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At least 451 records · Page 25Linked to original sources
USGS2013

Assessing total nitrogen in surface-water samples--precision and bias of analytical and computational methods

The characterization of total-nitrogen (TN) concentrations is an important component of many surface-water-quality programs. However, three widely used methods for the determination of total nitrogen—(1) derived from the alkaline-persulfate digestion of whole-water samples (TN-A); (2) calculated as the sum of total Kjeldahl nitrogen and dissolved nitrate plus nitrite (TN-K); and (3) calculated as the sum of dissolved nitrogen and particulate nitrogen (TN-C)—all include inherent limitations. A digestion process is intended to convert multiple species of nitrogen that are present in the sample into one measureable species, but this process may introduce bias. TN-A results can be negatively biased in the presence of suspended sediment, and TN-K data can be positively biased in the presence of elevated nitrate because some nitrate is reduced to ammonia and is therefore counted twice in the computation of total nitrogen. Furthermore, TN-C may not be subject to bias but is comparatively imprecise. In this study, the effects of suspended-sediment and nitrate concentrations on the performance of these TN methods were assessed using synthetic samples developed in a laboratory as well as a series of stream samples. A 2007 laboratory experiment measured TN-A and TN-K in nutrient-fortified solutions that had been mixed with varying amounts of sediment-reference materials. This experiment identified a connection between suspended sediment and negative bias in TN-A and detected positive bias in TN-K in the presence of elevated nitrate. A 2009–10 synoptic-field study used samples from 77 stream-sampling sites to confirm that these biases were present in the field samples and evaluated the precision and bias of TN methods. The precision of TN-C and TN-K depended on the precision and relative amounts of the TN-component species used in their respective TN computations. Particulate nitrogen had an average variability (as determined by the relative standard deviation) of 13 percent. However, because particulate nitrogen constituted only 14 percent, on average, of TN-C, the precision of the TN-C method approached that of the method for dissolved nitrogen (2.3 percent). On the other hand, total Kjeldahl nitrogen (having a variability of 7.6 percent) constituted an average of 40 percent of TN-K, suggesting that the reduced precision of the Kjeldahl digestion may affect precision of the TN-K estimates. For most samples, the precision of TN computed as TN-C would be better (lower variability) than the precision of TN-K. In general, TN-A precision (having a variability of 2.1 percent) was superior to TN-C and TN-K methods. The laboratory experiment indicated that negative bias in TN-A was present across the entire range of sediment concentration and increased as sediment concentration increased. This suggested that reagent limitation was not the predominant cause of observed bias in TN-A. Furthermore, analyses of particulate nitrogen present in digest residues provided an almost complete accounting for the nitrogen that was underestimated by alkaline-persulfate digestion. This experiment established that, for the reference materials at least, negative bias in TN-A was caused primarily by the sequestration of some particulate nitrogen that was refractory to the digestion process. TN-K biases varied between positive and negative values in the laboratory experiment. Positive bias in TN-K is likely the result of the unintended reduction of a small and variable amount of nitrate to ammonia during the Kjeldahl digestion process. Negative TN-K bias may be the result of the sequestration of a portion of particulate nitrogen during the digestion process. Negative bias in TN-A was present across the entire range of suspended-sediment concentration (1 to 14,700 milligrams per liter [mg/L]) in the synoptic-field study, with relative bias being nearly as great at sediment concentrations below 10 mg/L (median of -3.5 percent) as that observed at sediment concentrations up to 750 mg/L (median of -4.4 percent). This lent support to the laboratory-experiment finding that some particulate nitrogen is sequestered during the digestion process, and demonstrated that negative TN-A bias was present in samples with very low suspended-sediment concentrations. At sediment concentrations above 750 mg/L, the negative TN-A bias became more likely and larger (median of -13.2 percent), suggesting a secondary mechanism of bias, such as reagent limitation. From a geospatial perspective, trends in TN-A bias were not explained by selected basin characteristics. Though variable, TN-K bias generally was positive in the synoptic-field study (median of 3.1 percent), probably as a result of the reduction of nitrate. Three alternative approaches for assessing TN in surface water were evaluated for their impacts on existing and future sampling programs. Replacing TN-A with TN-C would remove the bias from subsequent data, but this approach also would introduce discontinuity in historical records. Replacing TN-K with TN-C would lead to the removal of positive bias in TN-K in the presence of elevated nitrate. However, in addition to the issues that may arise from a discontinuity in the data record, this approach may not be applicable to regulatory programs that require the use of total Kjeldahl nitrogen for stream assessment. By adding TN-C to existing TN-A or TN-K analyses, historical-data continuity would be preserved and the transitional period could be used to minimize the impact of bias on data analyses. This approach, however, imposes the greatest burdens on field operations and in terms of analytical costs. The variation in these impacts on different sampling programs will challenge U.S. Geological Survey scientists attempting to establish uniform standards for TN sample collection and analytical determinations.

Scientific Investigations Report↗
USGS2012

Evidence from central Mexico supporting the Younger Dryas extraterrestrial impact hypothesis

We report the discovery in Lake Cuitzeo in central Mexico of a black, carbon-rich, lacustrine layer, containing nanodiamonds, microspherules, and other unusual materials that date to the early Younger Dryas and are interpreted to result from an extraterrestrial impact. These proxies were found in a 27-m-long core as part of an interdisciplinary effort to extract a paleoclimate record back through the previous interglacial. Our attention focused early on an anomalous, 10-cm-thick, carbon-rich layer at a depth of 2.8 m that dates to 12.9 ka and coincides with a suite of anomalous coeval environmental and biotic changes independently recognized in other regional lake sequences. Collectively, these changes have produced the most distinctive boundary layer in the late Quaternary record. This layer contains a diverse, abundant assemblage of impact-related markers, including nanodiamonds, carbon spherules, and magnetic spherules with rapid melting/quenching textures, all reaching synchronous peaks immediately beneath a layer containing the largest peak of charcoal in the core. Analyses by multiple methods demonstrate the presence of three allotropes of nanodiamond: n-diamond, i-carbon, and hexagonal nanodiamond (lonsdaleite), in order of estimated relative abundance. This nanodiamond-rich layer is consistent with the Younger Dryas boundary layer found at numerous sites across North America, Greenland, and Western Europe. We have examined multiple hypotheses to account for these observations and find the evidence cannot be explained by any known terrestrial mechanism. It is, however, consistent with the Younger Dryas boundary impact hypothesis postulating a major extraterrestrial impact involving multiple airburst(s) and and/or ground impact(s) at 12.9 ka.

Lake Cuitzeo↗
USGS2021

Repeating caldera collapse events constrain fault friction at the kilometer scale

Fault friction is central to understanding earthquakes, yet laboratory rock mechanics experiments are restricted to, at most, meter scale. Questions thus remain as to the applicability of measured frictional properties to faulting in situ. In particular, the slip-weakening distance d c "> d c dc strongly influences precursory slip during earthquake nucleation, but scales with fault roughness and is challenging to extrapolate to nature. The 2018 eruption of K̄ılauea volcano, Hawaii, caused 62 repeatable collapse events in which the summit caldera dropped several meters, accompanied by M W "> M W MW 4.7 to 5.4 very long period (VLP) earthquakes. Collapses were exceptionally well recorded by global positioning system (GPS) and tilt instruments and represent unique natural kilometer-scale friction experiments. We model a piston collapsing into a magma reservoir. Pressure at the piston base and shear stress on its margin, governed by rate and state friction, balance its weight. Downward motion of the piston compresses the underlying magma, driving flow to the eruption. Monte Carlo estimation of unknowns validates laboratory friction parameters at the kilometer scale, including the magnitude of steady-state velocity weakening. The absence of accelerating precollapse deformation constrains d c "> d c dc to be ≤ 10 "> ≤ 10 ≤10 mm, potentially much less. These results support the use of laboratory friction laws and parameters for modeling earthquakes. We identify initial conditions and material and magma-system parameters that lead to episodic caldera collapse, revealing that small differences in eruptive vent elevation can lead to major differences in eruption volume and duration. Most historical basaltic caldera collapses were, at least partly, episodic, implying that the conditions for stick–slip derived here are commonly met in nature.

Hawaii↗
USGS2005

Mudstone sedimentation at high latitudes: Ice as a transport medium for mud and supplier of nutrients

Controls on mudstone deposition at high latitudes are poorly known relative to low latitudes. In recent sediments deposited in these environments, ice significantly influences sediment transport and primary productivity. The products of ice transport are relatively well known in glacimarine settings, but are less well known from below melting sea ice. This latter setting is significant as today it is associated with high primary organic productivity. The aim of this study is to assess how sea ice might have controlled lithofacies variability and organic-matter distribution and preservation in an ancient marine, siliciclastic mudstone-dominated succession deposited at high latitudes. Combined sedimentary logging, optical and electron optical (back-scatte red electron imagery), geochemical, and isotopic methods were used to determine sample variability in forty-five samples collected from the Lower Cretaceous succession in the Mikkelsen Bay State #1 borehole (North Slope, Alaska). The succession overall fines upward and contains muddy sandstones and sand- and silt-bearing, clay-rich mudstones towards its base in contrast to clay-rich and clay-dominated mudstones towards its top. Some of the mudstone units exhibit thin (< 5 mm), relic-beds that fine upward weakly. In some units small (0.5 mm), bed-parallel silt-filled microburrows disrupt depositional laminae whereas in others pervasive burrowing completely obliterates original depositional textures. Many of the units are pelleted. These mudstones are unusual in that they contain minor but very striking outsize grains, composed of subrounded to rounded sand and granule-size material. In addition, they are good petroleum source rocks, with between 2.8 and 5.9 wt % total organic carbon, of predominantly Type II kerogen. The organic matter has an isotopic signature ranging from -25.4??? ??13C to -28.1??? ??13C. Thin tuffs (< 20 mm) and carbonate-cemented units are also present. Given the absence of significant polar ice in the Early Cretaceous the outsized grains are interpreted to have been deposited from a combination of melting, dirty anchor, and fast ice. The mud fraction, which forms the bulk of the sediment, is interpreted to have been deposited from melting, sediment-laden frazil ice, and fast ice. After deposition sediments were partially reworked by bottom currents generated by brine rejection during sea ice formation. Sympagic organisms, grazing on algae and bacteria both within and below the ice, pelleted the sediment. Bioturbation, which varies through the succession, indicates that sedimentation probably occurred beneath a predominantly oxic or dysoxic water column. In this setting productivity was fueled by nutrients released from melting sea ice in the marginal ice zone. The good petroleum source potential of these mudstones is attributed to high organic productivity coupled to episodic and rapid sedimentation rather than existence of bottom-water anoxia linked to upwelling. Because sea-ice rafting was probably the dominant sediment transport mechanism it is not appropriate to use sequence stratigraphic methodology to predict lithofacies variability in this environment. Copyright ?? 2005, SEPM (Society for Sedimentary Geology).

Journal of Sedimentary Research↗
USGS2003

Near-field survey of the 1946 Aleutian tsunami on Unimak and Sanak Islands

The 1946 Aleutian earthquake stands out among tsunamigenic events because it generated both very high run-up near the earthquake source region and a destructive trans-Pacific tsunami . We obtained new data on the distribution of its tsunami in the near field along south-facing coasts between Unimak Pass on the west and Sanak Island on the east by measuring the height of driftwood and beach materials that were deposited by the tsunami above the extreme storm tide level. Our data indicate that (1) the highest measured run-up, which is at the Scotch Cap lighthouse, was 42 m above tide level or about 37 m above present storm tide elevation; (2) run-up along the rugged coast from Scotch Cap for 12 km northwest to Sennett Point is 12-18 m, and for 30 km east of Scotch Cap to Cape Lutke it is 24-42 m; (3) run-up along the broad lowlands bordering Unimak Bight is 10-20 m, and in-undation is locally more than 2 km; (5) run-up diminishes to 8 m or less at the southeast corner of Unimak Island ; (6) no evidence was found for run-up above present storm tides (about 4-5 m above MLLW) on the Ikatan Peninsula or areas along the coast to the west; and (7) run-up above storm tide level in the Sanak Island group is restricted to southwest-facing coasts of Sanak , Long, and Clifford Islands , where it is continuous and locally up to 24 m high. Generation of the tsunami by one or more major earthquake-triggered submarine landslides near the shelf edge south of Unimak Island seems to be the only viable mechanism to account for the data on wave arrival time, run-up heights, and distribution, as well as for unconfirmed anecdotal reports of local postquake increases in water depth and diminished bottom-fisheries productivity. A preliminary hydrodynamic simulation of the local tsunami propagation and run-up using a dipolar model of a possible landslide off Davidson Bank provides an acceptable fit to the characteristics of the distribution of local run-up, with a value at 34 m at the Scotch Cap lighthouse.

Bulletin of the Seismological Society of America↗
USGS1982

Production and decomposition of forest litter fall on the Apalachicola River flood plain, Florida

Measurements of litter fall (leaves and other particulate organic material) and leaf decomposition were made on the bottom-land hardwood swamp of the Apalachicola River flood plain in 1979-80. Litter fall was collected monthly from nets located in 16 study plots. The plots represented five forest types in the swamp and levee areas of the Apalachicola River flood plain. Forty-three species of trees, vines, and other plants contributed to the total litter fall, but over 90 percent of the leaf material originated from 12 species. Nonleaf material comprised 42 percent of the total litter fall. Average litter fall was determined to be 800 grams per square meter per year, resulting in an annual deposition of 360,000 metric tons of organic material in the 454-square-kilometer flood plain. The levee communities have lower tree biomass but higher tree diversity than swamp communities. The levee vegetation, with lower tree biomass, produces slightly more litter fall per ground surface area than the swamp vegetation. The swamps are dominated by three genera: tupelo (Nyssa), cypress (Taxodium), and ash (Fraxinus). These genera account for over 50 percent of the total leaf fall in the flood plain but they are the least productive, on a weight-per-biomass basis, of any of the 12 major leaf producers. Decomposition rates of leaves from five common flood-plain tree species were measured using a standard leaf-bag technique. Leaf decomposition was highly species-dependent. Tupelo (Nyssa spp.) and sweetgum (Liquidambar styraciflua) leaves decomposed completely in 6 months when flooded by river water. Leaves of baldcypress (Taxodium distichum) and diamond-leaf oak (Quercus laurifolia) were much more resistant. Water hickory (Carya aquatica) leaves showed intermediate decomposition rates. Decomposition of all species was greatly reduced in dry environments. Carbon and biomass loss rates from the leaves were nearly linear over a 6-month period, but nitrogen and phosphorus leaching was nearly complete within 1 month. Much of the organic substance may be recycled in the forest ecosystem, but annual flooding of the river provides an important mechanism for mobilization of the litter-fall products.

Florida↗
USGS1996

The roles of organic matter in the formation of uranium deposits in sedimentary rocks

Because reduced uranium species have a much smaller solubility than oxidized uranium species and because of the strong association of organic matter (a powerful reductant) with many uranium ores, reduction has long been considered to be the precipitation mechanism for many types of uranium deposits. Organic matter may also be involved in the alterations in and around tabular uranium deposits, including dolomite precipitation, formation of silicified layers, iron-titanium oxide destruction, dissolution of quartz grains, and precipitation of clay minerals. The diagenetic processes that produced these alterations also consumed organic matter. Consequently, those tabular deposits that underwent the more advanced stages of diagenesis, including methanogenesis and organic acid generation, display the greatest range of alterations and contain the smallest amount of organic matter. Because of certain similarities between tabular uranium deposits and Precambrian unconformity-related deposits, some of the same processes might have been involved in the genesis of Precambrian unconformity-related deposits. Hydrologic studies place important constraints on genetic models of various types of uranium deposits. In roll-front deposits, oxidized waters carried uranium to reductants (organic matter and pyrite derived from sulfate reduction by organic matter). After these reductants were oxidized at any point in the host sandstone, uranium minerals were reoxidized and transported further down the flow path to react with additional reductants. In this manner, the uranium ore migrated through the sandstone at a rate slower than the mineralizing ground water. In the case of tabular uranium deposits, the recharge of surface water into the ground water during flooding of lakes carried soluble humic material to the water table or to an interface where humate precipitated in tabular layers. These humate layers then established the chemical conditions for mineralization and related alterations. In the case of Precambrian unconformity-related deposits, free thermal convection in the thick sandstones overlying the basement rocks carried uranium to concentrations of organic matter in the basement rocks.

Ore Geology Reviews↗
USGS1977

Surficial and applied surficial geology of the Belchertown Quadrangle, Massachusetts

Till and stratified drift overlie maturely dissected topography in the Belchertown quadrangle, an area that straddles the New England Upland and Connecticut Valley Lowland in central Massachusetts. Lower Paleozoic, massive quartzo-feldspathic gneiss, quartzite and schist of the Pelham dome and Devonian granodiorite and quartz diorite of the Belchertown intrusive complex are in contact with Triassic arkosic fanglomerate and basalt along a lengthy normal fault separating the New England Upland from the Connecticut Valley Lowland. The orientation of striae, roches moutonnees, and streamline ridges indicate that the last Wisconsinian glacier advanced generally south 12? east. This glacier removed several meters of rock from the upland and an unknown larger quantity from the preglacial valley of the Connecticut River. Till is thin in the uplands, but several tens of feet of drift overlie bedrock in the lowland. Three lithic facies of sandy, clast-rich, non-compact, subarkosic till derived from the three major source rocks rest on bedrock or on highly weathered, compact, clast-poor, fissile probably older till. The mean for all upper till is 69.6% sand, 21.7% silt, and 8.8% clay; lower till consists of 48% sand, 23% silt and 29% clay. Mud-rich, compact, sparsely stony till in drumlins in and along the flank of the Connecticut Valley Lowland is composed of 51.5% sand, 28% silt, and 20.5% clay. Upper tills are facies equivalent deposits of the youngest Wisconsinian drift. Lower till is compact deeply weathered, jointed and stained suggesting it is correlative with other lower till in New England deposited by an earlier Wisconsinian glacier. Drumlin till may be a facies equivalent of a lower till or a mud-rich upper till derived from earlier glaciolacustrine deposits. Upper and lower till of the Belchertown quadrangle is texturally similar to other New England upper and lower tills to which they are equivalent. Both tills are interpreted as lodgment till derived from similar bedrock terrane by two different glaciers. The older glacier incorporated mud-rich saprolite producing a fine grained till, while the younger glacier eroded fresh bedrock or a thin regolith produced by mechanical weathering. During stagnation zone retreat of the last glacier, stratified drift was deposited by melt water in, on, alongside or down valley from stagnant ice. The absence of stratified drift along upland divides indicates that stagnation did not begin till large nunataks were emergent. Kame terraces, kame deltas, and ice channel fillings indicate that melt water flowed along stagnant ice and emptied into temporary proglacial lakes. As downwasting progressed, water was able to drain at lower elevation into expanding lakes, the last of which merged with northward-expanding proglacial Lake Hitchcock in the Connecticut Valley. Initial melt water drainage to the southeast was followed by drainage to the southwest to the ancestral Chicopee River. With the opening of the Narrows, Lake Hitchcock expanded northward and eastward to form the Amherst embayment into which melt water from the eastern uplands drained. Sand and gravel overlying varves in the Amherst embayment was deposited in late-glacial Lake Lawrence, which coalesced with equivalent Lake Hadley through cols between drumlins in the Connecticut Valley Lowland. Deglaciation of the Belchertown quadrangle probably occurred in a span of about 100 years in the interval 12,000 to 12,500 years B.P. Unconsolidated sediments of the Belchertown quadrangle are summarized as to their geologic and geotechnical properties for land use planning. Drift as it influences groundwater flow, yield, and quality and as a construction material is assessed. Some environmental degradation has occurred from the indiscriminant disposal of liquid and solid waste as well as injudicious use of road salt.

Open-File Report↗
USGS1960

Evaporation control research, 1955-58

One hundred fifty-two compounds and compositions of matter were screened as potential evaporation retardants. The homologous straight-chain fatty alkanols are considered the best materials for retardants. Several methods of application of the alkanols to the reservoir surface were investigated. Although wick-type drippers for the application of liquids and cage rafts for the application of solids appear to be the most promising methods from an economic standpoint, both methods have serious disadvantages. Considerable study was given to reducing biochemical oxidation of the evaporation retardants. Copper in several forms was found adequate as a bacteriostatic agent but posed a potential hazard because of its toxicity. Many other bactericides that were tested were also toxic. Two sets of large-scale field tests have been completed and several others are still in progress. On the larger reservoirs, the reduction of evaporation was not more than 20 percent under the prevailing conditions and the application procedure used. Three major practical problems remain; namely, the effects and action of wind on the monofilm, the effects of biochemical oxidation, and the most effective method of application. Fundamental problems remaining include the effects of various impurities, and the composition of the best evaporation retardant; the long-range effects of monofilms on the limnology of a reservoir, including the transfer of oxygen and carbon dioxide; toxicological aspects of all components of any evaporation-retardant composition, plus toxicology of any composition chosen for large-scale use; and further studies of the calorimetry and thermodynamics involved in the mechanism of evaporation and its reduction by a monofilm.

Water Supply Paper↗
USGS2012

Impact crater outflows on Venus: Morphology and emplacement mechanisms

Many of the 932 impact craters discovered by the Magellan spacecraft at Venus are associated with lobate flows that originate at or near the crater rim. They extend for several to several hundred kilometers from the crater, and they commonly have a strong radar backscatter. A morphologic study of all identifiable crater outflows on Venus has revealed that many individual flows each consist of two areas, defined by distinct morphologic features. These two areas appear to represent two stages of deposition for each flow. The part of the flow that is generally deposited closest to the crater tends to be on the downrange side of the crater, flows in the downrange direction, and it is interpreted to be a late-stage ejecta. In many cases, this proximal part of the flow is too thin to completely bury the large blocks in subjacent ejecta deposits. Dendritic channels, present in many proximal flows, appear to have drained liquid from the proximal part in the downhill direction, and they debouch to feed the outer part of the flows. This distal part flows downhill, fills small grabens, and is ponded by ridges, behavior that mimics that of volcanic lava flows. The meandering and dendritic channels and the relation of the distal flows to topography strongly suggest that the distal portion is the result of coalescence and slow drainage of impact melt from the proximal portion. Impact melt forms a lining to the transient crater and mixes turbulently with solid clasts, and part of this mixture may be ejected to form the proximal part of the flow during the excavation stage of crater development. A statistical study of the Venusian craters has revealed that, in general, large craters produced by impacts with relatively low incidence angles to the surface are more likely to produce flows than small craters produced by higher-angle impacts. The greater flow production and downrange focusing of the proximal flows with decreasing incidence angle indicate a strong control of the flows by the impactor flight direction, and a high downrange velocity imparted to the proximal flow material in lower angle impacts. On the Moon, small flows interpreted to be composed of impact melt are observed atop the ejecta of large, fresh craters; on Earth, melt-rich suevite deposits form the uppermost layer of ejecta of some fresh craters. These features, albeit much smaller, may be analogous to the flows on Venus. Numerical models have predicted that larger volumes of impact melt would be produced on Venus than on the cooler terrestrial bodies due to high atmospheric and target temperatures, perhaps 3 times the volume produced on the Moon for a given crater diameter.

Journal of Geophysical Research E: Planets↗
USGS2022

Museum genomics provide evidence for persistent genetic differentiation in a threatened seabird species in the Western Atlantic

Connectivity among wildlife populations facilitates exchange of genetic material between groups. Changes to historical connectivity patterns resulting from anthropogenic activities can therefore have negative consequences for genetic diversity, particularly for small or isolated populations. DNA obtained from museum specimens can enable direct comparison of temporal changes in connectivity among populations, which can aid in conservation planning and contribute to understanding of population declines. However, museum DNA can be degraded and only available in low quantities, rendering it challenging for use in population genomic analyses. Applications of genomic methodologies such as targeted sequencing address this issue by enabling capture of shared variable sites, increasing quantity and quality of recovered genomic information. We used targeted sequencing of Ultra-conserved Elements (UCEs) to evaluate potential changes in connectivity and genetic diversity of roseate terns ( Sterna dougallii ) with a breeding distribution in the Northwestern Atlantic and the Caribbean. Both populations experienced range contractions and population declines due to anthropogenic activity in the 20 th century, which has the potential to alter historical connectivity regimes. Instead, we found that the two populations were differentiated historically as well as contemporaneously, with little evidence of migration between them for either time period. We also found no evidence for temporal changes in genetic diversity, although these interpretations may have been limited due to sequencing artifacts caused by the degraded nature of the museum samples. Population structuring in migratory seabirds is typically reflective of low rates of divergence and high connectivity among geographically segregated subpopulations. Our contrasting results suggest the potential presence of ecological mechanisms driving population differentiation, and highlight the value of targeted sequencing on DNA derived from museum specimens to uncover long-term patterns of genetic differentiation in wildlife populations.

Integrative and Comparative Biology↗
USGS2013

Thermokarst and thaw-related landscape dynamics -- an annotated bibliography with an emphasis on potential effects on habitat and wildlife

Permafrost has warmed throughout much of the Northern Hemisphere since the 1980s, with colder permafrost sites warming more rapidly (Romanovsky and others, 2010; Smith and others, 2010). Warming of the near-surface permafrost may lead to widespread terrain instability in ice-rich permafrost in the Arctic and the Subarctic, and may result in thermokarst development and other thaw-related landscape features (Jorgenson and others, 2006; Gooseff and others, 2009). Thermokarst and other thaw-related landscape features result from varying modes and scales of permafrost thaw, subsidence, and removal of material. An increase in active-layer depth, water accumulation on the soil surface, permafrost degradation and associated retreat of the permafrost table, and changes to lake shores and coastal bluffs act and interact to create thermokarst and other thaw-related landscape features (Shur and Osterkamp, 2007). There is increasing interest in the spatial and temporal dynamics of thermokarst and other thaw-related features from diverse disciplines including landscape ecology, hydrology, engineering, and biogeochemistry. Therefore, there is a need to synthesize and disseminate knowledge on the current state of near-surface permafrost terrain. The term "thermokarst" originated in the Russian literature, and its scientific use has varied substantially over time (Shur and Osterkamp, 2007). The modern definition of thermokarst refers to the process by which characteristic landforms result from the thawing of ice-rich permafrost or the melting of massive ice (van Everdingen, 1998), or, more specifically, the thawing of ice-rich permafrost and (or) melting of massive ice that result in consolidation and deformation of the soil surface and formation of specific forms of relief (Shur, 1988). Jorgenson (2013) identifies 23 distinct thermokarst and other thaw-related features in the Arctic, Subarctic, and Antarctic based primarily on differences in terrain condition, ground-ice volume, and heat and mass transfer processes. Typical Arctic thermokarst landforms include thermokarst lakes, collapsed pingos, sinkholes, and pits. Thermokarst is differentiated from thermal erosion, which refers to the erosion of the land surface by thermal and mechanical processes (Mackay, 1970; van Everdingen, 1998). Typical thermal erosional features include thermo-erosional gullies. Thermal abrasion is further differentiated from thermokarst and thermal erosion by association with the reworking of ocean, river, and lake bluffs (Are, 1988). Typical thermo-abrasion features include erosional niches at the base of bluffs. Thermal denudation is another distinct term that refers to the effect of incoming solar energy on the thaw of frozen slopes and permafrost bodies that subsequently become transported downhill by gravity (Shur and Osterkamp, 2007). Active layer detachment slides and thaw slumps are typical thermal denudation features. Shur and Osterkamp (2007) noted that these various transport processes may occur together with thermokarst or in instances that would not be considered thermokarst. This compilation of references regarding thermokarst and other thaw-related features is focused on the Arctic and the Subarctic. References were drawn from North America as well as Siberia. English-language literature mostly was targeted, with 167 references annotated in version 1.0; however, an additional 28 Russian-language references were taken from Shur and Osterkamp (2007) and are provided at the end of this document. This compilation may be missing key references and inevitably will become outdated soon after publication. We hope that this document, version 1.0, will serve as the foundation for a comprehensive compilation of thermokarst and permafrost-terrain stability references, and that it will be updated continually over the coming years.

Open-File Report↗
USGS1999

Magmatic interactions as recorded in plagioclase phenocrysts of Chaos Crags, Lassen Volcanic Center, California

The silicic lava domes of Chaos Crags in Lassen Volcanic National Park contain a suite of variably quenched, hybrid basaltic andesite magmatic inclusions. The inclusions represent thorough mixing between rhyodacite and basalt recharge liquids accompanied by some mechanical disaggregation of the inclusions resulting in crystals mixing into the rhyodacite host preserved by quenching on dome emplacement. 87Sr/86Sr ratios (~0.7037-0.7038) of the inclusions are distinctly lower than those of the host rhyodacite (~0.704-0.7041), which are used to fingerprint the origin of mineral components and to monitor the mixing and mingling process. Chemical, isotopic, and textural characteristics indicate that the inclusions are hybrid magmas formed from the mixing and undercooling of recharge basaltic magma with rhyodacitic magma. All the host magma phenocrysts (biotite, plagioclase, hornblende and quartz crystals) also occur in the inclusions, where they are rimmed by reaction products. Compositional and strontium isotopic data from cores of unresorbed plagioclase crystals in the host rhyodacite, partially resorbed plagioclase crystals enclosed within basaltic andesite inclusions, and partially resorbed plagioclase crystals in the rhyodacitic host are all similar. Rim 87Sr/86Sr ratios of the partially resorbed plagioclase crystals in both inclusions and host are lower and close to those of the whole-rock hybrid basaltic andesite values. This observation indicates that some crystals originally crystallized in the silicic host, were partially resorbed and subsequently overgrown in the hybrid basaltic andesite magma, and then some of these partially resorbed plagioclase crystals were recycled back into the host rhyodacite. Textural evidence, in the form of sieve zones and major dissolution boundaries of the resorbed plagioclase crystals, indicates immersion of crystals into a hotter, more calcic magma. The occurrence of partially resorbed plagioclase together with plagioclase microlites and olivine crystals reflects disaggregation of inclusions and mingling of this material into the silicic host. These processes are commonplace in some orogenic magma systems and may be elucidated by isotopic microsampling and analysis of the plagioclases crystallizing from them.

Journal of Petrology↗
USGS2020

The future of landslides’ past—A framework for assessing consecutive landsliding systems

Landslides often happen where they have already occurred in the past. The potential of landslides to reduce or enhance conditions for further landsliding has long been recognized and has often been reported, but the mechanisms and spatial and temporal scales of these processes have previously received little specific attention. Despite a preponderance of qualitative and anecdotal evidence, there has been limited analysis. As a result, there is little consensus on the meaning of terms such as landslide repetition, recurrence, and reactivation. This source of confusion is evident when such terms are also used to describe systems where landsliding is prevalent but unrelated to landslide history. Recent findings, partly based on a rare multi-temporal landslide inventory for an area in Italy, show that the impacts of earlier landslides affect a substantial fraction of landslides, that landslides following earlier landslides differ from those that do not, and that accounting for the effect of previous landslides can improve susceptibility assessments. These findings await confirmation in other landslide prone landscapes but show that consecutive landsliding deserves more attention, which requires consistent terminology. No such terminology is presently available, and we therefore propose it in this manuscript. We use the term 'uncorrelated landsliding' to describe situations where landslides are common, but where a correlation with environmental variables such as terrain steepness is not implied. We propose 'correlated landsliding' to describe situations where landslides are common and correlations with environmental variables exist, and 'path-dependent landsliding' to describe situations where causal relations exist between consecutive landslides, for instance when landslides occur at the scarp of previous landslides. These are situations where past landslides impact future landslides. Within the path-dependent category, we distinguish three subcategories based on the spatial distance between earlier and later landslides: 'reactivation' or 'continuation' if essentially the same material recommences or continues to slide, 'local activation' if an earlier slide causes changes in a local hillslope that cause a later slide, and 'remote activation' if an earlier slide causes changes elsewhere in the landscape that cause a later landslide. We use this proposed set of terms to outline some prominent knowledge gaps and potential research questions.

Landslides↗
USGS1969

Theoretical basis of the borehole deepening method of absolute stress measurement

Knowledge of the initial state of stress in rocks provides a key to the solution of many problems in rock mechanics. The initial state of stress is part of the basic data required for rational design of structures in rock, since its redistribution when engineering activities are conducted is a primary load on the rock portion of the engineering system. Knowledge of initial and subsequent changes in the state of stress is also relevant in the study of active faults and crustal strain. The purposes of stress measurements are not generally well served by methods which disclose only one of the stress components at a point. Recently, interest has centered on overcoring methods which though expensive and difficult have the important advantage of yielding data on three or more stress components. In a previous paper, the authors introduced a new method--termed borehole deepening--based on measurement of the deformations that occur close to the bottom of a borehole when it is deepened by further drilling without overcoring . The proposed method is at a disadvantage when compared with overcoring procedures in that the quantities to be measured are somewhat smaller and the measuring environment is more hostile. However, the borehole deepening method presents three distinct advantages in comparison with overcoring procedures: (1) Using the same borehole, both the initial and the subsequent changes in the state of stress can be obtained by borehole deepening. Stress changes with time are very significant for stability monitoring as well as in predicting earthquake activity in regions close to known active faults and volcanoes. (2) The necessity of completely unloading a portion of the rock mass where deformation measurements are being carried out in the overcoring methods is ill-suited to nonlinearly elastic materials such as rocks. The borehole deepening method, on the other hand, is based on a change of stress from one level to another, rather than complete strain relief and is therefore less affected by nonlinear behavior. (3) Numerous stress measurements can be carried out economically in a single borehole. Thus, the regional stress distribution can be more readily obtained. Such information is considerably more significant than a single stress measurement at a point; considering the variability of rock masses and the magnitudes and direction of the stresses acting on them from one region to another and within the regions themselves, the reliability of a single measurement when extrapolated for the entire region is not very reasonable. This advantage of more numerous measurements makes it possible to predetermine the initial state of stress with confidence before actual access and construction. It also makes it possible to consider studying regional tectonic systems. Integrated regional measurements of in-situ state of stress would provide the necessary information for plotting the variation of crustal stresses; this would be of great interest in evaluating the several theories of orogenesis and in delineating tectonically active regions. This chapter is concerned with the theoretical basis for the borehole deepening method--the "software" for converting deformation measurements into stress values.

Conference Paper↗
USGS2009

Sediment characterization and dynamics in Lake Pontchartrain, Louisiana

Lake Pontchartrain in southeastern Louisiana is the largest of several shallow estuaries that together cover over 15,000 km 2 . Wetlands, forests, and large urban areas surround the lake. Primary transport mechanisms of sediments to Lake Pontchartrain include urban runoff, major diversions of the Mississippi River, discharge from streams along the north and west shores, and tidal circulation. Sediments deposited in Lake Pontchartrain are subjected to resuspension and mixing by natural and human activities. Bioturbation and water turbulence throughout the lake are the major mixing agents, and mechanical shell dredging has reworked much of the lake bottom over the last century. Sediment characterization through direct sampling and geophysical surveys indicates that these processes continually rework the top meter of sediment. The lake receives discharge from roadways and industrial and agricultural sources. Contaminants from these sources accumulate in the lake sediments and are an important contributor to the degradation of the estuary. Decline in populations of various benthic organisms, such as shrimp and clams, has been documented in the lake. To characterize the health of this important estuary, the U.S. Geological Survey (USGS) conducted a comprehensive evaluation of the geology, geomorphology, coastal processes, and environmental condition of the Pontchartrain Basin from 1994 to 1997. This report presents an assessment of sediment distribution and quality using a multidisciplinary approach to characterize the influence of various physical and chemical parameters: nearsurface stratigraphy, major trace metal concentrations (Cu, Pb, Zn, and Ni), and short-lived radionuclides ( 210 Pb, 7 Be, and 137 Cs). The results are compared with water-circulation patterns to determine high-resolution sedimentation patterns in the lake. The data show a significant increase in trace metals in the top 1 m of lake sediments. Above this horizon, pollen analysis indicates a correlation with land clearing in the area, a proxy for increasing human development of the surrounding landscape and an increase in surface run-off. The data also show that the top meter of sediment undergoes frequent resuspension during high-energy circulation events and via circulation gyres in the lake. This regular turnover does not allow stratification of recently deposited sediments, restricting the sequestration of contaminated material that enters the lake.

Louisiana↗
USGS1988

Retardations in fault creep rates before local moderate earthquakes along the San Andreas fault system, central California

Records of shallow aseismic slip (fault creep) obtained along parts of the San Andreas and Calaveras faults in central California demonstrate that significant changes in creep rates often have been associated with local moderate earthquakes. An immediate postearthquake increase followed by gradual, long-term decay back to a previous background rate is generally the most obvious earthquake effect on fault creep. This phenomenon, identified as aseismic afterslip, usually is characterized by above-average creep rates for several months to a few years. In several cases, minor step-like movements, called coseismic slip events, have occurred at or near the times of mainshocks. One extreme case of coseismic slip, recorded at Cienega Winery on the San Andreas fault 17.5 km southeast of San Juan Bautista, consisted of 11 mm of sudden displacement coincident with earthquakes of ML=5.3 and ML=5.2 that occurred 2.5 minutes apart on 9 April 1961. At least one of these shocks originated on the main fault beneath the winery. Creep activity subsequently stopped at the winery for 19 months, then gradually returned to a nearly steady rate slightly below the previous long-term average. The phenomena mentioned above can be explained in terms of simple models consisting of relatively weak material along shallow reaches of the fault responding to changes in load imposed by sudden slip within the underlying seismogenic zone. In addition to coseismic slip and afterslip phenomena, however, pre-earthquake retardations in creep rates also have been observed. Onsets of significant, persistent decreases in creep rates have occurred at several sites 12 months or more before the times of moderate earthquakes. A 44-month retardation before the 1979 ML=5.9 Coyote Lake earthquake on the Calaveras fault was recorded at the Shore Road creepmeter site 10 km northwest of Hollister. Creep retardation on the San Andreas fault near San Juan Bautista has been evident in records from one creepmeter site for the past 5 years. Retardations with durations of 21 and 19 months also occurred at Shore Road before the 1974 and 1984 earthquakes of ML=5.2 and ML=6.2, respectively. Although creep retardation remains poorly understood, several possible explanations have been discussed previously. (1) Certain onsets of apparent creep retardation may be explained as abrupt terminations of afterslip generated from previous moderate-mainshock sequences. (2) Retardations may be related to significant decreases in the rate of seismic and/or aseismic slip occurring within or beneath the underlying seismogenic zone. Such decreases may be caused by changes in local conditions related to growth of asperities, strain hardening, or dilatancy, or perhaps by passage of stress-waves or other fluctuations in driving stresses. (3) Finally, creep rates may be lowered (or increased) by stresses imposed on the fault by seismic or aseismic slip on neighboring faults. In addition to causing creep-rate increases or retardations, such fault interactions occasionally may trigger earthquakes. Regardless of the actual mechanisms involved and the current lack of understanding of creep retardation, it appears that shallow fault creep is sensitive to local and regional effects that promote or accompany intermediate-term preparation stages leading to moderate earthquakes. A strategy for more complete monitoring of fault creep, wherever it is known to occur, therefore should be assigned a higher priority in our continuing efforts to test various hypotheses concerning the mechanical relations between seismic and aseismic slip. ?? 1988 Birkha??user Verlag.

Pure and Applied Geophysics PAGEOPH↗
USGS2018

Volcanic ash activates the NLRP3 inflammasome in murine and human macrophages

Volcanic ash is a heterogeneous mineral dust that is typically composed of a mixture of amorphous (glass) and crystalline (mineral) fragments. It commonly contains an abundance of the crystalline silica (SiO 2 ) polymorph cristobalite. Inhalation of crystalline silica can induce inflammation by stimulating the NLRP3 inflammasome, a cytosolic receptor complex that plays a critical role in driving inflammatory immune responses. Ingested material results in the assembly of NLRP3, ASC, and caspase-1 with subsequent secretion of the interleukin-1 family cytokine IL-1β. Previous toxicology work suggests that cristobalite-bearing volcanic ash is minimally reactive, calling into question the reactivity of volcanically derived crystalline silica, in general. In this study, we target the NLRP3 inflammasome as a crystalline silica responsive element to clarify volcanic cristobalite reactivity. We expose immortalized bone marrow-derived macrophages of genetically engineered mice and primary human peripheral blood mononuclear cells (PBMCs) to ash from the Soufrière Hills volcano as well as representative, pure-phase samples of its primary componentry (volcanic glass, feldspar, cristobalite) and measure NLRP3 inflammasome activation. We demonstrate that respirable Soufrière Hills volcanic ash induces the activation of caspase-1 with subsequent release of mature IL-1β in a NLRP3 inflammasome-dependent manner. Macrophages deficient in NLRP3 inflammasome components are incapable of secreting IL-1β in response to volcanic ash ingestion. Cellular uptake induces lysosomal destabilization involving cysteine proteases. Furthermore, the response involves activation of mitochondrial stress pathways leading to the generation of reactive oxygen species. Considering ash componentry, cristobalite is the most reactive pure-phase with other components inducing only low-level IL-1β secretion. Inflammasome activation mediated by inhaled ash and its potential relevance in chronic pulmonary disease was further evidenced in PBMC using the NLRP3 small-molecule inhibitor CP-456,773 (CRID3, MCC950). Our data indicate the functional activation of the NLRP3 inflammasome by volcanic ash in murine and human macrophages in vitro . Cristobalite is identified as the apparent driver, thereby contesting previous assertions that chemical and structural imperfections may be sufficient to abrogate the reactivity of volcanically derived cristobalite. This is a novel mechanism for the stimulation of a pro-inflammatory response by volcanic particulate and provides new insight regarding chronic exposure to environmentally occurring particles.

Frontiers in Immunology↗