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USGS2023

Multiresidue extraction of current-use pesticides from complex solid matrices using energized dispersive guided extraction with analysis by gas and liquid chromatography tandem mass spectroscopy

The development of sample processing techniques that recover a broad suite of pesticides from solid matrices, while mitigating coextracted matrix interferences, and reducing processing time is beneficial for high throughput analyses. The objective of this study was to evaluate the effectiveness of an automated extraction system for pesticide analyses in solid environmental samples. An Energized Dispersive Guided Extraction (EDGE) system was used to evaluate two different extraction solvents in optimizing the extraction of 210 pesticides and pesticide transformation products. A graphitized carbon cleanup step was implemented, and three elution solvents were evaluated separately for analyte recoveries. Recoveries between 70 and 130% were achieved for 167 compounds in a test soil using acetonitrile as an extraction solvent and carbon cleanup with acetonitrile and dichloromethane elutions. Nine field samples (soil, sediment, and biosolids) were extracted using the newly developed method and were compared with a previously validated pressurized liquid extraction (PLE) method using an Accelerated Solvent Extraction (ASE) system. Concentrations obtained from the two methods were comparable (linear R 2 > 0.999), suggesting similar performance between the EDGE and PLE extractions in complex matrices. The new method provided slightly better sensitivities in comparison to the PLE method, ranging from 0.09 to 2.56 ng g −1 . The method presented here significantly reduces extraction setup and runtimes while also minimizing the volume of carcinogenic solvents ( e.g. , dichloromethane) used in the laboratory and presents a sensitive multiresidue method for a wide range of pesticides in solid matrices.

Chemosphere↗

USGS2021

Long-term multidecadal data from a prairie-pothole wetland complex reveal controls on aquatic-macroinvertebrate communities

Interactions between climate and hydrogeologic settings contribute to the hydrologic and chemical variability among depressional wetlands, which influences their aquatic communities. These interactions and resulting variability have led to inconsistent results in terms of identifying reliable predictors of aquatic-macroinvertebrate community composition for depressional wetlands. This is especially true in the Prairie Pothole Region of North America where, in addition to pronounced climate variability, studies are often confounded by fish introductions. We used environmental monitoring data collected over a 24-year period from a complex of sixteen depressional wetlands and structural equation modeling techniques that incorporated theoretical and empirical relationships outlined in the Wetland Continuum to identify key environmental (climate and hydrogeologic setting) and biotic (competition and predation) drivers of aquatic-macroinvertebrate community composition for prairie-pothole wetlands. Uplands in the study area were primarily native prairie, thus, embedded wetlands were impacted minimally by agricultural influences. Additionally, study wetlands were predominately fishless. In the absence of the overwhelming influence of fishes, major drivers influencing aquatic-macroinvertebrate communities were revealed through the use of data spanning multidecadal-long climate cycles. We found variables related to the placement of wetlands along axes of the Wetland Continuum, e.g., hydrogeologic setting (relative wetland elevation) and hydroclimatic setting (proportion of wetland ponded), to be influential drivers of within-wetland habitat characteristics, such as the proportion of open-water area, which in turn was the strongest predictor of macroinvertebrate community composition. In contrast, predatory invertebrate and salamander abundance and non-predatory invertebrate biomass (i.e., predation and competition) were found to have minimal influence on community composition.

North Dakota↗

USGS2024

Complex landslide patterns explained by local intra-unit variability of stratigraphy and structure: Case study in the Tyee Formation, Oregon, USA

Lithology and geologic structure are important controls on landslide susceptibility and are incorporated into many regional landslide hazard models. Typically, metrics for mapped geologic units are used as model input variables and a single set of values for material strength are assumed, regardless of spatial heterogeneities that may exist within a map unit. Here we describe how differences in bedding thickness, grain size, inferred uniaxial compressive strength, and bedding dip control the inherent susceptibility of slopes to deep-seated failure within a single mapped geologic unit - the Tyee Formation of Oregon, USA. The Tyee, which covers over 15,000 km2 and underlies much of the Oregon Coast Range, comprises gently folded alternating beds of sandstone and siltstone deposited as turbidites, forming a 2-km thick Eocene submarine fan which has been uplifted and exhumed through the Cenozoic. Deep-seated landslides are widespread in the Tyee, but form a complex spatial pattern such that landslide density ranges from 0 to 24% of the total landscape area. These slides are often extensive and sufficiently deep to reduce local hillslope gradients, resulting in a strong negative correlation between landslide density and mean local slope. Mean annual precipitation and predicted strong ground motions from Cascadia earthquake scenarios also fail to explain the spatial distribution of deep-seated landslides. Consequently, landslide stability models, which are strongly influenced by landscape slope, pore-water pressure, and seismic acceleration, yield landslide susceptibility maps which are broadly anti-correlated with mapped deep-seated landslide density. Through a multivariable linear regression model, we show that much of the variance in deep-seated landslide density can be explained by variability of intra-unit stratigraphic and structural characteristics, which we measure at 128 sites across two study areas totaling ∼3000 km2. Our results suggest bedding dip is only weakly correlated to landslide density, but strongly influences landslide failure style. Subtle increases in bedding dip, even in the gently folded Tyee Formation, result in a substantially higher likelihood of a landslide being cataclinal, or parallel to bedding. Overall, we find a slight majority of landslides fail within these cataclinal slopes, and that these landslides tend to be larger than non-cataclinal landslides. We also show that the lithological and structural properties that influence landslide susceptibility are distinct for these two populations of landslides. Our results demonstrate how localized, intra-unit, geologic variability can exert strong control on landslide susceptibility and failure style. This suggests that in some locations, landslide hazard models could be significantly improved by incorporating detailed, spatially variable, geologic properties rather than relying solely on generalized geologic map units.

Oregon↗

USGS2012

Complexity of human and ecosystem interactions in an agricultural landscape

The complexity of human interaction in the commercial agricultural landscape and the resulting impacts on the ecosystem services of water quality and quantity is largely ignored by the current agricultural paradigm that maximizes crop production over other ecosystem services. Three examples at different spatial scales (local, regional, and global) are presented where human and ecosystem interactions in a commercial agricultural landscape adversely affect water quality and quantity in unintended ways in the Delta of northwestern Mississippi. In the first example, little to no regulation of groundwater use for irrigation has caused declines in groundwater levels resulting in loss of baseflow to streams and threatening future water supply. In the second example, federal policy which subsidizes corn for biofuel production has encouraged many producers to switch from cotton to corn, which requires more nutrients and water, counter to national efforts to reduce nutrient loads to the Gulf of Mexico and exacerbating groundwater level declines. The third example is the wholesale adoption of a system for weed control that relies on a single chemical, initially providing many benefits and ultimately leading to the widespread occurrence of glyphosate and its degradates in Delta streams and necessitating higher application rates of glyphosate as well as the use of other herbicides due to increasing weed resistance. Although these examples are specific to the Mississippi Delta, analogous situations exist throughout the world and point to the need for change in how we grow our food, fuel, and fiber, and manage our soil and water resources.

Arkansas, Louisiana, Mississippi, Missouri↗

USGS2012

Automating calibration, sensitivity and uncertainty analysis of complex models using the R package Flexible Modeling Environment (FME): SWAT as an example

Parameter optimization and uncertainty issues are a great challenge for the application of large environmental models like the Soil and Water Assessment Tool (SWAT), which is a physically-based hydrological model for simulating water and nutrient cycles at the watershed scale. In this study, we present a comprehensive modeling environment for SWAT, including automated calibration, and sensitivity and uncertainty analysis capabilities through integration with the R package Flexible Modeling Environment (FME). To address challenges (e.g., calling the model in R and transferring variables between Fortran and R) in developing such a two-language coupling framework, 1) we converted the Fortran-based SWAT model to an R function (R-SWAT) using the RFortran platform, and alternatively 2) we compiled SWAT as a Dynamic Link Library (DLL). We then wrapped SWAT (via R-SWAT) with FME to perform complex applications including parameter identifiability, inverse modeling, and sensitivity and uncertainty analysis in the R environment. The final R-SWAT-FME framework has the following key functionalities: automatic initialization of R, running Fortran-based SWAT and R commands in parallel, transferring parameters and model output between SWAT and R, and inverse modeling with visualization. To examine this framework and demonstrate how it works, a case study simulating streamflow in the Cedar River Basin in Iowa in the United Sates was used, and we compared it with the built-in auto-calibration tool of SWAT in parameter optimization. Results indicate that both methods performed well and similarly in searching a set of optimal parameters. Nonetheless, the R-SWAT-FME is more attractive due to its instant visualization, and potential to take advantage of other R packages (e.g., inverse modeling and statistical graphics). The methods presented in the paper are readily adaptable to other model applications that require capability for automated calibration, and sensitivity and uncertainty analysis.

Environmental Modelling and Software↗

USGS2018

Sulfur cycle in the Valles Caldera volcanic complex, New Mexico – Letter 1: Sulfate sources in aqueous system, and implications for S isotope record in Gale Crater on Mars

Initial in situ sulfur (S) isotope measurements of the Martian bedrock in Gale Crater have revealed an unexpectedly wide range of δ 34 S values (−47 to +28%). Generally, it is unclear what processes could have contributed to these large isotope fractionations. Therefore, we studied S sources and aqueous SO 2− 4 cycling in the Valles Caldera volcanic complex, New Mexico to better understand S isotope fractionations related to S degassing, hydrothermal activity, and low-temperature processes in aqueous environment. Overall, our study demonstrates that volcanic systems show large spatial heterogeneity in δ 34 S. Magmatic S sources are obvious in steam-dominated H 2 S degassing and precipitation of secondary minerals from hydrothermal fluids with low δ 34 S values of +0.9 ±3%. Locally, however, hydrothermal processes have resulted in more negative δ 34 S values in sulfide minerals (−18 to −4%) and more positive δ 34 S values in sulfate minerals (−1 to +3%). Major aqueous SO 2− 4 sources are oxidation of H 2 S from modern hydrothermal gas emission, and oxidation and dissolution of sulfide and sulfate minerals present in the hydrothermally altered bedrock and crater-lake sediments. The δ 34 S of aqueous SO 2− 4 in surface water and groundwater varies widely (−8 to +5%) and is similar to major S endmembers that undergo oxidation and/or dissolution by active hydrological system. Minor SO 2− 4 contributions with more positive δ 34 S values (+9 to +14%) come from deeply circulating geothermal fluids and negligible amounts from atmospheric deposition (+5 to +7% in snow). Elevated SO 2− 4 contents are mainly associated with modern and past H 2 S emissions and oxidations near the surface. On regional scale, however, most of the intracaldera bedrock is S-depleted, thus the SO 2− 4 contents are usually low in the surface aquatic system and younger sedimentary lake deposits formed at times of negligible near surface hydrothermal activity. In general, magmatic-hydrothermal processes apparently cause the largest δ 34 S variation in S-bearing minerals on volcanic terrains. Therefore, we infer that the measured wide range of δ 34 S values in the Gale sediments by the Curiosity rover on Mars can be explained by S isotope composition of magmatic-hydrothermal sulfide and sulfate minerals that were present in the initial igneous/volcanic rocks prior to crater formation. Later aqueous processes involved oxidation and dissolution of S minerals initially present in these rocks and led to subsequent formation of diagenetic fluids and alteration products enriched in SO 2− 4 with relatively large δ 34 S variation. Additionally, physical erosion, transport and deposition of detrital hydrothermal S minerals from igneous/volcanic rocks might be in part responsible for the measured wide range of δ 34 S in Gale Crater. These unique S isotope results, measured in situ on another planet for the first time, imply the importance of magmatic-hydrothermal fluids in S transport on early Mars and their subsequent alteration in low-temperature aqueous environments.

New Mexico↗

USGS2023

Tracing magmatic genesis and evolution through single zircon crystals from successive supereruptions from the Socorro Caldera Complex, USA

Large volume rhyolitic ignimbrite volcanism is a significant contributor to the evolving crust. The introduction of high-silica material into the upper crust, differentiation within the middle crust, and partial melting in the lower crust contributes to geochemical and isotopic evolution of the crust. Developing accurate models for the genetic evolution of these events is dependent upon geochronology to determine rates of magmatic processes as model constraints. We present new zircon high-precision CA-ID-TIMS U-Pb geochronology and MC-ICPMS Hf isotope geochemistry for four ignimbrites from the nested caldera complex near Socorro, New Mexico (USA), within the Mogollon-Datil volcanic field. In agreement with past 40 Ar- 39 Ar data, interpretations of new U-Pb data indicate eruptions from the Socorro caldera cluster were pulsed. These pulses were intermittently spaced, and a volcanic hiatus following the Hells Mesa Tuff at 33.442 ± 0.015 Ma was interrupted by four successive eruptions, beginning with the La Jencia Tuff at 29.158 ± 0.025 Ma and finishing with the South Canyon Tuff at 28.066 ± 0.021 Ma. Zircon age spectra became more protracted with each eruption, exhibiting age dispersions ranging from 0.347 Myr in the Hells Mesa Tuff to 4.502 Myr in the South Canyon Tuff. The increased dispersion is paralleled by an increase in the proportion of normally discordant grains, indicative of xenocryst incorporation. These protracted age spectra are not necessarily a function of thermal maturation in the middle to upper crust due to long-lived magma chambers. Rather, they are likely the result of increased melting of zircon-bearing lower crust due to deep thermal maturation from repeated juvenile magma injections based on the incorporation of zircon material at the melt source. In contrast, the Hf isotope record is volumetrically dominated by autocrystic zircon domains and becomes more radiogenic through time, recording juvenile replenishment of the lower crust during progressive melting. Together, these data record the protracted evolution of the lower crust sampled by ignimbrites, lend insight into that evolution, and emphasize the need for detailed interpretation of high-precision datasets to advance volcanic models.

Arizona, New Mexico↗

USGS2014

Angler effort and catch within a spatially complex system of small lakes.

Spatial layout of waterbodies and waterbody size can affect a creel clerk’s ability to intercept anglers for interviews and to accurately count anglers, which will affect the accuracy and precision of estimates of effort and catch. This study aimed to quantify angling effort and catch across a spatially complex system of 19 small (<100 ha) lakes, the Fremont lakes. Total (±SE) angling effort (hours) on individual lakes ranged from 0 (0) to 7,137 (305). Bank anglers utilized 18 of the 19 lakes, and their mean (±SE) trip lengths (hours) ranged from 0.80 (0.31) to 7.75 (6.75), depending on the waterbody. In contrast, boat anglers utilized 14 of the 19 lakes, and their trip lengths ranged from 1.39 (0.24) to 4.25 (0.71), depending on the waterbody. The most sought fishes, as indexed by number of lakes on which effort was exerted, were anything (17 of 19 lakes), largemouth bass Micropterus salmoides (15 of 19 lakes), and channel catfish Ictalurus punctatus (13 of 19 lakes). Bluegill Lepomis machrochirus , crappie Pomoxis spp., and largemouth bass were caught most frequently across the lakes, but catch rates varied considerably by lake. Of the 1,138 parties interviewed, most parties (93%) visited a single lake but there were 77 (7%) parties that indicated that they had visited multiple lakes during a single day. The contingent of parties that visited more than one lake a day were primarily (87%) bank anglers.. The number of lake-to-lake connections made by anglers visiting more than one waterbody during a single day was related to catch rates and total angling effort. The greater resolution that was achieved with a lake specific creel survey at Fremont lakes revealed a system of lakes with a large degree of spatial variation in angler effort and catch that would be missed by a coarser, system-wide survey that did not differentiate individual lakes.

Fisheries Research↗

USGS2005

Direct observation of heavy metal-mineral association from the Clark Fork River Superfund Complex: Implications for metal transport and bioavailability

Two sets of samples from riverbeds and adjacent floodplains, separated by 80 river kilometers, were collected from the Clark Fork River Superfund Complex, Montana, (the largest Superfund site in the United States), and studied primarily with transmission electron microscopy (TEM) with several supporting techniques to determine heavy metal-mineral association. Seven of the eight samples studied were strongly influenced by material that once resided in mining and smelting dumps and impoundments; this material was transported downstream sometime during the last century and a half from the Butte/Anaconda areas. The eighth sample was from a deeper floodplain level and dates to premining days. The TEM observations afford a direct look, down to the nanometer level, at secondary mineral formation as a result of the breakdown of sulfides and silicates in the acid environment of this massive mine-drainage system. In the shallow, oxic floodplain sediments, heavy metals of concern in this system (As, Cu, Pb, and Zn) are taken up by the formation of sulfates (particularly Pb in jarosite), as well as hydrous metal oxides (As, Cu, Pb, and Zn in and on ferrihydrite, and a possibly new vernadite-like mineral). The oxides are long-lived in these systems, as they were also found in the anoxic riverbeds. Metals are also taken up by the formation of sulfides in sulfate-reducing environments as observed in the formation of nanoclusters of chalcopyrite and sphalerite. In all samples, clays make up between 5 and 20% of the sediment and carry significant amounts of Cu and Zn. The hydrous oxides, secondary sulfides, and clays provide several routes for metal transport downstream over long distances. Besides the potential bioavailability of heavy metals exchanged on and off the hydrous metal oxides and clays, nanometer-sized sulfides may also be highly reactive in the presence of biologic systems. Copyright ?? 2005 Elsevier Ltd.

Geochimica et Cosmochimica Acta↗

USGS2019

Direct measurements of copper speciation in basaltic glasses: Understanding the relative roles of sulfur and oxygen in copper complexation in melts

Micro-analytical determination of copper (Cu) speciation in natural magmatic glasses, equilibrated below the nickel – nickel oxide (NNO) buffer, reveals that two copper species are commonly stabilized in such basaltic melts. X-ray absorption fine structure (XAFS) spectroscopic analysis of basaltic matrix glasses and melt inclusions (MI) from samples of mid-ocean ridge basalt (MORB), and from Nyamuragira, Etna and Kīlauea volcanoes show that both Cu(I)-sulfide and Cu(I)-oxide species are stabilized. The proportion of each species correlates with the measured sulfur (S) abundance of the glass. In glasses with S abundances greater than ~1000 ppm, Cu(I)-sulfide species are dominant, whereas in glasses with S abundances between 500 and 1000 ppm, both species are found to coexist. The Cu(I)-oxide species dominate at S concentrations below 500 ppm. In 1 atm S-free experimental glasses of basaltic composition that we analyzed, only Cu(I)-oxide species are detectable, regardless of the oxygen fugacity (fO2), even at relatively high fO2 values well above the NNO buffer. Our results demonstrate that XAFS techniques are highly sensitive in measuring Cu speciation in reduced (below NNO) basaltic glasses and that both oxide and sulfide complexes can be stabilized. The relative proportion of these two species is highly dependent on the concentration of S in the melt, and thus the Cu speciation in natural melts changes as S is lost from the melt by low pressure degassing.

Hawaii↗

USGS2018

Inferring presence of the western toad (Anaxyrus boreas) species complex using environmental DNA

Western toads (species complex comprised of Anaxyrus boreas , A. canorus , A. exsul , and A. nelsoni ) are widely distributed in the western United States but are declining, particularly in the southeastern extent of their range. The subspecies A. b. boreas is listed as a Species of Greatest Conservation Need in New Mexico, Colorado, Utah, and Wyoming. Reliable and sensitive methods for delineating distributions of western toads are critical for monitoring the status of the species and prioritizing conservation efforts. We developed two qPCR assays for detecting western toad DNA in environmental DNA samples. Both markers efficiently and reliably detect low concentrations of western toad DNA across their range in the conterminous U. S. without detecting non-target, sympatric species. To determine the optimal annual sampling period, we then tested these markers using repeated sampling in ponds where western toads were known to be present. Quantities of collected eDNA varied widely across samples, but sample-level detections across sites exceeded 80% for June sampling. In the later summer, detection dropped off sharply with only a single detection in the ten samples collected throughout August.

Global Ecology and Conservation↗

USGS2022

Complex demographic responses to contrasting climate drivers lead to divergent population trends across the range of a threatened alpine plant

Alpine plants are likely to be particularly vulnerable to climate change because of their restricted distributions and sensitivity to rapid environmental shifts occurring in high-elevation ecosystems. The well-studied Haleakalā silversword (‘āhinahina, Argyroxiphium sandwicense subsp. macrocephalum ) already exhibits substantial climate-associated population decline, and offers the opportunity to understand the ecological and demographic mechanisms that underlie ongoing and predicted range shifts. We use nearly four decades of demographic monitoring for this threatened Hawaiian species, in combination with other biological, ecological and climate data to explore demographic responses across its entire range. We construct and independently validate population models for two elevation zones representing the species’ lower trailing and higher stable regions. Differences in population growth rate (lambda) between trailing and stable regions were influenced most strongly by lower survival of juvenile and small adult size classes, as well as by lower recruitment and lower survival of seedlings and large adults in the trailing region. Furthermore, seed production appears to have decreased from the 1980’s to present in the trailing region, and is now significantly less than in the stable region. Lambda and several underlying vital rates were significantly associated with wetter dry season conditions in the lower trailing region, indicating water limitation. In the higher elevation stable region, in contrast, lambda and vital rates were associated with warmer air temperatures, indicating cold limitation. These contrasting demographic patterns and climate dependencies lead to a high probability of extinction over the next century in the lower region, where most plants occur, but zero probability of the same in the higher region, according to stochastic population projections. Drier future scenarios further increase the probability of extinction at low elevations. The combined results illustrate the complexity in the demographic response and future viability that can occur across the range of a single species.

Global Ecology and Conservation↗

USGS2013

Quantifying mineral abundances of complex mixtures by coupling spectral deconvolution of SWIR spectra (2.1-2.4 μm) and regression tree analysis

This paper presents a methodology for assessing mineral abundances of mixtures having more than two constituents using absorption features in the 2.1-2.4 μm wavelength region. In the first step, the absorption behaviour of mineral mixtures is parameterised by exponential Gaussian optimisation. Next, mineral abundances are predicted by regression tree analysis using these parameters as inputs. The approach is demonstrated on a range of prepared samples with known abundances of kaolinite, dioctahedral mica, smectite, calcite and quartz and on a set of field samples from Morocco. The latter contained varying quantities of other minerals, some of which did not have diagnostic absorption features in the 2.1-2.4 μm region. Cross validation showed that the prepared samples of kaolinite, dioctahedral mica, smectite and calcite were predicted with a root mean square error (RMSE) less than 9 wt.%. For the field samples, the RMSE was less than 8 wt.% for calcite, dioctahedral mica and kaolinite abundances. Smectite could not be well predicted, which was attributed to spectral variation of the cations within the dioctahedral layered smectites. Substitution of part of the quartz by chlorite at the prediction phase hardly affected the accuracy of the predicted mineral content; this suggests that the method is robust in handling the omission of minerals during the training phase. The degree of expression of absorption components was different between the field sample and the laboratory mixtures. This demonstrates that the method should be calibrated and trained on local samples. Our method allows the simultaneous quantification of more than two minerals within a complex mixture and thereby enhances the perspectives of spectral analysis for mineral abundances.

Geoderma↗

USGS2005

Complex channel responses to changes in stream flow and sediment supply on the lower Duchesne River, Utah

Channel responses to flow depletions in the lower Duchesne River over the past 100 years have been highly complex and variable in space and time. In general, sand-bed reaches adjusted to all perturbations with bed-level changes, whereas the gravel-bed reaches adjusted primarily through width changes. Gravel-bed reaches aggraded only when gravel was supplied to the channel through local bank erosion and degraded only during extreme flood events. A 50% reduction in stream flow and an increase in fine sediment supply to the study area occurred in the first third of the 20th century. The gravel-bed reach responded primarily with channel narrowing, whereas bed aggradation and four large-scale avulsions occurred in the sand-bed reaches. These avulsions almost completely replaced a section of sinuous channel about 14 km long with a straighter section about 7 km long. The most upstream avulsion, located near a break in valley slope and the transition from a gravel bed upstream and a sand bed downstream, transformed a sinuous sand-bed reach into a braided gravel-bed reach and eventually into a meandering gravel-bed reach over a 30-year period. Later, an increase in flood magnitudes and durations caused widening and secondary bed aggradation in the gravel-bed reaches, whereas the sand-bed reaches incised and narrowed. Water diversions since the 1950s have progressively eliminated moderate flood events, whereas larger floods have been less affected. The loss of frequent flooding has increased the duration and severity of drought periods during which riparian vegetation can establish along the channel margins. As a result, the channel has gradually narrowed throughout the study area since the late 1960s, despite the occasional occurrence of large floods. No tributaries enter the Duchesne River within the study area, so all reaches have experienced identical changes in stream flow and upstream sediment supply. ?? 2004 Elsevier B.V. All rights reserved.

Geomorphology↗

USGS2020

The roles of flood magnitude and duration in controlling channel width and complexity on the Green River in Canyonlands, Utah, USA

Predictions of river channel adjustment to changes in streamflow regime based on relations between mean channel characteristics and mean flood magnitude can be useful to evaluate average channel response. However, because these relations assume equilibrium sediment transport, their applicability to cases where streamflow and sediment transport are decoupled may be limited. These general relations also lack the specificity that is required to connect specific characteristics of the streamflow and sediment regime with the dynamics of channel morphological change that create channel complexity, which is often of ecological interest. We integrate historical records of channel change, observations of scour and fill during a snowmelt flood, measurements of sediment transport, and predictions from a two-dimensional streamflow model to describe how annual peak flow magnitude and peak-flow duration interact with the upstream sediment supply to control channel form for a 15-km study reach on the regulated Green River in Canyonlands National Park, Utah. Two major decadal-scale episodes of channel narrowing have occurred within the study area. For each of these episodes, the reduction in average channel width was consistent with the change predicted by hydraulic geometry relations as a function of average flood magnitude. However, channel narrowing occurred during periods of exceptionally low annual floods. The most recent episode of channel narrowing occurred between 1988 and 2009, during low-flow cycles when the 5-yr mean peak flow was less than 60% of the long-term (1959–2016) mean peak flow. These findings, together with findings from previous studies, demonstrate that decreases in peak-flow magnitude caused by streamflow regulation, climate change, or a combination of those factors have driven episodes of channel narrowing on the Green River. Observations of streamflow, sediment-transport, and morphologic change coupled with predictions from a two-dimensional streamflow model indicate that peak flow magnitudes of at least 75% of the long-term mean peak flow are required to transport bed-material sand in suspension in all regions of the multi-thread channel and that the ~2-month duration of the snowmelt flood played an important role in creating conditions necessary to maintain channel conveyance. These results indicate that detailed characterizations of channel response such as these are needed to predict how river channels will respond to changes in streamflow regime that affect annual peak flow magnitude and duration.

Utah↗

USGS2024

Ore mineralization in the Mofete and San Vito geothermal fields, Campi Flegrei volcanic complex, Naples, Italy

The Mofete and San Vito geothermal fields, located west of Naples, Italy, are part of the Campi Flegrei volcanic complex. In the 1970s, exploratory wells were drilled to a depth of ~3000 m in an attempt to locate high-enthalpy fluids for potential power production. Drill core samples from Mofete wells (MF1, MF2, and MF5) and from San Vito wells (SV1 and SV3) contain authigenic ore mineralization. Pyrite, pyrrhotite, and galena are abundant. Less common are chalcopyrite, sphalerite, arsenopyrite, and scheelite; rare are millerite, violarite, native bismuth, tellurobismuthite, cassiterite, molybdenite, and acanthite. Mineral chemistry was determined by electron microprobe wavelength dispersive spectroscopy aided by a scanning electron microscope equipped with energy-dispersive spectroscopy. The mineral assemblage suggests a low sulfidation environment and the absence of pyrrhotite in the MF1 well and upper part of the SV1 well indicates variable sulfur activity. Both molybdenite and scheelite were identified in samples SV1–2860 and SV3–2353 and scheelite in the SV3 well is zoned with variable Mo 6+ content; low Mo 6+ zones show blue cathodoluminescence, whereas, zones with high Mo 6+ content are yellow to brown. Zoned scheelite and the occurrence of both Mo-bearing minerals attest to the variability of ƒO 2 and ƒS 2 in the geothermal fluid.

Naples↗

USGS2020

Parsing complex terrain controls on mountain glacier response to climate forcing

Glaciers are a key indicator of changing climate in the high mountain landscape. Glacier variations across a mountain range are ultimately driven by regional climate forcing. However, changes also reflect local, topographically driven processes such as snow avalanching, snow wind-drifting, and radiation shading as well as the initial glacier conditions such as hypsometry and ice thickness. Here we assess the role of these various terrain influences on change to Little Ice Age (LIA) glaciers in Glacier National Park, U.S.A . With available data for LIA and modern glacier areas, we estimate glacier volumes using simple ice flow assumptions, and topographically driven processes using terrain proxies. At the LIA glacial maxima there were 82 glaciers larger than 0.1 km 2 ranging from 0.11 to 4.97 km 2 . Over the course of the 20 th century, every single LIA glacier decreased in area and 60% (49 glaciers) diminished to below the 0.1 km 2 threshold. Glaciers with large initial area (>1.5 km 2 ) at the end of LIA persisted. Within the intermediate size class (0.5 km 2 < area < 1.5 km 2 ), LIA glacier persistence is poorly explained by initial glacier volume, ice thickness, or elevation. Instead, wind exposure is an important explanatory factor. Our analysis demonstrates the complex response of cirque glaciers to post-LIA climate change in this region: individual glaciers have not necessarily undergone equivalent and synchronous change. Nevertheless, that all glaciers in this mountain range experienced retreat demonstrates that local processes mediated adjustments of some glaciers, but completely decoupled none from the regional climate forcing.

Montana↗

USGS2005

Thermal state and complex geology of a heterogeneous salty crust of Jupiter's satellite, Europa

The complex geology of Europa is evidenced by many tectonic and cryomagmatic resurfacing structures, some of which are "painted" into a more visible expression by exogenic alteration processes acting on the principal endogenic cryopetrology. The surface materials emplaced and affected by this activity are mainly composed of water ice in some areas, but in other places there are other minerals involved. Non-ice minerals are visually recognized by their low albedo and reddish color either when first emplaced or, more likely, after alteration by Europan weathering processes, especially sublimation and alteration by ionizing radiation. While red chromophoric material could be due to endogenic production of solid sulfur allotropes or other compounds, most likely the red substance is an impurity produced by radiation alteration of hydrated sulfate salts or sulphuric acid of mainly internal origin. If the non-ice red materials or their precursors have a source in the satellite interior, and if they are not merely trace contaminants, then they can play an important role in the evolution of the icy crust, including structural differentiation and the internal dynamics. Here we assume that these substances are major components of Europa's cryo/hydrosphere, as some models have predicted they should be. If this is an accurate assumption, then these substances should not be neglected in physical, chemical, and biological models of Europa, even if major uncertainties remain as to the exact identity, abundance, and distribution of the non-ice materials. The physical chemical properties of the ice-associated materials will contribute to the physical state of the crust today and in the geological past. In order to model the influence of them on the thermal state and the geology, we have determined the thermal properties of the hydrated salts. Our new lab data reveal very low thermal conductivities for hydrated salts compared to water ice. Lower conductivities of salty ice would produce steeper thermal gradients than in pure ice. If there are salt-rich layers inside the crust, forming salt beds over the seafloor or a briny eutectic crust, for instance, the high thermal gradients may promote endogenic geological activity. On the seafloor, bedded salt accumulations may exhibit high thermochemical gradients. Metamorphic and magmatic processes and possible niches for thermophilic life at shallow suboceanic depths result from the calculated thermal profiles, even if the ocean is very cold. ?? 2004 Elsevier Inc. All rights reserved.

Icarus↗