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At least 415 records · Page 23Linked to original sources
USGS2003

Brittle structures and their role in controlling porosity and permeability in a complex Precambrian crystalline-rock aquifer system in the Colorado Rocky Mountain front range

Expansion of the Denver metropolitan area has resulted in substantial residential development in the foothills of the Rocky Mountain Front Range. This type of sub-urban growth, characteristic of much of the semiarid intermountain west, often relies on groundwater from individual domestic wells and is exemplified in the Turkey Creek watershed. The watershed is underlain by complexly deformed and fractured crystalline bedrock in which groundwater resources are poorly understood, and concerns regarding groundwater mining and degradation have arisen. As part of a pilot project to establish quantitative bounds on the groundwater resource, an outcrop-based geologic characterization and numerical modeling study of the brittle structures and their controls on the flow system was initiated. Existing data suggest that ground-water storage, flow, and contaminant transport are primarily controlled by a heterogeneous array of fracture networks. Inspections of well-permit data and field observations led to a conceptual model in which three dominant lithologic groups underlying sparse surface deposits form the aquifer system-metamorphic rocks, a complex array of granitic intrusive rocks, and major brittle fault zones. Pervasive but variable jointing of each lithologic group forms the "background" permeability structure and is an important component of the bulk storage capacity. This "background" is cut by brittle fault zones of varying structural styles and by pegmatite dikes, both with much higher fracture intensities relative to "background" that likely make them spatially complex conduits. Probabilistic, discrete-fracture-network and finite-element modeling was used to estimate porosity and permeability at the outcrop scale using fracture network data collected in the field. The models were conditioned to limited aquifer test and borehole geophysical data and give insight into the relative hydraulic properties between locations and geologic controls on storage and flow. Results from this study reveal a complex aquifer system in which the upper limits on estimated hydraulic properties suggest limited storage capacity and permeability as compared with many sedimentary-rock and surficial-deposit aquifers.

Geological Society of America Bulletin↗
USGS2006

Sedimentary textures formed by aqueous processes, Erebus crater Meridiani Planum, Mars

New observations at Erebus crater (Olympia outcrop) by the Mars Exploration Rover Opportunity between sols 671 and 735 (a sol is a martian day) indicate that a diverse suite of primary and penecontemporaneous sedimentary structures is preserved in sulfate-rich bedrock. Centimeter-scale trough (festoon) cross-lamination is abundant, and is better expressed and thicker than previously described examples. Postdepositional shrinkage cracks in the same outcrop are interpreted to have formed in response to desiccation. Considered collectively, this suite of sedimentary structures provides strong support for the involvement of liquid water during accumulation of sedimentary rocks at Meridiani Planum.

Geology↗
USGS2014

Widespread loess-like deposit in the Martian northern lowlands identifies Middle Amazonian climate change

Consistently mappable units critical to distinguishing the style and interplay of geologic processes through time are sparse in the Martian lowlands. This study identifies a previously unmapped Middle Amazonian (ca. 1 Ga) unit (Middle Amazonian lowland unit, mAl) that postdates the Late Hesperian and Early Amazonian lowland plains by >2 b.y. The unit is regionally defined by subtle marginal scarps and slopes, has a mean thickness of 32 m, and extends >3.1 × 10 6 km 2 between lat 35°N and 80°N. Pedestal-type craterforms and nested, arcuate ridges (thumbprint terrain) tend to occur adjacent to unit mAl outcrops, suggesting that current outcrops are vestiges of a more extensive deposit that previously covered ∼16 × 10 6 km 2 . Exposed layers, surface pits, and the draping of subjacent landforms allude to a sedimentary origin, perhaps as a loess-like deposit emplaced rhythmically through atmospheric fallout. We propose that unit mAl accumulated coevally with, and at the expense of, the erosion of the north polar basal units, identifying a major episode of Middle Amazonian climate-driven sedimentation in the lowlands. This work links ancient sedimentary processes to climate change that occurred well before those implied by current orbital and spin axis models.

Geology↗
USGS2014

Sub-decadal turbidite frequency during the early Holocene: Eel Fan, offshore northern California

Remotely operated and autonomous underwater vehicle technologies were used to image and sample exceptional deep sea outcrops where an ∼100-m-thick section of turbidite beds is exposed on the headwalls of two giant submarine scours on Eel submarine fan, offshore northern California (USA). These outcrops provide a rare opportunity to connect young deep-sea turbidites with their feeder system. 14 C measurements reveal that from 12.8 ka to 7.9 ka, one turbidite was being emplaced on average every 7 yr. This emplacement rate is two to three orders of magnitude higher than observed for turbidites elsewhere along the Pacific margin of North America. The turbidites contain abundant wood and shallow-dwelling foraminifera, demonstrating an efficient connection between the Eel River source and the Eel Fan sink. Turbidite recurrence intervals diminish fivefold to ∼36 yr from 7.9 ka onward, reflecting sea-level rise and re-routing of Eel River sediments.

Geology Today↗
USGS2019

Post-12 Ma deformation of the lower Colorado River corridor, southwestern USA: Implications for diffuse transtension and the Bouse Formation

Structural evidence presented here documents that deformation was ongoing within the lower Colorado River corridor (southwestern USA) during and after the latest Miocene Epoch, postdating large-magnitude extension and metamorphic core complex formation. Geometric and kinematic data collected on faults in key geologic units constrain the timing of deformation in relation to the age of the Bouse Formation, a unit that records the first arrival and integration of the Colorado River. North-south–striking extensional, NW-SE–striking oblique dextral, NE-SW–striking oblique sinistral, and east-west–striking contractional faults and related structures are observed to deform pre– (>6 Ma), syn– (6–4.8 Ma), and post–Bouse Formation (<4.8 Ma) strata. Fault displacements are typically at the centimeter to meter scale, and locally exhibit 10-m-scale displacements. Bouse Formation basalt carbonate locally exhibits outcrop-scale (tens of meters) syndepositional dips of 30°–90°, draped over and encrusted upon paleotopography, and has a basin-wide vertical distribution of as much as 500 m. We argue that part of this vertical distribution of Bouse Formation deposits represents syn- and post-Bouse deformation that enhanced north-south–trending depocenters due to combined tectonic and isostatic subsidence in a regional fault kinematic framework of east-west diffuse extension within an overall strain field of dextral transtension. Here we (1) characterize post-detachment tectonism within the corridor, (2) show that diffuse tectonism is cumulatively significant and likely modified original elevations of Bouse Formation outcrops, and (3) demonstrate that this tectonism may have played a role in the integration history of the lower Colorado River. We suggest a model whereby intracontinental transtension took place in a several hundred kilometers-wide area inboard of the San Andreas fault within a diffuse Pacific–North America plate margin since the latest Miocene.

Arizona, California, Nevada↗
USGS1991

Upper Devonian biostratigraphy of Michigan Basin

The Late Devonian Michigan Basin was floored by the Middle and Upper Devonian Squaw Bay Limestone, which was deposited during the downwarping that produced the basin within a former Middle Devonian carbonate platform. The Squaw Bay comprises three beds, each having a different conodont fauna. The two upper beds, deposited during the transitans Zone, have different conodont biofacies that reflect this deepening. The basin was largely filled by the deep-water, anaerobic to dysaerobic, organic-rich, black Antrim Shale, which has a facies relationship with the prodeltaic, greenish gray Ellsworth Shale that prograded into the basin from the west. The Upper Devonian (Frasnian to Famennian) Antrim Shale is divided into four members, from base to top: the Norwood, Paxton, Lachine, and upper members. These members are more or less precisely dated by conodonts. The Norwood was deposited during the transitans Zone to Ancyrognathus triangularis Zone, and the Paxton was deposited from that zone probably through the linguiformis Zone at the end of the Frasnian. The overlying Lachine was deposited during the early Famennian and has yielded faunas of the Upper crepida and Lower rhomboidea Zones. Only the lower part of the upper member is exposed, and near Norwood, Michigan, it yielded conodonts of the Lower marginifera Zone. The widespread Famennian floating plant Protosalvinia (Foerstia) has not yet been found in outcrops of the Antrim, and should not be expected to occur except in the upper member or highest part of the Lachine Member. Its range in terms of conodont zones is from the Upper trachytera Zone through the Lower expansa Zone and possibly into the Middle expansa Zone. One known subsurface occurrence might be datable as rhomboidea or Lower marginifera Zone, depending on gamma ray correlations to outcrops. Black shale deposition ended when the Late Devonian mud delta of the Bedford Shale prograded across the Michigan Basin from the east and then retreated as the regressive Berea Sandstone was being deposited during the major eustatic sea-level fall that ended the Devonian. The Bedford was deposited during the Upper expansa to Lower praesulcata Zones, and the Berea was deposited during the Middle to Upper praesulcata Zones. Both formations contain the spore Retispora lepidophyta, which is a global indicator of latest Devonian age.

Michigan↗
USGS1994

Deep structure beneath Lake Ontario: Crustal-scale Grenville subdivisions

Lake Ontario marine seismic data reveal major Grenville crustal subdivisions beneath central and southern Lake Ontario separated by interpreted shear zones that extend to the lower crust. A shear zone bounded transition between the Elzevir and Frontenac terranes exposed north of Lake Ontario is linked to a seismically defined shear zone beneath central Lake Ontario by prominent aeromagnetic and gravity anomalies, easterly dipping wide-angle reflections, and fractures in Paleozoic strata. We suggest the central Lake Ontario zone represents crustal-scale deformation along an Elzevir&ndash;Frontenac boundary zone that extends from outcrop to the south shore of Lake Ontario.Seismic images from Lake Ontario and the exposed western Central Metasedimentary Belt are dominated by crustal-scale shear zones and reflection geometries featuring arcuate reflections truncated at their bases by apparent east-dipping linear reflections. The images show that zones analogous to the interpreted Grenville Front Tectonic Zone are also present within the Central Metasedimentary Belt and support models of northwest-directed crustal shortening for Grenvillian deep crustal deformation beneath most of southeastern Ontario.A Precambrian basement high, the Iroquoian high, is defined by a thinning of generally horizontal Paleozoic strata over a crestal area above the basement shear zone beneath central Lake Ontario. The Iroquoian high helps explain the peninsular extension into Lake Ontario forming Prince Edward County, the occurrence of Precambrian inlier outcrops in Prince Edward County, and Paleozoic fractures forming the Clarendon&ndash;Linden structure in New York.

Lake Ontario↗
USGS1976

Gravity and magnetic fields of polygonal prisms and application to magnetic terrain corrections

Computer programs based on the exact calculations of the gravity and magnetic anomalies of polygonal prisms are faster in operation and more accurate than previous programs based on the numerical integration of polygonal laminas. The prism programs also are of more general application than existing computer programs that are based on the exact gravity and magnetic effects of rectangular prisms. There are no restrictions on the use of the exact formula for the gravitational attraction of a polygonal prism, but the formulas for the magnetic effect are restricted in that demagnetization is not considered, and a finite answer is not obtained in the unrealistic circumstance where an observation point coincides with an edge of the prism.Least-squares methods permit calculation of the gravity or magnetic effect of models without knowledge of the density or magnetization contrasts, respectively, by comparison of the observed anomalies with theoretical dimensionless values to determine contrasts as regression coefficients. The coefficient of correlation provides a goodness of fit estimate that helps model evaluation. After calculating a magnetic terrain correction for an outcrop of Quaternary dacite and andestite near Clear Lake, Calif., an improvement of the coefficient of correlation from 88 to the 92 percent level indicates that this volcanic unit probably extends at least 150 m beneath the surface. Application of a magnetic terrain correction to disconnected outcrops of Tertiary andesite, eliminates most of a prominent v-shaped magnetic anomaly south of the San Juan Mountains, Colo.

Arizona↗
USGS2020

Surface to subsurface correlation of the Middle-Upper Triassic Shublik Formation within a revised sequence stratigraphic framework

Recent work on cores and outcrops of the Middle-Upper Triassic Shublik Formation has facilitated surface to subsurface correlation of depositional sequences across the Alaska North Slope. Five transgressive-regressive depositional sequences have been defined within three large-scale stratigraphic units. Outcrop spectral gamma-ray (GR) profiles were used to correlate observed stacking patterns with nearby exploration wells, and GR logs from 161 exploration wells were used to correlate the three large-scale stratigraphic units across the North Slope and nearby offshore. Interpretations of depositional facies and sequence stratigraphy in cores from 26 wells were used to corroborate regional correlations. Isochore maps constructed for each of the three stratigraphic units illustrate the influence of accommodation on depositional patterns and suggest reactivation of several older tectonic elements during Shublik deposition. An isochore map of the richest, oil-prone interval of the Shublik Formation reveals a thick pod south of Harrison Bay, the eastern part of which lies beneath a recent giant Shublik-sourced oil discovery in the Cretaceous Nanushuk Formation. In addition, when integrated with thermal maturity, this isochore map may provide leads for areas that are optimal for unconventional resource exploration.

Alaska↗
USGS2003

Tidal-bundle sequences in the Jordan Sandstone (Upper Cambrian), southeastern Minnesota, U.S.A.: Evidence for tides along inboard shorelines of the Sauk Epicontinental Sea

This study documents for the first time tidal bundling in a lower Paleozoic sheet sandstone from the cratonic interior of North America, providing insights into the hydrodynamics of ancient epicontinental seas. The Jordan Sandstone (Upper Cambrian) in the Upper Mississippi Valley contains large-scale planar tabular cross-sets with tidal-bundle sequences, which were analyzed in detail at an exceptional exposure. Tidal-bundle sequences (neap-spring-neap cycles) were delineated by foreset thickening-thinning patterns and composite shale drapes, the latter of which represent accumulations of mud during the neap tides of neap-spring-neap tidal cycles. Fourier analysis of the bundle thickness data from the 26 measurable bundle sequences revealed cycles ranging from 15 to 34 bundles per sequence, which suggests a semidiurnal or mixed tidal system along this part of the Late Cambrian shoreline. We extend the tidal interpretation to widespread occurrences of the same facies in outcrops of lesser quality, where the facies is recognizable but too few bundles are exposed for tidal cycles to be measured. By doing so, this study shows that tidally generated deposits have a significant geographic and temporal extent in Upper Cambrian strata of central mid-continent North America. The deposition and preservation of tidal facies was related to the intermittent development of shoreline embayments during transgressions. The tidally dominated deposits filled ravined topographies that were repeatedly developed on the updip parts of the shoreface. Resulting coastal geomorphologies, accompanied perhaps by larger-scale changes in basinal conditions and/or configuration, led to changes in depositional conditions from wave-dominated to tide-dominated. Outcrops of the Jordan Sandstone tidal facies in the Upper Mississippi Valley represent the farthest inboard recorded transmission of ocean-generated tides in the Laurentian epicontinental seas, demonstrating that tidal currents were significant agents in the transport of sand along the far cratonic interior shorelines of Cambrian North America. The results of this study improve the facies-level understanding of the genesis of sheet sandstones. Furthermore, tidalites documented here occur in a specific position within a sequence stratigraphic architecture for the Jordan Sandstone. This provides a framework to compare these ancient deposits and processes to younger (e.g., Carboniferous) epicontinental systems where stratal and sediment dynamics are better documented.

Illinois, Indiana, Iowa, Michigan, Minnesota, Miss↗
USGS2012

Ordovician of the Sauk megasequence in the Ozark region of northern Arkansas and parts of Missouri and adjacent states

Exposures of Ordovician rocks of the Sauk megasequence in Missouri and northern Arkansas comprise Ibexian and lower Whiterockian carbonates with interspersed sandstones. Subjacent Cambrian strata are exposed in Missouri but confined to the subsurface in Arkansas. The Sauk-Tippecanoe boundary in this region is at the base of the St. Peter Sandstone. Ulrich and associates divided the Arkansas section into formations early in the 20th century, principally based on sparse collections of fossil invertebrates. In contrast, the distribution of invertebrate faunas and modern studies of conodonts will be emphasized throughout this chapter. Early workers considered many of the stratigraphic units to be separated by unconformities, but modern analysis calls into question the unconformable nature of some of their boundaries. The physical similarity of the several dolomites and sandstones, complex facies relations, and lack of continuous exposures make identification of individual formations difficult in isolated outcrops. The oldest formation that crops out in the region is the Jefferson City Dolomite, which may be present in outcrops along incised river valleys near the Missouri-Arkansas border. Rare fossil gastropods, bivalves, brachiopods, conodonts, and trilobites permit correlation of the Cotter through Powell Dolomites with Ibexian strata elsewhere in Laurentia. Conodonts in the Black Rock Limestone Member of the Smithville Formation and the upper part of the Powell Dolomite confirm regional relationships that have been suggested for these units; those of the Black Rock Limestone Member are consistent with deposition under more open marine conditions than existed when older and younger units were forming. Brachiopods and conodonts from the overlying Everton Formation assist in interpreting complex facies within that formation and its correlation to equivalent rocks elsewhere. The youngest conodonts in the Everton Formation provide an age limit for the Sauk-Tippecanoe unconformity near the southern extremity of the great American carbonate bank. The correlation to coeval strata in the Ouachita Mountains of central Arkansas and in the Arbuckle Mountains of Oklahoma and to rocks penetrated in wells drilled in the Reelfoot rift basin has been improved greatly in recent years by integration of biostratigraphic data with lithologic information.

Arkansas, Missouri↗
USGS1987

Formation of scalloped cross-bedding without unsteady flows

Scalloped cross-bedding --compound cross-bedding with internal bounding surfaces that cyclically scoop into the previously deposited foresets and into the sediment below the set--is a common and distinctive structure in eolian, fluvial, tidal, and nearshore-marine sands. Scalloped cross-bedding in shallow-marine deposits previously has been interpreted to be produced by cyclic flows, such as neap-spring tidal flows, which are known to cause cyclic fluctuations in the depth of scour in the troughs of migrating bedforms, but scalloped cross-bedding also originates by a process that does not require fluctuating flow: migration of small bedforms across the lee slopes or along the troughs of larger bedforms. Intersections of the troughs of the two sets of bedforms form topographically low scour pits, and cyclic passage of these scour pits through the outcrop plane--the plane that later becomes an outcrop surface--causes the lower-set boundary to rise and fall. Scalloped cross-bedding formed by fluctuating flow superficially resembles that formed by superimposed or intersecting bedforms, but, as illustrated in three-dimensional computer plots, the two kinds of structures commonly can be distinguished by directional properties of the bedding. Scallops deposited by alongslope-migrating, superimposed bedforms have cross-bed and bounding-surface dip patterns that lack bilateral symmetry and have cross-bed dips that are asymmetrically distributed relative to bounding-surface dips. Scallops with dip patterns that are bilaterally symmetrical and with cross-bed dips that are symmetrically distributed relative to the bounding-surface dips can be produced either by fluctuating flow or by downslope or upslope migration of superimposed bedforms. An example of nearshore-marine scalloped cross-bedding of Pleistocene age was examined in detail in a coastal terrace of Monterey Bay, California. The three-dimensional structure and directional properties of the bedding suggest that the deposit was produced by a series of small bedforms migrating offshore, down a rip channel that was bounded on one side by a migrating oblique bar.

Journal of Sedimentary Petrology↗
USGS1975

Stratigraphy of Atlantic coastal margin of United States north of Cape Hatteras: Brief survey

A synthesis of studies of sea-floor outcrops of the sedimentary wedge beneath the northeastern United States continental shelf and slope and a reassessment of coastal plain Mesozoic stratigraphy, particularly of the coastal margin, provide insight for estimating the oil and gas potential and provide geologic control for marine seismic investigations of the Atlantic continental margin. The oldest strata known to crop out on the continental slope are late Campanian in age. The Cretaceous-Tertiary contact along the slope ranges from a water depth of 0.6 to 1.5 km south of Georges Bank to 1.8 km in Hudson Canyon. Few samples are available from Tertiary and Late Cretaceous outcrops along the slope. Sediments of the Potomac Group, chiefly of Early Cretaceous age, constitute a major deltaic sequence in the emerged coastal plain. This thick sequence lies under coastal Virginia, Maryland, Delaware, southeastern New Jersey, and the adjacent continental shelf. Marine sands associated with this deltaic sequence may be present seaward under the outer continental shelf. South of the Norfolk arch, under coastal North Carolina, carbonate rocks interfinger with Lower Cretaceous clastic strata. From all available data, Mesozoic correlations in coastal wells between coastal Virginia and Long Island have been revised. The Upper-Lower Cretaceous boundary is placed at the transition between Albian and Cenomanian floras. Potential hydrocarbon source beds are present along the coast in the subsurface sediments of Cretaceous age. Potential reservoir sandstones are abundant in this sequence.

Atlantic coastal plain↗
USGS2007

Geologic and anthropogenic factors influencing karst development in the Frederick region of Maryland

Karst features pervade the outcrop belts of Triassic, Ordovician, and Cambrian rocks in the Frederick Valley region of Maryland's western Piedmont. Detailed stratigraphic analysis and geologic and karst mapping demonstrate that individual stratigraphic units have differing susceptibilities of karst feature creation. Although the Triassic Leesburg Member of the Bull Run Formation and Rocky Springs Station Member of the Cambrian Frederick Formation have many surface depressions within their outcrop belts, the Lime Kiln Member of the Frederick Formation and the Ceresville, Fountain Rock, and Woodsboro members of the Ordovician Grove Formation have the greatest potential for development of catastrophic collapse sinkholes. Although these four members have the highest relative susceptibility, human activity can increase the potential for sinkhole activation in all units. Rerouting of surface drainage patterns, unlined drainage, and storm-water management areas and removal of significant overburden deposits significantly increase sinkhole development, but mainly, these units are inherently more susceptible to begin with. Copyright ?? 2007. The American Association of Petroleum Geologists/Division of Environmental Geosciences. All rights reserved.

Environmental Geosciences↗
USGS2009

Characterization of the Helderberg Group as a geologic seal for CO 2 sequestration

The Midwest Regional Carbon Sequestration Partnership recognizes that both the Devonian Oriskany Sandstone and the Silurian Salina Group offer potential for subsurface carbon dioxide storage in northern West Virginia. The Silurian-Devonian Helderberg Group lies stratigraphically between these two units, and consequendy, its potential as a geologic seal must be evaluated. Predominantly a carbonate interval with minor interbedded siliciclastics and chert, the Helderberg Group was deposited in an ancient epeiric sea. Although most previous investigations of this unit have concentrated on outcrops in eastern West Virginia, new information is available from an injection well drilled along the Ohio River at First Energy's R. E. Burger electric power plant near Shadyside, Ohio. Geophysical, seismic, and core data from this well have been combined with existing outcrop information to evaluate the Helderberg Group's potential as a seal. The data collected suggest that only secondary porosity remains, and permeability, if it exists, most likely occurs along faults or within fractures. ?? 2009. The American Association of Petroleum Geologists/Division of Environmental Geosciences. All rights reserved.

Environmental Geosciences↗
USGS2009

Reservoir uncertainty, Precambrian topography, and carbon sequestration in the Mt. Simon Sandstone, Illinois Basin

Sequestration sites are evaluated by studying the local geological structure and confirming the presence of both a reservoir facies and an impermeable seal not breached by significant faulting. The Cambrian Mt. Simon Sandstone is a blanket sandstone that underlies large parts of Midwest United States and is this region's most significant carbon sequestration reservoir. An assessment of the geological structure of any Mt. Simon sequestration site must also include knowledge of the paleotopography prior to deposition. Understanding Precambrian paleotopography is critical in estimating reservoir thickness and quality. Regional outcrop and borehole mapping of the Mt. Simon in conjunction with mapping seismic reflection data can facilitate the prediction of basement highs. Any potential site must, at the minimum, have seismic reflection data, calibrated with drill-hole information, to evaluate the presence of Precambrian topography and alleviate some of the uncertainty surrounding the thickness or possible absence of the Mt. Simon at a particular sequestration site. The Mt. Simon is thought to commonly overlie Precambrian basement granitic or rhyolitic rocks. In places, at least about 549 m (1800 ft) of topographic relief on the top of the basement surface prior to Mt. Simon deposition was observed. The Mt. Simon reservoir sandstone is thin or not present where basement is topographically high, whereas the low areas can have thick Mt. Simon. The paleotopography on the basement and its correlation to Mt. Simon thickness have been observed at both outcrops and in the subsurface from the states of Illinois, Ohio, Wisconsin, and Missouri. ?? 2009. The American Association of Petroleum Geologists/Division of Environmental Geosciences. All rights reserved.

Environmental Geosciences↗
USGS2016

Reconnaissance stratigraphy of the Red Glacier Formation (Middle Jurassic) near Hungryman Creek, Cook Inlet basin, Alaska

Geochemical data suggest the source of oil in upper Cook Inlet fields is Middle Jurassic organic-rich shales in the Tuxedni Group (Magoon and Anders, 1992; Lillis and Stanley, 2011; LePain and others, 2012, 2013). Of the six formations in the group (Detterman, 1963), the basal Red Glacier Formation is the only unit that includes fine-grained rocks in outcrop that appear to be organic-rich (fig. 3-1). In an effort to better understand the stratigraphy and source-rock potential of the Red Glacier Formation, the Alaska Division of Geological & Geophysical Surveys, in collaboration with the Alaska Division of Oil and Gas and the U.S. Geological Survey, has been investigating the unit in outcrop between Tuxedni Bay and the type section at Lateral and Red glaciers (Stanley and others, 2013; LePain and Stanley, 2015; Helmold and others, 2016 [this volume]). Fieldwork in 2015 focused on a southeast-trending ridge south of Hungryman Creek, where the lower 60–70 percent of the formation (400–500 m) is exposed and accessible, except for the near-vertical faces of three segments near the southeast end of the ridge (figs. 3-2 and 3-3). Three stratigraphic sections were measured along the ridge to document facies and depositional environments (figs. 3-3 and 3-4). Steep terrain precluded study of the upper part of the formation exposed east of the ridge. This report includes a preliminary summary of findings from the 2015 field season.

Alaska↗
USGS2019

Variability in results from mineralogical and organic geochemical interlaboratory testing of U. S. Geological Survey shale reference materials

The expansion of unconventional petroleum resource exploration and production in the United States has led to an increase in source rock characterization efforts, particularly related to bulk organic and mineralogical properties. To support the analytical and research needs of industry and academia, as well as internal work, the U.S. Geological Survey (USGS) has collected and prepared shale geochemical reference materials (GRMs) from several major shale petroleum systems in the U.S. The sources of these materials are the Late Cretaceous Boquillas (lower Eagle Ford-equivalent) Formation (roadcut near Del Rio, TX), Late Cretaceous Mancos Shale (outcrop near Delta, CO), Devonian–Mississippian Woodford Shale (outcrop near Ardmore, OK), Late Cretaceous Niobrara Formation (quarry near Lyons, CO), Middle Devonian Marcellus Shale (creek bed in LeRoy, NY), and Eocene Mahogany zone oil shale of the Green River Formation (oil shale mine near Rifle, CO). Of particular interest in the development of these GRMs has been the examination of variability between laboratories and specific methods or instruments in commonly made measurements, including major- and trace-element concentrations, X-ray diffraction (XRD) mineralogy, total organic carbon (TOC) content, and programmed pyrolysis (PP) parameters. For the component concentrations and parameters we measured, the techniques and instrument types included: (1) elemental analysis by X-ray fluorescence, inductively coupled plasma mass spectrometry, and instrumental neutron activation analysis; (2) XRD mineralogy with various preparatory methods (spray drying or micronizing with or without internal standard); (3) TOC by combustion with infrared detection after carbonate removal or the PP approach; (4) PP by Rock-Eval 2 or more recently developed instruments (Rock-Eval 6, Source Rock Analyzer or SRA, and Hydrocarbon Analyzer With Kinetics or HAWK). Overall, the results showed that the selected shales cover a wide range of source rock organic and mineralogical properties. Major- and trace-element chemistry results showed low heterogeneity consistent with other USGS GRMs. Comparison of TOC results showed coefficients of variation (COV) of around 5% and the most consistent organic geochemical results between different laboratories and methods. Arguably the most relevant PP measurement, S2 or kerogen hydrocarbon-generating potential (mg-HC/g-rock), showed a somewhat wider range of variability than TOC (COV ~10%), but was consistent between the three modern instruments and the industry-standard Rock-Eval 2. Major phase mineralogy (mineral concentrations ≥10 wt. %, organic-free basis) were comparable between laboratories, but variability in minor phase identification and quantification was observed. Utilization of these shale GRMs as quality control samples and testing materials is expected to help support analytical and experimental efforts in the continued development of unconventional petroleum resources.

Colorado, Texas, Oklahoma↗