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At least 433 records · Page 24Linked to original sources

USGS2024

Computationally efficient emulation of spheroidal elastic deformation sources using machine learning models: a Gaussian-process-based approach

Elastic continuum mechanical models are widely used to compute deformations due to pressure changes in buried cavities, such as magma reservoirs. In general, analytical models are fast but can be inaccurate as they do not correctly satisfy boundary conditions for many geometries, while numerical models are slow and may require specialized expertise and software. To overcome these limitations, we trained supervised machine learning emulators (model surrogates) based on parallel partial Gaussian processes which predict the output of a finite element numerical model with high fidelity but >1,000× greater computational efficiency. The emulators are based on generalized nondimensional forms of governing equations for finite non‐dipping spheroidal cavities in elastic halfspaces. Either cavity volume change or uniform pressure change boundary conditions can be specified, and the models predict both surface displacements and cavity (pore) compressibility. Because of their computational efficiency, using the emulators as numerical model surrogates can greatly accelerate data inversion algorithms such as those employing Bayesian Markov chain Monte Carlo sampling. The emulators also permit a comprehensive evaluation of how displacements and cavity compressibility vary with geometry and material properties, revealing the limitations of analytical models. Our open‐source emulator code can be utilized without finite element software, is suitable for a wide range of cavity geometries and depths, includes an estimate of uncertainties associated with emulation, and can be used to train new emulators for different source geometries.

JGR Machine Learning and Computation↗

USGS2011

Decomposition of heterogeneous organic matterand its long-term stabilization in soils

Soil organic matter is a complex mixture of material with heterogeneous biological, physical, and chemical properties. Decomposition models represent this heterogeneity either as a set of discrete pools with different residence times or as a continuum of qualities. It is unclear though, whether these two different approaches yield comparable predictions of organic matter dynamics. Here, we compare predictions from these two different approaches and propose an intermediate approach to study organic matter decomposition based on concepts from continuous models implemented numerically. We found that the disagreement between discrete and continuous approaches can be considerable depending on the degree of nonlinearity of the model and simulation time. The two approaches can diverge substantially for predicting long-term processes in soils. Based on our alternative approach, which is a modification of the continuous quality theory, we explored the temporal patterns that emerge by treating substrate heterogeneity explicitly. The analysis suggests that the pattern of carbon mineralization over time is highly dependent on the degree and form of nonlinearity in the model, mostly expressed as differences in microbial growth and efficiency for different substrates. Moreover, short-term stabilization and destabilization mechanisms operating simultaneously result in long-term accumulation of carbon characterized by low decomposition rates, independent of the characteristics of the incoming litter. We show that representation of heterogeneity in the decomposition process can lead to substantial improvements in our understanding of carbon mineralization and its long-term stability in soils.

Ecological Monographs↗

USGS2015

Magma fracturing and degassing associated with obsidian formation: The explosive–effusive transition

This paper explores the role of melt fracturing in degassing rhyolitic volcanic systems. The Monte Pilato-Rocche Rosse eruptions in Italy evolved from explosive to effusive in style, and H 2 O content in quenched glasses changed over time from relatively H 2 O-rich (~ 0.90 wt.%) to H 2 O-poor dense obsidian (~ 0.10–0.20 wt.%). In addition, healed fractures have been recorded in all different eruptive materials, from the glass of early-erupted tube pumice and rinds of breadcrusted obsidian pyroclasts, to the glass of late-erupted dense obsidian pyroclasts, and throughout the final effusive Rocche Rosse lava flow. These rocks show multiple fault sets, some with crenulated fault planes indicating resumption of viscous flow after faulting, complex obsidian breccias with evidence for post-brecciation folding and stretching, and centimetre- to metre-thick tuffisite preserved in pyroclasts and lava, representing collapsed foam due to fracturing of vesicle walls. These microstructural observations indicate that multiple fracturing and healing events occurred during both explosive and effusive eruptions. H 2 O content in glass decreases by as much as 0.14 wt.% towards healed fractures/faults and decreases in stretched obsidian breccias towards regions of intense brecciation. A drop in pressure and/or increase in temperature along fractures caused diffusive H 2 O migration through melt towards fracture surfaces. Repetitive and pervasive fracturing and healing thereby create conditions for diffusive H 2 O loss into fractures and subsequent escape through permeable paths. This type of progressive magma degassing provides a potential mechanism to explain the formation of dense obsidian and the evolution from explosive to effusive eruption style.

Monte Pilato-Rocche Rosse↗

USGS2020

Combining ash analyses with remote sensing to identify juvenile magma involvement and fragmentation mechanisms during the 2018/19 small eruption of Peteroa volcano (Southern Andes)

The Planchón Peteroa Volcanic Complex (PPVC) is located on the border of Chile and Argentina, and is one of the most active volcanic systems in the Andes. Holocene activity has included magma-water interaction with an evolving series of crater lakes, mainly sourced from Peteroa volcano. This study examines data from the 2018/19 eruption, together with the volcanic history of the PPVC, to elucidate the complex interplay between magmatic activity and summit water and ice. From February 2016 to mid-2019, three seismic swarms occurred in the PPVC, preceding the explosive eruption from September 2018 to April 2019. The activity originated from a small vent nested within the easternmost crater, the most active portion of the complex (Peteroa). The explosions interacted with a crater lake, producing ash plumes up to 2 km above the crater and building a small tephra cone. To investigate the eruption mechanisms, we performed remote sensing analysis of plume dispersal, thermal anomalies and ground deformation, and characterized the volcanic products, including grain size, componentry, morphology, internal textures, composition and mineralogy. Our results suggest that the precursory seismicity beginning in 2016 was related to the intrusion of a new magma batch that reached the surface during the 2018/19 eruption. The eruption was also preceded by thermal anomalies, geomorphic changes and increased hydrothermal activity at the surface, though without any ground deformation recognized through radar interferometry (InSAR). The eruption initially produced predominantly recycled ash (phreatic activity), then evolved to increasing proportions of juvenile magma (phreatomagmatic) by April 2019. The juvenile clasts had a trachyandesite composition (~59 wt% SiO 2 ), with vesicular and dense scoria containing plagioclase and pyroxene. The ash surfaces show external quenching cracks and step fractures consistent with phreatomagmatic fragmentation within the active crater lake. Textural characteristics also point to a slowly ascending batch of magma that was relatively viscous by the time it interacted with water in the crater lake. Notably, these juvenile particles are distinctive from the pre-2018 products. Ash erupted from 2010/11 did not contain recognizable juvenile material, and is inferred to have been a mainly phreatic eruption. Our findings suggest that the interplay between phreatic and phreatomagmatic eruptions fed by small magma batches intruding at shallow levels characterize much of the eruptive behavior of the PPVC during the last three decades. Multi-parametric assessment is a powerful tool to discriminate between phreatic and phreatomagmatic eruptions.

Southern Andes↗

USGS2006

Frictional strength heterogeneity and surface heat flow: Implications for the strength of the creeping San Andreas fault

Heat flow measurements along much of the San Andreas fault (SAF) constrain the apparent coefficient of friction (??app) of the fault to <0.2, much lower than laboratory-derived friction values for most geologic materials. However, heat flow data are sparse near the creeping section of the SAF, a frictional "asperity" where the fault slips almost exclusively by aseismic creep. We test the hypothesis that the creeping section has a substantially higher or lower ?? app than adjacent sections of the SAF. We use numerical models to explore the effects of faults with spatially and temporally heterogeneous frictional strength on the spatial distribution of surface heat flow. Heat flow from finite length asperities is uniformly lower than predicted by assuming an infinitely long fault. Over geologic time, lateral offset from strike-slip faulting produces heat flow patterns that are asymmetric across the fault and along strike. We explore a range of asperity sizes, slip rates, and displacement histories for comparing predicted spatial patterns of heat flow with existing measurements. Models with ??app ??? 0.1 fit the data best. For most scenarios, heat flow anomalies from a frictional asperity with ??app > 0.2 should be detectable even with the sparse existing observations, implying that ??app for the creeping section is as low as the surrounding SAF. Because the creeping section does not slip in large earthquakes, the mechanism controlling its weakness is not related to dynamic processes resulting from high slip rate earthquake ruptures. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

USGS1991

A comparison of Sr-Nd-Pb isotopes in young and old continental lithospheric mantle: Patagonia and eastern China

It is commonly accepted that beneath the continental crust lies a keel of lithospheric mantle, which extends 50–200 kilometres downward to a transition zone into the asthenosphere. The chemical and physical properties of this reservoir are best known through studies of the basalts and xenoliths that provide samples of the subcrustal mantle. Although sharing many characteristics with oceanic island basalts, some continental basalts become increasingly distinct isotopically as crustal age increases, strongly supporting a permanent association between crust and mantle. Consequently, the distinctive trace element and isotope composition of the lithospheric mantle is able to give important clues to its origin and evolution. The mantle under newly‐created crust is typified by a radiogenic isotope variability that emphasizes the materials from which the continental lithosphere is assembled. Old lithospheric mantle, on the other hand, exhibits more evolved isotopic patterns that attest to the existence of long‐lived, chemically complex systems. A comparison of the Pb, Sr and Nd isotopes in alkalic to sub‐alkalic basalt derived from Phanerozoic (Patagonia) and Middle Archaean to Early Proterozoic (eastern China) subcrustal mantle is useful for identifying ‘end‐member’ components of the lithosphere. One component, having an isotopic composition close to PREMA, either continues to evolve virtually unchanged after incorporation into the lithosphere or is, itself, a relatively new addition even to old lithosphere. Another component, beginning with the isotopic composition of BSE, undergoes significant reduction in U/Pb and Sm/Nd (but not Rb/Sr) upon incorporation into the lithosphere and, with time, shows an increasingly retarded evolution of 206 Pb/ 204 Pb and negative ε Nd‐values approaching the isotopic composition of EMI. Five models are discussed that relate the isotopic composition of the continental lithospheric mantle to that of other parts of the terrestrial system, which may be involved in its origin and evolution. The potential locations of the contributing components and the mechanisms and timing of their assembly into lithosphere are considered. Current knowledge, however, does not allow us to distinguish unequivocally among the various scenarios for the creation and evolution of this reservoir.

Australian Journal of Earth Sciences↗

USGS2024

International Ocean Discovery Program Expedition 389 preliminary report: Hawaiian drowned reefs

Our understanding of the mechanisms controlling eustatic sea level and global climate changes has been hampered by a lack of appropriate fossil coral records over the last 500 ky, particularly into and out of the glacial periods. This problem was addressed by International Ocean Discovery Program Expedition 389 by drilling a unique succession of Hawaiian drowned coral reefs now at 110–1300 meters below sea level (mbsl). The four objectives are to investigate (1) the timing, rate, and amplitude of sea level variability to examine cryosphere and geophysical processes, including the assessment of abrupt sea level change events; (2) the processes that determine changes in mean and high-frequency (seasonal–interannual) climate variability from times with different boundary conditions (e.g., ice sheet size, p CO 2 , and solar forcing); (3) the response of coral reef systems to abrupt sea level and climate changes; and (4) the variation through space and time of the subsidence and the volcanic evolution of the island. To achieve these objectives, 35 holes at 16 sites ranging 131.9–1241.8 mbsl were drilled during the expedition. A total of 425 m of core was recovered, comprising reef (83%) and volcanic (17%) material. Average core recoveries were 66%, with numerous intervals characterized by very well preserved mixtures of coralgal and microbialite frameworks with recoveries >90%. Some science-critical shallow sites were not drilled due to a failure to secure permits to operate in Hawaiian state waters. Furthermore, apart from one site the target penetration depths were not achieved. Preliminary radiometric dates indicate that the recovered reef deposits are from 488 to 13 ka in age. The Onshore Science Party took place in February 2024. Cores were CT and hyperspectral scanned and described. Standard measurements were made, and samples were taken for postcruise research. Preliminary assessment of the age and quality of the reef and basalt cores suggest that many of the expedition objectives will be met.

Hawaii↗

USGS2020

Plastic faulting in ice

Plastic faulting is a brittle‐like failure phenomenon exhibited by water ice and several other rock types under confinement. It is suspected to be the mechanism of deep earthquakes and extreme cases of shear localization in shallow rocks. Unlike ordinary Coulombic failure, plastic faulting is characterized by a pressure‐independent failure strength and fault plane oriented 45° to maximum principal stress. To research the question of how the instability initiates, we conducted over 50 constant‐displacement‐rate experiments on polycrystalline ice (phases Ih and II) near the brittle‐to‐ductile (B‐D) transition, at confining pressures P = 0–300 MPa, applied strain rates = 5 × 10 −5 – 7 × 10 −3 s −1 , temperatures T = 105–233 K, and mean grain sizes d = 0.25–1.18 mm. We find that (1) the width of the B‐D transition in variable space is vanishingly narrow, to the point of appearing as a crossover, (2) a plastic fault plane, once formed, is not a zone of subsequent weakness, (3) distributed ice I→II phase transformation in small amounts (<1 vol%) shows no causal relationship to subsequent failure, and (4) plastic faulting also occurs in ice II. We hypothesize that the elusive nucleating “trigger” parallels that of metals and ceramics undergoing severe plastic deformation, wherein transient local structural rearrangement occurs, in turn causing material strength to drop to a level sufficiently low, in a volume sufficiently large, that adiabatic instability is nucleated. Our results do not require and often are inconsistent with phase transformation. Plastic faulting may therefore be available to all solids undergoing severe deformation, and its appearance in so few is simply the result of insufficiently extreme conditions.

Journal of Geophysical Research- Solid Earth↗

USGS2016

Rock-avalanche dynamics revealed by large-scale field mapping and seismic signals at a highly mobile avalanche in the West Salt Creek valley, western Colorado

On 25 May 2014, a rain-on-snow–induced rock avalanche occurred in the West Salt Creek valley on the northern flank of Grand Mesa in western Colorado (United States). The avalanche mobilized from a preexisting rock slide in the Green River Formation and traveled 4.6 km down the confined valley, killing three people. The avalanche was rare for the contiguous United States because of its large size (54.5 Mm3) and high mobility (height/length = 0.14). To understand the avalanche failure sequence, mechanisms, and mobility, we conducted a forensic analysis using large-scale (1:1000) structural mapping and seismic data. We used high-resolution, unmanned aircraft system imagery as a base for field mapping, and analyzed seismic data from 22 broadband stations (distances < 656 km from the rock-slide source area) and one short-period network. We inverted broadband data to derive a time series of forces that the avalanche exerted on the earth and tracked these forces using curves in the avalanche path. Our results revealed that the rock avalanche was a cascade of landslide events, rather than a single massive failure. The sequence began with an early morning landslide/debris flow that started ∼10 h before the main avalanche. The main avalanche lasted ∼3.5 min and traveled at average velocities ranging from 15 to 36 m/s. For at least two hours after the avalanche ceased movement, a central, hummock-rich core continued to move slowly. Since 25 May 2014, numerous shallow landslides, rock slides, and rock falls have created new structures and modified avalanche topography. Mobility of the main avalanche and central core was likely enhanced by valley floor material that liquefied from undrained loading by the overriding avalanche. Although the base was likely at least partially liquefied, our mapping indicates that the overriding avalanche internally deformed predominantly by sliding along discrete shear surfaces in material that was nearly dry and had substantial frictional strength. These results indicate that the West Salt Creek avalanche, and probably other long-traveled avalanches, could be modeled as two layers: a thin, liquefied basal layer, and a thicker and stronger overriding layer.

Colorado↗

USGS1994

The Nd-, Sr- and Pb-isotopic character of lavas from Taal, Laguna de Bay and Arayat volcanoes, southwestern Luzon, Philippines: Implications for arc magma petrogenesis

Following the amalgamation of a collage of pre-Neogene terranes largely by strike-slip and convergence mechanisms to form the Philippine islands, volcanic chains, related to oppositely dipping subduction zones, developed along the eastern and western margins of the archipelago. There is ample field evidence that this volcanic activity, predominantly calc-alkaline in chemical character, had commenced by the Oligocene. Volcanoes resulting from subduction along the Manila-Negros trench in the west (e.g. Taal, Laguna de Bay and Arayat) form a high-angle linear array, trending away from the MORE field on Pb-isotopic covariation diagrams; have the highest Sr- and lowest Nd-isotopic compositions, of the two chains (but nevertheless plotting above bulk earth on the 87 Sr/ 86 Sr versus 143 Nd/ 144 Nd covariation diagram); and exhibit Sm/Nd and Rb/Sr values that are lower and higher, respectively, than the estimated values for bulk earth. While the Sm/Nd and Rb/Sr characteristics are common to both chains, volcanoes associated with the Philippine-East Luzon trench have Pb-isotopic compositions that fall in the Indian Ocean MORB field and that require time-integrated evolution in a high Th/U environment. They also have higher Nd- and lower Sr-isotopic ratios. The source materials of Philippine volcanoes, therefore, have undergone varied recent enrichments in LILE, as indicated by the decoupling of isotopic and elemental ratios. These enrichments, particularly for the western volcanoes, cannot be entirely due to small degrees of partial melting in the mantle wedge, considering that they were accompanied by elevations in radiogenic Pb. Elevated Pb ratios are best explained by the introduction of subducted, continentally derived sediments. The sedimentary component in the western volcanoes is probably the South China Sea sediments derived largely from Eurasia. That this component is not available in the Philippine-East Luzon trench is reflected by the fact that the eastern volcanoes have higher Nd- and lower Sr-isotopic ratios as well as less radiogenic common Pb.

southwestern Luzon↗

USGS2024

Origins and nature of large explosive eruptions in the lower East Rift Zone of Kīlauea volcano, Hawaii: Insights from ash characterization and geochemistry

Several powerful explosive eruptions have taken place in the populated lower East Rift Zone of Kīlauea within the past ∼750 years. These have created distinctive landforms, including a tephra rim enclosing Puʻulena Crater immediately south of the Puna Geothermal Venture power station, a tuff cone at Kapoho Crater near the eastern cape of the Island of Hawaiʻi, and a set of littoral cones, the Sand Hill in Nānāwale, where the 1840 lava flow poured into the ocean. Kapoho Crater tuff cone is the largest of these recent pyroclastic features. Mineral, glass, and melt inclusion analyses of tuff cone ash and later fissure-related scoriaceous materials also found within the crater indicate slightly evolved basaltic magmas (1120–1130 °C) that are compositionally similar to parts of the effusive lower East Rift Zone eruptions in 1955 and 2018. Tuff cone magmas were stored at depths of ∼2.5–3.5 km and had pre-eruptive volatile contents (0.5–0.8 wt% H 2 O, 280–340 ppm CO 2 , 1400–1800 ppm S) similar to other Kīlauea eruptions (e.g., 1959, 1960), suggesting that internal magma properties were unlikely to account for the unusual explosiveness of this eruption. Tephra componentry, grain-size analyses, and field observations confirm that the cone grew during a phreatomagmatic eruption mostly of vitric ash, probably where a fissure opened across the coastline or shallow ocean floor nearby. Supporting this hypothesis is the identification of at least two genera of marine diatoms within tuff cone strata. Sand Hill littoral cone ash is also vitric like that of Kapoho Crater, but distinctly coarser with abundant fluidal ejecta represented. In contrast, the Puʻulena Crater eruption deposited lithic ash and related blocks with minor juvenile magmatic contribution; a phreatomagmatic eruption that was dominantly phreatic. Differences in eruption styles are related to unique mechanics that tephra analyses help us interpret. While powerful explosive eruptions in the lower East Rift Zone are rare, they present a definite future hazard for inhabitants in this part of Hawaii.

Hawaii↗

USGS2021

Characteristics of frequent dynamic triggering of microearthquakes in Southern California

Dynamic triggering of earthquakes has been reported at various fault systems. The triggered earthquakes are thought to be caused either directly by dynamic stress changes due to the passing seismic waves, or indirectly by other nonlinear processes that are initiated by the passing waves. Distinguishing these physical mechanisms is difficult because of the general lack of high‐resolution earthquake catalogs and robust means to quantitatively evaluate triggering responses, particularly, delayed responses. Here we use the high‐resolution Quake Template Matching catalog in Southern California to systematically evaluate teleseismic dynamic triggering patterns in the San Jacinto Fault Zone and the Salton Sea Geothermal Field from 2008 to 2017. We develop a new statistical approach to identify triggered cases, finding that approximately 1 out of every 5 global M w ≥ 6 earthquakes dynamically trigger microearthquakes in Southern California. The triggering responses include both instantaneous and delayed triggering, showing a highly heterogeneous pattern and indicating possible evolving triggering thresholds. We do not observe a clear peak ground velocity triggering threshold that can differentiate triggering earthquakes from non‐triggering events, but there are subtle differences in the frequency content that may possibly differentiate the earthquakes. In contrast to the depth distribution of background seismicity, the identified triggered earthquakes tend to concentrate at the edges of the seismogenic zones. Although instantaneously triggered earthquakes are likely a result of dynamic Coulomb stress changes, the cases of delayed dynamic triggering are best explained by nonlinear triggering processes, including cyclic material fatigue, accelerated transient creep, and stochastic frictional heterogeneities.

California↗

USGS2020

A stress-similarity triggering model for aftershocks of the MW6.4 and MW7.1 Ridgecrest earthquakes

The July 2019 M w "> M w 6.4 and 7.1 Ridgecrest earthquakes triggered numerous aftershocks, including clusters of off‐fault aftershocks in an extensional stepover of the Garlock fault, near the town of Olancha, and near Panamint Valley. The locations of the off‐fault aftershocks are consistent with the stress‐similarity model of triggering, which hypothesizes that aftershocks preferentially occur in areas where the mainshock static stress change tensor is similar in orientation to the background stress tensor. The background stress field is determined from the inversion of earthquake focal mechanisms, with the spatial resolution adapted to the local density of earthquakes. The mainshock static stress change is computed using finite‐source models for the M w "> M w 6.4 foreshock and M w "> M w 7.1 mainshock. I quantify the similarity between these two stress fields using the tensor dot product of the normalized deviatoric stress tensors. The off‐fault aftershocks in the Garlock stepover and the Olancha area fall within lobes of positive stress similarity, whereas the aftershocks near Panamint Valley are partially within a lobe. The cluster in the Garlock fault stepover and the smaller of two clusters near Olancha occur in regions of locally anomalous background stress that results in higher stress similarity. I compute the spatial density of M ≥ 2.0 "> M≥2.0 aftershocks and find that the aftershock density increases as a function of stress similarity, with a factor of ∼ 15 "> ∼15 difference between high stress‐similarity and low stress‐similarity areas. This result is robust with respect to the choice of mainshock model and the uncertainty of the background stress field. The aftershock density varies substantially inside the high stress‐similarity lobes, however, indicating that other variable background conditions, such as material properties, temperature, and fluid pressure, may also be playing a role. Specifically, temperature and fluid pressure conditions might help explain the low rate of aftershocks in the Coso geothermal field.

California↗

USGS2009

Northern Monterey Bay upwelling shadow front: Observations of a coastally and surface-trapped buoyant plume

During the upwelling season in central California, northwesterly winds along the coast produce a strong upwelling jet that originates at Point A??o Nuevo and flows southward across the mouth of Monterey Bay. A convergent front with a mean temperature change of 3.77 ?? 0.29??C develops between the warm interior waters and the cold offshore upwelling jet. To examine the forcing mechanisms driving the location and movement of the upwelling shadow front and its effects on biological communities in northern Monterey Bay, oceanographic conditions were monitored using cross-shelf mooring arrays, drifters, and hydrographic surveys along a 20 km stretch of coast extending northwestward from Santa Cruz, California, during the upwelling season of 2007 (May-September). The alongshore location of the upwelling shadow front at the northern edge of the bay was driven by: regional wind forcing, through an alongshore pressure gradient; buoyancy forces due to the temperature change across the front; and local wind forcing (the diurnal sea breeze). The upwelling shadow front behaved as a surface-trapped buoyant current, which is superimposed on a poleward barotropic current, moving up and down the coast up to several kilometers each day. We surmise that the front is advected poleward by a preexisting northward barotropic current of 0.10 m s -1 that arises due to an alongshore pressure gradient caused by focused upwelling at Point A??o Nuevo. The frontal circulation (onshore surface currents) breaks the typical two-dimensional wind-driven, cross-shelf circulation (offshore surface currents) and introduces another way for water, and the material it contains (e.g., pollutants, larvae), to go across the shelf toward shore.Copyright 2009 by the American Geophysical Union.

Journal of Geophysical Research C: Oceans↗

USGS1995

Geology, hydrology, and mechanics of a slow-moving, clay-rich landslide, Honolulu, Hawaii

The Alani-Paty landslide has damaged streets, utilities, and homes built on a debris apron in Honolulu, Oahu, Hawaii. Failure of weathered, crudely stratified, highly plastic, debris-apron deposits has created several similar landslides in southeastern Oahu. The Alani-Paty landslide affects about 60 residential lots. It is about 300 m long, 160 m wide, 7-10 m thick, and consists of two main kinematic elements that are separated by a right-lateral shear zone. One element has moved about 4 m, mainly by translation, down a slope of about 12°, and the adjacent element has moved about 3 m down a slope of 9°. Longitudinal stretching in the upslope third and shortening in the downslope two-thirds characterize deformation in each element; landslides in Ohio, Utah, and Colorado have deformed similarly. Smectite-rich clay layers within the deposits are medium to stiff, and measured angles of residual friction range from 6° to 11° with cohesion intercepts less than 12.5 kPa. Saturated hydraulic conductivity within the landslide decreases with depth; below the slip surface, the hydraulic conductivity increases. Rainfall infiltrates at the ground surface, percolates downward and perches on the zone of low hydraulic conductivity near the slip surface, keeping the slide mostly saturated year round. The main body of the landslide moves during rainy periods, when the ten-day average rainfall exceeds 25 mm/day and the pore-water pressures in the upslope quarter of the landslide increase 10-30 kPa. Pore pressure increases within the landslide occur 1-2 days following the onset of rainfall and result from infiltration of rainfall and runoff; after materials above the perennial water table become saturated, downward propagating pressure waves triggered by bursts of intense rainfall produce further, short-lived increases in pore pressure. This elevated pore pressure at the slip surface triggers movement. The ground-water response in the upslope quarter of the landslide is relatively rapid compared to responses in other landslides described in the literature.

Hawai'i↗

USGS1988

Denitrification in a sand and gravel aquifer

Denitrification was assayed by the acetylene blockage technique in slurried core material obtained from a freshwater sand and gravel aquifer. The aquifer, which has been contaminated with treated sewage for more than 50 years, had a contaminant plume greater than 3.5-km long. Near the contaminant source, groundwater nitrate concentrations were greater than 1 mM, whereas 0.25 km downgradient the central portion of the contaminant plume was anoxic and contained no detectable nitrate. Samples were obtained along the longitudinal axis of the plume (0 to 0.25 km) at several depths from four sites. Denitrification was evident at in situ nitrate concentrations at all sites tested; rates ranged from 2.3 to 260 pmol of N 2 O produced (g of wet sediment) −1 h −1 . Rates were highest nearest the contaminant source and decreased with increasing distance downgradient. Denitrification was the predominant nitrate-reducing activity; no evidence was found for nitrate reduction to ammonium at any site. Denitrifying activity was carbon limited and not nitrate limited, except when the ambient nitrate level was less than the detection limit, in which case, even when amended with high concentrations of glucose and nitrate, the capacity to denitrify on a short-term basis was lacking. These results demonstrate that denitrification can occur in groundwater systems and, thereby, serve as a mechanism for nitrate removal from groundwater.

Massachusetts↗

USGS2024

Hepatotoxic response of perfluorooctane sulfonamide (PFOSA) in early life stage zebrafish (Danio rerio) is greater than perfluorooctane sulfonate (PFOS)

Perfluorooctane sulfonamide (PFOSA), a typical perfluorooctane sulfonate precursor (PreFOS), has been detected in the aquatic environment globally. However, the effects of PFOSA at levels measured in the environment have not been well characterized in aquatic organisms. In this study, we evaluated the transcriptional, biochemical, histopathological, and morphological effects of PFOSA to characterize the underlying mechanisms of toxicity by using a universal model in aquatic ecotoxicology, zebrafish ( Danio rerio ). Transcriptional changes in PFOSA-exposed zebrafish predicted hepatic fibrosis and associated immune function. Subsequent, sublethal impacts were observed, which included significant alterations in liver-specific protein levels, increased immune cell numbers, and liver pathological structural damage. In addition, we compared the effects caused by PFOSA and perfluorooctane sulfonate (PFOS) at the same exposure concentration and found a greater hepatotoxic effect of PFOSA relative to PFOS, indicating that the adverse impacts of PFOSA may be more severe. This was the first study to comparatively explore the hepatotoxic response of PFOSA and PFOS in aquatic organisms, which can be used for ecological risk assessments of PreFOS compounds.

Journal of Hazardous Materials↗

USGS2012

Evaluation of volatile organic compound (VOC) blank data and application of study reporting levels to groundwater data collected for the California GAMA Priority Basin Project, May 2004 through September 2010

Volatile organic compounds (VOCs) were analyzed in quality-control samples collected for the California Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project. From May 2004 through September 2010, a total of 2,026 groundwater samples, 211 field blanks, and 109 source-solution blanks were collected and analyzed for concentrations of 85 VOCs. Results from analyses of these field and source-solution blanks and of 2,411 laboratory instrument blanks during the same time period were used to assess the quality of data for the 2,026 groundwater samples. Eighteen VOCs were detected in field blanks or source-solution blanks: acetone, benzene, bromodichloromethane, 2-butanone, carbon disulfide, chloroform, 1,1-dichloroethene, dichloromethane, ethylbenzene, tetrachloroethene, styrene, tetrahydrofuran, toluene, trichloroethene, trichlorofluoromethane, 1,2,4-trimethylbenzene, m - and p -xylenes, and o -xylene. The objective of the evaluation of the VOC-blank data was to determine if study reporting levels (SRLs) were needed for any of the VOCs detected in blanks to ensure the quality of the data from groundwater samples. An SRL is equivalent to a raised reporting level that is used in place of the reporting level used by the analyzing laboratory [long‑term method detection level (LT-MDL) or laboratory reporting level (LRL)] to reduce the probability of reporting false-positive detections. Evaluation of VOC-blank data was done in three stages: (1) identification of a set of representative quality‑control field blanks (QCFBs) to be used for calculation of SRLs and identification of VOCs amenable to the SRL approach, (2) evaluation of potential sources of contamination to blanks and groundwater samples by VOCs detected in field blanks, and (3) selection of appropriate SRLs from among four potential SRLs for VOCs detected in field blanks and application of those SRLs to the groundwater data. An important conclusion from this study is that to ensure the quality of the data from groundwater samples, it was necessary to apply different methods of determining SRLs from field blank data to different VOCs, rather than use the same method for all VOCs. Four potential SRL values were defined by using three approaches: two values were defined by using a binomial probability method based on one-sided, nonparametric upper confidence limits, one was defined as equal to the maximum concentration detected in the field blanks, and one was defined as equal to the maximum laboratory method detection level used during the period when samples were collected for the project. The differences in detection frequencies and concentrations among different types of blanks (laboratory instrument blanks, source-solution blanks, and field blanks collected with three different sampling equipment configurations) and groundwater samples were used to infer the sources and mechanisms of contamination for each VOC detection in field blanks. Other chemical data for the groundwater samples (oxidation-reduction state, co-occurrence of VOCs, groundwater age) and ancillary information about the well sites (land use, presence of known sources of contamination) were used to evaluate whether the patterns of detections of VOCs in groundwater samples before and after application of potential SRLs were plausible. On this basis, the appropriate SRL was selected for each VOC that was determined to require an SRL. The SRLs for ethylbenzene [0.06 microgram per liter (μg/L)], m - and p -xylenes (0.33 μg/L), o -xylene (0.12 μg/L), toluene (0.69 μg/L), and 1,2,4-trimethylbenzene (0.56 μg/L) corresponded to the highest concentrations detected in the QCFBs and were selected because they resulted in the most censoring of groundwater data. Comparisons of hydrocarbon ratios in groundwater samples and blanks and comparisons between detection frequencies of the five hydrocarbons in groundwater samples and different types of blanks suggested three dominant sources of contamination that affected groundwater samples and blanks: (1) ethylbenzene, m - and p -xylenes, o -xylene, and toluene from fuel or exhaust components sorbed onto sampling lines, (2) toluene from vials and the source blank water, and (3) 1,2,4-trimethylbenzene from materials used for collection of samples for radon-222 analysis.

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