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Determination of the δ 15 N of nitrate in solids; RSIL lab code 2894

The purpose of the Reston Stable Isotope Laboratory (RSIL) lab code 2894 is to determine the δ 15 N of nitrate (NO 3 - ) in solids. The nitrate fraction of the nitrogen species is dissolved by water (called leaching) and can be analyzed by the bacterial method covered in RSIL lab code 2899. After leaching, the δ 15 N of the dissolved NO 3 - is analyzed by conversion of the NO 3 - to nitrous oxide (N 2 O), which serves as the analyte for mass spectrometry. A culture of denitrifying bacteria is used in the enzymatic conversion of NO 3 - to N 2 O, which follows the pathway shown in equation 1: NO 3 - → NO 2 - → NO → 1/2 N 2 O (1) Because the bacteria Pseudomonas aureofaciens lack N 2 O reductive activity, the reaction stops at N 2 O, unlike the typical denitrification reaction that goes to N 2 . After several hours, the conversion is complete, and the N 2 O is extracted from the vial, separated from volatile organic vapor and water vapor by an automated -65 °C isopropanol-slush trap, a Nafion drier, a CO 2 and water removal unit (Costech #021020 carbon dioxide absorbent with Mg(ClO 4 ) 2 ), and trapped in a small-volume trap immersed in liquid nitrogen with a modified Finnigan MAT (now Thermo Scientific) GasBench 2 introduction system. After the N 2 O is released, it is further purified by gas chromatography before introduction to the isotope-ratio mass spectrometer (IRMS). The IRMS is a Thermo Scientific Delta V Plus continuous flow IRMS (CF-IRMS). It has a universal triple collector, consisting of two wide cups with a narrow cup in the middle; it is capable of simultaneously measuring mass/charge ( m/z ) of the N 2 O molecule 44, 45, and 46. The ion beams from these m/z values are as follows: m/z = 44 = N 2 O = 14 N 14 N 16 O; m/z = 45 = N 2 O = 14 N 15 N 16 O or 14 N 14 N 17 O; m/z = 46 = N 2 O = 14 N 14 N 18 O. The 17 O contributions to the m/z 44 and m/z 45 ion beams are accounted for before δ 15 N values are reported.

Techniques and Methods↗

Determination of the δ 15 N and δ 18 O of nitrate in solids; RSIL lab code 2897

The purpose of the Reston Stable Isotope Laboratory (RSIL) lab code 2897 is to determine the δ 15 N and δ 18 O of nitrate (NO 3 - ) in solids. The NO 3 - fraction of the nitrogen species is dissolved by water (called leaching) and can be analyzed by the bacterial method covered in RSIL lab code 2900. After leaching, the δ 15 N and δ 18 O of the dissolved NO 3 - is analyzed by conversion of the NO 3 - to nitrous oxide (N 2 O), which serves as the analyte for mass spectrometry. A culture of denitrifying bacteria is used in the enzymatic conversion of NO 3 - to N 2 O, which follows the pathway shown in equation 1: NO 3 - → NO 2 - → NO → 1/2 N 2 O (1) Because the bacteria Pseudomonas aureofaciens lack N 2 O reductive activity, the reaction stops at N 2 O, unlike the typical denitrification reaction that goes to N 2 . After several hours, the conversion is complete, and the N 2 O is extracted from the vial, separated from volatile organic vapor and water vapor by an automated -65 °C isopropanol-slush trap, a Nafion drier, a CO 2 and water removal unit (Costech #021020 carbon dioxide absorbent with Mg(ClO 4 ) 2 ), and trapped in a small-volume trap immersed in liquid nitrogen with a modified Finnigan MAT (now Thermo Scientific) GasBench 2 introduction system. After the N 2 O is released, it is further purified by gas chromatography before introduction to the isotope-ratio mass spectrometer (IRMS). The IRMS is a Thermo Scientific Delta V Plus continuous flow IRMS (CF-IRMS). It has a universal triple collector, consisting of two wide cups with a narrow cup in the middle; it is capable of simultaneously measuring mass/charge ( m/z ) of the N 2 O molecule 44, 45, and 46. The ion beams from these m/z values are as follows: m/z = 44 = N 2 O = 14 N 14 N 16 O; m/z = 45 = N 2 O = 14 N 15 N 16 O or 14 N 14 N 17 O; m/z = 46 = N 2 O = 14 N 14 N 18 O. The 17 O contributions to the m/z 44 and m/z 45 ion beams are accounted for before δ 15 N values are reported.

Techniques and Methods↗

Rapidly assessing social characteristics of drought preparedness and decision making: A guide for practitioners

Executive Summary This guide is intended to provide managers, decision makers, and other practitioners with advice on conducting a rapid assessment of the social dimensions of drought. Findings from a rapid assessment can provide key social context that may aid in decision making, such as when preparing a drought plan, allocating local drought resilience funding, or gathering the support of local agencies and organizations for collective action related to drought mitigation. Part I —In the introduction to Part I, we describe the unique problems associated with drought—particularly its slow onset and long duration, which make it difficult to define drought—and highlight five major types of drought (see Box 1). We introduce a few social dimensions of drought (such as economic and institutional perspectives), demonstrate how these dimensions can be interrelated, and describe a few of the modern challenges (such as transformational change and cascading risks) that practitioners face. We also provide background on the rapid assessment method, first describing it as a “snapshot” of the social landscape, then providing some key advantages of the method (it can be quicker and cheaper than more in-depth methods), and lastly describing how secondary data and other methods can help overcome some of the disadvantages of rapid assessments. Then, after summarizing the process of developing this guide, we outline the process of using the guide. Importantly, we compare the guide to a travel guide, which provides many different types of information and is best approached with specific interests in mind. Ultimately, we hope for this guide to be malleable enough that it can be helpful to researchers and practitioners in many different contexts, using many different research methods. Related to how to use the guide, we characterize the type of person who might be motivated to use this guide. We also specify key qualifications for a researcher conducting a rapid assessment, drawing particular attention to training on ethical considerations. We sketch out key considerations when choosing social dimensions of drought to focus on, and the type of data used for analysis. First, it is important to note that in this guide we provide nine important social dimensions of drought, but this is by no means a comprehensive list, and a researcher may find that other dimensions better fit their local context. Second, we provide some pros and cons to a narrow (focusing on just a few dimensions or at a smaller scale) versus broad research focus. Lastly, we describe the pros and cons of using primary versus secondary data (one strategy is to use both, sequentially) and qualitative versus quantitative data. Ultimately, Part I of this guide functions as an exploration of the various decisions a researcher will make when designing a rapid assessment. These decisions will inform the type of findings and other outcomes that result from the rapid assessment. Part II —Part II of this guide introduces nine key social dimensions of drought: defining the problem of drought, individual perceptions, social relationships, technology, economics and livelihoods, water governance, decision making, information, and social vulnerability. Each section provides background and key considerations related to a particular dimension, as well as ideas for how to explore the dimension via a rapid assessment. Part III —Part III of this guide provides two hypothetical examples of how one might use this guide to aid the practitioner in implementing the lessons learned here. In the first example, a watershed group uses two dimensions, defining the problem of drought and social relationships, to inform a community meeting about protecting fisheries from drought. In the second example, a resource manager uses the economics and livelihoods and social vulnerability dimensions to inform the development of a livestock grazing drought management plan.

Techniques and Methods↗

Documentation of the Surface-Water Routing (SWR1) Process for modeling surface-water flow with the U.S. Geological Survey Modular Ground-Water Model (MODFLOW-2005)

A flexible Surface-Water Routing (SWR1) Process that solves the continuity equation for one-dimensional and two-dimensional surface-water flow routing has been developed for the U.S. Geological Survey three-dimensional groundwater model, MODFLOW-2005. Simple level- and tilted-pool reservoir routing and a diffusive-wave approximation of the Saint-Venant equations have been implemented. Both methods can be implemented in the same model and the solution method can be simplified to represent constant-stage elements that are functionally equivalent to the standard MODFLOW River or Drain Package boundary conditions. A generic approach has been used to represent surface-water features (reaches) and allows implementation of a variety of geometric forms. One-dimensional geometric forms include rectangular, trapezoidal, and irregular cross section reaches to simulate one-dimensional surface-water features, such as canals and streams. Two-dimensional geometric forms include reaches defined using specified stage-volume-area-perimeter (SVAP) tables and reaches covering entire finite-difference grid cells to simulate two-dimensional surface-water features, such as wetlands and lakes. Specified SVAP tables can be used to represent reaches that are smaller than the finite-difference grid cell (for example, isolated lakes), or reaches that cannot be represented accurately using the defined top of the model. Specified lateral flows (which can represent point and distributed flows) and stage-dependent rainfall and evaporation can be applied to each reach. The SWR1 Process can be used with the MODFLOW Unsaturated Zone Flow (UZF1) Package to permit dynamic simulation of runoff from the land surface to specified reaches. Surface-water/groundwater interactions in the SWR1 Process are mathematically defined to be a function of the difference between simulated stages and groundwater levels, and the specific form of the reach conductance equation used in each reach. Conductance can be specified directly or calculated as a function of the simulated wetted perimeter and defined reach bed hydraulic properties, or as a weighted combination of both reach bed hydraulic properties and horizontal hydraulic conductivity. Each reach can be explicitly coupled to a single specific groundwater-model layer or coupled to multiple groundwater-model layers based on the reach geometry and groundwater-model layer elevations in the row and column containing the reach. Surface-water flow between reservoirs is simulated using control structures. Surface-water flow between reaches, simulated by the diffusive-wave approximation, can also be simulated using control structures. A variety of control structures have been included in the SWR1 Process and include (1) excess-volume structures, (2) uncontrolled-discharge structures, (3) pumps, (4) defined stage-discharge relations, (5) culverts, (6) fixed- or movable-crest weirs, and (7) fixed or operable gated spillways. Multiple control structures can be implemented in individual reaches and are treated as composite flow structures. Solution of the continuity equation at the reach-group scale (a single reach or a user-defined collection of individual reaches) is achieved using exact Newton methods with direct solution methods or exact and inexact Newton methods with Krylov sub-space methods. Newton methods have been used in the SWR1 Process because of their ability to solve nonlinear problems. Multiple SWR1 time steps can be simulated for each MODFLOW time step, and a simple adaptive time-step algorithm, based on user-specified rainfall, stage, flow, or convergence constraints, has been implemented to better resolve surface-water response. A simple linear- or sigmoid-depth scaling approach also has been implemented to account for increased bed roughness at small surface-water depths and to increase numerical stability. A line-search algorithm also has been included to improve the quality of the Newton-step upgrade vector, if possible. The SWR1 Process has been benchmarked against one- and two-dimensional numerical solutions from existing one- and two-dimensional numerical codes that solve the dynamic-wave approximation of the Saint-Venant equations. Two-dimensional solutions test the ability of the SWR1 Process to simulate the response of a surface-water system to (1) steady flow conditions for an inclined surface (solution of Manning's equation), and (2) transient inflow and rainfall for an inclined surface. The one-dimensional solution tests the ability of the SWR1 Process to simulate a looped network with multiple upstream inflows and several control structures. The SWR1 Process also has been compared to a level-pool reservoir solution. A synthetic test problem was developed to evaluate a number of different SWR1 solution options and simulate surface-water/groundwater interaction. The solution approach used in the SWR1 Process may not be applicable for all surface-water/groundwater problems. The SWR1 Process is best suited for modeling long-term changes (days to years) in surface-water and groundwater flow. Use of the SWR1 Process is not recommended for modeling the transient exchange of water between streams and aquifers when local and convective acceleration and other secondary effects (for example, wind and Coriolis forces) are substantial. Dam break evaluations and two-dimensional evaluations of spatially extensive domains are examples where acceleration terms and secondary effects would be significant, respectively.

Techniques and Methods↗

Vertical datum conversion process for the inland and coastal gage network located in the New England, Mid-Atlantic, and South Atlantic-Gulf hydrologic regions

Datum conversions from the National Geodetic Vertical Datum of 1929 to the North American Vertical Datum of 1988 among inland and coastal gages throughout the hydrologic regions of New England, the Mid-Atlantic, and the South Atlantic-Gulf have implications among river and storm surge forecasting, general commerce, and water-control operations. The process of data conversions may involve the application of a recovered National Geodetic Vertical Datum of 1929–North American Vertical Datum of 1988 offset, a simplistic datum transformation using VDatum or VERTCON software, or a survey, depending on a gaging network datum evaluation, anticipated uncertainties for data use among the cooperative water community, and methods used to derive the conversion. Datum transformations from National Geodetic Vertical Datum of 1929 to North American Vertical Datum of 1988 using VERTCON purport errors of ± 0.13 foot at the 95 percent confidence level among modeled points, claiming more consistency along the east coast. Survey methods involving differential and trigonometric leveling, along with observations using Global Navigation Satellite System technology, afford a variety of approaches to establish or perpetuate a datum during a survey. Uncertainties among leveling approaches are generally < 0.1 foot, and and Global Navigation Satellite System approaches may be categorized with uncertainties of ≤0.1 foot for a Level I quality category and ≥0.1 foot for Level II or III quality categories (defined by the U.S. Geological Survey) by observation and review of experienced practice. The conversion process is initiated with an evaluation of the inland and coastal gage network datum, beginning with altitude datum components and the history of those components queried through the U.S. Geological Survey Groundwater Site Inventory database. Subsequent edits to the Groundwater Site Inventory database may be required and a consensus reached among the U.S. Geological Survey Water Science Centers to identify the outstanding workload categorized as in-office datum transformations or offset applications versus out-of-office survey efforts. Datum conversions or datum establishment for the inland or coastal gaging network should meet datum uncertainty requirements among other Federal agencies. Datum uncertainty requirements are ±0.25 foot for U.S. Army Corps of Engineers water-control or construction projects and ±0.16 foot for Federal Emergency Management Agency field surveys and checkpoint surveys used for mapping. River level forecasts generally are defined as ± 0.10 foot among the National Oceanic and Atmospheric Administration–National Weather Service. Collaboration and communication among the cooperative water community is necessary during a datum conversion or datum change. Datum notification time-change requirements set by the National Oceanic and Atmospheric Administration–National Weather Service vary from 30 to 120 days, depending on datum conversion or datum-change case scenarios. Notification times associated with these case scenarios may be useful to the National Oceanic and Atmospheric Administration–National Weather Service and U.S. Army Corps of Engineers, because their daily operations are time sensitive, unlike the notification time change requirements of other entities that make up the cooperative water community. At the time of this writing, a future geopotential datum resulting from Gravity for the Redefinition of the American Vertical Datum is anticipated in 2022. A future version of VDatum and VERTCON is anticipated to provide a transformation among North American Vertical Datum of 1988 elevations to the new geopotential datum.

Techniques and Methods↗

Documentation of the Unsaturated-Zone Flow (UZF1) Package for modeling Unsaturated Flow Between the Land Surface and the Water Table with MODFLOW-2005

Percolation of precipitation through unsaturated zones is important for recharge of ground water. Rain and snowmelt at land surface are partitioned into different pathways including runoff, infiltration, evapotranspiration, unsaturated-zone storage, and recharge. A new package for MODFLOW-2005 called the Unsaturated-Zone Flow (UZF1) Package was developed to simulate water flow and storage in the unsaturated zone and to partition flow into evapotranspiration and recharge. The package also accounts for land surface runoff to streams and lakes. A kinematic wave approximation to Richards? equation is solved by the method of characteristics to simulate vertical unsaturated flow. The approach assumes that unsaturated flow occurs in response to gravity potential gradients only and ignores negative potential gradients; the approach further assumes uniform hydraulic properties in the unsaturated zone for each vertical column of model cells. The Brooks-Corey function is used to define the relation between unsaturated hydraulic conductivity and water content. Variables used by the UZF1 Package include initial and saturated water contents, saturated vertical hydraulic conductivity, and an exponent in the Brooks-Corey function. Residual water content is calculated internally by the UZF1 Package on the basis of the difference between saturated water content and specific yield. The UZF1 Package is a substitution for the Recharge and Evapotranspiration Packages of MODFLOW-2005. The UZF1 Package differs from the Recharge Package in that an infiltration rate is applied at land surface instead of a specified recharge rate directly to ground water. The applied infiltration rate is further limited by the saturated vertical hydraulic conductivity. The UZF1 Package differs from the Evapotranspiration Package in that evapotranspiration losses are first removed from the unsaturated zone above the evapotranspiration extinction depth, and if the demand is not met, water can be removed directly from ground water whenever the depth to ground water is less than the extinction depth. The UZF1 Package also differs from the Evapotranspiration Package in that water is discharged directly to land surface whenever the altitude of the water table exceeds land surface. Water that is discharged to land surface, as well as applied infiltration in excess of the saturated vertical hydraulic conductivity, may be routed directly as inflow to specified streams or lakes if these packages are active; otherwise, this water is removed from the model. The UZF1 Package was tested against the U.S. Geological Survey's Variably-Saturated Two-Dimensional Flow and Transport Model for a vertical unsaturated flow problem that includes evapotranspiration losses. This report also includes an example in which MODFLOW-2005 with the UZF1 Package was used to simulate a realistic surface-water/ground-water flow problem that includes time and space variable infiltration, evapotranspiration, runoff, and ground-water discharge to land surface and to streams. Another simpler problem is presented so that the user may use the input files as templates for new problems and to verify proper code installation.

Techniques and Methods↗

One-Water Hydrologic Flow Model: A MODFLOW based conjunctive-use simulation software

The U.S. Geological Survey’s (USGS) Modular Ground-Water Flow Model (MODFLOW-2005) is a computer program that simulates groundwater flow by using finite differences. The MODFLOW-2005 framework uses a modular design that allows for the easy development and incorporation of new features called processes and packages that work with or modify inputs to the groundwater-flow equation. A process solves a flow equation or set of equations. For example, the central part of MODFLOW is the groundwater-flow process that solves the groundwater-flow equation; the surface-water routing process is an additional process that solves the surface-water flow equation. Packages are code related to the groundwater-flow process. For example, the subsidence package modifies the groundwater-flow process by including aquifer compaction effects on flow. With the development of new packages and processes, the MODFLOW-2005 base framework diverged into multiple independent versions designed for specific simulation needs. This divergence limited each independent MODFLOW release to its specific purpose, so that there was no longer a single, comprehensive, general-purpose hydraulic-simulation framework. The MODFLOW One-Water Hydrologic Flow Model (MF-OWHM, also informally known as OneWater) is an integrated hydrologic flow model that combines multiple MODFLOW-2005 variants in one cohesive simulation software; changes were made to enable multiple capabilities in one code. This fusion of the MODFLOW-2005 versions resulted in a simulation software that can be used to address and analyze a wide class of conjunctive-use, water-management, water-food-security, and climate-crop-water scenarios. As a second core version of MODFLOW-2005, MF-OWHM maintains backward compatibility with existing MODFLOW-2005 versions, with features that include the following: Process-based simulation. Saturated groundwater flow (three-dimensional). Surface-water flow (one- and two-dimensional). Stream and river flow. Lake and reservoir storage. Landscape simulation and irrigated agriculture. Land-use and crop simulation. Root uptake of groundwater. Actual evapotranspiration. Estimated irrigation demand. Reservoir operations. Aquifer compaction and subsidence by vertical model-grid deformation. Seawater intrusion by a sharp-interface assumption. Karst-aquifer and fractured-bedrock flow. Turbulent and laminar-pipe network flow. Unsaturated groundwater flow (one-dimensional). Internal linkages among the processes that couple hydraulic head, flow, and deformation. Redesigned code for faster simulation, increased user-input options, easier model updates, and more robust error reporting than in previous models. MF-OWHM is a MODFLOW-2005 based integrated hydrologic model that can simulate and analyze varying environmental conditions to allow for the evaluation of management options from many components of human and natural water movement through a physically based, supply and demand framework. The term “integrated,” in the context of this report, refers to the tight coupling of groundwater flow, surface-water flow, landscape processes, aquifer compaction and subsidence, reservoir operations, and conduit (karst) flow. Another benefit of this integrated hydrologic model is that models developed to run by MODFLOW-2005, MODFLOW-NWT, MODFLOW-CFP, or MODFLOW-FMP can also be simulated with MF-OWHM. At the time of this report’s publication, MF-OWHM version 2 (MF-OWHM2) does not include a direct internal simulation of snowmelt, advanced mountainous watershed rainfall-runoff simulation, detailed shallow soil-moisture accounting, or atmospheric moisture content. Atmospheric moisture may be accounted for indirectly by, optionally, specifying a pan-evaporation rate, reference evapotranspiration, and precipitation. These features are not included to ensure that simulation runtime remains short enough to enable the use of automated methods of calibrating model parameters to field observations, which typically require many simulation model runs. The MF-OWHM approach is to include as much detail as possible to simulate hydrological processes, providing the simulation runtimes remain reasonable enough to allow for robust parameter estimation and model calibration. To represent both natural and human-influenced flow, MF-OWHM integrates physically based flow processes derived from MODFLOW-2005 in a supply and demand framework. From this integration, the physically based movement of groundwater, surface water, imported water, and precipitation serve as supply to meet consumptive demands associated with irrigated and non-irrigated agriculture, natural vegetation, and urban water uses. Water consumption is determined by balancing the available water supply with water demand, leading to the concept of a demand-driven, supply-constrained simulation. The MF-OWHM Supply-and-Demand Framework is especially useful for the analysis of agricultural water use, where there are often few data available to describe changes in land-use through time, such as crop type and distribution, and the associated changes in groundwater pumpage. This framework attempts to satisfy each land-use water demand with available water supplies—that is, groundwater uptake, precipitation, and irrigation. An option provided in MF-OWHM2 is to automatically increase groundwater pumping for irrigation, which often is unknown, by the calculated residual between demand and the other available sources of supply. From large- to small-scale applications, the physically based supply and demand framework provides key capabilities for simulating and analyzing historical, current, and future conjunctive-use of surface water and groundwater. To achieve the physically based supply and demand framework, the MODFLOW-2005 standard of no inter-package and -process communication was relaxed for MF-OWHM2. Traditional MODFLOW simulation models required that all packages and processes interact through the groundwater-flow equation or by removing the water flow from the simulation domain. For example, the MODFLOW-2005 representation of a groundwater well extracts water from the groundwater-flow equation (by subtraction) and removes it from the simulation domain. This feature is available in the MF-OWHM framework, but options have been added to allow the specification of a use or destination of pumped groundwater within the model domain, for example, it can be used for irrigation, managed aquifer recharge, or return-flow to streams.

Techniques and Methods↗

TracerLPM (Version 1): An Excel&reg; workbook for interpreting groundwater age distributions from environmental tracer data

TracerLPM is an interactive Excel&reg; (2007 or later) workbook program for evaluating groundwater age distributions from environmental tracer data by using lumped parameter models (LPMs). Lumped parameter models are mathematical models of transport based on simplified aquifer geometry and flow configurations that account for effects of hydrodynamic dispersion or mixing within the aquifer, well bore, or discharge area. Five primary LPMs are included in the workbook: piston-flow model (PFM), exponential mixing model (EMM), exponential piston-flow model (EPM), partial exponential model (PEM), and dispersion model (DM). Binary mixing models (BMM) can be created by combining primary LPMs in various combinations. Travel time through the unsaturated zone can be included as an additional parameter. TracerLPM also allows users to enter age distributions determined from other methods, such as particle tracking results from numerical groundwater-flow models or from other LPMs not included in this program. Tracers of both young groundwater (anthropogenic atmospheric gases and isotopic substances indicating post-1940s recharge) and much older groundwater (carbon-14 and helium-4) can be interpreted simultaneously so that estimates of the groundwater age distribution for samples with a wide range of ages can be constrained. TracerLPM is organized to permit a comprehensive interpretive approach consisting of hydrogeologic conceptualization, visual examination of data and models, and best-fit parameter estimation. Groundwater age distributions can be evaluated by comparing measured and modeled tracer concentrations in two ways: (1) multiple tracers analyzed simultaneously can be evaluated against each other for concordance with modeled concentrations (tracer-tracer application) or (2) tracer time-series data can be evaluated for concordance with modeled trends (tracer-time application). Groundwater-age estimates can also be obtained for samples with a single tracer measurement at one point in time; however, prior knowledge of an appropriate LPM is required because the mean age is often non-unique. LPM output concentrations depend on model parameters and sample date. All of the LPMs have a parameter for mean age. The EPM, PEM, and DM have an additional parameter that characterizes the degree of age mixing in the sample. BMMs have a parameter for the fraction of the first component in the mixture. An LPM, together with its parameter values, provides a description of the age distribution or the fractional contribution of water for every age of recharge contained within a sample. For the PFM, the age distribution is a unit pulse at one distinct age. For the other LPMs, the age distribution can be much broader and span decades, centuries, millennia, or more. For a sample with a mixture of groundwater ages, the reported interpretation of tracer data includes the LPM name, the mean age, and the values of any other independent model parameters. TracerLPM also can be used for simulating the responses of wells, springs, streams, or other groundwater discharge receptors to nonpoint-source contaminants that are introduced in recharge, such as nitrate. This is done by combining an LPM or user-defined age distribution with information on contaminant loading at the water table. Information on historic contaminant loading can be used to help evaluate a model's ability to match real world conditions and understand observed contaminant trends, while information on future contaminant loading scenarios can be used to forecast potential contaminant trends.

Techniques and Methods↗

Remote sensing-based 3D assessment of landslides: A review of the data, methods, and applications

Remote sensing (RS) techniques are essential for studying hazardous landslide events because they capture information and monitor sites at scale. They enable analyzing causes and impacts of ongoing events for disaster management. There has been a plethora of work in the literature mostly discussing (1) applications to detect, monitor, and predict landslides using various instruments and image analysis techniques, (2) methodological mechanics in using optical and microwave sensing, and (3) quantification of surface geological and geotechnical changes using 2D images. Recently, studies have shown that the degree of hazard is mostly influenced by speed, type, and volume of surface deformation. Despite available techniques to process lidar and image/radar-derived 3D geometry, prior works mostly focus on using 2D images, which generally lack details on the 3D aspects of assessment. Thus, assessing the 3D geometry of terrain using elevation/depth information is crucial to determine its cover, geometry, and 3D displacements. In this review, we focus on 3D landslide analysis using RS data. We include (1) a discussion on sources, types, benefits, and limitations of 3D data, (2) the recent processing methods, including conventional, fusion-based, and artificial intelligence (AI)-based methods, and (3) the latest applications.

Remote Sensing↗

Combining individual and close-kin mark–recapture to design an effective wildlife population survey

Close-kin mark–recapture (CKMR) is a promising approach for assessing population size of species that have been difficult to survey using more traditional methods. Here, we combine individual and close-kin mark–recapture in a single modeling framework (ICKMR) and provide an example of study design using this approach for Pacific walrus ( Odobenus rosmarus divergens ). We develop the ICKMR model and test it using simulated datasets, then use properties of the pseudo-likelihood to investigate the expected precision in estimates of abundance with different proposed survey designs. Our motivating example, the Pacific walrus, is an ice-associated marine mammal found in the Bering and Chukchi seas, where it is an important resource for Indigenous peoples. Pacific walrus abundance declined in the late 20th century, and it is currently a species of conservation concern due to potential impacts of climate change, particularly the loss of sea ice. To reduce uncertainty in population size estimates, researchers undertook a genetic mark–recapture sampling campaign from 2013 to 2017 and collected tissue samples from over 8000 individuals. Another campaign of a similar scale is ongoing (2023–2028). While sample collection was designed for individual mark–recapture, advances in CKMR methods and associated molecular techniques mean that these samples could also be suitable for CKMR. The advantages of CKMR over mark–recapture include an increased effective sample size (because each individual tags itself and its parents, siblings, and offspring) and additional insights into demographic quantities of interest. To make best use of genetic samples, we combine individual mark–recapture (IMR) with CKMR (ICKMR) and investigate whether different sampling strategies can increase precision in estimates of abundance. Our modeling approach includes special considerations for walrus life history, including a multi-year inter-birth interval. We found that expected coefficients of variation (CVs) of the ICKMR estimates of abundance, adult female survival, juvenile female survival, and proportion of breeding females are lower than those expected from IMR alone, and with ICKMR, fewer years of sampling can be conducted to obtain sufficient precision in estimates of abundance. This work demonstrates the utility of ICKMR and could be applicable across a variety of taxa.

Ecology↗

Near-real-time geochemical monitoring of Hawaiian volcanoes using energy dispersive X-ray fluorescence (EDXRF)

Syn-eruption geochemical monitoring during volcanic activity is an important component of integrated volcanic monitoring. Volcanoes on the Island of Hawai‘i are primarily monitored by the U.S. Geological Survey’s Hawaiian Volcano Observatory using instrumental networks, field surveys, satellite observations, and petrologic monitoring. In collaboration with the University of Hawaiʻi at Hilo, an important component of this monitoring is near-real-time (generally within 24 h of sample collection) bulk-rock geochemistry using benchtop energy-dispersive X-ray fluorescence (EDXRF). Bulk-rock geochemistry, coupled with additional petrologic and geophysical analyses, are used to track eruption dynamics to help facilitate identification and understanding of changes that signal the onset of potentially hazardous activity. In this paper, we present EDXRF methodology for bulk-rock analysis used to evaluate the 2018 Kīlauea and 2022 Mauna Loa eruptions and compare this technique to other geochemical methods. Syn-eruption geochemical monitoring using EDXRF provides reliable quantitative data that is important for understanding eruption dynamics. Critical to this process are calibrating the instrument for analysis over the same range of compositions expected during volcanic activity, compiling a relevant database from past eruptions on the same instrument for comparison, and having the physical infrastructure and trained personnel to complete the analyses in a timely fashion. In addition to the scientific goals of petrologic monitoring, near-real-time geochemical analysis in Hawaii provides important information about the nature of on-going eruptions and informs decision-makers and the public about associated evolving hazards.

Hawaii↗

Current advances in coastal wetland elevation dynamics: Introduction to the special issue

The thematic issue entitled, “Current Advances in Coastal Wetland Elevation Dynamics,” draws on topics from two special sessions at the CERF 2021 conference plus additional recent research describing scientific insights gained from the Surface Elevation Table–Marker Horizon (SET–MH) method and its application across the globe to quantify and understand subsurface process influences on wetland elevation change and wetland responses to sea-level rise. The findings group articles within each of five thematic topics. (1) A 30-year retrospective on the scientific insights gained on surface and shallow subsurface process dynamics. (2) Investigations of the subsurface soil process influences on wetland elevation. (3) How the scientific community applies the SET–MH method to quantify and understand wetland responses to RSLR and other environmental drivers such as altered hydrology and sediment supply. (4) How SET–MH data are used in long-term monitoring networks at different geographic scales. (5) Pairing the SET-MH method with (a) survey techniques to increase lateral coverage of wetland elevation trends and (b) geodetic measurements to increase vertical coverage of vertical land motion.

Estuaries and Coasts↗

Fluxes of metals to a manganese nodule: Radiochemical, chemical, structural, and mineralogical studies

Fluxes of metals to the top and bottom surfaces of a manganese nodule were determined by combining radiochemical ( 230 Th, 231 Pa, 232 Th, 238 U, 234 U) and detailed chemical data. The top of the nodule had been growing in its collected orientation at 4.7 mm Myr −1 for at least 0.5 Myr and accreting Mn at 200 μg cm −2 kyr −1 . The bottom of the nodule had been growing in its collected orientation at about 12 mm Myr −1 for at least 0.3 Myr and accreting Mn at about 700 μg cm −2 yr −1 . Although the top of the nodule was enriched in iron relative to the bottom, the nodule had been accreting Fe 50% faster on the bottom. 232 Th was also accumulating more rapidly in the bottom despite a 20-fold enrichment of 230 Th on the top. The distribution of alpha-emitting nuclides calculated from detailed radiochemical measurements matched closely the pattern revealed by 109-day exposures of alpha-sensitive film to the nodule. However, the shape and slope of the total alpha profile with depth into the nodule was affected strongly by 226 Ra and 222 Rn migrations making the alpha-track technique alone an inadequate method of measuring nodule growth rates. Diffusion of radium in the nodule may have been affected by diagenetic reactions which produce barite, phillipsite and todorokite within 1 mm of the nodule surface; however, our sampling interval was too broad to document the effect. We have not been able to resolve the importance of nodule diagenesis on the gross chemistry of the nodule.

Earth and Planetary Science Letters↗

Fission track dating of kimberlitic zircons

The only reliable method for dating kimberlites at present is the lengthy and specialized hydrothermal procedure that extracts 206 Pb and 238 U from low-uranium zircons. This paper describes a second successful method by fission track dating of large single-crystal zircons, 1.0–1.5 cm in dimension. The use of large crystals overcomes the limitations imposed in conventional fission track analysis which utilizes crushed fragments. Low track densities, optical track dispersion, and the random orientation of polished surfaces in the etch and irradiation cycle are effectively overcome. Fission track ages of zircons from five African kimberlites are reported, from the Kimberley Pool (90.3 ± 6.5 m.y.), Orapa (87.4 ± 5.7 and 92.4 ± 6.1 m.y.), Nzega (51.1 ± 3.8 m.y.), Koffiefontein (90.0 ± 8.2 m.y.), and Val do Queve (133.4 ± 11.5 m.y.). In addition we report the first radiometric ages (707.9 ± 59.6 and 705.5 ± 61.0 m.y.) of crustal zircons from kimberlites in northwest Liberia. The fission track ages agree well with earlier age estimates. Most of the zircons examined in this study are zoned with respect to uranium but linear correlations are established (by regression analysis) between zones of variable uranium content, and within zones of constant uranium content (by analysis of variance). Concordance between the fission track method and the U/Pb technique is established and we concluded that track fading from thermal annealing has not taken place. Kimberlitic zircons dated in this study, therefore, record the time of eruption.

Earth and Planetary Science Letters↗

Estimating the sources and transport of nutrients in the Waikato River Basin, New Zealand

We calibrated SPARROW (Spatially Referenced Regression on Watershed Attributes) surface water‐quality models using measurements of total nitrogen and total phosphorus from 37 sites in the 13,900‐km 2 Waikato River Basin, the largest watershed on the North Island of New Zealand. This first application of SPARROW outside of the United States included watersheds representative of a wide range of natural and cultural conditions and water‐resources data that were well suited for calibrating and validating the models. We applied the spatially distributed model to a drainage network of nearly 5000 stream reaches and 75 lakes and reservoirs to empirically estimate the rates of nutrient delivery (and their levels of uncertainty) from point and diffuse sources to streams, lakes, and watershed outlets. The resulting models displayed relatively small errors; predictions of stream yield (kg ha −1 yr −1 ) were typically within 30% or less of the observed values at the monitoring sites. There was strong evidence of the accuracy of the model estimates of nutrient sources and the natural rates of nutrient attenuation in surface waters. Estimated loss rates for streams, lakes, and reservoirs agreed closely with experimental measurements and empirical models from New Zealand, North America, and Europe as well as with previous U.S. SPARROW models. The results indicate that the SPARROW modeling technique provides a reliable method for relating experimental data and observations from small catchments to the transport of nutrients in the surface waters of large river basins.

Waikato River↗

Venus cartography

The entire surface of the planet Venus is being mapped at global and regional scales (1:50,000,000 through 1:1,500,000) with synthetic aperture radar (SAR), radar altimeter, and radiometer measurements of physical properties from the Magellan spacecraft. The mapping includes SAR image mosaics, shaded relief maps, and topographic contour overlays made from altimetry data and by radargrammetric methods. Methods used include new techniques of radar image processing that became operational as a result of the Magellan mission. The area being mapped (at a resolution of 75 m/pixel) is roughly equivalent to that of Earth, including seafloors. The mapping is designed to support geologic and geophysical investigations.

Journal of Geophysical Research E: Planets↗

Absolute method of measuring magnetic susceptibility

An absolute method of standardization and measurement of the magnetic susceptibility of small samples is presented which can be applied to most techniques based on the Faraday method. The fact that the susceptibility is a function of the area under the curve of sample displacement versus distance of the magnet from the sample, offers a simple method of measuring the susceptibility without recourse to a standard sample. Typical results on a few substances are compared with reported values, and an error of less than 2% can be achieved.

Review of Scientific Instruments↗

The participatory vulnerability scoping diagram - deliberative risk ranking for community water systems

Natural hazards and climate change present growing challenges to community water system (CWS) managers, who are increasingly turning to vulnerability assessments to identify, prioritize, and adapt to risks. Effectively assessing CWS vulnerability requires information and participation from various sources, one of which is stakeholders. In this article, we present a deliberative risk-ranking methodology, the participatory vulnerability scoping diagram (P-VSD), which allows rapid assessment and integration of multiple stakeholder perspectives of vulnerability. This technique is based on methods of deliberative risk evaluation and the vulnerability scoping diagram. The goal of the methodology is to engage CWS managers and stakeholders collectively to provide qualitative contextual risk rankings as a first step in a vulnerability assessment. We conduct an initial assessment using a case study of CWS in two U.S. counties, sites with broadly similar exposures but differences in population, land use, and other social sensitivity factors. Results demonstrate that CWS managers and stakeholders in the two case study communities all share the belief that their CWS are vulnerable to hazards but differ in how this vulnerability manifests itself in terms of the exposure, sensitivity, and adaptive capacity of the system.

Annals of the Association of American Geographers↗