of atmospheric N deposition of 4 to 5 (kg/ha)/yr. Atmospheric N deposition in the Front Range east of the Divide may have altered the composition of alpine tundra-plant communities and lake diatoms, but additional studies would be needed to definitively demonstrate the hypothesized cause-and-effect relations. Rates of N-mineralization and nitrification in soils of the Front Range have increased in response to increased atmospheric N deposition. Projected future population growth and energy use in Colorado and the west increase the likelihood that the subtle effects of atmospheric N deposition now evident in the Front Range will become more pronounced and widespread in the future. The likelihood of future increased N emissions along the Front Range warrants a continuation of existing long-term precipitation and surface-water chemistry monitoring programs, and an expansion of the networks into areas that receive large amounts of atmospheric N deposition, but currently lack adequate monitoring. Long-term study and expanded sampling are needed to address uncertainties about the effects of atmospheric N deposition on terrestrial plant communities, nutrient limitation in lake plankton, shifts of dominant species within diatom communities, and on amphibian response to episodic surface-water acidification.

Colorado, Wyoming↗
USGS2007

Earth science and public health: Proceedings of the Second National Conference on USGS Health-Related Research

The mission of the U.S. Geological Survey (USGS) is to serve the Nation by providing reliable scientific information to describe and understand the earth; minimize loss of life and property from natural disasters; manage water, biological, energy, and mineral resources; and enhance and protect our quality of life. As the Nation?s largest water, earth, and biological science and civilian mapping agency, the USGS can play a significant role in providing scientific knowledge and information that will improve our understanding of the relations of environment and wildlife to human health and disease. USGS human health-related research is unique in the Federal government because it brings together a broad spectrum of natural science expertise and information, including extensive data collection and monitoring on varied landscapes and ecosystems across the Nation. USGS can provide a great service to the public health community by synthesizing the scientific information and knowledge on our natural and living resources that influence human health, and by bringing this science to the public health community in a manner that is most useful. Partnerships with health scientists and managers are essential to the success of these efforts. USGS scientists already are working closely with the public health community to pursue rigorous inquiries into the connections between natural science and public health. Partnering agencies include the Armed Forces Institute of Pathology, Agency for Toxic Substances Disease Registry, Centers for Disease Control and Prevention, U.S. Environmental Protection Agency, Food and Drug Administration, Mine Safety and Health Administration, National Cancer Institute, National Institute of Allergy and Infectious Disease, National Institute of Environmental Health Sciences, National Institute for Occupational Safety and Health, U.S. Public Health Service, and the U.S. Army Medical Research Institute of Infectious Diseases. Collaborations between public health scientists and earth scientists can lead to improved solutions for existing and emerging environmental health problems. This report summarizes the presentations and discussions held at the Second National Conference on USGS Health-Related Research, held at the USGS national headquarters in Reston, Virginia. The report presents 68 abstracts of technical presentations made at the conference and summaries of six topical breakout sessions. The abstracts cover a broad range of issues and demonstrate connections between human health and the quality and condition of our environment and wildlife. The summaries of the topical breakout sessions present ideas for advancing interdisciplinary science in areas of earth science and human health.

Scientific Investigations Report↗
USGS1935

Geology and ground-water resources of the island of Oahu, Hawaii

Oahu, one of the islands of the Hawaiian group, lies in the Mid-Pacific 2,100 miles southwest of San Francisco. The principal city is Honolulu. The Koolau Range makes up the eastern part of the island, and the Waianae Range the western part. Both are extinct basaltic volcanoes deeply dissected by erosion. The Koolau Volcano was the later to become extinct. The Waianae Range is made up of three groups of lavas erupted in Tertiary and possibly in early Pleistocene time. The exposed part of the older lava is nearly 2,000 feet thick and consists largely of thin-bedded pahoehoe. It is separated in most places from the middle lavas by an angular unconformity and talus breccia and in a few places by an erosional unconformity. The middle basalts are about 2,000 feet thick and closely resemble the lower ones except that they contain more aa. The upper lavas reach a thickness of about 2,300 feet and are mostly massive aa flows. The last eruptions produced large cinder cones and some nephelite basalts. The Waianae Volcano, like other Hawaiian volcanoes, produced only small amounts of ash, and the lavas were largely extruded from fissures a few feet wide, now occupied by dikes. The center of activity was near Kolekole Pass, at the head of Lualualei Valley. The Koolau Volcano is made up of two groups of lavas extruded in Tertiary and early Pleistocene (?) time. The older group, the Kailua volcanic series, is greatly altered by hydrothermal action and was extruded from fissures near Lanikai. The flows of the younger group, the Koolau volcanic series, were extruded from fissures about a mile south of the Kailua rift and have an exposed thickness of about 3,000 feet. The Koolau Volcano produced even less ash than the Waianae Volcano, and its flows are thin-bedded pahoehoe and aa. The eruptive center of the Koolau Volcano lies between Kaneohe and Waimanalo. Great amounts of both the Waianae and Koolau Ranges were removed by fluvial and marine erosion during the Pleistocene. The master streams are characterized by deep amphitheater-headed valleys. After this erosion cycle the island was submerged more than 1,200 feet, and these great valleys were drowned and alluviated. Besides this submergence, several strand lines, preserved up to 100 feet above present sea level occur, which may be due to world-wide changes in sea level in response to the withdrawal and restoration of water concurrent with the advances and recessions of the polar ice caps and to accompanying changes in the ocean floor. During this time of shifting ocean levels spasmodic eruptions occurred on the southeast end of the Koolau Range, producing numerous lava flows and tuff cones, most of which are nephelite basalt. The last of these eruptions occurred in Recent time. A description of the climate, rates of run-off, and results of experiments to determine evaporation and transpiration in the areas of high rainfall are given. It was found that the consumptive use decreases materially and becomes a very small percentage of the rainfall in the areas of high precipitation. The lava rocks of the island are very permeable and, because of a rainfall reaching a maximum of 300 inches a year, carry large amounts of ground water, confined and unconfined, basal and perched. The basal ground water floats on salt water because of its lower specific gravity. Consequently for each foot the water table stands above sea level, salt water lies about 42 feet below sea level, in accordance with the sea along the coast as basal ground water. In most places the lava rocks along the shore are overlain by an impermeable or nearly impermeable caprock consisting of submerged lateritic soils and marine noncalcareous sediments. These deposits retard the escape of basal ground water into the sea and give rise to artesian water, but unlike most other artesian systems, this one has no lower restraining formation. The artesian water is the principal source of domestic, municipal, and irrigation supplies. The average annual quantity pumped for the period 1928 to 1933 amounted to about 105,000,000,000 gallons, nearly 90 percent of which came from Koolau hasalt and the remainder from Waianae basalt. There are ten artesian areas in the Koolau Range and two in the Waianae Range. Hydraulic gradients in these basins were found to range from 1.2 to 3 feet to the mile. Because of these extremely flat gradients and the high permeability of the aquifers it is possible to reverse the hydraulic gradients by draft and make the water flow from one artesian area to another. The artesian water levels fluctuate in response to seasonal variations in draft and recharge and in a lesser way to tidal, barometric, and seismic pressures. The water, as shown by chemical analysis, is of excellent quality except where it is contaminated with sea water. Methods have been devised for freshening wells that have gone salty, for detecting leaks, for sealing leaky and defective wells, and for recharging the artesian basins. Owing to the danger of the wells becoming brackish with increased draft, it is believed that further large developments will be more successful if shafts are sunk to sea level in the basalt as far inland as practicable, and tunnels are driven from the bottom of the shafts near the top of the saturated zone. Favorable places for such development exist in Honolulu. In addition to the basal water in the volcanic rocks, water is found in the recent gravel, beach, and dune deposits, and the emerged reef limestone. This water has been recovered by wells and tunnels, and there are favorable localities for developing additional water of this type. The island contains two types of basal springs—those like the Pearl Harbor Springs, which issue from basalt and are supplied by overflow and leakage from the artesian basin, and those which issue from the coastal-plain sediments and are mainly return irrigation water. The total quantity of basal ground water issuing as springs is estimated to be 100,000,000 gallons a day. Ground water occurs at high levels, confined by dikes and perched on tuff, alluvium, and soil beds. These structures give rise to innumerable high-level springs. In the Koolau Range 60 tunnels yield about 33,000,000 gallons daily, of which about 95 percent is obtained from tunnels penetrating the dike complex of the Koolau volcanic series, about 2 percent from tunnels entering post-Koolau ash or tuff deposits, and the remainder from tunnels whose geologic relations are not certainly known. The average daily yield of the tunnels that recover dike water is 2,330 gallons a foot, but the average daily yield of the tunnels in post-Koolau tuff is 450 gallons a foot, and that of the tunnels in alluvium or soil is only 23 gallons a foot. Owing largely to the much lower rainfall on the Waianac Range, its 35 tunnels (not including two new tunnels under construction) yield only about 2,400,000 gallons daily, about 94 percent of which is believed to be obtained from dike systems. The average daily yield of the tunnels in this range that are supplied by dike systems is 581 gallons a foot, as compared to 5 gallons a foot from tunnels in ash or tuff. An extensive tunnel system is proposed to develop a large supply of high-level water for Honolulu from the dike complex of the Koolau series, and high-level water can be recovered by tunnels at many other places. The average daily discharge of all high-level springs in the Koolau Range is about 58,000,000 gallons, of which about 94 percent comes from the Koolau dike complex and about 6 percent from post-Koolau volcanic rocks. The average daily discharge of all high-level springs in the Waianae Range is about 500,000 gallons of which about 81 percent issues from the dike complex.

Hawaii↗
USGS2012

Development of a flood-warning system and flood-inundation mapping in Licking County, Ohio

Digital flood-inundation maps for selected reaches of South Fork Licking River, Raccoon Creek, North Fork Licking River, and the Licking River in Licking County, Ohio, were created by the U.S. Geological Survey (USGS), in cooperation with the Ohio Department of Transportation; U.S. Department of Transportation, Federal Highway Administration; Muskingum Watershed Conservancy District; U.S. Department of Agriculture, Natural Resources Conservation Service; and the City of Newark and Village of Granville, Ohio. The inundation maps depict estimates of the areal extent of flooding corresponding to water levels (stages) at the following USGS streamgages: South Fork Licking River at Heath, Ohio (03145173); Raccoon Creek below Wilson Street at Newark, Ohio (03145534); North Fork Licking River at East Main Street at Newark, Ohio (03146402); and Licking River near Newark, Ohio (03146500). The maps were provided to the National Weather Service (NWS) for incorporation into a Web-based flood-warning system that can be used in conjunction with NWS flood-forecast data to show areas of predicted flood inundation associated with forecasted flood-peak stages. As part of the flood-warning streamflow network, the USGS re-installed one streamgage on North Fork Licking River, and added three new streamgages, one each on North Fork Licking River, South Fork Licking River, and Raccoon Creek. Additionally, the USGS upgraded a lake-level gage on Buckeye Lake. Data from the streamgages and lake-level gage can be used by emergency-management personnel, in conjunction with the flood-inundation maps, to help determine a course of action when flooding is imminent. Flood profiles for selected reaches were prepared by calibrating steady-state step-backwater models to selected, established streamgage rating curves. The step-backwater models then were used to determine water-surface-elevation profiles for up to 10 flood stages at a streamgage with corresponding streamflows ranging from approximately the 50 to 0.2-percent chance annual-exceedance probabilities for each of the 4 streamgages that correspond to the flood-inundation maps. The computed flood profiles were used in combination with digital elevation data to delineate flood-inundation areas. Maps of Licking County showing flood-inundation areas overlain on digital orthophotographs are presented for the selected floods. The USGS also developed an unsteady-flow model for a reach of South Fork Licking River for use by the NWS to enhance their ability to provide advanced flood warning in the region north of Buckeye Lake, Ohio. The unsteady-flow model was calibrated based on data from four flooding events that occurred from June 2008 to December 2011. Model calibration was approximate due to the fact that there were unmeasured inflows to the river that were not able to be considered during the calibration. Information on unmeasured inflow derived from NWS hydrologic models and additional flood-event data could enable the NWS to further refine the unsteady-flow model.

Ohio↗
USGS2022

Strength and memory of precipitation's control over streamflow across the conterminous United States

How precipitation (P) is translated into streamflow (Q) and over what timescales (i.e., “memory”) is difficult to predict without calibration of site-specific models or using geochemical approaches, posing barriers to prediction in ungauged basins or advancement of general theories. Here, we used a data-driven approach to identify regional patterns and exogenous controls on P–Q interactions. We applied an information flow analysis, which quantifies uncertainty reduction, to a daily time series of P and Q from 671 watersheds across the conterminous United States. We first demonstrated that information transfer from P to Q primarily reflects the quickflow component of water-budgets, based on a watershed model. Readily quantifiable information flows show a functional relationship with model parameters, suggesting utility for model calibration. Second, applied to real watersheds, P–Q information flows exhibit seasonally varying behavior within regions in a manner consistent with dominant runoff generation mechanisms. However, the timing and the magnitude of information flows also reflect considerable subregional heterogeneity, likely attributable to differences in watershed size, baseflow contributions, and variation in aerial coverage of preferential flow paths. A regression analysis showed that a combination of climate and watershed characteristics are predictive of P–Q information flows. Though information flows cannot, in most cases, uniquely determine dominant runoff mechanisms, they provide a means to quantify the heterogeneous outcomes of those mechanisms within regions, thereby serving as a benchmarking tool for models developed at the regional scale. Last, information flows characterize regionally specific ways in which catchment connectivity changes from the wet to dry season.

conterminous United States↗
USGS2013

Use of NMR logging to obtain estimates of hydraulic conductivity in the High Plains aquifer, Nebraska, USA

Hydraulic conductivity (K) is one of the most important parameters of interest in groundwater applications because it quantifies the ease with which water can flow through an aquifer material. Hydraulic conductivity is typically measured by conducting aquifer tests or wellbore flow (WBF) logging. Of interest in our research is the use of proton nuclear magnetic resonance (NMR) logging to obtain information about water-filled porosity and pore space geometry, the combination of which can be used to estimate K. In this study, we acquired a suite of advanced geophysical logs, aquifer tests, WBF logs, and sidewall cores at the field site in Lexington, Nebraska, which is underlain by the High Plains aquifer. We first used two empirical equations developed for petroleum applications to predict K from NMR logging data: the Schlumberger Doll Research equation (K SDR ) and the Timur-Coates equation (K T-C ), with the standard empirical constants determined for consolidated materials. We upscaled our NMR-derived K estimates to the scale of the WBF-logging K(K WBF-logging ) estimates for comparison. All the upscaled K T-C estimates were within an order of magnitude of K WBF-logging and all of the upscaled K SDR estimates were within 2 orders of magnitude of K WBF-logging . We optimized the fit between the upscaled NMR-derived K and KWBF-logging estimates to determine a set of site-specific empirical constants for the unconsolidated materials at our field site. We conclude that reliable estimates of K can be obtained from NMR logging data, thus providing an alternate method for obtaining estimates of K at high levels of vertical resolution.

Nebraska↗
USGS2001

Critical habitat for ovigerous Dungeness crabs

The Dungeness crab, Cancer magister , supports an important fishery in the northeastern Pacific Ocean, yet there is limited knowledge of ovigerous female brooding locations and brooding behavior. Our earlier research suggests that ovigerous crabs aggregate at the same brooding locations for many years. Within these locations, ovigerous females occur in high densities, with the majority of the aggregation buried within the sediment. These locations often have similar water depths and sediment types and appear to be critical for this life history stage. Our study was designed to examine the bathymetric distribution of Dungeness crabs in bays with and without sea otters at eight locations within the Glacier Bay area by conducting transects with a video-equipped manned submersible. Two of the bays investigated contained large aggregations of ovigerous females. At both sites the substrate was composed primarily of sand. However, only a small percentage of the 33 km of transects were classified as sand. These data suggest that sand substrate may be a limiting resource. Since crab brooding aggregations represent a large portion of the crab population within a small area, and because they are a critical component of Dungeness life history, areas with these characteristics need to be investigated, mapped, and protected from development or exploitation. The areas requiring protection from the impact of anthropogenic wastes, fishing, and logging activities could be quite small, thus limiting conflict with alternative users.

Conference Paper↗
USGS2024

Beyond the wedge: Impact of tidal streams on salinization of groundwater in a coastal aquifer stressed by pumping and sea-level rise

Saltwater intrusion (SWI) is a well-studied phenomenon that threatens the freshwater supplies of coastal communities around the world. The development and advancement of numerical models has led to improved assessment of the risk of salinization. However, these studies often fail to include the impact of surface waters as potential sources of aquifer salinity and how they may impact SWI. Based on field-collected data, we developed a regional, variable-density groundwater model using SEAWAT for east Dover, Delaware. In this location, major users of groundwater from the surficial aquifer are the City of Dover and irrigation for agriculture. Our model includes salinized marshland and tidal streams, along with irrigation and municipal pumping wells. Model scenarios were run for 100 years and included changes in pumping rates and sea-level rise (SLR). We examined how these drivers of SWI affect the extent and location of salinization in the surficial aquifer by evaluating differences in chloride concentration near surface waters and the subsurface freshwater-saltwater interface. We found the presence of the marsh inverts the typical freshwater-saltwater wedge interface and that the edge of the interface did not migrate farther inland. Additionally, we found that tidal streams are the dominant pathways of SWI at our site with salinization from streams being exacerbated by SLR. Our results also show that spatial distribution of pumping affects both the magnitude and extent of salinization, with an increase in concentrated pumping leading to more intensive salinization than a more widely distributed increase of the same total pumping volume.

Delaware↗
USGS2017

Fluorine

Fluorine compounds are essential in numerous chemical and manufacturing processes. Fluorspar is the commercial name for fluorite (isometric CaF 2 ), which is the only fluorine mineral that is mined on a large scale. Fluorspar is used directly as a fluxing material and as an additive in different manufacturing processes. It is the source of fluorine in the production of hydrogen fluoride or hydrofluoric acid, which is used as the feedstock for numerous organic and inorganic chemical compounds. The United States was the world’s leading producer of fluorspar until the mid-1950s. In the mid-1970s, the U.S. fluorspar mining industry began to decline because of foreign competition. By 1982, there was essentially only a single U.S. producer left, and that company ceased mining in 1996. Consumption of fluorspar in the United States peaked in the early 1970s, which was also the peak period of U.S. steel production. Since then, U.S. fluorspar consumption has decreased substantially; the United States has nonetheless increased its imports of downstream fluorine compounds, such as, in order of tonnage imported, hydrofluoric acid, aluminum fluoride, and cryolite. This combination of no U.S. production (until recently) and high levels of consumption has made the United States the world’s leading fluorspar-importing country, in all its various forms. The number of fluorspar-exporting countries has decreased substantially in recent decades, and, as a result, the United States has become dependent on just a few countries to supply its needs. In 2013, the United States imported the majority of its fluorspar from three countries, which were, in descending order of the amount imported, Mexico, China, and South Africa. Geologically, in igneous systems, fluorine is one of a number of elements that are “incompatible.” These incompatible elements become concentrated in the residual magma while the common silicates crystallize upon magma ascent and cooling, leading to relatively high fluorine concentrations in the more evolved or differentiated igneous rocks and in hydrothermal deposits associated with those evolved igneous rocks. In sedimentary rocks, fluorine’s highest concentrations are found in phosphorites because fluorine substitutes for hydroxyl ions in apatite, which leads to fluorine concentrations of, typically, from 2 to 4 weight percent in phosphorites. Because of the presence of fluorine, phosphate fertilizer manufacturers can produce a fluorosilicic acid byproduct. Most deposits mined for fluorine are hydrothermal, however, and consist of fluorine minerals that precipitated from hot water. Magmatic brines and brines from deep within sedimentary basins that have high concentrations of dissolved fluoride are the mineralizing fluids for various types of hydrothermal fluorspar deposits. Relatively dilute hydrothermal fluids that formed in some volcanic rocks can also transport sufficient fluoride to form a high-grade fluorspar deposit. Fluorite has low solubility in a common range of hydrothermal temperatures, particularly from about 160 degrees Celsius (°C) down to 60 °C. The increasing fluorite solubility below 60 °C partly explains why some water with exceptionally high levels of dissolved fluorine are found even at ambient temperatures in evaporitic lake basins in some East African Rift valleys in Kenya and Tanzania. The geologic conditions that led to the high concentrations there are known to exist in a number of other places in the world as well, including, perhaps, places in the Basin and Range province of the United States. Eight minerals or mineral groups have sufficient fluorine in their structures to be considered as possible ores of the element; they are bastnaesite (also spelled bastnäsite; and other fluorocarbonates), cryolite, sellaite, villiaumite, fluorite, fluorapatite (in phosphorites), various phyllosilicates, and topaz. Fluorite is currently the only mineral that is mined for fluorine, and nomineral except fluorite is likely to become a source of commercially produced fluorine as a primary product as long as supplies from relatively thick and high-grade fluorite deposits continue to be available. At least seven classes (which include one subclass) of hydrothermal fluorite deposits are recognized; they are classified according to their tectonic and (or) magmatic settings, as follows: (1) carbonatite-related fluorspar deposits; (2) alkaline-intrusion-related fluorspar deposits; (3) alkaline-volcanic-related epithermal fluorspar deposits; (4) Mississippi Valley-type fluorspar deposits (and a subclass of salt-related carbonate-hosted fluorspar deposits); (5) fluorspar deposits related to strongly differentiated granites; (6) subalkaline-volcanic-related epithermal fluospar deposits; and (7) fluorspar deposits that appear to be conformable within tuffaceous limy lacustrine sediments. An eighth class (not hydrothermal) is that of fluorspar deposits concentrated in soils and weathered zones; that is, residual fluorspar deposits. Generally, fluorspar deposits related to strongly differentiated granites have larger tonnages and lower grades than carbonatite-related fluorspar deposits, which, in turn, have larger tonnages and lower grades than fluorspar vein deposits from various other classes. The United States has a few identified resources of fluorspar, most notably the Klondike II property in the Illinois- Kentucky fluorspar district located about 8 kilometers southwest of Salem, Kentucky, which has a large vein that contains at least 1.6 million metric tons at a grade of 60 percent CaF 2 (Feytis, 2009). Additional fluorspar resources of lower grade but larger tonnage have been identified at Hicks Dome in the Illinois-Kentucky fluorspar district and at Lost River near the western tip of the Seward Peninsula in Alaska, along with a couple of dozen smaller, higher grade resources. Internationally, new mines that either opened before the beginning of 2013 or were scheduled to open soon after that time include the Nui Phao tungsten-fluorspar-bismuth-copper-gold deposit in northern Vietnam; the St. Lawrence project in Newfoundland, Canada, which is located in a well-known fluorspar district; the Bamianshan deposit, which is related to a strongly differentiated granite in northwestern Zhejiang Province, China, near some of that Province’s large, subalkaline-volcanic-related epithermal veins; and the Nokeng project in South Africa, which is also related to a strongly differentiated granite. Other deposits in northwestern Australia, Nevada (United States), Norway, South Africa, and Sweden have been identified and could be put into production within just a few years. Among undiscovered resources, an interesting possibility might be to produce a fluorine product from evaporitic, high-fluorine, high-pH sodium-carbonate brines like Lake Magadi (Kenya) and Lake Natron (Tanzania) in Africa’s Eastern Rift Valley. In addition, apparently conformable fluorspar deposits in tuffaceous limy lacustrine sediments, such as those in Italy, are likely to occur in similar young alkalic volcanic settings elsewhere in the world. Modern geophysical and geochemical exploration techniques have typically not been brought to bear in exploration for new fluorspar deposits, although such techniques are likely to be used in future exploration. The tendency for fluorine to dissolve in significant concentrations in water at low temperature allows both surface water and groundwater to be used as sampling media in geochemical exploration. Evolved granite-related fluorspar deposits may be particularly susceptible to geophysical exploration methods because crystalline rocks that form a basement to sedimentary sections can be approximately defined with gravity and magnetic methods, and magnetite-bearing skarns can be directly detected with magnetic surveys. Environmental considerations of fluorine mining focus especially on drinking water, where high fluorine concentrations can lead to tooth decay; dental and skeletal fluorosis; and bone and cartilage conditions, including genu valgum, which is the crippling bone deformity more commonly known as knock knee. Trace amounts of other elements in fluorspar ores are a concern at some deposits; for example, high beryllium concentrations in alkaline-volcanic-related epithermal deposits or high cadmium concentrations associated with Mississippi Valley-type and salt-related carbonate-hosted fluorspar deposits. Future research might include testing whether fluorine can be extracted economically from high-pH, sodium-carbonate brines and exploring for new occurrences of apparently conformable fluorspar deposits in tuffaceous limy lacustrine sediments outside of the Latium Region of Italy. Other promising new areas of research could be studies of fluorspar deposit fluid inclusion compositions by quadrupole mass spectrometry, by noble gas mass spectrometry on irradiated fluid inclusions, or by chlorine isotopes, while also measuring the chemistry of the same fluid inclusions either by bulk crush-and-leach methods or by laser ablation-inductively coupled plasma mass spectrometry. Advanced studies of fluid inclusion chemistry could be applied beneficially to some of the enigmatic large epithermal fluorspar veins at various places in the world, where they might determine those deposits’ possible relationships to igneous intrusions, or to dissolved salt, or to heated meteoric water in volcanic sections, or perhaps to all three. This knowledge could help focus new exploration.

Professional Paper↗
USGS2018

Exploring drivers of regional water-quality change using differential spatially referenced regression – A pilot study in the Chesapeake Bay watershed

An understanding of riverine water-quality dynamics in regional mixed-land use watersheds is the foundation for advances in landscape biogeochemistry and informed land management. A differential implementation of the statistical/process-based model SPAtially Referenced Regressions on Watershed attributes (SPARROW; Smith et al., https://doi.org/10.1029/97wr02171 ) is proposed to empirically relate a regional pattern of changes in flow-normalized constituent flux, over a multiyear period, to contemporaneous changes in spatially referenced explanatory variables. In a pilot application, the differential model, called Spatiotemporal Watershed Accumulation of Net effects (SWAN), is used to explore factors influencing changes in flow-normalized flux of total nitrogen over the period 1990–2010 at 43 sites in the nontidal Chesapeake Bay watershed. A seven-parameter model explains 80% of the transformed variability in independently estimated flux changes, indicating that storage effects having characteristic time scales greater than 20 years had a small influence, relative to changes in inputs, on regional water-quality response. Results suggest that 1990–2010 changes in total-nitrogen flux are largely the outcome of increased nonpoint-source pollution associated with urban and suburban development, modulated to the point of negation by terrestrial losses stemming from widespread increases in air temperature and precipitation. The loss mechanism is qualitatively consistent with denitrification; however, increases in aboveground biomass, agricultural nitrogen exports, or hydrologic flushing are also plausible contributors. Although qualified by a small sample size and constraints on explanatory data availability, the pilot suggests that SWAN is a promising approach for broadening scientific understanding of factors driving regional water-quality change and for supporting evidence-based land-management decisions.

Chesapeake Bay watershed↗
USGS2002

Application of advanced geophysical logging methods in the characterization of a fractured-sedimentary bedrock aquifer, Ventura County, California

An integrated suite of advanced geophysical logging methods was used to characterize the geology and hydrology of three boreholes completed in fractured-sedimentary bedrock in Ventura County, California. The geophysical methods included caliper, gamma, electromagnetic induction, borehole deviation, optical and acoustic televiewer, borehole radar, fluid resistivity, temperature, and electromagnetic flowmeter. The geophysical logging 1) provided insights useful for the overall geohydrologic characterization of the bedrock and 2) enhanced the value of information collected by other methods from the boreholes including core-sample analysis, multiple-level monitoring, and packer testing. The logged boreholes, which have open intervals of 100 to 200 feet, penetrate a sequence of interbedded sandstone and mudstone with bedding striking 220 to 250 degrees and dipping 15 to 40 degrees to the northwest. Fractures intersected by the boreholes include fractures parallel to bedding and fractures with variable strike that dip moderately to steeply. Two to three flow zones were detected in each borehole. The flow zones consist of bedding-parallel or steeply dipping fractures or a combination of bedding-parallel fractures and moderately to steeply dipping fractures. About 75 to more than 90 percent of the measured flow under pumped conditions was produced by only one of the flow zones in each borehole.

California↗
USGS2006

Evaluating uncertainty in predicting spatially variable representative elementary scales in fractured aquifers, with application to Turkey Creek Basin, Colorado

Computational limitations and sparse field data often mandate use of continuum representation for modeling hydrologic processes in large‐scale fractured aquifers. Selecting appropriate element size is of primary importance because continuum approximation is not valid for all scales. The traditional approach is to select elements by identifying a single representative elementary scale (RES) for the region of interest. Recent advances indicate RES may be spatially variable, prompting unanswered questions regarding the ability of sparse data to spatially resolve continuum equivalents in fractured aquifers. We address this uncertainty of estimating RES using two techniques. In one technique we employ data‐conditioned realizations generated by sequential Gaussian simulation. For the other we develop a new approach using conditioned random walks and nonparametric bootstrapping (CRWN). We evaluate the effectiveness of each method under three fracture densities, three data sets, and two groups of RES analysis parameters. In sum, 18 separate RES analyses are evaluated, which indicate RES magnitudes may be reasonably bounded using uncertainty analysis, even for limited data sets and complex fracture structure. In addition, we conduct a field study to estimate RES magnitudes and resulting uncertainty for Turkey Creek Basin, a crystalline fractured rock aquifer located 30 km southwest of Denver, Colorado. Analyses indicate RES does not correlate to rock type or local relief in several instances but is generally lower within incised creek valleys and higher along mountain fronts. Results of this study suggest that (1) CRWN is an effective and computationally efficient method to estimate uncertainty, (2) RES predictions are well constrained using uncertainty analysis, and (3) for aquifers such as Turkey Creek Basin, spatial variability of RES is significant and complex.

Water Resources Research↗
USGS2022

Potential effects of energy development on environmental resources of the Williston Basin in Montana, North Dakota, and South Dakota—Executive summary

Executive Summary The Williston Basin, which includes parts of Montana, North Dakota, and South Dakota in the United States and parts of Manitoba and Saskatchewan in Canada, has been explored as a potential source of energy resources since the early 20th century; however, commercially viable petroleum drilling and recovery began in earnest in the 1950s. When oil prices rose in the mid-1980s, the number of wells also increased and then subsequently declined. Interest in the Williston Basin increased again in the mid-2000s with the application of new drilling technology. Since then, development has increased rather quickly. Most of this new development has been facilitated by advances in horizontal drilling and hydraulic fracturing technologies. The North Dakota Department of Mineral Resources reported an increase of more than 10,000 producing wells between 2000 and the spring of 2016. In total, 84 percent of those 10,000 wells target the Bakken Formation, which is now home to one of the Nation’s largest energy booms. Current estimates suggest that exploration and drilling activities are expected to continue for the next 20 to 50 years; however, future activity will likely ebb and flow in response to energy prices. Although most energy has been developed on non-Federal property, more than 2,000 wells were started on federally managed lands in the three States that contain the Williston Basin between 2004 and 2015, though these numbers do not reflect whether or not these wells targeted the Bakken Formation. Executive Order no. 13604 (March 22, 2012) directs Federal agencies to improve the timeliness of the permitting process for extracting publically owned minerals, while minimizing negative environmental effects. This means that Federal agencies need information about how energy development may affect other resources they are tasked with managing. One example of where information about potential effects of development may be useful is the Bureau of Land Management’s permitting process. Permits may include stipulations or special conditions that limit unforeseen negative consequences or ameliorate potential conflicts of future development. Federal agencies also need to coordinate permitting actions to ensure that development complies with existing regulations (for example, the Endangered Species Act [16 U.S.C. § 1531 et seq.] or the National Environmental Protection Act [42 U.S.C. § 4321 et seq.]) without unnecessarily restricting or delaying development. Part of this coordination entails agreeing on the information that will be used to assess the potential effects of energy development, which should also improve efficiency of the permitting process. Within the Williston Basin, a group of Federal agencies called the Bakken Federal Executive Group is developing coordination strategies for numerous energy-related issues on Federal lands. This report was developed in cooperation with the Bureau of Land Management to provide them with the best available scientific information to support documentation of potential effects on resources that Federal agencies manage. This report summarizes information about the effects of energy development on air, water, and biological resources within the U.S. part of the Williston Basin. The topics discussed in the report were based on a prioritized list of information needs elicited from the Bakken Federal Executive Group. The list was developed using a process known as structured decision making or decision analysis. This process began with an initial scoping workshop to determine the range of decisions made by those involved directly in managing energy development and resources on public land. U.S. Geological Survey staff then developed a simple quantitative ranking tool to assess which information needs were of greatest importance to those decisions.

Montana, North Dakota, South Dakota↗
USGS2013

Nutrient and sediment concentrations, yields, and loads in impaired streams and rivers in the Taunton River Basin, Massachusetts, 1997-2008

Rapid development, population growth, and the changes in land and water use accompanying development are placing increasing stress on water resources in the Taunton River Basin. An assessment by the Massachusetts Department of Environmental Protection determined that a number of tributary streams to the Taunton River are impaired for a variety of beneficial uses because of nutrient enrichment. Most of the impaired reaches are in the Matfield River drainage area in the vicinity of the City of Brockton. In addition to impairments of stream reaches in the basin, discharge of nutrient-rich water from the Taunton River contributes to eutrophication of Mount Hope and Narragansett Bays. To assess water quality and loading in the impaired tributary stream reaches in the basin, the U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection compiled existing water-quality data from previous studies for the period 1997-2006, developed and calibrated a Hydrological Simulation Program-FORTRAN (HSPF) precipitation-runoff model to simulate streamflow in areas of the basin that contain the impaired reaches for the same time period, and collected additional streamflow and water-quality data from sites on the Matfield and Taunton Rivers in 2008. A majority of the waterquality samples used in the study were collected between 1999 and 2006. Overall, the concentration, yield, and load data presented in this report represent water-quality conditions in the basin for the period 1997-2008. Water-quality data from 52 unique sites were used in the study. Most of the samples from previous studies were collected between June and September under dry weather conditions. Simulated or measured daily mean streamflow and water-quality data were used to estimate constituent yields and loads in the impaired tributary stream reaches and the main stem of the Taunton River and to develop yield-duration plots for reaches with sufficient water-quality data. Total phosphorus concentrations in the impaired-reach areas ranged from 0.0046 to 0.91 milligrams per liter (mg/L) in individual samples (number of samples (n)=331), with a median of 0.090 mg/L; total nitrogen concentrations ranged from 0.34 to 14 mg/L in individual samples (n=139), with a median of 1.35 mg/L; and total suspended solids concentrations ranged from 2/d) for total phosphorus and 100 lb/mi 2 /d for total nitrogen in these reaches. In most of the impaired reaches not affected by the Brockton Advanced Water Reclamation Facility outfall, yields were lower than in reaches downstream from the outfall, and the difference between measured and threshold yields was fairly uniform over a wide range of flows, suggesting that multiple processes contribute to nonpoint loading in these reaches. The Northeast and Mid-Atlantic SPAtially-Referenced Regression On Watershed (SPARROW) models for total phosphorus and total nitrogen also were used to estimate annual nutrient loads in the impaired tributary stream reaches and main stem of the Taunton River and predict the distribution of these loads among point and diffuse sources in reach drainage areas. SPARROW is a regional, statistical model that relates nutrient loads in streams to upstream sources and land-use characteristics and can be used to make predictions for streams that do not have nutrient-load data. The model predicts mean annual loads based on longterm streamflow and water-quality data and nutrient source conditions for the year 2002. Predicted mean annual nutrient loads from the SPARROW models were consistent with the measured yield and load data from sampling sites in the basin. For conditions in 2002, the Brockton Advanced Water Reclamation Facility outfall accounted for over 75 percent of the total nitrogen load and over 93 percent of the total phosphorus load in the Salisbury Plain and Matfield Rivers downstream from the outfall. Municipal point sources also accounted for most of the load in the main stem of the Taunton River. Multiple municipal wastewater discharges in the basin accounted for about 76 and 46 percent of the delivered loads of total phosphorus and total nitrogen, respectively, to Mount Hope Bay. For similarly sized watersheds, total delivered loads were lower in watersheds without point sources compared to those with point sources, and sources associated with developed land accounted for most of the delivered phosphorus and nitrogen loads to the impaired reaches. The concentration, yield, and load data evaluated in this study may not be representative of current (2012) point-source loading in the basin; in particular, most of the water-quality data used in the study (1999-2006) were collected prior to completion of upgrades to the Brockton Advanced Water Reclamation Facility that reduced total phosphorus and nitrogen concentrations in treated effluent. Effluent concentration data indicate that, for a given flow rate, effluent loads of total phosphorus and total nitrogen declined by about 80 and 30 percent, respectively, between the late 1990s and 2008 in response to plant upgrades. Consequently, current (2012) water-quality conditions in the impaired reaches downstream from the facility likely have improved compared to conditions described in the report.

Massachusetts↗
USGS2014

Reconnaissance of pharmaceuticals and wastewater indicators in streambed sediments of the lower Columbia River basin, Oregon and Washington

One by-product of advances in modern chemistry is the accumulation of synthetic chemicals in the natural environment. These compounds include contaminants of emerging concern (CECs), some of which are endocrine disrupting compounds (EDCs) that can have detrimental reproductive effects. The role of sediments in accumulating these types of chemicals and acting as a source of exposure for aquatic organisms is not well understood. Here we present a small-scale reconnaissance of CECs in bed sediments of the lower Columbia River and several tributaries and urban streams. Surficial bed sediment samples were collected from the Columbia River, the Willamette River, the Tualatin River, and several small urban creeks in Oregon. Thirty-nine compounds were detected at concentrations ranging from <1 to >1,000 ng [g sediment] -1 dry weight basis. Columbia River mainstem, suggesting a higher risk of exposure to aquatic life in lower order streams. Ten known or suspected EDCs were detected during the study. At least one EDC was detected at 21 of 23 sites sampled; several EDCs were detected in sediment from most sites. This study is the first to document the occurrence of a large suite of CECs in the sediments of the Columbia River basin. A better understanding of the role of sediment in the fate and effects of emerging contaminants is needed.

Oregon;Washington↗
USGS2024

Prefabricated Zero Ascend Omnispecies (ZAO) modular fish passage modules using advanced manufacturing techniques

The Zero Ascend Omnispecies (ZAO) fish passage attraction module “ZAO Attractor” is a novel system designed to facilitate upstream passage for a broad spectrum of fish species, with a particular focus on American shad and river herring (alewife and/or blueback herring). Combining the use of prefabricated, modular components with advanced manufacturing, the ZAO aims to provide a cost-effective and scalable solution for fish passage attractions across various hydropower sites. The system features a surface level entry, so fish do not need to climb. In addition, it is designed to be adjusted and repositioned to create the most effective attraction flows by managing the outflows from hydropower turbines. Budget Period 1 (BP1) focused on the design and modeling of the ZAO Attractor and demonstrated the engineering feasibility of a modular, prefabricated, hydrodynamically efficient structure with surface level entry and passage. During BP1, the hypothesis was that certain structural adaptations, such as the addition of long fins, could direct turbine outflows to create a desirable downstream flow. Simulations, however, were inconclusive, revealing the complex nature of fish preferences for hydraulic conditions. It was discovered that there were limited published studies on the direct correlation between quantified flow patterns and fish attraction, emphasizing the need for controlled studies to observe and measure these effects. In Budget Period 2 (BP2), controlled studies with live fish were prioritized to address these complexities. A partially scaled ZAO Attractor was evaluated in laboratory conditions using native river water to assess its capability to attract and guide fish. Despite challenges with flume flow conditions and the impact of flume dimensions on flow directionality and velocity, the studies provided insights into fish behavior and preferences, particularly the requirement for a consistent flow stream for migration cues. Adjustments to the fin structure demonstrated potential effectiveness in guiding fish toward the module. However, the hydraulic conditions within the flume environment did not accurately reflect typical in-river scenarios, therefore the results were inconclusive with respect to the optimal system configuration for in-river use. In the future, conducting comprehensive field studies can enhance understanding of the interactions between fish behavior and flow conditions created by the ZAO Attractor. Additionally, a design review is advised, particularly regarding the load scenarios throughout the seasons and positioning of the ZAO Attractor. These studies should continue to refine the design to achieve its intended benefits: economical and effective fish attraction and passage that can be adapted to specific site conditions while allowing for continued energy generation at sites up for re-licensure and adding hydropower generation to previously untapped resources in non-powered dams and new stream reaches. In conclusion, the ZAO fish passage attraction module presents a promising approach to fish passage at hydropower stations, with the potential to balance environmental concerns with renewable energy development. However, further field validation and optimization are necessary to ensure its effectiveness and practicality in real-world applications.

Final Technical Report↗