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The evolution of thermal structure and water chemistry in Lake Nyos

We collected a time series of physical and chemical data to gain a better understanding of the dynamics of Lake Nyos. Measurements of water and gas chemistry, and temperature made during January, March, and May 1987 are compared to data taken in September 1986 just after the initial CO2 gas release. There is no pattern of change in overall heat content of the lake, although heat input to bottom waters (185-208 m) has occurred at a rate of 1600 mW m-2. This increase in heat content translates to a change from 23.38 to 24.12??C at 200 m and can be explained by geothermal heat flow and addition of thermal spring water. Concentrations of Ca2+, Mg2+, Na+, K+, Fe2+ and alkalinity have increased only in bottom waters. In situ lake processes such as sulfate and iron reduction are unable to account for the changes in alkalinity. Observed chemical changes are consistent with a scenario where slightly thermal soda water is being input to the bottom of the lake. Measurements of pCO2 at depth ranged from 18 to 28% of saturation and exhibited horizontal variability. Overall recharge of CO2 in bottom waters is negligible. Mainly because of increasing ion concentrations in bottom water, total stability of the water column increased 33% from 48,800 J m-2 in September 1986 to 64,700 J m-2 in May 1987. As long as CO2 concentrations remain the same, this level of stability is higher than could be disrupted by common limnologic or meteorologic processes. There is thermal and chemical evidence that a buildup of dissolved iron and CO2 in bottom waters must have preceded the August 1986 gas release. In addition, a survey of all crater lakes in Cameroon indicates that only Lakes Nyos and Monoun contain high concentrations of dissolved iron and CO2. Thus there is a low probability of any other Cameroonian lake releasing a substantial volume of CO2. ?? 1989.

Journal of Volcanology and Geothermal Research↗

The initial giant umbrella cloud of the May 18th, 1980, explosive eruption of Mount St. Helens

The initial eruption column of May 18th, 1980 reached nearly 30 km altitude and released 1017 joules of thermal energy into the atmosphere in only a few minutes. Ascent of the cloud resulted in forced intrusion of a giant umbrella-shaped cloud between altitudes of 10 and 20 km at radial horizontal velocities initially in excess of 50 m/s. The mushroom cloud expanded 15 km upwind, forming a stagnation point where the radial expansion velocity and wind velocity were equal. The cloud was initiated when the pyroclastic blast flow became buoyant. The flow reduced its density as it moved away from the volcano by decompression, by sedimentation, and by mixing with and heating the surrounding air. Observations indicate that much of the flow, covering an area of 600 km2, became buoyant within 1.5 minutes and abruptly ascended to form the giant cloud. Calculations are presented for the amount of air that must have been entrained into the flow to make it buoyant. Assuming an initial temperature of 450??C and a magmatic origin for the explosion, these calculations indicate that the flow became buoyant when its temperature was approximately 150??C and the flow consisted of a mixture of 3.25 ?? 1011 kg of pyroclasts and 5.0 ?? 1011 kg of air. If sedimentation is considered, these figures reduce to 1.1 ?? 1011 kg of pyroclasts and 1.0 ?? 1011 kg of air. ?? 1986.

Journal of Volcanology and Geothermal Research↗

Volume predictability of historical eruptions at Kilauea and Mauna Loa volcanoes

Cumulative volumes of eruptions at the Kilauea and Mauna Loa volcanoes in Hawaii appear to fit a volume-predictable model (i.e., the volume of an eruption episode is approximately proportional to the time since the previous episode) for many larger episodes during long periods of time (decades). This observation suggests that the magmatic pressure of each volcano tends to drop to a common level at the end of these episodes during each such period. ?? 1989.

Journal of Volcanology and Geothermal Research↗

Fumarole emissions at Mount St. Helens volcano, June 1980 to October 1981: Degassing of a magma-hydrothermal system

This study is an investigation of the chemical changes in the Mount St. Helens fumarole gases up to October 1981, the sources of the fumarole gases, and the stability of gas species in the shallow magma system. These problems are investigated by calculations of element compositions, thermodynamic equilibria, and magmatic volatile-hydrothermal steam mixing models. The fumarole gases are treated as mixtures of magmatic volatiles and hydrothermal steam formed by magma degassing and boiling of local waters in a dryout zone near conduit and dome magma. The magmatic volatile fraction is significant in fumaroles with temperatures in excess of the magma cracking-temperature (??? 700??C) - i.e., the temperature below which cracking is induced by thermal stresses during cooling and solidification. Linear composition changes of the fumarole gases over time appear to be the result of a steady decline in the magmatic volatile mixing fraction, which may be due to the tapping of progressively volatile-depleted magma. The maximum proportion of hydrothermal steam in the fumaroles rose from about 25-35% in September 1980 to around 50-70% by October 1981. Fractional degassing of magmatic CO2 and sulfur also contributed to the chemical changes in the fumarole gases. The steady chemical changes indicate that replenishment of the magma system with undegassed magma was not significant between September 1980 and September 1981. Extrapolations of chemical trends suggest that fumarole gases emitted at the time of formation of the first dome in mid-June 1980 were more enriched in a magmatic volatile fraction and contained a minimum of 9% CO2. Calculations show H2S is the predominant sulfur species in Mount St. Helens magma below depths of 200 m. Rapid release of gases from magma below this depth is a plausible mechanism for producing the high H2S/SO2 observed in Mount St. Helens plumes during explosive eruptions. This study suggests that dacite-andesite volcanos may emit gases richer in CO2 during the earlier episodes of an eruptive cycle and burden the atmosphere with much more H2S than SO2 during explosive eruptions. ?? 1986.

Journal of Volcanology and Geothermal Research↗

Anomalous chloride flux discharges from Yellowstone National Park

The chloride concentration of some thermal springs in and adjacent to Yellowstone National Park is constant through time although their discharge varies seasonally. As a result the chloride flux from these springs increases during periods of increased discharge. We believe that this is caused by changes in the height of the local groundwater table, which affects the discharge of the springs but not their chloride concentration. The discharge from Mammoth Hot Springs varies seasonally, but its chloride concentration remains constant. We take this as evidence that this major thermal feature is derived from orifices that are tapping the local water table close to its surface. Three of the four major rivers (Yellowstone, Snake and Falls) exiting the Park also show an increased chloride flux during the spring runoff that cannot be explained solely by the contribution of snowmelt, nor by release of hot-spring-derived chloride stored in the soil during the winter and released in the spring. The increased chloride flux in these rivers is attributed to their draining shallow hot springs similar to those mentioned above. In contrast to the Yellowstone, Snake and Falls Rivers, the Firehole and Gibbon Rivers, which unite to form the Madison River and which collectively drain several major geyser basins, display a poor correlation between chloride flux and discharge. The cause, we believe, is that a large part of the thermal water input to these two rivers originated at great depths where the seasonal variation in the height of the water table had a negligible effect on hot spring discharge. Monitoring of seasonal discharge and chloride concentration of thermal features yields information on the depths at which these thermal features tap the local water table. ?? 1990.

Journal of Volcanology and Geothermal Research↗

Origin and age of the Lake Nyos maar, Cameroon

Lake Nyos occupies a young maar crater in the Precambrian granitic terrane of northwest Cameroon. The lake is partly surrounded by poorly consolidated, ultramafic nodule-bearing pyroclastic surge deposits that were explosively ejected from the Nyos crater at the time of its formation. Radiocarbon dates show that the maar probably formed about 400 years ago. Field evidence suggests that carbon dioxide could have been the principal volatile involved in the formation of the Nyos maar, and that the role of water may have been minor. The formation of the Nyos maar was preceded by a brief period of effusive basaltic volcanism, but the maar itself may have largely formed by cold, 'dry' explosive processes. Carbon dioxide may still be trapped interstitially in a diatreme inferred to underlie Lake Nyos; its gradual release into the waters of Lake Nyos may have set the stage for the tragic gas-release event of August 21, 1986. Only young maar lakes such as Nyos may pose a danger of future lethal gas releases. ?? 1989.

Journal of Volcanology and Geothermal Research↗

Seismicity following the 1985 eruption of Nevado del Ruiz, Colombia

Over 200 of the best-recorded earthquakes occurring near Nevado del Ruiz, Colombia, between December 1985 and May 1986 are examined for spatial patterns, information on local stress orientations, and evidence for seismogenic structures that may be related to magma-transport processes. These earthquakes occurred following the devastating eruption of November 13, 1985. Earthquake activity that is probably related to the volcanic system occurs over a large area, of the order of 50 km2. A pattern of earthquakes beneath the southern half of Ruiz may be the expression of a conduit system, but evidence is inconclusive due to low spatial resolution of most hypocenters. Epicenter and first-motion plots suggest most earthquakes occur on small faults of varying orientation. Most seismicity during this time period was unrelated to mapped faults, including some with Holocene offsets, except for the Villamaria Fault near Ruiz's northeast sector. Composite focal mechanisms show a variation of nearly 90?? in the strike of T-axes and indicate Ruiz is in a zone of local extension. ?? 1990.

Journal of Volcanology and Geothermal Research↗

Perturbation and melting of snow and ice by the 13 November 1985 eruption of Nevado del Ruiz, Colombia, and consequent mobilization, flow and deposition of lahars

A complex sequence of pyroclastic flows and surges erupted by Nevado del Ruiz volcano on 13 November 1985 interacted with snow and ice on the summit ice cap to trigger catastrophic lahars (volcanic debris flows), which killed more than 23,000 people living at or beyond the base of the volcano. The rapid transfer of heat from the hot eruptive products to about 10 km2 of the snowpack, combined with seismic shaking, produced large volumes of meltwater that flowed downslope, liquefied some of the new volcanic deposits, and generated avalanches of saturated snow, ice and rock debris within minutes of the 21:08 (local time) eruption. About 2 ?? 107 m3 of water was discharged into the upper reaches of the Molinos, Nereidas, Guali, Azufrado and Lagunillas valleys, where rapid entrainment of valley-fill sediment transformed the dilute flows and avalanches to debris flows. Computed mean velocities of the lahars at peak flow ranged up to 17 m s-1. Flows were rapid in the steep, narrow upper canyons and slowed with distance away from the volcano as flow depth and channel slope diminished. Computed peak discharges ranged up to 48,000 m3 s-1 and were greatest in reaches 10 to 20 km downstream from the summit. A total of about 9 ?? 107 m3 of lahar slurry was transported to depositional areas up to 104 km from the source area. Initial volumes of individual lahars increased up to 4 times with distance away from the summit. The sedimentology and stratigraphy of the lahar deposits provide compelling evidence that: (1) multiple initial meltwater pulses tended to coalesce into single flood waves; (2) lahars remained fully developed debris flows until they reached confluences with major rivers; and (3) debris-flow slurry composition and rheology varied to produce gradationally density-stratified flows. Key lessons and reminders from the 1985 Nevado del Ruiz volcanic eruption are: (1) catastrophic lahars can be generated on ice- and snow-capped volcanoes by relatively small eruptions; (2) the surface area of snow on an ice cap can be more critical than total ice volume when considering lahar potential; (3) placement of hot rock debris on snow is insufficient to generate lahars; the two materials must be mechanically mixed together for sufficiently rapid head transfer; (4) lahars can increase their volumes significantly by entrainment of water and eroded sediment; and (5) valley-confined lahars can maintain relatively high velocities and can have catastrophic impacts as far as 100 km downstream. ?? 1990.

Journal of Volcanology and Geothermal Research↗

Deformation monitoring at Nevado del Ruiz, Colombia - October 1985 - March 1988

Deformation studies began at Nevado del Ruiz 23 days before the devastating 13 November 1985 eruption, at least 12 months after precursory seismicity and fumarolic activity began. The late start in geodetic monitoring, limited number of stations in the pre-eruption network, and inconsistent patterns in the observed deformation limit conclusions about intrusive activity in the months and weeks prior to the eruption. However, the data require that the magma source of the devastating eruption was either deeper than 7 km or, if shallow, recovered the same volume and position within one week of the eruption. Geodetic monitoring resumed 1 week after the eruption and, by April 1986, included 11 tilt-leveling stations, 38 EDM lines, and 7 short leveling lines - a network capable of detecting emplacement or movement of magma volumes as small as 3 MCM (3 ?? 106 m3) to a depth of 2-3 km (using a point-source model), 10 MCM to 7 km, 50 MCM to 10 km, and 200 MCM to 15 km beneath Ruiz. In addition, 4 telemetered tiltmeters provided the capability of detecting, in real time, the fairly rapid ascent of much smaller magma bodies. Stations established to detect instability of the summit ice cap after the eruption were discontinued in early 1986. The data collected from the geodetic networks have higher than normal variance but demonstrate that little or no cumulative deformation of Ruiz occurred from October 1985 through March 1988. Thus, little, if any, magma intruded above 5 km beneath the summit during or after the 13 November 1985 eruption. This lack of significant intrusive activity agrees with the surprisingly low seismic energy release under Ruiz and makes direct degassing of a large batholith an improbable explanation of the large sulfur flux to date at Ruiz. Part of the variance in the geodetic data results from real but noncumulative deformation that may in part be pressure-buffered by a fairly large geothermal water-gas mixture for which abundant physical evidence exists. Part of the noncumulative deformation, some of the fairly dispersed and low-level seismicity under Ruiz, and some phreatic events appear to correlate with seasonal precipitation patterns. Hence rain/snow-loading and groundwater interaction may cause deformation events and possibly help trigger some phreatic explosions and seismic events at Ruiz and, as search of the literature reveals, at other volcanoes in metastable states. ?? 1990.

Journal of Volcanology and Geothermal Research↗

Oxygen and carbon isotope ratios of hydrothermal minerals from Yellowstone drill cores

Oxygen and carbon isotope ratios were measured for hydrothermal minerals (silica, clay and calcite) from fractures and vugs in altered rhyolite, located between 28 and 129 m below surface (in situ temperatures ranging from 81 to 199??C) in Yellowstone drill holes. The purpose of this study was to investigate the mechanism of formation of these minerals. The ??18O values of the thirty-two analyzed silica samples (quartz, chalcedony, ??-cristobalite, and ??-cristobalite) range from -7.5 to +2.8???. About one third of the silica 7samples have ??18O values that are consistent with isotopic equilibrium with present thermal waters; most of the other silica samples appear to have precipitated from water enriched in 18O (up to 4.7???) relative to present thermal water, assuming precipitation at present in situ temperatures. Available data on fluid-inclusion homogenization temperatures in hydrothermal quartz indicate that silica precipitation occurred mostly at temperatures above those measured during drilling and imply that 15O enrichments in water during silica precipitation were generally larger than those estimated from present conditions. Similarly, clay minerals (celadonite and smectite) have ??18O values higher (by 3.5 to 7.9???) than equilibrium values under present conditions. In contrast, all eight analyzed calcite samples are close to isotopic equilibrium with present thermal waters. The frequent incidence of apparent 18O enrichment in thermal water from which the hydrothermal minerals precipitated may indicate that a higher proportion of strongly 18O-enriched deep hydrothermal fluid once circulated through shallow portions of the Yellowstone system, or that a recurring transient 18O-enrichment effect occurs at shallow depths and is caused either by sudden decompressional boiling or by isotopic exchange at low water/rock ratios in new fractures. The mineralogy and apparent 18O enrichments of hydrothermal fracture-filling minerals are consistent with deposition during transient boiling or rock-water exchange (fracturing) events. ?? 1990.

Journal of Volcanology and Geothermal Research↗

Chemical equilibrium and mass balance relationships associated with the Long Valley hydrothermal system, California, U.S.A.

Recent drilling and sampling of hydrothermal fluids from Long Valley permit an accurate characterization of chemical concentrations and equilibrium conditions in the hydrothermal reservoir. Hydrothermal fluids are thermodynamically saturated with secondary quartz, calcite, and pyrite but are in disequilibrium with respect to aqueous sulfide-sulfate speciation. Hydrothermal fluids are enriched in 18O by approximately 1??? relative to recharge waters. 18O and Cl concentrations in well cuttings and core from high-temperature zones of the reservoir are extensively depleted relative to fresh rhyolitic tuff compositions. Approximately 80% of the Li and 50% of the B are retained in the altered reservoir rock. Cl mass balance and open-system 18O fractionation models produce similar water-rock ratios of between 1.0 and 2.5 kg kg-1. These water-rock ratios coupled with estimates of reservoir porosity and density produce a minimum fluid residence time of 1.3 ka. The low fluid Cl concentrations in Long Valley correlate with corresponding low rock concentrations. Mass balance calculations indicate that leaching of these reservoir rocks accounts for Cl losses during hydrothermal activity over the last 40 ka. ?? 1991.

Journal of Volcanology and Geothermal Research↗

14C age of the "Museum Breccia" (Campi Flegrei) and its relevance for the origin of the Campanian Ignimbrite

Field stratigraphic investigations and AMS 14C dating of carbon particles in paleosols has resulted in a framework of the sequence and age of the pyroclastic products in the Campi Flegrei area of Southern Italy. The Museum Breccia cannot be the early phase of the Campanian Ignimbrite, as was previously believed, but is from a smaller and later eruption with an age of approximately 17,900 y B.P. This date also precludes its correlation with the Neapolitan Yellow Tuff (12,000 y B.P.). ?? 1991.

Journal of Volcanology and Geothermal Research↗

History of earthquakes and vertical ground movement in Campi Flegrei caldera, Southern Italy: comparison of precursory events to the A.D. 1538 eruption of Monte Nuovo and of activity since 1968

The record of felt earthquakes around Naples Bay in southern Italy is probably complete since the mid-15th century. According to this record, intense earthquake swarms originating beneath Campi Flegrei, an explosive caldera located along the north coast of Naples Bay, have occurred only twice: (1) before the only historical eruption in Campi Flegrei in 1538; and (2) from mid-1983 to December 1984. Earthquake activity during the earlier period, which began at least a few years, and possibly as many as 30 years, before the 1538 eruption, damaged many buildings in the city of Pozzuoli, located near the center of Campi Flegrei. Minor seismic activity, which consisted of only a few felt earthquakes, occurred from 1970 to 1971. The second period of intense earthquake swarms lasted from mid-1983 to 1984, again damaging many buildings in Pozzuoli. Two periods of uplift along the shoreline within Campi Flegrei have also been noted since the mid-15th century: (1) during the few decades before the 1538 eruption; and (2) as two distinct episodes since 1968. Uplift of a few meters probably occurred a few decades before the 1538 eruption; uplift of as much as 3.0 m has occurred in Pozzuoli since 1968. These similarities strongly suggest that, for the first time in 440 years, the same process that caused intense local earthquake swarms and uplift in the early 1500's and led to an eruption in 1538, has again occurred beneath Campi Flegrei. Though no major seismicity or uplift has occurred since December 1984, because of the large amount of extensional strain accumulated during the past two decades, if a third episode of seismicity and rapid uplift occurs, it may lead to an eruption within several months after the resumption of activity. ?? 1991.

Journal of Volcanology and Geothermal Research↗

Degassing and differentiation in subglacial volcanoes, Iceland

Within the neovolcanic zones of Iceland many volcanoes grew upward through icecaps that have subsequently melted. These steep-walled and flat-topped basaltic subglacial volcanoes, called tuyas, are composed of a lower sequence of subaqueously erupted, pillowed lavas overlain by breccias and hyaloclastites produced by phreatomagmatic explosions in shallow water, capped by a subaerially erupted lava plateau. Glass and whole-rock analyses of samples collected from six tuyas indicate systematic variations in major elements showing that the individual volcanoes are monogenetic, and that commonly the tholeiitic magmas differentiated and became more evolved through the course of the eruption that built the tuya. At Herdubreid, the most extensively studies tuya, the upward change in composition indicates that more than 50 wt.% of the first erupted lavas need crystallize over a range of 60??C to produce the last erupted lavas. The S content of glass commonly decreases upward in the tuyas from an average of about 0.08 wt.% at the base to < 0.02 wt.% in the subaerially erupted lava at the top, and is a measure of the depth of water (or ice) above the eruptive vent. The extensive subsurface crystallization that generates the more evolved, lower-temperature melts during the growth of the tuyas, apparently results from cooling and degassing of magma contained in shallow magma chambers and feeders beneath the volcanoes. Cooling may result from percolation of meltwater down cracks, vaporization, and cycling in a hydrothermal circulation. Degassing occurs when progressively lower pressure eruption (as the volcanic vent grows above the ice/water surface) lowers the volatile vapour pressure of subsurface melt, thus elevating the temperature of the liquidus and hastening liquid-crystal differentiation. ?? 1991.

Journal of Volcanology and Geothermal Research↗

Fossil and active fumaroles in the 1912 eruptive deposits, Valley of ten thousand smokes, Alaska

Fumaroles in the ash-flow sheet emplaced during the 1912 eruption of Novarupta were intensely active throughout the Valley of Ten Thousand Smokes (VTTS) when first studied in 1917. Fumarole temperatures recorded in 1919 were as hot as 645??C. Influx of surface waters into the hot ash-flow sheet provided the fluid flow to sustain the fumaroles but also enhanced cooling so that by the mid-1930's vigorous activity survived only in the vent region. Configuration and distribution of high-temperature fissure fumaroles tens of meters long, that are prevalent in the middle and upper VTTS, were controlled largely by sintering and degree of welding, which in turn controlled fracturing and permeability of the ash-flow tuff. One fracture type developed parallel to the enclosing valley walls during compaction of the ash-flow sheet. Another type extends across the VTTS nearly perpendicular to the flow direction. A third type of randomly oriented fractures developed as cooling contraction cracks during vapor-phase devitrification. In distal parts of the ash-flow sheet where the tuff is nonwelded, prominent fumaroles have irregular funnel-shaped morphologies. Fumarole distribution in the nonwelded part of the ash-flow sheet is concentrated above pre-emplacement river channels. The hottest, longest-lived fumaroles occurred in the upper VTTS near the 1912 vent where the ash-flow sheet is thicker, more indurated, and on average more mafic (richer in dacite and andesite) in contrast to the thinner, nonwelded rhyolitic tuff in the distal part of the sheet. Fumarolic activity was less intense in the distal part of the tuff because of lower emplacement temperatures, more diffuse fumarole conduits in the nonwelded tuff, and the thinness of the ash-flow sheet. Chemical leaching of ash-flow tuff by hot rising fluids took place adjacent to fumarolic conduits in deep parts of the fumaroles. Deposition of incrustation minerals, the components of which were carried upward by fumarolic gases, took place in the upper part of the ejecta, mostly in the fallout layers. The permeability difference between the ash-flow tuff and the overlying coarse dacite fallout was a critical factor in promoting the abrupt gradients in temperature, pressure, and fO2 that resulted in deposition of minerals from the fumarolic gases. The permeability difference between nonwelded ash-flow tuff and overlying fine-grained fall layers in the lower VTTS is less pronounced. The total mass of fumarolically deposited minerals appears large at first glance owing to the conspicuous coloration by Fe minerals; the mass is appreciably less than is apparent, however, because most incrustations are composed largely of ejecta coated or cemented by fine-grained fumarolic minerals. A large mass of unstable incrustation minerals, mainly chlorides and sulfates, reported during the 1917-1919 studies have since been removed by dissolution and weathering. In the vent region, argillic alteration that followed high-temperature degassing is localized along arcuate subsidence fractures in fallback ejecta. At widely scattered residual orifices, fumarolic gases presently are near-neutral steam, and temperatures are as hot as 90??C. ?? 1991.

Journal of Volcanology and Geothermal Research↗

Exploration drilling and reservoir model of the Platanares geothermal system, Honduras, Central America

Results of drilling, logging, and testing of three exploration core holes, combined with results of geologic and hydrogeochemical investigations, have been used to present a reservoir model of the Platanares geothermal system, Honduras. Geothermal fluids circulate at depths ??? 1.5 km in a region of active tectonism devoid of Quaternary volcanism. Large, artesian water entries of 160 to 165??C geothermal fluid in two core holes at 625 to 644 m and 460 to 635 m depth have maximum flow rates of roughly 355 and 560 l/min, respectively, which are equivalent to power outputs of about 3.1 and 5.1 MW(thermal). Dilute, alkali-chloride reservoir fluids (TDS ??? 1200 mg/kg) are produced from fractured Miocene andesite and Cretaceous to Eocene redbeds that are hydrothermally altered. Fracture permeabillity in producing horizons is locally greater than 1500 and bulk porosity is ??? 6%. A simple, fracture-dominated, volume-impedance model assuming turbulent flow indicates that the calculated reservoir storage capacity of each flowing hole is approximately 9.7 ?? 106 l/(kg cm-2), Tritium data indicate a mean residence time of 450 yr for water in the reservoir. Multiplying the natural fluid discharge rate by the mean residence time gives an estimated water volume of the Platanares system of ??? 0.78 km3. Downward continuation of a 139??C/km "conductive" gradient at a depth of 400 m in a third core hole implies that the depth to a 225??C source reservoir (predicted from chemical geothermometers) is at least 1.5 km. Uranium-thorium disequilibrium ages on calcite veins at the surface and in the core holes indicate that the present Platanares hydrothermal system has been active for the last 0.25 m.y. ?? 1991.

Journal of Volcanology and Geothermal Research↗

A geochemical model of the Platanares geothermal system, Honduras

Results of exploration drilling combined with results of geologic, geophysical, and hydrogeochemical investigations have been used to construct a geochemical model of the Platanares geothermal system, Honduras. Three coreholes were drilled, two of which produced fluids from fractured Miocene andesite and altered Cretaceous to Eocene conglomerate at 450 to 680 m depth. Large volume artesian flows of 160-165??C, predominantly bicarbonate water are chemically similar to, but slightly less saline than widespread boiling hot-spring waters. The chemistry of the produced fluid is dominated by equilibrium reactions in sedimentary rocks at greater depths and higher temperatures than those measured in the wells. Chemical, isotope, and gas geothermometers indicate a deep fluid temperature of 200-245??C and reflect a relatively short residence time in the fractures feeding the wells. Chloride-enthalpy relations as well as isotopic and chemical compositions of well discharges, thermal springs, and local cold waters support a conceptual model of ascending high-temperature (minimum 225??C) parent fluid that has cooled conductively to form the 160-165??C shallow (to 680 m) fluid encountered by the wells. The hot-spring waters are formed by boiling and steam loss from more or less conductively cooled parent fluid. The more dilute boiling spring waters (Cl = ???32 mg/kg) have cooled from > 225??C to about 160??C by conduction and from 160??C to 98??C by boiling. The most concentrated boiling spring waters (Cl = 37 mg/kg) have cooled from > 225??C to about 200??C by conduction and from 200??C to 98??C by boiling. Intermediate concentrations reflect mixed cooling paths. ?? 1991.

Journal of Volcanology and Geothermal Research↗

Thermal waters along the Konocti Bay fault zone, Lake County, California: a re-evaluation

The Konocti Bay fault zone (KBFZ), initially regarded by some as a promising target for liquid-dominated geothermal systems, has been a disappointment. At least five exploratory wells were drilled in the vicinity of the KBFZ, but none were successful. Although the Na-K-Ca and Na-Li geothermometers indicate that the thermal waters discharging in the vicinity of Howard and Seigler Springs may have equilibrated at temperatures greater than 200??C, the spring temperatures and fluid discharges are low. Most thermal waters along the KBFZ contain >100 mg/l Mg. High concentrations of dissolved magnesium are usually indicative of relatively cool hydrothermal systems. Dissolution of serpentine at shallow depths may contribute dissolved silica and magnesium to rising thermal waters. Most thermal waters are saturated with respect to amorphous silica at the measured spring temperature. Silica geothermometers and mixing models are useless because the dissolved silica concentration is not controlled by the solubility of either quartz or chalcedony. Cation geothermometry indicates the possibility of a high-temperature fluid (> 200??C) only in the vicinity of Howard and Seigler Springs. However, even if the fluid temperature is as high as that indicated by the geothermometers, the permeability may be low. Deuterium and oxygen-18 values of the thermal waters indicate that they recharged locally and became enriched in oxygen-18 by exchange with rock. Diluting meteoric water and the thermal water appear to have the same deuterium value. Lack of tritium in the diluted spring waters suggest that the diluting water is old. ?? 1992.

Journal of Volcanology and Geothermal Research↗