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Four-band image mosaic of the Colorado River Corridor downstream of Glen Canyon Dam in Arizona, derived from the May 2021 airborne image acquisition

In May 2021, the U.S. Geological Survey’s Grand Canyon Monitoring and Research Center acquired airborne multispectral high-resolution data for the Colorado River in the Grand Canyon, Arizona. The image data, which consist of four spectral bands (red, band 1; green, band 2; blue, band 3; and near infrared, band 4) with a ground resolution of 20 centimeters, are available as 16-bit unsigned-integer GeoTIFF files in Sankey and others (2024) (available online at https://doi.org/10.5066/P9BBGN6G ). The image files are projected in the State Plane Coordinate System, using the central Arizona zone (202) with the North American Datum of 1983 National Adjustment of 2011. The assessed spatial accuracy for these data is based on 47 ground-control points that were independent from the ground-control points used by the contractor for aerotriangulation and is reported at the 95-percent confidence level as 0.514 meter (m) and a root mean square error of 0.297 m. The intended uses of this dataset are primarily in support of scientific research and monitoring applications. Examples of these applications include high-resolution spatial and temporal change detection of the river channel, geomorphic landforms, riparian vegetation, and backwater and nearshore habitat, as well as other ecosystem-wide mapping. These imagery data also serve as reference material for field science mission planning, as base data for field data collection including community science activities, and as a highly detailed guide for technical boat operation during science activities such as reconnaissance for nighttime missions and navigating rapids during low flows.

Arizona, Nevada, Utah

Cultural benefits knowledge and social learning in Elwha River dam removal and ecosystem decision-making

In a retrospective case study of the seminal Elwha River dam removal in Washington State, USA, we explore pathways through which ecosystem services (ES) knowledge can inform environmental decision-making. We specifically investigate how knowledge of cultural benefits linked to the Elwha River ecosystem was made available. Through interviews and historical document review we identify diverse forms of cultural benefits knowledge (i.e., how individuals or groups know the contributions of an ecosystem to their identities, experiences, and capabilities), including both knowledge in the form of practices – embodied or enacted forms of knowledge, and knowledge in the form of products – quantitative or written documentation. Recognizing and learning from the diverse forms in which benefits knowledges are conveyed can support more accurate and equitable consideration of the diverse values, well-beings, and human-nature relationships linked to ecosystems. With this case study, we illuminate pathways for meaningful consideration of multiple knowledge forms, and the plural ecosystem values they convey, with relevance for environmental decision processes in the Puget Sound and beyond.

Washington

Constraining landslide frequency across the United States to inform county-level risk reduction

Informative landslide hazard estimates are needed to support landslide mitigation strategies to reduce landslide risk across the United States. Whereas existing national-scale landslide susceptibility products assess where landslides are likely to occur, they do not address how often , which is a critical element of landslide hazard and risk assessments. In particular, the U.S. Federal Emergency Management Agency's National Risk Index (NRI) requires landslide frequency estimates to inform expected annual loss estimates. We present county-level landslide frequency (landslides per area per year) estimates for the 50 US states. We applied Bayesian negative binomial regression to estimate both the expected (average) reported landslide frequency and full distribution of annual landslide counts for each county. We compared a suite of models that used combinations of landslide-susceptible area, probability of potentially triggering earthquakes, frequency of potentially triggering precipitation, and ecological region as predictors. We trained our models with landslide inventory data from counties with the most comprehensive records available nationwide and used zero-inflated negative binomial distributions as an incompleteness model to correct for temporal reporting gaps. We selected a preferred frequency model to inform the NRI based on information criteria and physically plausible parameter estimates. The model showed that average annual reported landslide frequencies vary by 5 orders of magnitude across US counties, ranging from 0.002 (0.00015–0.05) landslides 1000 km −2 yr −1 in Kusilvak Census Area, Alaska, to 29 (19–46) landslides 1000 km −2 yr −1 in Lake County, California, reflecting the country's strong variations in landslide susceptibility, earthquake probability, and other factors for which ecological region serves as a proxy. Counties with estimated frequencies in the top 20 % of all counties are predominately along the West Coast of the continental United States, in mountainous regions of the Pacific Northwest and Intermountain West, in locally steep or earthquake-prone regions of the Midwest and Southeast, along the Appalachians, in southern and southeastern Alaska, and on some Hawaiian islands. By examining the number of landslides predicted in 99th percentile years for each county, we identified that 26 % of US counties likely have potential for widespread landsliding with more than 10 landslides 1000 km −2 yr −1 , even when such large events have not been reported in the training data for that county. Overall, our results better represent the range of possible landslide frequencies and spatial variations than previous national-scale estimates reported in the NRI, and our approach can inform other risk-reduction and loss-mitigation efforts across the United States and globally.

Natural Hazards and Earth System Sciences

Evaluating mass flow meter measurements from chambers for greenhouse gas emissions from orphan wells and other point sources

This study evaluates the performance of a rigid gas flux chamber equipped with a mass flow meter (MFM) for measuring gas emissions from leaking orphan wells and similar pressure-driven gas point sources. We conducted a series of laboratory and field experiments to evaluate the sensitivity, stability, and dynamic range of an MFM chamber system and found an optimal method for sealing the chamber to the ground to isolate the emission source. From these results, we estimate the effects of different soil gas permeabilities on measurements and identify the uncertainty of environmental processes that can impact measurements. Simulations of an MFM chamber are compared to those of a dynamic flux chamber to contrast the data derived with both methodologies and illustrate the potential for measuring high variability leaks with the MFM chamber. Using a low flow resistance MFM and a chamber well-sealed to the ground, it is possible to measure leaks down to 1.08 x 10 -3 cubic meters per hour (m 3 h −1 ) (refenced to 25°/1 atm), corresponding to 0.77 grams per hour (g h −1 ) methane or 2.11 g h −1 carbon dioxide, with a mean uncertainty of 0.89 % relative standard deviation. Environmental processes such as heated gas inside the chamber from solar gain, wind blowing across the chamber vent, and changing humidity in the chamber, can cause variation in MFM measurements. Over 11 d of continuous monitoring under varying weather conditions, the standard deviation of the environmentally sourced signals was found to be 7.40 x 10 -3 m 3 h −1 (equivalent to or 5.27 g h −1 methane or 14.45 g h −1 carbon dioxide). Strategies to obtain the highest quality data from MFM chambers include burying the edges of the chamber below the surface sufficiently deep to seal the chamber edges against gas flow and soaking the dirt with water to lower the chances of escaping gases, while monitoring the gas flow and adjusting the chamber seal to achieve a maximum flow rate.

Atmospheric Measurement Techniques

World minerals outlook—Cobalt, gallium, helium, lithium, magnesium, palladium, platinum, and titanium through 2029

Given the rapid expansion in the demand for mineral commodities that underpin worldwide economic growth and technological advancement, information regarding expected country-level mine production and production capacity is becoming increasingly important to industry stakeholders, end users, and policymakers. Production capacity can limit future supply, depending on how rapidly that capacity is able to expand. Current capacity can be evaluated on the basis of past production. Decreases to future capacity can be taken into account from announcements of planned shutdowns of mines or processing facilities, which are frequently publicized well in advance of such closures. Likewise, capacity expansions, which usually involve multiple stages—such as permitting, financing, and construction (all of which take time)—can also be estimated. As such, it is possible to evaluate midterm future capacity based on estimates of today’s capacities along with consideration of future investment plans. This World Minerals Outlook provides estimated capacities for cobalt, gallium, helium, lithium, magnesium, palladium, platinum, and titanium for 2025 through 2029. The results of this analysis indicate that two mineral commodities important to the manufacture of lithium-ion batteries—cobalt and lithium—are expected to have large capacity growth in the next few years, likely owing to expectations for increased demand for these batteries. For gallium, helium, palladium, and platinum, capacity is expected to remain stable or exhibit moderate growth. Still, these expected capacity levels are higher than current production, allowing for future production growth. The production capacity outlook is opaque for magnesium and titanium metal, which have a significant fraction of current production in nonmarket economies, such as China and Russia. Ultimately, though, where free market conditions prevail, full utilization of capacity potential for those commodities is likely to depend on supply deficits and prices that are above production costs.

Scientific Investigations Report

Local, regional, and distal recordings of seismic unrest at Tau Island volcano, American Samoa

A seismic swarm near Taʻū Island, a volcanic island in eastern American Samoa, occurred from July to October 2022. The earliest unrest was noted as felt shaking reports in late July, and instrumentation varied in the beginning of the sequence as the U.S. Geological Survey (USGS) Hawaiian Volcano Observatory responded by installing temporary and then permanent seismometers to monitor the activity. This network variability made it difficult to characterize the earliest seismicity and contextualize the entire sequence to discriminate between an underlying tectonic or volcanic source. Here, we present results analyzing hydroacoustic detections from an International Monitoring System hydrophone array near Wake Island, 4500 km northwest of Taʻū Island volcano. Using least-squares beamforming analysis, we create a catalog of T-wave detections from the direction of Taʻū Island to track the earthquakes, some of which were located by the USGS National EarthquakeInformation Center. Both the rate and hydroacoustic pressures, which we interpret as a proxy for earthquake size, gradually increased from late July to August, peaking on August 19 (rate) and August 24 (size), before decreasing to background in late September. Minutes-long bursts of tremor were also contemporaneously recorded as local network data became avail-able on August 20. Tremor activity continued throughout the rest of August, peaking on August 25, before ending in earlySeptember. These tremor bursts were band-limited to ~ 1–5 Hz and recorded as S waves at a regional station on the island of Upolu in Samoa, 250 km to the west of Taʻū Island. Our results do not constrain the tremor locations, but comparisons of earthquake and tremor reduced displacements recorded locally and regionally suggest a deeper tremor source. We interpret the increase in earthquake size and rate, together with the occurrence, characteristics, and relative depth of the tremor to be the result of magmatic activity beneath Taʻū Island volcano.

American Samoa, Taʻū Island

Deep-ocean macrofaunal assemblages on ferromanganese and phosphorite-rich substrates in the Southern California Borderland

Mineral-rich hardgrounds, such as ferromanganese (FeMn) crusts and phosphorites, occur on seamounts and continental margins, gaining attention for their resource potential due to their enrichment in valuable metals in some regions. This study focuses on the Southern California Borderland (SCB), an area characterized by uneven and heterogeneous topography featuring FeMn crusts, phosphorites, basalt, and sedimentary rocks that occur at varying depths and are exposed to a range of oxygen concentrations. Due to its heterogeneity, this region serves as an optimal setting for investigating the relationship between mineral-rich hardgrounds and benthic fauna. This study characterizes the density, diversity, and community composition of macrofauna (>300 μm) on hardgrounds as a function of substrate type and environment (depth and oxygen ranges). Rocks and their macrofauna were sampled quantitatively using remotely operated vehicles (ROVs) during expeditions in 2020 and 2021 at depths above, within, and below the oxygen minimum zone (OMZ). A total of 3,555 macrofauna individuals were counted and 416 different morphospecies (excluding encrusting bryozoans and hydrozoans) were identified from 82 rocks at depths between 231 and 2,688 m. Average density for SCB macrofauna was 11.08 ± 0.87 ind. 200 cm −2 and mean Shannon-Wiener diversity per rock (H′ [loge] ) was 2.22 ± 0.07. A relationship was found between substrate type and macrofaunal communities. Phosphorite rocks had the highest H′ of the four substrates compared on a per-rock basis. However, when samples were pooled by substrate, FeMn crusts had the highest H′ and rarefaction diversity. Of all the environmental variables examined, water depth explained the largest variance in macrofaunal community composition. Macrofaunal density and diversity values were similar at sites within and outside the OMZ. This study is the first to analyze the macrofaunal communities of mineral-rich hardgrounds in the SCB, which support deep-ocean biodiversity by acting as specialized substrates for macrofaunal communities. Understanding the intricate relationships between macrofaunal assemblages and mineral-rich substrates may inform effects from environmental disruptions associated with deep-seabed mining or climate change. The findings contribute baseline information useful for effective conservation and management of the SCB and will support scientists in monitoring changes in these communities due to environmental disturbance or human impact in the future.

California

Monitoring and assessment of urban stormwater best management practices at selected Chicago public schools in Chicago, Illinois, from September 1, 2016, to July 1, 2017

The Space to Grow program helps transform aging and neglected schoolyards of Chicago Public Schools into outdoor community spaces with the goal of promoting health and learning while addressing neighborhood flooding issues. Virgil I. Grissom Elementary School and Donald L. Morrill Math and Science School were selected in 2014 for schoolyard upgrades and the installation of various green infrastructure (GI) improvements. The U.S. Geological Survey installed sensors to measure precipitation, groundwater levels, and stormwater runoff volumes from September 1, 2016, to July 1, 2017. At Virgil I. Grissom Elementary School, about 933,000 gallons of water fell on the schoolyard during the monitoring period. No discharge was recorded coming from the GI sewer lines, but backflow indicated water was flowing from the sewer line draining the impervious running track into the combined manhole structure and backwards into the GI retention basins (as designed). This design allowed for a 100-percent capture rate. Native soil at Virgil I. Grissom Elementary School also was conducive to rapid infiltration. Soil borings at Virgil I. Grissom Elementary School indicated about 10.5 feet (ft) of fine sand overlying silty clay to a depth of at least 16 ft. At Donald L. Morrill Math and Science School, about 1,120,000 gallons of water fell on the schoolyard during the monitoring period. About 72.5 precent of this water was discharged into the sewer system, and the other 27.5 percent was captured by the GI. Unlike Virgil I. Grissom Elementary School, the soil profile at Donald L. Morrill Math and Science School consisted of about 5 ft of clay loam overlying stiff blue clay to a depth of at least 12 ft. The sewer line coming from the GI under the football field was at the bottom of the reservoir. This design seemed to allow water to flow out of the line before being absorbed by the retention basin.

Illinois

Bathymetric survey and storage capacity of Upper Lake Mary near Flagstaff, Arizona in 2024

The U.S. Geological Survey (USGS), in cooperation with the city of Flagstaff, collected bathymetric, light detection and ranging (lidar), and land-survey data of Upper Lake Mary in Arizona during the months of April and October 2024. The city of Flagstaff uses a combination of groundwater from well fields throughout the Flagstaff area and surface water, mainly from Upper Lake Mary, for its potable water supply. The purpose of the survey is to update previous surveys using new technology and compare the results to previous surveys to determine if there was a decrease in storage capacity that could affect the city’s water supply. The lakebed was mapped in April 2024 using a vessel equipped with a multibeam echosounder (MBES) and mobile lidar scanner with positioning captured using a real-time kinematic global navigation satellite system (RTK GNSS) base and receivers. In October 2024, areas of the reservoir that were too shallow for the boat and shoreline that were not captured by the vessel-based lidar were surveyed on foot using hand-held RTK GNSS receivers. At full pool (spillway elevation of 6,831.82 feet above NAVD 88 [2,082.34 meters (m)], Upper Lake Mary has a storage capacity of 16,449.80 acre-feet (20,290,611.73 cubic meters) and a surface area of 953.57 acres (3,860,926.075 square meters). The reservoir is 5.7 miles (9.7 kilometers) long and varies in width from 326 feet (99.36 m) near the central, narrow portion of the reservoir to 2,613 feet (796.44 m) in the upper portion. Comparisons between this survey and the previous two surveys from the 1950s and 2006 indicate no apparent decrease in reservoir area or storage capacity. Results of the 2024 survey indicate that Upper Lake Mary’s storage capacity increased by 0.9 percent from the 2006 survey and a 1.6 percent increase in surface area from the 2006 survey.

Arizona

The 3D National Topography Model Call for Action—Part 1. The 3D Hydrography Program

The U.S. Geological Survey is initiating the 3D Hydrography Program (3DHP), the first systematic remapping of the Nation’s surface waters since the original 1:24,000-scale topographic mapping program was active from 1947 to 1992. Building on decades of experience maintaining the National Hydrography Dataset (NHD), the Watershed Boundary Dataset (WBD), and the NHDPlus High Resolution (NHDPlus HR), the 3DHP will completely refresh the Nation’s hydrography data and improve discovery and sharing of water-related data. The design of the 3DHP is based on the results of a study that estimated that the fully implemented program would have the potential to provide more than $1 billion in benefits to Federal, State, Tribal, Territorial, and local governments and to private and nonprofit organizations every year, in addition to myriad societal benefits. The 3DHP would directly support better decision making regarding water resources by providing more accurate, complete, and integrated information than is currently available. The 3DHP datasets will include a three-dimensional (3D) hydrography network generated from and integrated with elevation data from the 3D Elevation Program (3DEP) to better represent stream gradients and channel conditions, along with waterbodies, hydrologic units, hydrologically enhanced elevation and other surfaces, and more consistent and accurate attributes. The 3DHP datasets will inherit key attributes of the NHD, WBD, and NHDPlus HR, and they also will include new attributes and links to other data such as the U.S. Fish and Wildlife Service National Wetlands Inventory, groundwater data, and engineered hydrologic systems such as stormwater networks. The 3DHP will be designed to provide a set of open and interoperable web-based tools, maps, and data catalogs, creating a robust system for users to reference their information about water; the system elements are collectively referred to as the “infostructure.” The 3DHP and the infostructure can provide a foundational geospatial underpinning for the Internet of Water, a community-based effort to modernize tools and technologies to share water data. As proposed, the 3DHP would begin providing products and services to the public in 2024.

Circular

Refining the earthquake history of south-central Alaska through lake records

The Alaska–Aleutian subduction zone (AASZ) is one of the world's most seismically active plate boundaries and the source of the 1964 M w 9.2 Great Alaska earthquake–the second largest instrumentally recorded earthquake in the world. Understanding the nature and frequency of such earthquakes is necessary for seismic and tsunami hazard assessment, but instrumental and historical records that span less than 150 years are too short to allow a statistically reliable analysis of earthquake recurrence times. This calls for studies of evidence of past earthquakes, extending the earthquake catalog further back in time. Subduction-zone paleoseismology in south-central Alaska is predominantly based on coastal evidence of land-level changes and tsunamis generated by megathrust earthquakes and preserved in the geological record. A complementary approach is lacustrine paleoseismology, which is still a relatively young discipline in Alaska. However, globally, lake basins are well-established high-resolution and continuous recorders of paleoseismic activity along subduction zones, relying on the identification of underwater landslide deposits and turbidites generated by seismic shaking. As a result, lake basins not only register ground shaking from megathrust earthquakes, but also from intraslab and crustal earthquakes, which are typically not accompanied by significant land-level changes. In this review paper, we combine coastal and lacustrine paleoseismology approaches to refine the south-central Alaskan earthquake history by comparing the paleoseismic records from two lakes (i.e., Eklutna Lake, located in the Chugach Mountain Range, and Skilak Lake, situated on the Kenai Peninsula) with the coastal and crustal earthquake catalog in Alaska. The resulting age ranges of all known megathrust earthquakes involving the Alaskan megathrust between the Kodiak and Prince William Sound (PWS) sections are more precise and accurate for the last 1.3 kyrs BP than the previously published age ranges from coastal records. As a result, this study supports the following key conclusions: (1) The 1964 CE earthquake was an exceptionally strong and unique event in the last 2000 years, rupturing the PWS, Kenai, Barren Islands, and Kodiak sections simultaneously. (2) The high-resolution and seasonal markings of the varved lake records now disentangle for the first time closely timed earthquakes, which was not possible based on the coastal evidence alone. (3) No persistent megathrust rupture boundaries exist. So, the possibility of a full rupture of the entire eastern AASZ, from PWS to Semidi cannot be excluded. (4) The rupture pattern in the eastern AASZ reveals superimposed cycles of multi-asperity ruptures (1964 earthquake) and clustered complementary partial ruptures, or rupture cascades. (5) The PWS section hosts the largest asperity in the eastern AASZ. (6) The shaking record of megathrust earthquakes indicates a time-dependent (quasiperiodic) behavior for the study area, but the observation of complementary clusters means that the hazards will not drop to zero but instead may even increase for a neighboring section. (7) The time-independent behavior of intraplate earthquakes implies that the intraslab hazard did not decrease following the 2016 and 2018 earthquakes. This study utilizes an integrated approach for subduction zone paleoseismology as a solution for unraveling recurrence and rupture patterns in Alaska, which can be applied worldwide.

Alaska

Decoding the oxidative digestion mechanism for polystyrene nanoplastic detection in the Great Lakes using a customizable Raman spectral processing algorithm

Despite the concerns surging around nanoplastics (NPs) regarding their prevalence and bioavailability in freshwater systems, robust detection of NPs in complex environmental matrices is hindered by the lack of standardized sample pretreatment and a mechanistic understanding of oxidative digestion. Here, we systematically investigate the interaction between hydrogen peroxide (H 2 O 2 ) and polystyrene (PS) NPs during digestion in deionized (DI) water and four environmental matrices from in and around the Great Lakes Basin. To facilitate high-throughput analysis, we develop Pre_peak, a customizable Raman spectral processing algorithm that achieves >99% accuracy for both NP identification and interference rejection, allowing reliable NP quantification via pixel counting and systematic decoding of the oxidative digestion mechanisms. In DI water, varying H 2 O 2 doses from 0 to 30% has negligible effects on the recovery and Raman signal intensity of PS NPs over 24 hours of digestion. However, morphological changes and aggregation of PS NPs are observed when the H 2 O 2 dose exceeds 20%. Prolonged digestion further leads to progressive NP loss. In natural waters, the optimal dosage and digestion duration depend on matrix characteristics, including dissolved organic matter (DOM) and ion composition. This study provides mechanistic insights into NP–oxidant interactions and underscores the need for matrix-tailored digestion protocols to advance standardized NP detection in freshwater environments.

Great Lakes

Geophysical characterization of mine influenced groundwater and surface water in the Mayflower section of the Animas River, Bonita Peak Mining District, Silverton Colorado

This report details findings from geophysical investigations to identify possible groundwater - surface water interactions near the Mayflower Section of the Animas River in Silverton, Colorado. The Mayflower Section is a mine influenced Superfund Site in Colorado. This investigation utilized electromagnetic induction (EM or EMI), magnetic, and fiber optic distributed temperature system (FODTS) geophysical methods to measure the bulk earth electrical conductivity, magnetic susceptibility, and temperature of specific surveyed volumes of the earth near the Mayflower Section of the Animas River. These physical parameters are used to understand the groundwater – surface water interactions, which can guide decision makers in their assessment of mine-impacted surface water. This report details the results from characterization and monitoring technologies to provide high data density and continuous monitoring of bulk earth electrical conductivity and temperature in the Mayflower section of the Animas River to identify zones of groundwater – surface water interactions and potential metal loading from mine influenced water. The investigation separated right and left bank characterization for each method and indicates more groundwater is entering from the right bank than the left bank and these predominantly right bank discharges potentially contain metal-rich water compared to the left bank. Results also indicate mineral veins facilitate preferential groundwater discharge to the river due to possible jointing, fractures, and permeability differences sometimes occurring along veins relative to host rock. For example, Boulder Gulch is likely groundwater dominated and may be receive water impacted by Mayflower Impoundments #1 and #2. Additionally, the beaver ponds near Blair Gulch may influence groundwater discharge and Mayflower Impoundment #4 is possibly impacting groundwater and surface water and may be connected to the wetlands to the west of the impoundment. These data could be further analyzed for smaller spatial scale analysis within areas of interest. The identification of these locations along sections of the river likely impacted by mine influenced groundwater potentially entering the Animas River and can be used by site investigators, decision makers, and stakeholders in mitigation decisions and strategies.

Colorado

Foundational uncertainties in terminal Ediacaran chronostratigraphy revealed by high-precision zircon U-Pb geochronology of the Nama Group, Namibia

The Nama Group of southern Namibia and northwestern South Africa hosts the best-dated mixed carbonate-siliciclastic foreland basin succession of the terminal Ediacaran [ca. 551 million years (Ma) ago to <538 Ma] and is key for resolving the chronology of early metazoan evolution. Numerous silicified volcanic tuff interbeds are present, but differing interpretations regarding the fidelity of their ages lead to different regional stratigraphic correlations, especially for the Urusis Formation of the Schwarzrand Subgroup. An expanded record of the Urusis Formation is found in the Swartpunt area of southern Namibia, which has yielded an important metazoan biota. But the succession in this area is preserved as a series of thrusts at the leading edge of the Gariep orogenic belt and zircon U-Pb data show systematic age repetition. We use regional stratigraphic and structural mapping, integrated with carbonate carbon isotope (δ 13 C carb ) chemostratigraphy and high-precision radioisotope U-Pb zircon geochronology from outcrop and recently acquired drill core to develop a temporally calibrated basin-wide depositional model. This integrated dataset either reflects complex zircon reworking, inheritance, or potential analytical biases (Scenario 1) or the presence of a Gariep-related cryptic décollement within the Spitskop Member that has resulted in stratigraphic repetition (Scenario 2). We investigate the evidence for and against both scenarios and consider their implications for stratigraphic and δ 13 C carb correlations between the Swartpunt area and coeval exposures along the Orange River border with South Africa. Given that these issues are in an area that hosts numerous silicified ash beds and extensive exposure, an inability to confidently discount either scenario highlights a level of compounding uncertainty in zircon U-Pb geochronology that must be considered when attempting to build global chronostratigraphic frameworks. Scenario 1 implies that some of the weighted mean ages and Bayesian eruption ages from the Swartpunt area may be >1 Myr older than the depositional age of their respective ash beds when assuming existing stratigraphic correlations. If this scenario is preferred, then a cautious approach would be to consider all weighted mean zircon U-Pb ages from ash beds to reflect maximum depositional ages. Both scenarios support deposition of the Huns Member >540 Ma in the Swartpunt area if the oldest weighted mean age reported here represents a near-depositional age, which has significant implications for the temporal calibration of important terminal Ediacaran ichnofossil assemblages and future cyclostratigraphic studies. Stratigraphic correlations common to both scenarios allow us to temporally calibrate a basin evolution model for the Nama Group. Temporal trends in initial hafnium isotope (εHf) compositions of zircon grains from ash beds throughout the succession may support progressive crustal thickening associated with underplating of the Damara orogenic belt along the northern periphery of the Kalahari craton from ca. 547 Ma to ca. 538 Ma. The compilation of new and published zircon U-Pb ages may also imply that the locus of carbonate platform development migrated from north to south (present co-ordinates), tracking the migration of foredeep subsidence.

Earth-Science Reviews

Stratigraphy, structure, and geomorphology of the central Appalachians across the North Mountain fault zone near Harrisonburg, Virginia, USA

This field trip focuses on the geology of the central Appalachian Valley and Ridge province near Harrisonburg, Virginia, USA. Recent geologic mapping utilizing 1-m resolution lidar data has revealed new insights into the Paleozoic stratigraphy, structural geology, and Neogene landscape evolution of the region. The detailed mapping reveals the presence of the Big Spring Station Member and multiple thrombolite zones in the Cambrian Conococheague Formation extending as far south as the Briery Branch 7.5 min quadrangle, providing insights into Late Cambrian sea-level fluctuations. Multiple outcrop exposures in the study area of this guidebook confirm recent work in Pennsylvania, USA, showing that the Ordovician Reedsville Shale overlies the Martinsburg Formation and that the two are distinct and mappable as separate formations rather than laterally equivalent units as previously interpreted. Our work extends the Silurian Williamsport Sandstone into Shenandoah County, Virginia, and describes its facies relationships with the Bloomsburg Formation along strike and across the Adams Run anticline. Mapping within the thick Devonian siliciclastic sequence reveals the presence of the Mahantango Formation on the western limb of Supin Lick syncline and illustrates its complex facies relationship with the Millboro Shale. In addition, we highlight new mapping criteria for the Brallier and Foreknobs Formations and demonstrate how the specific changes to the placement of the contact between them addresses previous challenges in their differentiation. We present cosmogenic burial ages of broad alluvial fan sediments in the Shenandoah Valley near Timberville and Briery Branch, Virginia, and erosion rates estimated for the Briery Branch stream basin. Both analyses provide new constraints on the timing of landscape evolution and karst development since the middle Pliocene. This field guide also highlights some significant structural features within the North Mountain fault zone, such as evidence of imbricated thrust sheets cut by cross-strike faults that have been exploited by Eocene igneous intrusions. Map-scale horses of Silurian and Ordovician rocks hold up ridges that are oblique to the regional strike. Deformation internal to one of these horse blocks is shown to be non-coaxial with respect to the main regional northwest directed transport.

Virginia

Shallow geologic framework of the Mississippi Sound and the potential for sediment resources

The Mississippi Sound, an estuarine environment located between the mainland and barrier islands bordering the northern Gulf of America (formerly the Gulf of Mexico), serves as a vital ecosystem for the States of Mississippi and Alabama. Spanning approximately 100 kilometers from east to west and covering 1,400 square kilometers, the sound is home to marine industry and ports, and its shallow and brackish waters sustain a diverse array of marine life. Barrier islands along the southern edge of the sound separate the microtidal estuary from the Gulf of America. This protection from gulf wave action mediates current flow within the sound, resulting in predominantly fine-grained sediment deposition along the seafloor. This study, conducted by the U.S. Geological Survey in cooperation with the U.S. Army Corps of Engineers, provides insight on fluvial and tidal processes spanning the past 5,000 years. The report synthesizes existing research to provide a comprehensive overview of the sound geology, from Pleistocene origins to present-day morphology, and utilizes high-resolution single channel seismic profiles and sediment data to identify and map sedimentary deposits and morphologic features at and below the seafloor. Despite its ecological significance, the Mississippi Sound faces environmental challenges, including water-quality issues, habitat degradation, storm-induced erosion, and the ongoing threats of sea-level rise and environmental changes. This study uses the present-day understanding of the sound's geology to inform coastal management decisions, hazard assessment, and potential mineral resources.

Louisiana, Mississippi

Understanding the resource potential of natural hydrogen on Earth: Scientific gaps, uncertainties and recommendations

A comprehensive scientific research roadmap is essential to bridge knowledge gaps and deepen the understanding of key geological, geochemical, and geophysical aspects of natural hydrogen (H 2 ) as a potential new energy resource. This paper reviews major scientific uncertainties on natural H 2 , suggesting research priorities, as a guide for defining exploration strategies, techniques, and data interpretation. The uncertainties concern all phases of the natural H 2 cycle, from generation (source rocks) through migration (advection and diffusion) and accumulation (reservoir and cap rocks) to the application and interpretation of subsurface and surface geochemical and geophysical exploration techniques. Understanding H 2 sources and generation rates (the amount of H 2 generated by a given volume of rock over time) is crucial for determining whether a geological H 2 system operates as a short-term dynamic system with rapid H 2 production and release, or as a conventional gas system with long-term accumulations, analogous to petroleum reservoirs. Preliminary estimates for serpentinisation, radiolysis, and organic matter degradation suggest that H 2 generation is not inherently fast, especially for non-hydrothermal continental systems (crystalline basement of shields, ophiolites, peridotite massifs, sedimentary basins), and long-term accumulations, like those of fossil natural gas systems, represent the most likely scenario. The mechanisms of H 2 migration through geological formations require application of fundamental principles of fluid-flow physics, distinguishing advection and diffusion, as well as their forms (from gas-phase, bubble flows to aqueous solutions). Additional studies of H 2 accumulation and retention in subsurface reservoirs could improve understanding of mechanisms of H 2 migration by focusing on the rock fluid-bearing properties and the factors affecting H 2 preservation, such as the presence of cap rocks impermeable to H 2 , pressure conditions, residence times, and microbial or abiotic consumption. Advanced techniques, including reservoir modelling, flow simulations, 3D imaging (micro-CT) of H 2 -bearing rocks, and extraction and analysis of gas occluded in rocks, can provide insights into the stability and potential recoverability of H 2 accumulations. The interpretation of surface exploration techniques, including gas geochemistry, geophysics, and remote sensing, long employed in mineral and energy resource exploration, is now being adapted for natural H 2 studies, but challenges remain in the data interpretation. Distinguishing H 2 seepage due to geological degassing from H 2 produced near the surface by modern microbial processes or artificial sources, such as hammering or drilling for soil-gas sampling, drilling into aquifers, and corrosion in boreholes, is an essential step in exploration. The simple detection of H 2 in soils, even in morphological structures like sub-circular depressions or “fairy circles”, cannot be cursorily interpreted as a signal of natural H 2 seepage from a deep source. A holistic geochemical approach, including isotopic analyses of gases associated with H 2 , is recommended to distinguish among the variety of possible H 2 origins. Observations of H 2 in wells should be interrogated to rule out possible artifacts such as corrosion and drill bit metamorphism. The integration of multiple geophysical methods, including seismic, gravimetric, magnetic, and electro-magnetic surveys, is recommended to mitigate interpretation ambiguities regarding the structure of a subsurface H 2 system (source and reservoir rocks, including fluid and gas storage), due to the non-uniqueness of rock-specific physical properties.

Earth-Science Reviews

Uncertainty quantification of geologic energy storage in depleted gas reservoirs using material balance equations embedded in a hierarchical errors-in-variables model

The storage potential for gas in geologic settings, such as depleted hydrocarbon reservoirs and solution-mined salt caverns, is becoming salient to future energy infrastructure planning. Technologies such as carbon capture, utilization, and storage, carbon dioxide-enhanced oil recovery, and natural gas and hydrogen storage help meet growing energy demands, reduce carbon emissions to meet climate goals, and provide energy security amid geopolitical uncertainties. Therefore, estimates of underground gas storage capacity could be useful for efficiently navigating the energy transitions. Material balance is a fundamental method in reservoir engineering for estimating original gas in place and potential storage capacity at the scale necessary for national assessments of subsurface pore space resources. However, the deterministic method cannot accommodate multiple data sources or quantify uncertainty in predictions. In this study, a method that embeds material balance equations within a hierarchical errors-in-variables model is proposed which allows the estimation of the distributions of reservoir properties needed for assessments. Uncertainties associated with these reservoir properties have traditionally been expert-elicited, whereas the uncertainty estimates from the proposed models are data-driven. Capacity and uncertainty estimates can be used in a probabilistic resource assessment, supplementing information traditionally used by assessors or even replacing this expert elicitation step when data are unavailable. Various regression models are compared in a case study of the Michigan Basin, a large contributor to the United States’ current natural gas storage capacity. In particular, errors-in-variables models help ameliorate regression dilution and can quantify uncertainty in predictions of pressure in addition to storage capacity. Overfitting is addressed by quantifying generalization error and model averaging in simple and stratified cross-validation against reported working gas capacity, representing the varying quality and quantity of available data. Incorporating a statistical framework into existing numerical methods in reservoir engineering can improve the quality of estimation, and in particular, this method brings rigor to uncertainty quantification as part of a larger effort by the U.S. Geological Survey to assess domestic energy gas storage resources in depleted hydrocarbon reservoirs.

Mathematical Geosciences