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Per- and polyfluoroalkyl substances in waters associated with oil and gas development in the Denver Basin

Use of per- and polyfluoroalkyl substances (PFAS) in the petroleum industry could be a cause for concern due to the large volumes of produced water (PW) generated during oil and gas extraction, the reuse of these wastes in water-stressed regions, and adverse health outcomes related to PFAS exposures. However, PW PFAS characterization is nearly absent in the literature, and hydraulic fracturing (HF) chemical disclosures often omit the identities of additives as proprietary. Here we evaluate PFAS in PW samples from three petroleum wells in the Denver Basin during their first year of production. Total concentrations of targeted PFAS (Σ 40 PFAS) were < 35 ng/L in PW samples, with short-chain PFAS like perfluorobutanoic acid persisting throughout the sampled duration. Analysis of freshwater inputs for hydraulic fracturing (Σ 40 PFAS ~ 113 ng/L) and mixed fracture fluid (Σ 40 PFAS ~ 69 ng/L) indicated much of the targeted PFAS content was derived from the input water, and not from HF additives, however samples subjected to oxidation indicated the presence of PFAS precursors that would not be detected by targeted analysis. This study highlights that while PFAS content is low in the studied PWs, the potential for redistribution of PFAS in the environment may be a consideration for reuse applications.

Colorado, Nebraska, Wyoming

Surficial geologic map of the Owlshead Mountains 30' x 60' quadrangle, Inyo and San Bernardino Counties, California

The surficial geologic map of the Owlshead Mountains 30' x 60' quadrangle depicts the distribution and characteristics of surficial-deposit materials and neotectonic deformation for an area of approximately 5,000 square kilometers (km 2 ) located in the western Basin and Range Province of eastern California. The map represents a new compilation of the surficial geology that encompasses deposits within the late Pliocene to Quaternary. The map is based primarily on new mapping conducted between 2001 and 2009. Map compilation was supported by field observations distributed across the map area, combined with reference to several published and unpublished mapping sources that mostly emphasized neotectonic deformation. The surficial-deposit units included in the map follow a classification scheme that systematically denotes depositional process, relative age, and any secondary sedimentologic or morphologic characteristics. Identification, correlation, and age estimation of map units are based primarily on the relative degree of development of certain time-dependent characteristics such as surface morphology, including local dissection and surface preservation, surface clast modification, and degree of soil development; these characteristics are implicitly incorporated into unit designations. The map represents a detailed and regionally uniform synthesis of the late Neogene geology for this large area that provides a framework applicable to many interpretative studies, such as regional patterns of deposition and dissection; surface drainage development and evolution; and the distribution, style, and timing of neotectonic deformation.

California

Hydrological control on soil redox condition and carbon loss of coastal wetland under sea-kevel rise

Coastal wetlands are critical carbon sinks with their biogeochemical and ecological functioning shaped by dynamic hydrological conditions that are increasingly influenced by climate change. A key unresolved question is how hydrologic flow, vegetation response, and rising sea levels interact to regulate soil redox condition and carbon loss in coastal wetlands. Using a field-tested hydrological–biogeochemical–ecological modeling framework, we reveal how the interplay between terrestrial groundwater discharge and tidal fluctuations generates complex groundwater flow patterns at the terrestrial–aquatic interface, and how these patterns modulate soil redox conditions, in turn influencing soil organic matter decomposition and carbon loss. Notably, rising sea levels suppress soil CO 2 emissions while reducing lateral dissolved carbon losses, thereby enhancing litter carbon sequestration under anoxic conditions. As vegetation responds to sea-level rise and carbon inputs diminish, litter carbon subsequently declines. These findings underscore a critical hydrological control on carbon cycling, advancing our understanding of coastal ecosystem resilience in a warming world.

Louisiana

Mapping eelgrass (Zostera marina) cover and biomass at Izembek Lagoon, Alaska, using in-situ field data and Sentinel-2 satellite imagery

The U.S. Geological Survey and the U.S. Fish and Wildlife Service have developed a three-tiered strategy for monitoring eelgrass ( Zostera marina ) beds at Izembek Lagoon, Alaska, that targets different spatial and temporal scales. The broadest-scale monitoring (tier-1) uses satellite imagery about every 5 years to delineate the spatial extent of eelgrass beds throughout the lagoon. This report describes the most recent (mid-2020s) tier-1 eelgrass monitoring at Izembek Lagoon. The monitoring effort began by canvasing all satellite imagery collected during summer, under clear daytime skies and at low-tide, since the last tier-1 effort in 2006. Two eelgrass maps of Izembek Lagoon were generated by first creating maps of spectrally unique classes from two Sentinel-2 satellite images collected on July 1, 2016, and August 14, 2020, then attributing those spectral classes with information about eelgrass conditions based on field data. Specifically, maps depicting various eelgrass metrics, such as percentage of cover and modeled biomass, were generated using summaries of the ground data that spatially intersected each spectral class. Comparisons of the 2016 and 2020 Sentinel-2 maps showing eelgrass distributional extent, as well as a 2006 Landsat map, indicated that areas where eelgrass presence may have declined during 2006–20 were most prevalent in the central part of Izembek Lagoon. More recently, during 2016-20, areas of possible biomass decline were more prevalent in the southern part of the lagoon. Monitoring eelgrass conditions at Izembek Lagoon with satellite imagery and concurrent ground data allows conditions to be compared over time, but the influences of tide levels, growing season phenology, and spatiotemporal co-registration accuracy should be considered when designing and interpreting change detection analyses.

Alaska

Sediment thickness map of United States Atlantic and Gulf Coastal Plain Strata, and their influence on earthquake ground motions

With the recent successful accounting of basin depth ground-motion adjustments in seismic hazard analyses for select areas of the western United States, we move toward implementing similar adjustments in the Atlantic and Gulf Coastal Plains by constructing a sediment thickness model and evaluating multiple relevant site amplification models for central and eastern United States seismic hazard analyses. We digitize and combine existing sediment thickness data sets into a composite surface that delineates the base of Cretaceous sediments under the Atlantic Coastal Plain and the base of Mesozoic sediments under the Gulf Coastal Plain. Amplification models dependent on sediment thickness, site natural period, and source-to-site path length are compared with data sets of observed ground motions to evaluate the ability of the new models to improve ground motion estimates. We find that the amplification models can account for observed trends in sediment-thickness and period-dependent residuals, but some tuning is required. For example, the model of Chapman and Guo requires a reference V S 30 , the time-averaged shear-wave velocity within 30 m of the Earth’s surface, for non-Coastal Plain sites, which we estimate to be between about 1 and 2 km/s. Along with our sediment thickness model, we estimate a velocity profile for application to the Harmon et al. site-natural-period-based model in order to best match the Chapman and Guo period dependence for a broad range of sediment thicknesses. The Next Generation of Attenuation models for the eastern United States Gulf Coast path-based adjustment models can also account for seismic attenuation in the Coastal Plain sediments and reduce the standard deviation of total residuals. If enacted in the U.S. Geological Survey National Seismic Hazard Model, these amplification models will reduce predicted short-period (<1 s) and increase predicted long-period (>1 s) ground motions in the Coastal Plains appreciably.

Earthquake Spectra

Sedimentological and geochemical characterization of lacustrine deposits of the Babouri-Figuil basin, northern Cameroon: Implications for source rocks distribution and petroleum exploration

The West and Central African Rift System (WCARS) refers to the series of Cretaceous rift basins where commercial hydrocarbon accumulations have been discovered. Some of the WCARS frontier basins are currently being investigated to increase our understanding of these basins in light of new commercial discoveries. The present study was performed in the Babouri-Figuil Basin (BFB), which is genetically related to the WCARS and constitutes an area of interest in terms of petroleum prospecting, where the distribution of petroleum source rocks and potential targets for petroleum exploration across the entire basin is poorly understood. For the current study, an integrated facies analysis along with organic and inorganic geochemical techniques were applied to the basin's Cretaceous deposits with the aim of reconstructing the paleodepositional environment, assessing factors that triggered the input of organic matter, and providing a spatial overview of the organic matter accumulation in the basin based on outcrop samples. An alluvial fan-lacustrine-braided river system is inferred from the facies analysis of the stratigraphic sequence consisting of conglomerate, sandstone, siltstone, limestone, marlstone, and claystone. Bulk analysis of organic matter reveals that black shale and massive claystone are the main prospective petroleum source rocks in the basin. Inorganic geochemical analyses reveal the influence of anoxic conditions, moderate to high primary productivity, and low terrigenous inputs in organic matter enrichment. The formations rich in organic matter are predominantly concentrated in the western and eastern parts of the basin which may represent areas with depressions, characterized by high accommodation space. In terms of the regional context of the WCARS rift basins, typical hydrocarbon exploration in the BFB may target basal-conglomerate, sandstone beds situated directly above or/and interbedded with the Lower Cretaceous source rocks, and the Upper Cretaceous sandstone beds. Basement rocks (granite, granodiorite, and gneisses) and oil shale deposits may represent potential unconventional hydrocarbon exploration. The current integrated study provides an insight that should guide future hydrocarbon exploration campaigns in the basin.

Babouri-Figuil basin

Identifying precursors and tracking pulses of magma ascent in multidisciplinary data during the 2018–2023 phreatomagmatic eruption at Semisopochnoi Island, Alaska

The 2018–2023 phreatomagmatic eruptions at Semisopochnoi Island, Alaska produced abundant long-period (LP) seismicity, harmonic and broadband tremor, and explosion signals over several well-monitored periods of eruption and quiescence. The corresponding dataset provides an excellent opportunity to investigate precursory and syn -eruptive geophysical signals of long-lived phreatomagmatic eruptions using multiparameter observations. We generated explosion and LP event catalogs through novel implementations of the REDPy ( Hotovec-Ellis, 2024 ) repeating event detector in mid-2021 following a network upgrade and the onset of a new phase of the eruption. The hundreds of detected explosions show a high degree of infrasound waveform similarity over more than a year, indicating a repeating source mechanism likely associated with explosive magma-water interaction. The seismic LP catalog shows that events began over a month prior to renewed explosive activity at the beginning of August 2021, and that lower frequency index (FI) LPs were generated in the week prior to the onset of explosions. We applied a recently developed machine learning tool (VOISS-Net, Tan et al., 2024 ) to catalog abundant broadband and harmonic seismic tremor recorded before and during the renewed explosive activity, along with LPs and explosions. The tremor catalogs complement the LP and explosion catalogs by filling out the seismic sequence with the dominant signal types. Together, these catalogs reveal a seismic sequence of renewed unrest that started with several weeks of LP events, followed by LPs with lower FI values and harmonic tremor in the days prior to explosive activity, and finally the onset of discrete explosions and broadband eruption tremor. We interpret this sequence as the ascent of a new pulse of magma that first interacted with the hydrothermal/groundwater system to produce LPs, followed by harmonic tremor, and that ultimately drove explosive magma-water interactions and periods of continuous ash emissions. The 2021 seismic sequence, in combination with long-term records of satellite SO 2 emissions, deformation from interferometric synthetic aperture radar (InSAR) analysis, ash sample analysis, infrasound, and volcano tectonic seismicity, allows us to interpret the entire 9-year period of unrest and eruption that began with an intrusion and earthquake swarm in 2014.

Alaska

Projected sea-level rise and high tide flooding at De Soto National Memorial, Florida

Introduction National parks and preserves in the South Atlantic-Gulf Region contain valuable coastal habitats such as tidal wetlands and mangrove forests, as well as irreplaceable historic buildings and archeological sites located in low-lying areas. These natural and cultural resources are vulnerable to accelerated sea-level rise and escalating high tide flooding events. Through a Natural Resources Preservation Program-funded project during 2021–23, the U.S. Geological Survey, in collaboration with the National Park Service, estimated the probability of inundation at De Soto National Memorial, Florida, and several other parks under various sea-level rise scenarios and contemporary high tide flooding thresholds. The maps produced for this effort can be used to assess potential habitat change and explore how infrastructure and cultural resources within the park may be exposed to future flooding-related hazards.

Florida

Projected sea-level rise and high tide flooding at Dry Tortugas National Park, Florida

Introduction National parks and preserves in the South Atlantic-Gulf Region contain valuable coastal habitats such as tidal wetlands and mangrove forests, as well as irreplaceable historic buildings and archeological sites located in low-lying areas. These natural and cultural resources are vulnerable to accelerated sea-level rise and escalating high tide flooding events. Through a Natural Resources Preservation Program-funded project during 2021–23, the U.S. Geological Survey, in collaboration with the National Park Service, estimated the probability of inundation at Dry Tortugas National Park, Florida, and several other parks under various sea-level rise scenarios and contemporary high tide flooding thresholds. The maps produced for this effort can be used to assess potential habitat change and explore how infrastructure and cultural resources within the park may be exposed to future flooding-related hazards.

Florida

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma — Nutrients, bacteria, organic carbon, and suspended sediment in surface water, 1993-95

Nutrient, bacteria, organic carbon, and suspended- sediment samples were collected from 1993-95 at 43 surface-water-quality sampling sites within the Ozark Plateaus National Water- Quality Assessment Program study unit. Most surface-water-quality sites have small or medium drainage basins, near-homogenous land uses (primarily agricultural or forest), and are located predominantly in the Springfield and Salem Plateaus. The water-quality data were analyzed using selected descriptive and statistical methods to determine factors affecting occurrence in streams in the study unit. Nitrogen and phosphorus fertilizer use increased in the Ozark Plateaus study unit for the period 1965-85, but the application rates are well below the national median. Fertilizer use differed substantially among the major river basins and physiographic areas in the study unit. Livestock and poultry waste is a major source of nutrient loading in parts of the study unit. The quantity of nitrogen and phosphorus from livestock and poultry wastes differed substantially among the river basins of the study unit's sampling network. Eighty six municipal sewage-treatment plants in the study unit have effluents of 0.5 million gallons per day or more (for the years 1985-91). Statistically significant differences existed in surface-water quality that can be attributed to land use, physiography, and drainage basin size. Dissolved nitrite plus nitrate, total phosphorus, fecal coliform bacteria, and dissolved organic carbon concentrations generally were larger at sites associated with agricultural basins than at sites associated with forested basins. A large difference in dissolved nitrite plus nitrate concentrations occurred between streams draining basins with agricultural land use in the Springfield and Salem Plateaus. Streams draining both small and medium agricultural basins in the Springfield Plateau had much larger concentrations than their counterparts in the Salem Plateau. Drainage basin size was not a significant factor in affecting total phosphorus, fecal coliform bacteria, or dissolved organic carbon concentrations. Suspended-sediment concentrations generally were small and indicative of the clear water in streams in the Ozark Plateaus. A comparison of the dissolved nitrite plus nitrate, total phosphorus, and fecal coliform data collected at the fixed and synoptic sites indicates that generally the data for streams draining basins of similar physiography, land-use setting, and drainage basin size group together. Many of the variations are most likely the result of differences in percent agricultural land use between the sites being compared or are discharge related. The relation of dissolved nitrite plus nitrate, total phosphorus, and fecal coliform concentration to percent agricultural land use has a strong positive 2 Water-Quality Assessment-Nutrients, Bacteria, Organic Carbon, and Suspended Sediment in Surface Water, 1993-95 correlation, with percent agricultural land use accounting for between 42 and 60 percent of the variation in the observed concentrations.

Arkansas, Kansas, Missouri, Oklahoma

Description and effects of 1988 drought on ground-water levels, streamflow, and reservoir levels in Indiana

Documentation of the 1988 drought in Indiana was undertaken to aid water-management agencies and planners concerned with periods of below-normal precipitation and their effect on commercial, agricultural, and residential water use. Precipitation, temperature, Palmer Drought Severity Indices, and ground- and surface-water levels from water years 1988 and 1989 were compared to the historical record to evaluate severity, extent, and duration of the 1988 drought in Indiana. Three types of drought-climatological, hydrologic, and agricultural--occurred in most of Indiana during water years 1988 and 1989. The drought began toward the end of calendar year 1987 as annual precipitation decreased to 4.6 inches below the long term mean. By the end of September 1988, statewide precipitation deficits had increased to almost 8 inches below normal. High temperatures during the summer months increased the stress on crops, livestock, and people. Northwest Indiana experienced the second warmest June-August on record. Palmer Drought Severity Indices indicated that a moderate-to-severe drought had occurred in Indiana during most of 1988. Ground-water levels were affected substantially in many areas of the State. Record low-water levels were observed at 12 of the 20 monitoring wells included in this report. A go-day ground-water emergency was declared in parts of northwestern Indiana. Streamflow throughout the State was affected to varying degrees by the drought. Annual mean discharge in some rivers was only slightly less than the mean annual discharge, while others flowed at less than half that value. The effects of low streamflows were felt by many as electric power plants reduced or ceased production and public-water utilities requested conservation measures by their customers. Major reservoirs in the State approached or reached record low levels, causing water supplies as well as recreational activities to be diminished. Most major crops produced in Indiana were affected by the dry conditions. Average yields in 1988 ranged from 50 to 86 percent of 1987 yields.

Indiana

The effects of the Chesapeake Bay impact crater on the geological framework and correlation of hydrogeologic units of the lower York-James Peninsula, Virginia

This report documents the highly variable structure, stratigraphy, and buried topography of the outer rim of the Chesapeake Bay impact crater created by its impact and burial. Lithologies of cores are correlated with borehole geophysical logs to characterize the physical properties of the stratigraphic units and their geophysical signatures. The correlation between cores, well cuttings, and borehole geophysical logs is augmented with seismic-reflection data, and these data are compiled into a lithostratigraphic cross section that illustrates the geological framework of the lower York-James Peninsula and immediate surrounding areas.

Virginia

State of science, gap analysis, and prioritization for southeastern United States water-quality impacts from coastal storms—Fiscal year 2023 program report to the Water Resources Mission Area from the Water Availability Impacts of Extreme Events Program—Hurricanes

Tropical cyclones (coastal storm events that include tropical depressions, tropical storms, and hurricanes) cause landscape-scale disturbances that can lead to impaired water quality and thus reduce water availability for use. Stakeholders and scientists at local and national scales have illustrated a need for understanding these risks to water quality. A regional and comprehensive understanding of the impacts of tropical storms and hurricanes on surface-water and groundwater quality—and thus water availability—is lacking for potentially impacted coastal and inland areas. As the U.S. Geological Survey considers development of tools to predict the extent to which water-quality impacts of hurricanes affect water availability, an assessment of the state of the science of hurricane impacts is needed, including a gap analysis and prioritization of data and science needs. This assessment focuses on the southeastern coastal States.

southeastern United States

Collision structures of the Prince William terrane and Chugach terrane docking along the Shumagin and Unimak convergent margins, Alaska, USA

Western Alaska’s convergent margins are composed of tectonostratigraphic terranes. On land, terrane assembly is recognized along boundaries or sutures between neighboring geologic elements with distinctly different origins. In marine areas where rock outcrops are covered by sediment, recognizing terrane sutures is problematic. A fault in seismic dip line 5 of the ALEUT project has been interpreted as a terrane suture. It is imaged intermittently down to the 30+-km-deep plate interface. Processing of ALEUT strike line 7 revealed the suture at ~18 km depths extending 300 km along the margin. Upper structures in line 5 are like the structures of adjacent seismic transects where imaging is only 8−10 km deep. They were previously not recognized as the upper reaches of terrane sutures and show structural details obscured at greater depths. The composite data are the basis for a simple tectonic model of terrane docking.

Alaska