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At least 433 records · Page 24Linked to original sources

Generalized potentiometric surface of the Arikaree aquifer, Pine Ridge Indian Reservation and Bennett County, South Dakota

INTRODUCTION The Pine Ridge Indian Reservation and Bennett County are located in southwest South Dakota. The Pine Ridge Indian Reservation includes all of Shannon County and the part of Jackson County south of the White River. Extensive Indian trust lands are in Bennett County. For purposes of this map, the Pine Ridge Indian Reservation and all of Bennett County are included in the study area (sheet 1). Ground water from wells and springs is the predominant source of public and domestic supply within the study area. The Arikaree aquifer is the largest source of ground water throughout this area. The Oglala Sioux Tribe is developing a ground-water management plan designed to “preserve, protect and maintain the quality of ground water for living and future members and non-members of the Oglala Sioux Indian Tribe within the internal and external boundaries of the Pine Ridge Reservation” (Michael Catches Enemy, Oglala Sioux Tribe Natural Resources Regulatory Agency, oral commun., 2007). Hydrologic information about the Arikaree aquifer is important to managing this resource. In 1998, the U.S. Geological Survey (USGS) began working in cooperation with the Oglala Sioux Tribe to develop a potentiometric map of the Arikaree aquifer in Jackson and Shannon Counties, with a primary component of that effort being a well inventory in those counties. In 2003, the study area was expanded to include Bennett County.

South Dakota

Inland waters

1. The total flux of carbon—which includes gaseous emissions, lateral flux, and burial—from inland waters across the conterminous United States (CONUS) and Alaska is 193 teragrams of carbon (Tg C) per year. The dominant pathway for carbon movement out of inland waters is the emission of carbon dioxide gas across water surfaces of streams, rivers, and lakes (110.1 Tg C per year), a flux not identified in the First State of the Carbon Cycle Report (SOCCR1; CCSP 2007). Second to gaseous emissions are the lateral fluxes of carbon through rivers to coastal environments (59.8 Tg C per year). Total carbon burial in lakes and reservoirs represents the smallest flux for CONUS and Alaska (22.5 Tg C per year) (medium confidence). 2. Based on estimates presented herein, the carbon flux from inland waters is now understood to be four times larger than estimates presented in SOCCR1. The total flux of carbon from inland waters across North America is estimated to be 507 Tg C per year based on a modeling approach that integrates high-resolution U.S. data and continental-scale estimates of water area, discharge, and carbon emissions. This estimate represents a weighted average of 24 grams of carbon per m2 per year of continental area exported and removed through inland waters in North America (low confidence). 3. Future research can address critical knowledge gaps and uncertainties related to inland water carbon fluxes. This chapter, for example, does not include methane emissions, which cannot be calculated as precisely as other carbon fluxes because of significant data gaps. Key to reducing uncertainties in estimated carbon fluxes is increased temporal resolution of carbon concentration and discharge sampling to provide better representations of storms and other extreme events for estimates of total inland water carbon fluxes. Improved spatial resolution of sampling also could potentially highlight anthropogenic influences on the quantity and quality of carbon fluxes in inland waters and provide information for land-use planning and management of water resources. Finally, uncertainties could likely be reduced if the community of scientists working in inland waters establishes and adopts standard measurement techniques and protocols similar to those maintained through collaborative efforts of the International Ocean Carbon Coordination Project and relevant governmental agencies from participating nations.

Book chapter

Hydrologic modeling and river corridor applications of HY_Features concepts

The WaterML2: Part 3 - Surface Hydrology Features (HY_Features) Conceptual Model was published by OGC in 2018. This report documents the use of HY_Features concepts in support of two key tasks: (1) local to continental hydrologic modeling; and (2) referencing river corridor data to hydrographic networks. The presented use cases are applicable in hydroscience research and assessments, water resources engineering practices, and drought and flood responses. Before the HY_Features conceptual model there was no internationally recognized standard for the design of software and data for the hydroscience and engineering community. This report presents progress towards a logical data model that interprets the abstract HY_Features concepts for use in geospatial workflows, modeling applications, and web data systems that integrate hydrologic data. The use cases addressed include: (1) hydrologic model control volume definition; (2) hydrologic network connectivity; (3) characterization of catchments with landscape and atmospheric data; (4) river corridor characterization; (5) hydrologic location; and (6) flow network location. Each use case is described briefly along with an analysis of the information requirements. This report presents a summary of the logical model designed to satisfy the needs of these use cases and a summary of updates and changes proposed for HY_Features. Changes for consideration by the HY_Features Standards Working Group include the following. Provide more clarity on the inherited properties and associations of features that "realize" the catchment and nexus concepts from HY_Features. Add nexus realization feature types to represent the outlet of catchments that are "frontal" (terminate to the ocean or a large waterbody) or "inland sinks." Add a "HY_Flowline" feature as a superclass of HY_Flowpath providing linear referencing on waterbodies that are not catchment realizations. Add an association or interface to support connection between surface catchments and hydrogeologic units.

OGC Public Engineering Report

Intrinsic and extrinsic regulation of water clarity in a large, floodplain-river ecosystem

Ecosystem processes in rivers are thought to be controlled more by extrinsic than intrinsic factors, that is, the result of processes that occur upstream or within their watersheds. However, large floodplain rivers have a diverse assemblage of aquatic areas spanning gradients of connectivity with the main channel and internal controls may at times regulate long-term dynamics. When and where internal controls are important has not been widely explored in rivers. The Upper Mississippi River System (UMRS) provides a unique opportunity to assess regulation of ecosystem processes in a large floodplain river as water clarity has increased in several reaches over the last two decades. To better understand when and where intrinsic variables (for example , aquatic vegetation and common carp) and extrinsic variables (for example , upstream main channel total suspended solids (TSS) concentration and discharge) regulate water clarity, we describe 24-year trends of TSS in six study reaches of the UMRS. We evaluated the degree to which trends were shared across aquatic areas within each study reach and identified potential drivers of long-term TSS dynamics. Results varied across and within UMRS reaches, but common carp abundance was the strongest predictor in nearly all study reaches. Several models indicated associations with both intrinsic and extrinsic factors, and the marginal model r 2 values (0.26–0.61) suggest that additional environmental factors may have influenced water clarity. Knowledge of the degree to which intrinsic and extrinsic processes regulate water clarity is important for understanding and managing large, floodplain rivers worldwide.

Ecosystems

Statistics for stochastic modeling of volume reduction, hydrograph extension, and water-quality treatment by structural stormwater runoff best management practices (BMPs)

The U.S. Geological Survey (USGS) developed the Stochastic Empirical Loading and Dilution Model (SELDM) in cooperation with the Federal Highway Administration (FHWA) to indicate the risk for stormwater concentrations, flows, and loads to be above user-selected water-quality goals and the potential effectiveness of mitigation measures to reduce such risks. SELDM models the potential effect of mitigation measures by using Monte Carlo methods with statistics that approximate the net effects of structural and nonstructural best management practices (BMPs). In this report, structural BMPs are defined as the components of the drainage pathway between the source of runoff and a stormwater discharge location that affect the volume, timing, or quality of runoff. SELDM uses a simple stochastic statistical model of BMP performance to develop planning-level estimates of runoff-event characteristics. This statistical approach can be used to represent a single BMP or an assemblage of BMPs. The SELDM BMP-treatment module has provisions for stochastic modeling of three stormwater treatments: volume reduction, hydrograph extension, and water-quality treatment. In SELDM, these three treatment variables are modeled by using the trapezoidal distribution and the rank correlation with the associated highway-runoff variables. This report describes methods for calculating the trapezoidal-distribution statistics and rank correlation coefficients for stochastic modeling of volume reduction, hydrograph extension, and water-quality treatment by structural stormwater BMPs and provides the calculated values for these variables. This report also provides robust methods for estimating the minimum irreducible concentration (MIC), which is the lowest expected effluent concentration from a particular BMP site or a class of BMPs. These statistics are different from the statistics commonly used to characterize or compare BMPs. They are designed to provide a stochastic transfer function to approximate the quantity, duration, and quality of BMP effluent given the associated inflow values for a population of storm events. A database application and several spreadsheet tools are included in the digital media accompanying this report for further documentation of methods and for future use. In this study, analyses were done with data extracted from a modified copy of the January 2012 version of International Stormwater Best Management Practices Database, designated herein as the January 2012a version. Statistics for volume reduction, hydrograph extension, and water-quality treatment were developed with selected data. Sufficient data were available to estimate statistics for 5 to 10 BMP categories by using data from 40 to more than 165 monitoring sites. Water-quality treatment statistics were developed for 13 runoff-quality constituents commonly measured in highway and urban runoff studies including turbidity, sediment and solids; nutrients; total metals; organic carbon; and fecal coliforms. The medians of the best-fit statistics for each category were selected to construct generalized cumulative distribution functions for the three treatment variables. For volume reduction and hydrograph extension, interpretation of available data indicates that selection of a Spearman’s rho value that is the average of the median and maximum values for the BMP category may help generate realistic simulation results in SELDM. The median rho value may be selected to help generate realistic simulation results for water-quality treatment variables. MIC statistics were developed for 12 runoff-quality constituents commonly measured in highway and urban runoff studies by using data from 11 BMP categories and more than 167 monitoring sites. Four statistical techniques were applied for estimating MIC values with monitoring data from each site. These techniques produce a range of lower-bound estimates for each site. Four MIC estimators are proposed as alternatives for selecting a value from among the estimates from multiple sites. Correlation analysis indicates that the MIC estimates from multiple sites were weakly correlated with the geometric mean of inflow values, which indicates that there may be a qualitative or semiquantitative link between the inflow quality and the MIC. Correlations probably are weak because the MIC is influenced by the inflow water quality and the capability of each individual BMP site to reduce inflow concentrations.

Scientific Investigations Report

Estimates of public-supply, domestic, and irrigation water withdrawal, use, and trends in the Upper Rio Grande Basin, 1985 to 2015

The Rio Grande flows approximately 670 miles from its headwaters in the San Juan Mountains of south-central Colorado to Fort Quitman, Texas, draining the Upper Rio Grande Basin (URGB) study area of 32,000 square miles that includes parts of Colorado, New Mexico, and Texas. Parts of the basin extend into the United Mexican States (hereafter “Mexico”), where the Rio Grande forms the international boundary between Texas and the State of Chihuahua, Mexico. The URGB was chosen as a focus area study (FAS) for the U.S. Geological Survey (USGS) National Water Census (NWC) as part of the WaterSMART initiative. The objective of the USGS NWC under WaterSMART is to focus on the technical aspects of providing information and tools to stakeholders so that they can make informed decisions on water availability. This report contains water-use withdrawal estimates of groundwater and surface water for public-supply, self-supplied domestic, and irrigation water use for years 1985–2015 at 5-year intervals for the 22 drainage basins at the subbasin 8-digit hydrologic unit code (HUC-8) level. Data for additional categories of self-supplied industrial, mining, livestock, aquaculture, thermoelectric, and hydroelectric water use are provided in the accompanying data release to illustrate total withdrawals for the URGB. The additional category data are provided in this report only for the year 2015. Deliveries of water from public-supply systems to domestic users are included and are the only water-delivery data presented in this report. Consumptive use for irrigation is reported for all HUC-8 subbasins for 2015 and for select HUC-8s in the other years beginning in 1985 (the irrigation category includes irrigation for both crop and golf). Water transported outside of the URGB (interbasin transfers) is not included as part of the withdrawals and are not accounted for in any category of use within the URGB. Estimated total withdrawals for all the water-use categories (including hydroelectric) in 2015 as reported in the USGS compilations in the URGB were 3,152.10 million gallons per day (Mgal/d). Surface water was the dominant source of water used in the URGB, providing about 71 percent of total withdrawals. Nearly all withdrawals were from freshwater sources; there was a small amount of saline groundwater that was used for public supply and self-supplied industrial, which were all reported in Texas. The proportions of total 2015 withdrawals from States in the URGB are 46 percent each in Colorado and New Mexico and 8 percent in Texas. A comparison of 2015 water withdrawals for the URGB—for the categories of public supply, self-supplied domestic, self-supplied industrial, thermoelectric, irrigation, livestock, mining, aquaculture, and hydroelectric—showed that irrigation is the dominant water use, at 74 percent of total withdrawals. Other water-use categories in the URGB that use about 1 percent or greater of the total water use by volume are public supply (9 percent) and self-supplied domestic and aquaculture (each about 1 percent). This report focuses on the higher volume, consumptively used categories of public supply, self-supplied domestic, and irrigation. A discussion on basin population provides context for the categories of public-supply and self-supplied domestic water use. The population in the part of the basin in the United States grew from 1.36 to 2.26 million people between 1985 and 2015. With the city of Ciudad Juarez, Chihuahua, Mexico, included, the total population of the URGB grew from an estimated 2.01 to 3.66 million people between 1985 and 2015. The largest concentrations of population are in New Mexico, Texas, and Chihuahua, with 98 percent of the total number of people in the basin in 1985 and 99 percent of the total in 2015 residing in these states. Albuquerque, El Paso, and Ciudad Juarez are the largest cities in the basin. Total withdrawals for public supply in the URGB averaged 277 Mgal/d from 1985 to 2015. About 60 percent of the URGB total public-supply withdrawals occurred in New Mexico, which averaged 170 Mgal/d. Groundwater provided 92 and 70 percent of the total withdrawals for public supply in 1985 and 2015, respectively. Deliveries to domestic users from public suppliers are reported for all drainage basins and years, and account for part of the total public-supply withdrawals. In the URGB, domestic deliveries from public suppliers increased from 1985 to 1995; since 2005, domestic deliveries from public supply have declined. The total populations served by public suppliers in the URGB increased by 90 percent from 1985 to 2015. In the URGB, more people were served by public-supply systems than were self-supplied, and the percentage of people on public-supply systems ranged from 81 to 92 percent from 1985 to 2015. Total domestic withdrawals in the URGB (deliveries plus self-supply withdrawals) ranged from 177.49 to 234.83 Mgal/d and peaked in 2005. Domestic use decreased from 2005 to 2010 by 17 percent and remained less than 200 Mgal/d in 2015. The per-capita daily use for the entire URGB fluctuated between the reporting years, but overall, domestic per-capita use across the basin has declined 46 percent from 145 gallons per capita daily (gpcd) in 1985 to 79 gpcd in 2015. Total irrigation withdrawals in the URGB had a mean value of 2,767.66 Mgal/d from 1985 to 2015 and withdrawals peaked in 1995 at 3,416.84 Mgal/d. Over the 30-year period, irrigation source water in the URGB has ranged from 69 to 84 percent surface water, and the most surface water diverted in the basin for irrigation was in 1995. Groundwater withdrawals for irrigation have fluctuated but overall decreased by 13 percent between 2005 and 2015. Slightly more than one-half of total irrigation withdrawals within the URGB occurred in Colorado, with a mean of 57 percent from 1985 to 2015. From the peak of water withdrawals in 1995 to the conclusion of this study in 2015, total irrigation withdrawals across the study area decreased by 32 percent. The total number of irrigated lands in the URGB from 1985 to 2015 had a mean of about 800 thousand acres, and more irrigated lands were consistently located in the headwaters of the URGB in the San Luis Valley, Colorado than the remainder of the study basin. In the 30-year period, Colorado had a mean of 68 percent of total irrigated lands whereas irrigated acres in New Mexico had a mean of 26 percent and the remaining 7 percent were in Texas. Since 2000, the number of irrigated acres in the URGB has fluctuated, but overall has decreased by 12 percent. More land was irrigated with surface systems (surface irrigation includes flood, furrow, and gated pipe systems, hereafter collectively termed “surface”) in the URGB than with other irrigation system types. Across the 30-year period, from 62 to 88 percent of total irrigated lands had surface-system irrigation, and surface systems covered a mean of 69 percent of the URGB’s acres. Microirrigation systems, predominantly in New Mexico and Texas, compose 0.2 percent or less of the irrigated acres in the basin and were first reported in 1995. From 1985 to 2015, the surface systems decreased in the basin by about 38 percent, and the number of acres of sprinkler and microirrigation systems increased. Acres irrigated by sprinkler systems (predominately center pivot systems) have increased 179 percent from about 99 thousand acres in 1985 to 275 thousand acres in 2015. In this dataset, the number of sprinkler acres surpassed the number of surface irrigated acres in 2000. Within the San Luis Valley in Colorado, the acreage of surface irrigation has decreased, and sprinkler irrigation has increased over the 30-year period. In the New Mexico part of the URGB, surface irrigation is reported as the dominant system type, where irrigation by surface systems accounts for 97–98 percent of how water is provided to crops. As in New Mexico, crops in Texas are irrigated primarily by surface systems. The mean of the mean simulated actual evapotranspiration (ETa) for crops in 2015 across the basin was highest for durum wheat at an estimated 36.00 inches per year (in/yr), and lowest for vegetables at an estimated 19.48 in/yr. Alfalfa and irrigated grass pastures mean ETa had a mean of 31.4 and 27.58 in/yr, respectively, for the basin. Pecans and peppers, both signature crops in the Rio Grande Basin, each had a mean ETa of 30.67 and 30.38 in/yr of mean. In general, mean ETa values for crops were lower in the HUCs of the Colorado San Luis Valley (13010001, 13010002, 13010003 and 13010004) which are more northerly and at higher elevations. The mean ETa for crops increased in the HUCs that are more southerly and at lower elevations in the basin.

New Mexico

Network global navigation satellite system surveys to harmonize American and Canadian datum for the Lake Champlain Basin

Historically high flood levels were observed during flooding in Lake Champlain and the Richelieu River from late April through May 2011. Flooding was caused by record spring precipitation and snowmelt from the third highest cumulative snowfall year on record, which included a warm, saturated late spring snowpack. Flood stage was exceeded for a total of 67 days from April 13 to June 19, 2011. During this flooding, shoreline erosion and lake flood inundation were exacerbated by wind-driven waves associated with local fetch and lake-wide seiche effects. In May 2011, a new water-surface-elevation record was set for Lake Champlain. Peak lake-level water-surface elevations varied at the three U.S. Geological Survey lake-level gages on Lake Champlain in 2011. The May 2011 peak water-surface elevations for Lake Champlain ranged from 103.20 feet above the National Geodetic Vertical Datum of 1929 at the northern end of Lake Champlain (at its outlet into the Richelieu River at Rouses Point, New York) to 103.57 feet above the National Geodetic Vertical Datum of 1929 at the southern end of the Lake in Whitehall, New York. The water-surface elevations for the Richelieu River in Canada are referenced to a different vertical datum than are those in Lake Champlain in the United States, which causes difficulty in assessing real-time flood water-surface elevations and comparing of flood peaks in the Lake Champlain Basin in the United States and Canada. On March 19, 2012, as a result of the flood event of April and May 2011, the Governments of Canada and the United States asked the International Joint Commission to draft a plan of study to examine the causes and the effects of the spring 2011 flooding on Lake Champlain and the Richelieu River and develop potential mitigation measures. Specific challenges noted by the International Lake Champlain-Richelieu River Technical Working Group (established by the International Joint Commission) included harmonization of vertical datums within the drainage basin. Harmonization of the vertical datum discrepancy is needed for flood assessment and future efforts to model the flow of water through the Lake Champlain Basin in the United States and Canada. In April 2015, the U.S. Geological Survey and Environment Canada began a joint field effort with the goal of obtaining precise elevations representing a common vertical datum for select reference marks used to determine water-surface elevations throughout Lake Champlain and the Richelieu River. To harmonize the datum difference between the United States and Canada, Global Navigation Satellite System surveys were completed at nine locations in the Lake Champlain Basin to collect simultaneous satellite data. These satellite data were processed to produce elevations for two reference marks associated with dams and seven reference marks associated with active water-level gages (lake gages in Lake Champlain and streamgages in the Richelieu River) to harmonize vertical datums throughout the Lake Champlain Basin. The Global Navigation Satellite System surveys were completed from April 14 to 16, 2015, at locations ranging from southern Lake Champlain near Whitehall, New York, to the northern end of the Richelieu River in Sorel, Quebec, at its confluence with the St. Lawrence River in Canada. Lake-gage water-surface elevations determined during the 3 days of surveys were converted to water-surface elevations referenced to the North American Vertical Datum of 1988 by using calculated offsets and historical water-surface elevations. In this report, an “offset” refers to the adjustment that needs to be applied to published data from a particular gage to produce elevation data referenced to the North American Vertical Datum of 1988. Offsets presented in this report can be used in the evaluation of water-surface elevations in a common datum for Lake Champlain and the Richelieu River. In addition, the water-level data referenced to the common datum (as determined from the offsets) may be used to calibrate flow models and support future modeling studies developed for Lake Champlain and the Richelieu River.

New York, Quebec, Vermont

Nitrate and pesticides in surficial aquifers and trophic state and phosphorus sources for selected lakes, eastern Otter Tail County, west-central Minnesota, 1993-96

Nitrate concentrations (as nitrogen) were analyzed in water from 73 wells completed in surficial aquifers. Water from about one-third of the wells had concentrations greater than 10 mg/L (milligrams per liter), the regulatory limit for drinking water established by the U.S. Environmental Protection Agency. Nitrate concentrations: (1) were greater in water from wells in agricultural settings than in nonagricultural settings; (2) were not greater in water from shallow wells (25 feet deep or less) in settings with rapid soil permeability than with moderate soil permeability, probably because the effects of permeability were offset by the effects of land use and well depth; and (3) were greater in water from shallow wells (25 feet deep or less) than from deep wells (greater than 25 feet deep). Triazine herbicides were detected in water from 23 of the 73 sampled wells by immunoassay tests. Most of these wells are in agricultural settings. Ten pesticides, which included seven triazine herbicide compounds, were detected in water from 19 of 25 wells analyzed by gas chromatography/mass spectrometry. Atrazine and deethylatrazine, a degradation product of atrazine, were detected in water from 18 and 16 wells, respectively. None of the detected pesticides had concentrations that exceeded their respective regulatory limits for drinking water established by the U.S. Environmental Protection Agency. Four lakes in the Otter Tail River Basin, which in downstream order are Little Pine, Big Pine, Rush, and Otter Tail Lakes, ranged in trophic state from upper oligotrophic to lower eutrophic. The Secchi disk transparencies were 4.0 to 7.4 feet, chlorophyll a concentrations (epilimnetic) were 4.4 to 28 micrograms per liter, and total phosphorus concentrations (epilimnetic) were less than 0.010 to 0.022 mg/L (except one concentration of 0.060 mg/L). The trophic state of these lakes may have become less eutrophic from upstream to downstream lakes. Major external sources of phosphorus to Big Pine Lake were the Otter Tail and Toad Rivers. The phosphorus load from these two streams during March 16, 1995, to March 15, 1996 was 10,400 pounds. The phosphorus load from the Toad River (5,730 pounds) was greater than from the Otter Tail River (4,670 pounds) even though streamflow from the Toad River was about 70 percent less than the Otter Tail River. Phosphorus removal from Big Pine Lake through the Otter Tail River outlet during the 1-year period was 8,460 pounds. The total annual accumulation of phosphorus, which includes an estimated 700 pounds from ground-water discharge, was 2,640 pounds. The accumulated phosphorus probably was utilized by phytoplankton or was absorbed by nonliving particulate matter that eventually settled into bottom sediments. Bottom sediments were an internal source of phosphorus to Little Pine and Big Pine Lakes. Increased total phosphorus concentrations (hypolimnetic) of 0.037 to 0.120 mg/L at depth during August 9-10, 1995, indicated phosphorus release from bottom sediments. The increased phosphorus probably was associated with anoxic conditions in the hypolimnion during summer stratification. Phosphorus at depth in Little Pine and Big Pine Lakes was mostly orthophosphate. During the fall turnover of the lakes, this orthophosphate may have circulated to near the lake surface and became an available nutrient for phytoplankton during the following growing season. The internal phosphorus load to Little Pine Lake may have been important because about three-fourths of the lake probably became stratified and anoxic in the hypolimnion. The internal phosphorus load to Big Pine Lake may not have been important because only a small portion of the lake became stratified and anoxic at depth.

Minnesota

Methods of collecting and interpreting ground-water data

Because ground water is hidden from view, ancient man could only theorize as to its sources of replenishment and its behavior. His theories held sway until the latter part of the 17th century, which marked the first experimental work to determine the source and movement of ground water. Thus founded, the science of ground-water hydrology grew slowly and not until the 19th century is there substantial evidence of conclusions having been based on observational data. The 20th century has witnessed tremendous advances in the science in the methods of field investigation and interpretation of collected data, in the methods of determining the hydrologic characteristics of water-bearing material, and in the methods of inventorying ground-water supplies. Now, as is true of many other disciplines, the science of ground-water hydrology is characterized by frequent advancement of new ideas and techniques, refinement of old techniques, and an increasing wealth of data awaiting interpretation. So that its widely scattered staff of professional hydrologists could keep abreast of new ideas and advances in the techniques of groundwater investigation, it has been the practice in the U.S. Geological Survey to distribute such information for immediate internal use. As the methods become better established and developed, they are described in formal publications. Six papers pertaining to widely different phases of ground-water investigation comprise this particular contribution. For the sake of clarity and conformity, the original papers have been revised and edited by the compiler.

Water Supply Paper

Lake-level variability and water availability in the Great Lakes

In this report, we present recorded and reconstructed (pre-historical) changes in water levels in the Great Lakes, relate them to climate changes of the past, and highlight major water-availability implications for storage, coastal ecosystems, and human activities. 'Water availability,' as conceptualized herein, includes a recognition that water must be available for human and natural uses, but the balancing of how much should be set aside for which use is not discussed. The Great Lakes Basin covers a large area of North America. The lakes capture and store great volumes of water that are critical in maintaining human activities and natural ecosystems. Water enters the lakes mostly in the form of precipitation and streamflow. Although flow through the connecting channels is a primary output from the lakes, evaporation is also a major output. Water levels in the lakes vary naturally on timescales that range from hours to millennia; storage of water in the lakes changes at the seasonal to millennial scales in response to lake-level changes. Short-term changes result from storm surges and seiches and do not affect storage. Seasonal changes are driven by differences in net basin supply during the year related to snowmelt, precipitation, and evaporation. Annual to millennial changes are driven by subtle to major climatic changes affecting both precipitation (and resulting streamflow) and evaporation. Rebounding of the Earth's surface in response to loss of the weight of melted glaciers has differentially affected water levels. Rebound rates have not been uniform across the basin, causing the hydrologic outlet of each lake to rise in elevation more rapidly than some parts of the coastlines. The result is a long-term change in lake level with respect to shoreline features that differs from site to site. The reconstructed water-level history of Lake Michigan-Huron over the past 4,700 years shows three major high phases from 2,300 to 3,300, 1,100 to 2,000, and 0 to 800 years ago. Within that record is a quasi-periodic rise and fall of about 160 ? 40 years in duration and a shorter fluctuation of 32 ? 6 years that is superimposed on the 160-year fluctuation. Recorded lake-level history from 1860 to the present falls within the longer-term pattern and appears to be a single 160-year quasi-periodic fluctuation. Independent investigations of past climate change in the basin over the long-term period of record confirm that most of these changes in lake level were responses to climatically driven changes in water balance, including lake-level highstands commonly associated with cooler climatic conditions and lows with warm climate periods. The mechanisms underlying these large hydroclimatic anomalies are not clear, but they may be related to internal dynamics of the ocean-atmosphere system or dynamical responses of the ocean-atmosphere system to variability in solar radiation or volcanic activity. The large capacities of the Great Lakes allow them to store great volumes of water. As calculated at chart datum, Lake Superior stores more water (2,900 mi3) than all the other lakes combined (2,539 mi3). Lake Michigan's storage is 1,180 mi3; Lake Huron's, 850 mi3; Lake Ontario's, 393 mi3; and Lake Erie's, 116 mi3. Seasonal lake-level changes alter storage by as much as 6 mi3 in Lake Superior and as little as 2.1 mi3 in Lake Erie. The extreme high and low lake levels measured in recorded lake-level history have altered storage by as much as 31 mi3 in Lake Michigan-Huron and as little as 9 mi3 in Lake Ontario. Diversions of water into and out of the lakes are very small compared to the total volume of water stored in the lakes. The water level of Lake Superior has been regulated since about 1914 and levels of Lake Ontario since about 1960. The range of Lake Superior water-level fluctuations and storage has not been altered greatly by regulation. However, fluctuations on Lake Ontario have been reduced from 6.6 ft preregulation

Circular

Comprehensive inter-laboratory calibration of reference materials for δ18O versus VSMOW using various on-line high-temperature conversion techniques

Internationally distributed organic and inorganic oxygen isotopic reference materials have been calibrated by six laboratories carrying out more than 5300 measurements using a variety of high-temperature conversion techniques (HTC) in an evaluation sponsored by the International Union of Pure and Applied Chemistry (IUPAC). To aid in the calibration of these reference materials, which span more than 125‰, an artificially enriched reference water ( δ 18 O of +78.91‰) and two barium sulfates (one depleted and one enriched in 18 O) were prepared and calibrated relative to VSMOW2 and SLAP reference waters. These materials were used to calibrate the other isotopic reference materials in this study, which yielded: Reference material δ 18 O and estimated combined uncertainty IAEA-602 benzoic acid +71.28 ± 0.36‰ USGS35 sodium nitrate +56.81 ± 0.31‰ IAEA-NO-3 potassium nitrate +25.32 ± 0.29‰ IAEA-601 benzoic acid +23.14 ± 0.19‰ IAEA-SO-5 barium sulfate +12.13 ± 0.33‰ NBS 127 barium sulfate +8.59 ± 0.26‰ VSMOW2 water 0‰ IAEA-600 caffeine −3.48 ± 0.53‰ IAEA-SO-6 barium sulfate −11.35 ± 0.31‰ USGS34 potassium nitrate −27.78 ± 0.37‰ SLAP water −55.5‰ The seemingly large estimated combined uncertainties arise from differences in instrumentation and methodology and difficulty in accounting for all measurement bias. They are composed of the 3-fold standard errors directly calculated from the measurements and provision for systematic errors discussed in this paper. A primary conclusion of this study is that nitrate samples analyzed for δ 18 O should be analyzed with internationally distributed isotopic nitrates, and likewise for sulfates and organics. Authors reporting relative differences of oxygen-isotope ratios ( δ 18 O) of nitrates, sulfates, or organic material should explicitly state in their reports the δ 18 O values of two or more internationally distributed nitrates (USGS34, IAEA-NO-3, and USGS35), sulfates (IAEA-SO-5, IAEA-SO-6, and NBS 127), or organic material (IAEA-601 benzoic acid, IAEA-602 benzoic acid, and IAEA-600 caffeine), as appropriate to the material being analyzed, had these reference materials been analyzed with unknowns. This procedure ensures that readers will be able to normalize the δ 18 O values at a later time should it become necessary. The high-temperature reduction technique for analyzing δ 18 O and δ 2 H is not as widely applicable as the well-established combustion technique for carbon and nitrogen stable isotope determination. To obtain the most reliable stable isotope data, materials should be treated in an identical fashion; within the same sequence of analyses, samples should be compared with working reference materials that are as similar in nature and in isotopic composition as feasible.

Rapid Communications in Mass Spectrometry

Global mineral resource assessment

Introduction In response to the growing demand for information on the global mineral-resource base, the U.S. Geological Survey (USGS) is conducting the Quantitative Global Mineral Resource Assessment Project (GMRAP), a cooperative international project, begun in 2002, to assess the world's undiscovered nonfuel mineral resources. Primary Objectives The USGS conducts national and global assessments of resources (mineral, energy, water, biologic) to provide science in support of decisionmaking. Mineral resource assessments provide a synthesis of available information about where mineral deposits are known and suspected in the Earth’s crust, what commodities may be present, and estimates of amounts of resources that may be present in undiscovered deposits. The Global Mineral Resource Assessment Project started in 2002 as a cooperative international effort to assess the world’s undiscovered nonfuel mineral resources. Primary objectives are to: Outline the regional locations and estimate the probable amounts of the world’s undiscovered resources of copper, platinum-group elements (PGE), and potash in selected types of mineral deposits to depths of 1 to 3 kilometers below the Earth’s surface. Provide the first globally consistent and comprehensive analysis of undiscovered nonfuel mineral resources to provide all nations with a regional and global context for evaluating their mineral resources, planning for new mineral exploration and anticipating the economic, environmental, and social impacts of mineral development, and making land use decisions. The project emphasizes the most important types of mineral deposits for world supply of copper, platinum-group elements (PGE) and nickel, and potash. Go to the Quantitative Global Mineral-Resource Assessments home page for more information.

Scientific Investigations Report

Methods of analysis and quality-assurance practices of the U.S. Geological Survey organic laboratory, Sacramento, California: Determination of pesticides in water by solid-phase extraction and capillary-column gas chromatography/mass spectrometry

Analytical method and quality-assurance practices were developed for a study of the fate and transport of pesticides in the Sacramento-San Joaquin Delta and the Sacramento and San Joaquin River. Water samples were filtered to remove suspended parti- culate matter and pumped through C-8 solid-phase extraction cartridges to extract the pesticides. The cartridges were dried with carbon dioxide, and the pesticides were eluted with three 2-milliliter aliquots of hexane:diethyl ether (1:1). The eluants were analyzed using capillary-column gas chromatography/mass spectrometry in full-scan mode. Method detection limits for analytes determined per 1,500-milliliter samples ranged from 0.006 to 0.047 microgram per liter. Recoveries ranged from 47 to 89 percent for 12 pesticides in organic-free, Sacramento River and San Joaquin River water samples fortified at 0.05 and 0.26 microgram per liter. The method was modified to improve the pesticide recovery by reducing the sample volume to 1,000 milliliters. Internal standards were added to improve quantitative precision and accuracy. The analysis also was expanded to include a total of 21 pesticides. The method detection limits for 1,000-milliliter samples ranged from 0.022 to 0.129 microgram per liter. Recoveries ranged from 38 to 128 percent for 21 pesticides in organic-free, Sacramento River and San Joaquin River water samples fortified at 0.10 and 0.75 microgram per liter.

California

Book review: Nonlinear ocean waves and the inverse scattering transform

Nonlinear Ocean Waves and the Inverse Scattering Transform is a comprehensive examination of ocean waves built upon the theory of nonlinear Fourier analysis. The renowned author, Alfred R. Osborne, is perhaps best known for the discovery of internal solitons in the Andaman Sea during the 1970s. In this book, he provides an extensive treatment of nonlinear water waves based on a nonlinear spectral theory known as the inverse scattering transform. The writing is exceptional throughout the book, which is particularly useful in explaining some of the more difficult mathematical concepts. Review info: N onlinear Ocean Waves and the Inverse Scattering Transform. B y Alfred R. Osborne, 2010. ISBN: 978-125286299, 917 pp.

Pure and Applied Geophysics

Differentiating transpiration from evaporation in seasonal agricultural wetlands and the link to advective fluxes in the root zone

The current state of science and engineering related to analyzing wetlands overlooks the importance of transpiration and risks data misinterpretation. In response, we developed hydrologic and mass budgets for agricultural wetlands using electrical conductivity (EC) as a natural conservative tracer. We developed simple differential equations that quantify evaporation and transpiration rates using flowrates and tracer concentrations atwetland inflows and outflows. We used two ideal reactormodel solutions, a continuous flowstirred tank reactor (CFSTR) and a plug flow reactor (PFR), to bracket real non-ideal systems. From those models, estimated transpiration ranged from 55% (CFSTR) to 74% (PFR) of total evapotranspiration (ET) rates, consistent with published values using standard methods and direct measurements. The PFR model more appropriately represents these nonideal agricultural wetlands in which check ponds are in series. Using a fluxmodel, we also developed an equation delineating the root zone depth at which diffusive dominated fluxes transition to advective dominated fluxes. This relationship is similar to the Peclet number that identifies the dominance of advective or diffusive fluxes in surface and groundwater transport. Using diffusion coefficients for inorganic mercury (Hg) and methylmercury (MeHg) we calculated that during high ET periods typical of summer, advective fluxes dominate root zone transport except in the top millimeters below the sediment–water interface. The transition depth has diel and seasonal trends, tracking those of ET. Neglecting this pathway has profound implications: misallocating loads along different hydrologic pathways; misinterpreting seasonal and diel water quality trends; confounding Fick's First Law calculations when determining diffusion fluxes using pore water concentration data; and misinterpreting biogeochemicalmechanisms affecting dissolved constituent cycling in the root zone. In addition,our understanding of internal root zone cycling of Hg and other dissolved constituents, benthic fluxes, and biological irrigation may be greatly affected.

Science of the Total Environment

Investigation of nitrogen transformations in a southern California constructed wastewater treatment wetland

A 9.9-ha combined habitat and wastewater treatment demonstration wetland was constructed and planted in the summer of 1994, at Eastern Municipal Water District’s (EMWD) Hemet/San Jacinto Regional Water Reclamation Facility (RWRF) in southern California. From January 1996 through September 1997, the marsh–pond–marsh wetland system was operated to polish an average of 3785 m 3 d −1 (1×10 6 gal day −1 ) of secondary-treated effluent from the RWRF. Nitrogen removal was a major objective of this wetland treatment. Weekly inflow/outflow water quality monitoring of the wetland was supplemented with biannual, 45-station synoptic surveys within the system to determine internal distribution patterns of the nitrogen species (total ammonia, nitrite, nitrate, and organic nitrogen), total organic carbon (TOC), and ultraviolet absorbance at 254 nm (UV 254 ). Synoptic surveys were carried out during May 22 and September 17, 1996, and May 6 and September 25, 1997 and the results were mapped using the ARC/INFO processing package and inverse distance weighted mathematical techniques. Distribution patterns of the various nitrogen species, TOC, and UV 254 within the wetland indicate that the nitrogen dynamics of the system are influenced both by variations in treatment plant loading, and, increasingly, by the degree of coverage and maturity of the emergent vegetation.

Ecological Engineering

Origin of the Mima Mounds, Thurston County region, Washington

There has been recent favorable consideration of the idea that the Mima mounds were made by gophers. The writer believes the evidence indicates that gophers function only in the reworking of the mound material, not in the primary construction. The plausibility of the earlier glacial or periglacial theory has been increased by recent knowledge of permafrost and of the deposits made by combined water and ice in cold climates. The gopher theory, as it has been applied to the Mima mounds, contains internal disharmonies and ignores significant field evidence supporting the earlier idea.

Journal of Geology

Effects of Climate Variability and Change on Groundwater Resources of the United States

Groundwater is an important part of the global fresh water supply and is affected by climate. U.S. Geological Survey (USGS) scientists are working with local, State, Federal, and international partners to understand how the availability and sustainability of groundwater resources in the United States will be affected by climate variability and change. This fact sheet describes climate variability and change, important groundwater resources of the Nation, and how USGS research is helping to answer critical questions about the effects of climate on groundwater.

Fact Sheet