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Chemical evolution and estimated flow velocity of water in the Trinity Aquifer, south-central Texas

Three permeable zones with varying lithology and water chemistry compose the Trinity aquifer, a principal source of water in the 5,500- square-mile study area in south-central Texas. The upper permeable zone locally yields small quantities of water to wells and was not included in this study. The middle permeable zone primarily is composed of limestone with minor amounts of dolostone. Terrigenous sand and marine limestone, with minor amounts of dolostone, are the principal lithologic units in the lower permeable zone. Dissolved solids concentrations range from 329 to 1,820 milligrams per liter in water samples from the middle permeable zone and from 518 to 3,030 milligrams per liter in water samples from the lower permeable zone. Principal hydrochemical facies in the middle permeable zone are calcium magnesium bicarbonate and calcium magnesium sulfate. Hydrochemical facies in ground-water samples from the lower permeable zone vary. Tritium concentrations as large as 5.3 tritium units in the southeastern part of the study area are indicative of relatively recent recharge. Results of a geochemical mass balance simulation along a flowpath in the middle permeable zone indicate a mass transfer of 4.25 millimoles per liter of dolomite dissolved, 5.74 millimoles per liter of gypsum dissolved, 0.46 millimole per liter of sodium chloride dissolved, 8.07 millimoles per liter of calcite precipitated, and 0.67 millimole per liter of calcium-for-sodium cation exchange between solid and aqueous phases. These results support dedolomitization as a principal chemical process in the middle permeable zone of the Trinity aquifer. Results of a simulation along a flowpath in the lower permeable zone indicate a mass transfer of 0.41 millimole per liter of dolomite dissolved, 0.001 millimole per liter of gypsum dissolved, 9.58 millimoles per liter of sodium chloride dissolved, 1.09 millimoles per liter of calcite precipitated, and 1.11 millimoles per liter of sodium-forcalcium cation exchange between solid and aqueous phases. Lower permeable zone processes indicate sodium chloride dissolution, dedolomitization, and cation exchange. Ground-water-flow velocities determined from adjusted carbon-14 ages, calculated using NETPATH, for selected flowpaths in the middle and lower permeable zones were about 1.7 feet per year and less than about 4.4 feet per year, respectively.

Texas

Moment magnitude for small earthquakes in the Delaware basin of west Texas and southeast New Mexico, USA

The Delaware Basin region of west Texas and southeast New Mexico has become one of the most prolific regions of seismic activity in the continental United States due to widespread hydraulic fracturing and wastewater disposal injection. In response to the increased number of earthquakes in this region, rapid and accurate characterization of earthquake sources is necessary to understand the evolution of seismic activity and level of seismic hazard associated with these earthquakes. This study re-evaluates earthquake magnitudes, estimating moment magnitude (MW) for small earthquakes in the Delaware Basin using 1) moment-rate spectra derived from S-wave coda envelopes, and 2) a relative magnitude method that relies exclusively on the ratio of waveform amplitudes between highly correlated waveform pairs. The coda-envelope method produces accurate M W estimates for small earthquakes ( M 1.5 – 3) that are consistent with independent, waveform modeled moment magnitudes for events with M W > 3 . Using the relative amplitudes method to extend these M W magnitudes to many other events, we successfully provide relative moment magnitude ( M W,rel ) values for 81% of the Texas Seismological Network catalog in the Delaware Basin region, and 45% of the USGS Induced Seismicity Project’s catalog of events in southeast New Mexico. The adoption and integration of the calibrated M W,rel method with current magnitude estimation methods offers valuable insights into the relationships between local and moment magnitude and will contribute to improved characterization of widespread induced seismicity.

New Mexico, Texas

Suitability of ground-motion models for seismic hazard assessment in Puerto Rico and the U.S. Virgin Islands

We perform linear mixed-effects analyses with a ground-motion dataset to evaluate how well ground-motion models (GMMs) fit active crustal, subduction interface, and subduction intraslab earthquakes in Puerto Rico and the US Virgin Islands. Most of the GMMs reproduce the spatial variation in peak ground motions with earthquake magnitude and rupture distance but predict ground motions 0.3–1.0 natural log units (35%–270%) greater than observations. Two GMMs developed for Puerto Rico that are based on ground-motion records from mostly magnitude 4–5 earthquakes do not perform as well. We attribute the period-dependent overprediction in observed ground motions to differences between the observed site response and the linear site response in the GMMs. Consequently, we developed region-specific GMMs by adjusting the period-dependent linear site response coefficients and period-dependent constant coefficients to remove most of the bias between predicted ground motions and observations. For the analysis, we compile ground-motion records and process waveforms to build a dataset with 10,127 records at 72 stations from 849 magnitude 4.0–6.4 earthquakes between 1 January 2006 and 31 March 2024. The earthquakes include active crustal, subduction interface, and subduction intraslab events. We evaluate the GMMs using the time-averaged shear wave speed in the top 30 m ( ), which we compile from site surveys and proxy values computed from horizontal to vertical spectral ratios. Site terms exhibit strong consistency across GMMs and crustal and subduction earthquakes, indicating that the linear mixed-effects analysis successfully isolates the effects of local site response. The event terms show little spatial correlation and more substantial variability than in other regions, which we attribute to uncertainties in the earthquake magnitudes. This analysis guides the selection of the GMMs for the 2025 update of the National Seismic Hazard Model for Puerto Rico and the US Virgin Islands.

Puerto Rico, U.S. Virgin Islands

Simulated effects of projected 2014–40 withdrawals on groundwater flow and water levels in the New Jersey Coastal Plain

Abstract Groundwater flow between 2014 through 2040 was simulated in the New Jersey Coastal Plain based on three withdrawal scenarios. Two of the scenarios were based on projected population trends and the assumption of water conservation; the nominal water-loss scenario projected a status quo in the efficiency of water loss in the delivery systems whereas the optimal water-loss scenario projected a better water-loss efficiency resulting in less withdrawals. The third scenario assumes that all wells will withdraw water at their full allocation level which is generally much more than reported withdrawals in 2013 or projected under the other two scenarios. Maps and summaries of heads and drawdowns are presented for nine confined aquifers. All the aquifers have areas with heads below sea level by 2040. Of the three scenarios, the drawdowns are most extreme in the full allocation scenarios; there are large areas of head decline greater than 20 feet in 5 of the 9 confined aquifers. The exceptions are the Vincentown aquifer, despite some areas of large drawdown in the vicinity of wells, and the three Potomac-Raritan-Magothy (PRM) aquifers where withdrawals are regulated by Critical Area restrictions. The nominal and optimal water-loss scenarios have some areas of head declines; most are less than 15 feet. The simulation of these scenarios shows some extensive areas of head recovery as well—especially in the aquifers that are regulated by the Critical Area restrictions. Budgets of inflow and outflow components were calculated for 44 hydrologic budget areas (HBAs). The budget analysis shows that the water movement is complex and varies based on the aquifer geometry and location of pumping wells. Flow components between the unconfined and confined parts of the system were summarized by HUC11 (hydrologic unit code 11) basins.

New Jersey

Lessons in business recovery following the 2023 Kahramanmaraş earthquake sequence, Türkiye informed by women entrepreneurs

On 6 February 2023, Southern Türkiye was hit by devastating earthquakes, directly affecting over 14 million people in 11 cities, causing more than 50,000 deaths and the destruction of more than 800,000 buildings. This article goes beyond the physical damage imposed by the catastrophe to discuss the effects of the earthquakes on the operations of women-owned businesses. The mixed-method study with entrepreneurs belonging to a women’s business association operating in a moderately disrupted part of the region explores their struggles and recovery expectations. Thirty-five questionnaires were analyzed to identify the reasons for business closure, challenges, and needs faced in the post-disaster period and their recovery strategies. In addition, 23 entrepreneurs participated in roundtable discussions to provide a broader context to their responses to survey topics as well as lessons learned. Across both the survey and roundtables, while many respondents reported minor physical damage to their building, they also experienced financial and personal challenges from disruption to equipment, infrastructure, services, supply chains, institutional decisions, employee well-being, and customer base. Many used their business resources and personal savings to assist employees and others in the community. The women entrepreneurs often felt their recovery needs were ignored by government and private relief organizations and encountered barriers to receiving assistance from public and private institutions. Organizing together as women in business, even informally, provided mutual support during the crisis and recovery periods and catalyzed their role in support of their communities. The results illuminate functional community recovery as a balance of recovery of built infrastructure functionality and recovery of the broader social and economic fabric of the community.

southern Turkey

Non-destructive sampling of larval amphibians shows tail tissues reflect whole-body methylmercury concentrations and trophic-related differences in bioaccumulation

Mercury (Hg), and specifically methylmercury (MeHg), is a contaminant of global concern to humans and wildlife, but there is still limited understanding of its effects on many taxa. Amphibians are closely associated with water, where Hg is converted to MeHg, and high concentrations of MeHg can reduce survival of amphibians in the wild. However, limited non-lethal proxies exist for estimating MeHg bioaccumulation in amphibian larvae, which could be used to reduce destructive sampling and allow sampling of imperiled species. We evaluated whether tail clips were indicative of whole-body MeHg concentrations of larval amphibians, whether dragonflies were an effective bioindicator of Hg concentrations of larval amphibians, and compared MeHg bioaccumulation in predatory caudate (salamanders, newts) and non-predatory anuran (frogs, toads) larvae. Tail-clip and whole-body MeHg concentrations were strongly correlated, especially for caudates. There was high variability among sites and species, but caudates had higher MeHg than anurans, and MeHg concentrations of caudates and anurans were strongly correlated. Dragonflies were a weak indicator of MeHg for anurans but strong indicators for larval caudates, likely because caudates and dragonflies are carnivorous and occupy similar trophic positions. Our study revealed that sampling tails can be an effective non-destructive index of whole-body MeHg for larval amphibians and demonstrates differences in MeHg bioaccumulation related to trophic position in larval amphibians and dragonflies. All post-embryo life stages for a broad suite of amphibian species can now be sampled non-lethally for MeHg, allowing for a broader examination of population-level effects and focus on imperiled species that cannot be sampled destructively.

conterminous United States

Late Jurassic igneous rocks in south-central Arizona and north-central Sonora: Magmatic accompaniment of crustal extension

In Middle Jurassic time, the region of south-central Arizona and north-central Sonora was part of a continental magmatic arc. In early Late Jurassic time, this magmatic arc gradually gave way to a extensional regime. Late Jurassic rifting was accompanied by magmatism, typically small in volume relative to the preceding arc phase, and with mildly alkaline compositions. These igneous rocks, the 158- to 146-Ma Ko Vaya Suite, make up much or most of the Comobabi, Artesa, Quijotoa, and Brownell Mountains and Sierra del Cobre. The bimodal Ko Vaya Suite constitutes volcanic to shallow plutonic complexes comprising chiefly trachyandesite and volcanic wacke; monzodiorite; rhyolite porphyry; distinctive, compositionally and texturally heterogeneous, quartzpoor granite (the Ko Vaya Granite); A-type perthite granite and quartz syenite; aphyric intrusive rhyolite; and locally abundant hematite veins. Alteration, particularly potassic alteration, is widespread. Minimally altered samples of granite and quartz syenite have the composition of trachyte or trachydacite and alkali rhyolite. The Ko Vaya Suite is nonconformably overlain by the latest Jurassic Sand Wells Formation, approximately correlative with the Glance Conglomerate, the basal unit of the Bisbee Group. The Ko Vaya Suite is in some ways analogous to the coeval Independence dike swarm of eastern California, but less diffuse. We infer that the Ko Vaya Suite represents especially intense or focused Late Jurassic extensional magmatism.

Arizona, Sonora

Uncertainty quantification of geologic energy storage in depleted gas reservoirs using material balance equations embedded in a hierarchical errors-in-variables model

The storage potential for gas in geologic settings, such as depleted hydrocarbon reservoirs and solution-mined salt caverns, is becoming salient to future energy infrastructure planning. Technologies such as carbon capture, utilization, and storage, carbon dioxide-enhanced oil recovery, and natural gas and hydrogen storage help meet growing energy demands, reduce carbon emissions to meet climate goals, and provide energy security amid geopolitical uncertainties. Therefore, estimates of underground gas storage capacity could be useful for efficiently navigating the energy transitions. Material balance is a fundamental method in reservoir engineering for estimating original gas in place and potential storage capacity at the scale necessary for national assessments of subsurface pore space resources. However, the deterministic method cannot accommodate multiple data sources or quantify uncertainty in predictions. In this study, a method that embeds material balance equations within a hierarchical errors-in-variables model is proposed which allows the estimation of the distributions of reservoir properties needed for assessments. Uncertainties associated with these reservoir properties have traditionally been expert-elicited, whereas the uncertainty estimates from the proposed models are data-driven. Capacity and uncertainty estimates can be used in a probabilistic resource assessment, supplementing information traditionally used by assessors or even replacing this expert elicitation step when data are unavailable. Various regression models are compared in a case study of the Michigan Basin, a large contributor to the United States’ current natural gas storage capacity. In particular, errors-in-variables models help ameliorate regression dilution and can quantify uncertainty in predictions of pressure in addition to storage capacity. Overfitting is addressed by quantifying generalization error and model averaging in simple and stratified cross-validation against reported working gas capacity, representing the varying quality and quantity of available data. Incorporating a statistical framework into existing numerical methods in reservoir engineering can improve the quality of estimation, and in particular, this method brings rigor to uncertainty quantification as part of a larger effort by the U.S. Geological Survey to assess domestic energy gas storage resources in depleted hydrocarbon reservoirs.

Mathematical Geosciences

Patterns and drivers of cliff erosion in Big Sur, California, USA using repeat photogrammetry, 2017–2023

Seacliff erosion in steep terrain poses major risks to transportation and critical infrastructure. In Big Sur, California, USA, seacliff erosion threatens the sustainability of the central coast stretch of California State Route 1, a transportation corridor that is critical to the region's economy. Published cliff retreat rates for the region range from 1 to 40 cm yr −1 , highlighting that high-resolution, process-based studies could enhance understanding of the causes of spatial and temporal variability. We quantified cliff erosion and investigated its drivers along ∼13 km of the Big Sur coastline at week–month timescales during the late fall to early spring wet seasons between January 2017 and June 2023 by analyzing 3D point clouds developed from aerial imagery using four-dimensional structure-from-motion (4D SfM) photogrammetry techniques. We calculated cliff face retreat rates of 2.23 ± 3.06 cm yr −1 (mean ±1 σ ), an order of magnitude lower than long-term estimated rates for the region (which included large deep-seated landslides), but in line with short-term rates reported across California. Change detection imagery comparison, cliff profiles through time, and statistical analysis reveal a cyclical cliff evolution process in which erosion by wave action at the cliff base destabilizes the cliff and primes it for subsequent failure during precipitation events. Although more erosion by volume could be attributed to precipitation-induced increases in soil moisture (784 m 3 km −1 yr −1 ) compared with erosion attributed to wave power (282 m 3 km −1 yr −1 ), our observations underscore the coupled nature of these processes in driving cliff evolution, consistent with established theory and observations.

California

Hydrogeology of stratified drift in Farmington, Connecticut: Available data and future needs

The purpose of this report is twofold. The first is to update hydrogeologic information on the major stratified-drift deposits that underlie much of Farmington. The second is to outline data requirements for future ground-water evaluation and management. The scope of the report is limited to the stratified drift, as it is the only aquifer capable of sustaining large withdrawals for public or industrial supply. This aquifer is composed of interbedded layers of gravel, sand, silt and clay. Most of this material was deposited by glacial meltwaters, but locally the aquifer contains some unconsolidated deposits of nonglacial origin. The most extensive stratified-drift deposits are in the valleys of the Farmington and Pequabuck Rivers.(See plate B.) A few small areas of stratified drift near East Farmington Heights and Oakland Gardens are not discussed in this report as their potential for large-scale development is slight.

Connecticut

Forecasting storm-induced coastal flooding for 21st century sea-level rise scenarios in the Hawaiian, Mariana, and American Samoan Islands

Oceanographic, coastal engineering, ecologic, and geospatial data and tools were combined to evaluate the increased risks of storm-induced coastal flooding in the populated Hawaiian, Mariana, and American Samoan Islands as a result of climate change and sea-level rise. We followed a hybrid (dynamical and statistical) downscaling approach to map flooding due to waves and storm surge at 10-square meter resolution along all 1,870 kilometers of these islands’ coastlines for annual (1-year), 20-year, and 100-year return-interval storm events and +0.00 meter (m), +0.25 m, +0.50 m, +1.00 m, +1.50 m, +2.00 m, and +3.00 m sea-level rise scenarios. We quantified the coastal flood depths and extents using the latest climate forcing from Intergovernmental Panel for Climate Change’s Sixth Assessment Report Coupled Model Intercomparison Project. The data generated using these methods provide stakeholders and decision makers with a spatially explicit, rigorous valuation of how, where, and when climate change and sea-level rise increase coastal storm-induced flooding to help identify areas where management and (or) restoration could potentially help reduce the risk to, and increase the resiliency of, the coastal communities in the populated Hawaiian, Mariana, and American Samoan Islands.

Hawaii

Sources of water and salts for the Zuni Salt Lake in west-central New Mexico

The Zuni Salt Lake is located in a maar in west-central New Mexico and contains hypersaline water that has long been used by Native Americans for religious purposes and the collection of salt. There have been several investigations suggesting different sources for the water and salt to the lake. Springs, seeps, and ephemeral streamflow have all been observed to contribute freshwater to the lake, and brackish to hypersaline seeps have been documented along the banks of the lake. This report summarizes the findings of a study that characterizes the lake’s hydrology, its water and salinity sources, and the hydrogeologic conceptual model. Regional groundwater levels indicate that each of the aquifers in the area have the potential to discharge groundwater to the lake. There is also evidence of vertical groundwater flow pathways at the maar that were likely created by the igneous intrusion that fractured the intersecting aquifers. A detailed water budget was constructed from continuous lake stage, precipitation, and evaporation data to estimate the groundwater inflow to the Zuni Salt Lake. It was determined that groundwater inflow to the lake is 441 ±94 acre-feet per year, which composes as much as 77 percent of the total inflows. The high sodium and chloride concentrations measured in two hypersaline samples collected near the lake indicate that the majority of the dissolved solids entering the lake are from a hypersaline groundwater source. The geochemical and isotopic compositions measured in the lake and surrounding features support the interpretation that hypersaline groundwater is the primary source of salts to the lake, which is likely sourced from the older (and deeper) Permian units. The hypersaline groundwater samples collected during this investigation have a unique aqueous chemistry relative to each of the mapped aquifers, and variability in groundwater compositions is interpreted to result from differences in minerology and residence time.

New Mexico

High resolution identification and quantification of diffuse deep groundwater discharge in mountain rivers using continuous boat-mounted helium measurements

Discharge of deeply sourced groundwater to streams is difficult to locate and quantify, particularly where both discrete and diffuse discharge points exist, but diffuse discharge is one of the primary controls on solute budgets in mountainous watersheds. The noble gas helium is a unique identifier of deep groundwater discharge because groundwater with long residence times is commonly enriched in helium. In this study, a portable mass spectrometer was used to measure longitudinal variation in dissolved helium concentrations in two mountainous rivers at high spatial resolution not feasible with traditional sampling techniques. Helium profiles were then simulated using a mass-balance model to quantify longitudinal variation in groundwater discharge to the receiving rivers. Results indicate helium concentrations were enriched by multiple orders of magnitude above atmospheric equilibrium in both rivers and that this persisted for up to 18 km below observed pulse inputs in the Colorado River. Helium mass-balance models match observed longitudinal patterns with the exception of sharp initial increases in helium observed in the rivers. Increased longitudinal groundwater discharge rates correspond to mapped geologic structures in both watersheds that likely transport deep geothermal water. Models show variable sensitivity to spatial assignment of input variables representing the groundwater source, illustrating the importance of collecting data from discrete groundwater discharges where possible. The methodology shows promise for field experiments designed to assess air–water exchange rates and to quantify total groundwater discharge from a combination of discrete and diffuse sources.

Colorado, Utah

Status and understanding of groundwater quality in the Mojave Basin Domestic-Supply Aquifer study unit, 2018—California GAMA Priority Basin Project

Groundwater quality in the western part of the Mojave Desert in San Bernardino County, California, was investigated in 2018 as part of the California State Water Resources Control Board Groundwater Ambient Monitoring and Assessment Program Priority Basin Project. The Mojave Basin Domestic-Supply Aquifer study unit (MOBS) region was divided into two study areas—floodplain and regional—to assess differences between the two major aquifers used for drinking water supply in the area. This assessment characterized the quality of ambient groundwater and not the quality of treated drinking water. The study included three components: (1) a status assessment, which characterized the quality of groundwater resources used for domestic drinking-water supply in the floodplain and regional study areas; (2) a brief understanding assessment, which evaluated factors that could potentially affect the quality of groundwater used by domestic wells in the region; and (3) a comparative assessment between the groundwater resources used by domestic wells and public-supply wells in the two study areas. The domestic-well assessment was based on data collected by the U.S. Geological Survey from 48 domestic wells in January–May 2018. The public-supply assessment was based on data for samples from 322 public-supply wells in 2008–18, either collected by the U.S. Geological Survey or compiled from the California State Water Resources Control Boards Division of Drinking Water publicly available database. Concentrations of water-quality constituents in ambient groundwater were compared to regulatory and non-regulatory benchmarks typically used by the State of California and Federal agencies as health-based or aesthetic standards for public drinking water. Relative concentrations, defined as the measured concentration divided by the benchmark concentration, were classified as high (greater than 1.0), moderate (greater than 0.5 for inorganic constituents or 0.1 for organic and special-interest constituents, and not high), or low (concentrations lower than moderate). The floodplain and regional study areas were divided into 15 and 35 grid cells, respectively, and grid-based methods were used to compute the areal proportions of the two study areas with high, moderate, or low relative concentrations of individual constituents and classes of constituents. For the domestic-supply assessment, one or more inorganic constituents with health-based benchmarks were detected at high relative concentrations in 58 percent of the regional study area and 13 percent of the floodplain study area. The inorganic constituents with health-based benchmarks detected at high relative concentrations in the regional study area were arsenic, chromium and hexavalent chromium, fluoride, adjusted gross alpha particle activity, uranium, molybdenum, strontium, and nitrate; only arsenic was detected at high relative concentrations in the floodplain study area. One or more inorganic constituents with secondary maximum contaminant level benchmarks were detected at high concentrations in 15 and 6.7 percent of the regional and floodplain study areas, respectively. The constituents detected at high relative concentrations in the regional study area were total dissolved solids, chloride, sulfate, and iron; only total dissolved solids and sulfate were detected at high relative concentrations in the floodplain study area. Organic constituents were not detected at moderate or high relative concentrations in either the regional or floodplain study areas. Volatile organic compounds were detected at low relative concentrations in 21 and 27 percent of the regional and floodplain study areas, respectively, and pesticides were detected at low relative concentrations in 9.1 and 20 percent of the regional and floodplain study areas, respectively. The only individual organic constituent detected in more than 10 percent of either study area was the trihalomethane trichloromethane. Total coliform bacteria were detected in 15 and 27 percent of the grid wells in the regional and floodplain study areas, respectively. The greater prevalence of high relative concentrations of many inorganic constituents in the regional study area compared to the floodplain area likely indicates the greater diversity of geologic material at depth in aquifer material and generally finer-grained alluvium compared to the floodplain study area combined with generally older groundwater that has had more contact time with aquifer materials. In general, trace element concentrations (1) increased with increasing groundwater age, (2) increased with distance from recharge sources in the mountains, and (3) increased with closer proximity to some types of geological units. In general, groundwater from domestic wells in the floodplain study area is young, with most samples containing a component of modern groundwater based on tritium and unadjusted carbon-14 activities, whereas groundwater from domestic wells in the regional study area generally is old, with most samples having unadjusted carbon-14 ages of 5,000–40,000 years. Public-supply wells in MOBS generally were deeper than domestic wells and presumably are in contact with older, more weathered alluvium that may have more mobile trace elements, such as arsenic or uranium. However, only 26 percent of the public-supply regional study area had high relative concentrations of inorganic constituents, compared to 58 percent for the domestic regional study area. The percentages of the public-supply and domestic floodplain study areas with high relative concentrations of inorganic constituents were 11 and 13 percent, respectively. The ages of groundwater used by public-supply and domestic wells in each study area were similar, which was not expected given the greater depth of the public-supply wells. Three potential factors may contribute to these results: (1) greater spatial footprint of domestic well network, which may result in domestic wells pumping groundwater from fractured bedrock or mineralized areas not used by public-supply wells; (2) greater pumping rates in public-supply wells, resulting in more water being withdrawn from coarse-grained, heterogeneous alluvium than finer-grained layers, which may have higher concentrations of (or more mobile) inorganic constituents; and (3) a greater degree of well management with public-supply wells, which may include pausing use of or decommissioning wells if treating or blending water is not feasible to lower constituent concentrations.

California

Biodegradation of chlorinated ethenes at a karst site in middle Tennessee

This report presents results of field and laboratory investigations examining the biodegradation of chlorinated ethenes in a karst aquifer contaminated with trichloroethylene (TCE). The study site, located in Middle Tennessee, was selected because of the presence of TCE degradation byproducts in the karst aquifer and available site hydrologic and chlorinated-ethene information. Additional chemical, biological, and hydrologic data were gathered to evaluate whether the occurrence of TCE degradation byproducts in the karst aquifer was the result of biodegradation within the aquifer or simply transport into the aquifer. Geochemical analysis established that sulfate-reducing conditions, essential for reductive dechlorination of chlorinated solvents, existed in parts of the contaminated karst aquifer. Other areas of the aquifer fluctuated between anaerobic and aerobic conditions and contained compounds associated with cometabolism, such as ethane, methane, ammonia, and dissolved oxygen. A large, diverse bacteria population inhabits the contaminated aquifer. Bacteria known to biodegrade TCE and other chlorinated solvents, such as sulfate-reducers, methanotrophs, and ammonia-oxidizers, were identified from karst-aquifer water using the RNA-hybridization technique. Results from microcosms using raw karst-aquifer water found that aerobic cometabolism and anaerobic reductive-dechlorination degradation processes were possible when appropriate conditions were established in the microcosms. These chemical and biological results provide circumstantial evidence that several biodegradation processes are active in the aquifer. Additional site hydrologic information was developed to determine if appropriate conditions persist long enough in the karst aquifer for these biodegradation processes to be significant. Continuous monitoring devices placed in four wells during the spring of 1998 indicated that pH, specific conductance, dissolved oxygen, and oxidation-reduction potentials changed very little in areas isolated from active ground-water flow paths. These stable areas in the karst aquifer had geochemical conditions and bacteria conducive to reductive dechlorination of chlorinated ethenes. Other areas of the karst aquifer were associated with active ground-water flow paths and fluctuated between anaerobic and aerobic conditions in response to rain events. Associated with this dynamic environment were bacteria and geochemical conditions conducive to cometabolism. In summary, multiple lines of evidence developed from chemical, biological, and hydrologic data demonstrate that a variety of biodegradation processes are active in this karst aquifer.

Tennessee

Insights into widespread landsliding in southern Appalachia from Hurricane Helene

Between 23 and 27 September 2024, antecedent rain followed by Hurricane Helene produced one of the most damaging weather events in southern Appalachia history. The back-to-back storm events resulted in a maximum cumulative rainfall of 848 mm and hurricane-force wind gusts over 170 km/h in western North Carolina, eastern Tennessee, and southwestern Virginia. The resulting regional flooding, landslides, and tree blowdown caused over 100 fatalities, damaged or destroyed critical infrastructure and thousands of structures, and severed connectivity across the region. Over the next several weeks, a multi-agency landslide response produced a rapid hazard assessment and mapped 2217 landslides, 55% of which damaged infrastructure or property. Orographic uplift enhanced rainfall, resulting in concentrated landsliding along the ~250 km swath of the Blue Ridge escarpment in western North Carolina. Landslides initiated predominantly on windward-facing (southeast-facing) slopes, and localized clustering of initiation points indicated a strong influence of hillslope-scale meteorological and geomorphic factors. Many shallow landslides mobilized into larger, highly mobile, and damaging debris flows that graded into floods. Here, we put our preliminary observations in the context of historical storm-driven landslide events and open new avenues for investigating the nature and extent of landslides and their effects in southern Appalachia and similar environments.

Georgia, North Carolina, South Carolina, Tennessee

Altitude of the potentiometric surface and depth to water in the Mississippi River Valley alluvial aquifer, spring 2024

Potentiometric-surface and depth-to-water maps for spring 2024 were created for the Mississippi River Valley alluvial aquifer using groundwater-altitude data from 1,151 wells completed in the Mississippi River Valley alluvial aquifer and from the altitude of the top of the water surface in area rivers from 160 U.S. Geological Survey and U.S. Army Corps of Engineers streamgages. The potentiometric-surface and depth-to-water maps for 2024 were created to support investigations to characterize the Mississippi River Valley alluvial aquifer as part of the U.S. Geological Survey Water Availability and Use Science Program. Sufficient data were available to map the potentiometric surface and depth to water of the Mississippi River Valley alluvial aquifer for spring 2024 for about 83 percent of the aquifer area. The potentiometric contours ranged from 0 to 330 feet (ft) above the North American Vertical Datum of 1988. The regional direction of the groundwater gradient was generally to the south-southwest, except in areas of groundwater-altitude depressions, where the groundwater gradient direction was into the depression, and near rivers, where the groundwater gradient direction was either from the aquifer to the river or from the river into the aquifer. Groundwater depressions in the potentiometric-surface map are in the lower one-half of the Cache region and in most of the Grand Prairie and Delta regions. Depth to water by well in the Mississippi River Valley alluvial aquifer in spring 2024 ranged from 0.27 ft above land surface to 145.65 ft below land surface.

Arkansas, Illinois, Kentucky, Louisiana, Mississip

Enhanced microplastic fragmentation along human built structures in an urban waterway

Plastic pollution and microplastic (MP, 1 µm to 5 mm) generation are growing problems affecting the global community and a wide range of natural and disturbed environments. Urban and suburban waterways are directly impacted by plastic pollution due to their proximity to population centers and many different types single use plastic waste sources. In this study, plastic waste accumulation and fragmentation was investigated along the Cooper River in Camden County, NJ. Polymer composition was identified for individual plastic waste particles collected along the Cooper River using Fourier transform infrared (FTIR) spectrometry. Multiple human-built structures (Wallworth Lake, Evans Pond and Hopkins Pond dams) along the Cooper River were found to accumulate different types of plastic waste. The accumulation of plastic waste along these structures resulted in the initial stages of plastic fragmentation and the identification of large MP particles (1 to 5 mm). Quantitative analysis revealed that fragmented polystyrene (PS) particles constituted 82.8% of the total plastic fragments identified, most of which were identified at the Wallworth Lake dam. Many other types of fragmented plastic litter, including polyethylene and polypropylene, were identified at the Wallworth Lake dam, as well. This research demonstrates that engineered structures within urban and suburban aquatic ecosystems serve as significant aggregators of plastic debris, thereby catalyzing its breakdown into microplastics. Considering the escalating ecological and human health ramifications of microplastic proliferation, the fragmentation of plastic waste in an urban and suburban waterway observed in this study can also result in potentially toxic smaller MP particles, and increased exposure to aquatic organisms and humans.

New Jersey