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At least 451 records · Page 25Linked to original sources
USGS2020

Fluoride occurrence in United States groundwater

Data from 38,105 wells were used to characterize fluoride (F) occurrence in untreated United States (U.S.) groundwater. For domestic wells (n = 11,032), water from which is generally not purposely fluoridated or monitored for quality, 10.9% of the samples have F concentrations >0.7 mg/L (U.S. Public Health Service recommended optimal F concentration in drinking water for preventing tooth decay) (87% are <0.7 mg/L); 2.6% have F > 2 mg/L (EPA Secondary Maximum Contaminant Level, SMCL); and 0.6% have F > 4 mg/L (EPA MCL). The data indicate the biggest concern with F in domestic wells at the national scale could be one of under consumption of F with respect to the oral-health benchmark (0.7 mg/L). Elevated F concentrations relative to the SMCL and MCL are regionally important, particularly in the western U.S. Statistical comparisons of potentially important controlling factors in four F-concentration categories (<0.1–0.7 mg/L; >0.7–2 mg/L; >2–4 mg/L; >4 mg/L) at the national scale indicate the highest F-concentration category is associated with groundwater that has significantly greater pH values, TDS and alkalinity concentrations, and well depths, and lower Ca/Na ratios and mean annual precipitation, than the lowest F-concentration category. The relative importance of the controlling factors appears to be regionally variable. Three case studies illustrate the spatial variability in controlling factors using groundwater-age (groundwater residence time), water-isotope (evaporative concentration), and water-temperature (geothermal processes) data. Populations potentially served by domestic wells with F concentrations <0.7, >0.7, >2, and >4 mg/L are estimated to be ~28,200,000, ~3,110,000; ~522,000; and ~172,000 people, respectively, in 40 principal aquifers with at least 25 F analyses per aquifer.

Science of the Total Environment↗
USGS2020

Evaluating the potential role of bioactive chemicals on the distribution of invasive Asian carp upstream and downstream from river mile 278 in the Illinois waterway

Two non-native carp species have invaded the Illinois Waterway and are a threat to Great Lakes ecosystems. Poor water quality in the upper Illinois Waterway, may be a factor contributing to the stalling of the carp population front near river mile 278. In 2015, the U.S. Geological Survey collected 4 sets of water samples from two sites upstream and 4 sites downstream from river mile 278, and one tributary. Each sample was analyzed for up to 649 unique parameters of which 287 were detected including 96 pesticides, 62 pharmaceuticals, 39 wastewater indicator compounds, 29 metals, 19 volatile organic compounds (VOCs), six disinfection by-products (DBPs), five hormones, and five carboxylic acids. Potential for bioactivity was estimated by comparing chemical concentrations to aquatic life or human health criteria and to in-vitro bioactivity screening results in the U.S EPA ToxCast™ database. The resulting hazard quotients and exposure-activity ratios (EARs) are toxicity indexes, that can be used to rank potential bioactivity of individual chemicals and chemical mixtures. This analysis indicates that several bioactive chemicals (BCs) including: carbendazim, 2,4-D, metolachlor, terbuthylazine, and acetochlor (pesticides); 1,4-dioxane (VOC); metformin, diphenhydramine, sulfamethoxazole, tramadol, fexofenadine, and the anti-depressants (pharmaceuticals); bisphenol A, 4-nonylphenol, galaxolide, 4-tert-octylphenol (wastewater indicator chemical); lead and boron (metals); and estrone (hormone) all occur in the upper Illinois Waterway at concentrations that produce elevated EARs values and may be adversely affecting carp reproduction and health. The clear differences in water quality upstream and downstream from river mile 278 with higher contaminant concentrations and potential bioactivity upstream could represent a barrier to carp range expansion.

Illinois↗
USGS2020

Freshwater neurotoxins and concerns for human, animal, and ecosystemhealth: A review of anatoxin-a and saxitoxin

Toxic cyanobacteria are a concern worldwide because they can adversely affect humans, animals, and ecosystems. However, neurotoxins produced by freshwater cyanobacteria are understudied relative to microcystin. Thus, the objective of this critical review was to provide a comprehensive examination of the modes of action, production, fate, and occurrence of the freshwater neurotoxins anatoxin-a and saxitoxin as they relate to human, animal, and ecosystem health. Literature on freshwater anatoxin-a and saxitoxin was obtained and reviewed for both laboratory and field studies. Current (2020) research identifies as many as 41 anatoxin-a producing species and 15 saxitoxin-producing species of freshwater cyanobacteria. Field studies indicate that anatoxin-a and saxitoxin have widespread distribution, and examples are given from every continent except Antarctica. Human and animal health concerns can range from acute to chronic. However, few researchers studied chronic or sublethal effects of freshwater exposures to anatoxin-a or saxitoxin. Ecosystemhealth also is a concern, as the effects of toxicity may be far reaching and include consequences throughout the food web. Several gaps in knowledgewere identified for anatoxin-a and saxitoxin, including triggers of production and release, environmental fate and degradation, primary and secondary exposure routes, diel variation, food web effects, effects of cyanotoxin mixtures, and sublethal health effects on individual organisms and populations. Despite the gaps, this critical review facilitates our current understanding of freshwater neurotoxins and thus can serve to guide future research on anatoxin-a, saxitoxin, and other cyanotoxins.

Science of the Total Environment↗
USGS2020

Short- and long-term responses of riparian cottonwoods (Populus spp.) to flow diversion: Analysis of tree-ring radial growth and stable carbon isotopes

Long duration tree-ring records with annual precision allow for the reconstruction of past growing conditions. Investigations limited to the most common tree-ring proxy of ring width can be difficult to interpret, however, because radial growth is affected by multiple environmental processes. Furthermore, studies of living trees may miss important effects of drought on tree survival and forest changes. Stable carbon isotopes can help distinguish drought from other environmental factors that influence tree-ring width and forest stand condition. We quantified tree-ring radial expansion and stable carbon isotope ratios (δ 13 C) in riparian cottonwoods ( Populus angustifolia and P. angustifolia x P. trichocarpa) along Snake Creek in Nevada, USA. We investigated how hydrological drought affected tree growth and death at annual to half-century scales in a partially dewatered reach (DW) compared to reference reaches immediately upstream and downstream. A gradual decline in tree-ring basal area increment (BAI) began at DW concurrent to streamflow diversion in 1961. BAI at DW diverged from one reference reach immediately but not from the other until nearly 50 years later. In contrast, tree-ring δ 13 C had a rapid and sustained increase following diversion at DW only, providing the stronger and clearer drought signal. BAI and δ 13 C were not significantly correlated prior to diversion; after diversion they both reflected drought and were correlated for DW trees only. Cluster analyses distinguished all trees in DW from those in reference reaches based on δ 13 C, but BAI patterns left trees intermixed across reaches. Branch and tree mortality were also highest and canopy vigor was lowest in DW. Results indicate that water scarcity strongly limited cottonwood photosynthesis following flow diversion, thus reducing carbon assimilation, basal growth and survival. The dieback was not sudden, but occurred over decades as carbon deficits mounted and depleted streamflow left trees increasingly vulnerable to local meteorological drought.

Nevada↗
USGS2020

Reduction in drinking water arsenic exposure and health risk through arsenic treatment among private well households in Maine and New Jersey, USA

Over 2 million people in the United States (U.S.) drink water from private wells that contain arsenic (As) exceeding the U.S. Environmental Protection Agency (USEPA) Maximum Contaminant Level (MCL) of 10 micrograms per liter (μg/L). While there are a number of commercially available treatment technologies for removing As from drinking water, it is up to the private well households to decide whether to treat for As or not. However, how well existing treatment technologies perform in real world situations, and to what extent they reduce health risks, are not well understood. This study evaluates the effectiveness of household As treatment systems in southern-central Maine (ME, n=156) and northern New Jersey (NJ, n=94) and ascertains how untreated well water chemistry and other factors influence As removal. Untreated and treated water samples, as well as a treatment questionnaire, were collected. Most ME households in this study had point-of-use reverse-osmosis systems (POU RO), while in NJ, dual-tank point-of-entry (POE) whole house systems were popular. Arsenic treatment systems reduced well water arsenic concentrations ([As]) by up to two orders of magnitude, i.e. from a median of 71.7 to 0.8 μg/L and from a mean of 105 to 14.3 μg/L in ME, and from a median of 8.6 to 0.2 μg/L and a mean of 15.8 to 2.1 μg/L in NJ. More than half (53%) of the systems in ME reduced water [As] to below 1 µg/L, compared to 69% in NJ. The treatment system failure rates were 19% in ME (> USEPA MCL 10 µg/L) and 16% in NJ (> NJ standard 5 μg/L). In both states, the higher the untreated well water [As] and the As(III)/As ratio, the higher the rate of treatment failure. POE systems failed less than POU systems, as did the treatment systems installed and maintained by vendors than those by homeowners. The 7-fold reduction of [As] in the treated water reduced skin cancer risk alone from 3,765 to 514 in 1 million in ME, and from 568 to 75 in 1 million in NJ.

Maine, New Jersey↗
USGS2020

Characterizing the diverse hydrogeology underlying rivers and estuaries using new floating transient electromagnetic methodology

The hydrogeology below large surface water features such as rivers and estuaries is universally under-informed at the long reach to basin scales (tens of km+). This challenge inhibits the accurate modeling of fresh/saline groundwater interfaces and groundwater/surface water exchange patterns at management-relevant spatial extents. Here we introduce a towed, floating transient electromagnetic (TEM) system (i.e. FloaTEM) for rapid (up to 15 km/h) high resolution electrical mapping of the subsurface below large water bodies to depths often a factor of 10 greater than other towed instruments. The novel FloaTEM system is demonstrated at a range of diverse 4th through 6th-order riverine settings across the United States including 1) the Farmington River, near Hartford, Connecticut; 2) the Upper Delaware River near Barryville, New York; 3) the Tallahatchie River near Shellmound, Mississippi; and, 4) the Eel River estuary, on Cape Cod, near Falmouth, Massachusetts. Airborne frequency-domain electromagnetic and land-based towed TEM data are also compared at the Tallahatchie River site, and streambed geologic scenarios are explored with forward modeling. A range of geologic structures and pore water salinity interfaces were identified. Process-based interpretation of the case study data indicated FloaTEM can resolve varied sediment-water interface materials, such as the accumulation of fines at the bottom of a reservoir and permeable sand/gravel riverbed sediments that focus groundwater discharge. Bedrock layers were mapped at several sites, and aquifer confining units were defined at comparable resolution to airborne methods. Terrestrial fresh groundwater discharge with flowpaths extending hundreds of meters from shore was also imaged below the Eel River estuary, improving on previous hydrogeological characterizations of that nutrient-rich coastal exchange zone. In summary, the novel FloaTEM system fills a critical gap in our ability to characterize the hydrogeology below surface water features and will support more accurate prediction of groundwater/surface water exchange dynamics and fresh-saline groundwater interfaces.

Science of the Total Environment↗
USGS2020

Beyond neonicotinoids – Wild pollinators are exposed to a range of pesticides while foraging in agroecosystems

Pesticide exposure is a growing global concern for pollinator conservation. While most current pesticide studies have specifically focused on the impacts of neonicotinoid insecticides toward honeybees and some native bee species, wild pollinators may be exposed to a broader range of agrochemicals. In 2016 and 2017 we collected a total of 637 wild bees and butterflies from the margins of cultivated agricultural fields situated on five Conservation Areas in mid-northern Missouri. Pollinators were composited by individual genera (90 samples) and whole tissues were then analyzed for the presence of 168 pesticides and degradation products. At least one pesticide was detected (% frequency) in the following wild bee genera: Bombus (96%), Eucera (75%), Melissodes (73%), Ptilothrix (50%), Xylocopa (50%), and Megachile (17%). Similarly, at least one pesticide was detected in the following lepidopteran genera: Hemaris (100%), Hylephila (75%), Danaus (60%), and Colias (50%). Active ingredients detected in >2% of overall pollinator samples were as follows: metolachlor (24%), tebuconazole (22%), atrazine (18%), imidacloprid desnitro (13%), bifenthrin (9%), flumetralin (9%), p, p'-DDD (6%), tebupirimfos (4%), fludioxonil (4%), flutriafol (3%), cyproconazole (2%), and oxadiazon (2%). Concentrations of individual pesticides ranged from 2 to 174 ng/g. Results of this pilot field study indicate that wild pollinators are exposed to and are potentially bioaccumulating a wide variety of pesticides in addition to neonicotinoids. Here, we provide evidence that wild bee and butterfly genera may face exposure to a wide range of insecticides, fungicides, and herbicides despite being collected from areas managed for conservation. Therefore, even with the presence of extensive habitat, minimal agricultural activity on Conservation Areas may expose pollinators to a range of pesticides.

Missouri↗
USGS2020

Fish growth rates and lake sulphate explain variation in mercury levels in ninespine stickleback (Pungitius pungitius) on the Arctic Coastal Plain of Alaska

Mercury concentrations in freshwater food webs are governed by complex biogeochemical and ecological interactions that spatially vary and are often mediated by climate. The Arctic Coastal Plain of Alaska (ACP) is a heterogeneous, lake-rich landscape where variability in mercury accumulation is poorly understood. Earlier research indicated that the level of catchment influence on lakes varied spatially on the ACP, and affected mercury accumulation in lake sediments. This work sought to determine drivers of spatial variation in mercury accumulation in lake food webs on the ACP. Three lakes that were a priori identified as “high catchment influence” (Reindeer Camp region) and three lakes that were a priori identified as “low catchment influence” (Atqasuk region) were sampled, and variability in water chemistry, food web ecology, and mercury accumulation was investigated. Among-lake differences in ninespine stickleback ( Pungitius pungitius ) length-adjusted methylmercury concentrations were significantly explained by sulphate concentration in lake water, a tracer of catchment runoff input. This effect was mediated by fish growth, which had no pattern between regions. Together, lake water sulphate concentration and fish age-at-size (proxy for growth) accounted for nearly all of the among-lake variability in length-adjusted methylmercury concentrations in stickleback (R 2 adj = 0.94, p < 0.01). The percentage of total mercury as methylmercury (a proxy for net Hg methylation) was higher in sediments of more autochthonous, “low catchment influence” lakes ( p < 0.05), and in the periphyton of more allochthonous, “high catchment influence” lakes (p < 0.05). The results indicate that dominant sources of primary production (littoral macrophyte/biofilm vs. pelagic phytoplankton) and food web structure (detrital vs. grazing) are regulated by catchment characteristics on the ACP, and that this ultimately influences the amount of methylmercury in the aquatic food web. These results have important implications for predicting future mercury concentrations in fish in lakes where fish growth rates and catchment inputs may change in response to a changing climate.

Alaska↗
USGS2020

Trihalomethane precursors: Land use hot spots, persistence during transport, and management options

To meet drinking water regulations, rather than investing in costly treatment plant operations, managers can look for ways to improve source water quality; this requires understanding watershed sources and fates of constituents of concern. Trihalomethanes (THMs) are one of the major classes of regulated disinfection byproducts, formed when a specific fraction of the organic carbon pool—referred to as THM precursors—reacts with chorine and/or bromine during treatment. Understanding the source, fate, timing and duration of the organic compounds that react to form THMs will allow identification of targeted and effective management actions. In this study we evaluated THM precursor contributions from multiple land use categories and hydrologic contexts, including novel data for urban land uses that demonstrate strong potential to release water with high THM formation potential (THMFP; median 618 μg L −1 ): greater than storm runoff integrated across a mixed-use (1/3 natural, 2/3 agricultural) watershed (median 460 μg L −1 ), irrigation runoff from agricultural systems (357 μg L −1 ), or runoff from a natural forested (median 123 μg L −1 ) and shrubland/grassland (median 259 μg L −1 ) watersheds. While individual storm events released high THM precursor concentrations over short periods, dry season agricultural irrigation as well as urban landscapes have the potential to release water high in THM precursors for several months. Experimental bioassays and sampling along 333 miles of the California Aqueduct confirmed bioavailability and photooxidation potential of less than 10% for THM precursors, suggesting that rivers with residence times of days to weeks may act as THM precursor conduits, shuttling THM precursors from hundreds of miles away to drinking water intakes with minimal degradation. This finding has considerable implications for water managers, who may therefore consider THM precursor management strategies that target even sources located far upstream.

California↗
USGS2020

Wildfire-driven changes in hydrology mobilize arsenic and metals from legacy mine waste

Wildfires burning in watersheds that have been mined and since revegetated pose unique risks to downstream water supplies. A wildfire near Boulder, Colorado that burned a forested watershed recovering from mining disturbance that occurred 80-160 years ago allowed us to 1) assess arsenic and metal contamination in streams draining the burned area for a five-year period after the wildfire and 2) determine the fire-affected hydrologic drivers that convey arsenic and metals to surface water. Most metal concentrations were low in the circumneutral waters draining the burned area. Water and sediment collected from streams downstream of the burned area had elevated arsenic concentrations during and after post-fire storms. Mining-related deposits were the main source of arsenic to streams. An increased proportion of overland flow relative to infiltration after the fire mobilized arsenic- and metal- rich surface deposits and wildfire ash into streams within and downstream of the burned area. The deposition of this sediment into stream channels resulted in the remobilization of arsenic for the five-year post-fire study period. It is also possible that enhanced subsurface flow after the fire increased contact of water with arsenic-bearing minerals exposed in underground mine workings. Other studies have reported that wildfire ash can be an important source of arsenic and metals to surface waters, but wildfire ash was not an important source of arsenic in this study. Predicted increases in frequency, size, and intensity of wildfires in the western U.S., a region with widely dispersed historical mines, suggest that the intersection of legacy mining and post-wildfire hydrologic response poses an increasing risk for water supplies.

Colorado↗
USGS2020

Leachable phosphorus from senesced green ash and Norway mapleleaves in urban watersheds

In urban watersheds, street tree leaf litter is a critical biogenic source of phosphorus (P) in stormwater runoff. Stormwater extracts P from leaf litter and transports it, through the storm sewer network, to a receiving waterbody potentially causing downstream eutrophication. The goal of this study is to understand P leaching dynamics of two prevalent tree species (Norway maple (Acer platanoides) and green ash (Fraxinus pennsylvanica)) in three urban residential watersheds in Madison, Wisconsin, USA. Leaf litter was collected from the three basins during Fall 2017 and 2018. Laboratory experiments showed an initial rapid total dissolved phosphorus (TDP) release that gradually plateaued over a 48-hour period. The total TDP released from Norway maple (2.10 mg g−1 ) was greater than from green ash (1.60 mg g−1 ).Within the same species, increased fragmentation of leaves led to more rapid initial TDP release, but not greater total TDP release. Increased aging of senescent leaves decreased total TDP release. Incubation temperature and volume of water in contact with leaves may not be critical factors affecting TDP leaching dynamics. Predictive equations were derived to characterize time-variable TDP release of both Norway maple and green ash leaves. Potential TDP release from leaf litter estimated using these equations was compared with field-measured end-of-pipe TDP loads in one of the study watersheds. Our results indicate that preventing leaf litter from accumulating in streets is an important stormwater quality control measure.

Science of the Total Environment↗
USGS2020

Wastewater-based epidemiology pilot study to examine drug use in the Western United States

The extent of prescription and illicit drug abuse in geographically isolated rural and micropolitan communities in the intermountain western United States (US) has not been well tracked. The goal of this pilot study was to accurately measure drug dose consumption rates (DCR) between two select populations, normalize the data and compare the DCRs to similar communities. To learn about patterns of drug abuse between the two disparate communities, we used the emergent field of wastewater-based epidemiology (WBE). A rapid, quantitative and systematic process for the determination of multiple classes of prescribed and illicit drugs was applied to influent wastewater samples. Influent samples were collected over the course of three months (April to June 2019) at two wastewater treatment plants representing a small urban and a rural community. Collection of sewage influent included 24-h composite samples and the use of polar organic chemical integrative samplers (POCIS), time-weighted samplers. Using the results from the composite sampling data, DCRs per 1000 population could be calculated from the concentration data and the use of excretion correction factors. The following 18 compounds: amphetamine, methamphetamine, MDA, MDMA, morphine, 6-acetylmorphine, methadone, EDDP, codeine, benzoylecgonine, hydrocodone, hydromorphone, oxycodone, noroxycodone, ketamine, fluoxetine, tramadol, and ritalinic acid; represent a subset of the targeted analytes that were consistently measured at detectable concentration levels, and present at both sites. Following normalization of the drug measurements to influent flow rates and per capita, the small urban community demonstrated greater collective excretion rates (CER) than the rural community, with the exceptions of amphetamine and methamphetamine.

Science of the Total Environment↗
USGS2020

Degradation of RDX (Hexahydro-1,3,5-trinitro-1,3,5-triazine) in contrasting coastal marine habitats: Subtidal non-vegetated (sand), subtidal vegetated (silt/eel grass), and intertidal marsh

Hundreds of explosive-contaminated marine sites exist globally, many of which contain the common munitions constituent hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX). Quantitative information about RDX transformation in coastal ecosystems is essential for management of many of these sites. Isotopically labelled RDX containing 15 N in all 3 nitro groups was used to track the fate of RDX in three coastal ecosystem types. Flow-through mesocosms representing subtidal vegetated (silt/eel grass), subtidal non-vegetated (sand) and intertidal marsh ecosystems were continuously loaded with isotopically labelled RDX for 16–17 days. Sediment, pore-water and overlying surface water were analyzed to determine the distribution of RDX, nitroso-triazine transformation products (NXs) and nitrogen containing complete mineralization products, including ammonium, nitrate+nitrite, nitrous oxide and nitrogen gas. The marsh, silt, and sand ecotypes transformed 94%, 90% and 76% of supplied RDX, respectively. Total dissolved NXs accounted for 2%–4% of the transformed 15 N-RDX. The majority of RDX transformation in the water column was by mineralization to inorganic N (dissolved and evaded; 64%–78% of transformed 15 N-RDX). RDX was mineralized primarily to N 2 O (62–74% of transformed 15 N-RDX) and secondarily to N 2 (1–2% of transformed 15 N-RDX) which exchanged with the atmosphere. Transformation of RDX was favored in carbon-rich lower redox potential sediments of the silt and marsh mesocosms where anaerobic processes of iron and sulfate reduction were most prevalent. RDX was most persistent in the carbon-poor sand mesocosm. Partitioning of 15 N derived from RDX onto sediment and suspended particulates was negligible in the overall mass balance of RDX transformation (2%–3% of transformed 15 N-RDX). The fraction of 15 N derived from RDX that was sorbed or assimilated in sediment was largest in the marsh mesocosm (most organic carbon), and smallest in the sand mesocosm (largest grain size and least organic carbon). Sediment redox conditions and available organic carbon stores affect the fate of RDX in different coastal marine habitats.

Connecticut, New York↗
USGS2020

Biological nitrogen fixation across major biomes in Latin America: Patterns and global change effects

Biological nitrogen fixation (BNF) supports terrestrial primary productivity and plays key roles in mediating human-induced changes in global nitrogen (N) and carbon cycling. However, there are still critical uncertainties in our understanding of the amount of BNF occurring across terrestrial ecosystems, and of how terrestrial BNF will respond to global change. We synthesized BNF data from Latin America, a region reported to sustain some of the highest BNF rates on Earth, but that is underrepresented in previous data syntheses. We used meta-analysis and modeling approaches to estimate BNF rates across Latin America's major biomes and to evaluate the potential effects of increased N deposition and land-use change on these rates. Unmanaged tropical and subtropical moist forests sustained observed and predicted total BNF rates of 10 ± 1 and 14 ± 1 kg N ha −1 y −1 , respectively, supporting the hypothesis that these forests sustain lower BNF rates than previously thought. Free-living BNF accounted for two-thirds of the total BNF in these forests. Despite an average 30% reduction of free-living BNF in response to experimental N-addition, our results suggest free-living BNF rate responses to current and projected N deposition across tropical and subtropical moist forests are small. In contrast, the conversion of unmanaged ecosystems to crop and pasture lands increased BNF rates across all terrestrial biomes, mostly in savannas, grasslands, and dry forests, increasing BNF rates 2-fold. The information obtained here provides a more comprehensive understanding of BNF patterns for Latin America.

Science of the Total Environment↗
USGS2020

Pesticide mixtures show potential toxicity to aquatic life in U.S. streams, water years 2013-2017

During water years (WY) 2013–2017, the U.S. Geological Survey, National Water-Quality Assessment (NAWQA) Project, sampled the National Water Quality Network – Rivers and Streams (NWQN) year-round and reported on 221 pesticides at 72 sites across the United States in agricultural, developed, and mixed land use watersheds. The Pesticide Toxicity Index (PTI) was used to estimate the potential chronic and acute toxicity to three taxonomic groups – fish, cladocerans, and benthic invertebrates. For invertebrates (either cladocerans, benthic invertebrates, or both), the maximum PTI score exceeded the predicted acute toxicity screening level at 18 of the 72 sites (25%) at some point during WY 2013–2017. The predicted toxicity of a single pesticide compound was found to overwhelm the toxicity of other pesticides in the mixtures after concentrations were toxicity weighted. For this study, about 71%, 72%, and 92% of the Fish-, Cladoceran-, and Benthic Invertebrate-PTI scores, respectively, had one pesticide compound primarily contributing to sample potential toxicity (>50%). There were 17 (13 insecticides, 2 herbicides, 1 fungicide, and 1 synergist) of the 221 pesticide compounds analyzed that were the primary drivers of potential toxicity in each water sample in which the PTI and TUmax (toxic unit score for the pesticide that makes the single largest contribution to the PTI) scores were above predicted chronic (>0.1) or acute (>1) toxicity levels for one of the three taxa. For cladocerans and benthic invertebrates, the drivers of predicted chronic (>0.1) and acute (>1) PTIs were mostly insecticides. For cladocerans, the pesticide compounds driving the PTI scores were bifenthrin, carbaryl, chlorpyrifos, diazinon, dichlorvos, dicrotophos, diflubenzuron, flubendiamide, and tebupirimfos. For benthic invertebrates, atrazine (an herbicide), as well as the insecticides – bifenthrin, carbaryl, carbofuran, chlorpyrifos, diazinon, dichlorvos, fipronil, imidacloprid, and methamidophos – were the drivers of predicted toxicity. For fish, there were three pesticide types that contributed the most to predicted chronic (>0.1) PTIs – acetochlor, an herbicide; carbendazim, a fungicide degradate; and piperonylbutoxide, a synergist.

Science of the Total Environment↗
USGS2020

Soil organic carbon stocks and sequestration rates of inland, freshwater wetlands: Sources of variability and uncertainty

Impacts of land use, specifically soil disturbance, are linked to reductions of soil organic carbon (SOC) stocks. Correspondingly, ecosystem restoration is promoted to sequester SOC to mitigate anthropogenic greenhouse gas emissions, which are exacerbating global climate change. Restored wetlands have relatively high potential to sequester carbon compared to other ecosystems, but SOC accumulation rates are variable, which leads to high uncertainty in sequestration rates. To assess soil properties and carbon sequestration rates of freshwater mineral soil wetlands, we analyzed an extensive database of SOC concentrations from the Prairie Pothole Region (549 wetlands over 160,000 km 2 ), which is considered one of the largest wetland ecosystems in North America. We demonstrate that SOC of wetland catchments varies among inner, transition, toe slope, and upland landscape positions (LSPs), as well as among land uses and soil depth segments. Soil organic carbon concentrations were greatest in the inner portion of the catchment (66 Mg ha −1 ) and progressively decrease towards the upland LSP (43 Mg ha −1 ). We also conducted a regional extrapolation based on LSP- and land-use-specific SOC stocks, and estimated that wetland and upland areas of PPR wetland catchments contain 141 and 178 Tg of SOC in the upper 15 cm of the soil profile, respectively. Regressing SOC by restoration age (years restored) showed that sequestration rates, which differ by LSP and depth, ranged from 0.35 to 1.10 Mg ha −1 year −1 . Using these SOC sequestration rates, along with data from natural and cropland reference sites, we estimated that it takes 20 to 64 years for SOC levels of restored wetlands to return to natural reference conditions, depending on LSP and depth segment. Accounting for LSP reduces uncertainty and should refine future assessments of the greenhouse gas mitigation potential from wetland restoration.

Iowa, Minnesota, Montana, North Dakota, South Dako↗
USGS2020

Plant biomass and rates of carbon dioxide uptake are enhanced by successful restoration of tidal connectivity in salt marshes

Salt marshes, due to their capability to bury soil carbon (C), are potentially important regional C sinks. Efforts to restore tidal flow to former salt marshes have increased in recent decades in New England (USA), as well as in some other parts of the world. In this study, we investigated plant biomass and carbon dioxide (CO 2 ) fluxes at four sites where restoration of tidal flow occurred five to ten years prior to the study. Site elevation, aboveground biomass, CO 2 flux, and porewater chemistry were measured in 2015 and 2016 in both restored marshes and adjacent marshes where tidal flow had never been restricted. We found that the elevation in restored marsh sites was 2–16 cm lower than their natural references. Restored marshes where porewater chemistry was similar to the natural reference had greater plant aboveground biomass, gross ecosystem production, ecosystem respiration, as well as net ecosystem CO 2 exchange (NEE) than the natural reference, even though they had the same plant species. We also compared respiration rates in aboveground biomass (AR) and soil (BR) during July 2016, and found that restored marshes had higher AR and BR fluxes than natural references. Our findings indicated that well-restored salt marshes can result in greater plant biomass and NEP, which has the potential to enhance rates of C sequestration at 10-yrs post restoration. Those differences were likely due to lower elevation and greater flooding frequency in the recently restored marshes than the natural marsh. The inverse relationship between elevation and productivity further suggests that, where sea-level rise rate does not surpass the threshold of plant survival, the restoration of these salt marshes may lead to enhanced organic and mineral sedimentation, extending marsh survival under increased sea level, and recouping carbon stocks that were lost during decades of tidal restriction.

Massachusetts↗
USGS2021

Trends in nitrogen, phosphorus, and sediment concentrations and loads in streams draining to Lake Tahoe, California, Nevada, USA

Lake Tahoe, a large freshwater lake of the eastern Sierra Nevada in California and Nevada, has 63 tributaries that are sources of nutrients and sediment to the lake. The Tahoe watershed is relatively small, and the surface area of the lake occupies about 38% of the watershed area (1313 km 2 ). Only about 6% of the watershed is urbanized or residential land, and as part of a plan to maintain water clarity, wastewater is exported out of the basin. The lake's clarity has been diminishing due to algae and fine sediment, prompting development of management plans. Much of the annual discharge and nutrient load to the lake results from snowmelt in the spring and summer months. To understand the relative importance of land use, climate, forest management, and other factors affecting trends in nutrient stream concentrations and loads, a Weighted Regression on Time Discharge and Season (WRTDS) model simulated these trends over a time frame of >25 years (mid-1970s to 2017). All studied locations generally show nitrate concentration and load trending down. Ammonium concentration and load initially trended down then increased continuously after 2005. Some locations show initially decreasing orthophosphate trends, followed by small significant increases in concentration and loads starting around 2000 to 2005. Total Kjeldahl nitrogen, total phosphorus and suspended sediment mostly trended downward. Overall, the trends in various forms of nitrogen were observed at most sites irrespective of the degree of development and indicate a change in ecological conditions is affecting the nitrogen cycle throughout the watershed, most likely attributable to forest aggradation and fire suppression. Ratios of bioavailable nitrogen in the form of nitrate and ammonium to orthophosphate have also trended downward during the period of record suggesting a shift of these streams from phosphorus limited to nitrogen limited.

California, Nevada↗