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Habitat evaluation using GIS a case study applied to the San Joaquin Kit Fox

Concern over the fate of plant and animal species throughout the world has accelerated over recent decades. Habitat loss is considered the main culprit in reducing many species' abundance and range, leading to numerous efforts to plan and manage habitat preservation. Our work uses Geographic Information Systems (GIS) data and modeling to define a spatially explicit analysis of habitat value, using the San Joaquin Kit Fox (Vulpes macrotis mutica) of California (USA) as an example. Over the last 30 years, many field studies and surveys have enhanced our knowledge of the life history, behavior, and needs of the kit fox, which has been proposed as an umbrella or indicator species for grassland habitat in the San Joaquin Valley of California. There has yet been no attempt to convert much of this field knowledge into a model of spatial habitat value useful for planning purposes. This is a significant omission given the importance and visibility of the imperiled kit fox and increasing trends toward spatially explicit modeling and planning. In this paper we apply data from northern California to derive a small-cell GIS raster of habitat value for the kit fox that incorporates both intrinsic habitat quality and neighborhood context, as well the effects of barriers such as roads. Such a product is a useful basis for assessing the presence and amounts of good (and poor) quality habitat and for eventually constructing GIS representations of viable animal territories that could be included in future reserves. ?? 2001 Elsevier Science B.V.

Landscape and Urban Planning↗

Chronology and geochemistry of late Holocene eolian deposits in the Brandon Sand Hills, Manitoba, Canada

Accelerator mass spectrometry and conventional radiocarbon age determinations of organic matter from paleosols indicate that the Brandon Sand Hills area of southern Manitoba has been subjected to recurrent intervals of eolian activity in the past 5000 years. Although precise regional correlations are precluded by dating uncertainties, periods of most notable paleosol development occurred around 2300 to 2000, 1400 to 1000, and 600 to 500 cal yr BP with eolian activity occurring before and after each of these periods. Episodes of eolian activity may correspond to periods of regional drought, whereas paleosols mark periods of increased moisture availability and stabilization by vegetation. The geochemistry of the eolian sands, paleosols and source sediments indicates that partial leaching of carbonates occurs from pedogenesis during humid climatic phases, and that this is probably the primary mechanism of carbonate depletion of eolian sands in this area. Recent trends in sand dune activity from historic aerial photography and early explorers' accounts indicate that the few active dunes that presently exist have stabilized at a rate of 10-20% per decade, despite several severe droughts in the 20th century. This may be attributed to pre-settlement droughts that were more severe than those in historic times although regional dune stabilization may also be related, in part, to the spread of forest cover in the past few hundred years. Crown copyright (C) 2000 Published by Elsevier Science Ltd. All rights reserved.

Quaternary International↗

Choosing and using climate change scenarios for ecological-impact assessments and conservation decisions

Increased concern over climate change is demonstrated by the many efforts to assess climate effects and develop adaptation strategies. Scientists, resource managers, and decision makers are increasingly expected to use climate information, but they struggle with its uncertainty. With the current proliferation of climate simulations and downscaling methods, scientifically credible strategies for selecting a subset for analysis and decision making are needed. Drawing on a rich literature in climate science and impact assessment and on experience working with natural resource scientists and decision makers, we devised guidelines for choosing climate-change scenarios for ecological impact assessment that recognize irreducible uncertainty in climate projections and address common misconceptions about this uncertainty. This approach involves identifying primary local climate drivers by climate sensitivity of the biological system of interest; determining appropriate sources of information for future changes in those drivers; considering how well processes controlling local climate are spatially resolved; and selecting scenarios based on considering observed emission trends, relative importance of natural climate variability, and risk tolerance and time horizon of the associated decision. The most appropriate scenarios for a particular analysis will not necessarily be the most appropriate for another due to differences in local climate drivers, biophysical linkages to climate, decision characteristics, and how well a model simulates the climate parameters and processes of interest. Given these complexities, we recommend interaction among climate scientists, natural and physical scientists, and decision makers throughout the process of choosing and using climate-change scenarios for ecological impact assessment.

Conservation Biology↗

Fate and transport of pesticides in the ground water systems of southwest Georgia, 1993-2005

Modern agricultural practices in the United States have resulted in nearly unrivaled efficiency and productivity. Unfortunately, there is also the potential for release of these compounds to the environment and consequent adverse affects on wildlife and human populations. Since 1993, the National Water-Quality Assessment (NAWQA) program of the U.S. Geological Survey has evaluated water quality in agricultural areas to address these concerns. The objective of this study is to evaluate trends in pesticide concentrations from 1993-2005 in the surficial and Upper Floridan aquifers of southwest Georgia using pesticide and pesticide degradate data collected for the NAWQA program. There were six compounds - five herbicides and one degradate - that were detected in more than 20% of samples: atrazine, deethylatrazine (DEA), metolachlor, alachlor, floumeturon, and tebuthiuron. Of the 128 wells sampled during the study, only eight wells had pesticide concentrations that either increased (7) or decreased (1) on a decadal time scale. Most of the significant trends were increasing concentrations of pesticides in older water; median pesticide concentrations did not differ between the surficial and Upper Floridan aquifers from 1993 and 2005. Deethylatrazine, in the Upper Floridan aquifer, was the only compound that had a significant change (increase) in concentration during the study. The limited number of wells with increases in pesticide concentrations suggest that ground-water sources of these compounds are not increasing in concentration over the time scale represented in this study. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Conference Paper↗

A summary of the U.S. Geological Survey National Water-Quality Assessment program

Beginning in 1986, the Congress appropriated funds for the U.S. Geological Survey to test and refine concepts for a National Water Quality Assessment Program. At present, the program is in a pilot phase with field studies occurring in seven areas around the Nation. In 1990, a committee of the National Academy of Sciences will complete an evaluation of the design and potential utility of the program. A decision about moving to full-scale implementation will be made upon completion of this evaluation. The program is intended to address a wide range of national water quality issues that include chemical contamination, acidification, eutrophication, salinity, sedimentation, and sanitary quality. The goals of the program are to: (1) provide nationally consistent descriptions of current water quality conditions for a large part of the Nation 's water resources; (2) define long-term trends (or lack of trends) in water quality; and (3) identify and describe the relations of both current conditions and trends in water quality to natural and human factors. This information will be provided to water managers, policy makers, and the public to provide an improved scientific basis for evaluating the effectiveness of water quality management programs and for predicting the likely effects of contemplated changes in land- and water-management practices. (USGS)

Open-File Report↗

Postglacial eruptive history of Laguna del Maule volcanic field and constraints on its magmatic system

The Laguna del Maule (LdM) volcanic field has produced >100 explosive and extrusive events over the past 17 ka. More than two-thirds of these have been silicic, with most being postglacial rhyolites (72–78 % SiO 2 ) concentrated near the eponymous lake (LdM), an extraordinary anomaly in the Quaternary Andes and unprecedented in this 1.5–Ma-old volcanic field as a whole. The postglacial field includes >70 separate vents distributed over ∼360 km 2 that together produced the many distinct eruptive events, of which 55 are rhyolitic (73 %−77 % SiO 2 ), 18 are rhyodacitic (68 %−72 % SiO 2 ), 4 are dacitic (63 %–66 % SiO 2 ), 26 are intermediate (54–62 % SiO 2 ), and 2 are true basalts (50 %–53 % SiO 2 ). Of these, most originated from single-vent domes, cones, or craters that erupted effusive and/or explosive products, each with relatively short lifespans. Some originated from multi-vent centers, the largest one being the Barrancas complex southeast of the lake, which has as many as 18 vents that erupted over as much as 10 kyr. The LdM basin itself is ringed by 13 separate silicic centers, many of which are also multi-vent and built over time by multiple explosive and extrusive events. These surround the lake, near the middle of which is the vent for the high-silica rhyolite Plinian eruption that produced the “ Rhyolite of Laguna del Maule ”, which was the first and largest silicic event from the postglacial field. Explosive and effusive products from all these events have been put in a time-stratigraphic framework supported by radiocarbon dating and chemical analyses to reconstruct the postglacial eruptive history. Correlations of pyroclastics to eruptive vents have provided a spatial-temporal framework that helps characterize the magmatic system beneath the LdM field. Distribution of both silicic and mafic vents support the likelihood that two separate magmatic systems produced the postglacial eruptions in the volcanic field—one in the Laguna del Maule basin and the other at the Barrancas complex—with a cluster of silicic vents at each and mafic vents situated between the two. Vent distributions, compositions of eruptive products, and temporal and spatial trends of eruptive units suggest that the abundant rhyodacitic and mafic units in the LdM basin have no common magma reservoir, but instead each had its own evolutionary trend. In contrast, there is enough affinity among some of the rhyolitic units in the Basin to imply magmatic connections and/or continuity that span both time and space, although neither geographic proximity nor temporal similarity have singular control on LdM-basin rhyolite compositions. Compositional trends through time at the Barrancas center suggest the rhyolitic eruptions at West and East Barrancas were derived from separate, zoned reservoirs that were tapped in batches, not permitting development of a large high-silica reservoir such as that beneath the LdM basin.

Laguna del Maule lake basin↗

Ecological change drives a decline in mercury concentrations in southern Beaufort Sea polar bears

We evaluated total mercury (THg) concentrations and trends in polar bears from the southern Beaufort Sea subpopulation from 2004 to 2011. Hair THg concentrations ranged widely among individuals from 0.6 to 13.3 μg g –1 dry weight (mean: 3.5 ± 0.2 μg g –1 ). Concentrations differed among sex and age classes: solitary adult females ≈ adult females with cubs ≈ subadults > adult males ≈ yearlings > cubs-of-the-year ≈ 2 year old dependent cubs. No variation was observed between spring and fall samples. For spring-sampled adults, THg concentrations declined by 13% per year, contrasting recent trends observed for other Western Hemispheric Arctic biota. Concentrations also declined by 15% per year considering adult males only, while a slower, nonsignificant decrease of 4.4% per year was found for adult females. Lower THg concentrations were associated with higher body mass index (BMI) and higher proportions of lower trophic position food resources consumed. Because BMI and diet were related, and the relationship to THg was strongest for BMI, trends were re-evaluated adjusting for BMI as the covariate. The adjusted annual decline was not significant. These findings indicate that changes in foraging ecology, not declining environmental concentrations of mercury, are driving short-term declines in THg concentrations in southern Beaufort Sea polar bears.

Alaska↗

Water priorities for the nation—The U.S. Geological Survey next generation water observing system

The challenges of providing safe and sustainable water supplies for human and ecological uses and protecting lives and property during water emergencies are well recognized. The U.S. Geological Survey (USGS) plays an essential role in meeting these challenges through its observational networks and renowned water science and research activities (National Academies of Science, Engineering, and Medicine, 2018). Substantial advances in water science, together with emerging breakthroughs in technical and computational capabilities, have led the USGS to develop a Next Generation Water Observing System (NGWOS) . The NGWOS will provide real-time data on water quantity and quality in more affordable and rapid ways than previously possible, and in more locations. The data will be served through a modernized USGS National Water Information System that will be coupled to advanced modeling tools to inform daily water operations, decision-making during water emergencies (like floods, droughts, and contaminant spills), assessments of past trends in water quantity and quality, and forecasts of future water availability.

Fact Sheet↗

Linking physical monitoring to coho and Chinook salmon populations in the Redwood Creek Watershed, California—Summary of May 3–4, 2012 Workshop

On Thursday, May 3, 2012, a science workshop was held at the Redwood National and State Parks (RNSP) office in Arcata, California, with researchers and resource managers working in RNSP to share data and expert opinions concerning salmon populations and habitat in the Redwood Creek watershed. The focus of the workshop was to discuss how best to synthesize physical and biological data related to the freshwater and estuarine phases of salmon life cycles in order to increase the understanding of constraints on salmon populations. The workshop was hosted by the U.S. Geological Survey (USGS) Status and Trends (S&T) Program National Park Monitoring Project ( http://www.fort.usgs.gov/brdscience/ParkMonitoring.htm ), which supports USGS research on priority topics (themes) identified by the National Park Service (NPS) Inventory and Monitoring Program (I&M) and S&T. The NPS has organized more than 270 parks with significant natural resources into 32 Inventory and Monitoring (I&M) Networks ( http://science.nature.nps.gov/im/networks.cfm ) that share funding and core professional staff to monitor the status and long-term trends of selected natural resources ( http://science.nature.nps.gov/im/monitor ). All 32 networks have completed vital signs monitoring plans (available at http://science.nature.nps.gov/im/monitor/MonitoringPlans.cfm ), containing background information on the important resources of each park, conceptual models behind the selection of vital signs for monitoring the condition of natural resources, and the selection of high priority vital signs for monitoring. Vital signs are particular physical, chemical, and biological elements and processes of park ecosystems that represent the overall health or condition of the park, known or hypothesized effects of stressors, or elements that have important human values (Fancy and others, 2009). Beginning in 2009, the I&M program funded projects to analyze and synthesize the biotic and abiotic data generated by vital signs monitoring and previous in-park natural resource monitoring and inventories to provide useful information, models, and tools to park managers for addressing resource management issues. The workshop described in this report is an element of the project funded by USGS NPS-I&M program to conduct a synthesis of salmon-related datasets in the Klamath (KLMN) and San Francisco Bay Area (SFAN) networks of national parks. The synthesis focused on four park units: Redwood National Park (KLMN), Point Reyes National Seashore, Muir Woods National Monument, and Golden Gate National Recreation Area (SFAN).

California↗

Land cover and forest formation distributions for St. Kitts, Nevis, St. Eustatius, Grenada and Barbados from decision tree classification of cloud-cleared satellite imagery

Satellite image-based mapping of tropical forests is vital to conservation planning. Standard methods for automated image classification, however, limit classification detail in complex tropical landscapes. In this study, we test an approach to Landsat image interpretation on four islands of the Lesser Antilles, including Grenada and St. Kitts, Nevis and St. Eustatius, testing a more detailed classification than earlier work in the latter three islands. Secondly, we estimate the extents of land cover and protected forest by formation for five islands and ask how land cover has changed over the second half of the 20th century. The image interpretation approach combines image mosaics and ancillary geographic data, classifying the resulting set of raster data with decision tree software. Cloud-free image mosaics for one or two seasons were created by applying regression tree normalization to scene dates that could fill cloudy areas in a base scene. Such mosaics are also known as cloud-filled, cloud-minimized or cloud-cleared imagery, mosaics, or composites. The approach accurately distinguished several classes that more standard methods would confuse; the seamless mosaics aided reference data collection; and the multiseason imagery allowed us to separate drought deciduous forests and woodlands from semi-deciduous ones. Cultivated land areas declined 60 to 100 percent from about 1945 to 2000 on several islands. Meanwhile, forest cover has increased 50 to 950%. This trend will likely continue where sugar cane cultivation has dominated. Like the island of Puerto Rico, most higher-elevation forest formations are protected in formal or informal reserves. Also similarly, lowland forests, which are drier forest types on these islands, are not well represented in reserves. Former cultivated lands in lowland areas could provide lands for new reserves of drier forest types. The land-use history of these islands may provide insight for planners in countries currently considering lowland forest clearing for agriculture. Copyright 2008 College of Arts and Sciences.

Caribbean Journal of Science↗

Trends in mercury wet deposition and mercury air concentrations across the U.S. and Canada

This study examined the spatial and temporal trends of mercury (Hg) in wet deposition and air concentrations in the United States (U.S.) and Canada between 1997 and 2013. Data were obtained from the National Atmospheric Deposition Program (NADP) and Environment Canada monitoring networks, and other sources. Of the 19 sites with data records from 1997–2013, 53% had significant negative trends in Hg concentration in wet deposition, while no sites had significant positive trends, which is in general agreement with earlier studies that considered NADP data up until about 2010. However, for the time period 2007–2013 (71 sites), 17% and 13% of the sites had significant positive and negative trends, respectively, and for the time period 2008–2013 (81 sites) 30% and 6% of the sites had significant positive and negative trends, respectively. Non-significant positive tendencies were also widespread. Regional trend analyses revealed significant positive trends in Hg concentration in the Rocky Mountains, Plains, and Upper Midwest regions for the recent time periods in addition to significant positive trends in Hg deposition for the continent as a whole. Sulfate concentration trends in wet deposition were negative in all regions, suggesting a lower importance of local Hg sources. The trend in gaseous elemental Hg from short-term datasets merged as one continuous record was broadly consistent with trends in Hg concentration in wet deposition, with the early time period (1998–2007) producing a significantly negative trend (− 1.5 ± 0.2% year − 1 ) and the recent time period (2008–2013) displaying a flat slope (− 0.3 ± 0.1% year − 1 , not significant). The observed shift to more positive or less negative trends in Hg wet deposition primarily seen in the Central-Western regions is consistent with the effects of rising Hg emissions from regions outside the U.S. and Canada and the influence of long-range transport in the free troposphere.

Science of the Total Environment↗

Controls of tectonics and sediment source locations on along-strike variations in transgressive deposits on the northern California margin

We identify two surfaces in the shallow subsurface on the Eel River margin offshore northern California, a lowstand erosion surface, likely formed during the last glacial maximum, and an overlying surface likely formed during the most recent transgression of the shoreline. The lowstand erosion surface, which extends from the inner shelf to near the shelfbreak and from the Eel River to Trinidad Head (???80 km), truncates underlying strata on the shelf. Above the surface, inferred transgressive coastal and estuarine sedimentary units separate it from the transgressive surface on the shelf. Early in the transgression, Eel River sediment was likely both transported down the Eel Canyon and dispersed on the slope, allowing transgressive coastal sediment from the smaller Mad River to accumulate in a recognizable deposit on the shelf. The location of coastal Mad River sediment accumulation was controlled by the location of the paleo-Mad River. Throughout the remainder of the transgression, dispersed sediment from the Eel River accumulated an average of 20 m of onlapping shelf deposits. The distribution and thickness of these transgressive marine units was strongly modified by northwest-southeast trending folds. Thick sediment packages accumulated over structural lows in the lowstand surface. The thinnest sediment accumulations (0-10 m) were deposited over structural highs along faults and uplifting anticlines. The Eel margin, an active margin with steep, high sediment-load streams, has developed a thick transgressive systems tract. On this margin sediment accumulates as rapidly as the processes of uplift and downwarp locally create and destroy accommodation space. Sequence stratigraphic models of tectonically active margins should account for variations in accommodation space along margins as well as across them. ?? 2003 Elsevier Science B.V. All rights reserved.

Marine Geology↗

Coastal-change and glaciological map of the Trinity Peninsula area and south Shetland Islands, Antarctica: 1843-2001: Chapter A in Coastal-change and glaciological maps of Antarctica

Changes in the area and volume of polar ice sheets are intricately linked to changes in global climate, and the resulting changes in sea level could severely impact the densely populated coastal regions on Earth. Melting of the West Antarctic part alone of the Antarctic ice sheet would cause a sea-level rise of approximately 6 meters (m). The potential sea-level rise after melting of the entire Antarctic ice sheet is estimated to be 65 m (Lythe and others, 2001) to 73 m (Williams and Hall, 1993). In addition to its importance, the mass balance (the net volumetric gain or loss) of the Antarctic ice sheet is highly complex, responding differently to different conditions in each region (Vaughan, 2005). In a review paper, Rignot and Thomas (2002) concluded that the West Antarctic ice sheet is probably becoming thinner overall; although it is thickening in the west, it is thinning in the north. Thomas and others (2004), on the basis of aircraft and satellite laser altimetry surveys, believe the thinning may be accelerating. Joughin and Tulaczyk (2002), on the basis of analysis of ice-flow velocities derived from synthetic aperture radar, concluded that most of the Ross ice streams (ice streams on the east side of the Ross Ice Shelf) have a positive mass balance, whereas Rignot and others (2004) infer even larger negative mass balance for glaciers flowing northward into the Amundsen Sea, a trend suggested by Swithinbank and others (2003a,b, 2004). The mass balance of the East Antarctic ice sheet is thought by Davis and others (2005) to be strongly positive on the basis of the change in satellite altimetry measurements made between 1992 and 2003. Measurement of changes in area and mass balance of the Antarctic ice sheet was given a very high priority in recommendations by the Polar Research Board of the National Research Council (1986), in subsequent recommendations by the Scientific Committee on Antarctic Research (SCAR) (1989, 1993), and by the National Science Foundation's (1990) Division of Polar Programs. On the basis of these recommendations, the U.S. Geological Survey (USGS) decided that the archive of early 1970s Landsat 1, 2, and 3 Multispectral Scanner (MSS) images of Antarctica and the subsequent repeat coverage made possible with Landsat and other satellite images provided an excellent means of documenting changes in the coastline of Antarctica (Ferrigno and Gould, 1987). The availability of this information provided the impetus for carrying out a comprehensive analysis of the glaciological features of the coastal regions and changes in ice fronts of Antarctica (Swithinbank, 1988; Williams and Ferrigno, 1988). The project was later modified to include Landsat 4 and 5 MSS and Thematic Mapper (TM) [and in some areas Landsat 7 Enhanced Thematic Mapper Plus (ETM+)], RADARSAT images, and other data where available, to compare changes that occurred during a 20- to 25- or 30-year time interval (or longer where data were available, as in the Antarctic Peninsula). The results of the analysis are being used to produce a digital database and a series of USGS Geologic Investigations Series Maps (I–2600) consisting of 23 maps at 1:1,000,000 scale and 1 map at 1:5,000,000 scale, in both paper and digital format (Williams and others, 1995; Williams and Ferrigno, 1998; Ferrigno and others, 2002).

IMAP↗

Coastal-Change and Glaciological Map of the Northern Ross Ice Shelf Area, Antarctica: 1962-2004

Changes in the area and volume of polar ice sheets are intricately linked to changes in global climate, and the resulting changes in sea level could severely impact the densely populated coastal regions on Earth. Melting of the West Antarctic part alone of the Antarctic ice sheet would cause a sea-level rise of approximately 6 meters (m). The potential sea-level rise after melting of the entire Antarctic ice sheet is estimated to be 65 m (Lythe and others, 2001) to 73 m (Williams and Hall, 1993). The mass balance (the net volumetric gain or loss) of the Antarctic ice sheet is highly complex, responding differently to different conditions in each region (Vaughan, 2005). In a review paper, Rignot and Thomas (2002) concluded that the West Antarctic ice sheet is probably becoming thinner overall; although it is thickening in the west, it is thinning in the north. Thomas and others (2004), on the basis of aircraft and satellite laser altimetry surveys, believe the thinning may be accelerating. Joughin and Tulaczyk (2002), on the basis of analysis of ice-flow velocities derived from synthetic aperture radar, concluded that most of the Ross ice streams (ice streams on the east side of the Ross Ice Shelf) have a positive mass balance, whereas Rignot and others (2004) infer even larger negative mass balance for glaciers flowing northward into the Amundsen Sea, a trend suggested by Swithinbank and others (2003a,b; 2004). The mass balance of the East Antarctic ice sheet is thought by Davis and others (2005) to be strongly positive on the basis of the change in satellite altimetry measurements made between 1992 and 2003. Measurement of changes in area and mass balance of the Antarctic ice sheet was given a very high priority in recommendations by the Polar Research Board of the National Research Council (1986), in subsequent recommendations by the Scientific Committee on Antarctic Research (SCAR) (1989, 1993), and by the National Science Foundation?s (1990) Division of Polar Programs. On the basis of these recommendations, the U.S. Geological Survey (USGS) decided that the archive of early 1970s Landsat 1, 2, and 3 Multispectral Scanner (MSS) images of Antarctica and the subsequent repeat coverage made possible with Landsat and other satellite images provided an excellent means of documenting changes in the coastline of Antarctica (Ferrigno and Gould, 1987). The availability of this information provided the impetus for carrying out a comprehensive analysis of the glaciological features of the coastal regions and changes in ice fronts of Antarctica (Swithinbank, 1988; Williams and Ferrigno, 1988). The project was later modified to include Landsat 4 and 5 MSS and Thematic Mapper (TM) images (and in some areas Landsat 7 Enhanced Thematic Mapper Plus [ETM+] images), RADARSAT images, and other data where available, in order to compare changes that occurred during a 20- to 25- or 30-year time interval (or longer where data were available, as in the Antarctic Peninsula). The results of the analysis are being used to produce a digital database and a series of USGS Geologic Investigations Series Maps (I?2600) (Williams and others, 1995; Williams and Ferrigno, 1998; Ferrigno and others, 2002) (available online at http://www.glaciers.er.usgs.gov).

IMAP↗

Long-term trends in a Dimictic Lake

The one-dimensional hydrodynamic ice model, DYRESM-WQ-I, was modified to simulate ice cover and thermal structure of dimictic Lake Mendota, Wisconsin, USA, over a continuous 104-year period (1911–2014). The model results were then used to examine the drivers of changes in ice cover and water temperature, focusing on the responses to shifts in air temperature, wind speed, and water clarity at multiyear timescales. Observations of the drivers include a change in the trend of warming air temperatures from 0.081 °C per decade before 1981 to 0.334 °C per decade thereafter, as well as a shift in mean wind speed from 4.44 m s −1 before 1994 to 3.74 m s −1 thereafter. Observations show that Lake Mendota has experienced significant changes in ice cover: later ice-on date(9.0 days later per century), earlier ice-off date (12.3 days per century), decreasing ice cover duration (21.3 days per century), while model simulations indicate a change in maximum ice thickness (12.7 cm decrease per century). Model simulations also show changes in the lake thermal regime of earlier stratification onset (12.3 days per century), later fall turnover (14.6 days per century), longer stratification duration (26.8 days per century), and decreasing summer hypolimnetic temperatures (−1.4 °C per century). Correlation analysis of lake variables and driving variables revealed ice cover variables, stratification onset, epilimnetic temperature, and hypolimnetic temperature were most closely correlated with air temperature, whereas freeze-over water temperature, hypolimnetic heating, and fall turnover date were more closely correlated with wind speed. Each lake variable (i.e., ice-on and ice-off dates, ice cover duration, maximum ice thickness, freeze-over water temperature, stratification onset, fall turnover date, stratification duration, epilimnion temperature, hypolimnion temperature, and hypolimnetic heating) was averaged for the three periods (1911–1980, 1981–1993, and 1994–2014) delineated by abrupt changes in air temperature and wind speed. Average summer hypolimnetic temperature and fall turnover date exhibit significant differences between the third period and the first two periods. Changes in ice cover (ice-on and ice-off dates, ice cover duration, and maximum ice thickness) exhibit an abrupt change after 1994, which was related in part to the warm El Niño winter of 1997–1998. Under-ice water temperature, freeze-over water temperature, hypolimnetic temperature, fall turnover date, and stratification duration demonstrate a significant difference in the third period (1994–2014), when air temperature was warmest and wind speeds decreased rather abruptly. The trends in ice cover and water temperature demonstrate responses to both long-term and abrupt changes in meteorological conditions that can be complemented with numerical modeling to better understand how these variables will respond in a future climate.

Wisconsin↗

Recent, widespread nitrate decreases may be linked to persistent dissolved organic carbon increases in headwater streams recovering from past acidic deposition

Long-term monitoring of water quality responses to natural and anthropogenic perturbation of watersheds informs policies for managing natural resources. Dissolved organic carbon (DOC) and nitrate (NO 3 − ) in streams draining forested landscapes provide valuable information on ecosystem function due to their biogeochemical reactivity and solubility in water. Here we evaluate a 20-year record (2001−2021) of biweekly stream-water samples ( n > 3000) and continuous discharge in three forested catchments in the Adirondack region of New York to investigate and interpret long-term trends in DOC and NO 3 − concentrations. Results from the intensively monitored catchments were compared with data from synoptic surveys of streams throughout the Adirondack region. A weighted regressions on time, discharge, and season (WRTDS) model, used to estimate daily flow-normalized concentrations, determined that DOC increased by ~30 to 50 % while NO 3 − decreased by ~50 to 70 % over the study period. The large amount of data from catchments with different soil properties permitted us to assess the relative effects of hydrology, season, and land cover factors on temporal trends in DOC and NO 3 − concentrations. We found weak evidence of climatic forcing of long-term increases in DOC, and instead contend that declining ionic strength in precipitation linked to declining anthropogenic acid deposition is driving DOC trends in stream waters. Nitrate concentrations were more variable but clearly decreased in recent years possibly related to declining N deposition. The recent increase in DOC:NO 3 − in all catchments indicates a major shift in stream stoichiometry that reflects changes in ecosystem functioning that may have important biogeochemical implications for terrestrial as well as aquatic ecosystems.

Science of the Total Environment↗

Transport of chemical and microbial compounds from known wastewater discharges: Potential for use as indicators of human fecal contamination

The quality of drinking and recreational water is currently (2005) determined using indicator bacteria. However, the culture tests used to analyze for these bacteria require a long time to complete and do not discriminate between human and animal fecal material sources. One complementary approach is to use chemicals found in human wastewater, which would have the advantages of (1) potentially shorter analysis times than the bacterial culture tests and (2) being selected for human-source specificity. At 10 locations, water samples were collected upstream and at two successive points downstream from a wastewaster treatment plant (WWTP); a treated effluent sample was also collected at each WWTP. This sampling plan was used to determine the persistence of a chemically diverse suite of emerging contaminants in streams. Samples were also collected at two reference locations assumed to have minimal human impacts. Of the 110 chemical analytes investigated in this project, 78 were detected at least once. The number of compounds in a given sample ranged from 3 at a reference location to 50 in a WWTP effluent sample. The total analyte load at each location varied from 0.018 μg/L at the reference location to 97.7 μg/L in a separate WWTP effluent sample. Although most of the compound concentrations were in the range of 0.01−1.0 μg/L, in some samples, individual concentrations were in the range of 5−38 μg/L. The concentrations of the majority of the chemicals present in the samples generally followed the expected trend:  they were either nonexistent or at trace levels in the upstream samples, had their maximum concentrations in the WWTP effluent samples, and then declined in the two downstream samples. This research suggests that selected chemicals are useful as tracers of human wastewater discharge.

Environmental Science & Technology↗

Contaminant trends in reservoir sediment cores as records of influent stream quality

When reconstructing water-quality histories from lake and reservoir cores, it is sometimes assumed that the chemical signatures in the cores reflect historical water quality in the influent streams. To investigate this assumption, concentrations of metals, PAHs, and organochlorine compounds in sediment cores were compared to those associated with an influent-stream suspended sediment for three reservoirs in Fort Worth, TX, and two reservoirs in Boston, MA, U.S.A., and interpreted in light of land-use and regulation histories. In evaluating relations between suspended sediments and cores, three levels of preservation were indicated: (1) influent concentrations and historical trends are preserved in cores (metals at all sites; some organic contaminants at some sites); (2) some loss occurs during transport and initial deposition but relative historical trends are preserved in cores (some organic contaminants at some sites); and (3) neither stream concentrations nor relative historical trends are preserved (dieldrin and p,p???-DDT). The degree of preservation of influent concentration histories varied between lakes, particularly for PAHs. The results support the use of sediment cores to infer streamwater-quality histories for many contaminants but indicate that reservoir-bottom sediment samples might underestimate concentrations of organic contaminants in some streams.

Environmental Science & Technology↗