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Temporal and spatial changes in seismic attenuation associated with inferred fluid migration in the 2016 central Apennines earthquake sequence

Prior work suggests that high‐frequency seismic attenuation acts as a highly sensitive proxy for crustal permeability and fluid mobility in fractured media. We test the hypothesis that the fault system responsible for the 2016–2017 Amatrice–Visso–Norcia–Capitignano sequence acted as an impermeable seal, compartmentalizing pressurized fluids until dynamic rupture triggered widespread fluid diffusion. By tracking across the sequence the spatiotemporal evolution of the S ‐wave anelastic attenuation parameter, we identify large, positive low‐frequency attenuation anomalies emerging within the hanging wall following the Amatrice mainshock and strictly preceding subsequent large ruptures. Conversely, we observe weaker, negative anomalies in the footwall, anticorrelated in time with those of the hanging wall, revealing a massive asymmetry in fluid redistribution and permeability evolution across the fault system. Furthermore, aftershock migration rates reveal distinct linear alignments in a distance‐reduced time space, allowing us to explicitly track and quantify episodes of lateral and upward fluid migration. These physically consistent patterns suggest that stress‐driven fluid diffusion directly weakens adjacent fault patches, dictating the spatiotemporal migration of seismicity. We conclude that near‐real‐time monitoring of seismic attenuation may help detect fluid redistribution in active fault systems and may provide useful information for time‐dependent seismic hazard assessment.

central Apennines

Effects of snowmobile use on snowpack chemistry in Yellowstone National Park, 1998

Snowmobile use in Yellowstone National Park has increased substantially in the past three decades. In areas of greatest snowmobile use, elevated levels of by-products of gasoline combustion such as ammonium and benzene have been detected in snowpack samples. Annual snowpacks and snow-covered roadways trap deposition from local and regional atmospheric emissions. Snowpack samples representing most of the winter precipitation were collected at about the time of maximum annual snow accumulation at a variety of locations in the park to observe effects of a range of snowmobile traffic levels. Concentrations of organic and inorganic compounds in snow samples from pairs of sites located directly in and off snow-packed roadways used by snowmobiles were compared to concentrations in samples collected at nearby off-road sites. Concentrations of ammonium were 2 to 5 times higher for the in-road snow compared to off-road snow for each pair of sites. Thus, concentrations decreased rapidly with distance from roadways. In addition, concentrations of ammonium, nitrate, sulfate, benzene, and toluene in snow were positively correlated with snowmobile use.

Wyoming

Concentration-discharge relations and transient metal loads reveal spatiotemporal variability in solute-generation mechanisms in a mine-affected watershed

Concentration-discharge (CQ) relations are commonly used to understand geochemical and hydrologic controls on the generation of solutes in watersheds. Despite the widespread application of CQ relations, this technique has been infrequently applied to acid mine drainage (AMD) sites, but the CQ framework may allow mechanistic understanding of remedial outcomes such as impoundment of water within underground mines. Results of CQ analyses and changes in metal loads in an AMD affected watershed in Colorado, USA indicate that dissolved loads increased at many individual locations following water impoundment within mine workings. Although increased loads were observed at most individual locations, these increases were offset by a large decrease in loading from the largest mine. A loading analysis that included data from an instream monitoring location showed a statistically significant decrease in Fe and Zn after bulkhead emplacement, indicating a net positive effect of bulkheads. Streams generally displayed dilution CQ patterns whereas mines and springs showed either flushing or chemostatic patterns prior to bulkheading, which transitioned to chemostatic patterns following bulkheading, indicating a transition from dynamic to equilibrium geochemical processes. Saturation indices for sulfide and secondary minerals indicated that mines and springs were near equilibrium for phases including schwertmannite, fluorite, and gypsum. Saturation indices vary through time for mines suggesting progressive leaching of sulfide minerals as the mass of available minerals in the mine workings decreases. Together, these diverse analyses provide an integrated understanding of the variability in solute generating processes in this watershed and may inform remediation plans for similarly affected sites by indicating the nature of mineralogic controls on water quality.

Colorado

Water resources related to breccia pipe uranium mining in the Grand Canyon region

Introduction In the arid Grand Canyon region, water resources are limited to primarily the Colorado River and associated tributaries and to groundwater in the form of seeps and springs. Groundwater resources in the region supply water for human use and support diverse and rich ecosystems in the locations immediately surrounding the seeps and springs. Throughout the region, uranium resources occur and may interact with water resources in both mined and unmined uranium deposits. There is a need to better understand groundwater in the region and the effects from uranium mining in order to better manage the limited water resources in the area. This Fact Sheet summarizes results from U.S. Geological Survey studies that were conducted on this topic from 2012 to 2023.

Arizona

Multidecadal change in pesticide concentrations relative to human health benchmarks in the Nation’s groundwater

Groundwater-quality trend assessments identify aquifers that are responding to changes in pesticide use and the compounds that may pose a threat to water availability. The U.S. Geological Survey has been monitoring pesticide concentrations in groundwater for 25 principal aquifers across the conterminous United States since 1993. The groundwater well locations represent a range of soils, climate, and landforms. The wells are used to monitor groundwater underlying selected agricultural and urban settings and groundwater used for domestic supply. This study examined changes in relative concentrations, defined here as the percentage of wells with pesticide concentrations exceeding a human health benchmark (HHB). HHBs used in this report are legally enforceable drinking-water standards and nonenforceable drinking water levels. Relative pesticide concentration increases may lead to decreased water availability, as restrictions may be put in place for groundwater used as a drinking-water source. This study focused on concentration changes in 22 pesticides that were included in laboratory analysis from 1993 to 2023. The analysis and interpretation of these pesticide concentrations in groundwater have been separated into approximate decadal intervals (decade 1 (1993–2001), decade 2 (2002–12), and decade 3 (2013–22). For one pesticide, 1,2-dibromo-3-chloropropane (DBCP), concentration data were also collected in decade 4 (2023–onward). Atrazine, deethylatrazine, alachlor, prometon, and simazine were 5 pesticides detected at moderate concentrations (greater than 10 percent of the HHB but less than or equal to the HHB). The percentage of wells that had groundwater pesticide concentrations in the moderate concentration category decreased from 7 percent in decade 1 to 2 percent in decade 3. The agricultural networks had the highest percentages of wells with moderate concentrations, and these percentages decreased from 13 percent in decade 1 to 4 percent in decade 3. Moderate concentrations in the urban networks decreased between decades 1 and 2 from 4 percent to 0 percent. No moderate concentrations occurred in the urban networks in decade 3. The percentage of wells with moderate concentrations in the domestic supply networks (1 percent) was the lowest of all the network types and did not change across the three decades. Moderate atrazine or deethylatrazine concentrations occurred across all three decades in aggregated ecoregions representing similar soils, climate, and landforms in the Semiarid West, Midcontinent, and Northeastern United States. Moderate concentrations of prometon, alachlor, and simazine also occurred in the Midcontinent, Arid West, Northeast, South Atlantic Gulf, and Semiarid West regions, but the moderate concentrations did not persist across all three decades. DBCP was the only pesticide that exceeded its respective HHB, and the exceedances occurred across all four decades. In this report, the DBCP analysis was limited to one well network in the Central Valley, California. Agricultural use of DBCP was suspended in 1977. Forty-five years after being banned, DBCP concentrations were greater than the maximum contaminant level of 2 micrograms per liter (μg/L), but the number of exceedances decreased from 50 percent to 15 percent of the samples between 1993 and 2023. This assessment of decadal groundwater pesticide concentrations provides a characterization of changes in water availability because of pesticide contamination in areas where groundwater is used as a drinking-water source. The results highlight the importance of continued long-term monitoring and assessment of groundwater pesticides to identify locations and specific compounds that may pose a potential risk to human health.

continental United States

Deformed submarine terraces in Puget Sound, Pacific Northwest, indicate only one M >~7.5 earthquake on the Seattle fault zone in the past 11,000 yr

Submerged marine terraces in Puget Sound, deformed across the Seattle fault zone (SFZ), indicate that only one earthquake as large as M~7.5 has occurred in at least the past 11 kyr. Previous paleoseismic studies document a M~7.5 earthquake between 923–4 CE, which uplifted coastal marine terraces by as much as 8 m. We demonstrate that this earthquake was the only such event since ~11 ka by mapping and quantifying deformation of older marine terraces, now submerged in Puget Sound. The submerged terraces, attributed to a late-glacial sea-level lowstand, record both glacial isostatic rebound and tectonic deformation. Vertical offset of the ~11 ka terraces within the SFZ is comparable to that of the marine terraces uplifted in 923 CE, implying no additional large (M>~7.5) earthquake on the SFZ since ~11 ka. This result implies a longer recurrence interval than current hazard estimates, which assumes recurrence of M>7.1 events every 5 kyr. Our mapping of SFZ deformation since ~11 ka also supports fault segmentation and contiguous block uplift between the Seattle and Tacoma fault zones.

Washington

Pesticides in surface waters of the Upper Colorado River Basin, Colorado, 1996-98

Forty-four river, stream, and drain sites in the Upper Colorado River Basin in Colorado were sampled during 1996-98 to determine the occurrence and distribution of pesticides in the basin. In a fixed-station study, 57 surface-water samples were collected from October 1996 through January 1998 at four sites. Each site was sampled approximately monthly for up to a year, with more frequent sampling during the spring and summer growing season. In a synoptic study, surface-water samples were collected at 43 sites in the agricultural areas of the Grand Valley and the Uncompahgre River Valley in May 1998. Each site was sampled once. Pesticide concentrations generally were low and varied seasonally and across land uses. Thirty-five pesticides were detected at least once in the two studies, and 11 pesticides accounted for almost 82 percent of the detections. Herbicides were more commonly detected than insecticides, and only the herbicides alachlor and atrazine were detected in more than 50 percent of the samples. Carbofuran was the most commonly detected insecticide and was detected in 19 percent of the samples. Pesticide detections increased and were measured at higher concentrations in the summer months and at the agriculture sites. All pesticide concentrations were less than drinking-water standards, and most complied with human-health advisories and criteria for the protection of freshwater aquatic life. Pesticides in the Upper Colorado River Basin in Colorado were detected slightly less frequently and generally at lower concentrations than in 20 National Water-Quality Assessment Program study-unit basins that collected water-quality data from 1992 through 1996. Results from surface-water sampling conducted during 1996?98 in the Upper Colorado River Basin in Colorado indicate that beneficial uses of water were not being impaired by the presence of pesticides in surface waters in the basin.

Colorado

In-situ geochronology using LA-ICP-MS/MS: Application of the Lu-Hf system in carbonate, apatite and fluorite

Geochronology is a fundamental tool for reconstructing earth history and constraining the timing of ore deposit formation. Traditionally, U-rich minerals like zircon, titanite, monazite and apatite have been analysed to determine the timing of mineralization and alteration events. However, not all deposits or alteration assemblages contain these minerals, and the U-Pb system can be disturbed due to open system behaviour. We present a methodology for obtaining in-situ Lu-Hf dates from various minerals to demonstrate the potential for dating ore deposits that lack U-rich minerals. Carbonate, apatite and fluorite minerals from different tectonic settings and geological environments were analysed. We acquired Lu-Hf and REE (rare earth element) data from carbonate minerals from a carbonatite orebody and dike samples from the Mountain Pass REE carbonatite deposit in California, USA. We also tested a ‘double-dating’ method, where U-Th-Pb dates and Lu-Hf dates were obtained from the same analysis of apatite from rocks in the Michigan’s Great Lakes Tectonic Zone. Preliminary results for Lu-Hf dating of fluorite from carbonatite rocks in the Lemitar Mountains of New Mexico are also included. The analytical methodology shows promising results in each of these cases where there is sufficient parent Lu and U and measurable daughter Hf and Pb respectively.

Conference Paper

The distribution of bromide in water in the Floridan aquifer system, Duval County, northeastern Florida

Although Duval County, Florida, has ample ground-water resources for public supply, the potential exists for a problem with excessive disinfectant by-products. These disinfectant by-products result from the treatment of raw water containing low concentrations of bromide and naturally occurring organic compounds. Because of this potential problem, the relation of bromide concentrations to aquifer tapped, well location and depth, and chemical characteristics of water in the Floridan aquifer system underlying Duval County were studied to determine if these relations could be applied to delineate water with low-bromide concentrations for future supplies. In 1992, water samples from 106 wells that tap the Floridan aquifer system were analyzed for bromide and major dissolved constituents. A comparison of bromide concentrations from the 1992 sampling with data from earlier studies (1979-80) indicates that higher bromide concentrations were detected during the earlier studies. The difference between the old and new data is probably because of a change in analytical methodology in the analysis of samples. Bromide concentrations exceeded the detection limit (0.10 milligrams per liter) in water from 28 of the 106 wells (26 percent) sampled in 1992. The maximum concentration was 0.56 milligrams per liter. There were no relations between bromide and major dissolved constituents, well depth, or aquifer tapped that would be useful for determining bromide concentrations. Areal patterns of bromide occurrence are not clearly defined, but areas with relatively high bromide concentrations tend to be located in a triangular area near the community of Sunbeam, Florida, and along the St. Johns River throughout Duval County.

Florida

Peri-Gondwanan sediment in the Arkoma Basin derived from the north: The detrital zircon record of a uniquely concentrated non-Laurentian source signal in the late Paleozoic

During the assembly of Pangea, peri-Gondwanan terranes collided with the eastern and southern margins of Laurentia and brought with them unique detrital zircon U-Pb signatures. Discriminating between individual peri-Gondwanan terranes in the detrital record is difficult due to their similar geologic histories. However, characterization of this provenance is critical for understanding late Paleozoic sediment routing during development of Pangea. Along southeastern Laurentia, in the Arkoma Basin (present-day Arkansas and eastern Oklahoma, southeastern United States), we identified Middle Pennsylvanian (Desmoinesian) strata that exhibit a concentrated peri-Gondwanan detrital zircon signature (e.g., ca. 800–550 Ma). Although several southern peri-Gondwanan terranes (e.g., Maya, Suwannee) are closer to the Arkoma Basin, geologic data, such as predominantly north-to-south paleocurrents and proximal-to-distal facies relationships in these Desmoinesian strata, support a northern source (e.g., Ganderia, Avalonia, Meguma). Further evidence of a northern source comes from detrital zircon source mapping, which reveals the persistence of this peri-Gondwanan signal in depocenters to the north of the basin after the signal had diminished in the Arkoma Basin. To this end, bottom-up detrital zircon source modeling, source mapping, regional stratigraphy, paleocurrent data, and sandstone petrography allow us to reconstruct the evolution of this Middle Pennsylvanian (Desmoinesian) sediment pathway in the context of intraplate and plate-margin tectonic activity. This reconstruction documents processes affecting Earth’s surface (e.g., tectonics, climate) during the assembly of Pangea and describes in detail part of a dynamic continental-scale drainage system.

Geosphere

Floods of February 1989 in Tennessee

Rainfall amounts of over 5 inches the night of February 13 and the morning of February 14, 1989, caused flooding in areas of Middle and West Tennessee. The towns of Lebanon in Middle Tennessee and Obion in West Tennessee were most severely affected. Most of the business district in Lebanon and many residential areas in Obion were flooded. Recurrence intervals for 24-hour rainfall totals were as high as 25 years at some sites but most peak discharges had recurrence intervals of less than 10 years. Rainfall amounts for the period February 13-20, 1989, peak stages and discharges for this flood, the peak of record, and a list of discharge measurements made during the flood are documented in this report.

Tennessee