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USGS1957

A truckmounted spectrographic laboratory for use in geochemical exploration

A truck-mounted spectrographic laboratory has been designed and built by the U. S. Geological Survey to investigate the feasibility of using and transporting such equipment in the field as an aid in supplying rapid on-the-spot analytical data to geochemical exploration field parties.The laboratory is housed inside a 7- X 12-foot insulated and air-conditioned van-type truck body and carries complete equipment for making qualitative, semiquantitative, and quantitative analyses of geological materials. The spectrograph is a fixed-position 1.5-meter grating instrument of the Wadsworth type which records a range of spectra from 2063 to 4837A in the second order on a 20-inch strip of film. Companion units are a projection type comparator-densitometer, a film processor, and other accessory equipment. Trailer-mounted motor-generators supply 230 volts d-c for the arc source unit and 115 volts a-c for lights and accessories.Since its completion in May 1955, the truck-mounted laboratory has been driven over 4,000 miles. During this travel all the equipment remained in good adjustment; the laboratory was made ready for operation in less than 2 hours after arrival at the site of a field project.Because of the large number of elements that can be determined from a single spectrogram, the truck-mounted laboratory is useful in the early stages of a geochemical exploration project to determine diagnostic suites of elements, and later, to guide the day-to-day sampling.

Economic Geology↗

USGS1947

Geology and ground-water resources of Puerto Rico

Puerto Rico, the easternmost and smallest of the Greater Antilles, has an axis of deformed and metamorphosed volcanic rocks of Upper Cretaceous age, intruded by dioritic rocks during the Antillean revolution. The hard-rock core is flanked on the north and south by limestones and clastic rocks of late Oligocene and early Miocene age, which have been gently arched and uplifted. Similar rocks were deposited in late Miocene or early Pliocene time along the west coast. During the Quaternary the island has been separated from the other major Antillean islands by faulting and has been arched, uplifted, and tilted to the northeast. Alluvium and littoral deposits have partially filled the valleys and have formed coastal plains on the north and south. The Upper Cretaceous volcanic and associated rocks yield small supplies of water to wells in most places. The Tertiary limestones yield large supplies in some places on the north, south, and west coasts. The Quaternary sands and gravels are the most important aquifers. They yield about 200 million gallons a day to wells in the main south coastal plain alone. The water is used largely for irrigation. A total of perhaps 250 to 300 million gallons a day is pumped from wells in the island, and moderate to large additional supplies are available in some places.

Puerto Rico↗

USGS1966

Phase relations involving sphalerite in the Fe-Zn-S system

The equilibrium diagram for the Fe - Zn - S System has been worked out in détail from 580° to 850° C. Previous work on this System is proven to be seriously in error and températures heretofore estimated from the " sphalerite geothermometer" are without a sound quantitative foundation. Sphalerite solid solutions lie essentially along the FeS-ZnS join. Neither pyrite nor pyrrhotite takes up appréciable amounts of zinc. The FeS-ZnS binary solvus (équivalent to the assemblage sphalerite + stoichi-ometric FeS) is very steep, passing through 56 mole percent FeS at 850° C and 52 mole percent FeS at 580° C. It is not useful geologically because of the rarity of stoichiometric FeS as a primary minerai in sphalerite -bearing assemblages; however, the relatively large rôle played by total pressure on the binary solvus might permit the iron content of sphalerite to be useful in determining the pressure of équilibration of some météorites. Of greater géologie interest is the sphalerite + pyrite + pyrrhotite assemblage in which the composition of sphalerite changes from 13 mole percent FeS at 742° C to 19 percent at 580° C. Unfortunately, this equilibrium cannot be quantitatively extrapolated to lower températures from the presently available data and therefore quantitative geothermom-etry of pyrite + pyrrhotite + sphalerite assemblages is not feasible at présent. Thermochemical calculations prove that the iron content of sphalerite in pyrite + sphalerite assemblages is very sensitive to variations in température and fugacity of S 2; this relationship provides an explanation of growth-zoned sphalerite as the resuit of fluctuations of sul-fur fugacity, and, in combination with other sulfide assemblages that define isobarically univariant relations between température and sulfur fugacity, forms a potential basis for quantitative geothermometry.

Economic Geology↗

USGS2012

The physical hydrogeology of ore deposits

Hydrothermal ore deposits represent a convergence of fluid flow, thermal energy, and solute flux that is hydrogeologically unusual. From the hydrogeologic perspective, hydrothermal ore deposition represents a complex coupled-flow problem—sufficiently complex that physically rigorous description of the coupled thermal (T), hydraulic (H), mechanical (M), and chemical (C) processes (THMC modeling) continues to challenge our computational ability. Though research into these coupled behaviors has found only a limited subset to be quantitatively tractable, it has yielded valuable insights into the workings of hydrothermal systems in a wide range of geologic environments including sedimentary, metamorphic, and magmatic. Examples of these insights include the quantification of likely driving mechanisms, rates and paths of fluid flow, ore-mineral precipitation mechanisms, longevity of hydrothermal systems, mechanisms by which hydrothermal fluids acquire their temperature and composition, and the controlling influence of permeability and other rock properties on hydrothermal fluid behavior. In this communication we review some of the fundamental theory needed to characterize the physical hydrogeology of hydrothermal systems and discuss how this theory has been applied in studies of Mississippi Valley-type, tabular uranium, porphyry, epithermal, and mid-ocean ridge ore-forming systems. A key limitation in the computational state-of-the-art is the inability to describe fluid flow and transport fully in the many ore systems that show evidence of repeated shear or tensional failure with associated dynamic variations in permeability. However, we discuss global-scale compilations that suggest some numerical constraints on both mean and dynamically enhanced crustal permeability. Principles of physical hydrogeology can be powerful tools for investigating hydrothermal ore formation and are becoming increasingly accessible with ongoing advances in modeling software.

Economic Geology↗

USGS2017

Mineral potential mapping in an accreted island-arc setting using aeromagnetic data: An example from southwest Alaska

The distribution of volcanogenic massive sulfide (VMS), porphyry-epithermal, Alaska-type ultramafic-mafic complexes, intrusion-related Au, and granitoid Sn-W ore deposits in southwest Alaska supports current metallogenic models linking the formation of these deposit types to the emplacement of different suites of igneous rocks during the evolution of this convergent plate margin. Regional-scale aeromagnetic data provide a continuous set of observations over the deposits and show contrasting patterns over the igneous rock suites hosting the various deposit types. Combined with surface geologic data and regional metallogenic constraints, aeromagnetic data—filtered to enhance the anomalous magnetic field and map magnetic domains—were used to produce a mineral potential map across this accreted island-arc setting. The reduced-to-pole, upward continuation, and total horizontal gradient transform maps show anomalies that could represent porphyry-epithermal deposits within the intraoceanic- and continental-arc terranes. The tilt derivative transform highlights lineaments within the back arc that may represent zones with potential for VMS deposits. The truncations of tilt derivative lineaments outline a major magnetic domain boundary between the back-arc and craton margin, which is prospective for granitoid Sn-W deposits. Annular tilt derivative highs outline granitoids that could be associated with intrusion-related Au deposits within the craton margin. Shallow, magnetite-rich Alaska-type ultramafic-mafic complexes are mapped by their short-wavelength, high-amplitude anomalies. Successful mineral potential mapping across southwestern Alaska as performed in the present study suggests that filtered aeromagnetic data can be effectively used in mineral exploration in convergent continental margin settings.

Alaska↗

USGS1984

Origins and exploration significance of replacement and vein-type alunite deposits in the Marysvale volcanic field, west central Utah

Alunite deposits formed 23 m.y. ago in near-surface, highly oxidizing conditions at the tops of hydrothermal plumes that were spaced at 3- to 4-km intervals around a monzonite stock. The delta 34 S values of 11.5 to 15.4 per mil for replacement alunite along with geologic constraints indicate that sulfate sulfur was derived from underlying Mesozoic evaporites. The delta 34 S values of -15.3 to +5.1 per mil of underlying pyrite, however, indicate that reduced sulfur, necessary to produce low pH during oxidation, either was produced by partial reduction of the evaporite sulfate or came from another source. Vein-type alunite deposits formed 14 m.y. ago as open-space fillings in extension fractures above a concealed stock. Crystals of alunite grew inward from the walls, forming veins of nearly pure alunite as much as 20 m thick. The delta 34 S values near zero per mil indicate that the vein-type alunite sulfur probably had a magmatic source, and it appears that the sulfur may have been present as SO 2 shortly after degassing from the magma. The probable magmatic origin for sulfur in the 14-m.y.-old vein-type alunite and its deposition from vapor-rich fluids, as well as the probable magmatic origin for sulfur in the surrounding base and precious metal deposits, suggest that the underlying stock may host porphyry-type deposits.

Economic Geology↗

USGS2025

Aeromagnetic and magnetotelluric imaging of west-central Idaho and the Stibnite-Yellow Pine mining district: A regional to district perspective

Aeromagnetic and magnetotelluric (MT) data are used to better understand the geology and mineral resources near the Stibnite-Yellow Pine mining district in central Idaho. The reduced-to-pole (RTP) transformation of regional-scale aeromagnetic data shows that allochthonous island-arc rocks west of the Salmon River suture are significantly more magnetic than the Laurentian continental rocks east of the suture and that the granitoids of the Idaho batholith have moderate to low magnetization in both early, metaluminous, and late, peraluminous phases. Application of tilt derivative to aeromagnetic data highlights major crustal-scale structures. The 5-km upward continued magnetic data indicate island-arc rocks have deep magnetic sources. The 110-km-long MT profile images resistivity structure to depths around 30 km. At shallow depths, resistivity corresponds to mapped geologic units, with moderate resistivities underlying volcanic and roof-pendant metasedimentary rocks and moderate to high resistivities occurring beneath the Idaho batholith. Crustal-scale moderate resistivities beneath the suture image the results of tectonomagmatic processes that accompanied suturing and translating allochthonous terranes. Low resistivity values beneath and fringing the batholith are derived from metasedimentary rocks that may have served as a melt source and reductant during melt generation and provided metals during later ore formation. In the Stibnite-Yellow Pine mining district, a high-resolution aeromagnetic compilation is shown to correlate with mapped lithologies and mineral deposit-related structures. The RTP transform distinguishes magnetic and nonmagnetic granitoid phases of the Idaho batholith. The tilt derivative highlights metasedimentary rocks, some of which are favorable ore hosts. The Meadow Creek fault hosts the Stibnite and Hangar Flats deposits and is imaged as a magnetic low due to hydrothermal alteration. Reconstructions of magnetic anomaly offsets and orebodies indicate around 3 km of post-95 Ma dextral separation, with some or all of the offset inferred to postdate the main Au mineralization episode (61–66 Ma).

Idaho↗

USGS1964

Origin of precambrian iron formations

A statistical study of the chemical composition of the Precambrian iron formations of the Canadian Shield affords a new approach to the origin of these unusual formations . The average total iron content of 2,200 samples from the literature and from unpublished mining company analyses is 26.7 percent Fe. The average Fe content for 16 iron formations in the United States and Canada ranges from 24.5 to 34.1 percent. Low contents of A1203, Ti02, P2O5, and CaO characterize the Precambrian iron formations compared to the relatively large amounts of these constituents in the post- Precambrian iron -bearing sediments. The chemical data emphasize that whereas iron , manganese, and silica were transported and deposited together in the cherty iron formations of the Precambrian , these same elements were chemically differentiated in younger geological time in large but separate deposits of iron and silica. Isotopic age determinations indicate that cherty iron formations were deposited during a long interval of geologic time from approximately 1,700 to 3,000 million years ago. A model is proposed to explain the origin of the iron formations of the Lake Superior type based on the absence or marked deficiency of free oxygen in the atmosphere prior to the Late Precambrian . Lateritic weathering under these conditions permitted the transport of iron and manganese together with silica. The weathered mantle effectively retained aluminum, titanium, phosphorus, and colloidal clay. Graphitic material of biogenic origin is closely associated with the Precambrian iron formations . Although it is uncertain whether iron was precipitated directly through biologic processes, the removal of C02 and the liberation of oxygen to the sea water through photosynthesis of primitive plants undoubtedly influenced the energy relationships among the iron minerals. As a result of the variable conditions the iron formations commonly are characterized by nonequilibrium mineral assemblages. In Late Precambrian time a critical level of free oxygen in the atmosphere was attained permitting a marked acceleration in plant growth and in accretion of oxygen. This stage in the development of an oxygenated atmosphere was reached at least 1,200 million years ago and effectively curtailed the development of cherty iron formations of the Lake Superior type.

Economic Geology↗

USGS1957

Reflecting curved-crystal X-ray spectrograph; a device for the analysis of small mineral samples

A curved-crystal reflecting spectrometer of the type described by Birks and Brooks of the Naval Research Laboratories, but adapted for use in mineralogical studies, has been built in the Geological Survey. It has been successfully applied to the analysis of tiny crystals, zones in minerals, and individual grains in mixed-mineral specimens such as thin or polished sections, on grains or areas about 0.5 mm in diameter, X-ray diffraction spindles, and small samples of powder weighing a fraction of a milligram have also been analyzed without any loss or alteration of the sample. Of great value in thin- and polished-section work is the fact that this technique can be used to analyze selected areas without mutilating the specimen by digging out grains.A modification of the curved-crystal spectrometer has made it possible to traverse a standard polished section in synchronization with a recorder, automatically plotting the distribution of various elements along a selected line. This method was applied, for example, to a polished section containing a central core of pyrite intergrown with and surrounded by a marcasite-like mineral. Chemical analysis of a concentrate of these two minerals gave selenium, cobalt, and iron as major constituents. A clear relationship between the cobalt, selenium, and iron was established by the X-ray method, identifying the second mineral as an intermediate member of the FeSe 2 -CoSe 2 series.

Economic Geology↗

USGS1996

Mg- and K-bearing borates and associated evaporites at Eagle Borax spring, Death Valley, California: A spectroscopic exploration

Efflorescent crusts at the Eagle Borax spring in Death Valley, California, contain an array of rare Mg and K borate minerals, several of which are only known from one or two other localities. The Mg- and/or K-bearing borates include aristarainite, hydroboracite, kaliborite, mcallisterite, pinnoite, rivadavite, and santite. Ulexite and probertite also occur in the area, although their distribution is different from that of the Mg and K borates. Other evaporite minerals in the spring vicinity include halite, thenardite, eugsterite, gypsum-anhydrite, hexahydrite, and bloedite. Whereas the first five of these minerals are found throughout Death Valley, the last two Mg sulfates are more restricted in occurrence and are indicative of Mg-enriched ground water.Mineral associations observed at the Eagle Borax spring, and at many other borate deposits worldwide, can be explained by the chemical fractionation of borate-precipitating waters during the course of evaporative concentration. The Mg sulfate and Mg borate minerals in the Eagle Borax efflorescent crusts point to the fractionation of Ca by the operation of a chemical divide involving Ca carbonate and Na-Ca borate precipitation in the subsurface sediments. At many other borate mining localities, the occurrence of ulexite in both Na borate (borax-kernite) and Ca borate (ulexite-colemanite) deposits similarly reflects ulexite's coprecipitation with Ca carbonate at an early concentration stage. Such ulexite may perhaps be converted to colemanite by later reaction with the coexisting Ca carbonate--the latter providing the additional Ca (super 2+) ions needed for the conversion. Mg and Ca-Mg borates are the expected late-stage concentration products of waters forming ulexite-colemanite deposits and are therefore most likely to occur in the marginal zones or nearby mud facies of ulexite-colemanite orebodies. Under some circumstances, Mg and Ca-Mg borates might provide a useful prospecting guide for ulexite-colemanite deposits, although the high solubility of Mg borate minerals may prevent their formation in lacustrine settings and certainly inhibits their geologic preservation. The occurrence of Mg borates in borax-kernite deposits is also related to fractionation processes and points to the operation of an Mg borate chemical divide, characterized by Mg borate precipitation ahead of Mg carbonate. All of these considerations imply that Mg is a significant chemical component of many borate-depositing ground waters, even though Mg borate minerals may not be strongly evident in borate orebodies.The Eagle Borax spring borates and other evaporite minerals were studied using spectroscopic and X-ray powder diffraction methods, which were found to be highly complementary. Spectral reflectance measurements provide a sensitive means for detecting borates present in mixtures with other evaporites and can be used to screen samples rapidly for X-ray diffraction analysis. The apparently limited occurrence of Mg and K borate minerals compared to Ca and Na borates may stem partly from the inefficiency of X-ray diffraction methods for delineating the mineralogy of large and complex deposits. Spectral reflectance measurements can be made in the laboratory, in the field, on the mine face, and even remotely. Reflectance data should have an important role in studies of existing deposit mineralogy and related chemical fractionation processes, and perhaps in the discovery of new borate mineral resources.

Economic Geology↗

USGS2010

Geochemical evolution of a high arsenic, alkaline pit-lake in the Mother Lode Gold District, California

The Harvard orebody at the Jamestown gold mine, located along the Melones fault zone in the southern Mother Lode gold district, California, was mined in an open-pit operation from 1987 to 1994. Dewatering during mining produced a hydrologic cone of depression; recovery toward the premining ground-water configuration produced a monomictic pit lake with alkaline Ca-Mg-HCO 3 -SO 4 –type pit water, concentrations of As up to 1,200 μ g/L, and total dissolved solids (TDS) up to 2,000 mg/L. In this study, pit-wall rocks were mapped and chemically analyzed to provide a context for evaluating observed variability in the composition of the pit-lake waters in relationship to seasonal weather patterns. An integrated hydrogeochemical model of pit-lake evolution based on observations of pit-lake volume, water composition (samples collected between 1998–2000, 2004), and processes occurring on pit walls was developed in three stages using the computer code PHREEQC. Stage 1 takes account of seasonally variable water fluxes from precipitation, evaporation, springs, and ground water, as well as lake stratification and mixing processes. Stage 2 adds CO 2 fluxes and wall-rock interactions, and stage 3 assesses the predictive capability of the model. Two major geologic units in fault contact comprise the pit walls. The hanging wall is composed of interlayered slate, metavolcanic and metavolcaniclastic rocks, and schists; the footwall rocks are chlorite-actinolite and talc-tremolite schists generated by metasomatism of greenschist-facies mafic and ultramafic igneous rocks. Alteration in the ore zone provides evidence for mineralizing fluids that introduced CO 2 , S, and K 2 O, and redistributed SiO 2 . Arsenian pyrite associated with the alteration weathers to produce goethite and jarosite on pit walls and in joints, as well as copiapite and hexahydrite efflorescences that accumulate on wall-rock faces during dry California summers. All of these pyrite weathering products incorporate arsenic at concentrations from <100 up to 1,200 ppm. In the pit lake, pH and TDS reach seasonal highs in the summer epilimnion; pH is lowest in the summer hypolimnion. Arsenic and bicarbonate covary in the hypolimnion, rising as stratification proceeds and declining during winter rains. The computational model suggests that water fluxes alone do not account for this seasonal variability. Loss of CO 2 to the atmosphere, interaction with pit walls including washoff of efflorescent salts during the first flush and seasonal rainfall, and arsenic sorption appear to contribute to the observed pit-lake characteristics.

California↗

USGS2018

Application of imaging spectroscopy for mineral exploration in Alaska: A study over porphyry Cu deposits in the eastern Alaska Range

The U.S. Geological Survey tested the utility of imaging spectroscopy (also referred to as hyperspectral remote sensing) as an aid to regional mineral exploration efforts in remote parts of Alaska. Airborne imaging spectrometer data were collected in 2014 over unmined porphyry Cu deposits in the eastern Alaska Range using the HyMap™ sensor. Maps of the distributions of predominant minerals, made by matching reflectance signatures in the remotely sensed data to reference spectra in the shortwave infrared region, do not uniquely discriminate individual rock units. However, they do highlight hydrothermal alteration associated with porphyry deposits and prospects hosted mostly within the Nabesna pluton. In and around porphyry Cu deposits at Orange Hill and Bond Creek, unique spectral signatures are related to variations in chlorite and white mica abundance and their chemical composition. This is best revealed in the longer-wavelength 2,200-nm Al-OH absorption feature positions in pixels spectrally dominated by white mica proximal to porphyry deposits. Similar spectral signatures of chlorite and white mica wavelength positions were also recognized away from the porphyry deposits; follow-up sampling identified these satellite areas to also contain Cu-Mo-Au mineralized rock. Our study confirms that airborne imaging spectroscopy has application for regional mineral exploration in exposed mountainous terrain in Alaska.

Alaska↗

USGS1977

Epithermal beryllium deposits in water-laid tuff, western Utah

Epithermal beryllium deposits in western Utah have distinctive geological and geochemical associations that provide guides to exploration for new resources of beryllium and associated metals. Beryllium deposits at Spor Mountain and the Honeycomb Hills are uniquely associated with topaz-bearing rhyolite of Late Tertiary age and are restricted to porous water-laid tuff and breccia that contains carbonate clasts. The beryllium deposits are near both local and regional faults that probably provided conduits for mineralizing fluids.The beryllium deposits contain sizable but uneconomic concentrations of fluorite, lithium (in smectite), manganese oxides, zinc (in smectite and manganese oxides), and uranium, as well as many trace elements. Distinctive zones of argillic and feldspathic alteration enclose the beryllium deposits and generally are parallel to the original stratification of the host tuff. Anomalous concentrations of fluorine, beryllium, cesium, lithium, gallium, niobium, and yttrium occur in relatively unmineralized tuff nearby; these elements form extensive but discontinuous halos around the Spor Mountain beryllium and fluorspar district.The mineralized areas at Spor Mountain and the Honeycomb Hills may be the tops of extensive altered zones that contain deep ore deposits. Anomalous molybdenum, lead, tin, and tungsten in beryllium deposits at Spor Mountain may indicate such leakage. Consideration of possible zonation of ore deposits suggests that if ore deposits do exist at depth, they are in greisens, banded tactites, and medium to high temperature veins similar to the tin-beryllium deposits in the York Mountains of Alaska.

Utah↗

USGS1963

Studies of fluid inclusions; [Part] 2, Freezing data and their interpretation

Aqueous and non-aqueous inclusions in 84 samples of various minerals from a wide range of geologic environments were studied with the freezing stage in order to gain an insight into the range of concentrations and compositions of fluid inclusions . Inclusions in most Mississippi Valley-type ore minerals contain highly concentrated saline solutions, showing freezing temperatures between -23.4° and -10.5° C; minerals from ore deposits of more typically hydrothermal affiliations mainly show temperatures of -9.4° to nearly 0° C; and inclusions in quartz crystals from sedimentary, metamorphic, and igneous rock environments show a wide range of freezing temperatures. Inclusions in pegmatite minerals in particular vary over a wide range, from the most concentrated solutions found in any inclusion (> 40% salts) to fairly dilute solutions (< 5% salts). Most inclusions in quartz from Swiss Alpine-type veins, and from Brazilian quartz veins and pegmatites, show freezing temperatures in the range -8.5° to - 2 .5°, and considerable free C02. Other geologic environments sampled include Colombian emerald, pegmatitic topaz and fluorite, the Triassic traprock zeolite assemblage, and sedimentary halite beds. Not all the phenomena exhibited by inclusions at low temperature are completely understood at present but several crystalline hydrate phases, such as NaCl-2H,0 and CO,-5%H,0 (structural formula 8C02-46H20), are shown to be stable in inclusions of appropriate composition even at temperatures above 0° C, and probably exist in the inclusions in natural rocks in polar regions. More significantly, the formation and recognition of such phases aid in establishing the gross composition of individual inclusions far too small for chemical analysis. The data obtained are useful in a variety of ways, such as: discriminating among gas, liquid, and supercritical fluid , and among liquid water, liquid oil, and liquid C02 in inclusions ; improving precision of the pressure corrections applied to inclusion filling temperature determinations; proving the general lack of leakage into or out of inclusions ; estimating the minimum pressure at the time of deposition of certain samples; verifying the lack of extraneous solid crystallization nuclei in the inclusions and hence their formation from exceedingly quiet, clean solutions; determining the total equivalent NaCl concentrations and some information concerning the composition of the fluids from which ores have formed; and determining changes in the composition of the fluids bathing a single crystal during its growth, and at certain times throughout its history.

Economic Geology↗

USGS2016

Regional geologic and petrologic framework for iron oxide ± apatite ± rare earth element and iron oxide copper-gold deposits of the Mesoproterozoic St. Francois Mountains terrane, southeast Missouri, USA

This paper provides an overview on the genesis of Mesoproterozoic igneous rocks and associated iron oxide ± apatite (IOA) ± rare earth element, iron oxide-copper-gold (IOCG), and iron-rich sedimentary deposits in the St. Francois Mountains terrane of southeast Missouri, USA. The St. Francois Mountains terrane lies along the southeastern margin of Laurentia as part of the eastern granite-rhyolite province. The province formed during two major pulses of igneous activity: (1) an older early Mesoproterozoic (ca. 1.50–1.44 Ga) episode of volcanism and granite plutonism, and (2) a younger middle Mesoproterozoic (ca. 1.33–1.30 Ga) episode of bimodal gabbro and granite plutonism. The volcanic rocks are predominantly high-silica rhyolite pyroclastic flows, volcanogenic breccias, and associated volcanogenic sediments with lesser amounts of basaltic to andesitic volcanic and associated subvolcanic intrusive rocks. The iron oxide deposits are all hosted in the early Mesoproterozoic volcanic and volcaniclastic sequences. Previous studies have characterized the St. Francois Mountains terrane as a classic, A-type within-plate granitic terrane. However, our new whole-rock geochemical data indicate that the felsic volcanic rocks are effusive derivatives from multicomponent source types, having compositional similarities to A-type within-plate granites as well as to S- and I-type granites generated in an arc setting. In addition, the volcanic-hosted IOA and IOCG deposits occur within bimodal volcanic sequences, some of which have volcanic arc geochemical affinities, suggesting an extensional tectonic setting during volcanism prior to emplacement of the ore-forming systems.

Missouri↗

USGS2004

A geologic framework for mineralization in the western Brooks Range

The Brooks Range is a 950-km-long north-vergent fold and thrust belt, which was formed during Mesozoic convergence of the continental Arctic Alaska terrane and the oceanic Angayucham terrane and was further shortened and uplifted in Tertiary time. The Arctic Alaska terrane consists of parautochthonous rocks and the Endicott Mountains and De Long Mountains subterranes. The Endicott Mountains allochthon of the western Brooks Range is the setting for many sulfide and barite occurrences, such as the supergiant Red Dog zinc-lead mine. Mineralization is sediment hosted and most commonly is present in black shale and carbonate turbidites of the Mississippian Kuna Formation. The reconstructed Kuna basin is a 200 by +600 km feature that represents the culmination of a remarkable chain of events that includes three fluvial-deltaic and two or more orogenic cycles, Middle Devonian to Mississippian episodes of extension and igneous activity, and the emergence of a seaward Lower Proterozoic landmass that may have constituted a barrier to marine circulation. Mississippian extension and related horst-and-graben architecture in the western Brooks Range is manifested in part by strong facies variability between coeval units of allochthons and structural plates. Shallow marine to possibly nonmarine arkose, platform to shelf carbonate, slope-to-basin shale, chert and carbonate turbidites, and submarine volcanic rocks are all represented in Mississippian time. The structural setting of Mississippian sedimentation, volcanism, and mineralization in the Kuna basin may be comparable to documented Devono-Mississippian extensional sags or half-grabens in the subsurface north of the Brooks Range. Climate, terrestrial ecosystems, multiple fluvial-deltaic aquifers, and structural architecture affected the liberation, movement, and redeposition of metals in ways that are incompletely understood.

Alaska↗

USGS1957

Eastern and central Montana as a possible source area of uranium

Geologic settings in central and eastern Montana and in a few places in southwestern Montana are similar to the settings in areas favorable for the occurrence of uranium deposits. Several areas in Montana seem especially favorable for the occurrence of uranium.The alkalic igneous rock province of central Montana is similar to the one of the Colorado Plateau. On the basis of this analogy, certain areas in Montana, where the lithology and (or) structure are considered favorable for the occurrence of uranium, are suggested for prospecting. Seleniferous plants, similar to those that are uranium indicators on the Colorado Plateau, might be used as an aid in prospecting for uranium provided that the seleniferous shale areas are taken into account.Uranium deposits, similar to those in North and South Dakota, may be found in Cretaceous and Tertiary sandstones, lignites, and low-grade coals of eastern Montana; also, the magnetite-bearing beds of certain Cretaceoussandstones may contain fossil placer deposits of radioactive black minerals. Theoccurrence of uranium in basal conglomerates, quartzites, and sandstones in Africa and Ontario suggests that similar basal sedimentary rocks in central Montana may contain uranium.Many of the radioactivity anomalies in Montana found from the air are closely associated with the Eagle sandstone; others are associated with Precambrian basement rocks, Upper Cretaceous and Lower Tertiary igneous rocks, or sedimentary rocks of Jurassic and Cretaceous age. Glacial cover and lack of outcrops locally may hinder prospecting for uranium.

Montana↗

USGS2012

Geologic setting, sedimentary architecture, and paragenesis of the Mesoproterozoic sediment-hosted Sheep Creek Cu-Co-Ag deposit, Helena embayment, Montana

The northern margin of the Helena Embayment contains extensive syngenetic to diagenetic massive pyrite horizons that extend over 25 km along the Volcano Valley-Buttress fault zone and extend up to 8 km basinward (south) within the Mesoproterozoic Newland Formation. The Sheep Creek Cu-Co deposit occurs within a structural block along a bend in the fault system, where replacement-style chalcopyrite mineralization is spatially associated mostly with the two stratigraphically lowest massive pyrite zones. These mineralized pyritic horizons are intercalated with debris flows derived from synsedimentary movement along the Volcano Valley-Buttress fault zone. Cominco American Inc. delineated a geologic resource of 4.5 Mt at 2.5% Cu and 0.1% Co in the upper sulfide zone and 4 Mt at 4% Cu within the lower sulfide zone. More recently, Tintina Resources Inc. has delineated an inferred resource of 8.48 Mt at 2.96% Cu, 0.12% Co, and 16.4 g/t Ag in the upper sulfide zone. The more intact upper sulfide zone displays significant thickness variations along strike thought to represent formation in at least three separate subbasins. The largest accumulation of mineralized sulfide in the upper zone occurs as an N-S–trending body that thickens southward from the generally E trending Volcano Valley Fault and probably occupies a paleograben controlled by normal faults in the hanging wall of the Volcano Valley Fault. Early microcrystalline to framboidal pyrite was accompanied by abundant and local barite deposition in the upper and lower sulfide zones, respectively. The sulfide bodies underwent intense (lower sulfide zone) to localized (upper sulfide zone) recrystallization and overprinting by coarser-grained pyrite and minor marcasite that is intergrown with and replaces dolomite. Silicification and paragenetically late chalcopyrite, along with minor tennantite in the upper sulfide zone, replaces fine-grained pyrite, barite, and carbonate. The restriction of chalcopyrite to inferred synsedimentary E- and northerly trending faults and absence of definitive zonation with respect to the Laramide Volcano Valley Fault in the lower sulfide zone suggest a diagenetic age related to basin development for the Sheep Creek Cu-Co-Ag deposit.

Montana↗