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At least 433 records · Page 24Linked to original sources

Changes in water budgets and sediment yields from a hypothetical agricultural field as a function of landscape and management characteristics--A unit field modeling approach

Crop agriculture occupies 13 percent of the conterminous United States. Agricultural management practices, such as crop and tillage types, affect the hydrologic flow paths through the landscape. Some agricultural practices, such as drainage and irrigation, create entirely new hydrologic flow paths upon the landscapes where they are implemented. These hydrologic changes can affect the magnitude and partitioning of water budgets and sediment erosion. Given the wide degree of variability amongst agricultural settings, changes in the magnitudes of hydrologic flow paths and sediment erosion induced by agricultural management practices commonly are difficult to characterize, quantify, and compare using only field observations. The Water Erosion Prediction Project (WEPP) model was used to simulate two landscape characteristics (slope and soil texture) and three agricultural management practices (land cover/crop type, tillage type, and selected agricultural land management practices) to evaluate their effects on the water budgets of and sediment yield from agricultural lands. An array of sixty-eight 60-year simulations were run, each representing a distinct natural or agricultural scenario with various slopes, soil textures, crop or land cover types, tillage types, and select agricultural management practices on an isolated 16.2-hectare field. Simulations were made to represent two common agricultural climate regimes: arid with sprinkler irrigation and humid. These climate regimes were constructed with actual climate and irrigation data. The results of these simulations demonstrate the magnitudes of potential changes in water budgets and sediment yields from lands as a result of landscape characteristics and agricultural practices adopted on them. These simulations showed that variations in landscape characteristics, such as slope and soil type, had appreciable effects on water budgets and sediment yields. As slopes increased, sediment yields increased in both the arid and humid environments. However, runoff did not increase with slope in the arid environment as was observed in the humid environment. In both environments, clayey soils exhibited the greatest amount of runoff and sediment yields while sandy soils had greater recharge and lessor runoff and sediment yield. Scenarios simulating the effects of the timing and type of tillage practice showed that no-till, conservation, and contouring tillages reduced sediment yields and, with the exception of no-till, runoff in both environments. Changes in land cover and crop type simulated the changes between the evapotransporative potential and surface roughness imparted by specific vegetations. Substantial differences in water budgets and sediment yields were observed between most agricultural crops and the natural covers selected for each environment: scrub and prairie grass for the arid environment and forest and prairie grass for the humid environment. Finally, a group of simulations was performed to model selected agricultural management practices. Among the selected practices subsurface drainage and strip cropping exhibited the largest shifts in water budgets and sediment yields. The practice of crop rotation (corn/soybean) and cover cropping (corn/rye) were predicted to increase sediment yields from a field planted as conventional corn.

Scientific Investigations Report↗

Water data to answer urgent water policy questions: Monitoring design, available data and filling data gaps for determining the effectiveness of agricultural management practices for reducing tributary nutrient loads to Lake Erie

Throughout its history, the United States has made major investments in assessing natural resources, such as soils, timber, oil and gas, and water. These investments allow policy makers, the private sector and the American public to make informed decisions about cultivating, harvesting or conserving these resources to maximize their value for public welfare, environmental conservation and the economy. As policy issues evolve, new priorities and challenges arise for natural resource assessment, and new approaches to monitoring are needed. For example, informed conservation and use of the nation’s finite fresh water resources in the context of increasingly intensive land development is a priority for today’s policy decisionmakers. There is a need to evaluate whether today’s water monitoring programs are generating the information needed to answer questions surrounding these new policy priorities. The Northeast-Midwest Institute (NEMWI), in cooperation with the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program, initiated this project to explore the types and amounts of water data needed to address water-quality related policy questions of critical concern to today’s policy makers. The collaborating entities identified two urgent water policy questions and conducted case studies in the Northeast-Midwest region to determine the water data needed, water data available, and the best ways to fill the data gaps relative to those questions. This report details the output from one case study and focuses on the Lake Erie drainage basin, a data-rich area expected to be a best-case scenario in terms of water data availability.

Indiana, Michigan, New York, Ohio, Pennsylvania↗

National seed strategy for rehabilitation and restoration progress report 2022 & 2023: Handout

Restoring healthy, resilient, biodiverse ecosystems is crucial for our Nation’s future. Native plant communities provide essential environmental benefits, such as buffering against extreme weather, improving air, soil, and water quality, and habitat for wildlife. However, the limited availability of locally adapted native plants hampers effective ecological restoration. To address this need, the Plant Conservation Alliance released the National Seed Strategy in 2015 to foster coordination to increase the supply of native seeds for restoration on public, Tribal, state, and private lands. Developing and using native seeds nurtures a growing restoration economy that creates jobs, stimulates rural economies, and reduces risks from environmental hazards.

Report↗

Sustainability of vegetation communities grazed by elk in Rocky Mountain National Park

Current management of the worlds' grazing lands in either based on changes in plant species composition or on other management evaluation programs that emphasize changes in net aboveground production. Management is based solely on changes in aboveground production has been criticized as too limited in view, because it ignores root production, nitrogen pools, nutrient processes, and the long-term sustainability of the ecosystem. The purpose of this study was to compare the effects of elk ( Cervus elaphus ) grazing on aboveground production, internal nitrogen (N) fluxes, N pools and inputs, and elk nutrient transfers across the landscape in different vegetation types in Rocky Mountain National Park (RMNP), Colorado. Nitrogen processes and possibly N pools were significantly reduced in the willow community, but not in the upland grass/shrub community. Nitrogen mineralization rates were lower in grazed versus ungrazed short willow sites (P = 0.07; n = 4 sites), as were nitrate (NO3) pools (P = 0.10), but not in tall willow sites (P > 1.10 n = 4 sites) after 4 years. There was about half the annual N inputs to the soil surface in grazed willow sites (5.79g N/m 2 /yr = annual herbaceous biomass a?? offtake + litterfall + elk urine and feces) compared to ungrazed sites (9.66 g N/m 2 /yr = annual herbaceous biomass + litterfall), suggesting elk herbivory and movement led to a net loss of N in the willow vegetation type. Elk substantially reduced the annual growth of willows (Salix spp.) by 98% after 35 years and 66% after 4 years of treatment. Thus, height and canopy and N yield of willows were reduced as well as willow litter biomass (65 g/m2/yr in ungrazed versus 33 g/m2/yr in grazed), and N yield of willows was 64% less in grazed plots. Elk grazing had no significant effect on other soil N pools (NH4) or litter decomposition rates in either of the two willow types, nor on any nitrogen process rates or pools in the upland grass/shrub type (P > 0.10). Nitrogen concentrations in plant tissue were not influenced for the most part by elk grazing (increased N concentration found in only 4 of 13 species). Elk apparently also transported N away from aspen at an even higher rate (N inputs were 1.65 g N/m2/yr in grazed sites vs. 3.79 g N/m 2 /yr ungrazed). CENTURY modeling supported these observations. This soil N model predicted almost no change (0.5$ - 2% less) in N or carbon (C) pools in 50 years in the upland grass/shrub vegetation type, but greater losses in the willow type. If elk population levels were increased to carrying capacity in the ecosystem (about 25% more consumption) projected losses after 50 years were greater, but still <4% for soil C and 1% for spoil N in the upland type, and 6% for soil C and 2% for soil N in the willow type. Total shrub C was projected to decline 10% in 50 years in the willow type at current elk densities. We recommend conservative management of elk numbers and grazing until additional years of measures are gathered on the lower mineralization rates in the short willow type and until the projected declines in N pools can be verified.

Report↗

Modelling streamwater chemistry as a mixture of soilwater end-members - An application to the Panola Mountain catchment, Georgia, U.S.A.

Streamwater chemistry at Panola Mountain research catchment, Georgia, U.S.A., is explained as a mixture of representative soilwater solutions that are considered to be temporally invariant to a first approximation. The selection of three end-members from all sampled soil waters is evaluated by comparing the observed and predicted streamwater concentration of six solutes (alkalinity, sulfate, sodium, magnesium, calcium and dissolved silica), which are assumed to mix conservatively, and by assessing the consistency of the implied hydrograph separation with the hydrological mechanisms that are believed to be operating in this catchment. The percentage of variation in the streamwater solute concentrations explained by the end-member mixing analysis (EMMA) ranges from 82 to >97%, and the hydrograph separation is, intuitively, physically reasonable. If the correct end-members have been identified, the streamwater chemical response to different levels of acidic deposition can be predicted by examining the change in each end-member under different loads; no hydrological model is required. If a traditional hydrochemical model, which is driven by rainfall quantity and quality, is desired, this analysis provides an indication of the model structure that would be necessary to reproduce both streamwater and soilwater chemistry.

Georgia↗

Assessment of site-specific agricultural Best Management Practices in the Upper East River watershed, Wisconsin, using a field-scale SWAT model

The Great Lakes “Priority Watershed” effort targeted the Upper East River watershed, a 116.5 km2 tributary watershed to Green Bay in Wisconsin, to reduce sediment and nutrients entering Green Bay. A Soil and Water Assessment Tool (SWAT) model was created to determine the effectiveness of Best Management Practices (BMPs) derived from the U.S. Department of Agriculture-Natural Resources Conservation Service National Conservation Planning (NCP) Database. The model was calibrated at the monthly timestep for flow, sediment, dissolved reactive phosphorus (DRP), total phosphorus (TP), and total nitrogen (TN). Field- and watershed-scale sediment and nutrient reductions were calculated due to the implementation of 74 BMP combinations on dairy and cash grain rotations. Modeling results indicated that when multiple BMPs are placed on a field, especially those that included filter strips and grassed waterways, generally reduced sediment and nutrient loads more than a single BMP implementation. The most effective in-field practice at reducing DRP and TP on dairy fields was a combination of 5 different BMPs: cover crops, crop rotation, nutrient management plan, reduced tillage, and a filter strip. Conservation cover was the most effective practice at reducing sediment and nutrient yields. Sediment and nutrient loads decreased at the watershed scale as the quantity and coverage of BMPs increased. When all contracted NCP BMPs were simulated at the watershed scale, sediment loads were reduced 2%, while TP, DRP, TN and nitrate loads were reduced 20%, 9%, 24%, and 17%, respectively. Modeling scenarios indicated that as the number and area of BMPs were increased, sediment and nutrient load reductions were also increased.

Wisconsin↗

Microbial-sized, carboxylate-modified microspheres as surrogate tracers in a variety of subsurface environments: An overview

Since 1986, fluorescent carboxylate-modified polystyrene/latex microspheres (FCM) have been co-injected into aquifers along with conservative tracers and viruses, bacteria, and (or) protozoa. Use of FCM has resulted in new information about subsurface transport behaviors of microorganisms in fractured crystalline rock, karst limestone, soils, and granular aquifers. FCM have been used as surrogates for oocysts of the pathogenic protist Cryptosporidium parvum in karst limestone and granular drinking-water aquifers. The advantages of FCM in subsurface transport studies are that they are safe in tracer applications, negatively charged, easy to detect, chemically inert, and available in wide range of sizes. The limitations of FCM are that the quantities needed for some field transport studies can be prohibitively expensive and that their surface characteristics may not match the microorganisms of interest. These limitations may be ameliorated, in part by using chemically modified FCM so that their surface characteristics are a better match to that of the organisms. Also, more sensitive methods of detection may allow using smaller quantities of FCM. To assess how the transport behaviors of FCM and pathogens might compare at the field scale, it is helpful to conduct side-by-side comparisons of their transport behaviors using the geologic media and site-specific conditions that characterize the field site.

Procedia Earth and Planetary Science↗

Comparison of remote sensing indices for monitoring of desert cienegas

This research considers the applicability of different vegetation indices at 30 m resolution for mapping and monitoring desert wetland (cienega) health and spatial extent through time at Cienega Creek in southeastern Arizona, USA. Multiple stressors including the risk of decadal-scale drought, the effects of current and predicted global warming, and continued anthropogenic pressures threaten aquatic habitats in the southwest and cienegas are recognized as important sites for conservation and restoration efforts. However, cienegas present a challenge to satellite-imagery based analysis due to their small size and mixed surface cover of open water, exposed soils, and vegetation. We created time series of five well-known vegetation indices using annual Landsat Thematic Mapper (TM) images retrieved during the April&ndash;June dry season, from 1984 to 2011 to map landscape-level distribution of wetlands and monitor the temporal dynamics of individual sites. Indices included the Normalized Difference Vegetation Index (NDVI), the Soil-Adjusted Vegetation Index (SAVI), the Normalized Difference Water Index (NDWI), and the Normalized Difference Infrared Index (NDII). One topographic index, the Topographic Wetness Index (TWI), was analyzed to examine the utility of topography in mapping distribution of cienegas. Our results indicate that the NDII, calculated using Landsat TM band 5, outperforms the other indices at differentiating cienegas from riparian and upland sites, and was the best means to analyze change. As such, it offers a critical baseline for future studies that seek to extend the analysis of cienegas to other regions and time scales, and has broader applicability to the remote sensing of wetland features in arid landscapes.

Arizona↗

Modeling radium and radon transport through soil and vegetation

A one-dimensional flow and transport model was developed to describe the movement of two fluid phases, gas and water, within a porous medium and the transport of 226Ra and 222Rn within and between these two phases. Included in this model is the vegetative uptake of water and aqueous 226Ra and 222Rn that can be extracted from the soil via the transpiration stream. The mathematical model is formulated through a set of phase balance equations and a set of species balance equations. Mass exchange, sink terms and the dependence of physical properties upon phase composition couple the two sets of equations. Numerical solution of each set, with iteration between the sets, is carried out leading to a set-iterative compositional model. The Petrov-Galerkin finite element approach is used to allow for upstream weighting if required for a given simulation. Mass lumping improves solution convergence and stability behavior. The resulting numerical model was applied to four problems and was found to produce accurate, mass conservative solutions when compared to published experimental and numerical results and theoretical column experiments. Preliminary results suggest that the model can be used as an investigative tool to determine the feasibility of phytoremediating radium and radon-contaminated soil. ?? 2003 Elsevier Science B.V. All rights reserved.

Journal of Contaminant Hydrology↗

Warming of alpine tundra enhances belowground production and shifts community towards resource acquisition traits

Climate warming is expected to stimulate plant growth in high‐elevation and high‐latitude ecosystems, significantly increasing aboveground net primary production (ANPP). However, the effects of simultaneous changes in temperature, snowmelt timing, and summer water availability on total net primary production (NPP)—and elucidation of both above‐ and belowground responses—remain an important area in need of further study. In particular, measures of belowground net primary productivity (BNPP) are required to understand whether ANPP changes reflect changes in allocation or are indicative of a whole plant NPP response. Further, plant functional traits provide a key way to scale from the individual plant to the community level and provide insight into drivers of NPP responses to environmental change. We used infrared heaters to warm an alpine plant community at Niwot Ridge, Colorado, and applied supplemental water to compensate for soil water loss induced by warming. We measured ANPP, BNPP, and leaf and root functional traits across treatments after 5 yr of continuous warming. Community‐level ANPP and total NPP (ANPP + BNPP) did not respond to heating or watering, but BNPP increased in response to heating. Heating decreased community‐level leaf dry matter content and increased total root length, indicating a shift in strategy from resource conservation to acquisition in response to warming. Water use efficiency (WUE) decreased with heating, suggesting alleviation of moisture constraints that may have enabled the plant community to increase productivity. Heating may have decreased WUE by melting snow earlier and creating more days early in the growing season with adequate soil moisture, but stimulated dry mass investment in roots as soils dried down later in the growing season. Overall, this study highlights how ANPP and BNPP responses to climate change can diverge, and encourages a closer examination of belowground processes, especially in alpine systems, where the majority of NPP occurs belowground.

Colorado↗

The role of the Wetland Reserve Program in conservation efforts in the Mississippi River Alluvial Valley

The Mississippi River Alluvial Valley includes the floodplain of the Mississippi River from Cairo, Illinois, USA, to the Gulf of Mexico. Originally this region supported about 10 million ha of bottomland hardwood forests, but only about 2.8 million ha remain today. Furthermore, most of the remaining bottomland forest is highly fragmented with altered hydrologic processes. During the 1990s landscape-scale conservation planning efforts were initiated for migratory birds and the threatened Louisiana black bear ( Ursus americanus luteolus ). These plans call for large-scale reforestation and restoration efforts in the region, particularly on private lands. In 1990 the Food, Agriculture, Conservation and Trade Act authorized the Wetlands Reserve Program (WRP). The WRP is a voluntary program administered by the United States Department of Agriculture that provides eligible landowners with financial incentives to restore wetlands and retire marginal farmlands from agricultural production. As of 30 September 2005, over 275,700 ha have been enrolled in the program in the Mississippi River Alluvial Valley, with the greatest concentration in Louisiana, Arkansas, and Mississippi, USA. Hydrologic restoration is common on most sites, with open-water wetlands, such as moist-soil units and sloughs, constituting up to 30% of a given tract. Over 33,200 ha of open-water wetlands have been created, potentially providing over 115,000,000 duck-use days. Twenty-three of 87 forest-bird conservation areas have met or exceed core habitat goals for migratory songbirds and another 24 have met minimum area requirements. The WRP played an integral role in the fulfillment of these goals. Although some landscape goals have been attained, the young age of the program and forest stands, and the lack of monitoring, has limited evaluations of the program's impact on wildlife populations.

Mississippi River Alluvial Valley↗

Preliminary evaluation of the potential for artificial ground-water recharge in eastern San Joaquin County, California

In response to increasing demand on water supplies and declining water levels in San Joaquin County, the U. S. Geological Survey, in cooperation with the San Joaquin County Flood Control and Water Conservation District, is evaluating the potential for artificially recharging the aquifer system in eastern San Joaquin County, California. Through a well canvass and analyses of existing data on geology, soils, and drillers logs, this study (phase one of three phases) resulted in identification of 20 sites for exploratory test drilling in areas potentially favorable for artificial recharge. Ten of the sites are in areas adjacent to the Mokelumne River, six are in areas adjacent to the Calaveras River and Mormon Slough, and four are north of Littlejohns Creek. (USGS)

Open-File Report↗

Secretive marsh bird habitat associations in the Mississippi Flyway: A meta-analysis

Secretive marsh birds, including rails and bitterns, have experienced widespread population declines due to the loss of wetland habitat on which they depend. Because of their cryptic behavior, secretive marsh birds are challenging to study and information on their habitat requirements is limited, especially across the full annual cycle. Quantifying habitat associations throughout the annual cycle and at broad geographic scales can advance a more comprehensive approach for secretive marsh bird conservation. The goal of this study was to quantitatively synthesize results from empirical studies that examined species-habitat relationships of secretive marsh birds in the North American Mississippi Flyway to identify general patterns and information gaps that can guide future management and conservation efforts. We performed a meta-analysis and incorporated results from 40 studies that quantitatively assessed habitat associations of American Bittern ( Botaurus lentiginosus ), Least Bittern ( Ixobrychus exilis ), King Rail ( Rallus elegans ), Sora ( Porzana carolina ), Virginia Rail ( Rallus limicola ), and Yellow Rail ( Coturnicops noveboracensis ). Most studies examined breeding season habitat, whereas only 13% reported on habitat use during migration and none during winter. At landscape scales, breeding marsh birds were positively associated with amount of wetlands, especially in the Great Lakes region, and negatively associated with amount of urban land cover, particularly for American Bittern. At the local scale, breeding marsh birds were positively associated with cattail coverage ( Typha spp) and other robust emergent vegetation. Overall, marsh birds were negatively associated with woody wetland vegetation, although effects were weaker in the Prairie region and varied among species. During autumn migration, moist-soil vegetation coverage was important for rails in the lower Midwest. The habitat use patterns we identified across studies provide a general characterization of marsh bird breeding habitat to aid in landscape-level multi-species conservation efforts. Our study also highlights the immediate research needs for full annual cycle conservation of secretive marsh bird habitat in North America: specifically, information during winter and migration.

Avian Conservation and Ecology↗

Mapping crop residue by combining Landsat and WorldView-3 satellite imagery

A unique, multi-tiered approach was applied to map crop-residue cover on the Eastern Shore of the Chesapeake Bay, USA. Field measurements of crop-residue cover were used to calibrate residue mapping using shortwave infrared (SWIR) indices derived from WorldView-3 imagery for an 8-km x 8-km footprint. The resulting map was then used to calibrate and subsequently classify residue mapping of Landsat imagery at a larger spatial resolution and extent. This manuscript describes how the method was applied and presents results in the form of crop-residue cover maps, validation statistics, and quantification of conservation tillage implementation in the agricultural landscape. Overall accuracy for maps derived from Landsat 7 (ETM+) and Landsat 8 (OLI) were comparable at roughly 92% (+/- 10%). Tillage class specific accuracy was also strong and ranged from 75% to 99%. The approach, which employed a 12-band image stack of six tillage spectral indices and six individual Landsat bands, was shown to be adaptable to variable soil-moisture conditions: under dry conditions (Landsat 7, May 14, 2015) the majority of predictive power was attributed to SWIR indices, and under wet conditions (Landsat 8, May 22, 2015) single band reflectance values were more effective at explaining variability in residue cover. Summary statistics of resulting tillage class occurrence matched closely with conservation tillage implementation totals reported by Maryland and Delaware to the Chesapeake Bay Program. This hybrid method combining WorldView-3 and Landsat imagery sources shows promise for monitoring progress in the adoption of conservation tillage practices and for describing crop-residue outcomes associated with a variety of agricultural management practices.

Maryland↗

Interactions among hydrogeomorphology, vegetation, and nutrient biogeochemistry in floodplain ecosystems

Hydrogeomorphic, vegetative, and biogeochemical processes interact in floodplains resulting in great complexity that provides opportunities to better understand linkages among physical and biological processes in ecosystems. Floodplains and their associated river systems are structured by four dimensional gradients of hydrogeomorphology: longitudinal, lateral, vertical, and temporal components. These four dimensions create dynamic hydrologic and geomorphologic mosaics that have a large imprint on the vegetation and nutrient biogeochemistry of floodplains. Plant physiology, population dynamics, community structure, and productivity are all very responsive to floodplain hydrogeomorphology. The strength of this relationship between vegetation and hydrogeomorphology is evident in the use of vegetation as an indicator of hydrogeomorphic processes. However, vegetation also influences hydrogeomorphology by modifying hydraulics and sediment entrainment and deposition that typically stabilize geomorphic patterns. Nitrogen and phosphorus biogeochemistry commonly influence plant productivity and community composition, although productivity is not limited by nutrient availability in all floodplains. Conversely, vegetation influences nutrient biogeochemistry through direct uptake and storage as well as production of organic matter that regulates microbial biogeochemical processes. The biogeochemistries of nitrogen and phosphorus cycling are very sensitive to spatial and temporal variation in hydrogeomorphology, in particular floodplain wetness and sedimentation. The least studied interaction is the direct effect of biogeochemistry on hydrogeomorphology, but the control of nutrient availability over organic matter decomposition and thus soil permeability and elevation is likely important. Biogeochemistry also has the more documented but indirect control of hydrogeomorphology through regulation of plant biomass. In summary, the defining characteristics of floodplain ecosystems are determined by the many interactions among physical and biological processes. Conservation and restoration of the valuable ecosystem services that floodplains provide depends on improved understanding and predictive models of interactive system controls and behavior.

Book chapter↗

Assessment of soil-gas, soil, and water contamination at the former hospital landfill, Fort Gordon, Georgia, 2009-2010

Soil gas, soil, and water were assessed for organic and inorganic constituents at the former hospital landfill located in a 75-acre study area near the Dwight D. Eisenhower Army Medical Center, Fort Gordon, Georgia, from April to September 2010. Passive soil-gas samplers were analyzed to evaluate organic constituents in the hyporheic zone of a creek adjacent to the landfill and soil gas within the estimated boundaries of the former landfill. Soil and water samples were analyzed to evaluate inorganic constituents in soil samples, and organic and inorganic constituents in the surface water of a creek adjacent to the landfill, respectively. This assessment was conducted to provide environmental constituent data to Fort Gordon pursuant to requirements of the Resource Conservation and Recovery Act Part B Hazardous Waste Permit process. Results from the hyporheic-zone assessment in the unnamed tributary adjacent to the study area indicated that total petroleum hydrocarbons and octane were the most frequently detected organic compounds in groundwater beneath the creek bed. The highest concentrations for these compounds were detected in the upstream samplers of the hyporheic-zone study area. The effort to delineate landfill activity in the study area focused on the western 14 acres of the 75-acre study area where the hyporheic-zone study identified the highest concentrations of organic compounds. This also is the part of the study area where a debris field also was identified in the southern part of the 14 acres. The southern part of this 14-acre study area, including the debris field, is steeper and not as heavily wooded, compared to the central and northern parts. Fifty-two soil-gas samplers were used for the July 2010 soil-gas survey in the 14-acre study area and mostly detected total petroleum hydrocarbons, and gasoline and diesel compounds. The highest soil-gas masses for total petroleum hydrocarbons, diesel compounds, and the only valid detection of perchloroethene were in the southern part of the study area to the west of the debris field. However, all other detections of total petroleum hydrocarbons greater than 10 micrograms and diesel greater than 0.04 micrograms, and all detections of the combined mass of benzene, toluene, ethylbenzene, and xylene were found down slope from the debris field in the central and northern parts of the study area. Five soil-gas samplers were deployed and recovered from September 16 to 22, 2010, and were analyzed for organic compounds classified as chemical agents or explosives. Chloroacetophenones (a tear gas component) were the only compounds detected above a method detection level and were detected at the same location as the highest total petroleum hydrocarbons and diesel detections in the southern part of the 14-acre study area. Composite soil samples collected at five locations were analyzed for 35 inorganic constituents. None of the inorganic constituents exceeded the regional screening levels. One surface-water sample collected in the western end of the hyporheic-zone study area had a trichlorofluoromethane concentration above the laboratory reporting level and estimated concentrations of chloroform, fluoranthene, and isophorone below laboratory reporting levels.

Georgia↗

Lead exposure of snakes near recreational and military shooting areas in a sagebrush steppe ecosystem

Lead exposure has been documented in a multitude of bird and mammal species but less frequently in reptiles. Of the studies that have evaluated lead concentrations in reptiles, few have focused on snakes. We analyzed lead concentrations in liver and two types of bone from 24 gophersnakes ( Pituophis catenifer; Pc) and 12 Great Basin rattlesnakes ( Crotalus oreganus lutosus; Col) found dead along roads in the Morley Nelson Snake River Birds of Prey National Conservation Area in southwestern Idaho, U.S.A from 2018 to 2021. Because this area has been heavily impacted by both military and recreational activity, we also quantified lead concentrations in the soil near where the dead snakes were found. All soil samples had detectable lead (median: 12.53 µg/g; range: 0.07–16.77). Within individuals of both species, dry weight lead concentrations in liver generally were lower than those in bone (n samples < LOQ Liver: 9 of 13 ( Pc ), 9 of 10 ( Col ) (only a subset of individuals were in good enough condition to provide liver samples); Bone: 0 of 24 ( Pc ), 3 of 12 ( Col ). We did not detect any differences in lead concentrations between the species for either tissue type, nor between bone from the front (anterior) or back (posterior) of the snake skeleton. Additionally, we did not detect any correlation between lead concentration in soil collected at the roadkill sites and the tissue in the snakes. These data provide baseline information for lead exposure of two snake species in southwestern Idaho and demonstrate how lead is present in higher trophic levels within this ecosystem.

Idaho↗