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At least 415 records · Page 23Linked to original sources
USGS2005

Streamflow trends in the Spokane River and tributaries, Spokane Valley/Rathdrum Prairie, Idaho and Washington

A clear understanding of the aquifer and river dynamics within the Spokane Valley/Rathdrum Prairie is essential in making proper management decisions concerning ground-water and surface-water appropriations. Management of the Spokane Valley/Rathdrum Prairie aquifer is complicated because of interstate, multi-jurisdictional responsibilities, and by the interaction between ground water and surface water. Kendall?s tau trend analyses were completed on monthly mean (July through December) and annual 7-day low streamflow data for the period 1968?2002 from gaging stations located within the Spokane Valley/Rathdrum Prairie. The analyses detected trends of decreasing monthly mean streamflow at the following gaging stations: Spokane River near Post Falls, Idaho (August and September); Spokane River at Spokane, Washington (September); and Little Spokane River at Dartford, Washington (September and October); and decreasing annual 7-day low streamflows at the following gaging stations: Spokane River near Post Falls, Idaho and Spokane River at Spokane, Washington. Limited analyses of lake-level, precipitation, tributary inflow, temperature, and water-use data provided little insight as to the reason for the decreasing trends in streamflow. A net gain in streamflow occurs between the gaging stations Spokane River near Post Falls, Idaho and Spokane River at Spokane, Washington. Significant streamflow losses occur between the gaging stations Spokane River near Post Falls, Idaho and Spokane River at Greenacres, Washington; most, if not all, of the gains occur downstream from the Greenacres gaging station. Trends of decreasing net streamflow gains in the Spokane River between the near Post Falls and at Spokane gaging stations were detected for the months of September, October, and November.

Scientific Investigations Report↗
USGS2005

Analysis of ground-water levels and associated trends in Yucca Flat, Nevada Test Site, Nye County, Nevada, 1951-2003

Almost 4,000 water-level measurements in 216 wells in the Yucca Flat area from 1951 to 2003 were quality assured and analyzed. An interpretative database was developed that describes water-level conditions for each water level measured in Yucca Flat. Multiple attributes were assigned to each water-level measurement in the database to describe the hydrologic conditions at the time of measurement. General quality, temporal variability, regional significance, and hydrologic conditions are attributed for each water-level measurement. The database also includes narratives that discuss the water-level history of each well. Water levels in 34 wells were analyzed for variability and for statistically significant trends. An attempt was made to identify the cause of many of the water-level fluctuations or trends. Potential causes include equilibration following well construction or development, pumping in the monitoring well, withdrawals from a nearby supply well, recharge from precipitation, earthquakes, underground nuclear tests, land subsidence, barometric pressure, and Earth tides. Some of the naturally occurring fluctuations in water levels may result from variations in recharge. The magnitude of the overall water-level change for these fluctuations generally is less than 2 feet. Long-term steady-state hydrographs for most of the wells open to carbonate rock have a very similar pattern. Carbonate-rock wells without the characteristic pattern are directly west of the Yucca and Topgallant faults in the southwestern part of Yucca Flat. Long-term steady-state hydrographs from wells open to volcanic tuffs or the Eleana confining unit have a distinctly different pattern from the general water-level pattern of the carbonate-rock aquifers. Anthropogenic water-level fluctuations were caused primarily by water withdrawals and nuclear testing. Nuclear tests affected water levels in many wells. Trends in these wells are attributed to test-cavity infilling or the effects of depressurization following nuclear testing. The magnitude of the overall water-level change for wells with anthropogenic trends can be large, ranging from several feet to hundreds of feet. Vertical water-level differences at 27 sites in Yucca Flat with multiple open intervals were compared. Large vertical differences were noted in volcanic rocks and in boreholes where water levels were affected by nuclear tests. Small vertical differences were noted within the carbonate-rock and valley-fill aquifers. Vertical hydraulic gradients generally are downward in volcanic rocks and from pre-Tertiary clastic rocks toward volcanic- or carbonate-rock units.

Scientific Investigations Report↗
USGS2008

Occurrence, Distribution, Sources, and Trends of Elevated Chloride Concentrations in the Mississippi River Valley Alluvial Aquifer in Southeastern Arkansas

Water-quality data from approximately 2,500 sites were used to investigate the distribution of chloride concentrations in the Mississippi River Valley alluvial aquifer in southeastern Arkansas. The large volume and areal distribution of the data used for the investigation proved useful in delineating areas of elevated (greater than 100 milligrams per liter) chloride concentrations, assessing potential sources of saline water, and evaluating trends in chloride distribution and concentration over time. Irrigation water containing elevated chloride concentrations is associated with negative effects to rice and soybeans, two of the major crops in Arkansas, and a groundwater chloride concentration of 100 milligrams per liter is recommended as the upper limit for use on rice. As such, accurately delineating areas with high salinity ground water, defining potential sources of chloride, and documenting trends over time is important in assisting the agricultural community in water management. The distribution and range of chloride concentrations in the study area revealed distinct areas of elevated chloride concentrations. Area I includes an elongated, generally northwest-southeast trending band of moderately elevated chloride concentrations in the northern part of the study area. This band of elevated chloride concentrations is approximately 40 miles in length and varies from approximately 2 to 9 miles in width, with a maximum chloride concentration of 360 milligrams per liter. Area II is a narrow, north-south trending band of elevated chloride concentrations in the southern part of the study area, with a maximum chloride concentration of 1,639 milligrams per liter. A zone of chloride concentrations exceeding 200 milligrams per liter is approximately 25 miles in length and 5 to 6 miles in width. In Area I, low chloride concentrations in samples from wells completed in the alluvial aquifer next to the Arkansas River and in samples from the upper Claiborne aquifer, which underlies the alluvial aquifer, indicate that leakage from the river and upward flow of saline water in underlying aquifers are not likely sources for the saline water in the alluvial aquifer in Area I. A good comparison was noted for chloride concentrations in Area I and surface geomorphology. In the majority of cases, elevated chloride concentrations occurred in backswamp deposits, with low concentrations (less than 50 milligrams per liter) in areas of active or abandoned channel deposits. The fine-grained, clay-rich deposits associated with backswamp areas likely restrict recharge, induce increased ratios between evapotranspiration and recharge, and experience minimal flushing of salts concentrated during evapotranspiration. In Area II, chloride isoconcentration maps of the underlying upper Claiborne aquifer, in addition to samples from wells completed in the middle and lower Claiborne aquifers, showed a similar chloride distribution to that of the alluvial aquifer with decreasing chloride concentrations to the east of the zone of elevated chloride concentrations, which suggests a deeper source of saline water that affects Tertiary and Quaternary aquifer systems. Mixing curves developed from bromide/chloride ratios in water samples from the alluvial aquifer, Tertiary aquifers, and samples of brine water from the Jurrasic Smackover Formation additionally discounted upward flow of saline water from underlying Tertiary formations as a potential mechanism for salinity in the alluvial aquifer in Area II. A review of information on oil exploration wells in Chicot County revealed that most of these wells were drilled from 1960 to 1980, after the elevated chloride concentrations were detected in the early 1950s. The elongated nature of the zone of elevated chloride concentrations in Area II suggests a line source or linear conduit connection with the source. Maps of a fractured limestone in the Smackover Formation in Arkansas, Mississippi, and Louisiana for purpose

Scientific Investigations Report↗
USGS2009

Trends in streamflow characteristics of selected sites in the Elkhorn River, Salt Creek, and Lower Platte River Basins, Eastern Nebraska, 1928-2004, and evaluation of streamflows in relation to instream-flow criteria, 1953-2004

The Nebraska Department of Natural Resources approved instream-flow appropriations on the Platte River to maintain fish communities, whooping crane roost habitat, and wet meadows used by several wild bird species. In the lower Platte River region, the Nebraska Game and Parks Commission owns an appropriation filed to maintain streamflow for fish communities between the Platte River confluence with the Elkhorn River and the mouth of the Platte River. Because Elkhorn River flow is an integral part of the flow in the reach addressed by this appropriation, the Upper Elkhorn and Lower Elkhorn Natural Resources Districts are involved in overall management of anthropogenic effects on the availability of surface water for instream requirements. The Physical Habitat Simulation System (PHABSIM) and other estimation methodologies were used previously to determine instream requirements for Platte River biota, which led to the filing of five water appropriations applications with the Nebraska Department of Natural Resources in 1993 by the Nebraska Game and Parks Commission. One of these requested instream-flow appropriations of 3,700 cubic feet per second was for the reach from the Elkhorn River to the mouth of the Platte River. Four appropriations were granted with modifications in 1998, by the Nebraska Department of Natural Resources. Daily streamflow data for the periods of record were summarized for 17 streamflow-gaging stations in Nebraska to evaluate streamflow characteristics, including low-flow intervals for consecutive durations of 1, 3, 7, 14, 30, 60, and 183 days. Temporal trends in selected streamflow statistics were not adjusted for variability in precipitation. Results indicated significant positive temporal trends in annual flow for the period of record at eight streamflow-gaging stations - Platte River near Duncan (06774000), Platte River at North Bend (06796000), Elkhorn River at Neligh (06798500), Logan Creek near Uehling (06799500), Maple Creek near Nickerson (06800000), Elkhorn River at Waterloo (06800500), Salt Creek at Greenwood (06803555), and Platte River at Louisville (06805500). In general, sites in the Elkhorn River Basin upstream from Norfolk showed fewer significant trends than did sites downstream from Norfolk and sites in the Platte River and Salt Creek basins, where trends in low flows also were positive. Historical Platte River streamflow records for the streamflow-gaging station at Louisville, Nebraska, were used to determine the number of days per water year (Sept. 30 to Oct. 1) when flows failed to satisfy the minimum criteria of the instream-flow appropriation prior to its filing in 1993. Before 1993, the median number of days the criteria were not satisfied was about 120 days per water year. During 1993 through 2004, daily mean flows at Louisville, Nebraska, have failed to satisfy the criteria for 638 days total (median value equals 21.5 days per year). Most of these low-flow intervals occurred in summer through early fall. For water years 1953 through 2004, of the discrete intervals when flow was less that the criteria levels, 61 percent were 3 days or greater in duration, and 38 percent were 7 days or greater in duration. The median duration of intervals of flow less than the criteria levels was 4 consecutive days during 1953 through 2004.

Nebraska↗
USGS2009

Sources and preparation of data for assessing trends in concentrations of pesticides in streams of the United States, 1992-2006

This report provides a water-quality data set of 44 commonly used pesticides and 8 pesticide degradates suitable for a national assessment of trends in pesticide concentrations in streams of the United States. Water-quality samples collected from January 1992 through August 2006 at stream-water sites of the U.S. Geological Survey National Water-Quality Assessment Program and the National Stream Quality Accounting Network Program were compiled, reviewed, selected, and prepared for trend analysis as described in this report. Samples analyzed at the U.S. Geological Survey National Water Quality Laboratory by a gas chromatography/mass spectrometry analytical method were the most extensive in time and space and were selected for national trend analysis. The selection criteria described in the report produced a trend data set of 16,869 pesticide samples at 201 stream and river sites.

Scientific Investigations Report↗
USGS2011

Trends in nutrient concentrations, loads, and yields in streams in the Sacramento, San Joaquin, and Santa Ana Basins, California, 1975-2004

A comprehensive database was assembled for the Sacramento, San Joaquin, and Santa Ana Basins in California on nutrient concentrations, flows, and point and nonpoint sources of nutrients for 1975-2004. Most of the data on nutrient concentrations (nitrate, ammonia, total nitrogen, orthophosphate, and total phosphorus) were from the U.S. Geological Survey's National Water Information System database (35.2 percent), the California Department of Water Resources (21.9 percent), the University of California at Davis (21.6 percent), and the U.S. Environmental Protection Agency's STOrage and RETrieval database (20.0 percent). Point-source discharges accounted for less than 1 percent of river flows in the Sacramento and San Joaquin Rivers, but accounted for close to 80 percent of the nonstorm flow in the Santa Ana River. Point sources accounted for 4 and 7 percent of the total nitrogen and total phosphorus loads, respectively, in the Sacramento River at Freeport for 1985-2004. Point sources accounted for 8 and 17 percent of the total nitrogen and total phosphorus loads, respectively, in the San Joaquin River near Vernalis for 1985-2004. The volume of wastewater discharged into the Santa Ana River increased almost three-fold over the study period. However, due to improvements in wastewater treatment, the total nitrogen load to the Santa Ana River from point sources in 2004 was approximately the same as in 1975 and the total phosphorus load in 2004 was less than in 1975. Nonpoint sources of nutrients estimated in this study included atmospheric deposition, fertilizer application, manure production, and tile drainage. The estimated dry deposition of nitrogen exceeded wet deposition in the Sacramento and San Joaquin Valleys and in the basin area of the Santa Ana Basin, with ratios of dry to wet deposition of 1.7, 2.8, and 9.8, respectively. Fertilizer application increased appreciably from 1987 to 2004 in all three California basins, although manure production increased in the San Joaquin Basin but decreased in the Sacramento and Santa Ana Basins from 1982 to 2002. Tile drainage accounted for 22 percent of the total nitrogen load in the San Joaquin River near Vernalis for 1985-2004. Nutrient loads and trends were calculated by using the log-linear multiple-regression model, LOADEST. Loads were calculated for water years 1975-2004 for 22 sites in the Sacramento Basin, 15 sites in the San Joaquin Basin, and 6 sites in the Santa Ana Basin. The average annual load of total nitrogen and total phosphorus for 1985-2004 in subbasins in the Sacramento and San Joaquin Basins were divided by their drainage areas to calculate average annual yield. Total nitrogen yields were greater than 2.45 tons per square mile per year [(tons/mi2)/yr] in about 61 percent of the valley floor in the San Joaquin Basin compared with only about 12 percent of the valley floor in the Sacramento Basin. Total phosphorus yields were greater than 0.34 (tons/mi2)/yr in about 43 percent of the valley floor in the San Joaquin Basin compared with only about 5 percent in the valley floor of the Sacramento Basin. In a stepwise multiple linear-regression analysis of 30 subbasins in the Sacramento and San Joaquin Basins, the most important explanatory variables (out of 11 variables) for the response variable (total nitrogen yield) were the percentage of land use in (1) orchards and vineyards, (2) row crops, and (3) urban categories. For total phosphorus yield, the most important explanatory variable was the amount of fertilizer application plus manure production. Trends were evaluated for three time periods: 1975-2004, 1985-2004, and 1993-2004. Most trends in flow-adjusted concentrations of nutrients in the Sacramento Basin were downward for all three time periods. The decreasing nutrient trends in the American River at Sacramento and the Sacramento River at Freeport for 1975-2004 were attributed to the consolidation of wastewater in the Sacramento metropolitan area in December 1982 to

California↗
USGS2011

Evaluation and trends of land cover, streamflow, and water quality in the North Canadian River Basin near Oklahoma City, Oklahoma, 1968-2009

The U.S. Geological Survey, in cooperation with the city of Oklahoma City, collected water-quality samples from the North Canadian River at the streamflow-gaging station near Harrah, Oklahoma (Harrah station), since 1968, and at an upstream streamflow-gaging station at Britton Road at Oklahoma City, Oklahoma (Britton Road station), since 1988. Statistical summaries and frequencies of detection of water-quality constituent data from water samples, and summaries of water-quality constituent data from continuous water-quality monitors are described from the start of monitoring at those stations through 2009. Differences in concentrations between stations and time trends for selected constituents were evaluated to determine the effects of: (1) wastewater effluent discharges, (2) changes in land-cover, (3) changes in streamflow, (4) increases in urban development, and (5) other anthropogenic sources of contamination on water quality in the North Canadian River downstream from Oklahoma City. Land-cover changes between 1992 and 2001 in the basin between the Harrah station and Lake Overholser upstream included an increase in developed/barren land-cover and a decrease in pasture/hay land cover. There were no significant trends in median and greater streamflows at either streamflow-gaging station, but there were significant downward trends in lesser streamflows, especially after 1999, which may have been associated with decreases in precipitation between 1999 and 2009 or construction of low-water dams on the river upstream from Oklahoma City in 1999. Concentrations of dissolved chloride, lead, cadmium, and chlordane most frequently exceeded the Criterion Continuous Concentration (a water-quality standard for protection of aquatic life) in water-quality samples collected at both streamflow-gaging stations. Visual trends in annual frequencies of detection were investigated for selected pesticides with frequencies of detection greater than 10 percent in all water samples collected at both streamflow-gaging stations. Annual frequencies of detection of 2,4-dichlorophenoxyacetic acid and bromacil increased with time. Annual frequencies of detection of atrazine, chlorpyrifos, diazinon, dichlorprop, and lindane decreased with time. Dissolved nitrogen and phosphorus concentrations were significantly greater in water samples collected at the Harrah station than at the Britton Road station, whereas specific conductance was greater at the Britton Road station. Concentrations of dissolved oxygen, biochemical oxygen demand, and fecal coliform bacteria were not significantly different between stations. Daily minimum, mean, and maximum specific conductance collected from continuous water-quality monitors were significantly greater at the Britton Road station than in water samples collected at the Harrah station. Daily minimum, maximum, and diurnal fluctuations of water temperature collected from continuous water-quality monitors were significantly greater at the Harrah station than at the Britton Road station. The daily maximums and diurnal range of dissolved oxygen concentrations were significantly greater in water samples collected at the Britton Road station than at the Harrah station, but daily mean dissolved oxygen concentrations in water at those streamflow-gaging stations were not significantly different. Daily mean and diurnal water temperature ranges increased with time at the Britton Road and Harrah streamflow-gaging stations, whereas daily mean and diurnal specific conductance ranges decreased with time at both streamflow-gaging stations from 1988–2009. Daily minimum dissolved oxygen concentrations collected from continuous water-quality monitors more frequently indicated hypoxic conditions at the Harrah station than at the Britton Road station after 1999. Fecal coliform bacteria counts in water decreased slightly from 1988–2009 at the Britton Road station.

Oklahoma↗
USGS2014

Water-quality trends for selected sampling sites in the upper Clark Fork Basin, Montana, water years 1996-2010

A large-scale trend analysis was done on specific conductance, selected trace elements (arsenic, cadmium, copper, iron, lead, manganese, and zinc), and suspended-sediment data for 22 sites in the upper Clark Fork Basin for water years 1996–2010. Trend analysis was conducted by using two parametric methods: a time-series model (TSM) and multiple linear regression on time, streamflow, and season (MLR). Trend results for 1996–2010 indicate moderate to large decreases in flow-adjusted concentrations (FACs) and loads of copper (and other metallic elements) and suspended sediment in Silver Bow Creek upstream from Warm Springs. Deposition of metallic elements and suspended sediment within Warm Springs Ponds substantially reduces the downstream transport of those constituents. However, mobilization of copper and suspended sediment from floodplain tailings and stream banks in the Clark Fork reach from Galen to Deer Lodge is a large source of metallic elements and suspended sediment, which also affects downstream transport of those constituents. Copper and suspended-sediment loads mobilized from within this reach accounted for about 40 and 20 percent, respectively, of the loads for Clark Fork at Turah Bridge (site 20); whereas, streamflow contributed from within this reach only accounted for about 8 percent of the streamflow at Turah Bridge. Minor changes in FACs and loads of copper and suspended sediment are indicated for this reach during 1996–2010. Clark Fork reaches downstream from Deer Lodge are relatively smaller sources of metallic elements than the reach from Galen to Deer Lodge. In general, small decreases in loads and FACs of copper and suspended sediment are indicated for Clark Fork sites downstream from Deer Lodge during 1996–2010. Thus, although large decreases in FACs and loads of copper and suspended sediment are indicated for Silver Bow Creek upstream from Warm Springs, those large decreases are not translated to the more downstream reaches largely because of temporal stationarity in constituent transport relations in the Clark Fork reach from Galen to Deer Lodge. Unlike metallic elements, arsenic (a metalloid element) in streams in the upper Clark Fork Basin typically is mostly in dissolved phase, has less variability in concentrations, and has weaker direct relations with suspended-sediment concentrations and streamflow. Arsenic trend results for 1996–2010 indicate generally moderate decreases in FACs and loads in Silver Bow Creek upstream from Opportunity. In general, small temporal changes in loads and FACs of arsenic are indicated for Silver Bow Creek and Clark Fork reaches downstream from Opportunity during 1996–2010. Contribution of arsenic (from Warm Springs Ponds, the Mill-Willow bypass, and groundwater sources) in the Silver Bow Creek reach from Opportunity to Warm Springs is a relatively large source of arsenic. Arsenic loads originating from within this reach accounted for about 11 percent of the load for Clark Fork at Turah Bridge; whereas, streamflow contributed from within this reach only accounted for about 2 percent of the streamflow at Turah Bridge.

Montana↗
USGS2016

Occurrence and trends in the concentrations of fecal-indicator bacteria and the relation to field water-quality parameters in the Allegheny, Monongahela, and Ohio Rivers and selected tributaries, Allegheny County, Pennsylvania, 2001–09

The U.S. Geological Survey (USGS), in cooperation with the Allegheny County Health Department and Allegheny County Sanitary Authority, collected surface-water samples from the Allegheny, Monongahela, and Ohio Rivers and selected tributaries during the period 2001–09 to assess the occurrence and trends in the concentrations of fecal-indicator bacteria during both wet- and dry-weather conditions. A total of 1,742 water samples were collected at 52 main-stem and tributary sites. Quantifiable concentrations of Escherichia coli ( E. coli ) were reported in 1,667 samples, or 97.0 percent of 1,719 samples; concentrations in 853 samples (49.6 percent) exceeded the U.S. Environmental Protection Agency (EPA) recreational water-quality criterion of 235 colonies per 100 milliliters (col/100 mL). Quantifiable concentrations of fecal coliform (FC) bacteria were reported in 1,693 samples, or 98.8 percent of 1,713 samples; concentrations in 780 samples (45.5 percent) exceeded the Commonwealth of Pennsylvania water contact criterion of 400 col/100 mL. Quantifiable concentrations of enterococci bacteria were reported in 912 samples, or 87.5 percent of 1,042 samples; concentrations in 483 samples (46.4 percent) exceeded the EPA recreational water-quality criterion of 61 col/100 mL. The median percentage of samples in which bacteria concentrations exceeded recreational water-quality standards across all sites with five or more samples was 48 for E. coli , 43 for FC, and 75 for enterococci. E. coli , FC, and enterococci concentrations at main-stem sites had significant positive correlations with streamflow under all weather conditions, with rho values ranging from 0.203 to 0.598. Seasonal Kendall and logistic regression were evaluated to determine whether statistically significant trends were present during the period 2001–09. In general, Seasonal Kendall tests for trends in E. coli and FC bacteria were inconclusive. Results of logistic regression showed no significant trends in dry-weather exceedance of the standards; however, significant decreases in the likelihood that wet-weather E. coli and FC bacteria concentrations will exceed EPA recreational standards were found at the USGS streamgaging station Allegheny River at 9th Street Bridge. Nonparametric correlation analysis, including Spearman’s rho and the paired Prentice-Wilcoxon test, was used to screen for associations among fecal indicator bacteria concentrations and the field characteristics streamflow, water temperature, pH, specific conductance, dissolved-oxygen concentration, and turbidity.

Pennsylvania↗
USGS2016

Streamflow characteristics and trends at selected streamgages in southwest and south-central Kansas

Historical data for nine selected streamgages in southwest and south-central Kansas were used in an assessment of streamflow characteristics and trends. This information is required by the U.S. Fish and Wildlife Service and the Kansas Department of Wildlife, Parks and Tourism to assist with the effective management of Etheostoma cragini (Arkansas darter) habitats and populations in the State. Changing streamflow conditions, such as a reduction or elimination of streamflow, may adversely affect the Arkansas darter. Priority basins for the Arkansas darter represented by the selected streamgages include the Cimarron River, Rattlesnake Creek, the North Fork Ninnescah River, the South Fork Ninnescah River, the Medicine Lodge River, and the Chikaskia River. Streamflow conditions were assessed using annual streamflow characteristics computed for the period of record for each of the selected streamgages. Specific streamflow characteristics computed were mean discharge, mean base flow, 90th-percentile flow, 10th-percentile flow, minimum 7-day mean flow, minimum 28-day mean flow, number of days of flow less than 1 cubic foot per second, and number of zero-flow days. Two of the priority basins had statistically significant decreases in annual mean discharge during the period of record. In the Cimarron River Basin, there was a pronounced multidecadal decrease in the magnitude and variability of annual mean discharge. Concurrently, the percentage of the annual mean discharge that was contributed by base flow increased. In the Rattlesnake Creek Basin, there was a pre-1985 decrease in annual mean discharge. Typically, in these two basins, significant decreases were indicated for mean base flow, 90th-percentile flow, 10th-percentile flow, minimum 7-day mean flow, and minimum 28-day mean flow. No significant trend in annual mean discharge was indicated for the North Fork Ninnescah, South Fork Ninnescah, Medicine Lodge, and Chikaskia River Basins. For the Medicine Lodge and Chikaskia River Basins as well as the downstream part of the South Fork Ninnescah River Basin, a significant increase in mean base flow and 10th-percentile flow was indicated. Also, for the latter two basins, a significant increase was indicated for minimum 7-day mean flow. Factors investigated to explain long-term trends in annual mean discharge, or lack thereof, included precipitation and groundwater withdrawals. Annual precipitation in the study area varied substantially from 1951 to 2013 with no pronounced long-term trend. Thus, a precipitation-related explanation for the significant decrease in annual mean discharge in the Cimarron River and Rattlesnake Creek Basins was not supported. Because the most pronounced decreases in annual mean discharge were in the basin with the largest groundwater-level declines (that is, the Cimarron River Basin), both in terms of magnitude and areal extent, it is likely that groundwater withdrawals were a primary, if not dominant, causative factor. The occurrence of extremely low-flow (less than 1 cubic foot per second) and zero-flow days varied by basin and year. Typically, such days occurred in the summer and autumn for all basins.

Kansas↗
USGS2016

External quality assurance project report for the National Atmospheric Deposition Program’s National Trends Network and Mercury Deposition Network, 2013–14

The U.S. Geological Survey Branch of Quality Systems operated five distinct programs to provide external quality assurance monitoring for the National Atmospheric Deposition Program’s (NADP) National Trends Network and Mercury Deposition Network during 2013–14. The National Trends Network programs include (1) a field audit program to evaluate sample contamination and stability, (2) an interlaboratory comparison program to evaluate analytical laboratory performance, and (3) a colocated sampler program to evaluate bias from precipitation sampler upgrades. The Mercury Deposition Network programs include the (4) system blank program and (5) an interlaboratory comparison program. The results indicate that NADP data continue to be of sufficient quality for the analysis of spatial distributions and time trends for chemical constituents in wet deposition. The field audit program results indicate that sample contamination levels for calcium, nitrate, and sulfate continued to increase during the study period while sodium and chloride contamination decreased and magnesium, potassium, ammonium, and hydrogen-ion contamination have remained relatively constant. Analyte losses due to potential sample instability were negligible. The NADP Central Analytical Laboratory produced interlaboratory comparison results with low bias and variability compared to other domestic and international laboratories that support atmospheric deposition monitoring. Colocated sampler program results from dissimilar colocated collectors suggest that the retrofit of the National Trends Network with N-CON Systems precipitation collectors could cause shifts in NADP annual deposition (concentration multiplied by depth) values from +6.2 to +51 percent for ammonium, from +8.1 to +61 percent for nitrate, from 3.8 to 71 percent for sulfate, from –24 to +15 percent for hydrogenion deposition, and larger shifts (from –14 to +102 percent) for calcium, magnesium, sodium, potassium, and chloride. The N-CON Systems collector typically catches more precipitation than the NADP-approved Aerochem Metrics Model 301 collector, but it typically caught slightly less precipitation than the Aerochem Metrics collector at a wind-swept, high-altitude site during water year 2013. Paired, identical OTT Pluvio-2 and ETI Noah IV rain gages were operated at the same sites. Results of the colocated rain gages indicate from 0 to 3.7 percent median absolute percent difference for weekly precipitation-depth measurements and from 0.05 to 5.6 absolute percent difference for annual total precipitation depth. The Mercury Deposition Network programs include the system blank program and an interlaboratory comparison program. System blank results indicated that maximum total mercury contamination concentrations in samples were less than the third percentile of all Mercury Deposition Network sample concentrations. The Mercury Analytical Laboratory produced chemical concentration results with low bias and variability compared with other domestic and international laboratories that support atmospheric-deposition monitoring.

Scientific Investigations Report↗
USGS2018

External quality assurance project report for the National Atmospheric Deposition Program’s National Trends Network and Mercury Deposition Network, 2015–16

The U.S. Geological Survey Precipitation Chemistry Quality Assurance project operated five distinct programs to provide external quality assurance monitoring for the National Atmospheric Deposition Program’s (NADP) National Trends Network and Mercury Deposition Network during 2015–16. The National Trends Network programs include (1) a field audit program to evaluate sample contamination and stability, (2) an interlaboratory comparison program to evaluate analytical laboratory performance, and (3) a colocated sampler program to evaluate bias and variability attributed to automated precipitation samplers. The Mercury Deposition Network programs include the (4) system blank program and (5) an interlaboratory comparison program. The results indicate that NADP data continue to be of sufficient quality for the analysis of spatial distributions and time trends for chemical constituents in wet deposition. The field audit program results indicate increased sample contamination for calcium, magnesium, and potassium relative to 2010 levels, and slight fluctuation in sodium contamination. Nitrate contamination levels dropped slightly during 2014–16, and chloride contamination leveled off between 2007 and 2016. Sulfate contamination is similar to the 2000 level. Hydrogen ion contamination has steadily decreased since 2012. Losses of ammonium and nitrate resulting from potential sample instability were negligible. The NADP Central Analytical Laboratory produced interlaboratory comparison results with low bias and variability compared to other domestic and international laboratories that support atmospheric deposition monitoring. Significant absolute bias above the magnitudes of the detection limits was observed for nitrate and sulfate concentrations, but no analyte determinations exceeded the detection limits for blanks. Colocated sampler program results from dissimilar colocated collectors indicate that the retrofit of the National Trends Network with N-CON Systems Company, Inc. precipitation collectors could cause substantial shifts in NADP annual deposition (concentration multiplied by depth) values. Median weekly relative percent differences for analyte concentrations ranged from -4 to +76 percent for cations, from 5 to 6 percent for ammonium, from +14 to +25 percent for anions, and from -21 to +8 percent for hydrogen ion contamination. By comparison, weekly absolute concentration differences for paired identical N-CON Systems Company, Inc., collectors ranged from 4–22 percent for cations; 2–9 percent for anions; 4–5 percent for ammonium; and 13–14 percent for hydrogen ion contamination. The N-CON Systems Company, Inc. collector caught more precipitation than the Aerochem Metrics Model 301 collector (ACM) at the WA99/99WA sites, but it typically caught slightly less precipitation than the ACM at ND11/11ND, sites which receive more wind and snow than WA99/99WA. Paired, identical OTT Pluvio-2 and ETI Noah IV precipitation gages were operated at the same sites. Median absolute percent differences for daily measured precipitation depths ranged from 0 to 7 percent. Annual absolute differences ranged from 0.08 percent (ETI Noah IV precipitation gages) to 11 percent (OTT Pluvio-2 precipitation gages). The Mercury Deposition Network programs include the system blank program and an interlaboratory comparison program. System blank results indicate that maximum total mercury contamination concentrations in samples were less than the third percentile of all Mercury Deposition Network sample concentrations (1.098 nanograms per liter; ng/L). The Mercury Analytical Laboratory produced chemical concentration results with low bias and variability compared with other domestic and international laboratories that support atmospheric-deposition monitoring. The laboratory’s performance results indicate a +1-ng/L shift in bias between 2015 (-0.4 ng/L) and 2016 (+0.5 ng/L).

Scientific Investigations Report↗
USGS2020

Trends in concentration, loads, and sources of trace metals and nutrients in the Spokane River Watershed, northern Idaho, water years 1990–2018

A long history of mining and widespread metals contamination in the Coeur d’Alene River watershed and downstream into the Spokane River has led to the area’s designation as a Superfund site and to extensive, ongoing (as of 2020) remedial actions. Long-term water-quality and streamflow data, collected by the U.S. Geological Survey for up to 29 years at 20 sampling sites in the Coeur d’Alene, Spokane and St. Joe River watersheds, were analyzed to evaluate the impact of remedial actions on metals in surface water. Analyses focused on total and dissolved cadmium, zinc and lead. Trends in total phosphorus, total nitrogen and dissolved orthophosphate were also evaluated; although these nutrients are not constituents of concern for the Superfund site, they are important to the health of Coeur d’Alene Lake. Dissolved cadmium, zinc and lead concentrations were compared to ambient water-quality criteria at 20 sample sites. For the 12 sites with the most extensive data records, Weighted Regressions on Time, Discharge and Season (WRTDS) models were developed to estimate flow-normalized annual mean concentrations and flow-normalized annual total loads; these results were used to evaluate trends because flow-normalization dampens the impact of interannual streamflow variability on concentrations and loads. WRTDS models with Kalman filtering (WRTDS_K) were developed to estimate annual mean concentrations and annual total loads; these results were used to evaluate spatial patterns in constituent sources. Models were developed for total and dissolved cadmium, lead, and zinc; total phosphorus and nitrogen; and dissolved orthophosphate, although not all constituents were modeled for all sites due to limited sample sizes. Bootstrapped confidence intervals were constructed to determine the statistical likelihood of trends and the slope of trends in flow-normalized concentrations and loads during the period of record (13–29 years, depending on the site), water years 1999–2009, and water years 2009–18.

Idaho↗
USGS2022

Assessment of streamflow trends in the eastern Dakotas, water years 1960–2019

Hydrologic extremes, whether periods of drought or flooding, are occurring more frequently with greater severity and can have substantial economic impacts. Along with flooding, the timing and volume of streamflow also is changing across the United States. The focus of this report is to characterize a unique trend in mean annual streamflow occurring in eastern North and South Dakota, hereafter referred to as the eastern Dakotas, that is not being observed anywhere else in the conterminous United States. Streamflow records for 1,853 U.S. Geological Survey streamgages obtained from the U.S. Geological Survey National Water Information System database with a continuous record of mean annual streamflow during water years 1960–2019 were included in this study. Using a Kendall tau statistical test ( p -value less than or equal to 0.10), 573 streamgages had a statistically significant upward trend in mean annual streamflow and are primarily located in the Midwest and northeastern United States. Of the streamgages, 182 had a statistically significant downward trend and are located primarily in the western and southeastern States. Several sites had increases in streamflow between 100 and 500 percent. Most of the streamgages with the highest increases in mean annual streamflow are along the same rivers in the eastern Dakotas, regardless of basin size. A comparison of mean annual streamflow of the last decade (2010–19) to the first decade (1960–69) of the study period shows that the largest increases in annual streamflow volumes in the United States also are in the eastern Dakotas. Among all 1,853 streamgages in the United States, the Sheyenne River near Warwick, North Dakota (U.S. Geological Survey station 05056000), has the greatest percent change, with an increase of 486 percent. Several factors may be contributing to increasing trends in streamflow in the eastern Dakotas and may include, in part, precipitation changes owing to climatic variation within the region, geologic makeup of the subsurface, and land-use changes. A better understanding of these research areas will help producers, resource managers, and infrastructure engineers to make more informed environmental and economic decisions.

North Dakota, South Dakota↗
USGS2025

Spatial patterns and temporal trends in water quality in Idaho’s lower Boise River and its tributaries, 1994–2023

The lower Boise River in southwestern Idaho is a vital cultural, economic, and ecological resource, but some of its beneficial uses are impaired by excess algae, sediment, nutrients, and bacteria. In response, a variety of water quality improvement projects and regulations have been implemented in recent decades. A recent study showed that, from water years 2003 to 2021, concentrations of total phosphorus at the mouth of the Boise River near Parma decreased by 60 percent, indicating the success of the improvement projects and progress towards reaching the regulatory target. However, although the progress of the system as a whole towards reaching the total phosphorus target is well documented, quantifying contributions and trends in total phosphorus loading from individual tributaries and upstream mainstem locations is needed. Similarly, tributary contributions and trends of other constituents of concern are unknown or have not been evaluated in a decade. To evaluate the success of past water-quality improvement efforts and help prioritize future investments, this study characterized spatial and seasonal patterns in concentrations and loads of suspended sediment, total phosphorus, orthophosphate, total nitrogen, nitrate plus nitrite, Escherichia coli bacteria, and periphyton chlorophyll a (chl-a) at three mainstem and seven tributary sites of the lower Boise River during water years 2019–2023. For sites and constituents with adequate data, temporal trends over a 15-year and 30-year period were also evaluated. Recent (in other words, water years 2019–2023) concentrations and loads of suspended sediment and total phosphorus were typically greatest during the irrigation season and often exceeded total maximum daily load targets. However, concentrations and loads of suspended sediment, total phosphorus, and orthophosphate have decreased over the past 15 to 30 years at many sites. In contrast, concentrations of total nitrogen and nitrate plus nitrite showed increasing trends at the Boise River near Parma, likely reflecting the effects of regional changes in agricultural practices in recent decades. Periphyton chl-a concentrations during October–November were highly likely increasing over the 30-year period at Boise River at Eckert, but were uncertain at Middleton and Parma. At Boise River at Middleton, periphyton chl-a concentrations exceeded the total maximum daily load target of 150 milligrams per square meter in 75 percent of samples during water years 2019–2023. Results therefore demonstrate that past watershed improvement efforts have been largely effective at reducing concentrations and loads of suspended sediment, total phosphorus, and orthophosphate in the lower Boise River watershed, but different strategies may be needed to reduce concentrations and loads of total nitrogen, nitrate plus nitrite, Escherichia coli , and periphyton chl-a.

Idaho↗
USGS2003

Trends in nitrogen concentration and nitrogen loads entering the South Shore Estuary Reserve from streams and ground-water discharge in Nassau and Suffolk counties, Long Island, New York, 1952–97

The 13 major south-shore streams in Nassau and Suffolk Counties, Long Island, New York with adequate long-term (1971-97) water-quality records, and 192 south-shore wells with sufficient water-quality data, were selected for analysis of geographic, seasonal, and long-term trends in nitrogen concentration. Annual total nitrogen loads transported to the South Shore Estuary Reserve (SSER) from 11 of these streams were calculated using long-term discharge records. Nitrogen loads from shallow and deep ground water also were calculated using simulated ground-water discharge of 1968-83 hydrologic conditions. Long-term declines in stream discharge occurred in East Meadow Brook, Bellmore Creek and Massapequa Creek in response to extensive sewering in Nassau County. The smallest longterm annual discharge to the SSER was from the westernmost stream, Pines Brook, which is in an area in which the water table has been lowered by sewers since 1952. The three largest average annual discharges to the SSER were from the Connetquot River, Carlls River, and Carmans River in Suffolk County; the discharges from each of these streams were at least twice those of the other streams considered in this study. Total nitrogen concentrations in streams show a geographic trend with a general eastward increase in median total nitrogen concentration in Nassau County and a decreasing trend from Massapequa Creek eastward into Suffolk County. Total nitrogen concentrations in streams generally are lowest during summer and highest in winter as a result of seasonal fluctuations in chemical reactions and biological activity. The greatest seasonal difference in median total nitrogen concentration was at Carlls River with values of 3.4 and 4.2 mg/L (milligrams per liter) as N during summer (April through September) and winter (October through March), respectively. Streams affected by the completion of sewer districts show long-term (1971-97) trends of decreasing total nitrogen concentration and streams showing an increase in total nitrogen concentration are in unsewered areas with increased urbanization. Discharges from shallow ground water (upper glacial aquifer) and deep ground water (upper part of Magothy aquifer) were simulated from a ground-water-flow model calibrated to steadystate (1968-83) conditions. Simulated discharges from shallow-ground-water system in Nassau County were 10,700 Mgal/yr (million gallons per year) or 40,500,000 m 3 /yr (cubic meters per year), and those from Suffolk County were 52,300 Mgal/yr or 198,000,000 m 3 /yr. Discharges from deep-ground-water system in Nassau County were 4,900 Mgal/yr or 18,500,000 m 3 /yr, and those in Suffolk County were 12,700 Mgal/yr or 48,200,000 m 3 /yr. Ground-water concentrations of nitrogen decrease with depth and from west to east. The shallow ground water median nitrogen concentration for each county was determined using 1,155 samples collected at 167 shallow wells (125 feet deep or less) within 1 mile of the shore. The deep ground water median nitrate concentration (nitrate represented almost all of the total nitrogen) for each county was determined using 112 samples collected at 25 deep wells (greater than 125 feet deep) within 1 mile of the shore. The median nitrogen concentration for the shallow and median nitrate concentration for the deep ground water in Nassau County were 3.85 and 0.15 mg/L as N, during 1952–97; the corresponding concentrations for Suffolk County were 1.74 and <0.10 (less than 0.10) mg/L as N, during 1952–97. Nitrogen loads discharged from streams to the SSER for each year during 1972–97 were calculated as the annual total nitrogen concentration multiplied by the annual discharge. These values were calculated only for the seven streams for which sufficient data were available. The largest long-term (1972–97) average annual nitrogen load from Carlls River was 104 ton/yr or 94,300 kg/yr—about twice that of Connetquot River (54 ton/yr or 48,900 kg/yr) and over three times that of Carmans River (33 ton/yr or 29,900 kg/yr). The smallest annual mean nitrogen load was from Pines Brook, which has the lowest annual mean discharge of all streams analyzed. The nitrogen load carried to the SSER by ground-water discharge in shallow-ground-water system in Nassau and Suffolk Counties was calculated as the simulated discharge for each county multiplied by the respective median nitrogen concentration, and loads from deep-ground-water system were calculated as the simulated discharge for each county multiplied by the respective median nitrate concentration. All discharges were obtained from the U.S. Geological Survey's Long Island ground-water-flow model. The resultant nitrogen loads discharged to the SSER from shallow ground water were 172 ton/yr (156,000 kg/yr) from Nassau County and 380 ton/yr (345,000 kg/yr) from Suffolk County; equaling 552 ton/yr entering the SSER. Those from deep ground water were 3 ton/yr (2,700 kg/yr) from Nassau County and <0.5 ton/yr (480 kg/yr) from Suffolk County; equaling about 3.5 ton/yr entering the SSER. The sum of both stream loads and groundwater loads results in the total load to the SSER. The largest calculated total nitrogen load entering the SSER from both streams and ground water occurred in 1979 with a total load of 1,260 ton/yr (1,140,000 kg/yr). The smallest calculated nitrogen load entering the SSER occurred in 1995 with a total load of 725 ton/yr (658,000 kg/yr).

New York↗
USGS2004

Background and comparison of water-quality, streambed-sediment, and biological characteristics of streams in the Viburnum Trend and the exploration study areas, southern Missouri, 1995 and 2001

Missouri has a long history of lead mining in the Park Hills and Viburnum Trend areas. Lead ore production has been a significant economic presence since the settlement of Missouri in the 1700?s. As lead sources are depleted in active mining areas, new areas are being explored for economical ore bodies. The exploration area south of Winona, a possible extension of the Viburnum Trend lead-producing area, lies in an area of intense interest because of its scenic beauty and sensitive environment. Water-quality, streambed-sediment, fish tissue, instream and riparian habitat, and invertebrate-community samples were collected from three sites in the Viburnum Trend for the National Water-Quality Assessment (NAWQA) program Black River synoptic study in 1995 and from four sites in the exploration study area in 2001. The samples, which were collected using NAWQA protocols, were analyzed and compared to establish background conditions and similarities between sites. Bacteria, lead, and zinc concentrations were substantially different between the study areas. Habitat characteristics, such as streambed substrate size and embeddedness were similar. The Eleven Point River at Turner?s Mill is substantially larger in size than the other six surveyed sites. Trace element concentrations in fish tissue samples collected in the two study areas are similar. Samples from both areas had elevated mercury levels. Invertebrate community data indicated similarity among the Viburnum Trend study area sites, but these sites had little in common with the exploration study area sites. The invertebrate community structure in the exploration study area were not similar.

Water-Resources Investigations Report↗
USGS1987

Analysis of trends in water-quality data for water conservation area 3A, the Everglades, Florida

Rainfall and water-quality data bases from the South Florida Water Management District were used to evaluate water quality trends at 10 locations near or in Water Conservation Area 3A in The Everglades. The Seasonal Kendall test was applied to specific conductance, orthophosphate-phosphorus, nitrate-nitrogen, total Kjeldahl nitrogen, and total nitrogen regression residuals for the period 1978-82. Residuals of orthophosphate and nitrate quadratic models, based on antecedent 7-day rainfall at inflow gate S-11B, were the only two constituent-structure pairs that showed apparent significant (p < 0.05) increases in constituent concentrations. Elimination of regression models with distinct residual patterns and data outlines resulted in 17 statistically significant station water quality combinations for trend analysis. No water quality trends were observed. The 1979 Memorandum of Agreement outlining the water quality monitoring program between the Everglades National Park and the U.S. Army Corps of Engineers stressed collection four times a year at three stations, and extensive coverage of water quality properties. Trend analysis and other rigorous statistical evaluation programs are better suited to data monitoring programs that include more frequent sampling and that are organized in a water quality data management system. Pronounced areal differences in water quality suggest that a water quality monitoring system for Shark River Slough in Everglades National Park include collection locations near the source of inflow to Water Conservation Area 3A. (Author 's abstract)

Florida↗