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Selected papers in the hydrologic sciences, 1986

Water-quality data from long-term (24 years), fixed- station monitoring at the Cape Fear River at Lock 1 near Kelly, N.C., and various measures of basin development are correlated. Subbasin population, number of acres of cropland in the subbasin, number of people employed in manufacturing, and tons of fertilizer applied in the basin are considered as measures of basinwide development activity. Linear correlations show statistically significant posi- tive relations between both population and manufacturing activity and most of the dissolved constituents considered. Negative correlations were found between the acres of harvested cropland and most of the water-quality measures. The amount of fertilizer sold in the subbasin was not statistically related to the water-quality measures considered in this report. The statistical analysis was limited to several commonly used measures of water quality including specific conductance, pH, dissolved solids, several major dissolved ions, and a few nutrients. The major dissolved ions included in the analysis were calcium, sodium, potassium, magnesium, chloride, sulfate, silica, bicarbonate, and fluoride. The nutrients included were dissolved nitrite plus nitrate nitrogen, dissolved ammonia nitrogen, total nitrogen, dissolved phosphates, and total phosphorus. For the chemicals evaluated, manufacturing and population sources are more closely associated with water quality in the Cape Fear River at Lock 1 than are agricultural variables.

Water Supply Paper↗

Effects of land use on water quality of the Fountain Creek alluvial aquifer, east-central Colorado

Water-quality data were collected from the Fountain Creek alluvial aquifer in 1988 and 1989 as part of the Toxic-Waste Ground-Water Contamination Program. These data indicate that dissolved solids, most major ions, fluoride, ammonium, boron, lithium, selenium, and strontium were more concentrated in the agricultural land-use area than in the upgradient urban land-use area. Nitrate and phosphate had significantly larger concentrations, and volatile organic compounds had significantly greater detection frequencies in the urban land-use area.

Water Supply Paper↗

Water supply of the Dakota sandstone in the Ellendale-Jamestown area, North Dakota, with reference to changes between 1923 and 1938

The Dakota sandstone underlies most of North Dakota and South Dakota and considerable parts of nearby States. In most of the area that it occupies it is covered with thick deposits of younger formations, chiefly shale, that confine the water in the sandstone under considerable pressure. Where the topography is favorable, as it is in the Ellendale-Jamestown area in southeastern North Dakota, wells that tap the sandstone flow at the surface. The first well in North Dakota to tap the Dakota sandstone was drilled in 1886 in the city of Ellendale. It was started as an 8- or 10-inch hole and was finished at a depth of 1,087 feet with a 3%-inch casing. It flowed 600 to 700 gallons a minute and had a pressure reported by different persons as being from 115 to 175 pounds to the square inch. The expense of drilling such large and deep wells discouraged their construction for a time. About 1900, however, the jetting method of drilling was introduced^ and during the following two decades hundreds of farm wells 1 inch to 2 inches in diameter were sunk to the sandstone. The decline in artesian head that resulted from the increased draft on the basin was not apparent at first, but by about 1915 the flow of most wells had decreased noticeably and the flow of a few wells in the western part of the area of flow stopped entirely. It is estimated that by 1923 the artesian head at the western boundary of the area of artesian flow had fallen about 330 feet from its original level. In 1916 steps were taken to initiate measures for conserving the artesian water in North Dakota, but it was not until 1921 that the State legislature passed a law providing for the reduction of flow of artesian wells to that which could be used beneficially. The enforcement of the law was placed in the office of the State geologist, and this difficult task was assigned to H. E. Simpson, who directed the work until his death in 1938. Between 1923 and 1928 each artesian well in the Ellendale-Jamestown area was visited and advice was given the owner regarding the flow to which his well should be reduced. Many of the wells were visited again between 1928 and 1935 in order to check on whether the flow had been sufficiently reduced. Through this program much artesian water was conserved and much valuable information was obtained on the discharge from the basin. It is estimated that between 1920 and 1923 the artesian head in the western part of the Ellendale-Jamestown area declined at an annual rate of about 4 feet, whereas in 1938 the rate of decline was only about 0.5 foot a year. Between 1915 and 1923 the part of the area of artesian flow in the Edgeley quadrangle was reduced an average of 16.5 square miles a year as a result of the eastward movement of the western boundary of the area. Between 1923 and 1938, however, the average rate of shrinkage of this part of the area of artesian flow was only about 4.5 square miles a year. The perennial recharge to each row of townships in the area of artesian flow has been estimated to be about 500 gallons a minute. In 1923 the flow from wells in T. 129 N., Rs. 50 to 65 W., was about 1,000 gallons a minute, or twice the estimated recharge. In 1938 the flow from wells in this row of townships was about 520 gallons a minute, or only slightly more than the estimated recharge. Thus it appears that a balance is being approached between the withdrawal of water from the basin and the perennial recharge to it. It is believed that the water withdrawn from the basin in excess of the perennial recharge has been obtained from storage by the compression of .the sandstone and associated beds of shale due to the increased load placed upon them by the decline in artesian pressure. Calculations made on this theory indicate that the coefficient of storage is about 0.001 that is, about 0.001 cubic foot of water is released from each column of sandstone and shale 1 foot square for each foot of decline in artesian head. Additional computations show that the effect of the large decline in artesian pressure in southeastern North Dakota probably has caused only a few feet of lowering of artesian head at distances of more than 100 miles west of the area of artesian flow. The quality of the artesian water is very poor and much of it is unfit for human consumption. Of the 33 analyses included in this report, all show total dissolved solids of more than 2,200 parts per million. Much of the water is salty, and all contains sufficient fluoride to cause mottling of the enamel of the teeth. The temperature of the water from flowing wells ranges from 47° to 69° F.

North Dakota↗

Oxidation of ammonia and methane in an alkaline, saline lake

The oxidation of ammonia (NH 3 ) and methane (CH 4 ) was investigated in an alkaline saline lake, Mono Lake, California (U.S.A.). Ammonia oxidation was examined in April and July 1995 by comparing dark 14 CO 2 fixation rates in the presence or absence of methyl fluoride (MeF), an inhibitor of NH 3 oxidation. Ammonia oxidizer‐mediated dark 14 CO 2 fixation rates were similar in surface (5–7 m) and oxycline (11–15 m) waters, ranging between 70–340 and 89–186 nM d −1 , respectively, or 1–7% of primary production by phytoplankton. Ammonia oxidation rates ranged between 580–2,830 nM d −1 in surface waters and 732–1,548 nM d −1 in oxycline waters. Methane oxidation was examined using a 14 CH 4 tracer technique in July 1994, April 1995, and July 1995. Methane oxidation rates were consistently higher in July, and rates in oxycline and anaerobic bottom waters (0.5–37 and 7–48 nM d −1 , respectively) were 10‐fold higher than those in aerobic surface waters (0.04–3.8 nM d −1 ). The majority of CH 4 oxidation, in terms of integrated activity, occurred within anoxic bottom waters. Water column oxidation reduced the potential lake‐atmosphere CH 4 flux by a factor of two to three. Measured oxidation rates and water column concentrations were used to estimate the biological turnover times of NH 3 and CH 4 . The NH 3 pool turns over rapidly, on time scales of 0.8 d in surface waters and 10 d within the oxycline, while CH 4 is cycled on 10 3 ‐d time scales in surface waters and 10 −2 time scales within oxycline and bottom waters. Our data suggest an important role for NH 3 oxidation in alkaline, saline lakes since the process converts volatile NH 3 to soluble NO 2 − , thereby reducing loss via lake‐atmosphere exchange and maintaining nitrogen in a form that is readily available to phyto‐plankton.

Limnology and Oceanography↗

Microbial degradation of the lamprey larvicide 3-trifluoromethyl-4-nitrophenol in sediment-water systems

The selective lampricide 3-trifluoromethyl-4-nitrophenol (TFM), maintained in the water at concentrations of 1 to 6 I?g/ml for several hours, kills larval sea lampreys (Petromyzon marinus) in tributaries of the Great Lakes. Because the fate of TFM in the environment is a matter of concern, the interactions of this chemical with river and lake sediments were studied in laboratory experiments. In mixtures of TFM, water, and sediment held in aquariums, the TFM decreased progressively and nearly or completely disappeared in 1 to 4 weeks; concentrations of the fluoride ion increased; and the systems became nontoxic for sea lamprey larvae and goldfish (Carassius auratus). If the reduction in TFM ceased before all of the chemical had disappeared, the process resumed when nutrient broth was added. Loss of TFM from the systems was prevented by the addition of an antiseptic (phenol) and by heat sterilization. Enrichment cultures of microorganisms isolated from stream and lake sediments degraded TFM in nutrient broths. I conclude that TFM is degraded by microorganisms that live in sediment-water systems.

Technical Report↗

Environmental Contaminants in Wildlife: Interpreting Tissue Concentrations

Covers the complex issue of how to evaluate contaminants in wildlife. This comprehensive resource deals with the question: 'How much of a chemical in the tissues of an animal is harmful?' Features: Authoritative and sound advice is provided on many environmental contaminants, including what the contaminants are and how to interpret the data on them. Each chapter includes a review of the literature on a specific chemical, followed by a clear technical summary that provides research guidance. Direction is given on how to interpret data that are sometimes conflicting or insufficient. Data are presented in easy to use tables. Primary attention is given to toxic concentrations of contaminants such as organochlorine pesticides, PCBs, dioxins, PAHs, metals, and fluorides.

SETAC Special Publications Series.↗

Ecotoxicology of aluminum to fish and wildlife

The toxicity of aluminum has been studied extensively in fish, less so in invertebrates, amphibians, and birds, and not at all in reptiles and free-ranging mammals. For aquatic organisms, Al bioavailability and toxicity are intimately related to ambient pH; changes in ambient acidity may affect Al solubility, dissolved Al speciation, and organism sensitivity to Al. At moderate acidity (pH 5.5 to 7.0), fish and invertebrates may be stressed due to Al adsorption onto gill surfaces and subsequent asphyxiation. At pH 4.5 to 5.5, Al can impair ion regulation and augment the toxicity of H+. At lower pH, elevated Al can temporarily ameliorate the toxic effects of acidity by competing for binding sites with H+. Aluminum toxicity in aquatic environments is further affected by the concentration of ligands such as dissolved organic matter, fluoride, or sulfate, and of other cations such as Ca and Mg which compete for cellular binding sites. Although risk of Al toxicity is often based on a model of free-ion (Al3+) activity, recent evidence suggests that factors determining Al toxicity may be more complex. In general, aquatic invertebrates are less sensitive to Al toxicity and acidity than fish; thus acidified, Al-rich waters may actually reduce predation pressure. Fish may be affected by asphyxiation at moderate acidic conditions or electrolyte imbalances at lower pH. In amphibians, embryos and young larvae are typically more sensitive than older larvae. Early breeding amphibians, which lay eggs in ephemeral ponds and streams subject to spring runoff, are most at risk from Al and acidification; those that breed later in the year in lakes or rivers are least vulnerable. Birds and mammals are most likely exposed through dietary ingestion of soil or Al-contaminated foods. Concentrations > 1000 mg.kg-1 in food may be toxic to young birds and mammals. Clinical signs in these animals are consistent with rickets because Al precipitates with P in the gut. Suggestions for additional research on the ecotoxicology of Al to wild animals are provided.

Book chapter↗

Chemical, isotopic, and dissolved gas compositions of the hydrothermal system in Twin Falls and Jerome counties, Idaho

The chemical, isotopic, and gas compositions of the hydrothermal system in Twin Falls and Jerome counties, Idaho, change systematically as the water moves northward from the Idaho-Nevada boundary toward the Snake River. Sodium, chloride, fluoride, alkalinity, dissolved helium, and carbon-13 increase as calcium and carbon-14 decrease. Water-rock reactions may result in dissolution of plagioclase or volcanic glass and calcite, followed by precipitation of zeolites and clays. On the basis of carbon-14 age dating, apparent water ages range from 2,000 to more than 26,000 years; most apparent ages range from about 4,000 to 10,000 years. The older waters, north of the Snake River, are isotopically depleted in deuterium and are enriched in chloride relative to waters to the south. Thermal waters flowing northward beneath the Snake River may join a westward flow of older thermal water slightly north of the river. The direction of flow in the hydrothermal system seems to parallel the surface drainage.

Geothermal Resources Council Transactions↗

Geological setting and petrogenesis of symmetrically zoned, miarolitic granitic pegmatites at Stak Nala, Nanga Parbat - Haramosh Massif, northern Pakistan

Miarolitic granitic pegmatites in the Stak valley in the northeast part of the Nanga Parbat - Haramosh Massif, in northern Pakistan, locally contain economic quantities of bi- and tricolored tourmaline. The pegmatites form flat-lying sills that range from less than 1 m to more than 3 m thick and show symmetrical internal zonation. A narrow outer or border zone of medium-to coarse-grained oligoclase - K-feldspar - quartz grades inward to a very coarse-grained wall zone characterized by K-feldspar - oligoclase - quartz - schorl tourmaline. Radiating sprays of schorl and flaring megacrysts of K-feldspar (intermediate microcline) point inward, indicating progressive crystallization toward the core. The core zone consists of variable mixtures of blocky K-feldspar (intermediate microcline), oligoclase, quartz, and sparse schorl or elbaite, with local bodies of sodic aplite and miarolitic cavities or "pockets". Minor spessartine-almandine garnet and lo??llingite are disseminated throughout the pegmatite, but were not observed in the pockets. The pockets contain well-formed crystals of albite, quartz, K-feldspar (maximum microcline ?? orthoclase overgrowths), schorl-elbaite tourmaline, muscovite or lepidolite, topaz, and small amounts of other minerals. Elbaite is color-zoned from core to rim: green (Fe2+- and Mn2+-bearing), colorless (Mn2+-bearing), and light pink (trace Mn3+). Within ???10 cm of the pegmatites, the granitic gneiss wallrock is bleached owing to conversion of biotite to muscovite, with local quartz and albite added. Schorl is disseminated through the altered gneiss, and veins of schorl with bleached selvages locally traverse the wallrock up to 1 m from the pegmatite contact. The schorl veins can be traced into the outer part of the wall zone, which suggests that they formed from aqueous fluids derived during early saturation of the pegmatite-forming leucogranitic magma rich in H2O, F, B, and Li. Progressive crystallization resulted in a late-stage sodic magma and abundant aqueous fluids. Two late stages of volatile escape are recognized: the first stage caused pressure-quenching of the last magma, which produced aplite and caused albitization (An3 to An8) of earlier crystallized K-feldspar and oligoclase. The second stage, released during the rupture of miarolitic cavities, produced platy albite ("cleavelandite," An1) locally associated with F-rich moscovite and elbaite. Albitization is likely due to cooling of alkali-fluoride-dominated fluids at less than 2 kbar pressure. The pegmatites are derived from Himalayan leucogranitic magma emplaced prior to 5 Ma into granulitic gneiss that was at 300?? to 550??C and 1.5 to 2 kbar. The pegmatites were emplaced during uplift of the Haramosh Massif, since they cross-cut ductile normal faults but are cut by brittle normal faults. Economically important pink tourmaline mineralization formed in pockets concentrated near the crest of a broad antiform, as a result of trapping of late magmatic aqueous fluids that had become Fe-poor owing to the prior crystallization of schorl.

Canadian Mineralogist↗

Simmonsite, Na2LiAlF6, a new mineral from the Zapot amazonite-topazzinnwaldite pegmatite, Hawthorne, Nevada, U.S.A

Simmonsite, Na2LiAlF6, a new mineral of pegmatitic-hydrothermal origin, occurs in a late-stage breccia pipe structure that cuts the Zapot amazonite-topaz-zinnvvaldite pegmatite located in the Gillis Range, Mineral Co., Nevada, U.S.A. The mineral is intimately intergrown with cryolite, cryolithionite and trace elpasolite. A secondary assemblage of other alumino-fluoride minerals and a second generation of cryolithionite has formed from the primary assemblage. The mineral is monoclinic, P21 or P21/m, a = 7.5006(6) A??, b = 7.474(1) A??, c = 7.503(1) A??, ??= 90.847(9) ??, V=420.6(1) A??3, Z = 4. The four strongest diffraction maxima [d(A??), likl, I/I100] are (4.33, 111 and 111, 100); (1.877, 400 and 004, 90); (2.25, 13T, 113, 131 and 311, 70); and (2.65, 220, 202, 022, 60). Simmonsite is pale buff cream with white streak, somewhat greasy, translucent to transparent, Mohs hardness of 2.5-3, no distinct cleavage, subconchoidal fracture, no parting, not extremely brittle, Dm is 3.05(2) g/cm3, and Dc is 3.06(1) g/cm3. The mineral is biaxial, very nearly Isotropie, N is 1.359(1) for ?? = 589 nm, and birefringence is 0.0009. Electron microprobe analyses gave (wt%) Na = 23.4, Al = 13.9, F = 58.6, Li = 3.56 (calculated), with a total of 99.46. The empirical formula (based on 6 F atoms) is Na1.98Li1.00 ooAl|ooF6. The crystal structure was not solved, presumably because of unit-cell scale twinning, but similarities to the perovskite-type structure exist. The mineral is named for William B. Simmons, Professor of Mineralogy and Petrology, University of New Orleans, New Orleans.

American Mineralogist↗

Potential effects of recurrent low oxygen conditions on the Illinois Cave amphipod

The caves of Illinois' sinkhole plain are the sole habitat of the Illinois Cave amphipod (Gammarus acherondytes), a federally endangered species. The sinkhole plain is a hydrologically-connected sequence of karstified limestone that constitutes an extensive karst aquifer which serves as an important source of potable water for area residents. During this investigation, we examined the ground-water quality in caves within two ground-water basins: 1) Illinois Caverns, where the amphipod is now present after previously reported to have been extirpated from the lower reaches, and 2) Stemler Cave, where the amphipod is reported to have been extirpated. The chemical composition of cave streams in Illinois Caverns and Stemler Cave were compared to determine which parameters, if any, could have contributed to the loss of G. acherondytes from Stemler Cave. Stream water in Stemler Cave contained higher concentrations of organic carbon, potassium, silica, chloride, fluoride, sulfate, iron and manganese than Illinois Caverns. Perhaps most importantly, dissolved oxygen (DO) concentrations in Stemler Cave were, during periods of low flow, substantially lower than in Illinois Caverns. Based on land use, there are probably at least eight times more private septic systems in the Stemler Cave ground-water basin than in the Illinois Caverns ground-water basin. Low DO concentrations were likely the result of microbial breakdown of soil organic matter and wastewater treatment system effluent, and the oxidation of pyrite in bedrock. The near-hypoxic DO in Stemler Cave that occurred during low-flow conditions, and, we speculate, a limited range of G. acherondytes within the Stemler Cave ground-water basin due to a metabolic advantage of the stygophilic aquatic invertebrates over the stygobitic G. acherodytes, resulted in the apparent loss of G. acherondytes from Stemler Cave.

Journal of Cave and Karst Studies↗

Mineral resource of the month: fluorspar

The article features the industrial mineral fluorspar, used in the manufacture of fluorochemicals, aluminum and steel. It defines fluorspar as crude or beneficiated material, mined or milled for the non-metallic mineral fluorite or calcium fluoride. Applications of acid-grade fluorspar in the U.S. are presented, including production of hydrofluoric acid for chemical production of refrigerants such as chlorofluorocarbons or CFCs. World demand for fluorspar decreased with the CFC ban in the 1990s, but recovered with the use of hydrofluorocarbons or HFCs.

Earth↗

Fluorite equilibria in thermal springs of the Snake River Basin, Idaho

Some thermal water sources of the Snake River basin, Idaho, are near saturation with respect to fluorite. That mineral was identified by X-ray diffraction in precipitates induced in three water samples by adding sodium fluoride. The derived solubility product (K S0 ) for zero ionic strength was close to that calculated from Latimer's thermodynamic data (10 -9.7 7 ). The relative ease of precipitation of fluorite from these water samples indicates that equilibrium with respect to fluorite may occur in some ground-water systems.

Idaho↗

Ground-water resources of the south metropolitan Atlanta region, Georgia

Ground-water resources of the nine county south metropolitan Atlanta region were evaluated in response to an increased demand for water supplies and concern that existing surface water supplies may not be able to meet future supply demands. Previous investigations have suggested that crystalline rock in the study area has low permeability and can not sustain well yields suitable for public supply. However, the reported yield for 406 wells drilled into crystalIine rock units in this area ranged from less than 1 to about 700 gallons per minute, and averaged 43 gallons per minute. The reported flow from 13 springs ranged from 0.5 to 679 gallons per minute. The yield of 43 wells and flow from five springs was reported to exceed 100 gallons per minute. Most of the high-yielding wells and springs were near contact zones between rocks of contrasting lithologic and weathering properties. The high-yielding wells and springs are located in a variety of topographic settings: hillsides, upland draws, and hilltops were most prevalent. The study area, which includes Henry, Fayette, Coweta, Spalding, Lamar, Pike, Meriwether, Upson and Talbot Counties, is within the Piedmont physiographic province except for the southernmost part of Talbot County, which is in the Coastal Plain physiographic province. In the Piedmont, ground-water storage occurs in joints, fractures and other secondary openings in the bedrock, and in pore spaces in the regolith. The most favorable geologic settings for siting highyielding wells are along contact zones between rocks of contrasting lithology and permeability, major zones of fracturing such as the Towaliga and Auchumpkee fault zones, and other numerous shear and microbreccia zones. Although most wells in the study area are from 101 to 300 feet deep, the highest average yields were obtained from wells 51 to 100 feet deep, and 301 to 500 feet deep. Of the wells inventoried, the average diameter of well casing was largest for wells located on hills and ridges, possibly indicating a preference for such topographic locations by cities and industrial users who typically develop larger diameter wells than do domestic users. Generally, for a given depth range or well diameter, the highest yielding wells were obtained in draws and valleys, followed by hills and ridges and slopes and flats. In 1985, wells and springs supplied about 16 million gallons per day or 37 percent of the total water withdrawn in the area. Average recharge to the aquifers in the upper Flint River basin, which constitutes 66 percent of the area, was estimated to be about 575 million gallons per day. Groundwater recharge in this basin ranged from 414 million gallons per day during an average dry year, to 77 million gallons per day during an average wet year. During the severe drought of 1954, the estimated recharge was 70 million gallons per day. Ground water in the study area generally is suitable for most uses. With the exception of local occurences of excessive iron, fluoride, and manganese, concentrations of total and/or dissolved constituents generally meets State and Federal drinking water standards. Ground-water quality may be affected by the presence of radionuclides associated with the decay of uranium found in igneous and metamorphic rocks.

Georgia↗

Notes on the bromine pentafluoride technique of oxygen extraction

The necessity to use a dry box when loading silicate samples into reaction vessels prior to fluorination is eliminated by the use of a simple loading technique. Data presented show the reproducibility of the fluorination reaction using this technique. Sodium fluoride, when added to saline waters prior to fluorination, improves the precision of the overall technique.

Journal of Research of the U.S. Geological Survey↗

Hydrogeology and ground-water use and quality, Brown County, Wisconsin

The Paleozoic rock of Brown County includes formations of Cambrian, Ordovician, and Silurian age. These formations are eastward-dipping sedimentary rock that rest on Precambrian crystalline rock and are overlain by Pleistocene deposits. The units that are the principal sources of ground water were grouped into three aquifers (upper, St. Peter, and Elk Mound), and the less permeable units are grouped into three confining units (Maquoketa-Sinnipee, St. Lawrence, and Precambrian). The geologic and hydraulic characteristics of the aquifers and confining units are estimated from logs of more than 1,000 Brown County wells, from results of a packer test, and from published values. Recharge to the water table, which was estimated at five monitored sites, ranges from 1 to 6 inches a year; most recharge is contributed by spring snowmelt and rainfall. A cone of depression caused by pumping the deeper aquifers in the Green Bay metropolitan area induces flow from the upper aquifer to the underlying st. Peter aquifer throughout most of the county. Several reaches of Duck Creek and the Suamico River also contribute water to the aquifers. A bout 13 million gallons per day of ground water was pumped in Brown County during 1979, 63 percent of which was from wells open to both the St. Peter and Elk Mound aquifers. Municipal and industrial water users pumped 9.44 million gallons per day or 72 percent of the ground water withdrawn in 1979. Most ground :water in the county is a calcium magnesium bicarbonate type. However, water from wells sampled in an area between the Fox River and Silurian escarpment have elevated levels of sodium (44 milligrams per liter) and sulfate (226 milligrams per liter). Water from wells that tap rocks older than Silurian dolomite contains high concentrations of strontium (more than 2.4 milligrams per liter) and fluoride (more than 0.85 milligrams per liter). A three-dimensional digital model was used to simulate flow in the ground-water system. Model results indicate that sources of ground water pumped from wells tapping the St. Peter and Elk Mound aquifers in Brown County, 1979, include 4.8 million gallons per day of underflow, most of which enters the county across the west border; 1.9 million gallons per day of flow from vertical leakage within the county; and 1.5 million gallons per day from storage. The model is most sensitive to the horizontal hydraulic conductivity of the upper aquifer. Vertical hydraulic conductivity of the confining units and recharge rates to the water-table aquifer are the least well-defined model parameters.

Wisconsin↗

Ground-water quality atlas of Wisconsin

This report summarizes data on ground-water quality stored in the U.S. Geological Survey's computer system (WATSTORE). The summary includes water quality data for 2,443 single-aquifer wells, which tap one of the State's three major aquifers (sand and gravel, Silurian dolomite, and sandstone). Data for dissolved solids, hardness, alkalinity, calcium, magnesium, sodium, potassium, iron, manganese, sulfate, chloride, fluoride, and nitrate are summarized by aquifer and by county, and locations of wells for which data are available 1 are shown for each aquifer. Calcium, magnesium, and bicarbonate (the principal component of alkalinity) are the major dissolved constituents in Wisconsin's ground water. High iron concentrations and hardness cause ground-water quality problems in much of the State. Statewide ,summaries of trace constituent (selected trace metals; arsenic, boron, and organic carbon) concentrations show that these constituents impair water quality in only a few isolated wells.

Wisconsin↗

Geology and ground-water resources of Wichita and Greeley Counties, Kansas

This report describes the geography, geology, and ground-water resources of Wichita and Greeley counties in western Kansas. The area consists of a flat to gently rolling plain, which slopes eastward [at] about 15 feet per mile. A short reach of Ladder Creek (Beaver) is the only perennially flowing stream in the two counties. Ephemeral streams, which flow only during and after heavy rains, are White Woman and Sand Creeks and the western reach of Ladder Creek. The climate is semiarid, the normal annual precipitation being about 17 inches in Wichita County and 16 inches in Greeley County. Agriculture is the principal occupation in the area, and wheat is the most important crop. A considerable area is irrigated; sugar beets and sorghums are the principal irrigated crops. The outcropping rocks range in age from late Cretaceous to Recent; the Smoky Hill chalk member of the Niobrara formation, which is exposed along White Woman Creek in western Greeley County, is the oldest. The Niobrara is almost everywhere overlain by the Ogallala formation of Pliocene age. Generally the Ogallala is overlain by windblown silt of the Pleistocene Sanborn formation, but in places it is exposed along streams. The most recent deposits are dune sand and the alluvium along the streams. The Dakota formation, which is an important aquifer in parts of Kansas, is 300 to 450 feet beneath the Niobrara formation. The ground water that is available to wells in Wichita and Greeley counties is derived entirely from precipitation in the area or in areas immediately west and north. Ground water moves in a generally easterly direction with a gradient that varies inversely with the permeability of the water-bearing beds. The ground-water reservoir is recharged principally by precipitation within the area or within adjacent areas, Ground-water discharge takes place principally by pumping from wells, subsurface outflow, and evaporation and transpiration. Most of the domestic, stock, public, and irrigation supplies are obtained from wells. It is estimated that probably more than 2 billion gallons of water is pumped annually from wells in the area. Since 1947, ground-water recharge has been about equal to ground-water discharge. The use of ground water for irrigation has increased greatly since 1946 and indications are that many more wells may be drilled and pumped without dangerously lowering the water table. Approximately 11,000 to 12,000 acres were irrigated in 1951. A map showing the thickness of water-bearing materials indicates that although much of the area has enough water-bearing material to support irrigation wells, parts of Wichita and Greeley counties have little or none. The Ogallala is the principal water-bearing formation in the area. Small amounts of water may also be obtained locally from alluvial deposits and from cracks in the Niobrara formation. Two deep test wells to the Dakota formation have been drilled but, because of the poor quality of the water, have never been used. The ground water in Wichita and Greeley counties, though hard, is suitable for most purposes. Water from the Ogallala is generally high in fluoride and in some cases may be injurious to the teeth of children. Water from the Dakota, though soft, is unfit for irrigation because of a high content of sodium. The field data upon which most of this report is based are given in tables; they include records of 417 wells, chemical analyses of 31 samples of water, and logs of 57 test holes and wells.

Kansas Geological Survey Bulletin↗