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Simulation of groundwater flow to evaluate hydrogeologic controls on a PFAS plume, Coakley Landfill Superfund site, Rockingham County, New Hampshire

Per- and polyfluoroalkyl substances (PFAS), including perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS), have been detected at combined concentrations above 2,000 nanograms per liter (ng/L) at groundwater seep locations near the Coakley Landfill Superfund site, in North Hampton, New Hampshire. The landfill was active from 1972 to 1985. An impermeable cap was placed on the landfill in 1998. The adjacent area to the Coakley Landfill has many water supply wells, and transport of PFAS compounds to the wells is a concern. Fracture anisotropy in the underlying bedrock aquifer complicates the understanding of PFAS transport because groundwater preferentially travels along fractures that may not align with the prevailing groundwater flow direction. In 2018, the U.S. Environmental Protection Agency and the U.S. Geological Survey began an investigation of the groundwater flow from the Coakley Landfill site. This report describes the modification of a numerical groundwater-flow model for the local area around the Coakley Landfill and summarizes findings of the investigation. In addition, this report includes a brief description of PFOA and PFOS occurrence, a discussion of model construction, evaluation of model performance through calibration, and discussion of simulation results for two periods (before and after capping). Limitations are also discussed. Results show that simulated groundwater flow moves from the Coakley Landfill to the west and north. Advective transport modeling using particle tracking shows that groundwater from the landfill discharges primarily to streams to the west and north, and a small amount is transported to distal wells. Dilution of contaminants through advection and dispersion likely plays a role in whether PFAS compounds from the landfill will be detected above laboratory reporting levels at distal wells.

New Hampshire

An evaluation of the effects of different deicing salt application rates on three watersheds in Essex County, New York

The U.S. Geological Survey, in cooperation with the New York State Department of Transportation, evaluated the effects of different deicing salt application rates on surface water, groundwater, and highway runoff quality near State highways in northern New York. Three reaches of State highways were tested with different deicing treatments between October 2019 and November 2022: a salt-sand mixture (Treatment A), a salt mixture applied at a lower rate (Treatment B), and a control mixture consistent with typical deicing salt amounts and application rates. Data on pavement conditions and the quality of surface water, highway runoff, and groundwater were collected. Surface electromagnetic data were also collected. Surface-water and groundwater quality downgradient from the State highways were compared with water quality at upgradient locations. The percentage of snow or ice coverage was used to evaluate the effectiveness of the salt applications. This report provides an overview of the transport of deicing salt. The Treatment B watershed had deicing mixture applied more frequently than other highway reaches, which caused it to have the highest annual total chloride application. Despite differences in chloride application, flow-weighted mean chloride concentrations in highway runoff were comparable across treatments. Chloride concentrations were elevated in surface water and groundwater downgradient from highways relative to chloride concentrations upgradient from highways. A chloride mass balance, calculated for one treatment watershed, indicated that groundwater affected by legacy deicing practices may be contributing additional chloride to surface water. Spatial patterns from electromagnetic surveys show a shallow saline plume alongside the highway in that area. Differences in winter severity and pavement-surface conditions drove deicing salt applications in the treatment areas. This study found that several factors affect chloride loads in the watersheds, including variable winter conditions, adaptive snow and ice management, legacy management practices, and area-specific aquifer and groundwater conditions.

New York

Development of a hydrologic flow model of the Zuñi Salt Lake and surrounding areas, west-central New Mexico

The terminal Zuñi Salt Lake is in a maar in west-​central New Mexico and contains hypersaline water that has long been used by Native Americans for religious purposes and the collection of salt. The U.S. Geological Survey (USGS), in cooperation with the Zuni Tribe of the Zuni Reservation, New Mexico, and Bureau of Reclamation, developed the Zuñi Salt Lake hydrologic flow model to simulate the steady-state conditions of the lake and surrounding groundwater-flow system. The model is a tool that can be used to analyze the potential hydrologic responses to resource development in the region under different water-use scenarios, which can support negotiations that could help protect future use of the lake. The USGS modular hydrologic model, MODFLOW 6, was used to simulate the hydrologic system of the lake and surrounding areas. To define the layering of the model, a three-dimensional hydrogeologic framework was constructed, which included seven informal hydrogeologic units and the locations of faults that truncate and offset the units. Calibration of the model was performed using the iterative ensemble smoother included in a parameter estimation software suite (PEST++). The iterative ensemble smoother approach resulted in a posterior parameter ensemble of model realizations with parameter and simulated values that show similar success in matching observations. Groundwater flux to the Zuñi Salt Lake simulated by using the posterior parameter distribution ranged from 26 to 730 acre-feet per year with a mean, median, and standard deviation of 530, 570, and 170 acre-feet per year, respectively. The relative contribution of groundwater discharge to the lake was simulated using a particle-tracking model for MODFLOW (MODPATH) to be from, in order of decreasing contribution, the Mesaverde, Cenozoic, Mancos, and Dakota hydrogeologic units. Simulations of future conditions using the ensemble of models can provide an empirical estimate of forecast uncertainty without substantial additional analysis.

New Mexico

Summary of results from monitoring the Geysers with continuous passive seismic and repeat magnetotelluric measurements (2021-2023)

Understanding temporal variations in a geothermal field can support operators in decision making that pertains to optimizing production and mitigating hazards. Between 2021 and 2023, The Geysers geothermal field in northern California was monitored with an array of continuous passive seismic sensors and annual repeat magnetotelluric (MT) measurements. Each of these data sets were analyzed and modelled separately to understand the data, sensitivity, and any observable changes. Then, the data were inverted jointly using a crossgradient method to further constrain temporal changes in geophysical properties within the geothermal field. Multiple permutations of annual datasets were used as inputs to the joint inversion. Results demonstrate seismic data constrain smooth inversion of the MT data, and the MT data provide supplementary information about the location of temporal fluid changes. Estimating relative changes in steam saturation for various time intervals of the joint models shows compartmentalized changes in the field, and good spatial correlation with the location of injection wells. These results demonstrate that collecting both passive seismic and MT measurements then modeling them jointly provide complementary information and a relatively inexpensive method for monitoring temporal changes in an active geothermal field that provides results to support operators.

California

Simulated effects of projected 2014–40 withdrawals on groundwater flow and water levels in the New Jersey Coastal Plain

Abstract Groundwater flow between 2014 through 2040 was simulated in the New Jersey Coastal Plain based on three withdrawal scenarios. Two of the scenarios were based on projected population trends and the assumption of water conservation; the nominal water-loss scenario projected a status quo in the efficiency of water loss in the delivery systems whereas the optimal water-loss scenario projected a better water-loss efficiency resulting in less withdrawals. The third scenario assumes that all wells will withdraw water at their full allocation level which is generally much more than reported withdrawals in 2013 or projected under the other two scenarios. Maps and summaries of heads and drawdowns are presented for nine confined aquifers. All the aquifers have areas with heads below sea level by 2040. Of the three scenarios, the drawdowns are most extreme in the full allocation scenarios; there are large areas of head decline greater than 20 feet in 5 of the 9 confined aquifers. The exceptions are the Vincentown aquifer, despite some areas of large drawdown in the vicinity of wells, and the three Potomac-Raritan-Magothy (PRM) aquifers where withdrawals are regulated by Critical Area restrictions. The nominal and optimal water-loss scenarios have some areas of head declines; most are less than 15 feet. The simulation of these scenarios shows some extensive areas of head recovery as well—especially in the aquifers that are regulated by the Critical Area restrictions. Budgets of inflow and outflow components were calculated for 44 hydrologic budget areas (HBAs). The budget analysis shows that the water movement is complex and varies based on the aquifer geometry and location of pumping wells. Flow components between the unconfined and confined parts of the system were summarized by HUC11 (hydrologic unit code 11) basins.

New Jersey

Geologic framework and Holocene sand thickness offshore of Seven Mile Island, New Jersey

The U.S. Geological Survey assessed the Quaternary evolution of Seven Mile Island, New Jersey, to quantify coastal sediment availability, which is crucial for establishing sediment budgets, understanding sediment dispersal, and managing coastlines. This report presents preliminary interpretations of seismic profiles, maps of Holocene sand thickness from the shoreline to 2 kilometers offshore, and tables quantifying the volume of available sediment along the coastal margin based on data collected during 2021 and 2022. The results reveal spatial variability in the thickness and cross-shore extent of Holocene sand. The study area was separated into northern, central, and southern zones by using underlying stratigraphy and geomorphic features. The characteristics and spatial extent of the Holocene sand deposit indicate that hydrodynamic processes contribute to its spatial variability. Northern Seven Mile Island contains the thickest deposits of Holocene sand that were formed by sediment bypass around the Townsends Inlet ebb-tidal delta. Specifically, swash bars have welded to the updrift end of Seven Mile Island and have formed thick deposits of Holocene sand that thicken landward and taper seaward. Despite their thickness, these deposits have the smallest cross-shore extent; therefore, northern Seven Mile Island has the smallest volume of Holocene sand of the three geomorphic zones. Central Seven Mile Island has the thinnest Holocene sand deposits because this section of the barrier island is outside the influence of ebb-tidal deltas. Southern Seven Mile Island has the greatest volumes of Holocene sand because of increased accommodation and deposition adjacent to the Hereford Inlet ebb-tidal delta. Even though tidal inlets exert variable influence on the three geomorphic zones, sediment is distributed fairly uniformly within each geomorphic zone; each of the three zones contains 31.05–36.48 percent of the volume of available Holocene sand.

New Jersey

An unexplained tsunami: Was there megathrust slip during the 2020 Mw7.6 Sand Point, Alaska, earthquake?

On October 19, 2020, the M w 7.6 Sand Point earthquake struck south of the Shumagin Islands in Alaska. Moment tensors indicate the earthquake was primarily strike-slip, yet the event produced an enigmatic tsunami that was larger and more widespread than expected for an earthquake of that magnitude and mechanism. Using a suite of hydrodynamic, seismic, and geodetic modeling techniques, we explore plausible causes of the tsunami. We find that strike-slip models consistent with the moment tensor orientation cannot produce the observed tsunami. Hydrodynamic inversion of sea surface deformation from deep ocean and tide gauge data suggest seafloor deformation more closely matches a megathrust, rather than a strike-slip, source. Static slip inversions, using sea level and Global Navigation Satellite System data, allow for a portion of co-seismic megathrust slip that can explain tsunamigenesis. Combining all available geophysical datasets to model the kinematic rupture, we show that considerable, relatively slow, megathrust slip is allowable in the Shumagin segment, concurrent with strike-slip faulting. We hypothesize that the slow megathrust rupture does not contribute much seismic radiation allowing it to previously go unnoticed with traditional seismic monitoring.

Alaska

Geochemical and hydrological investigations of historical data collected at the Lee Acres Landfill and Giant Bloomfield Refinery, New Mexico, 1985–2020

The Lee Acres Landfill and Giant Bloomfield Refinery are adjacent properties near the City of Farmington, New Mexico, each having undergone monitoring and remediation related to historical site activities. At the landfill, site cleanup has included the installation of a capillary barrier over former liquid waste lagoons and periodic monitoring of groundwater elevations and groundwater quality. At the refinery, remediation has focused on several petrochemical and crude oil release areas and included soil excavation, groundwater treatment, and regular monitoring of groundwater elevations and quality. Groundwater at both sites has higher concentrations of volatile organic compounds and trace metals than background aquifer concentrations. In 2022, the U.S. Geological Survey compiled the Lee Acres-Giant Bloomfield Refinery Database (LAGBRD), which contains publicly available groundwater-elevation data and organic and inorganic groundwater-quality data from both sites, spanning from 1985 to 2020. Data from the LAGBRD and precipitation data from other sources were used to better understand the cause of relatively high manganese concentrations observed in some groundwater wells at the site through comparison of groundwater chemistry to chemical end members, interpretation of spatial and temporal patterns in the groundwater chemistry, and interpretation of groundwater flow properties. In this study, elevated chloride concentrations in groundwater downgradient from the landfill have been attributed to landfill leachate based on the temporal and spatial variability of chloride concentrations and chloride-to-bromide ratios. Installation of a capillary barrier and surface-water runoff controls at the landfill in 2005 appears to have altered infiltration patterns at that site, resulting in a decrease in chloride at some wells but an increase in chloride and dissolved manganese at others. The timing and relation among groundwater elevation, chloride concentration, and manganese concentration suggest that leachate stored in the vadose zone provides a continued source of contamination to groundwater.

New Mexico

The Long Island Sound and Watershed Metadata map application

The Long Island Sound and its watershed encompass an area of about 17,000 square miles and include the Connecticut, Housatonic, and Thames Rivers, which all drain to the sound. Dozens of organizations from government agencies, nonprofits, and Tribal Nations have developed projects and monitoring programs to analyze and protect the water resources of the watershed and sound. The abundance of data and lack of an existing searchable index require a centralized metadata repository to allow users to find water resources data more efficiently. The U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the Long Island Sound Study, has created an interactive map application to visualize and search for metadata information across organizations working to monitor and protect the Long Island Sound.

Connecticut, Massachusetts, New Hampshire, New Yor

Geotechnical description of four Mississippi Delta soil borings

The submerged portion of the Mississippi Delta complex forms an ideal natural laboratory to study the effects of rapid deposition. One of the most obvious of these effects is the mass movements of sediments. Slump and slide signatures, mudflow characteristics, and evidence for creep are all found in abundance on the delta platform. These types of features have been studied by Colemen and Wright (1974) with regard to form and by Garrison (1974) with regard to their spatial distribution. Assembling these authors' findings, it is clear that the entire offshore zone contiguous with the Mississippi River is a myriad of geological action. This situation is indeed stimulating to the sedimentologist, yet it represents a nightmare to the foundation engineer. Emplacing offshore structures in such an environment is a most difficult task, particularly since the high degree of local variability dictates that each case must be handled separately. It is under these circumstances that a marriage between geology and engineering is most fruitful, for determining the relationships between the sedimentological processes and the engineering properties is satisfying to parties from both disciplines. This, then, is the underlying objective of the Mississippi Delta research project. By investigating the instability in a geologic sense, it is hoped that many of the engineering problems will become more soluble and that extrapolation and prediction will become more realistic.

Mississippi Delta

Evaluating Laramide orogenesis via flexural basin response in the San Juan basin, New Mexico and Colorado

A challenge in interpreting the location, timing, and magnitude of ancient orogenic events is that ongoing uplift and erosion in the hinterlands often destroys much of the primary record of these events. However, basin-thickness patterns in the sedimentary record can provide complimentary evidence of uplift via flexural effects. Here, we deploy well-log correlation, isochores, basin modeling, flexural modeling, and subcrop mapping to evaluate the Late Cretaceous to Paleogene basin response to Laramide tectonism in the San Juan basin. A wedge of upper Campanian to Maastrichtian sedimentary rock thickens from 200 to 800 meters from southeast to northwest in the basin. This pattern can be successfully simulated via flexural modeling if we infer early Laramide uplift along the northwest basin flank that produced a 0.8 km high topographic load. The Laramide unconformity bounds the top of this Upper Cretaceous sedimentary wedge and truncates progressively older strata to the east, further supporting a westward tilt of the basin. The onset of Campanian Laramide flexure may have also contributed to the profound transgression from the upper Menefee Formation to the Lewis Shale. The Paleocene isochore map displays an approximately symmetrical pattern, with thickening towards the center of the basin. This suggests the possibility of competing flexural loads. The base Eocene structure indicates an asymmetric deep on the northeast flank of the basin, providing flexural evidence of contemporaneous uplift/loading of the Nacimiento uplift and Archuleta arch; this has been modeled as ~2.1 km load height. Both Cretaceous and Paleocene sedimentary wedges are narrow, suggesting low flexural rigidity; modeled effective elastic thicknesses (EET) are 20-30 km, comparable to estimates of modern EET for the region.

Colorado, New Mexico

Sources of water and salts for the Zuni Salt Lake in west-central New Mexico

The Zuni Salt Lake is located in a maar in west-central New Mexico and contains hypersaline water that has long been used by Native Americans for religious purposes and the collection of salt. There have been several investigations suggesting different sources for the water and salt to the lake. Springs, seeps, and ephemeral streamflow have all been observed to contribute freshwater to the lake, and brackish to hypersaline seeps have been documented along the banks of the lake. This report summarizes the findings of a study that characterizes the lake’s hydrology, its water and salinity sources, and the hydrogeologic conceptual model. Regional groundwater levels indicate that each of the aquifers in the area have the potential to discharge groundwater to the lake. There is also evidence of vertical groundwater flow pathways at the maar that were likely created by the igneous intrusion that fractured the intersecting aquifers. A detailed water budget was constructed from continuous lake stage, precipitation, and evaporation data to estimate the groundwater inflow to the Zuni Salt Lake. It was determined that groundwater inflow to the lake is 441 ±94 acre-feet per year, which composes as much as 77 percent of the total inflows. The high sodium and chloride concentrations measured in two hypersaline samples collected near the lake indicate that the majority of the dissolved solids entering the lake are from a hypersaline groundwater source. The geochemical and isotopic compositions measured in the lake and surrounding features support the interpretation that hypersaline groundwater is the primary source of salts to the lake, which is likely sourced from the older (and deeper) Permian units. The hypersaline groundwater samples collected during this investigation have a unique aqueous chemistry relative to each of the mapped aquifers, and variability in groundwater compositions is interpreted to result from differences in minerology and residence time.

New Mexico

Quaternary-active faults and the role of inherited structures in the Sacramento-San Joaquin Delta, western Central Valley, northern California

Seismic sources and their associated hazards within the Sacramento-San Joaquin Delta region of north-central California are relatively poorly characterized as compared to other, more heavily studied regions of northern California, such as the San Francisco Bay Area. Here we present a synthesis of subsurface, bedrock geology, and geodetic datasets from the Delta and from the Coast Ranges and Diablo Range to the northwest and southwest, respectively. We integrate these data and our own surface geologic and geomorphic observations to present a comprehensive review of faults in the Delta that exhibit Quaternary activity. Structural geologic data from the surrounding region highlight the significant influence that Late Cretaceous-to-Paleogene forearc structures exert on the geometry and kinematics of major Quaternary-active structures within the Delta. These inherited structures — including the Pittsburg-Kirby Hills Fault, Midland Fault, and Great Valley Fault System — exhibit a range of geometries and kinematics. Analysis of geomorphology along these structures suggests that these structures combine to accommodate Quaternary strain across the Delta region. A clearer understanding of subsurface geometries and structural relationships, built upon the regional tectonic history, provides insight into modern deformation accommodated on older structures and helps inform interpretations of seismic hazard within the Delta.

California

New 10Be-26Al isochron burial dating informs the Pliocene and Pleistocene evolution of the lower Colorado River, southwestern United States

Four new 10 Be- 26 Al isochron burial ages ranging from 4.4 to 2 Ma on ancestral Colorado River deposits in the lower Colorado River corridor (LCRC) help constrain the river’s evolution during the Pliocene and early Pleistocene. They help fill a gap between previous work that focused on older and younger deposits: Older dated deposits include the 5 Ma Bouse Formation, which records the integration of the Colorado River through a series of preexisting basins to the Gulf of California and the ca. 4.5 - 3.5 Ma Bullhead Alluvium, a 200 to 300 m thick aggregational package that immediately followed integration. The much younger, 100 - 70 ka, Chemehuevi Formation is another major aggradation package mapped throughout the LCRC. The new burial ages on the facies of Santa Fe Railway (4.37 ± 0.71 Ma), boulder conglomerate of Bat Cave Wash (2.12 ± 0.26 and 2.05 ± 0.31 Ma), and the Palo Verde alluvium (3.03 ± 0.26 Ma) partially fill in a 3.5 M.y. gap between the deposition of the Bullhead Alluvium and the Chemeheuvi Formation and document the timescales over which the Colorado River was able to remove the Bullhead aggradational package and initiate newer and smaller aggradational pulses.

Arizona, California, Nevada

Fiber-optic distributed temperature sensing of hydrologic processes—Diverse deployments and new applications by the U.S. Geological Survey

Fiber-optic distributed temperature sensing instruments harness the temperature-dependent properties of glass to measure temperature continuously along optical fibers by using precise pulses of laser light. In the mid-2000s, this technology was refined for environmental monitoring purposes such as snowpack-air exchange, groundwater/surface-water exchange, and lake-water stratification. Fiber-optic distributed temperature sensing has revealed unprecedented details about preferential flow processes; however, the method is labor intensive and requires specific training, resulting in limited use by the broader water community. With the ongoing national implementation of the U.S. Geological Survey Next Generation Water Observing System, there has been renewed interest in harnessing the unique spatiotemporal monitoring capabilities of fiber-optic distributed temperature sensing. This fact sheet briefly describes this technology, highlights uses by the U.S. Geological Survey, and discusses current applications and future opportunities.

Fact Sheet

Use of a ground-penetrating radar system to detect pre- and post-flood scour at selected bridge sites in New Hampshire, 1996-98

Ground-penetrating radar was used to measure the depth and extent of existing and infilled scour holes and previous scour surfaces at seven bridges in New Hampshire from April 1996 to November 1998. Ground-penetrating-radar survey techniques initially were used by the U.S. Geological Survey to study streambed scour at 30 bridges. Sixteen of the 30 bridges were re-surveyed where floods exceeded a 2-year recurrence interval. A 300-megahertz signal was used in the ground-penetrating radar system that penetrated through depths as great as 20 feet of water and as great as 32 feet of streambed materials. Existing scour-hole dimensions, infilled thickness, previous scour surfaces, and streambed materials were detected using ground-penetrating radar. Depths to riprap materials and pier footings were identified and verified with bridge plans. Post data-collection-processing techniques were applied to assist in the interpretation of the data, and the processed data were displayed and printed as line plots. Processing included distance normalization, migration, and filtering but processing was kept to a minimum and some interference from multiple reflections was left in the record. Of the 16 post-flood bridges, 22 ground-penetrating-radar cross sections at 7 bridges were compared and presented in this report. Existing scour holes were detected during 1996 (pre-flood) data collection in nine cross sections where scour depths ranged from 1 to 3 feet. New scour holes were detected during 1998 (post-flood) data collection in four cross sections where scour depths were as great as 4 feet deep. Infilled scour holes were detected in seven cross sections, where depths of infilling ranged from less than 1 to 4 feet. Depth of infilling by means of steel rod and hammer was difficult to verify in the field because of cobble and boulder streambeds or deep water. Previous scour surfaces in streambed materials were identified in 15 cross sections and the depths to these surfaces ranged from 1 to 10 feet below the streambed. Riprap materials or pier footings were identified in all cross sections. Calculated record depths generally agree with bridge plans. Pier footings were exposed at two bridges and steel pile was exposed at one bridge. Exposures were verified by field observations.

New Hampshire

Evidence for organic and igneous carbon sources in the Mesoproterozoic Adirondack Highlands graphite district, New York

This study examined the origin of graphite mineralization in the Mesoproterozoic Adirondack Highlands. Flake graphite was mined from the historic mining district around Ticonderoga, New York, USA, from the 1850s to the 1920s. Most of the production and reserves from the district are disseminated graphite from feldspathic quartz schists (e.g., Dixon-American Graphite Co. mine, Faxon property, Flake Graphite Company). Protolith sediments of the schists were deposited in the Trans-Adirondack backarc basin at ca. 1.25 Ga and were metamorphosed to high grade at 1.18–1.15 Ga during the accretionary Shawinigan orogeny and at 1.09–1.02 Ga during the Ottawan phase of the Grenvillian orogeny. Major elements and carbon isotopes of graphite from schists (δ 13 C = −28.1‰ to −5.4‰ relative to Vienna Peedee belemnite) are consistent with derivation from organic carbon in protolith sandstones that devolatilized during metamorphism. Some small mines and prospects in the district mined graphitic calcite marbles and clinopyroxene ± scapolite skarns associated with a pegmatite suite dated by U-Pb in zircon to 1.04–1.01 Ga (e.g., Lead Hill and Crown Point deposits), and rare graphite veins are observed at several deposits. Hydrothermal flake graphite from pegmatites, skarns, and veins are distinct from graphite in schist-hosted deposits and have δ 13 C values that cluster around −7‰ to −5‰, consistent with deposition from igneous CO 2 . Covariation of carbon and oxygen stable isotopes and U-Pb zircon geochronology are not compatible with precipitation from fluids derived from country rock metapelites or marbles. Some graphite districts elsewhere show compelling evidence for remobilization and redeposition of sedimentary-derived carbon as hydrothermal graphite, sometimes as thick veins producing world-class, high-grade deposits. In the Adirondacks, there is evidence for two generations of graphite mineralization with distinct carbon sources: syngenetic graphite with an organic origin in Shawinigan quartz schists and epigenetic graphite with an igneous origin in Ottawan skarns and pegmatites.

New York