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USGS2024

Quality of groundwater used for domestic supply in the eastern Sacramento Valley and adjacent foothills, California

Summary More than 2 million Californians rely on groundwater from privately owned domestic wells for drinking-water supply. This report summarizes a water-quality survey of domestic and small-system drinking-water supply wells in the eastern Sacramento Valley and adjacent foothills where more than 25,000 residents are estimated to use privately owned domestic wells. Study results show that inorganic and organic constituents in groundwater were present above regulatory (maximum contaminant level, MCL) benchmarks for public drinking-water quality in 8 and 3 percent, respectively, of the aquifer area used for domestic drinking-water supply (herein, “domestic groundwater resources”; fig. 1). The only inorganic constituent detected above regulatory benchmarks was arsenic. The only organic constituent exceeding regulatory benchmarks was the fumigant 1,2,3-trichloropropane (1,2,3-TCP). Three additional organic constituents—the disinfection by-product chloroform, the gasoline oxygenate methyl tert -butyl ether (MTBE), and the solvent tetrachloroethene (PCE)—were detected at low concentrations below one-tenth of regulatory benchmarks in 34, 10, and 10 percent of domestic groundwater resources, respectively. Total dissolved solids (TDS), iron, and manganese exceeded non-regulatory aesthetic guidelines for drinking water in 5, 10, and 26 percent of domestic groundwater resources, respectively. Per- and polyfluoroalkyl substances (PFASs) were detected in 29 percent of domestic groundwater resources,with 5 percent exceeding the recently enacted (April 2024) U.S. Environmental Protection Agency MCLs. Total coliform and enterococci bacteria were detected in 13 and 8 percent of domestic groundwater resources, respectively. Redox sensitive constituents in this study included arsenic, manganese, nitrate, and iron. In the lower elevation portions of the eastern Sacramento Valley study area, reducing conditions in groundwater aquifers promote elevated arsenic, iron, and manganese, and conversely lower concentrations of nitrate. The presence of the volatile organic compound (VOC) 1,2,3-TCP was related to its past history in select agricultural land uses (on orchards or vineyards) in the Sacramento Valley; however, unlike in the San Joaquin Valley where orchards and vineyards are more common, its detection frequency was low (only detected in one well in this study). Chloroform was frequently detected in this study at low levels. Chloroform is a disinfection byproduct commonly found in domestic wells treated by shock chlorination. The solvent PCE is among the most frequently detected VOCs in groundwater, which is primarily related to its long history of use and its persistence in groundwater in oxic conditions. The gasoline oxygenate MTBE was a contaminant introduced to groundwater through atmospheric exchange when it was used as a fuel additive to decrease smog inducing emissions from vehicles. Its occurrence in groundwater at low levels is expected and makes it a potentially useful tracer of relatively recent recharge water being withdrawn from wells. The PFASs are anthropogenic chemicals with hundreds of uses, and they have been incorporated into many different products, processes, and applications worldwide. Like MTBE, the occurrence of PFASs in groundwater may be in part due to atmospheric exchange, but there are several other pathways that contribute PFASs to the environment.

California↗
USGS2026

Groundwater-level elevations in the bedrock aquifers of the Denver Basin aquifer system, Elbert County, Colorado, 2015–23

Water users in Elbert County, Colorado, rely on groundwater from bedrock aquifers in the Denver Basin aquifer system (upper Dawson, lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers) for approximately half of their water uses. Withdrawals from the bedrocks aquifers have increased to meet the water use needs of expanding regional population growth and development. The U.S. Geological Survey, in cooperation with the Elbert County Board of County Commissioners, began a study in 2015 to monitor groundwater levels within Elbert County. The primary purpose of this report is to present a summary of groundwater levels measured during the study period (2015–23) and present results from statistical analyses of changes in groundwater-level elevations through time. Discrete groundwater levels were measured at 36 wells within Elbert County. Seven of those wells contained equipment to make and record continuous groundwater-level measurements at hourly intervals. All aquifers, except the lower Dawson aquifer, had only declining groundwater-level elevations in discrete measurements for wells with statistically significant trends. Of the eight statistically significant trends in the lower Dawson aquifer, two wells indicated increasing groundwater-level elevation from discrete measurements. The groundwater-level elevation trend medians in the upper Dawson, lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers were −0.23, −0.66, −0.64, −0.39, and −0.63 feet per year, respectively, for discrete groundwater-level elevation measurements. Trends in continuous groundwater-level elevations were in agreement with statistically significant trends in discrete groundwater-level elevations for all wells. The groundwater-level elevation trend medians in this study, compared to the overall trends in a 2015−2018 study, both indicated declining groundwater-level elevations except in the upper Dawson aquifer, where the trend direction was opposite, a positive trend from 2015 to 2018 and a negative trend (declining groundwater elevations) from 2015 to 2023. The change in trends within the upper Dawson aquifer may be affected by differences in the study period and the trend analysis applied. Trends during the 2015–23 study period were compared to departures from the median 2015 groundwater-level elevation for each site in each aquifer. In general, the departures from the 2015 median supported trends observed at each site and correlated spatially with greater departures near the western border of Elbert County. Additionally, 30-year precipitation data showing wet and dry periods were overlaid with the departure from the 2015 median to assess groundwater-level patterns in wells in the five aquifers. Departures from the 2015 median groundwater-level elevations appeared greatest during the dry period between 2020 and 2023. Potentiometric-surface maps of the upper and lower Dawson aquifers created from static April 2023 groundwater elevations indicated groundwater-flow direction is generally from the south to the north. Results of this study could be used to guide additional groundwater monitoring in Elbert County and could aid in long-term planning of water resources.

Colorado↗
USGS2024

Cold blood in warming waters: Effects of air temperature, precipitation, and groundwater on Gulf Sturgeon thermal habitats in a changing climate

Objective In a changing climate, the effects of air temperature, precipitation, and groundwater on water temperature and thermal habitat suitability for Gulf Sturgeon Acipenser desotoi , listed as threatened under the U.S. Endangered Species Act, are not well understood. Hence, we incorporated these factors into thermal habitat models to forecast how Gulf Sturgeon may be affected by wide‐ranging climate change scenarios in 2024–2074. Methods Using data from the Choctawhatchee River, Florida, we developed precipitation‐ and groundwater‐corrected air–water temperature models, compared their accuracy with that of conventional air–water temperature models used in fisheries management, and projected future Gulf Sturgeon thermal habitat suitability for normal physiological functioning and fieldwork (i.e., population sampling and telemetry surgeries) in summer (May–August) under 16 climate change scenarios. Result Precipitation‐ and groundwater‐corrected models were more accurate than conventional air–water temperature models (mean improvement in adjusted R 2 = +0.45; range = +0.09 to +0.75). Water temperature was projected to warm at widely variable rates across climate change scenarios encompassing different air temperature, precipitation, and groundwater regimes. Importantly, Gulf Sturgeon summer aggregation areas were cooler and influenced more by precipitation and groundwater and less by air temperature than were non‐aggregation areas. If precipitation and groundwater—as drivers of cooling—become warm in a changing climate, summer aggregation areas were projected to exhibit thermal habitat degradation equivalent to or greater than that of non‐aggregation areas. Conclusion Our results add hydrological context to the premise that aggregation areas provide cool water and energetic savings for Gulf Sturgeon during summer, underscoring the importance of protecting these habitats through groundwater conservation, water quality monitoring, and riparian/watershed habitat management. Our findings indicate that identifying thermally appropriate times for fieldwork activities will be increasingly important and time‐restricted as climate change intensifies. However, our research provides managers with a portfolio of water temperature models and an accurate, cost‐effective, management‐relevant approach to forecasting thermal habitat conditions for Gulf Sturgeon and other species in a changing climate.

Alabama, Florida↗
USGS2025

Potentiometric surface maps and groundwater-level hydrographs for confined aquifers of the New Jersey Coastal Plain, 2018

The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection (NJDEP), prepared potentiometric surface maps for 10 confined aquifers of the New Jersey Coastal Plain physiographic province based on water-level measurements collected during late 2018 and early 2019 from 951 wells in New Jersey and parts of Pennsylvania and Delaware. Maps were prepared for the confined Cohansey aquifer, Rio Grande water-bearing zone, Atlantic City 800-foot sand, Piney Point aquifer, Vincentown aquifer, Wenonah-Mount Laurel aquifer, Englishtown aquifer system, and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy aquifer system. Potentiometric surface maps indicate regional cones of depression in the following aquifers and the counties in which they are centered: Atlantic City 800-foot sand in Atlantic County, the Piney Point aquifer in Cumberland County, the Wenonah-Mount Laurel aquifer and Englishtown aquifer system in Monmouth and Ocean Counties, the Wenonah-Mount Laurel aquifer in Camden and Gloucester County, the upper aquifer of the Potomac-Raritan-Magothy aquifer system in Ocean County, and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy aquifer system in Camden County. Cones of depression with smaller areal extents were in the confined Cohansey aquifer, the Rio Grande water-bearing zone, the Atlantic City 800-foot sand centered in Cape May County, the Piney Point aquifer centered in Ocean County, the Wenonah-Mount Laurel aquifer in Salem and Burlington Counties, the Englishtown aquifer system in Camden County, the upper aquifer of the Potomac-Raritan-Magothy aquifer system in Monmouth County, and the middle aquifer of the Potomac-Raritan-Magothy aquifer system in Monmouth, Ocean, and Salem Counties. No cone of depression was interpreted in the Vincentown aquifer. Long-term hydrographs are presented for 75 wells spanning each of the 10 confined aquifers, and contain a mix of discrete water-level measurements and daily mean water levels based on continuously recorded 15-minute data. Changes of water levels during 2014–19, as indicated by the hydrographs, were compared with those of previous periods to assess any departures from historical data. During 2014–19, water levels were stable and fluctuated within similar ranges as previous periods in the following aquifers and locations: all wells in the confined Cohansey aquifer, the Rio Grande water-bearing zone, the Vincentown aquifer, the Englishtown aquifer system, the Piney Point aquifer wells in Burlington and Ocean Counties, six of eight wells in the Wenonah-Mount Laurel aquifer, all wells in the upper and lower aquifers of the Potomac-Raritan-Magothy aquifer system outside NJDEP Critical Areas, and all wells in the middle aquifer of the Potomac-Raritan-Magothy aquifer system except those within NJDEP Critical Area II. Increasing water levels in 2014–19, ongoing since historical periods, were indicated in the following aquifers and locations: Atlantic County wells in the Piney Point aquifer, all wells in the upper and lower aquifers of the Potomac-Raritan-Magothy aquifer system outside NJDEP Critical Areas, and all wells in the middle aquifer of the Potomac-Raritan-Magothy aquifer system within NJDEP Critical Area II. Water levels in the Atlantic City 800-foot sand also increased during 2014–19 in wells in Atlantic County and northern Cape May County closer to the center of the cone of depression in that aquifer, which is a response unique to this period and absent from previous periods. During 2013–19, continued decreasing water levels, ongoing since previous periods, were indicated by hydrographs of Atlantic City 800-foot sand wells in southern Cape May County, Piney Point aquifer wells in Cumberland County where the regional cone of depression is located, and two wells in the Wenonah-Mount Laurel aquifer—070478, which in 2014–19 departed from previous periods, and 330020, which continued a gradual decrease throughout its period of record.

New Jersey↗
USGS2025

Using hydrogeologic context and water budgets to evaluate the potential for groundwater contributions to contaminants in Lake Superior

This study presents a synthesis of the hydrogeology in the U.S. Lake Superior watershed and the contribution of groundwater to the water budget of the U.S. Lake Superior basin. Much of the shoreline of Lake Superior in Minnesota and Michigan is composed of hydrogeologic units contributing very little direct groundwater discharge to the lake. Groundwater in watersheds adjacent to the lake typically flows in short, local flow systems characterized by thin glacial sediments with active groundwater flow in fractured bedrock within the top 60–90 m below land surface. The complex groundwater system in Wisconsin’s Bayfield Peninsula has the largest groundwater reservoir near the lake, characterized by thick sand and gravel glacial deposits and underlying sandstone aquifer. Although these thick sandy glacial deposits are not in direct contact with the lake at the shoreline, groundwater discharge may still be significant via subsurface exposures beyond the shoreline or flow through the underlying sandstone aquifer. Overall, most groundwater in the watershed is contributed as indirect base flow in streams around the lakeshore and comprises about 60 percent of the upland water budget. Direct groundwater flow to the shoreline contributes 2 to 9 percent of the inflow. Identifying possible contamination sources through direct sampling of groundwater would be an inefficient way to detect problems if sources are unknown, particularly for some chemicals of concern such as PFAS, pesticides, PCBs, chloride, and nutrients. Evaluating the chemical characteristics of contamination is also important to consider in evaluating how groundwater may contribute to pollution in Lake Superior.

Lake Superior↗
USGS2026

Rare earth element potential in coal and coal ash in the U.S. Gulf Coast

United States heavy reliance on imports of critical minerals (CMs), including rare earth elements (REEs), underscores the importance of development of domestic sources. The study objective was to quantify CM and REE concentrations in coal and coal ash in the US Gulf Coast region. CM and REE concentrations were measured for 118 samples from outcrops and 14 mines in the Gulf Coast. Results show that total REE + Yttrium (REY) concentrations (dry coal basis) are comparable to those of the upper continental crust (UCC) with localized hot spots, such as the Texas Gibbons Creek mine (REY ≤ ~ 2860 ppm). When normalized to UCC REY concentration (169 ppm, dry coal basis), REY to UCC ratios for Gulf Coast coal samples range from 0.1 to 17 (median ratio 0.6). REE extractability from lignites is high (median: 63%–93%) using environmentally benign weak acid. In addition to raw coal, coal ash from power plants could also serve as an REE source with a median ratio of REY in ash relative to coal of 4; however, extractability from coal ash is generally much lower (≤ 5% using the same weak acid as in coal). The median basket price for extracted REY as oxides from coal, assuming 70% extractability, is $3.2 per tonne of coal and $186 billion based on 58 billion metric tonnes of dry coal in the Gulf Coast. REEs important for magnets (Pr + Nd + Tb + Dy) account for ~ 80% of the total value. The corresponding median basket price for extracted REY as oxides from coal ash, assuming ~ 30% extractability, is ~$4.4 per tonne of ash and $1.2 billion based on 258 million tonnes of ash. REE production from coal would likely require co-products, such as activated carbon or humic acids, to attain economic viability. Production of REEs from coal ash could offset remediation costs related to potential water contamination. This reconnaissance study shows the potential for REE production from coal and coal ash in the Gulf Coast; however, carbon coproducts and/or societal benefits would likely be required for socioeconomic viability.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2026

Increasing artificial light at night enhances salmonid predator foraging efficiency in an urbanized lake

Artificial light at night (ALAN) poses a threat to ecosystems globally. It includes both direct and indirect light, or skyglow, which occurs when ALAN scatters in the atmosphere, extending beyond its original source. We analyzed ALAN trends in Lake Washington, WA, from 2014 to 2023 using Visible Infrared Imaging Radiometer Suite (VIIRS) nighttime light measurements, evaluated the relationship between in situ and satellite measurements, and modeled predator search volumes for a juvenile salmon predator, cutthroat trout ( Oncorhynchus clarki ), as a function of ambient light and turbidity conditions. Open water regions experienced significant increases in ALAN, while nearshore areas primarily showed no or negative trends, revealing the role of skyglow in shaping open water light environments. Using a visual foraging model for cutthroat trout, we found that juvenile salmon at the shallow southern pelagic site experienced light 28 times brighter, resulting in a 168% greater predation vulnerability than those at the northern site. In the Ship Canal, a narrow corridor for outmigrating salmon, predator search volumes were 249% higher than at the southern site. These contrasts in predation vulnerability demonstrate how local conditions influence predator–prey dynamics and provide critical insight for targeting mitigation of both nearshore and distant light sources.

Washington↗
USGS2024

Will there be water? Climate change, housing needs, and future water demand in California

Climate change in California is expected to alter future water availability, impacting water supplies needed to support future housing growth and agriculture demand. In groundwater-dependent regions like California's Central Coast, new land-use related water demand and decreasing recharge is already stressing depleted groundwater basins. We developed a spatially explicit state-and-transition simulation model that integrates climate, land-use change, water demand, and groundwater gain-loss to examine the impact of future climate and land use change on groundwater balance and water demand in five counties along the Central Coast from 2010 to 2060. The model incorporated downscaled groundwater recharge projections based on a Warm/Wet and a Hot/Dry climate future from a spatially explicit hydrological process-based model. Two urbanization projections from a parcel-based, regional urban growth model representing 1) recent historical and 2) state-mandated housing growth projections were used as alternative spatial targets for future urban growth. Agricultural projections were based on recent historical trends from remote sensing data. Annual projected changes in groundwater balance were calculated as the difference between land-use related water demand, based on historical estimates, and climate-driven recharge plus agriculture return flows. Results indicate that future changes in climate-driven groundwater recharge, coupled with cumulative increases in agricultural water demand, result in overall declines in future groundwater balance, with a Hot/Dry future resulting in cumulative groundwater decline in all but Santa Cruz County. Cumulative declines by 2060 are especially prominent in San Luis Obispo (−2.9 to −5.1 Bm 3 ) and Monterey counties (−6.5 to −8.7 Bm 3 ), despite limited changes in agricultural water demand over the model period. These two counties show declining groundwater reserves in a Warm/Wet future as well, while San Benito and Santa Barbara County barely reach equilibrium. These results suggest future groundwater supplies may not be able to keep pace with regional demand and declining climate-driven recharge, resulting in a potential reduction in water security in the region. However, our county-scale projections showed new housing and associated water demand does not conflict with California's groundwater sustainability goals. Rather, future climate coupled with increasing agricultural groundwater demand may reduce water security in some counties, potentially limiting available groundwater supplies for new housing.

California↗
USGS2024

Correction to A regime shift in sediment export from a coastal watershed during a record wet winter, California: Implications for landscape response to hydroclimatic extremes

In the referenced article, the authors would like to correct text in the first paragraph on page 2571, Figure 9 and its caption. The changes reflect an error made in the processing of the rainfall intensity-duration data used to compare storms to published debris flow triggering thresholds. The correctly processed data does not change the interpretations made in the paper but does correctly indicate that the investigated storms did not exceed the rainfall intensity – duration threshold of Cannon (1988) but did significantly exceed the debris flow triggering threshold of Wieczorek (1987).

Earth Surface Processes and Landforms↗
USGS2025

Relationship of basin structure and bedrock lithology to faulting in the 2019 Ridgecrest earthquake region, California, from gravity and aeromagnetic data

We investigate patterns of cumulative offsets on the faults that ruptured in 2019 and along the Garlock Fault in the Ridgecrest region, California using recently published gravity and aeromagnetic data. We also examine the relationship of basin structure and bedrock structure to the 2019 M7.1 Ridgecrest earthquake ruptures (Fig. 1A), which were primarily along a dextral northwest-striking fault system, and along a sinistral northeast-striking fault, which ruptured hours earlier with a M6.4 event.

California↗
USGS2026

Beaver dam analogs as nature-based solutions to mitigate snowpack loss in northern New Mexico

Reductions in snow have left many streams in northern New Mexico dry or with very low flows during the summer. Base flow, defined as the contribution of groundwater to streamflow, can sustain streamflow during the summer and during drought conditions. Beaver dam analogs can be used to “slow the flow,” or increase the infiltration of rain-based runoff to replenish shallow groundwater reservoirs and increase base flow and potentially increase summertime streamflow.

New Mexico↗
USGS2024

Declining groundwater storage expected to amplify mountain streamflow reductions in a warmer world

Groundwater interactions with mountain streams are often simplified in model projections, potentially leading to inaccurate estimates of streamflow response to climate change. Here, using a high-resolution, integrated hydrological model extending 400 m into the subsurface, we find groundwater an important and stable source of historical streamflow in a mountainous watershed of the Colorado River. In a warmer climate, increased forest water use is predicted to reduce groundwater recharge resulting in groundwater storage loss. Losses are expected to be most severe during dry years and cannot recover to historical levels even during simulated wet periods. Groundwater depletion substantially reduces annual streamflow with intermittent conditions predicted when precipitation is low. Expanding results across the region suggests groundwater declines will be highest in the Colorado Headwater and Gunnison basins. Our research highlights the tight coupling of vegetation and groundwater dynamics and that excluding explicit groundwater response to warming may underestimate future reductions in mountain streamflow.

Nature Water↗
USGS2025

Hydrogeology and groundwater quality in the Snake River alluvial aquifer at Jackson Hole Airport, Wyoming, 2011–20

The Snake River alluvial aquifer underlying the Jackson Hole Airport (JHA) in northwest Wyoming is an important source of water used for domestic, commercial, and irrigation purposes by the airport and nearby residents. The U.S. Geological Survey, in response to previously identified water-quality concerns in the area, monitored and evaluated changes in hydrogeologic characteristics and groundwater-quality conditions of the alluvial aquifer during 2011–20. During that period, the Jackson Hole Airport made several changes that potentially improved water quality at and downgradient from the airport. Well, water level, and hydrogeologic data were collected from the alluvial aquifer to identify hydrogeologic characteristic and groundwater quality changes. Additionally, results of statistical tests were applied to water-quality results to evaluate trends in selected physical properties and constituent concentrations with time. The trends of those data show that water quality did improve overall during the study period compared to previously collected data. Presumably, these trends are in response to the changes in the aircraft deicing/anti-icing fluid (ADAF) formulation used by the JHA, the many JHA infrastructure improvements made during 2011–20, the degradation of existing ADAFs in subsurface soils and groundwater, or some combination of these possibilities.

Wyoming↗
USGS1976

Neutron activation analysis in hydrology

Neutron activation analysis in hydrogeochemical and related investigations is increasingly practical because of developments in radiation detectors and computerized data processing. While neutron activation is the most widely used kind of activation analysis other kinds (for example, charged particle activation) are available for special applications. Neutron activation analysis is promising because approximately 70 percent of the elements in the periodic table are detected with satisfactory sensitivity, contamination from reagents is eliminated, simultaneous determination of more than 20 elements is often possible, technique is versatile, is applicable to small samples and is non-destructive in the instrumental form. Developments in theU.S. Geological Survey include a special sampling technique for water; a comprehensive technique using carriers precipitated with sulfide to concentrate desired trace elements; a determination of mercury, silver, and gold; determination of aluminum, vanadium and nine other elements; determinations of two groups of rare earth elements; and adaptations of the analytical methods to sediment and biota.

Open-File Report↗
USGS2024

Perchlorate, metals, organic compounds, and lead isotopes in groundwater, surface water, shallow groundwater, and soil within and near the Middleton Municipal Airport–Morey Field (C29), Middleton, Wisconsin, 2022

The Middleton Municipal Airport–Morey Field (C29) is in the City of Middleton and adjacent to the towns of Middleton and Springfield, Wisconsin. Nearby homes in the towns rely on private drinking water wells, and residents are concerned about the potential contamination of groundwater and surface water by airport activities, including flights by small aircraft that use leaded aviation fuel and a fireworks display in July 2021. The U.S. Geological Survey, in cooperation with the Town of Middleton, completed a study in 2022 to characterize the occurrence and sources of perchlorate, metals (including lead), and organic compounds in samples of groundwater, surface water, shallow groundwater, and soils within and near the airport. Lead isotopes were also measured to determine sources of lead by comparing samples to environmental references. Magnitudes of concentrations from samples of water and soil collected in 2022, and their spatial patterns across site locations, indicate the fireworks display in July 2021 was a likely source of perchlorate and metals in the airport study area. The highest perchlorate concentration was measured in surface water at the southeastern corner of the airport near the fireworks launch site; the highest concentrations of fireworks-associated metals were measured in shallow groundwater near the same location. Fireworks were not the only possible source of perchlorate and metals in the airport study area because both were also detected upgradient and away from the fireworks launch site. Ratios of lead isotopes indicate that lead measured in water and soil within the airport study area was primarily sourced from background atmospheric lead deposition or Wisconsin galena lead ore. However, two groundwater samples (one upgradient and one downgradient from the airport; both with concentrations less than 1 microgram per liter) had isotopic signatures matching leaded aviation fuel sold at the airport.

Wisconsin↗
USGS2026

Spatio-temporal modeling for assessing geoenergy resources: A workflow applied to gas in place variation in coal beds

The ability to estimate spatio-temporal changes in hydrocarbon reservoir properties and energy resources within pore volumes is essential for optimizing production, reservoir management, geologic energy storage, and safety in underground mining operations. In coal seams, predicting remaining methane gas-in-place (GIP) is critical for quantifying producible gas and improving mine safety and productivity through effective ventilation planning. Although such changes are commonly evaluated using physics-based numerical simulation models, these approaches often require extensive data, calibration effort, and time. This study presents a spatio-temporal geostatistical modeling approach that bridges the gap between purely spatial models and full numerical simulations. The method is applied to a case study of coal seam degasification in the Mary Lee coal group, Black Warrior Basin, Alabama, USA, to estimate GIP evolution over time within a selected mining district. The analysis uses published data from prior natural gas production history-matching of degasification using vertical wells. Empirical spatial and temporal statistics were calculated for reservoir pressure and water saturation, and spatio-temporal variogram models were fitted to experimental variograms. These models provided the structural basis for spatio-temporal kriging, integrated with spatial estimates of time-invariant parameters (porosity, density, and thickness) to estimate GIP. This approach enabled estimation of GIP changes over time, including periods without data. Boxplots of GIP estimates indicated systematic depletion and decreasing spatial variability, reflecting the impacts of degasification. Comparison with cumulative gas production from empirical well records showed approximately 85% agreement based on a relative similarity metric. Spatio-temporal GIP estimates were also used to estimate methane emissions to longwall ventilation systems and compared with reported emissions from the U.S. EPA Greenhouse Gas Reporting Program, showing similar distributions (≈80%) given data limitations. Overall, this integrated modeling approach provides time-dependent GIP estimates with broader implications for resource assessment applications.

Alabama↗
USGS1999

Environmental setting and water-quality issues in the lower Tennessee River basin

The goals of the National Water-Quality Assessment Program are to describe current water-quality conditions for a large part of the Nation's water resources, identify water-quality changes over time, and identify the primary natural and human factors that affect water quality. The lower Tennessee River Basin is one of 59 river basins selected for study. The water-quality assessment of the lower Tennessee River Basin study unit began in 1997. The lower Tennessee River Basin study unit encompasses an area of about 19,500 square miles and extends from Chattanooga, Tennessee, to Paducah, Kentucky. The study unit had a population of about 1.5 million people in 1995. The study unit was subdivided into subunits with relatively homogeneous geology and physiography. Subdivision of the study unit creates a framework to assess the effects of natural and cultural settings on water quality. Nine subunits were delineated in the study unit; their boundaries generally coincide with level III and level IV ecoregion boundaries. The nine subunits are the Coastal Plain, Transition, Western Highland Rim, Outer Nashville Basin, Inner Nashville Basin, Eastern Highland Rim, Plateau Escarpment and Valleys, Cumberland Plateau, and Valley and Ridge.The lower Tennessee River Basin consists of predominantly forest (51 percent) and agricultural land (40 percent). Activities related to agricultural land use, therefore, are the primary cultural factors likely to have a widespread effect on surface- and ground-water quality in the study unit. Inputs of total nitrogen and phosphorus from agricultural activities in 1992 were about 161,000 and 37,900 tons, respectively. About 3.7 million pounds (active ingredient) of pesticides was applied to crops in the lower Tennessee River Basin in 1992. State water-quality agencies identified nutrient enrichment and pathogens as water-quality issues affecting both surface and ground water in the lower Tennessee River Basin. Water-quality data collected by State and Federal agencies between 1980 and 1996 were summarized to characterize surface- and ground-water quality of the subunits with respect to these issues. Median concentrations of nitrogen species generally were less than 1 milligram per liter in surface and ground water in all subunits, and were highest throughout the subunits that had the largest percentages of agricultural land use. Median phosphorus concentrations also were less than 1 milligram per liter in all subunits. Phosphatic limestones present in two subunits had a larger effect on phosphorus concentrations in surface and ground water than did the amount of agricultural land use in these subunits. Median counts of fecal coliform were higher in surface water than in ground water in all subunits. The highest median counts in surface water were in the Valley and Ridge (7,500 colonies per 100 milliliters) and the Outer Nashville Basin subunits (5,000 colonies per 100 milliliters). Highest median counts in ground water were in the Inner and Outer Nashville Basin subunit. Natural setting likely has an important effect with respect to fecal contamination of surface and ground water in the lower Tennessee River Basin.

Alabama, Georgia, Kentucky, Mississippi, Tennessee↗