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At least 433 records · Page 24Linked to original sources

USGS2026

Estimating paleotemperature using stable isotopes of soil-formed phyllosilicates from paleosols: A review

Fossilized soils, or paleosols, contain soil-formed phyllosilicates whose stable isotopic compositions may be used to calculate paleotemperature and thus reconstruct ancient terrestrial environments. Though paleosols are common in the geologic record, the use of phyllosilicates as paleotemperature proxies is limited in the literature owing to difficulties with selecting optimal paleosols, isolation from non-clay minerals and organic materials, mixtures of phyllosilicates in natural samples, wide variations of chemical compositions for phyllosilicates, and limited to undefined equilibrium fractionation factors between phyllosilicates-water. Here, we address these challenges by examining and comparing methods used for sample selection, mineral isolation, pretreatments, mineral identification, conventional and developing methods for oxygen and hydrogen isotopic analyses, and determination of phyllosilicate-water equilibrium fractionation factors, concluding with recommendations for best approaches for paleotemperature estimation. Additionally, we discuss how to identify and avoid detrital phyllosilicates, the impacts of diagenesis, comparison of stable isotope and non-isotope paleosol paleotemperature proxies, and challenges and opportunities for broadly using paleosols as paleoclimate archives. With ongoing efforts to refine this multi-faceted paleotemperature approach, the stable isotope geochemistry of soil-formed phyllosilicates continues to be an invaluable proxy system, enhancing our understanding of terrestrial paleoenvironments and paleoclimate.

Kansas↗

USGS2005

Arsenate adsorption mechanisms at the allophane: Water interface

We investigated arsenate (As(V)) reactivity and surface speciation on amorphous aluminosilicate mineral (synthetic allophane) surfaces using batch adsorption experiments, powder X-ray diffraction (XRD), and X-ray absorption spectroscopy (XAS). The adsorption isotherm experiments indicated that As(V) uptake increased with increasing [As(V)] o from 50 to 1000 μM (i.e., Langmuir type adsorption isotherm) and that the total As adsorption slightly decreased with increasing NaCl concentrations from 0.01 to 0.1 M. Arsenate adsorption was initially (0−10 h) rapid followed by a slow continuum uptake, and the adsorption processes reached the steady state after 720 h. X-ray absorption spectroscopic analyses suggest that As(V) predominantly forms bidentate binuclear surface species on aluminum octahedral structures, and these species are stable up to 11 months. Solubility calculations and powder XRD analyses indicate no evidence of crystalline Al−As(V) precipitates in the experimental systems. Overall, macroscopic and spectroscopic evidence suggest that the As(V) adsorption mechanisms at the allophane−water interface are attributable to ligand exchange reactions between As(V) and surface-coordinated water molecules and hydroxyl and silicate ions. The research findings imply that dissolved tetrahedral oxyanions (e.g., H 2 PO 4 2 - and H 2 AsO 4 2 - ) are readily retained on amorphous aluminosilicate minerals in aquifer and soils at near neutral pH. The inner-sphere adsorption mechanisms might be important in controlling dissolved arsenate and phosphate in amorphous aluminosilicate-rich low-temperature geochemical environments.

Environmental Science & Technology↗

USGS2009

Eolian transport of geogenic hexavalent chromium to ground water

A conceptual model of eolian transport is proposed to address the widely distributed, high concentrations of hexavalent chromium (Cr +6 ) observed in ground water in the Emirate of Abu Dhabi, United Arab Emirates. Concentrations (30 to more than 1000 μg/L Cr +6 ) extend over thousands of square kilometers of ground water systems. It is hypothesized that the Cr is derived from weathering of chromium-rich pyroxenes and olivines present in ophiolite sequence of the adjacent Oman (Hajar) Mountains. Cr +3 in the minerals is oxidized to Cr +6 by reduction of manganese and is subsequently sorbed on iron and manganese oxide coatings of particles. When the surfaces of these particles are abraded in this arid environment, they release fine, micrometer-sized, coated particles that are easily transported over large distances by wind and subsequently deposited on the surface. During ground water recharge events, the readily soluble Cr +6 is mobilized by rain water and transported by advective flow into the underlying aquifer. Chromium analyses of ground water, rain, dust, and surface (soil) deposits are consistent with this model, as are electron probe analyses of clasts derived from the eroding Oman ophiolite sequence. Ground water recharge flux is proposed to exercise some control over Cr +6 concentration in the aquifer.

Ground Water↗

USGS1970

Comparative hydrogeology: An example of its use

As a start toward needed classifications of hydrogeologic settings, a type of setting is described. The setting includes areas where soluble materials are exposed to considerable recharge from precipitation and where both the topographic relief and permeability are inappreciable. Typical areas of this setting are (1) the Black Belt of the Coastal Plain of Alabama and Mississippi, underlain by chalk of the Selma Group, and (2) a 25-sq-mi area near Harrisburg, Cabarrus County, North Carolina, underlain by gabbro in the Piedmont province. Hydrologic conditions that may be inferred and that are easily discernible from this type of setting include: excessive evapotranspiration, low water-table gradient, water table near land surface, thin soils, ground-water movement being almost inappreciable, and the zone of movement being almost limited to a thin zone that includes the contact between the soil and rock, inappreciable ground-water discharge to streams leading, in turn, to a low base flow in streams, low drainage density, and subsurface water relatively high in dissolved mineral matter. Evaluation of the hydrogeologic setting described leads inductively into the undeveloped field of comparative hydrology, which represents a quick useful means of discerning the significance of processes and principles in particular environments. The setting reveals the significance of solution by subsurface water in developing some plains. Comparative hydrology, using the described setting and typical karst settings as examples, allows an advanced analysis of some pertinent factors.

Alabama, Mississippi, North Carolina↗

USGS2023

High-resolution geophysical and geochronological analysis of a relict shoreface deposit offshore central California: Implications for slip rate along the Hosgri fault

The Cross-Hosgri slope is a bathymetric lineament that crosses the main strand of the Hosgri fault offshore Point Estero, central California. Recently collected chirp seismic reflection profiles and sediment cores provide the basis for a reassessment of Cross-Hosgri slope origin and the lateral slip rate of the Hosgri fault based on offset of the lower slope break of the Cross-Hosgri slope. The Cross-Hosgri slope is comprised of two distinct stratigraphic units. The lower unit (unit 1) overlies the post–Last Glacial Maximum transgressive erosion surface and is interpreted as a Younger Dryas (ca. 12.85–11.65 ka) shoreface deposit based on radiocarbon and optically stimulated luminescence (OSL) ages, Bayesian age modeling, seismic facies, sediment texture, sediment infauna, and heavy mineral component. The shoreface was abandoned and partly eroded during rapid sea-level rise from ca. 11.5 to 7 ka. Unit 2 consists of fine sand and silt deposited in a midshelf environment when the rate of sea-level rise slowed between ca. 7 ka and the present. Although unit 2 provides a thin, relatively uniform cover over the lower slope break of the older shoreface, this feature still represents a valuable piercing point, providing a Hosgri fault slip rate of 2.6 ± 0.8 mm/yr. Full-waveform processing of chirp data resulted in significantly higher resolution in coarser-grained strata, which are typically difficult to interpret with more traditional envelope processing. Our novel combination of offshore radiocarbon and OSL dating is the first application to offshore paleoseismic studies, and our results indicate the utility of this approach for future marine neotectonic investigations.

California↗

USGS2008

Hierarchy of sedimentary discontinuity surfaces and condensed beds from the middle Paleozoic of eastern North America: Implications for cratonic sequence stratigraphy

Sedimentological analyses of middle Paleozoic epeiric sea successions in North America suggest a hierarchy of discontinuity surfaces and condensed beds of increasing complexity. Simple firmgrounds and hardgrounds, which are comparatively ephemeral features, form the base of the hierarchy. Composite hardgrounds, reworked concretions, authigenic mineral crusts and monomictic intraformational conglomerates indicate more complex histories. Polymictic intraformational conglomerates, ironstones and phosphorites form the most complex discontinuity surfaces and condensed beds. Complexity of discontinuities is closely linked to depositional environments duration of sediment starvation and degree of reworking which in turn show a relationship to stratigraphic cyclicity. A model of cratonic sequence stratigraphy is generated by combining data on the complexity and lateral distribution of discontinuities in the context of facies successions. Lowstand, early transgressive and late transgressive systems tracts are representative of sea-level rise. Early and late transgressive systems tracts are separated by the maximum starvation surface (typically a polymictic intraformational conglomerate or condensed phosphorite), deposited during the peak rate of sea-level rise. Conversely the maximum flooding surface, representing the highest stand of sea level, is marked by little to no break in sedimentation. The highstand and falling stage systems tracts are deposited during relative sea-level fall. They are separated by the forced-regression surface, a thin discontinuity surface or condensed bed developed during the most rapid rate of sea-level fall. The lowest stand of sea level is marked by the sequence boundary. In subaerially exposed areas it is occasionally modified as a rockground or composite hardground.

Conference Paper↗

USGS1980

A lead isotope study of mineralization in the Saudi Arabian Shield

New lead isotope data are presented for some late Precambrian and early Paleozoic vein and massive sulfide deposits in the Arabian Shield. Using the Stacey Kramers (1975) model for lead isotope evolution, isochron model ages range between 720 m.y. and 420 m.y. Most of the massive sulfide deposits in the region formed before 680 m.y. ago, during evolution of the shield. Vein type mineralization of higher lead content occurred during the Pan African event about 550 m.y. ago and continued through the Najd period of extensive faulting in the shield that ended about 530 m.y. ago. Late post-tectonic metamorphism may have been responsible for vein deposits that have model ages less than 500 m.y. Alternatively some of these younger model ages may be too low due to the mineralizing fluids acquiring radiogenic lead from appreciably older local crustal rocks at the time of ore formation. The low207Pb/204Pb ratios found for the deposits in the main part of the shield and for those in north-eastern Egypt, indicate that the Arabian craton was formed in an oceanic crustal environment during the late Precambrian. Involvement of older, upper-crustal material in the formation of the ore deposits in this part of the shield is precluded by their low207Pb/204Pb and208Pb/204Pb characteristics. In the eastern part of the shield, east of longitude 44??20???E towards the Al Amar-Idsas fault region, lead data are quite different. They exhibit a linear207Pb/204Pb-206Pb/204Pb relationship together with distinctly higher208Pb/204Pb characteristics. These data imply the existence of lower crustal rocks of early Proterozoic age that apparently have underthrust the shield rocks from the east. If most of the samples we have analyzed from this easterly region were mineralized 530 m.y. ago, then the age of the older continental rocks is 2,100??300 m.y. (2??). The presence of upper crustal rocks, possibly also of early Proterozoic age, is indicated by galena data from Hailan in South Yemen and also from near Muscat in Oman. These data are the first to indicate such old continental material in these regions. ?? 1980 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

USGS1961

Origin of Pennsylvanian underclay and related seat rocks

Seat rocks, including underclay, underlie coal beds and show features such as roots, profiles similar to water-logged soils, lack of bedding, soil-like fracture, and gradation into normally bedded sedimentary rocks indicating that they were once soils. Coarse-grained seat rocks range from argillaceous to nearly pure quartz sandstone (ganister). Seat rocks composed of clay-sized particles (underclays) range from mixtures of illite, mixed-layer clay, and kaolinite to essentially pure kaolinite. Variations in the quartz or kaolinite content suggest that there are degrees of alteration in the formation of a seat rock and that all kinds of seat rock were formed by leaching of the substratum in a swamp. The increasing crystallinity of the clay minerals from plastic underclays to semiflint clay to flint clay and the corresponding increase in titanium support this conclusion. These two features suggest strongly that flint clays formed in place in an acidic swamp environment. The Olive Hill clay shows residual acidity. Seat rocks are affected by the chemical environments in the swamp before peat accumulation, during peat accumulation, and during coalification. Kaolinite is forming in present-day swamps and in wet acidic soils in Hawaii and probably formed in late Paleozoic swamps. The facts can be interpreted to show that all kinds of seat rocks could have formed in Pennsylvanian swamps and probably most did.

Geological Society of America Bulletin↗

USGS2003

Applied geochemistry, geology and mineralogy of the northernmost Carlin trend, Nevada

Investigations in the northernmost Carlin trend were undertaken to advance understanding of the geochemical signatures and genesis of precious metal deposits in the trend . Two fundamental geologic relationships near the trend significantly affect regional geochemical distributions: a remarkably intact lower Paleozoic stratigraphic sequence of siliceous rocks in the upper plate of the middle Paleozoic Roberts Mountains thrust, and the widespread repetition of rocks high in the upper plate during late Paleozoic thrusting that thickens the cover above mineralized rock in the lower plate. A compilation of previously published chemical analyses of 440 stream sediment samples and 115 rocks from two 7 1/2-minute quadrangles, as well as new chemical analyses of approximately 1,000 drill core samples in a 1,514 m (4,970 ft) hole through the Rodeo Creek deposit were used to construct three-dimensional element distribution models that highlight metal zonation in the mineralized systems. The Rodeo Creek deposit comprises deep Ag base-metal ± Au-mineralized rock below the Roberts Mountains thrust and contains an unusually high Ag/Au ratio greater than 30. Stacked geochemical halos related to the deposit are confined to the lower plate of the Roberts Mountains thrust and include two horizons of Hg, Cu, and Zn anomalies-as much as 180 m above the deposit-that mostly result from mercurian sphalerite. Extremely subtle indications of mineralization in the upper plate of the Roberts Mountains thrust above the deposit include arsenopyrite overgrowths on small pyrite crystals in 50- to 75-μm-wide clay-carbonate veinlets that lack alteration halos, arsenical rims on small disseminated crystal of recrystallized diagenetic pyrite, and partial replacement of diagenetic pyrite by tennantite. Some of these minerals contain anomalously high Au. However, these As-(Au)-bearing rocks most likely represent another locus of largely untested mineralized rock rather than distal halos related to either the Rodeo Creek or the nearby Dee and Storm gold deposits. Application of micromineralogic techniques helped to identify mineral assemblages that are specific to mineralization and provided an empirical foundation for interpretations of geochemical halos in the Carlin trend . District-scale geochemical patterns of several elements in stream sediments and surface rocks coincide with the northernmost Carlin trend and can be used to explore for Carlin -type deposits. Concentrations of elevated As and Sb in stream sediments (as much as 54 ppm As) have northwest-elongate lobate patterns that clearly outline the trend across a width of approximately 4 km. Arsenic contents of exposed rocks (as much as 90 ppm As) strongly correlate with As contents of derivative stream sediments, and rock contents of Sb show a somewhat lesser but nonetheless strong and similar correspondence. Factor analysis of stream-sediment data shows that those factor scores that are correlated with As, Sb, Au, and Pb also are high along the trend and suggest that mineralized rocks may be present. Although As was not detected by scanning electron microscope-energy dispersive spectrometer (SEM-EDS) studies in heavy mineral concentrates of high-As stream sediments in the Carlin trend , X-ray absorption near-edge spectra (XANES) of selected light fractions of stream sediment samples indicate that Al-bearing phases, such as gibbsite, amorphous Al oxyhydroxides, or aluminosilicate clay minerals host most of the As(V). The best fit, visually and in terms of the lowest residual, was obtained by a model compound of As(V) sorbed to gibbsite. Thus, most As in stream sediments derived from altered rock within the Carlin trend apparently is contained in light fractions. The geochemical character of young, unconsolidated, postmineral deposits that cover mineralized rocks on the Carlin trend partly results from mineralized sources along the trend . Concentration of As in the Miocene Carlin Formation shows an exceptionally well developed progressive increase to about 30 ppm As as altered rock surrounding the trend is approached. Mineralized and/or altered rock fragments probably have been shed directly into the sedimentary basin of the Carlin Formation, and migration of As, now fixed as As(V), also may have occurred in the supergene environment after material was recycled out of the Carlin Formation and into present-day gulleys.

Nevada↗

USGS1996

Paragenetic and minor- and trace-element studies of Mississippi Valley-type ore deposits of the Silesian-Cracow district, Poland

Paragenetic and minor- and trace-element studies were conducted on samples of epigenetic ore and gangue minerals collected from mines and drill core in the Silesian-Cracow (S-C) district of southern Poland. Four discrete mineral suites representing four mineralizing stages can be identified throughout the district. The earliest epigenetic minerals deposited during stage 1 consist of a late dolomite cement together with minor pyrite and marcasite. Stage 2 was the first ore-forming stage and included repetitive deposition of sphalerite and galena in a variety of morphologies. Stage 3 abruptly followed the first ore stage and deposited marcasite and pyrite with variable amounts of late sphalerite and galena. In the samples studied, minerals deposited during stage 3 are predominately marcasite-pyrite with minor sphalerite and galena in the Pomorzany and Olkusz mines, whereas, at the Trzebionka mine, stage 3 mineralization deposited mostly galena and sphalerite with little marcasite or pyrite. Stage 4 minerals include contains barite, followed by calcite, with very minor pyrite and a rare, late granular sphalerite. Compared to other major Mississippi Valley-type (MVT) districts of the world, the Silesian-Cracow district contains sphalerite with the second largest range in Ag concentrations and the largest range in Fe and Cd concentrations of any district. Unlike in other districts, very wide ranges in minor- and trace-element concentrations are also observed in paragenetically equivalent samples collected throughout the district. This wide range indicates that the minor- and trace-element content of the ore-forming environment was highly variable, both spatially and temporally, and suggests that the hydrologic system that the ore fluids traversed from their basinal source was very complex. Throughout the district, a significant increase in Tl, Ge, and As concentrations is accompanied by a lightening of sulfur isotopes between stage 2 and stage 3 minerals. This change appears to record a major district-scale hydrologic event that probably reflects the introduction of fluids with significantly different geochemistry than that of earlier ore-forming fluids.

Prace - Panstwowego Instytutu Geologicznego↗

USGS2005

Mineral mapping on the Chilean-Bolivian Altiplano using co-orbital ALI, ASTER and Hyperion imagery: Data dimensionality issues and solutions

Hyperspectral data coverage from the EO-1 Hyperion sensor was useful for calibrating Advanced Land Imager (ALI) and Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) images of a volcanic terrane area of the Chilean-Bolivian Altiplano. Following calibration, the ALI and ASTER datasets were co-registered and joined to produce a 13-channel reflectance cube spanning the Visible to Short Wave Infrared (0.4-2.4 ??m). Eigen analysis and comparison of the Hyperion data with the ALI + ASTER reflectance data, as well as mapping results using various ALI+ASTER data subsets, provided insights into the information dimensionality of all the data. In particular, high spectral resolution, low signal-to-noise Hyperion data were only marginally better for mineral mapping than the merged 13-channel, low spectral resolution, high signal-to-noise ALI + ASTER dataset. Neither the Hyperion nor the combined ALI + ASTER datasets had sufficient information dimensionality for mapping the diverse range of surface materials exposed on the Altiplano. However, it is possible to optimize the use of the multispectral data for mineral-mapping purposes by careful data subsetting, and by employing other appropriate image-processing strategies.

Remote Sensing of Environment↗

USGS1979

Analysis of borehole geophysical information across a uranium deposit in the Jackson Group, Karnes County, Texas

Borehole geophysical studies across a uranium deposit in the Jackson Group, South Texas, show the three geochemical environments often associated with uranium roll-type deposits: an altered (oxidized) zone, an ore zone, and an unaltered (reduced) zone. Mineralogic analysis of the total sulfides contained in the drill core shows only slight changes in the total sulfide content among the three geochemical regimes. However, induced polarization measurements on the core samples indicate that samples obtained from the reduced side of the ore zone are more electrically polarizable than those from the oxidized side of the ore zone, and therefore probably contain more pyrite. Analysis of the clay-size fraction in core samples indicates that montmorillonite is the dominant clay mineral. High resistivity values within the ore zone indicate the presence of calcite cement concentrations that are higher than those seen outside of the ore zone. Between-hole resistivity and induced polarization measurements show the presence of an extensive zone of calcite cement within the ore zone, and electrical polarizable material (such as pyrite) within and on the reduced side of the ore zone. A quantitative analysis of the between-hole resistivity data, using a layered-earth model, and a qualitative analysis of the between-hole induced polarization measurements showed that mineralogic variations among the three geochemical environments were more pronounced than were indicated by the geophysical and geologic well logs. Uranium exploration in the South Texas Coastal Plain area has focused chiefly in three geologic units: the Oakville Sandstone, the Catahoula Tuff, and the Jackson Group. The Oakville Sandstone and the Catahoula Tuff are of Miocene age, and the Jackson Group is of Eocene age (Eargle and others, 1971). Most of the uranium mineralization in these formations is low grade (often less than 0.02 percent U3O8) and occurs in shallow deposits that are found by concentrated exploratory drilling programs. The sporadic occurrence of these deposits makes it desirable to develop borehole geophysical techniques that will help to define the depositional environments of the uranium ore, which is characterized by geochemical changes near the uranium deposits. Geochemical changes are accompanied by changes in the physical characteristics of the rocks that can be detected with borehole geophysical tools. This study is concerned with a uranium deposit within the Jackson Group that is located just east of Karnes City, Tex. Five holes were drilled on this property to obtain borehole geophysical data and cores. The cores were analyzed for mineralogic and electrical properties. The borehole geophysical information at this property included induced polarization, resistivity, gamma-gamma density, neutron-neutron, gamma-ray, caliper, and single-point-resistance logs. Between-hole resistivity and induced polarization measurements were made between hole pairs across the ore deposit and off the ore deposit.

Open-File Report↗

USGS2004

Geochemistry of shallow ground water in coastal plain environments in the southeastern United States: Implications for aquifer susceptibility

Ground-water chemistry data from coastal plain environments have been examined to determine the geochemical conditions and processes that occur in these areas and assess their implications for aquifer susceptibility. Two distinct geochemical environments were studied to represent a range of conditions: an inner coastal plain setting having more well-drained soils and lower organic carbon (C) content and an outer coastal plain environment that has more poorly drained soils and high organic C content. Higher concentrations of most major ions and dissolved inorganic and organic C in the outer coastal plain setting indicate a greater degree of mineral dissolution and organic matter oxidation. Accordingly, outer coastal plain waters are more reducing than inner coastal plain waters. Low dissolved oxygen (O2) and nitrate (NO 3-) concentrations and high iron (Fe) concentrations indicate that ferric iron (Fe (III)) is an important electron acceptor in this setting, while dissolved O2 is the most common terminal electron acceptor in the inner coastal plain setting. The presence of a wide range of redox conditions in the shallow aquifer system examined here underscores the importance of providing a detailed geochemical characterization of ground water when assessing the intrinsic susceptibility of coastal plain settings. The greater prevalence of aerobic conditions in the inner coastal plain setting makes this region more susceptible to contamination by constituents that are more stable under these conditions and is consistent with the significantly (p<0.05) higher concentrations of NO3- found in this setting. Herbicides and their transformation products were frequently detected (36% of wells sampled), however concentrations were typically low (<0.1 ??g/L). Shallow water table depths often found in coastal plain settings may result in an increased risk of the detection of pesticides (e.g., alachlor) that degrade rapidly in the unsaturated zone.

Applied Geochemistry↗

USGS2020

Position-specific distribution of hydrogen isotopes in natural propane: Effects of thermal cracking, equilibration and biodegradation

Intramolecular isotope distributions, including isotope clumping and position specific fractionation, can provide proxies for the formation temperature and formation and destruction pathways of molecules. In this study, we explore the position-specific hydrogen isotope distribution in propane. We analyzed propane samples from 10 different petroleum systems with high-resolution molecular mass spectrometry. Our results show that the hydrogen isotope fractionation between central and terminal positions of natural propanes ranges from −102‰ to +205‰, a much larger range than that expected for thermodynamic equilibrium at their source and reservoir temperatures (36–63‰). Based on these findings, we propose that the hydrogen isotope structure of catagenic propane is largely controlled by irreversible processes, expressing kinetic isotope effects (KIEs). Kinetic control on hydrogen isotope composition of the products of thermal cracking is supported by a hydrous pyrolysis experiment using the Woodford Shale as substrate, in which we observed isotopic disequilibrium in the early stage of pyrolysis. We make a more general prediction of KIE signatures associated with kerogen cracking by simulating this chemistry in a kinetic Monte Carlo model for different types of kerogens. In contrast, unconventional shale fluids or hot conventional reservoirs contain propane with an isotopic structure close to equilibrium, presumably reflecting internal and/or heterogeneous exchange during high temperature storage (ca. 100–150 °C). In relatively cold (<100 °C) conventional gas accumulations, propane can discharge from its source to a colder reservoir, rapidly enough to preserve disequilibrium signatures even if the source rock thermal maturity is high. These findings imply that long times at elevated temperatures are required to equilibrate the hydrogen isotopic structure of propane in natural gas host rocks and reservoirs. We further defined the kinetics of propane equilibration through hydrogen isotope exchange experiments under hydrous conditions; these experiments show that hydrogen in propane is exchangeable over laboratory timescales when exposed to clay minerals such as kaolinite. This implies rather rapid transfer of propane from sources to cold reservoirs in some of the conventional petroleum systems. Propane is also susceptible to microbial degradation in both oxic and anoxic environments. Biodegradation of propane in the Hadrian and Diana Hoover oil fields (Gulf of Mexico) results in strong increases in central-terminal hydrogen isotope fractionation. This reflects preferential attack on the central position, consistent with previous studies.

Geochimica et Cosmochimica Acta↗

USGS2009

A New Occurrence Model for National Assessment of Undiscovered Volcanogenic Massive Sulfide Deposits

Volcanogenic massive sulfide (VMS) deposits are very significant current and historical resources of Cu-Pb-Zn-Au-Ag, are active exploration targets in several areas of the United States and potentially have significant environmental effects. This new USGS VMS deposit model provides a comprehensive review of deposit occurrence and ore genesis, and fully integrates recent advances in the understanding of active seafloor VMS-forming environments, and integrates consideration of geoenvironmental consequences of mining VMS deposits. Because VMS deposits exhibit a broad range of geological and geochemical characteristics, a suitable classification system is required to incorporate these variations into the mineral deposit model. We classify VMS deposits based on compositional variations in volcanic and sedimentary host rocks. The advantage of the classification method is that it provides a closer linkage between tectonic setting and lithostratigraphic assemblages, and an increased predictive capability during field-based studies.

Open-File Report↗

USGS1978

Wood River mining district, Idaho - intrusion-related lead-silver deposits derived from country rock source

Lead-silver deposits in the Wood River mining district occur in shear zones in hornfelsed argillite of the Devonian Milligen Formation near granitic plutons and under the Wood River thrust fault. The principal ore minerals are argentiferous galena and sphalerite; siderite is the principal gangue. The δ 34 S values of the sulfide minerals range from +2.2 to +15.0 permil, indicating that the sulfur had a shallow crustal source. Δ 34 S values between sphalerite and galena range from +2.3 to +3.4 permil, corresponding to sulfur isotope temperatures between 280° and 182 °C. Hydrothermal barite has a δ 34 S of +13.2 permil. Lead isotope ratios are radiogenic, also pointing to a shallow crustal source. Quartz gangue has δ 18 O of +16.4 permil and a calculated δ 18 O H20 at 270°C of +8.4 permil. This value is reasonable for a hydrothermal fluid that had reached equilibrium with the argillite country rock. The siderite gangue has δ 18 O and δ 13 C values of +14.0 and -5.5 permil, respectively. Fluid inclusions have homogenization temperatures of 244°-307°C and average 270°C. Freezing-stage measurements ranged from -1.85 to -2.8°C, suggesting salinities of 3.2 to 4.8 weight percent. The δD values of inclusion fluid in ore and gangue minerals are -110 to -120 permil. The geology, isotope, and fluid-inclusion data are consistent with a model of hydrothermal systems of meteoric water in faulted and shattered Paleozoic rocks near plutonic masses. This environment permitted deep circulation of the hydrothermal fluids, which dissolved the metals and sulfur from the Paleozoic host rocks and deposited ore in favorable beds or structures under the regional Wood River thrust fault.

Idaho↗

USGS2022

Geochemical studies of the Green River Formation in the Piceance Basin, Colorado: I. Major, minor, and trace elements

The Eocene Green River Formation contains the largest oil shale deposits in the world and is a welldocumented example of a lacustrine depositional system. In addition, mineral resources associated with oil shale in the Piceance Basin nahcolite [NaHCO3] and dawsonite [NaAl(CO3)(OH)2)] are of current and potential economic value, respectively. Detailed geochemical analysis across the basin can aid in the understanding of the depositional environment, sedimentary processes, and water-chemistry evolution in this system. Quantitative geochemical data for Green River oil shale from the Piceance Basin of Colorado were collected by inductively coupled plasma optical emission spectroscopy and mass spectrometry as part of this study. The basin margin is represented by samples from exposures at Douglas Pass (Garfield County) and the basin center area is characterized by core samples from two drilled wells: the Shell 23X-2 and John Savage 24-1 (Rio Blanco County). Major elements and groups of elements are used as proxies for clastic influx (Si, Al, K, Ti), carbonate deposition (Ca, Mg), salinity (Na), paleo-productivity (P), and redox state (Fe, S), respectively. Minor and trace elements reinforce observations based on major elements, including Rb, Zr, Nb for clastic influx and Mn, Sr for carbonate. Trace elements are used to characterize redox conditions (As, Mo, U, V, Co, Ni, Cu, Zn) and salinity (Rb/K, B/Ga). Chemical distinctions between the basin margin and the basin center, in terms of these components and total organic carbon concentrations, support the model of a permanently stratified lake through most of the depositional interval. A primary purpose of the study was to conduct more extensive sampling to confirm conclusions of a previous reconnaissance study. Geochemical data from this study indicates elevated Na around the basin margin occurring earlier than in the deeper basin. Early in the history of Lake Uinta, the salinity may have been elevated first in the shallower marginal waters, due to increased evaporation, which then led to elevated salinity in the basin center through transport of saline density currents. Other indicators of salinity (Rb/K, B/Ga) do not track Na content in intervals where clay minerals are absent due to diagenetic alteration under hypersaline conditions but may be used to indicate the salinities at which authigenic Na-bearing minerals begin to form. Most Na-rich samples show high proportions of clastic constituents (Si, Al, K, Ti) compared to conventional carbonate constituents (Ca, Mg). Redox-sensitive period IV transition metal elements (V, Co, Ni, Cu, Zn) show only local occurrence of significant enrichment relative to average shale abundances. Analysis of Fe/Al ratios for this dataset suggests that the depletion of these elements may be related to source rocks depleted in mafic constituents, with apparent redox-related enrichments subdued by this effect. The basin margin samples reflect generally oxic bottom waters, with some intervals deposited under more reducing, possibly dysoxic to anoxic conditions. The basin center results indicate more reducing conditions, with Mo and U enrichment factors suggesting operation of a particulate shuttle mechanism that scavenged Mo on Fe/Mn-oxyhydroxides that redissolved at depth, with Mo precipitating along with sulfides and/or organic matter at or near the sediment/water interface.

Colorado↗

USGS2021

GIS-based identification of areas that have resource potential for lode gold in Alaska

Several comprehensive, data-driven geographic information system (GIS) analyses were conducted to assess prospectivity for lode gold in Alaska. These analyses use available geospatial datasets of lithologic, geochemical, mineral occurrence, and geophysical data to build models for recognizing different types of gold deposits within physiographic units defined by stream drainage basins that are approximately 100 square kilometers in area. The analytical methods successfully delineated areas in the State that contain known lode gold deposits and occurrences, providing some measure of confidence in their ability to predict gold prospectivity in areas of unknown lode gold potential. The results of our analyses indicate high prospectivity in a few areas scattered around the State that are not known to contain lode gold deposits. In addition to assessing the potential for lode gold deposits in Alaska, we designed analyses to distinguish different lode gold deposit types, including orogenic, reduced-intrusion-related, epithermal, and gold-bearing porphyry. These can primarily be differentiated using their unique trace element geochemical fingerprints and elemental enrichments, which reflect the characteristics of the geologic environment and chemistry of the ore-forming fluids. We identified multiple parameters that would discriminate the different types of gold deposits, but owing to the limits of available data, the compositional similarity of ore-forming fluids among some types of lode gold deposits, and overlapping geologic environments, distinguishing deposit types at the state scale in Alaska remains problematic. These limitations resulted in overlapping areas of prospectivity for different deposit types, highlighting the challenges for targeted gold exploration in Alaska. Adjustment of some scoring parameters and recharacterization at smaller scales to highlight individual mineral systems for application of prospectivity analyses may be helpful at a district scale. At a regional scale, the aerial overlap of individual deposit type analyses reinforces confidence in prospectivity for a lode gold resource in a drainage basin. Our analysis for undivided lode gold deposits will be the most practical analysis for landuse decisions in which delineation of areas that have confident potential for gold deposits in general is the primary goal. Data-driven GIS analysis for lode gold potential in Alaska, although limited by the size and uneven coverage of available datasets, objectively indicates prospectivity in areas where exposure is good as well as in areas under cover. The results of our analyses show medium to high prospectivity in areas that surround known deposits, indicating an overall expansion of areas that have the potential to contain gold deposits. Exploration in these areas may help improve the balance between the volume of gold produced in placer districts statewide and the relatively low volume of identified lode resources that contribute to these placer deposits. The results of our analyses can help focus future investigations in areas that show prospectivity but are not known to contain gold deposits, as well as in areas where data are lacking and the geology is poorly understood, and acquisition of additional data may help better define and constrain gold prospectivity.

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