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At least 433 records · Page 24Linked to original sources

USGS2022

Anthropogenic and natural lead isotopes in Fe-hydroxides and Fe-sulphates in a watershed associated with arsenic-enriched groundwater, Maine, USA

A survey of the natural and anthropogenic sources of lead contributing to secondary minerals in sulphidic schists associated with arsenic-enriched groundwater in Coastal Maine shows that the most likely source is natural Pb, particularly from coexisting sulphide minerals. The secondary minerals also reflect notable contributions from anthropogenic Pb. The Pb isotopes establish pathways by which Pb, and by inference As, could have been transported from As-bearing minerals (arsenian pyrite, arsenopyrite, lollingite, orpiment, arsenic oxide and others), via sulphide oxidation or carbonation reactions into multiple generations of secondary minerals (goethite, hematite, jarosite, natrojarosite and others). Lead isotopic compositions of the sulphides and secondary minerals determined by thermal ionization mass spectrometry ( n =53) range widely. Lead and As contents of the sulphides and secondary minerals overlap, and are generally positively correlated. Pyrite, the dominant sulphide in sulphidic schists associated with As-enriched groundwater in Coastal Maine, has values of 206 Pb/ 204 Pb from 18.186 to 18.391, 207 Pb/ 204 Pb from 15.617 to 15.657, 208 Pb/ 204 Pb from 38.052 to 38.210, 206 Pb/ 207 Pb from c . 1.1625 to 1.1760 and 208 Pb/ 207 Pb from c . 2.4276 to 2.4394. Mixtures of Fe-hydroxide and oxide minerals (predominantly goethite and hematite) and secondary Fe-sulphate minerals (jarosite, natrojarosite, rozenite and melanterite) in the sulphidic schists have overlapping but generally higher values of 206 Pb/ 204 Pb from 18.495 to 19.747 (one sample at 21.495), 207 Pb/ 204 Pb from 15.595 to 15.722 (one sample at 15.839), 208 Pb/ 204 Pb from 38.186 to 39.162, 206 Pb/ 207 Pb from c. 1.1860 to 1.2575 (one sample at 1.3855) and 208 Pb/ 207 Pb from c . 2.4441 to 2.4865 than the sulphides. Sulphides from Zn-Pb metal mines are somewhat less radiogenic than sulphides from the schists. Other sulphides (mostly pyrite) associated with pegmatites and granitic rocks are heterogeneous and more radiogenic than the pyrite-rich sulphidic schists. Sulphides from other regional bedrock units also have heterogeneous isotope values. Lead isotopic compositions of the sulphides from the sulphidic schists and coexisting Fe-oxides and Fe-sulphates produced by weathering and alteration overlap, but the secondary minerals extend toward more radiogenic values that broadly indicate the addition of Pb from anthropogenic origin. As a component of Pb from extensively used arsenical pesticides may also be present in the secondary minerals, the range in Pb isotope values is consistent with multiple sources: natural Pb from the schists and anthropogenic Pb (industrial and possibly from agricultural activities). Contributions from past mining activities or from other bedrock sources are not implicated.

Maine↗

USGS2022

Anthropogenic vs. natural pollution: An environmental study of an industrial site under remediation (Naples, Italy)

Heavy metal concentrations and Pb isotopic composition were determined in the soils, slags, scums and landfill materials from a shut down industrial (brownfield) site. This was the second largest integrated steelworks in Italy, and is now under remediation by a Government project. It is located in the outskirts of Napoli on the Bagnoli-Fuorigrotta plain (BFP), which is part of the Campi Flegrei (CF) volcanic caldera, where many spas and geothermal springs occur. The purpose of this work is to distinguish the natural (geogenic) component, originated by hydrothermal activity, from anthropogenic contamination owing to industrial activity. 'In-situ sediments' (soils), slags, scums and landfill materials from 20 drill-cores were selected from a network of 197 drills carried out on a 100 ?? 100 m grid, covering the entire brownfield site. In general, heavy metal enrichments in the upper 3 m of the cores strongly suggest mixing between natural (geogenic) and anthropogenic components. Pb isotopic data are suggestive of three potential end members, and confirm the existence of a strong natural component in addition to contamination from anthropogenic activities. The slags, scums and landfill materials have been proved, through mineralogy and leachate experiments, to be geochemically stable; this shows that metal pollutants are not bio-available and, hence, do not pose a risk to future developments on this site. The natural contribution of hydrothermal fluids to soil pollution, in addition to the non-bio-availability of metal pollutants from industrial materials, indicate that heavy metal remediation of soils in this area would be of little use. Continuous discharge from mineralized hydrothermal solutions would cancel out any remediation effort.

Geochemistry: Exploration, Environment, Analysis↗

USGS1999

Mapping the glacial geology of the Central Great Lakes region in three dimensions: A model for state-federal cooperation

Planners need to evaluate complex and competing public-policy options for managing water, land, and biological resources; they must ensure economic growth, meet the needs of an increasing population, assess hazards, and manage the environment in a sustainable manner. The State Geological Surveys of Illinois, Indiana, Michigan, and Ohio and the U.S. Geological Survey (USGS) receive many requests from local, State, and Federal planners and officials for geologic information. Thick and complex layers of glacial and related sediments blanket the bedrock of these States: a three-dimensional understanding of these deposits is critical to making informed resource-management and other planning decisions. At two recent forums (in Indianapolis, March 1997, and Columbus, Ohio, February 1999), more than 200 attendees from more than 60 local, State, and Federal agencies provided a clear message. They need three-dimensional geologic information to use in making decisions on the following issues: • Quality, quantity, distribution, and accessibility of surface and ground water • Aggregate sources and land-use conflicts • Energy and mineral resource management • Environmental management and mitigation of land and water contamination • Acceleration of the permitting processes of regulatory agencies • Industrial, commercial, residential, and infrastructure siting and construction • Agricultural land loss, erosion, sedimentation, and agrichemical use • Waste-disposal planning and mitigation • Habitat alteration and biodiversity • Coastal erosion, landslides, radon, floods, and earthquakes

Illinois, Indiana, Michigan, Ohio↗

USGS2017

Global nonfuel mineral exploration trends 2001-2015

This review summarizes significant exploration trends related to active sites and budgets, mineral commodities and regional factors for the years 2001-2015. Data were compiled by specialists in the USGS-NMIC, and reported annually in the USGS-NMIC Minerals Yearbook series and in the May issue of Mining Engineering magazine. External data for these analyses were derived from industry sources, published literature, and SNL Metals & Mining, an offering of S&P Global Market Intelligence (New York, NY).

Mining Engineering↗

USGS2017

Geologic map of the Dusar area, Herat Province, Afghanistan; Modified from the 1973 original map compilations of V.I. Tarasenko and others

The geologic maps and cross sections presented in this report are redrafted and modified versions of the Geologic map and map of useful minerals of the Dusar area (scale 1:50,000) and Geologic sketch map of the Dusar and Namak-sory ore occurrences (scale 1:10,000), located in the Herat Province, Afghanistan. The original maps and cross sections are contained in unpublished Soviet report no. 0290 (Tarasenko and others, 1973) prepared in cooperation with the Ministry of Mines and Industries of the Royal Government of Afghanistan, in Kabul during 1973 under contract no. 50728. The redrafted maps and cross sections (modified from Tarasenko and others, 1973) illustrate the geological structure and mineral occurrences of the Dusar copper-gold-silver-lead-zinc prospect area of western Afghanistan, located within the Dusar-Shaida copper and tin area of interest (AOI), Herat Province, Afghanistan. Mineralization in the Dusar area is hosted within Early Jurassic to Early Cretaceous stratified volcanic and sedimentary rocks associated with numerous diabase and gabbro-diabase intrusive bodies and is generally near a major northeast-trending system of faults and quartz veins. Host rocks consist of quartz keratophyre and quartz-feldspar porphyry, with layers of schist, phyllite, and quartz-chlorite and chlorite-sericite slate; and limestone and shale, with schist and carbonate-chlorite and chlorite slate. Known mineralization includes an extensive quartz vein system, shown on the map as the “northern occurrence,” as well as the Dusar and Namak-sory gossan zones, interpreted to have formed from remnant pyrite mineralization. The veins of the northern occurrence and their altered host rocks are known to contain anomalous to economic concentrations of precious and base metals, with concentrations locally in excess of 2 parts per million gold, 100 parts per million silver, 5 percent copper, and 1 percent lead. These veins occur in swarms, and are hosted along structures that are approximately concordant with the plane of the metamorphic fabric. The veins consist mostly of quartz, with minor carbonate and sulfide minerals, and display weak alteration halos along their margins. The gossans are locally anomalous in these metals, but their size and extent makes them attractive exploration targets for potential massive sulfide mineralization. The Dusar gossan zone is a massive, ochreous, and siliceous limonitic rock, approximately 2,200 meters long, 30 to 250 meters wide, and 2.0 to 7.2 meters thick. Drilling below the Dusar gossan intersected a siliceous, sericitic, and limonitic rock underlain by quartz keratophyre with abundant disseminated pyrite. Mineralized sections grade 0.06 weight percent copper and up to 0.05 weight percent zinc. The Namak-sory gossan zone contains a similar deposit with anomalous concentrations of copper, zinc, and gold. The redrafted maps and cross sections reproduce the topology of rock units, contacts, and faults of the original Soviet maps and cross sections, and include minor modifications based on examination of the originals and observations made during two brief field visits by USGS staff in August, 2010, and June, 2013.

Dusar Area, Herat Province↗

USGS2014

Powder X-ray diffraction laboratory, Reston, Virginia

The powder x-ray diffraction (XRD) laboratory is managed jointly by the Eastern Mineral and Environmental Resources and Eastern Energy Resources Science Centers. Laboratory scientists collaborate on a wide variety of research problems involving other U.S. Geological Survey (USGS) science centers and government agencies, universities, and industry. Capabilities include identification and quantification of crystalline and amorphous phases, and crystallographic and atomic structure analysis for a wide variety of sample media. Customized laboratory procedures and analyses commonly are used to characterize non-routine samples including, but not limited to, organic and inorganic components in petroleum source rocks, ore and mine waste, clay minerals, and glassy phases. Procedures can be adapted to meet a variety of research objectives.

Virginia↗

USGS2023

China, the Democratic Republic of the Congo, and artisanal cobalt mining from 2000 through 2020

From 2000 through 2020, demand for cobalt to manufacture batteries grew 26-fold. Eighty-two percent of this growth occurred in China and China’s cobalt refinery production increased 78-fold. Diminished industrial cobalt mine production in the early-to-mid 2000s led many Chinese companies to purchase ores from artisanal cobalt miners in the Democratic Republic of the Congo (DRC), many of whom have been found to be children. Despite extensive research on artisanal cobalt mining, fundamental questions about its production remain unanswered. This gap is addressed here by estimating artisanal cobalt production, processing, and trade. The results show that, while total DRC cobalt mine production grew from 11,000 metric tons (t) in 2000 to 98,000 t in 2020, artisanal production only grew from 1,000 to 2,000 t in 2000 to 9,000 to 11,000 t in 2020 (with a peak of 17,000 to 21,000 t in 2018). Artisanal production’s share of world and DRC cobalt mine production peaked around 2008 at 18 to 23% and 40 to 53%, respectively, before trending down to 6 to 8% and 9 to 11% in 2020, respectively. Artisanal production was chiefly exported to China or processed within the DRC by Chinese firms. An average of 72 to 79% of artisanal production was processed at facilities within the DRC from 2016 through 2020. As such, these facilities may be potential monitoring points for artisanal production and its downstream consumers. This finding may help to support responsible sourcing initiatives and better address abuses related to artisanal cobalt mining by focusing local efforts at the artisanal processing facilities through which most artisanal cobalt production flows.

PNAS↗

USGS2010

Mineral resource of the month: sulfur

The article presents information on sulfur. Sulfur is said to be among the few solid elements found in elemental form in nature and has industrial uses. Changes in the sulfur production process over the years are discussed as well as the mining process developed by German engineer Herman Frasch that involves melting the sulfur underground and pumping it to the surface.

Earth↗

USGS2025

World minerals outlook—Cobalt, gallium, helium, lithium, magnesium, palladium, platinum, and titanium through 2029

Given the rapid expansion in the demand for mineral commodities that underpin worldwide economic growth and technological advancement, information regarding expected country-level mine production and production capacity is becoming increasingly important to industry stakeholders, end users, and policymakers. Production capacity can limit future supply, depending on how rapidly that capacity is able to expand. Current capacity can be evaluated on the basis of past production. Decreases to future capacity can be taken into account from announcements of planned shutdowns of mines or processing facilities, which are frequently publicized well in advance of such closures. Likewise, capacity expansions, which usually involve multiple stages—such as permitting, financing, and construction (all of which take time)—can also be estimated. As such, it is possible to evaluate midterm future capacity based on estimates of today’s capacities along with consideration of future investment plans. This World Minerals Outlook provides estimated capacities for cobalt, gallium, helium, lithium, magnesium, palladium, platinum, and titanium for 2025 through 2029. The results of this analysis indicate that two mineral commodities important to the manufacture of lithium-ion batteries—cobalt and lithium—are expected to have large capacity growth in the next few years, likely owing to expectations for increased demand for these batteries. For gallium, helium, palladium, and platinum, capacity is expected to remain stable or exhibit moderate growth. Still, these expected capacity levels are higher than current production, allowing for future production growth. The production capacity outlook is opaque for magnesium and titanium metal, which have a significant fraction of current production in nonmarket economies, such as China and Russia. Ultimately, though, where free market conditions prevail, full utilization of capacity potential for those commodities is likely to depend on supply deficits and prices that are above production costs.

Scientific Investigations Report↗

USGS2019

Heavy mineral sands resources in China

About 200 known coastal deposits of heavy mineral sands (HMS) occur in China, in which considerable mineral resources of titanium, zircon, rare earth elements, and thorium exist in the forms of ilmenite, rutile, zircon, and monazite. More than 20 of these HMS deposits are reported as having been or are actively being mined in China during the past three decades, of which 12 have been reported to have industrial resources. Commercially important deposits occur almost entirely in Cenozoic beach and sand dune deposits, principally along China’s eastern coast (e.g., Shandong Province) and southern coast (e.g., Guangxi, Guangdong, Hainan, and Fujian provinces), and particularly on Hainan island. There are also important deposits of HMS along coastal areas of Taiwan. China has the largest share of the world’s economic ilmenite resources in HMS deposits (31%). A variety of igneous and associated metamorphic rocks along the coastal areas of China provided an abundant source of heavy minerals for the formation of the HMS occurrences. Studies of titanium-rich HMS deposits have shown that ilmenite is mostly sourced from igneous rocks. For example, 40% of the bedrock of Hainan island consists of Triassic and Cretaceous granites emplaced into rocks of the Cathyasia Block, and all of the HMS districts on the island lie no more than 15 km downstream from a Middle Triassic suite of syenite to granite intrusions. The southern coastal regions of Guangdong and Guangxi provinces are dominated by Jurassic granodiorite, biotite granite, two-mica granite, and A-type granite, with minor gabbro and syenite. Identified accessory minerals in the Jurassic alkaline granitoids include zircon, apatite, allanite, titanite, magnetite, ilmenite, monazite, and niobite. Thus, multiple plutons are in proximity to the Cenozoic coastal plain and are available as bedrock sources for the detrital titanium minerals, zircon, and monazite. More than 100 HMS deposits and prospects have been identified in Shandong Province, consisting of more than 20 varieties of heavy minerals in quartz sand, which include zircon, ilmenite, rutile, monazite, magnetite, xenotime, and gold (in general order of abundance) derived from Precambrian metamorphic basement and Mesozoic intrusions. Of these minerals, zircon, magnetite, gold, and quartz sand have economic significance. The quartz sands are used by the glass and construction industries. The placers mainly occur in and adjacent to the littoral zones of the northern and southern coasts of the Jiaodong Peninsula in Shandong province. Seven beach placer, HMS prospective areas have been delineated in coastal areas of the peninsula. Due to nearly exhausted placer reserves in the Chinese coastal zones, as well as increased environmental restrictions, future prospecting for heavy minerals will likely focus on ancient beach systems in China’s inland sedimentary basins. Also, offshore deposits of HMS in shallow coastal waters are other potential sources of heavy minerals, such as the Baoding Sea zircon-titanium, minerals-rich placer under development near Wanning on Hainan. Similarly, there is potential for offshore HMS deposits in shallow waters of the entire coastal area of southern Taiwan that remains to be fully evaluated. Reconnaissance sampling along Taiwan island’s coasts has revealed the potential for extensive, high-grade HMS accumulations nearshore.

Book chapter↗

USGS2014

Mineral Resource of the Month: Talc

When people think of talc, they often think of talcum and baby powder. However, these uses of talc are minor compared to its use in industrial manufacturing. The leading use of talc in the United States is in the production of ceramics, where it is a source of magnesium oxide, serves as a flux to reduce firing temperatures, and improves thermal shock characteristics of the final product. Worldwide, the major use of talc is as a paper constituent, where it fills the interstices between cellulose paper fibers, reduces paper transparency, improves ink receptivity, and absorbs undesirable tree sap residues that can generate blemishes in the paper.

Earth↗

USGS1964

Water resources of the Green Bay area, Wisconsin

The Green Bay area comprises an area of about 525 square miles in eastern Wisconsin at the south end of Green Bay. It includes the western three-fourths of Brown County and the eastern one-ninth of Outagamie County. In 1960, the population of the area was estimated at 124,000. The most prominent topographic feature is the northwest-facing, southwestward trending Niagara escarpment. The area northwest of the escarpment drains into Green Bay via the Fox River, Suamico River, Duck Creek, and their tributaries. The area southeast of the escarpment is drained by streams that flow into Lake Michigan. The chief sources of surface water in the Green Bay area are the Fox River, Green Bay, and Lake Michigan. Smaller amounts of water are available from the East and Suamico Rivers and other streams. A sandstone aquifer is the principal source of the ground-water supply. The Niagara dolomite, although largely undeveloped, is potentially an important aquifer in the eastern part of the area. Small amounts of water are obtained also from the Platteville formation and from deposits of Pleistocene and Recent age. Water from the surfaceand ground-water sources is moderately hard to very hard. The Fox River, tributary to Lake Michigan at Green Bay, is a significant source of water for industrial use in the Green Bay area. The Menasha Dam, which controls release of water from the Lake Winnebago pool, is the major regulation on the Fox River, and it has considerable effect in reducing peak flows and supplementing low flows in the lower Fox River. The average discharge of the lower Fox River for the period 1898-1959, as measured at the gaging station at Rapide Croche Dam, was 2,687 mgd (million gallons per day). The longest consecutive period during which the discharge averaged less than 500 mgd was 80 days. The average discharge can be expected to fall below 700 mgd about once every 5 years for a 7-day period. In 1959, the average withdrawal of water from the Fox River was about 62 mgd. The water in the river is of the calcium magnesium bicarbonate type and is hard. The small streams in the area are utilized chiefly for stock watering; some of the water, however, is used for irrigation. The water in the small streams is more highly mineralized than the water in the Fox River and is very hard. Large quantities of water are available from Green Bay, but the disposal of industrial waste into the bay has restricted the use of the water. The major withdrawal is for condenser cooling, and, in 1959, it averaged about 415 mgd. The water from Green Bay is moderately hard but is of better chemical quality than the water from the Fox River and the small streams in the area. The only withdrawals of water from Lake Michigan for use in the Green Bay area are made by the city of Green Bay. In 1959, these withdrawals averaged 7.8 mgd. The lower Fox River is not subject to extremes of flow owing to the dampening effect of the Lake Winnebago pool and the regulation of flow at Menasha Dam. Cloudbursts over the lower Fox River valley below Menasha Dam, however, have occasionally caused extremely high water, as in 1922, when the discharge at the mouth of the Fox River was estimated to be about 50,000 mgd. Daily discharges greater than about 13,000 mgd occurred only 7 times in the period 1918-59. The 50-year flood of 15,500 mgd represents an average runoff of less than 2.6 mgd per square mile of drainage area, a relatively low runoff for a 50-year flood in Wisconsin. The sandstone aquifer is the principal source of ground water in the Green Bay area and furnishes water for public supply and industrial use. This aquifer includes rocks of Late Cambrian age, and the Prairie du Chien group and St. Peter sandstone of Ordovician age; it ranges in thickness from 550 to 640 feet. Ground water is found in openings along fractures and bedding planes and in the interstices between sand grains. The sandstone aquifer can support additional development of large supplies of ground water. Wells can be developed in most of the area that will yield 500 gpm (gallons per minute) or more, provided they are properly spaced and penetrate the entire thickness of the aquifer. It is estimated that the perennial yield of the sandstone in the Green Bay area could be at least 30 mgd if the aquifer is properly developed; only 5.4 mgd was withdrawn in 1959. The water from this sandstone aquifer is of the calcium magnesium bicarbonate type, is very hard, and, at a few places, contains objectionable amounts of iron. The Niagara dolomite, potentially a source of moderate to large quantities of water in the eastern part of the area, probably will yield 500 gpm or more to wells. In 1959, the average withdrawal of water for all uses was estimated at 495 mgd, of which 98.2 percent was from surface-water sources and 1.8 percent was from wells. About 485 mgd of water was withdrawn for industrial use, 6 mgd for public supply, and 4 mgd for rural use. The industrial use of water averaged 441 mgd for condenser cooling, 38 mgd fot processing by the paper industry, and 6 mgd for other industrial uses. The city of Green Bay used 7.8 mgd of water from Lake Michigan; other public supplies in the area used 2.6 mgd from wells. Of the withdrawals of water for rural use, about 75 percent was from wells and about 25 percent was from streams. The discharge of wastes into the lower Fox River and its tributary streams has altered the quality of the natural water. The wastes consist chiefly of treated municipal sewage and treated and untreated wastes from the paper industry, rendering plants, a sugar mill, and other industries. The industrial waste makes up about 90 percent of the oxygen-demand loading in the lower Fox River, and treated municipal sewage accounts for about 10 percent. The dissolved-oxygen concentration of water in the lower Fox River decreases rapidly in the vicinity of Green Bay during the summer when the river water is warm. If the periods when the river water is warmest, generally during July and early August, were to coincide with periods of lowest annual streamflow, generally in late August, the river would be unable to assimilate the loading of decomposable organic matter. In an emergency, industrial and public supply wells could supply at least 6 mgd for a sustained period and probably as much as 10 mgd for a period of several days. Six of the wells that formerly supplied the city of Green Bay are maintained in operating condition and could furnish about the same quantity of water as the industrial and other public supply wells. Small streams in the area would be supplemental sources of water, and the water in the Fox River and Green Bay is easily accessible.

Wisconsin↗

USGS1972

Water resources inventory of Connecticut Part 6: Upper Housatonic River basin

The upper Housatonic River basin report area has an abundant supply of water of generally good quality, which is derived from precipitation on the area and streams entering the area. Annual precipitation has averaged about 46 inches over a 30-year period. Of this, approximately 22 inches of water is returned to the atmosphere each year by evaporation and transpiration; the remainder flows overland to streams or percolates downward to the water table and ultimately flows out of the report area in the Housatonic River or in smaller streams tributary to the Hudson River. During the autumn and winter precipitation normally is sufficient to cause a substantial increase in the amount of water stored in surface reservoirs and in aquifers, whereas in the summer, losses through evaporation and transpiration result in sharply reduced streamflow and lowered ground-water levels. Mean monthly storage of water in November is 2.8 inches more than it is in June. The amount of water that flows into, through, and out of the report area represents the total amount potentially available for use ignoring reuse. For the 30-year period 1931 through 1960, the annual runoff from precipitation has averaged 24 inches (294 billion gallons). During the same period, inflows from Massachusetts and New York have averaged 220 and 64 billion gallons per year, respectively. A total average annual runoff of 578 billion gallons is therefore available. Although runoff indicates the total amount of water potentially available, it is rarely feasible to use all of it. On the other hand, with increased development, some water may be reused several times. The water availability may be tapped as it flows through the area or is temporarily stored in streams, lakes, and aquifers. The amounts that can be developed differ from place to place and time to time, depending on the amount of precipitation, on the size of drainage area, on the thickness, transmissivity, and areal extent of aquifers, and on the variations in chemical and physical quality of water. Differences in precipitation cause differences in the amount of streamflow whereas differences in the proportion of stratified drift affect its timing. Water can be obtained from wells almost anywhere in the area, but the amount obtainable at any particular point depends on the type and water-bearing properties of the aquifers tapped. Stratified-drift aquifers are the only ones generally capable of yielding more than 100 gpm (gallons per minute) to individual wells. Drilled, screened wells tapping this unit yield from 17 to 1,400 gpm, with a median yield of 200 gpm. Till and bedrock are widespread but generally provide only small supplies of water. Till is tapped in a few places by dug wells, which can yield small supplies of only a few hundred gallons per day throughout all or most of the year. Bedrock is the chief aquifer for privately owned domestic and rural supplies; it is tapped by drilled wells, about 90 percent of which will supply at least 2 gpm. Only 1 of 10 bedrock wells, however, will supply more than 30 gpm. The amount of ground water potentially available in the report area depends upon the thickness and hydraulic properties of aquifers, the amount of salvageable natural discharge of ground water, and the quantity of water available by induced infiltration from streams and lakes. From data on transmissivity, thickness, recharge, well performance, and streamflow, preliminary estimates of ground-water availability can be made for most stratified-drift aquifers in the report area. Long-term yields estimated for eight areas of stratified drift especially favorable for development of large ground-water supplies ranged from 0.6 to 5 mgd (million gallons per day). Detailed site studies are needed to verity these estimates and to determine optimum yields, drawdowns, and spacing of individual wells before major ground-water development is undertaken in these or other areas. The chemical quality of water in the report area is generally good; carbonate-bedrock units exert considerable local influence on water quality. Samples of naturally occurring surface water collected at 24 sites during low flow averaged 90 mg/l (milligrams per liter) dissolved solids and 60 mg/l hardness. Water from wells is generally more highly mineralized than naturally occurring water from streams. About 37 percent of the wells sampled yielded water with more than 200 mg/l dissolved solids and 50 percent yielded water with more than 120 mg/l hardness. These concentrations reflect the high degree of mineralization of ground water in carbonate bedrock and unconsolidated deposits derived from this bedrock. The larger streams, which transport varying amounts of industrial and domestic effluents, averaged about 150 mg/l dissolved solids and 90 mg/l hardness. Iron and manganese concentrations in both ground water and surface water at some places exceed recommended limits for domestic and industrial use. Most wells in the report area yield water with little or no iron or manganese. In certain localities however, the probability is high of encountering water with excessive concentrations of these constituents. Schists, especially the unit in the northwestern corner of the basin, are the likely sources of water with excessive iron and manganese. Iron concentrations in naturally occurring stream water exceed 0.3 mg/l under low-flow conditions at 29 percent of the sites sampled. These excessive concentrations result from discharge of iron-bearing water from aquifers or from swamps where iron is released from decaying vegetation. Water temperature in the larger streams ranges from 0°C (degrees Celsius) to about 28°C. Ground water between 30 feet and 200 feet below the land surface has a relatively constant temperature, usually between 8°C and 11°C. The quantity of suspended sediment transported by streams under natural conditions is negligible. Even in streams affected by man, turbidity is rarely a problem. The total amount of water used in the report area for all purposes during 1967 was about 6,360 million gallons, or 140 gpd per person. Public supplies furnished the domestic needs of nearly half the population of the area. All of the 14 public supplies sampled provided water that meets the drinking water standards of the U.S. Public Health Service.

Connecticut↗

USGS1983

Ground water in the southeastern Uinta Basin, Utah and Colorado

The potential for developing oil-shale resources in the southeastern Uinta Basin of Utah and Colorado has created the need for information on the quantity and quality of water available in the area. This report describes the availability and chemical quality of ground water, which might provide a source or supplement of water supply for an oil-shale industry. Ground water in the southeastern Uinta Basin occurs in three major aquifers. Alluvial aquifers of small areal extent are present in valley-fill deposits of six major drainages. Consolidated-rock aquifers include the bird's-nest aquifer in the Parachute Creek Member of the Green River Formation, which is limited to the central part of the study area; and the Douglas Creek aquifer, which includes parts of the Douglas Creek Member of the Green River Formation and parts of the intertonguing Renegade Tongue of the Wasatch Formation; this aquifer underlies most of the study area. The alluvial aquifers are recharged by infiltration of streamflow and leakage from consolidated-rock aquifers. Recharge is estimated to average about 32,000 acre-feet per year. Discharge from alluvial aquifers, primarily by evapotranspiration, also averages about 32,000 acre-feet per year. The estimated volume of recoverable water in storage in alluvial aquifers is about 200,000 acre-feet. Maximum yields to individual wells are less than 1,000 gallons per minute. Recharge to the bird's-nest aquifer, primarily from stream infiltration and downward leakage from the overlying Uinta Formation, is estimated to average 670 acre-feet per year. Discharge from the bird's-nest aquifer, which is primarily by seepage to Bitter Creek and the White River, is estimated to be 670 acre-feet per year. The estimated volume of recoverable water in storage in the bird's-nest aquifer is 1.9 million acre-feet. Maximum yields to individual wells in some areas may be as much as 5,000 gallons per minute. A digital-computer model of the flow system was used to evaluate the effects of oil-shale development on the bird's-nest aquifer at the Federal lease tracts Ua and Ub. Results of model simulations indicate that during construction of a vertical access shaft, a pumping rate of about 900 gallons per minute would be required to dewater the aquifer. The model also indicates that the construction of a proposed reservoir on the White River may raise water levels in the bird's-nest aquifer near the reservoir site by as much as 45 feet. The flow model was used to evaluate the potential ground-water supply available for oil-shale development in the vicinity of the Federal lease tracts Ua and Ub. The results of the simulation indicate that the bird's-nest aquifer could supply about 10,000 acre-feet of water per year at that site, for a period of 20 years. Drawdown after 20 years of pumping would exceed 250 feet near the simulated well field. Based on the results of the model simulation, it is estimated that the aquifer could simultaneously supply another 10,000 acre-feet of water per year in the northern part of the study area, but some interference between well fields could be expected. The Douglas Creek aquifer is recharged by precipitation and stream infiltration at an average rate of about 20,000 acre-feet per year. Discharge is estimated to be about the same and is primarily through springs and diffuse seepage. The estimated volume of recoverable water in storage is 16 million acre-feet. Maximum yields to individual wells are estimated to be less than 500 gallons per minute. A model of the flow system in the Douglas Creek aquifer indicates that the aquifer could supply about 700 acre-feet of water per year for oil-shale development at Federal lease tracts Ua and Ub and at the TOSCO Corp. site. After 20 years of pumping, water levels in production wells would be near the base of the aquifer. Based on the results of the model simulation, it is estimated that the aquifer could supply another 700 acre-feet of water per year in the southern part of the modeled area, but some interference between wells could be expected. Chemical quality of the ground water in the southeastern Uinta Basin varies considerably. Water from alluvial wells ranges from about 440 to 27,800 milligrams per liter of dissolved solids. Water from two consolidated- rock aquifers has dissolved-solids concentrations ranging from 870 to 5,810 milligrams per liter in the bird's-nest aquifer, and from 640 to 6,100 milligrams per liter in the Douglas Creek aquifer. Water from alluvial wells generally is a sodium sulfate type, whereas water in both the consolidated- rock aquifers generally changes from a sodium sulfate type to a sodium bicarbonate type. All ground water is very alkaline, and the alluvial aquifers contain very hard water. None of the water is suitable for public supply, but all the water could be used for industrial purposes such as washing and cooling. Changes in chemical composition of the ground water can be attributed to several physiochemical processes, including mineral precipitation and dissolution, oxidation and reduction, mixing, ion exchange, and evaporative concentration. Mass-transfer modeling of these processes shows how they can account for the variability in the ground-water quality. The mass-transfer model of the Bitter Creek alluvial aquifer shows that evaporative concentration, combined with precipitation of calcite, dolomite, gypsum, and release of carbon dioxide to the atmosphere results in the documented changes in pH and dissolved solids in the water. The water-quality changes in the consolidated-rock aquifers are a result of precipitation of calcium carbonate and perhaps dolomite (calcium magnesium carbonate) with the reduction of sulfate by organic carbon, as well as ion exchange of magnesium for sodium. These processes result in large values of pH and alkalinity in the water.

Colorado, Utah↗

USGS1987

Ground water in the southeastern Uinta Basin, Utah and Colorado

The potential for developing oil-shale resources in the southeastern Uinta Basin of Utah and Colorado has created the need for information on the quantity and quality of water available in the area. This report describes the availability and chemical quality of ground water, which might provide a source or supplement of water supply for an oil-shale industry. Ground water in the southeastern Uinta Basin occurs in three major aquifers. Alluvial aquifers of small areal extent are present i n val ley-f i 11 deposits of six major drainages. Consolidated-rock aquifers include the birds's-nest aquifer i n the Parachute Creek Member of the G reen River Formation, which is limited to the central part of the study area; and the Douglas Creek aquifer, which includes parts of the Douglas Creek Member of the Green River Formation and parts of the intertonguing Renegade Tongue of the Wasatch Formation; this aquifer underlies most of the study area. The alluvial aquifers are recharged by infiltration of streamflow and leakage from consolidated-rock aquifers. Recharge is estimated to average about 32,000 acre-feet per year. Discharge from alluvial aquifers, primarily by evapotranspiration, also averages about 32,000 acre-feet per year. The estimated volume of recoverable water in storage in alluvial aquifers is about 200,000 acre-feet. Maximum yields to individual wells are less than 1,000 gallons per minute. Recharge to the bird's-nest aquifer, primarily from stream infiltration and downward leakage from the overlying Uinta Formation, is estimated to average 670 acre-feet per year. Discharge from the bird's-nest aquifer, which is primarily by seepage to Bitter Creek and the White River, is estimated to be at 670 acre-feet per year. The estimated volume of recoverable water in storage in the bird's-nest aquifer is 1.9 million acre-feet. Maximum yields to individual wells in some areas may be as much as 5,000 gallons per minute. A digital-computer model of the flow system was used to evaluate the effects of oil-shale development on the bird's-nest aquifer at the Federal lease tracts Ua and Ub. Results of model simulations indicate that during construction of a vertical access shaft, a pumping rate of about 900 gallons per minute would be required to dewaterthe aquifer. The model also indicates that the construction of a proposed reservoir on the White River may raise water levels in the bird's-nest aquifer near the reservoir site by as much as 45 feet. The flow model was used to evaluate the potential ground-water supply available for oil-shale development in the vicinity of the Federal lease tracts Ua and Ub. The results of the simulation indicate that bird's-nest aquifer could supply about 10,000 acre-feet of water per year at that site, for a period of 20 years. Downdraw after 20 years of pumping would exceed 250 feet near the simulated well field. Based on the results of the model simulation, it is estimated that the aquifer could simultaneously supply another 10,000 acre-feet of water per year in the northern part of the study area, but some interference between well fields could be expected. The Douglas Creek aquifer is recharged by precipitation and stream infiltration at an average rate of about 20.000 acre-feet per year. Discharge is estimated to be about the same and is primarily through springs and diffuse seepage. The estimated volume of recoverable water in storage is 16 million acre-feet. Maximum yields to individual wells are estimated to be less than 500 gallons per minute. A model of the flow system in the Douglas Creek aquifer indicates that the aquifer could supply about 700 acre-feet of water per year for oil-shale development at Federal lease tracts Ua and Ub and at the TOSCO Corp. site. After 20 years of pumping, water levels in production wells would be near the base of the aquifer. Based on the results of the model simulation, it is estimated that the aquifer could supply another 700 acre-feet of water per year in the southern part of the modeled area, but some interference between wells could be expected. Chemical quality of the ground water in the southeastern Uinta Basin varies considerably. Water from alluvial wells ranges from about 440 to 27,800 milligrams per liter of dissolved solids. Water from two consolidated-rock aquifers has dissolved-solids concentrations ranging from 870 to 5,810 milligrams per liter in the bird's-nest aquifer, and from 640 to 6,100 milligrams per liter in the Douglas Creek aquifer. Water from alluvial wells generally is a sodium sulfate type, whereas water in both the consolidated-rock aquifers generally changes from a sodium sulfate type to a sodium bicarbonate type. All ground water is very alkaline, and the alluvial aquifers contain very hard water. None of the water is suitable for public supply, but all the water could be used for industrial purposes such as washing and cooling. Changes in chemical composition of the ground water can be attributed to several physiochemical processes, including mineral precipitation and dissolution, oxidation and reduction, mixing, ion exchange, and evaporative concentration. Mass-transfer modeling of these processes shows how they can account for the variability in the ground-water quality. The mass-transfer model of the Bitter Creek alluvial aquifer shows that evaporative concentration, combined with precipitation of calcite, dolomite, gypsum, and release of carbon dioxide to the atmosphere results in the documented changes in the pH and dissolved solids in the water. The water-quality changes in the consolidated-rock aquifers are a result of precipitation of calcium carbonate and perhaps dolomite (calcium magnesium carbonate) with the reduction of sulfate by organic carbon, as well as ion exchange of magnesium for sodium. These processes result in large values of pH and alkalinity in the water.

Colorado, Utah↗

USGS2021

Economic geology and environmental characteristics of antimony deposits

Antimony is commonly listed as a critical mineral, particularly in the United States and European Union [1]. Its criticality, or supply risk, is derived from a combination of economic vulnerability, disruption potential of supply, and trade exposure [2].Disruption potential relates a country’s ability and willingness to supply a commodity. Commodities for which supply is concentrated in the fewest countries have the greatest potential for supply disruption, trade exposure, and economic vulnerability. In 2018, approximately 61% of the world production of antimony was mined from China, followed by Russia (20%) and Tajikistan (10%) [3] (Fig. 3.1). Several reviews of antimony as a critical mineral have been recently published [4, 5]. The uses of antimony can be divided into three main categories: metal products, non-metal uses, and flame retardants [5]. Most metallic antimony use is inlead-acid batteries. Antimony trioxide (Sb 2 O 3 ) combined with halogenated com-pounds is used as a fire retardant in plastics, fabrics, and other applications. Other non-metallic uses include as a catalyst for plastics, and in the glass industry. Emerging uses include data storage and novel photovoltaic cells. Recycling of batteries represents an important reuse of antimony, but other uses of antimony do not lend themselves to recycling. This chapter describes mineral deposit types that are primary sources of antimony, and environmental effects related to their mining. Antimony can be re-covered as either a primary commodity from some deposits or as a by product commodity from some gold or silver deposits. Environmental risks associated with antimony mining include those related to mining in general, such as the acid-generating potential of solid mine waste, and some issues specific to antimony, as described below.

Book chapter↗

USGS1957

Water resources of the Yadkin-Pee Dee River basin, North Carolina

Sufficient water is available in the basin of the Yadkin and Pee Dee Rivers to meet present requirements and those for many years to come if water use increases at about the present rate. Data presented in this report show that the average annual streamflow from approximately 82 percent of the basin area during the 25-year period, 1929-53, was about 6,200 mgd, representing essentially the total available water supply. Comparison of the available water supply to the estimated withdrawal use (excluding water power) of both surface and ground water of 600 mgd indicates the relative utilization of the water resources of the basin at present. If proper pollution controls are observed and practiced so that water in the various streams may be reused several times, the potential water available is even greater than indicated by the above comparison. Preliminary studies indicate that the quantity of water now being withdrawn from ground-water reservoirs in the basin is only a fraction of the total that may be obtained from this source. Twenty-eight of the 64 municipalities having public water-supply systems use surface water; however, as the largest cities in the area use surface supplies, about 85 percent of the water used for public supplies is from surface sources. Of the 20 complete-record stream-gaging stations now in operation in this area 7 have been in operation for 24 years or longer. Periodic measurements of the rate of flow have been made at 31 additional sites on streams scattered widely over the basin. All available streamflow data including those for 1953 are summarized in either graphic or tabular form, or both. Because of the critically low flows occurring during the drought of 1954, several illustrations include data for 1954 and the early months of 1955 for comparison with the minima of previous years. Adequate water for domestic use is available from wells throughout the basin. The consolidated rocks of the Piedmont furnish water for small industries and for municipalities whose population is less than about 1,500. The yields of wells in rock range from less than 1 gpm to as much as 200 gpm with local, rather than regional, geologic factors controlling the yield. The average municipal well in consolidated rocks yields about 30 gpm. In contrast, the sands of the Coastal Plain, in the eastern part of the basin, furnish as much as 500 gpm to individual wells, and ground-water conditions are generally similar throughout that region. A cumulative deficiency in rainfall from 1953 to 1955, has caused ground-water levels to fall below the seasonal averages, but the decline is thought not to indicate a long-term trend. The most serious problem involving future use of ground water is the lack of knowledge of the characteristics of the ground-water provinces in the basin. Generally the chemical quality of the surface waters in the Yadkin-Pee Dee River basin is good. They are low in mineral matter and soft, although some of the surface water contains excessive quantities of iron. In some local areas the streams have been polluted by municipal and industrial wastes. During periods of high runoff many of the streams transport large quantities of suspended sediment. Tributary streams in the lower eastern part of the basin are highly colored because of drainage from swampy areas. Ground water from the consolidated rocks in the Piedmont region is more variable in quality than water from other areas in the basin. The dissolved solids in water from the consolidated rocks ranged from 26 to 1,480 ppm with a median of 109 ppm. Wells in the Cretaceous clay province normally yield slightly acid waters. The pH ranges from 4.7 to 7.7 with a median of 5.3. Generally ground water in this province is extremely soft and low in dissolved solids. Wells in the Cretaceous sand province yield a sodium bicarbonate type of water ranging in hardness from 2 to 130 ppm.

North Carolina, Virginia↗

USGS1968

Water for the growing needs of Harrison County, Mississippi

The potential for water-supply development in Harrison County is almost unlimited. During an average year, more than 350 billion gallons of water flow into the Gulf of Mexico from the streams of the county. With storage reservoirs these streams have a potential sustained supply of hundreds of millions of. gallons per day. Recreation uses and flood-control benefits could also be considered in reservoir design. Upstream from the zones of salt-water penetration, mineral content is low and fairly constant. Water in the streams generally has high color and low pH ; treatment would be required for most municipal and industrial uses. Impoundment in reservoirs normally would have little effect on the quality of the surface water. However, impoundment would trap most of the suspended-sediment load of the streams. Flooding along the major streams of Harrison County is a minor hazard at present (1966), but with further industrial development and urbanization, flooding in these now rural areas could become serious. Intense rainfall from thunderstorms and hurricanes causes serious local flooding in the populous areas near the coast. Tidal flooding, a result of tropical storms, is an ever-present hazard in areas near the coast. The ground-water reservoir, which at present provides all fresh-water supplies, is capable of supporting many times the 25 million gallons per day withdrawal through existing wells. Fresh water occurs to depths as great as 2,500 feet in sand aquifers of Pliocene and Miocene age. Many of the aquifers have high transmissibility; most of those tested have transmissibility in the range, of 50,000-100,000 gallons per day per foot. Although few wells produce more than 1,000 gallons per minute, several of the aquifers can yield two to three times that amount to wells designed for the higher production. Artesian water levels along the coast are declining at a rate of 1 foot per year on the average; however, water levels are still above or only slightly below the land surface in most places, and considerable additional drawdown is economically available. Newly discovered deep aquifers (1,700-2,500 ft) have water levels 100 feet above the surface and probably will provide flow yields of 2,000 gallons per minute or more. The temperature of this deep water is nearly 100?F. Nearly all the ground water is of good quality and requires little or no treatment for most uses. It is soft, and total mineral content is usually less than 250 parts per million. Color is seldom a problem, although it may have to be considered in the undeveloped deep aquifers. The pH ordinarily is greater than 7.0, but it is slightly less than 7.0 in most places in the shallow aquifers.

Water Supply Paper↗