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635 records · Page 25Linked to original sources

Spatial differences in soil nutrients along a hydrographic gradient on floodplains in Dongting Lake

The spatial heterogeneity of soil nutrients is crucial for the water bird and whole floodplain wetland ecosystem in large lakes, and it is influenced by the dramatic water level changes and sedimentation progress in West Dongting Lake (WDL). Soil samples were collected at various soil depths along the Yuan River and Li River that feed into WDL. The concentrations of soil total organic carbon (TOC), total nitrogen (TN), total phosphorus (TP), and soil grain size were tested. The stoichiometric ratios of C, N, P, and the mean value of soil grain size ( Mz ) were calculated. The differences of soil TOC, TN, TP and the stoichiometric ratio at different sites and soil depths were compared. Linear regression was used to explore the relationships of Mz and nutrient concentrations, and relationships between TOC, TN, and TP. Redundancy analysis was used to explore the relationship between soil nutrients, heavy metal concentrations, and plant community diversity. The results showed that the distributions of soil TOC, TN, and TP concentrations differed across regions in west Dongting Lake along the Yuan and Li Rivers. Total organic carbon concentration differed at different sedimentation depths. Soil grain size showed negative effect with soil TOC, TN, and TP concentrations in this region. Plant community diversity correlated positively with soil TOC and negatively with Hg. West Dongting Lake was N limited despite the high wet deposition of N. It could potentially be attributed to the insufficient presence of aerobic environments for microbes during intermittent flooding of the floodplain, coupled with feeble mineralization. This study can provide valuable insights for the conservation of water bird habitats and wetland ecosystems.

West Dongting Lake

U.S. Geological Survey Karst Interest Group proceedings, Nashville, Tennessee, October 22-24, 2024

Karst hydrogeologic systems represent challenging and unique conditions to scientists studying groundwater flow and contaminant transport. Karst terrains are characterized by distinct and beautiful landscapes, caverns, and springs, and many of the exceptional karst areas are designated as national or state parks. The range and complexity of landforms and groundwater flow systems associated with karst terrains are enormous, perhaps more than any other aquifer type. The U.S. Geological Survey (USGS) Karst Interest Group (KIG), formed in 2000, is a loosely knit, grassroots organization of USGS and non-USGS scientists and researchers devoted to fostering better communication among scientists working on, or interested in, karst aquifers. The primary mission of the KIG is to encourage and support interdisciplinary collaboration and technology transfer among scientists working in karst areas. To accomplish its mission, the KIG has organized a series of workshops. To date (2024), nine KIG workshops, including the workshop documented in this report, have been held. The abstracts and extended abstracts provide a snapshot in time of past and current karst related studies. The USGS Water Availability and Use Science Program funded the workshop and proceedings. The planning committee for the ninth workshop includes Thomas D. Byl (USGS and Tennessee State University), Allan K. Clark (USGS), Laura M. DeMott (USGS), Eve L. Kuniansky (USGS, Emeritus), Benjamin V. Miller (USGS), and Lawrence E. Spangler (USGS, Emeritus). The workshop proceedings are edited by Eve L. Kuniansky and Lawrence E. Spangler. The field trip guide was produced by Benjamin V. Miller and Brian Ham (Tennessee Department of Environment and Conservation) and included in the proceedings from the KIG’s 2021 virtual workshop to be used on the optional field trip held on Thursday, October 24, 2024.

Open-File Report

Methodology for inclusion of produced and stored carbon dioxide in the U.S. Geological Survey Federal lands greenhouse gas inventory

The U.S. Geological Survey (USGS) has developed two new carbon dioxide (CO2) emissions and sequestration accounting methods for use in future reports. The first method is a Federal lease-produced CO2 emissions calculation for an update of the report, “Federal Lands Greenhouse Gas Emissions and Sequestration in the United States.” The methodology to incorporate Federal lease CO2 production emissions into the updated report relies on CO2 sales royalty data from the Office of Natural Resources Revenue (ONRR). The end usage points for the gas include enhanced oil recovery with CO2 (CO2-EOR), food and beverage, and chemical production. CO2-EOR is the main end point for natural CO2 production in the United States; it accounted for 94% of usage in 2022 [1]. Federal lands emissions from this sector are estimated at 460 metric tons of CO2 in 2022, a very small amount relative to most other Federal lands emissions sector estimates. The second new method, planned for a separate report, is a calculation of the geologic storage of CO2 on Federal lands. The second method estimates the CO2 stored under Federal surface lands and documents Federal climate change mitigation efforts. Currently, there is no storage of CO2 at an industrial level on Federal lands, however multiple proposals and projects are planned. This method was developed on non-Federal lands datasets in an effort to prepare for when these activities on Federal lands will require accounting. National estimates for CO2 geologic storage using this method, but without a Federal lands filtering step, totaled 8.0 million metric tons (Mt) in 2022. The two methods described here are new benchmark methods in a collection of accounting procedures to document the current state of greenhouse gas emissions and their storage on Federal lands. These benchmarks can then be used to measure any subsequent changes in emissions from or carbon storage beneath Federal lands. While the magnitude of the values is currently non-existent to small, emissions mitigation goals established by decision makers indicate that these values will grow, and their documentation will take on greater value and use.

continental United States

Uncertainty quantification of geologic energy storage in depleted gas reservoirs using material balance equations embedded in a hierarchical errors-in-variables model

The storage potential for gas in geologic settings, such as depleted hydrocarbon reservoirs and solution-mined salt caverns, is becoming salient to future energy infrastructure planning. Technologies such as carbon capture, utilization, and storage, carbon dioxide-enhanced oil recovery, and natural gas and hydrogen storage help meet growing energy demands, reduce carbon emissions to meet climate goals, and provide energy security amid geopolitical uncertainties. Therefore, estimates of underground gas storage capacity could be useful for efficiently navigating the energy transitions. Material balance is a fundamental method in reservoir engineering for estimating original gas in place and potential storage capacity at the scale necessary for national assessments of subsurface pore space resources. However, the deterministic method cannot accommodate multiple data sources or quantify uncertainty in predictions. In this study, a method that embeds material balance equations within a hierarchical errors-in-variables model is proposed which allows the estimation of the distributions of reservoir properties needed for assessments. Uncertainties associated with these reservoir properties have traditionally been expert-elicited, whereas the uncertainty estimates from the proposed models are data-driven. Capacity and uncertainty estimates can be used in a probabilistic resource assessment, supplementing information traditionally used by assessors or even replacing this expert elicitation step when data are unavailable. Various regression models are compared in a case study of the Michigan Basin, a large contributor to the United States’ current natural gas storage capacity. In particular, errors-in-variables models help ameliorate regression dilution and can quantify uncertainty in predictions of pressure in addition to storage capacity. Overfitting is addressed by quantifying generalization error and model averaging in simple and stratified cross-validation against reported working gas capacity, representing the varying quality and quantity of available data. Incorporating a statistical framework into existing numerical methods in reservoir engineering can improve the quality of estimation, and in particular, this method brings rigor to uncertainty quantification as part of a larger effort by the U.S. Geological Survey to assess domestic energy gas storage resources in depleted hydrocarbon reservoirs.

Mathematical Geosciences

Hydrogeologic characterization of the Cahuilla Valley and Terwilliger Valley Groundwater Basins, Riverside County, California

The relation between the groundwater and the amount of natural recharge to the Cahuilla Valley and Terwilliger Valley groundwater basins is not well understood. During the 20th century, the reliance on groundwater near Anza, California, used for agricultural, domestic, and municipal reasons has increased, and there is the potential for changes in groundwater availability related to climate change. Several types of existing data were evaluated, and new data were collected for this study, with the goal of characterizing the region’s hydrogeology. The study’s scope included constructing a geologic framework model to show where the groundwater-bearing units are present and their relation to each other, estimating the major components of the groundwater budget, and understanding local short-term and regional long-term groundwater flow and how that has changed since the early 1900s. Two electrical resistivity tomography surveys were done in the Durasno Valley about 2,150 feet apart to identify the thickness of the alluvium, its horizontal extent, and the depth-to-basement along two profiles perpendicular to Cahuilla Creek. The subsurface sediments were mostly horizontally layered and the transitional boundary between the alluvium and basement was thinner and shallower along the upgradient profile where the depth-to-basement was about 70 feet below land surface; the depth-to-basement at the downgradient profile was more than about 140 feet below land surface. The results from the surveys were used to place four monitoring wells at two sites along the survey profiles. Artesian flow from the deepest well at the downgradient site indicated that the decomposed and competent basement likely contributed some groundwater to the overlying alluvium, laterally, from below, or both. A digital three-dimensional geologic framework model was constructed using EarthVision software to represent the subsurface geometry of the alluvium, decomposed basement, and competent basement. Maps and cross sections of the modeled thicknesses of the alluvium and decomposed basement, and the modeled elevation of the top of the competent basement, were made to show the subsurface geometry of vertical faults, selected wells, and the groundwater-bearing units. Because natural recharge is related to the variable cycles of precipitation, estimates are difficult to quantify. Recharge and runoff have extreme interannual variability in the study area; recharge and runoff can be sporadic, and a substantive amount may not occur in some years. Estimates of recharge from a previous study and the regional-scale Basin Characterization Model for California for four different periods ranged from 3,800 acre-feet/year for 1897–1947 to 5,900 acre-feet/year for 1971–2000. Potential recharge from the disposal of domestic septic systems may have been as much as 500 acre-feet in 2020. It was estimated that between about 400 and 2,400 acre-feet/year of groundwater is lost through evapotranspiration by vegetation and evaporation from open water bodies, but the main source of discharge is through pumpage, mainly used for agriculture from the alluvium in the Cahuilla Valley and Terwilliger Valley groundwater basins. The estimated total pumpage for 1991–2021 ranged from about 1,140 acre-feet in 2019 to about 3,450 acre-feet in 1994. When summed, the cumulative amount of estimated pumpage between 1991 and 2021 was about 81,400 acre-feet. The general direction of groundwater flow is from the northeast along the San Jacinto fault zone at the headwaters of Cahuilla and Hamilton Creeks, to the surface-water outlets at the west and southeast parts of the study area. Groundwater-level data from the 1950s and earlier indicate that there was a natural groundwater divide between the Cahuilla Valley and Terwilliger Valley groundwater basins, but the changing magnitude and extent of the groundwater depressions caused by pumping since about 1950 indicate that the location of the natural groundwater boundary between the Cahuilla Valley and Terwilliger Valley groundwater basins has migrated over time. Flow from the upper to the lower parts of the Cahuilla Valley groundwater basin roughly follows the course of Cahuilla Creek through the narrow Durasno Valley where an estimated volume of flow in April 2019 was about 10–150 acre-feet/year. Short-term trends in groundwater levels, particularly in wells where groundwater is shallow and in the basement unit, show how some areas respond quickly to recharge and discharge. Wells located further to the east within the Cahuilla Valley groundwater basin in the alluvium show much less of a response to recharge events; areas of sustained pumpage from the alluvium, primarily for agriculture, show long-term declines in groundwater levels and generally do not show the effects of storm events or recent runoff. Groundwater levels in wells that are farthest from where most of the recharge occurs and where pumping has been the greatest, had some of the largest long-term groundwater-level declines at a rate of about 0.8 foot/year between 1971 and 2021.

California

Landsliding follows signatures of wildfire history and vegetative regrowth in a steep coastal shrubland

Five years after the deadly and destructive 9 January 2018 Montecito debris flows (Santa Barbara County, California, USA), an atmospheric river storm on 9 January 2023 triggered widespread landsliding that affected many of the same drainages in the Santa Ynez Mountains. Using high-resolution aerial imagery, we identified >10,000 landslides over an ∼160 km 2 area. Most of the landslides were shallow (<1 m in depth) translational debris slides that initiated on steep (∼40°), south-facing hillslopes, with the highest incidence of landsliding in a sandstone-dominated bedrock unit. The landslides mobilized into debris flows and delivered substantial quantities of sediment downstream, which contributed to costly infrastructure impairments. We detected order-of-magnitude differences in landslide density across the study area that could not be attributed to variations in geomorphology (topographic aspect and slope), geology (bedrock type), or hydrology (seasonal antecedent rainfall, peak hourly storm rainfall intensity, total storm rainfall), which are usually considered relevant factors for shallow landsliding. Rather, we found that vegetation regrowth following wildfire was likely a relevant factor associated with the highly variable landslide densities. Hillslopes with less and different types of vegetation regrowth after fire appear to have been more susceptible to shallow landslides. We identify a possible vegetation control on postfire landsliding, which highlights an opportunity for hypothesis testing using more advanced techniques to track the evolution of vegetation cover and vegetation type in steep shrubland environments following wildfire.

California

Stable isotope composition and geochemistry of calcite and dolomite in the Mountain Pass carbonatite: A lens into petrogenesis

Carbonatites host most of the global rare earth element (REE) deposits. The petrogenesis of these rocks, including magmatic and post-magmatic processes, are poorly understood but critical in forming and upgrading these deposits. The Mountain Pass carbonatite, which hosts the only active REE mine in North America, is lithologically variable but consistently contains >50% calcite and/or dolomite. Multiple generations of carbonates are evident, suggesting bulk analysis of carbonate minerals would generate a mixed isotopic and geochemical signature. In-situ stable carbon and oxygen isotopes, combined with geochemical analysis and petrography, distinguish carbonate generations, trace the source region of the carbonatite magma, and link carbonate genesis to REE mineralization throughout the intrusion. Primary carbon and oxygen isotope values outside the accepted mantle range may suggest a subduction-related carbon and oxygen source in the mantle. Deformation textures in primary calcite indicate syn- or post-crystallization ductile flow. Carbonates with secondary textures and heavy δ 13 C and δ 18 O values are associated with ore mineralization, suggesting fluid mobilization was important in concentrating REE and upgrading of the Mountain Pass deposit.

California

Evaluating harvest liberalization strategies on population dynamics of southern latitude temperate-breeding Canada geese

The recovery of the Canada goose ( Branta canadensis ) is one of North America's greatest conservation success stories. Today, continental abundance of temperate-breeding Canada geese (those breeding in southern Canada and lower 48 states in the United States) greatly exceeds historical levels. As a result of increased abundance, human–goose conflicts have also increased, ranging from private and agricultural property damage to human health concerns. Managers have primarily attempted to lower Canada goose populations using hunter harvest via liberalized hunting regulations (increased bag limits and total hunting days). To evaluate the effectiveness of harvest strategies for temperate-breeding Canada geese, managers need a better understanding of how liberalized hunting regulations affect population dynamics. We estimated survival and harvest probabilities, abundance, and recovery distribution of temperate-breeding Canada geese banded in Arkansas, USA, during 2005–2020. We found that adult harvest probabilities declined overall during the study and adult survival probabilities increased. Annual abundances of juvenile geese (≤1 year old) declined during the study, whereas there was no detectable trend in abundance of the adult population over time. Most Canada geese breeding in Arkansas were shot in Arkansas, indicating potential for population dynamics to be influenced largely by state-specific harvest regulations. However, our results suggest that harvest liberalization as a management tool may have limited capacity to further influence population dynamics of Canada geese. Declines in productivity and recruitment likely had a greater influence on the similar observed declines in juvenile and adult abundances, respectively, during our study. More research is needed to better understand the ecological mechanism affecting the population dynamics of Canada geese in both urban and rural environments.

Arkansas

Agricultural tile drains increase the susceptibility of streams to longer and more intense streamflow droughts

Streamflow droughts are receiving increased attention worldwide due to their impact on the environment and economy. One region of concern is the Midwestern United States, whose agricultural productivity depends on subsurface pipes known as tile drains to improve trafficability and soil conditions for crop growth. Tile drains accomplish this by rapidly transporting surplus soil moisture and shallow groundwater from fields, resulting in reduced watershed storage. However, no work has previously examined the connection between tile drainage and streamflow drought. Here, we pose the question: does the extent of watershed-level tile drainage lead to an increased susceptibly and magnitude of streamflow droughts? To answer this, we use daily streamflow data for 122 watersheds throughout the Midwestern United States to quantify streamflow drought duration, frequency, and intensity. Using spatial multiple regression models, we find that agricultural tile drainage generates statistically significant ( p < 0.05) increases in streamflow drought duration and intensity while significantly reducing drought frequency. The magnitude of the effect of tile drainage on streamflow drought characteristics is similar to that of water table depth and precipitation seasonality, both of which are known to influence streamflow droughts. Furthermore, projected changes in regional precipitation characteristics will likely drive the installation of additional tile drainage. We find that for each 10% increase in tile-drained watershed area, streamflow drought duration and intensity increase by 0.03 d and 12%, respectively, while frequency decreases by 0.10 events/year. Such increases in tile drainage may lead to more severe streamflow droughts and have a detrimental effect on the socio-environmental usage of streams throughout the Midwest.

Illinois, Indiana, Iowa, Michigan, Minnesota, Ohio

Competition between invasive round goby and native slimy sculpin in a coldwater laboratory setting

Slimy sculpin ( Cottus cognatus ) abundance has substantially declined in many regions of the Laurentian Great Lakes coincident with the arrival and range expansions of invasive round goby ( Neogobius melanostomus ). Previous studies have shown that round goby can outcompete native mottled sculpin ( C. bairdii ) for shelter and negatively affect native spoonhead sculpin ( C. ricei ) growth, but direct behavioral interactions of slimy sculpin and round goby have not been observed. We conducted a laboratory experiment in which a pair of slimy sculpin were placed in an aquarium that contained an artificial spawning shelter and one round goby (treatment, n = 10) or no other fish (control, n = 10) for at least 30 days at temperatures reflective of their potential offshore overlap. We measured slimy sculpin egg deposition, aggressive interactions, artificial shelter occupancy, growth, and survival. Slimy sculpin were less likely to occupy shelters and experienced increased intraspecific competition when a round goby was present. In contrast, round goby rarely chased slimy sculpin, slimy sculpin were more likely to chase round goby, and slimy sculpin growth, egg deposition, and survival were not significantly different between groups. Differences in density between treatments and the relative size of fish could confound our observations. However, the dominant slimy sculpin occupied the shelter at similar rates between experimental groups if the round goby was smaller. Our results indicate that larger round goby overlapping with slimy sculpin could affect slimy sculpin shelter and space use, but the Great Lakes environment may create more stress for slimy sculpin than we observed.

Lake Michigan, Lake Superior

Measuring stress In high pressure deformation experiments with high speed fiber-optics

High‐pressure, high‐temperature rock deformation experiments are essential for understanding deep Earth processes, but accurately measuring stress is challenging due to the inaccuracy introduced by seal friction within the apparatus and large inertia, which affects earthquake process measurements made far from the experimental fault. To overcome these limitations, we developed and implemented a simple, compact fiber‐optic sensor based on an External Cavity Fabry–Perot Interferometer for in situ load measurement on a piston inside the pressure vessel of a Griggs‐type high‐pressure apparatus. The sensor can be used at sample temperatures up to 800°C for both slow creep and fast rupture testing with bandwidth capability from DC to 6 MHz. Two important experimental results are described: (1) the first direct measurements of seal friction in this apparatus type; these measurements record seal friction approximately one‐tenth of the confining pressure under both low (150 MPa) and high (1 GPa) pressure conditions; and (2) high‐temporal resolution capture of dynamic stress drops during stick‐slip faulting events at high‐confining pressure, revealing near‐fault wave propagation details, high‐frequency oscillations, and implying high‐transient slip rates (6–12 m/s) previously inaccessible with external sensors.

The Seismic Record

Comparisons of shoreline positions from satellite-derived and traditional field- and remote-sensing techniques

Satellite-derived shorelines (SDS) have the potential to help researchers answer critical coastal science questions and support work to predict coastal change by filling in the spatial and temporal gaps present in current field-based and remote-sensing data collection methods. The U.S. Geological Survey conducted comparison analyses of traditionally sourced shorelines and SDS in diverse coastal landscapes to determine how SDS could be used in ongoing and future work across varied coastal environments and provided some initial findings that could be used for implementation. Using CoastSeg, a browser-based program for SDS detection and mapping, SDS for the period 1984–2023 for multiple locations across the United States were compared to shoreline positions from traditionally sourced shoreline data. In this report, the authors present these comparisons alongside lessons learned and challenges encountered when building SDS workflows in different coastal locations. Results show that individual SDS have larger uncertainty and yet produced similar linear trends to sparser, traditionally sourced shoreline data; because SDS methods provide orders of magnitude more data than traditional shoreline-detection methods, they can be used to evaluate shoreline behaviors. Refining average scalar slopes used in tidal corrections did not result in substantial decreases in uncertainty. Using lessons from this work to outline needs for regional implementation, initial setup time would be considerable, being on the order of weeks. However, once complete, shoreline detections and analyses are fast (on the order of minutes to hours) and achievable using a desktop computer.

Alaska, Florida, Massachusetts, Washington

Colored shaded relief bathymetry and acoustic backscatter of Ozette Lake, Washington

Offshore of the Pacific Northwest of the United States is the Cascadia Subduction Zone, a 1,000-kilometer-long tectonic boundary defined by a large fault, called a megathrust, that extends from the Mendocino Junction off northern California to the Nootka Fracture Zone off Vancouver Island, Canada (U.S. Geological Survey, 2023). The Juan de Fuca and Gorda oceanic plates to the west of this boundary subduct under the North America continental plate to the east. Several other smaller faults that cut through the North America plate crust also affect the region. Although their effects upon Ozette Lake are uncertain, geological evidence for past earthquakes, such as underwater landslides, may be found in Pacific Northwest lakes. Underwater landslides caused by past earthquakes should be well preserved in these relatively undisturbed lake environments. The floor of Ozette Lake, Washington, located along the Pacific coast of the United States, west of the Puget Sound region and about 140 kilometers east of the megathrust was mapped by the U.S. Geological Survey in July of 2019 to search for evidence of past earthquakes. Mapping was completed using a SWATHplus-M 234-kHz interferometric side scan sonar system pole-mounted on the U.S. Geological Survey research vessel San Lorenzo. The system collected full-coverage bathymetric and acoustic backscatter data that were processed to 2-meter spatial resolution (Dartnell and others, 2024). This two-map series displays the results of this mapping. A colored shaded relief bathymetry map (sheet 1) and an acoustic backscatter map (sheet 2) show the lake floor morphology and backscatter intensities, respectively, that can be analyzed for evidence of past earthquakes.

Washington

Spatial distribution of API gravity and gas/oil ratios for petroleum accumulations in Upper Cretaceous strata of the San Miguel, Olmos, and Escondido Formations of the south Texas Maverick Basin—Implications for petroleum migration and charge history

The Maverick Basin of south Texas is currently undergoing active exploration and production of gas and oil from tight sandstone reservoirs. The most productive tight sandstones in the basin are in the Upper Cretaceous San Miguel, Olmos, and Escondido Formations. These units are second only to the Eagle Ford Shale in terms of cumulative production volumes. The structural history of the Maverick Basin, from rifting to subsidence to exhumation, has had a profound effect on the characteristics of these reservoirs and the petroleum resources contained therein. This U.S. Geological Survey review of the production history of these strata reflects a recent shift from conventional production to horizontal drilling (unconventional) that exploits low permeability reservoirs in previously overlooked areas of existing oil and gas fields in southern Texas, typically outside of established field boundaries. To investigate the physical properties of the Maverick Basin hydrocarbon accumulations, this case study compiled American Petroleum Institute (API) gravity measurements and calculated cumulative gas/oil ratios (GOR) for thousands of producing wells from the San Miguel, Olmos, and Escondido Formations. Maps were generated from the compiled well production data to show the spatial heterogeneity of API gravity and GOR values for the three formations within the Maverick Basin and immediately outside the basin to the northeast. Within the Maverick Basin, the spatial patterns of API gravity values indicate lighter oils downdip towards the southern basin edge. GOR values indicative of wet and dry gases within the basin are seen interspersed, with values that correspond to black and heavy oils. Differences in the spatial patterns of the petroleum properties within the Maverick Basin are interpreted as effects of Eocene basin inversion caused by Laramide orogenic deformation, and the resulting reservoir exhumation of basin strata. East of the Maverick Basin, spatial distributions of API gravity and GOR values show progressively heavier oils updip to the northwest, grading to dry gases downdip to the southeast, which correlates to the oil and gas windows of the underlying Eagle Ford Shale. Correlation of API gravity and GOR values from the San Miguel, Olmos, and Escondido Formations with thermal maturity data from the Eagle Ford Shale suggests that the Eagle Ford Shale is the petroleum source, and that petroleum migration was approximately vertical for areas to the east of the Maverick Basin. The discontinuity of API gravity and GOR properties within the Maverick Basin implies a complex petroleum charge history, possibly involving the remigration of petroleum and the addition of petroleum from other source intervals in Mexico, to the southwest. Depressurization of exhumed, overpressured reservoirs of the San Miguel, Olmos, and Escondido Formations can explain the intermittent occurrence of gas production throughout the southern Maverick Basin by exsolution of gas from formation brines and the resulting dry gas flushing of hydrocarbon-charged reservoirs. The introduction of dry gas through flushing can, in turn, explain why the patterns of API gravity and GOR values are so dissimilar in the Maverick Basin. This process has implications for possible future production of unconventional resources from undiscovered tight-gas reservoirs in strata of the San Miguel, Olmos, and Escondido Formations, and a different approach to petroleum exploration may be needed in the Maverick Basin relative to exploration techniques applied in other basins within the northern Gulf of Mexico.

Texas

Layered intrusions in the Precambrian: Observations and perspectives

Layered intrusions are plutonic bodies of cumulates that form by the crystallization of mantle-derived melts. These intrusions are characterized by igneous layering distinguishable by shifts in mineralogy, texture, or composition. Layered intrusions have been fundamental to our understanding of igneous petrology; however, it is their status as important repositories of critical metals – such as platinum-group elements, chromium, and vanadium – that has predominantly driven associated research in recent decades. Many layered intrusions were emplaced during the Precambrian, predominantly at the margins of ancient cratons during intervals of supercontinent accretion and destruction. It appears that large, layered intrusions require rigid crust to ensure their preservation, and their geometry and layering is primarily controlled by the nature of melt emplacement. Layered intrusions are best investigated by integrating observations from various length-scales. At the macroscale, intrusion geometries can be discerned, and their presence understood in the context of the regional geology. At the mesoscale, the layering of an intrusion may be characterized, intrusion-host rock contact relationships studied, and the nature of stratiform mineral occurrences described. At the microscale, the mineralogy and texture of cumulate rocks and any mineralization are elucidated, particularly when novel microtextural and mineral chemical datasets are integrated. For example, here we demonstrate how mesoscale observations and microscale datasets can be combined to understand the petrogenesis of the perplexing snowball oiks outcrop located in the Upper Banded Series of the Stillwater Complex. Our data suggest that the orthopyroxene oikocrysts did not form in their present location, but rather formed in a dynamic magma chamber where crystals were transported either by convective currents or within crystal-rich slurries. Critical metals may be transported to the level of a nascent intrusion as dissolved components in the melt. Alternatively, ore minerals are entrained from elsewhere in a plumbing system, potentially facilitated by volatile-rich phases. There are many ore-forming processes propounded by researchers to occur at the level of emplacement; however, each must address the arrival of the ore mineral, its concentration of metals, and its accumulation into orebodies. In this contribution, several of these processes are described as well as our perspectives on the future of layered intrusion research.

Precambrian Research

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–2023, California groundwater ambient monitoring and assessment program, priority basin project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–2023. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban- and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert-butyl ether (MTBE) showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids (TDS) statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in TDS by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and MTBE are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

EarthArXiv

Land-based nutrient flux to a fringing reef: Insights from Ofu Island, American Samoa

Submarine groundwater discharge (SGD) is a critical driver of nutrient transport in coral reef ecosystems, shaping water quality, primary productivity, and overall reef health. This study quantifies SGD fluxes and associated nutrient dynamics in two reef flat pools within the Ofu Unit of the National Park of American Samoa: Papaloloa and Fatuana. A multi-method approach integrating unoccupied aerial system-based thermal infrared (UAS-TIR) surveys, radon-based SGD measurements, multichannel electrical resistivity tomography (ERT), and discrete water sampling was used to assess SGD rates and nutrient contributions. UAS-TIR imagery revealed cooler sea surface temperatures in both pools, indicative of SGD, with the higher fluxes observed in Papaloloa. Radon measurements revealed a strong inverse correlation between SGD rates and tidal stage, with a more immediate SGD response at Papaloloa due to its highly permeable calcareous sand and gravel substrate. In contrast, a 2–3-hour lag in SGD response at Fatuana suggests discharge from a more inland aquifer that has lower diffusivity. Nutrient concentrations correlated with temperature and salinity, confirming SGD as the dominant nutrient transport mechanism, whereas isotopic analyses indicated inputs from both groundwater and potential anthropogenic sources. Despite lower SGD flux at Fatuana, higher algal cover suggests additional factors influencing algal proliferation, including substrate availability and hydrodynamic conditions. Excess nutrient inputs from SGD may contribute to algal overgrowth, which threatens Ofu’s thermally tolerant corals by increasing competition for space and light. These findings underscore the complexity of SGD-mediated nutrient dynamics in reef environments and emphasize the need for integrated hydrological and ecological assessments to support effective reef conservation and management strategies.

American Samoa, Ofu Island, Olosega Island

International data gaps at the Center for Engineering Strong Motion Data

The Center for Engineering Strong Motion Data (CESMD) is utilized by seismologists, engineers, and disaster management professionals in the US and has historically achieved and distributed waveforms from across the globe for significant earthquakes. The increased access to the waveforms via Web API (Application Programming Interface) offers a unique opportunity to provide the community complete datasets, sampling a variety of tectonic environments and geologic conditions, increasing the number of available ground motion records for use in ground motion models (GMMs) and improving the accuracy of earthquake engineering evaluations. The objective of this study is to programmatically identify gaps in global event data from the past decade and backfill missing data gaps at CESMD. We first compare the CESMD catalog with the Advanced National Seismic System (ANSS) Comprehensive Earthquake Catalog identifying regions and time periods where strong-motion data is limited or inadequate. To backfill datasets at CESMD for significant events, we pinpoint regions and time intervals that lack information, creating a list of events for which we’d like to obtain data. An important facet of this work is identifying the source of data and metadata across earthquake repositories around the world and integrating these data repositories into our current strong-motion data processing workflow. In parallel with these newly processed datasets, we are developing a script to produce data origination citations to include provenance and attribution information to associate with respective datasets at CESMD. We showcase our methodology for identifying and filling data gaps at CESMD using three case studies (the 2018 Anchorage Alaska earthquake sequence, seismicity associated with the 2018 Hawaiian Kilauea volcano eruption, and several earthquakes in Turkey) and then outline our strategy to apply our data gap backfilling methods on an international scale.

Conference Paper