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At least 451 records · Page 25Linked to original sources

Rare earths in phosphorites: Geochemistry and potential recovery

Rare earths are but trace constituents of marine apatite. However, as millions of tones of such apatite are dissolved annually to make phosphoric acid, an opportunity exists for greatly increasing RE output as by-product of fertilizer production. New, complete, quantitative analysis of RE in representative apatite concentrates reveal that the potential for by-product RE equals current production. The RE assemblage in marine apatite is unusual, showing depletion in cerium and relative enrichment in the heavier lanthonons, a favorable distribution for RE technology and utilization.

Open-File Report

A summary of niobium and rare earth localities from Ha'il and other areas in western Saudi Arabia: a preliminary study

Investigations in 1965 located veins containing radioactive material in the Halaban Group on the east side of a granite pluton at Jabal Aja near Ha'il. Later study extended the known area of radioactivity to a total length of about 30 km. Mineralogic studies indicated that the samples were low in uranium and that the radioactivity was due principally to thorium in niobium-bearing minerals. Two samples were reexamined to identify the sources of radioactivity, but X-ray and alpha plate studies did not reveal the radioactive minerals, even though uranium mineralization was indicated by the alpha plates. Further sampling is suggested to isolate the sources of radioactivity. This study indicates that niobium occurrences are related to alkaline intrusives in many areas of western Saudi Arabia. These areas should be investigated for their possible niobium and rare earth contents; their uranium content is apparently too low to be of economic interest.

Open-File Report

Examples of the use of earth-science information by decisionmakers in the San Francisco Bay region, California

In the six examples discussed and illustrated here, innovative decisionmakers -- public and private -- have used earth-science information to avoid areas with geologic hazards, protect natural resources, and reduce possible property damage in the San Francisco Bay region. The examples show how: 1) development in fault-rupture areas is regulated, 2) potential waste-disposal sites are identified, 3) aquatic and wildlife habitats are protected, 4) site investigations are required in hazardous areas, 5) supplemental building standards can be applied to unstable baylands, and 6) hazards are disclosed to real-estate buyers.

California

The Earth Resources Observation Systems data center's training technical assistance, and applications research activities

The Earth Resources Observation Systems (EROS) Data Center (EDO, administered by the U.S. Geological Survey, U.S. Department of the Interior, provides remotely sensed data to the user community and offers a variety of professional services to further the understanding and use of remote sensing technology. EDC reproduces and sells photographic and electronic copies of satellite images of areas throughout the world. Other products include aerial photographs collected by 16 organizations, including the U.S. Geological Survey and the National Aeronautics and Space Administration. Primary users of the remotely sensed data are Federal, State, and municipal government agencies, universities, foreign nations, and private industries. The professional services available at EDC are primarily directed at integrating satellite and aircraft remote sensing technology into the programs of the Department of the Interior and its cooperators. This is accomplished through formal training workshops, user assistance, cooperative demonstration projects, and access to equipment and capabilities in an advanced data analysis laboratory. In addition, other Federal agencies, State and local governments, universities, and the general public can get assistance from the EDC Staff. Since 1973, EDC has contributed to the accelerating growth in development and operational use of remotely sensed data for land resource problems through its role as educator and by conducting basic and applied remote sensing applications research. As remote sensing technology continues to evolve, EDC will continue to respond to the increasing demand for timely information on remote sensing applications. Questions most often asked about EDC's research and training programs include: Who may attend an EDC remote sensing training course? Specifically, what is taught? Who may cooperate with EDC on remote sensing projects? Are interpretation services provided on a service basis? This report attempts to define the goals and objectives of and policies on the following EDC services: Training Program. User Assistance. Data Analysis Laboratory. Cooperative Demonstration Projects. Research Projects.

Open-File Report

Table-top earthquakes; a demonstration of seismology for teachers and students that can be used to augment lessons in earth science, physics, math, social studies, geography

The apparatus consists of a heavy object that is dragged steadily with an elastic cord. Although pulled with a constant velocity, the heavy object repeatedly slides and then stops. A small vibration sensor, attached to a computer display, graphically monitors this intermittent motion. 2 This intermittent sliding motion mimics the intermittent fault slippage that characterizes the earthquake fault zones. In tectonically active regions, the Earth's outer brittle shell, which is about 50 km thick, is slowly deformed elastically along active faults. As the deformation increases, stress also increases, until fault slippage releases the stored elastic energy. This process is called elastic rebound. Detailed instructions are given for assembly and construction of this demonstration. Included are suggested sources for the vibration sensor (geophone) and the computer interface. Exclusive of the personal computer, the total cost is between $125 and $150. I gave a talk at the Geological Society of America's Cordilleran Section Centennial meeting on June 2, 1999. The slides show how this table-top demonstration can be used to help meet many of the K-12 teaching goals described in Benchmarks for Science Literacy (American Association for the Advancement of Science, 1993).

Open-File Report

Hydrologic conditions and lake-level fluctuations at Long Lost Lake, 1939-2004, White Earth Indian Reservation, Clearwater County, Minnesota

Long Lost Lake, a closed-basin lake in Clearwater County, Minnesota, has had a substantial rise in lake level since 1990. The increased level and surface area of the lake has led to the inundation of nearby homes and roads. The U.S. Geological Survey, in cooperation with the White Earth Band of Chippewa Indians, conducted a study to document the historical lake-level fluctuations, to investigate reasons for hydrologic change, and to develop a general understanding of the hydrology of lakes that have had rapid changes in lake level. Lake levels were recorded continuously from August 2003 through December 2004. The purpose was to establish a temporal, detailed record of lake levels and to connect this record to precipitation and ground-water-level data. A long-term record is critical to understanding the relation between surface water and ground water. This is especially true for closed-basin lakes. Between August 2003 and December 2004, the lake level generally declined. The highest lake altitude was 492.58 meters above NAVD 88 on August 5, 2003, and the low of 492.11 meters above NAVD 88 occurred on August 29, 2004. Results of water-level measurements in 5 observation wells and 14 wetlands and ponds show that the water-table level is substantially higher on the north side of the lake than the lake level, providing the head pressure necessary for ground-water discharge into Long Lost Lake. In contrast, on the south and east sides of the lake, water-table levels are similar to the lake level. This indicates a general north-northwest to south-southeast ground-water flow direction. Results of a synoptic survey of lake temperature and other measurements supported the direction of water inflow and outflow. Aerial photography and a geographic information system were used to construct a historical lake record from 1939 to 2001. Lake-level increases match similar increases in precipitation, indicating a strong link between the two. Results show that lake-level increases in Long Lost Lake appear to primarily be due to natural rather than anthropogenic effects.

Minnesota

Earth Mapping Resources Initiative protocols—Sampling hard-rock mine waste and perpetual mine water sources

Supporting the overarching goal to evaluate critical minerals nationwide, the mine waste characterization effort in the U.S. Geological Survey (USGS) Earth Mapping Resources Initiative has created a series of protocols to standardize sampling carried out under this effort by the participating State geological surveys and their cooperators. The protocols are based on published, reviewed methods that can be deployed in the field. The protocols include (1) collecting and processing composite samples of mine and mill waste, including tailings, waste rock, gangue, heap leach piles, ore stockpiles, slag, or other mineralized and processed materials and (2) collecting and preserving water samples from perpetual or long-term mine water sources. The protocols also specify information to document on field sheets and detail the collection of geospatial data. The analytical methods used by the USGS and USGS contract laboratories are described in this report, including the data delivery pathway for USGS-derived data.

Scientific Investigations Report

Regional characterization of coal resources in the Gulf Coast Coal Region—In support of coal as a potential source for critical minerals and rare earth elements

There is increasing interest in extracting critical minerals (CM), including rare earth elements (REE), from coals in the United States to address the overreliance on imported REE. The Gulf Coast and the Fort Union regions are the two major lignite-bearing regions within the United States. Recent REE and CM studies of the lignite in these regions have indicated that the coals may be a viable source material for REE and CM extraction. To evaluate in-place coal as a potential source of REE and CM, the coal resources need to be quantified. This study presents the results of a regional analysis of Gulf Coast Coal Region lignite and bituminous coal resources that might be available as potential sources of REE and CM. The resource analysis used kriging methods to develop isopleth maps of cumulative coal thickness throughout the region using data from drill holes and measured mine and outcrop sections for a total of 31,181 data points. The estimated total remaining coal resource in the Gulf Coast Coal Region is about 83 billion metric tons in the upper 90 meters (approximately 300 feet) of the subsurface. The current estimate of remaining coal resources includes approximately 1.88 billion metric tons of coal that have been extracted in the region since 1983. Texas accounted for 39 percent (32 billion metric tons) of the remaining total resource, followed by Mississippi (24 percent, 20 billion metric tons ), Louisiana (14 percent, 12 billion metric tons), Tennessee (10 percent, 8.5 billion metric tons), and Arkansas (6 percent, 5.1 billion metric tons). Alabama, Georgia, Kentucky, and Missouri each accounted for less than 5 percent of the total resource; Georgia had the smallest resource estimated at 7 million metric tons. Here we report the first known statewide lignite resource estimates for Georgia, Kentucky (820 million metric tons), and Missouri (1,800 million metric tons). A comparison of the results of this study with those of previous Gulf Coast Coal Region and Fort Union Coal Region resource studies is difficult because each study used different data sources, assessment methodologies, overburden depths, and qualifying coal thicknesses.

Alabama, Arkansas, Florida, Georgia, Illinois, Lou

Estimating hydraulic properties of the Floridan Aquifer System by analysis of earth-tide, ocean-tide, and barometric effects, Collier and Hendry Counties, Florida

Aquifers are subjected to mechanical stresses from natural, non-anthropogenic, processes such as pressure loading or mechanical forcing of the aquifer by ocean tides, earth tides, and pressure fluctuations in the atmosphere. The resulting head fluctuations are evident even in deep confined aquifers. The present study was conducted for the purpose of reviewing the research that has been done on the use of these phenomena for estimating the values of aquifer properties, and determining which of the analytical techniques might be useful for estimating hydraulic properties in the dissolved-carbonate hydrologic environment of southern Florida. Fifteen techniques are discussed in this report, of which four were applied. An analytical solution for head oscillations in a well near enough to the ocean to be influenced by ocean tides was applied to data from monitor zones in a well near Naples, Florida. The solution assumes a completely non-leaky confining unit of infinite extent. Resulting values of transmissivity are in general agreement with the results of aquifer performance tests performed by the South Florida Water Management District. There seems to be an inconsistency between results of the amplitude ratio analysis and independent estimates of loading efficiency. A more general analytical solution that takes leakage through the confining layer into account yielded estimates that were lower than those obtained using the non-leaky method, and closer to the South Florida Water Management District estimates. A numerical model with a cross-sectional grid design was applied to explore additional aspects of the problem. A relation between specific storage and the head oscillation observed in a well provided estimates of specific storage that were considered reasonable. Porosity estimates based on the specific storage estimates were consistent with values obtained from measurements on core samples. Methods are described for determining aquifer diffusivity by comparing the time-varying drawdown in an open well with periodic pressure-head oscillations in the aquifer, but the applicability of such methods might be limited in studies of the Floridan aquifer system.

Florida

Water-quality characteristics and trends for selected sites in or near the Earth Resources Observation Systems (EROS) Data Center, South Dakota, 1973-2000

This report presents data on water-quality samples that were collected in and near the Earth Resources Observation Systems (EROS) Data Center from 1973 through 2000. The investigation is a collaborated effort between the U.S. Geological Survey, Water Resources Discipline (WRD), and Geography (formerly National Mapping) Discipline, EROS Data Center. A water-quality monitoring program was initiated in 1973, when the EROS Data Center was constructed, and continues at the present time (2003). Under this program, water-quality samples were collected at various sites on the EROS Data Center's property and in the surrounding area. These sites include 4 wastewater-treatment lagoons, 1 site on EROS Lake located behind the EROS Data Center, 2 stream sites near the EROS Data Center, and 9 ground-water wells surrounding the EROS Data Center. Additionally, 3 sites on EROS Lake, 7 stream sites, and 9 ground-water sites are located within the study area and have been sampled during the period covered in the report. Some of these additional sites were part of the initial water-quality monitoring conducted during and immediately after the construction of the EROS Data Center. For other sites, some special sampling (depth-profile and bottom material) has occurred at times during the sampling history; however, these sites have little water-quality data and were not used for statistical or trend analysis. A trend-analysis program, Estimate TREND (ESTREND), was used to analyze for trends for one surface-water site, the Big Sioux River, which was the only site that had a substantial number of samples collected during an extensive period. The ESTREND trend-analysis program was used to analyze 16 constituents. Specific conductance and dissolved orthophosphate were the only constituents determined to have statistically significant trends. Results showed an increasing trend for specific conductance and a decreasing trend for dissolved orthophosphate. Scatter plots with regression smoothing lines for selected constituents are presented for selected surface-water and ground-water sites. Regression analyses using a Lowess (Locally Weighted Scatterplot Smoothing) smoothing line for Split Rock Creek, EROS Lake, the lagoon sites, and the ground-water sites indicated variable results, with some constituents indicating an increasing or decreasing trend, some having varied results, and others indicating no change during the sampling period.

South Dakota

Enhancing the application of Earth observations for improved environmental decision-making using the Early Warning eXplorer (EWX)

The mitigation of losses due to extreme climate events and long-term climate adaptation requires climate informed decision-making. In the past few decades, several remote sensing and modeled-based Earth observations (EOs) have been developed to provide an unprecedented global overview and routine monitoring of climate and its impacts on vegetation and hydrologic conditions, with the goal of supporting informed decision-making. However, their usage in decision-making is particularly limited in climate-risk vulnerable and in situ data-scarce regions such as sub-Saharan Africa, due to lack of access to EOs. Here, we describe the Early Warning eXplorer (EWX), which was developed to address this crucial limitation and facilitate the application of EOs in decision-making, particularly in the food and water-insecure regions of the world. First, the EWX's core framework, which includes (i) the Viewer, (ii) GeoEngine, and (iii) Support Applications, is described. Then, a comprehensive overview of the Viewer, which is a web-based interface used to access EOs, is provided. This includes a description of (i) the maps and associated features to access gridded EO data and anomalies for different temporal averaging periods, (ii) time series graphs and associated features to access EOs aggregated over polygons such as administrative boundaries, and (iii) commonly used EOs served by the EWX that provide assessments of climate and vegetation conditions. Next, examples are provided to demonstrate how EWX can be used to monitor development, progression, spatial extent, and severity of climate-driven extreme events to support timely decisions related to mitigation of food insecurity and flooding impacts. Finally, the value of a regional implementation of EWX at the Regional Centre for Mapping of Resources for Development (RCMRD) in Nairobi, Kenya, is highlighted. Regional implementation of the EWX facilitates access to regionally focused EOs and their availability at polygon boundaries most relevant to the local decision-makers. Similar instances of EWX implemented in other regions, especially those susceptible to food and water security, will likely further enhance the application of EOs for informed decision-making.

Frontiers in Climate

Influence of organic matter thermal maturity on rare earth element distribution: A study of Middle Devonian black shales from the Appalachian Basin, USA

This study focuses on understanding the association of rare earth elements (REE; lanthanides + yttrium + scandium) with organic matter from the Middle Devonian black shales of the Appalachian Basin. Developing a better understanding of the role of organic matter (OM) and thermal maturity in REE partitioning may help improve current geochemical models of REE enrichment in a wide range of black shales. We studied relationships between whole rock REE content and total organic carbon (TOC) and compared the correlations with a suite of global oil shales that contain TOC as high as 60 wt.%. The sequential leaching of the Appalachian shale samples was conducted to evaluate the REE content associated with carbonates, Fe–Mn oxyhydroxides, sulfides, and organics. Finally, the residue from the leaching experiment was analyzed to assess the mineralogical changes and REE extraction efficiency. Our results show that heavier REE (HREE) have a positive correlation with TOC in our Appalachian core samples. However, data from the global oil shales display an opposite trend. We propose that although TOC controls REE enrichment, thermal maturation likely plays a critical role in HREE partitioning into refractory organic phases, such as pyrobitumen. The REE inventory from a core in the Appalachian Basin shows that (1) the total REE ranges between 180 and 270 ppm and the OM-rich samples tend to contain more REE than the calcareous shales; (2) there is a relatively higher abundance of middle REE (MREE) to HREE than lighter REE (LREE); (3) there is a disproportionate increase in Y and Tb with TOC likely due to the rocks being over-mature; and (4) the REE extraction demonstrates that although the OM has higher HREE concentration, the organic leachates contain more LREE, suggesting it is more challenging to extract HREE from OM than using traditional leaching techniques.

Middle Devonian Appalachian Basin

Tungsten skarn quantitative mineral resource assessment and gold, rare earth elements, graphite, and uranium qualitative assessments of the Kuldjuktau and Auminzatau Ranges, in the central Kyzylkum region, Uzbekistan

A new quantitative mineral resource assessment for tungsten skarn was conducted for the Auminzatau and Kuldjuktau mountain ranges in Central Uzbekistan, along with qualitative assessments of orogenic gold, rare earth elements (REEs), amorphous graphite, and uranium. By integrating a variety of geological, geochemical, geophysical, and remote sensing data sets, estimates of undiscovered tungsten skarn deposits in permissive tracts are combined with grade and tonnage distributions of known deposits to generate probabilistic estimates of undiscovered resources. Undiscovered deposits in Auminzatau are estimated to contain median resources of 98 thousand metric tons (kt) of WO 3 with a 70 percent (%) probability of at least 28 kt and a 10% probability of at least 468 kt, of which 16 kt to 293 kt may be economic to extract. In Kuldjuktau, the undiscovered deposits are estimated to contain median resources of 27 kt of WO 3 with a 60% probability of at least 12 kt and a 10% probability of at least 208 kt, of which 5 kt to 132 kt may be economic to extract. Our results suggest that the Auminzatau–Kuldjuktau Mountains area is highly prospective for additional discovery of significant Au and U resources and has low prospectivity for discovery of significant REE and graphite resources.

Minerals

Marine phosphorites as potential resources for heavy rare earth elements and yttrium

Marine phosphorites are known to concentrate rare earth elements and yttrium (REY) during early diagenetic formation. Much of the REY data available are decades old and incomplete, and there has not been a systematic study of REY distributions in marine phosphorite deposits that formed over a range of oceanic environments. Consequently, we initiated this study to determine if marine phosphorite deposits found in the global ocean host REY concentrations of high enough grade to be of economic interest. This paper addresses continental-margin (CM) and open-ocean seamount phosphorites. All 75 samples analyzed are composed predominantly of carbonate fluorapatite and minor detrital and authigenic minerals. CM phosphorites have low total REY contents (mean 161 ppm) and high heavy REY (HREY) complements (mean 49%), while seamount phosphorites have 4–6 times higher individual REY contents (except for Ce, which is subequal; mean ΣREY 727 ppm), and very high HREY complements (mean 60%). The predominant causes of higher concentrations and larger HREY complements in seamount phosphorites compared to CM phosphorites are age, changes in seawater REY concentrations over time, water depth of formation, changes in pH and complexing ligands, and differences in organic carbon content in the depositional environments. Potential ore deposits with high HREY complements, like the marine phosphorites analyzed here, could help supply the HREY needed for high-tech and green-tech applications without creating an oversupply of the LREY.

Minerals

Mean composite fire severity metrics computed with Google Earth Engine offer improved accuracy and expanded mapping potential

Landsat-based fire severity datasets are an invaluable resource for monitoring and research purposes. These gridded fire severity datasets are generally produced with pre-and post-fire imagery to estimate the degree of fire-induced ecological change. Here, we introduce methods to produce three Landsat-based fire severity metrics using the Google Earth Engine (GEE) platform: the delta normalized burn ratio (dNBR), the relativized delta normalized burn ratio (RdNBR), and the relativized burn ratio (RBR). Our methods do not rely on time-consuming a priori scene selection and instead use a mean compositing approach in which all valid pixels (e.g. cloud-free) over a pre-specified date range (pre- and post-fire) are stacked and the mean value for each pixel over each stack is used to produce the resulting fire severity datasets. This approach demonstrates that fire severity datasets can be produced with relative ease and speed compared the standard approach in which one pre-fire and post-fire scene are judiciously identified and used to produce fire severity datasets. We also validate the GEE-derived fire severity metrics using field-based fire severity plots for 18 fires in the western US. These validations are compared to Landsat-based fire severity datasets produced using only one pre- and post-fire scene, which has been the standard approach in producing such datasets since their inception. Results indicate that the GEE-derived fire severity datasets show improved validation statistics compared to parallel versions in which only one pre-fire and post-fire scene are used. We provide code and a sample geospatial fire history layer to produce dNBR, RdNBR, and RBR for the 18 fires we evaluated. Although our approach requires that a geospatial fire history layer (i.e. fire perimeters) be produced independently and prior to applying our methods, we suggest our GEE methodology can reasonably be implemented on hundreds to thousands of fires, thereby increasing opportunities for fire severity monitoring and research across the globe.

Remote Sensing

Mapping vegetation index-derived actual evapotranspiration across croplands using the Google Earth Engine platform

Precise knowledge of crop water consumption is essential to better manage agricultural water use, particularly in regions where most countries struggle with increasing water and food insecurity. Approaches such as cloud computing and remote sensing (RS) have facilitated access, process, and visualization of big geospatial data to map and monitor crop water requirements. To find the most reliable Vegetation Index (VI)-based evapotranspiration (ETa) for croplands in drylands, we modeled and mapped ETa using empirical RS methods across the Zayandehrud river basin in Iran for two decades (2000–2019) on the Google Earth Engine platform using the Normalized Difference Vegetation Index (NDVI) and the Enhanced Vegetation Index 2 (EVI2). Developed ET-VI products in this study comprise three NDVI-based ETa (ET-NDVI*, ET-NDVI* scaled , and ET-NDVI Kc ) and an EVI2-based ETa (ET-EVI2). We (a) applied, for the first time, the ET-NDVI* method to croplands as a crop-independent index and then compared its performance with the ET-EVI2 and crop ET, and (b) assessed the ease and feasibility of the transferability of these methods to other regions. Comparing four ET-VI products showed that annual ET-EVI2 and ET-NDVI* scaled estimations were close. ET-NDVI Kc consistently overestimated ETa. Our findings indicate that ET-EVI2 and ET-NDVI Kc were easy to parametrize and adopt to other regions, while ET-NDVI* and ET-NDVI* scaled are site-dependent and sensitive to image acquisition time. ET-EVI2 performed robustly in arid and semi-arid regions making it a better tool. Future research should further develop and confirm these findings by characterizing the accuracy of VI-based ETa over croplands in drylands by comparing them with available ETa products and examining their performance using crop-specific comparisons.

Remote Sensing

Outlining potential biomarkers of exposure and effect to critical minerals: Nutritionally essential trace elements and the rare earth elements

Emerging and low-carbon technologies and innovations are driving a need for domestic sources, sustainable use, and availability of critical minerals (CMs)—those vital to the national and economic security of the United States. Understanding the known and potential health effects of exposures to such mineral commodities can inform prudent and environmentally responsible handling and harvesting. We review the occurrence, use, predominant exposure pathways, and adverse outcome pathways (AOP) for human and fish receptors of those CMs that are nutritionally essential trace metals (specifically, cobalt, chromium, manganese, nickel, and zinc), as well as the rare earth elements. Biological responses to some elements having comparable biogeochemistry can sometimes be similar. Candidate quantifiable biomarkers for assessing potential AOP are conveyed.

Toxics

Normalized rare earth elements in water, sediments, and wine: identifying sources and environmental redox conditions

The concentrations of the rare earth elements (REE) in surface waters and sediments, when normalized on an element-by-element basis to one of several rock standards and plotted versus atomic number, yield curves that reveal their partitioning between different sediment fractions and the sources of those fractions, for example, between terrestrial-derived lithogenous debris and seawater-derived biogenous detritus and hydrogenous metal oxides. The REE of ancient sediments support their partitioning into these same fractions and further contribute to the identification of the redox geochemistry of the sea water in which the sediments accumulated. The normalized curves of the REE that have been examined in several South American wine varietals can be interpreted to reflect the lithology of the bedrock on which the vines may have been grown, suggesting limited fractionation during soil development.

American Journal of Analytical Chemistry