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At least 433 records · Page 24Linked to original sources
USGS2013

Chemistry and age of groundwater in bedrock aquifers of the Piceance and Yellow Creek watersheds, Rio Blanco County, Colorado, 2010-12

Fourteen monitoring wells completed in the Uinta and Green River Formations in the Piceance Creek and Yellow Creek watersheds in Rio Blanco County, Colorado, were sampled for chemical, isotopic, and groundwater-age tracers to provide information on the overall groundwater quality, the occurrence and distribution of chemicals that could be related to the development of underlying natural-gas reservoirs, and to better understand groundwater residence times in the flow system. Methane concentrations in groundwater ranged from less than 0.0005 to 387 milligrams per liter. The methane was predominantly biogenic in origin, although the biogenic methane was mixed with thermogenic methane in water from seven wells. Three BTEX compounds (benzene, toluene, and ethylbenzene) were detected in water from six of the wells, but none of the concentrations exceeded Federal drinking-water standards. The presence of thermogenic methane in the aquifers indicates a connection and vulnerability to chemicals in deeper geologic units. Helium-4 data indicate that groundwater had ages ranging from less than 1,000 years to greater than 50,000 years. The presence of old groundwater in parts of the aquifers indicates that these aquifers may not be useful for large-scale water supply because of low recharge rates.

Colorado↗
USGS2003

Hydrogeology and Ground-Water Quality of Brunswick County, North Carolina

Brunswick County is the southernmost coastal county in North Carolina and lies in the southeastern part of the Coastal Plain physiographic province. In this report, geologic, hydrologic, and chemical data were used to investigate and delineate the hydrogeologic framework and ground-water quality of Brunswick County. The major aquifers and their associated confining units delineated in the Brunswick County study area include, from youngest to oldest, the surficial, Castle Hayne, Peedee, Black Creek, upper Cape Fear, and lower Cape Fear aquifers. All of these aquifers, with the exception of the Castle Hayne aquifer, are located throughout Brunswick County. The Castle Hayne aquifer extends across only the southeastern part of the county. Based on available data, the Castle Hayne and Peedee confining units are missing in some areas of Brunswick County, which allows direct hydraulic contact between the surficial aquifer and underlying Castle Hayne or Peedee aquifers. The confining units for the Black Creek, upper Cape Fear, and lower Cape Fear aquifers appear to be continuous throughout Brunswick County. In examining the conceptual hydrologic system for Brunswick County, a generalized water budget was developed to better understand the natural processes, including precipitation, evapotranspiration, and stream runoff, that influence ground-water recharge to the shallow aquifer system in the county. In the generalized water budget, an estimated 11 inches per year of the average annual precipitation of 55 inches per year in Brunswick County is estimated to infiltrate and recharge the shallow aquifer system. Of the 11 inches per year that recharges the shallow system, about 1 inch per year is estimated to recharge the deeper aquifer system. The surficial aquifer in Brunswick County is an important source of water for domestic supply and irrigation. The Castle Hayne aquifer is the most productive aquifer and serves as the principal ground-water source of municipal supply for the county. The upper part of the Peedee aquifer is an important source of ground-water supply for domestic and commercial use. Ground water in the lower part of the Peedee aquifer and the underlying aquifers is brackish and is not known to be used as a source of supply in Brunswick County. Most of the precipitation that recharges the surficial aquifer is discharged to local streams that drain into the Waccamaw River, Cape Fear River, and Atlantic Ocean. Recharge to the Castle Hayne aquifer occurs primarily from the surficial aquifer. Recharge to the Peedee aquifer occurs primarily from the surficial and Castle Hayne aquifers, with some upward leakage of water also occurring from the underlying Black Creek aquifer. Discharge from the Castle Hayne and Peedee aquifers occurs to local streams, the Cape Fear River, and the Atlantic Ocean. Evaluation of water-level data for the period January 1970 through May 2002 indicated no apparent long-term temporal trends in water levels in the surficial and Castle Hayne aquifers and in the upper part of the Peedee aquifer. The most significant water-level trends were noted for wells tapping the lower part of the Peedee aquifer and tapping the Black Creek aquifer where water levels have declined as much as 41 and 37 feet, respectively. These ground-water-level declines are attributed to regional ground-water pumping in areas outside of Brunswick County. Water-level data for Brunswick County wells tapping the upper Cape Fear and lower Cape Fear aquifers tend to fluctuate within a fairly uniform range with no apparent temporal trend noted. Analysis of vertical hydraulic gradients during this same period primarily indicate downward flow of ground water within and among the surficial, Castle Hayne, and Peedee aquifers. The vertical flow of ground water in the Black Creek aquifer is upward into the overlying Peedee aquifer. Upward flow also is noted for the upper and lower Cape Fear aquifers. Historic and recent analytic data were evaluated to better understand the sources of water contained in Brunswick County aquifers and the suitability of the water for consumption. Based on analytical results obtained for recent samples collected during this study, ground water from the surficial aquifer, Castle Hayne aquifer, and upper part of the Peedee aquifer appears to be generally suitable for drinking water. Although concentrations of iron and manganese commonly exceeded the drinking-water standards, the concern generally associated with the occurrence of these analytes in a water supply is one of aesthetics. In all samples, nitrate, nitrite, and sulfate were detected at concentrations less than drinkingwater standards. Based on historic analytical data, the brackish water in the lower part of the Peedee aquifer and in the Black Creek, upper Cape Fear, and lower Cape Fear aquifers is classified as a sodium-chloride type water. The presence of brackish water in these deeper systems combined with upward vertical gradients presents the potential for upward migration of brackish water into overlying aquifers, or upconing beneath areas of pumping. The current (2001) location of the boundary between freshwater and brackish water in Brunswick County aquifers is unknown.

North Carolina↗
USGS1984

A reconnaissance study of saltwater contamination in the El Dorado aquifer, Union County, Arkansas

Since 1960 chloride concentrations in the El Dorado aquifer have increased near El Dorado, Arkansas. The aquifer is a major source for municipal and industrial water supply in Union County. Greatest withdrawal occurs near El Dorado. Because of this withdrawal, the potentiometric surface at El Dorado has been lowered more than 300 feet. Geologic, hydrologic, and chemical data indicate that water from a graben south and east of El Dorado is the source of contamination from salt within the El Dorado aquifer. The data indicates that surface brines and deeper aquifers are not the sources of chloride contamination. Lowering the potentiometric surface near El Dorado has caused water to move out of the graben toward El Dorado. Estimates based on interpretation of electric logs for two wells in the graben indicate chloride equivalents may be as high as 2,500 milligrams per liter in the aquifer. Concentrations outside the graben range from 130 to 650 milligrams per liter at the west end of the graben and from 25 to 150 milligrams per liter farther west and north. (USGS)

Water-Resources Investigations Report↗
USGS1980

Bibliography of U.S. Geological Survey water-resources reports for Utah

This bibliography contains a complete listing to June 30, 1980, of reports relating to the water resources of Utah prepared by personnel of the U.S. Geological Survey. Discussions of the related subjects of geology, hydrology, and chemical quality of the water are included in many of the reports. The reports were, for the most part, prepared by personnel assigned to the Water Resources Division, Utah District, in cooperation with State and local agencies.

Utah↗
USGS1966

Bibliography of U.S. Geological Survey water-resources reports for Utah

This bibliography contains a complete listing to December 1966 of reports relating to the water resources of Utah prepared by personnel of the U.S. Geological Survey. Discussions of the related subjects of geology, hydrology, and chemical quality of the water are included in many of the reports. The reports were, for the most part, prepared by personnel assigned to the Water Resources Division, Utah District, in cooperation with State and local agencies.

Utah↗
USGS1975

Bibliography of U.S. Geological Survey water-resources reports for Utah

This bibliography contains a complete listing to December 31, 1974, of reports relating to the water resources of Utah prepared by personnel of the U.S. Geological Survey. Discussions of the related subjects of geology, hydrology, and chemical quality of the water are included in many of the reports. The reports were, for the most part, prepared by personnel assigned to the Water Resources Division, Utah District, in cooperation with State and local agencies.

Utah↗
USGS1972

Bibliography of U.S. Geological Survey water-resources reports for Utah

This bibliography contains a complete listing to December 31, 1971, of reports relating to the water resources of Utah prepared by personnel of the U.S. Geological Survey. Discussions of the related subjects of geology, hydrology, and chemical quality of the water are included in many of the reports. The reports were, for the most part, prepared by personnel assigned to the Water Resources Division, Utah District, in cooperation with State and local agencies.

Utah↗
USGS2001

Mars Global Surveyor Thermal Emission Spectrometer experiment: Investigation description and surface science results

The Thermal Emission Spectrometer (TES) investigation on Mars Global Surveyor (MGS) is aimed at determining (1) the composition of surface minerals, rocks, and ices; (2) the temperature and dynamics of the atmosphere; (3) the properties of the atmospheric aerosols and clouds; (4) the nature of the polar regions; and (5) the thermophysical properties of the surface materials. These objectives are met using an infrared (5.8- to 50-μm) interferometric spectrometer, along with broadband thermal (5.1- to 150-μm) and visible/near-IR (0.3- to 2.9-μm) radiometers. The MGS TES instrument weighs 14.47 kg, consumes 10.6 W when operating, and is 23.6×35.5×40.0 cm in size. The TES data are calibrated to a 1-σ precision of 2.5 −6 ×10 −8 W cm −2 sr −1 /cm −1 , 1.6×10 −6 W cm −2 sr −1 , and ∼0.5 K in the spectrometer, visible/near-IR bolometer, and IR bolometer, respectively. These instrument subsections are calibrated to an absolute accuracy of ∼4×10 −8 W cm −2 sr −1 /cm −1 (0.5 K at 280 K), 1–2%, and ∼1–2 K, respectively. Global mapping of surface mineralogy at a spatial resolution of 3 km has shown the following: (1) The mineralogic composition of dark regions varies from basaltic, primarily plagioclase feldspar and clinopyroxene, in the ancient, southern highlands to andesitic, dominated by plagioclase feldspar and volcanic glass, in the younger northern plains. (2) Aqueous mineralization has produced gray, crystalline hematite in limited regions under ambient or hydrothermal conditions; these deposits are interpreted to be in-place sedimentary rock formations and indicate that liquid water was stable near the surface for a long period of time. (3) There is no evidence for large-scale (tens of kilometers) occurrences of moderate-grained (>50-μm) carbonates exposed at the surface at a detection limit of ∼10%. (4) Unweathered volcanic minerals dominate the spectral properties of dark regions, and weathering products, such as clays, have not been observed anywhere above a detection limit of ∼10%; this lack of evidence for chemical weathering indicates a geologic history dominated by a cold, dry climate in which mechanical, rather than chemical, weathering was the significant form of erosion and sediment production. (5) There is no conclusive evidence for sulfate minerals at a detection limit of ∼15%. The polar region has been studied with the following major conclusions: (1) Condensed CO 2 has three distinct end-members, from fine-grained crystals to slab ice. (2) The growth and retreat of the polar caps observed by MGS is virtually the same as observed by Viking 12 Martian years ago. (3) Unique regions have been identified that appear to differ primarily in the grain size of CO 2 ; one south polar region appears to remain as black slab CO 2 ice throughout its sublimation. (4) Regional atmospheric dust is common in localized and regional dust storms around the margin and interior of the southern cap. Analysis of the thermophysical properties of the surface shows that (1) the spatial pattern of albedo has changed since Viking observations, (2) a unique cluster of surface materials with intermediate inertia and albedo occurs that is distinct from the previously identified low-inertia/bright and high-inertia/dark surfaces, and (3) localized patches of high-inertia material have been found in topographic lows and may have been formed by a unique set of aeolian, fluvial, or erosional processes or may be exposed bedrock.

Journal of Geophysical Research E: Planets↗
USGS1967

Hydrologic and chemical data for wells, springs, and streams in Nevada, TPS. 1-21 N., and Rs. 41-57 E

Studies of published and unpublished geologic, hydrologic, and chemical-quality data for ground and surface water in central Nevada, Tps. 1 to 21 N. and Rs. 41 to 57 E., Mount Diablo base and meridian, reveal the following information: Rocks exposed in central Nevada are of sedimentary and igneous origin and range in age from Cambrian to Recent. Rocks of Paleozoic age generally are carbonate or clastic, and rocks of Mesozoic age generally are clastic and granitic. Rocks of Tertiary age principally are volcanic, and the valley fill of Quaternary age is alluvial-fan and lake deposits. The rocks are folded, faulted, and highly fractured. Precipitation is closely related to altitude. In general, as the altitude increases the precipitation increases. Most of the streamflow in the valleys originates as snow in the nearby mountains. The streams generally flow only in response to snowmelt and to flash-flood-producing storms. Important chemical quality characteristics of the ground and surface water in central Nevada are hardness, expressed as CaCO 3 , generally in excess of 120 ppm, and a dissolved-solids content of less than 500 ppm. The principal chemical types of both ground and surface waters are sodium and calcium bicarbonates. The major uses of ground water in central Nevada are for irrigation and stock. Frequency of use of wells in decreasing order is: irrigation, stock, domestic, industrial, municipal, and observation. Of the 606 wells tabulated, 29 have multiple uses. Frequency of use of spring water in decreasing order is: stock, irrigation, domestic, and public facilities. Of the 135 springs tabulated, 5 have multiple uses.

Nevada↗
USGS1983

Mechanical and chemical compaction in fine-grained shallow-water limestones

Artificial compaction of in-situ cores of sediments resulted in: 1) reduction of sediment thickness by 50 percent and more; 2) reduction of initial porosities of 65 to 75 percent to 35 to 45 percent; 3) creation of megascopic textures almost identical to many ancient lime mud- and wackestone; 4) creation of organic, wispy "stylolite-like" layers; 5) chemical compaction, evidenced by thin sections showing quartz grains piercing mollusc shells without causing fractures and SEM evidence of solutional interfitting of 1 to 4-mu m-size aragonitic carbonate grains; 6) obliteration of pellets and birdseye or fenestral voids in those sediments where early cementation was lacking; obliteration of identifiable marine grasses and vertical "root" tube voids; 8) mashing of sediment-filled circular burrows to produce ellipsoidal structures. Significant mechanical compaction resulted from pressures simulating less than 1,000 ft of burial. Increasing loads to more than 10,000 ft did not significantly increase compaction. Chemical compaction was detected only in cores compacted to pressures greater than 10,000 ft of burial. These experiments suggest that chemical compaction would begin at much shallower depths given geologic time. Experiments that caused chemical compaction lend support to the hypothesis that cement required to produce a low-porosity/low-permeability fine-grained limestone is derived internally. Dissolution, ion diffusion, and reprecipitation are the most likely processes for creating significant thicknesses of dense limestones. Continuation of chemical compaction after significant porosity reduction necessitates expulsion of connate fluids, possibly including hydrocarbons.--Modified journal abstract.

Journal of Sedimentary Petrology↗
USGS2023

Creating oriented and precisely sectioned mineral mounts for in situ chemical analyses—An example using olivine for diffusion chronometry studies

Diffusion chronometry is now a widely applied methodology for determining the rates and timescales of geologic processes from the chemical zoning observed in minerals. Despite the popularity of the method, several challenges still remain during its application, including: (1) the random sectioning of minerals either in thin sections or grain mounts in which both off-center and oblique sections contribute substantial uncertainty to modeled timescales and (2) diffusion anisotropy needs to be accounted for in models, which generally requires determining the principal crystallographic axes of the mineral using electron backscatter diffraction, a technique that is both challenging and limiting because few scanning electron microscopes have an electron backscatter detector. This guide developed by the U.S. Geological Survey focuses on a step-by-step methodology for mounting individually oriented minerals that are sectioned through their cores prior to polishing for analytical work. Using this technique, one can significantly reduce the uncertainties associated with off-center sections and minimize or completely remove the need for determining crystallographic orientation via electron backscatter diffraction analyses. This report is presented as a guide for using the technique on olivine crystals but can be applied to any minerals that can be extracted for analysis. Two variations of the methodology are included here: (1) The individual crystal method that entails mounting individually sectioned single crystals and crystal groups and (2) the whole mount method in which multiple single crystals or crystal clusters are mounted and sectioned at the same time.

Techniques and Methods↗
USGS1974

Water quality effects of seepage from earthen dams

Analyses of surface and seepage waters from selected floodwater retarding structures in west-central Oklahoma, U.S.A. show the salinity of seepage to be several times greater than that of the impounded waters. The increases in concentration of the several chemical components are not proportional. This phenomenon appears to be caused largely by simple solution, which is closely related to the chemical character of the geologic formation that provides the reservoir site and the earth fill of the dam. Concentration of certain chemical components in the seepage water progressively decreases as the structure ages. This is probably a function of depletion, which is related to the amounts and solubility of the parent materials subjected to solution. In contrast, the concentration of certain other components, such as iron and calcium, increases with time. The chemical activities within the accumulating mud on the bottom of the reservoir apparently cause these increases.

Oklahoma↗
USGS1979

Chemical analyses of coal from the Tongue River Member, Fort Union Formation, Decker coal deposit, Big Horn County, Montana

As part of a continuing cooperative program between the U. S. Geological Survey and the Montana Bureau of Mines and Geology to collect and chemically analyze representative samples of Montana coals, 50 coal and 2 carbonaceous shale samples were collected from the Anderson, Dietz 1 and Dietz 2 coal beds in the Paleocene Tongue River Member of the Fort Union Formation. These samples were collected at six locations in sections 9 and 15, T. 9 S., R. 40 E., section 26, T. 8 S., R. 39 E., and section 29, T. 9 S., R. 39 E., Big Horn County, Montana.

Montana↗
USGS2012

The Stanford-U.S. Geological Survey SHRIMP ion microprobe--a tool for micro-scale chemical and isotopic analysis

Answers to many questions in Earth science require chemical analysis of minute volumes of minerals, volcanic glass, or biological materials. Secondary Ion Mass Spectrometry (SIMS) is an extremely sensitive analytical method in which a 5–30 micrometer diameter "primary" beam of charged particles (ions) is focused on a region of a solid specimen to sputter secondary ions from 1–5 nanograms of the sample under high vacuum. The elemental abundances and isotopic ratios of these secondary ions are determined with a mass spectrometer. These results can be used for geochronology to determine the age of a region within a crystal thousands to billions of years old or to precisely measure trace abundances of chemical elements at concentrations as low as parts per billion. A partnership of the U.S. Geological Survey and the Stanford University School of Earth Sciences operates a large SIMS instrument, the Sensitive High-Resolution Ion Microprobe with Reverse Geometry (SHRIMP–RG) on the Stanford campus.

Fact Sheet↗
USGS2000

Europa's Crust and Ocean: Origin, Composition, and the Prospects for Life

We have considered a wide array of scenarios for Europa's chemical evolution in an attempt to explain the presence of ice and hydrated materials on its surface and to understand the physical and chemical nature of any ocean that may lie below. We postulate that, following formation of the jovian system, the europan evolutionary sequence has as its major links: (a) initial carbonaceous chondrite rock, (b) global primordial aqueous differentiation and formation of an impure primordial hydrous crust, (c) brine evolution and intracrustal differentiation, (d) degassing of Europa's mantle and gas venting, (e) hydrothermal processes, and (f) chemical surface alteration. Our models were developed in the context of constraints provided by Galileo imaging, near infrared reflectance spectroscopy, and gravity and magnetometer data. Low-temperature aqueous differentiation from a carbonaceous CI or CM chondrite precursor, without further chemical processing, would result in a crust/ocean enriched in magnesium sulfate and sodium sulfate, consistent with Galileo spectroscopy. Within the bounds of this simple model, a wide range of possible layered structures may result; the final state depends on the details of intracrustal differentiation. Devolatilization of the rocky mantle and hydrothermal brine reactions could have produced very different ocean/crust compositions, e.g., an ocean/crust of sodium carbonate or sulfuric acid, or a crust containing abundant clathrate hydrates. Realistic chemical-physical evolution scenarios differ greatly in detailed predictions, but they generally call for a highly impure and chemically layered crust. Some of these models could lead also to lateral chemical heterogeneities by diapiric upwellings and/or cryovolcanism. We describe some plausible geological consequences of the physical-chemical structures predicted from these scenarios. These predicted consequences and observed aspects of Europa's geology may serve as a basis for further analys is and discrimination among several alternative scenarios. Most chemical pathways could support viable ecosystems based on analogy with the metabolic and physiological versatility of terrestrial microorganisms. ?? 2000 Academic Press.

Icarus↗
USGS2013

Software for analysis of chemical mixtures--composition, occurrence, distribution, and possible toxicity

The composition, occurrence, distribution, and possible toxicity of chemical mixtures in the environment are research concerns of the U.S. Geological Survey and others. The presence of specific chemical mixtures may serve as indicators of natural phenomena or human-caused events. Chemical mixtures may also have ecological, industrial, geochemical, or toxicological effects. Chemical-mixture occurrences vary by analyte composition and concentration. Four related computer programs have been developed by the National Water-Quality Assessment Program of the U.S. Geological Survey for research of chemical-mixture compositions, occurrences, distributions, and possible toxicities. The compositions and occurrences are identified for the user-supplied data, and therefore the resultant counts are constrained by the user’s choices for the selection of chemicals, reporting limits for the analytical methods, spatial coverage, and time span for the data supplied. The distribution of chemical mixtures may be spatial, temporal, and (or) related to some other variable, such as chemical usage. Possible toxicities optionally are estimated from user-supplied benchmark data. The software for the analysis of chemical mixtures described in this report is designed to work with chemical-analysis data files retrieved from the U.S. Geological Survey National Water Information System but can also be used with appropriately formatted data from other sources. Installation and usage of the mixture software are documented. This mixture software was designed to function with minimal changes on a variety of computer-operating systems. To obtain the software described herein and other U.S. Geological Survey software, visit http://water.usgs.gov/software/.

Scientific Investigations Report↗